EP1780483A1 - Cooling box - Google Patents
Cooling box Download PDFInfo
- Publication number
- EP1780483A1 EP1780483A1 EP05758333A EP05758333A EP1780483A1 EP 1780483 A1 EP1780483 A1 EP 1780483A1 EP 05758333 A EP05758333 A EP 05758333A EP 05758333 A EP05758333 A EP 05758333A EP 1780483 A1 EP1780483 A1 EP 1780483A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- temperature
- refrigerating machine
- refrigerant
- heat radiation
- stirling refrigerating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D11/00—Self-contained movable devices, e.g. domestic refrigerators
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B49/00—Arrangement or mounting of control or safety devices
- F25B49/02—Arrangement or mounting of control or safety devices for compression type machines, plants or systems
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
- F25B9/14—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the cycle used, e.g. Stirling cycle
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D29/00—Arrangement or mounting of control or safety devices
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D21/00—Defrosting; Preventing frosting; Removing condensed or defrost water
- F25D21/04—Preventing the formation of frost or condensate
Definitions
- the present invention relates to a cooling box, and particularly to a cooling box incorporating a Stirling refrigerating machine.
- a primary object of the present invention is to provide a cooling box of high reliability.
- a cooling box according to the present invention is a cooling box incorporating a Stirling refrigerating machine, which includes: temperature detection means for detecting a temperature of a warm head of the Stirling refrigerating machine; and control means for controlling such that an increase of the temperature of the warm head is restricted before the Stirling refrigerating machine is stopped, in response to the event that the temperature detected by the temperature detection means has exceeded a predetermined reference temperature.
- a heat radiator receiving hot heat from the warm head of the Stirling refrigerating machine via a refrigerant and performing heat radiation to an environment outside the box; and a heat radiation fan promoting the heat radiation of the heat radiator are further provided.
- the control means maximizes the quantity of air supplied by the heat radiation fan in response to the event that the temperature detected by the temperature detection means has exceeded the reference temperature and, thereafter, reduces an output of the Stirling refrigerating machine when the temperature detected by the temperature detection means does not become lower than the reference temperature even after a lapse of a predetermined time.
- a refrigerant circulation circuit transmitting the hot heat of the warm head to an outer wall surface of the box via the refrigerant to prevent condensation is further provided.
- the control means maximizes the quantity of the refrigerant circulated in the refrigerant circulation circuit in response to the event that the temperature detected by the temperature detection means has exceeded the reference temperature and, thereafter, reduces an output of the Stirling refrigerating machine when the temperature detected by the temperature detection means does not become lower than the reference temperature even after a lapse of a predetermined time.
- a heat radiator receiving hot heat from the warm head of the Stirling refrigerating machine via a refrigerant and performing heat radiation to an environment outside the box; a heat radiation fan promoting the heat radiation of the heat radiator; and a refrigerant circulation circuit transmitting the hot heat of the warm head to an outer wall surface of the box via the refrigerant to prevent condensation are further provided.
- the control means maximizes the quantity of air supplied by the heat radiation fan in response to the event that the temperature detected by the temperature detection means has exceeded the reference temperature and, thereafter, maximizes the quantity of the refrigerant circulated in the refrigerant circulation circuit when the temperature detected by the temperature detection means does not become lower than the reference temperature even after a lapse of a first predetermined time, and reduces an output of the Stirling refrigerating machine when the temperature detected by the temperature detection means does not become lower than the reference temperature even after a lapse of a second predetermined time.
- a heat radiator receiving hot heat from the warm head of the Stirling refrigerating machine via a refrigerant and performing heat radiation to an environment outside the box; a heat radiation fan promoting the heat radiation of the heat radiator; and a refrigerant circulation circuit transmitting the hot heat of the warm head to an outer wall surface of the box via the refrigerant to prevent condensation are further provided.
- the control means maximizes the quantity of the refi-igerant circulated in the refrigerant circulation circuit in response to the event that the temperature detected by the temperature detection means has exceeded the reference temperature and, thereafter, maximizes the quantity of air supplied by the heat radiation fan when the temperature detected by the temperature detection means does not become lower than the reference temperature even after a lapse of a first predetermined time, and reduces an output of the Stirling refrigerating machine when the temperature detected by the temperature detection means does not become lower than the reference temperature even after a lapse of a second predetermined time.
- control means reduces the output of the Stirling refrigerating machine in a stepwise manner in response to the event that the temperature detected by the temperature detection means has exceeded the reference temperature.
- control means stops the Stirling refrigerating machine in response to the event that the temperature detected by the temperature detection means has exceeded a predetermined critical temperature higher than the reference temperature.
- the cooling box further includes inspection means for inspecting whether the temperature detection means is normal or not in response to the event that the temperature detected by the temperature detection means has exceeded the reference temperature.
- the cooling box of the present invention it is controlled to restrict an increase in temperature of the warm head of the Stirling refrigerating machine before stopping the Stirling refrigerating machine in response to the event that the temperature of the warm head has exceeded a reference temperature. Accordingly, it is possible to prevent the cooling box from being stopped abruptly, and thus to increase the reliability of the cooling box.
- the quantity of the air supplied by the heat radiation fan is maximized in response to the event that the temperature of the warm head has exceeded the reference temperature, and thereafter, if the temperature of the warm head does not become lower than the reference temperature even after a lapse of a predetermined time, the output of the Stirling refrigerating machine is reduced.
- the temperature of the warm head can firstly be lowered without increasing the temperature inside the box. This can increase the reliability of the cooling box.
- the quantity of the refrigerant circulated in the refrigerant circulation circuit is maximized in response to the event that the temperature of the warm head has exceeded the reference temperature, and thereafter, if the temperature of the warm head does not become lower than the reference temperature even after a lapse of a predetermined time, the output of the Stirling refrigerating machine is reduced.
- the temperature of the warm head can firstly be lowered without increasing the temperature inside the box, and thus, the reliability of the cooling box can be increased.
- the quantity of the air supplied by the heat radiation fan is maximized in response to the event that the temperature of the warm head has exceeded the reference temperature, and thereafter, if the temperature of the warm head does not become lower than the reference temperature even after a lapse of a first predetermined time, the quantity of the refrigerant circulated in the refrigerant circulation circuit is maximized, and further, if the temperature of the warm head does not become lower than the reference temperature even after a lapse of a second predetermined time, the output of the Stirling refrigerating machine is reduced.
- the temperature of the warm head can firstly be lowered without increasing the temperature inside the box, and thus, the reliability of the cooling box can be increased.
- the quantity of the refrigerant circulated in the refrigerant circulation circuit is maximized in response to the event that the temperature of the warm head has exceeded the reference temperature, and thereafter, if the temperature of the warm head does not become lower than the reference temperature even after a lapse of a first predetermined time, the quantity of the air supplied by the heat radiation fan is maximized, and further, if the temperature of the warm head does not become lower than the reference temperature even after a lapse of a second predetermined time, the output of the Stirling refrigerating machine is reduced.
- the temperature of the warm head can firstly be lowered without increasing the temperature inside the box, and thus, the reliability of the cooling box can be increased.
- the output of the Stirling refrigerating machine is reduced in a stepwise manner. This can restrict the increase in temperature inside the box.
- the Stirling refrigerating machine is stopped in response to the event that the temperature of the warm head has exceeded a critical temperature higher than the reference temperature. This can prevent a failure of the Stirling refrigerating machine.
- inspection means for inspecting whether the temperature detection means is normal or not in response to the event that the temperature detected by the temperature detection means has exceeded the reference temperature. This can prevent malfunction of the cooling box due to a failure of the temperature detection means.
- cooling box 10: housing; 11, 12, 13: cooling compartment; 14, 15, 16: heat insulating door; 17: packing; 18: shelf; 19: machine room; 20: duct; 21: cool air blowoff port; 22: cooling fan; 30: Stirling refrigerating machine; 40: low-temperature side refrigerant circulation circuit; 41: low-temperature side condenser; 42: low-temperature side evaporator; 50, 60: high-temperature side refrigerant circulation circuit; 51: high-temperature side evaporator, 52: high-temperature side condenser; 53: heat radiation fan; 61: circulation pump; 62: condensation preventing section; 70: electric heater; 80: box interior temperature sensor; 81: cold head temperature sensor; 82: warm head temperature sensor; 83: inspection section; 84: reference value storage section; 85: alarm lamp; 86: controller; and 87: timer 87.
- Fig. 1 is a schematic cross sectional view showing a configuration of a cooling box 1 according to an embodiment of the present invention.
- Fig. 2 is a piping configuration diagram of cooling box 1.
- cooling box 1 is for storing food, and is provided with a housing 10 of heat insulating structure. Cooling compartments 11, 12, 13 partitioned into three parts in the vertical direction are provided inside housing 10. Cooling compartments 11, 12, 13 have openings on the front side (left side in Fig. 1) of housing 10, and the openings are closed by heat insulating doors 14, 15, 16, respectively, which can be opened/closed freely.
- a packing 17 is provided on the back surface of each of heat insulating doors 14, 15, 16, in the form surrounding the opening of corresponding one of cooling boxes 11, 12, 13.
- Inside cooling compartments 11, 12, 13, shelves 18 are arranged as appropriate in accordance with the types of food to be stored.
- a cooling system and a heat radiation system having Stirling refrigerating machine 30 as the main element are arranged from the top surface through the back surface to the bottom surface of housing 10.
- a machine room 19 is provided at a corner on the upper back surface of housing 10, and Stirling refrigerating machine 30 is installed therein.
- a part of Stirling refrigerating machine 30 forms a cold head when driven.
- a low-temperature side condenser 41 is attached to the cold head.
- a low-temperature side evaporator 42 is arranged on the back of cooling box 13.
- Low-temperature side condenser 41 and low-temperature side evaporator 42 are connected via a refrigerant pipe, to constitute a low-temperature side refrigerant circulation circuit 40.
- Low-temperature side refrigerant circulation circuit 40 has a natural refrigerant such as CO 2 sealed therein, and heat is given and received by low-temperature side evaporator 42 and low-temperature side condenser 41.
- a duct 20 is provided inside housing 10 for distributing cool air obtained by low-temperature side evaporator 42 to cooling compartments 11, 12, 13.
- Duct 20 has cool air blowoff ports 21 at appropriate positions for communication with cooling compartments 11, 12, 13. Further, cooling fans 22 are arranged inside duct 20 at appropriated positions to forcibly send out the cool air.
- a duct for collecting the air from cooling compartments 11, 12, 13 is provided inside housing 10.
- the duct has a blowoff port at the bottom of low-temperature side evaporator 42, to supply low-temperature side evaporator 42 with the air to be cooled, as shown by an arrow of broken line in Fig. 1.
- Stirling refrigerating machine 30 forms a warm head when driven.
- a high-temperature side evaporator 51 is attached to the warm head.
- a high-temperature side condenser (heat radiator) 52 and a heat radiation fan 53 are provided for performing heat radiation to the environment outside the box.
- High-temperature side evaporator 51 and high-temperature side condenser 52 are connected via a refrigerant pipe, to constitute a high-temperature side refrigerant circulation circuit 50.
- High-temperature side refrigerant circulation circuit 50 has water (including solution) or hydrocarbon-based natural refrigerant sealed therein, and the refrigerant flows within high-temperature side refrigerant circulation circuit 50 by natural circulation.
- High-temperature side evaporator 51 is connected to a high-temperature side refrigerant circulation circuit 60 as well.
- High-temperature side refrigerant circulation circuit 60 has a circulation pump 61 forcibly circulating the refrigerant, and a condensation preventing section 62.
- Circulation pump 61 may be a piezoelectric pump, for example.
- Condensation preventing section 62 is formed with a part of the refrigerant pipe routed through the openings of cooling compartments 11, 12, 13, and is configured to heat the vicinity of the openings where condensation would likely to occur (the vicinity of the contact portions of packing 17 and housing 10, i.e., the boundary area between the interior and the outside of the box) with the hot heat of the refrigerant to thereby prevent condensation.
- An electric heater 70 generating heat when energized is attached to the place where occurrence of condensation is expected but high-temperature side refrigerant circulation circuit 60 cannot be placed for the reasons of manufacture.
- cooling box 1 configured as described above, when Stirling refrigerating machine 30 is driven, the temperature of the cold head decreases. Thus, low-temperature side condenser 41 is cooled, and the refrigerant therein is condensed.
- the refrigerant condensed at low-temperature side condenser 41 flows through low-temperature side refrigerant circulation circuit 40 into low-temperature side evaporator 42.
- the refrigerant flowing into low-temperature side evaporator 42 evaporates with the heat of the air flowing along the outer side of low-temperature side evaporator 42, to thereby reduce the surface temperature of low-temperature side evaporator 42.
- the air flowing through low-temperature side evaporator 42 becomes cool air, which is blown into cooling compartments 11, 12, 13 via cool air blowoff ports 21 of duct 20, so that the temperatures in cooling compartments 11, 12, 13 are lowered. Thereafter, the air within cooling compartments 11, 12, 13 returns to low-temperature side evaporator 42 via a duct not shown.
- the refrigerant evaporated at low-temperature side evaporator 42 returns via low-temperature side refrigerant circulation circuit 40 to low-temperature side condenser 41, where it condenses again with its heat deprived.
- the above-described heat exchange operation is repeated.
- the refrigerant in the gas phase heated at high-temperature side evaporator 51 flows through high-temperature side refrigerant circulation circuit 50 and enters into high-temperature side condenser 52 provided on the top.
- the refrigerant flowing into high-temperature side condenser 52 condenses as its heat is deprived by the airflow introduced from the exterior of the box into high-temperature side condenser 52 by heat radiation fan 53.
- the refrigerant condensed at high-temperature side condenser 52 flows through high-temperature side refrigerant circulation circuit 50 back to high-temperature side evaporator 51, where it evaporates again by receiving the heat.
- the above-described heat exchange operation is repeated.
- the refrigerant in the liquid phase is forcibly circulated by circulation pump 61 to high-temperature side refrigerant circulation circuit 60, and is guided to condensation preventing section 62.
- the vicinity of the openings of cooling compartments 11, 12, 13 is heated with the hot heat of the introduced refrigerant.
- the temperature in the vicinity of the openings where condensation would likely occur can be kept at a level not lower than the dew point to prevent condensation, without unnecessary consumption of electric power.
- electric heater 70 is applied with electricity, so that the temperature at the portion can be kept at a level not lower than the dew point to thereby prevent condensation.
- Fig. 3 is a block diagram showing a portion of cooling box 1 related to operation control.
- cooling box 1 includes a box interior temperature sensor 80, a cold head temperature sensor 81, a warm head temperature sensor 82, an inspection section 83, a reference value storage section 84, an alarm lamp 85, and a controller 86.
- Controller 86 includes a timer 87.
- Box interior temperature sensor 80 is arranged at a prescribed position on a surface of duct 20 on the box interior side, for example, and detects the temperature of the space inside the box and provides a signal indicating the detected value to controller 86.
- Cold head temperature sensor 81 is provided at the cold head of Stirling refrigerating machine 30, and detects the temperature of the cold head and provides a signal indicating the detected value to controller 86.
- Warm head temperature sensor 82 is provided at the warm head of Stirling refrigerating machine 30, and detects the temperature Th of the warm head and provides a signal indicating the detected value to controller 86.
- Inspection section 83 carries out an inspection as to whether warm head temperature sensor 82 is normal or not, and provides a signal indicating the result of inspection to controller 86.
- Reference value storage section 84 is formed of a read only memory such as a ROM, and stores a reference temperature of the space inside the box, a reference temperature of the cold head, a reference temperature Th1 of the warm head, and a critical temperature Th2 of the warm head.
- Alarm lamp 85 is provided on the external surface of heat insulating door 14, for example, and turns on when cooling box 1 fails to operate properly to notify the user of the failure of cooling box 1.
- Controller 86 controls Stirling refrigerating machine 10, heat radiation fan 53, circulation pump 61 and alarm lamp 85 based on various kinds of information from temperature sensors 80-82, inspection section 83 and reference value storage section 84.
- Figs. 4 and 5 are flowcharts illustrating an operation of controller 86.
- Controller 86 controls the output of Stirling refrigerating machine 10 such that the detected values of temperature sensors 80-82 coincide with the reference values stored in reference value storage section 84, and also controls the rotation speed of heat radiation fan 53, i.e., the quantity of air supplied thereby.
- Controller 86 further controls the output of circulation pump 61, i. e., the quantity of the refrigerant circulated in high-temperature side refrigerant circulation circuit 60.
- controller 86 determines whether the temperature Th of the warm head is higher than the reference temperature Th1 stored in reference value storage section 84, and if it is not Th > Th1, it carries out step S1 again. If Th > Th1, it proceeds to step S2. In step S2, controller 86 causes inspection section 83 to carry out an inspection as to whether warm head temperature sensor 82 is normal or not. Inspection section 83 checks whether warm head temperature sensor 82 is normal or not, and provides a signal indicating the result of inspection to controller 86.
- controller 86 determines whether warm head temperature sensor 82 is normal or not based on the signal from inspection section 83, and if warm head temperature sensor 82 is not normal, it performs temperature sensor abnormality notification processing in step S4, such as turning on of alarm lamp 85, while it proceeds to step S5 if it is normal.
- step S5 controller 86 determines whether the rotation speed of heat radiation fan 53 is maximum or not, and if it is not maximum, it maximizes the rotation speed of heat radiation fan 53 in step S6.
- step S7 it awaits a lapse of a predetermined time, and then proceeds to step S12. If the rotation speed of heat radiation fan 53 is maximum, it proceeds to step S8.
- Timer 87 is used to count the predetermined time.
- controller 86 determines whether the output of circulation pump 61 is maximum or not, and if it is not maximum, it maximizes the output of circulation pump 61 in step S9. In step S10, it awaits a lapse of a predetermined time, and then proceeds to step S12. If the output of circulation pump 61 is maximum, it reduces the output of Stirling refrigerating machine 30 in step S11, and then proceeds to step S12. In step S 11, controller 86 reduces the output of Stirling refrigerating machine 30 from the current value to the minimum value stepwise over a plurality of number of times.
- step S 12 controller 86 determines whether temperature Th of the warm head is higher than reference temperature Th1 stored in reference value storage section 84, and if Th > Th1 does not hold, it returns to step S1. If Th > Th1, it proceeds to step S 13. In step S 13, controller 86 determines whether the output of Stirling refrigerating machine 30 is minimum or not. If it is not minimum, it returns to step S8. If it is minimum, it proceeds to step S 14.
- step S 14 controller 86 determines whether temperature Th of the warm head is higher than critical temperature Th2 stored in reference value storage section 84. If Th > Th2 does not hold, it returns to step S8. If Th > Th1, it proceeds to step S15.
- step S 15 controller 86 performs the warm head abnormality display processing, such as turning on of alarm lamp 85 or the like.
- step S16 it stops Stirling refrigerating machine 30, and returns to step S1.
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Abstract
The controller (86) of a cooling box is configured such that when the temperature (Th) of the warm head of a Stirling refrigerating machine (30) exceeds a reference temperature (Th1), it maximizes the speed of a heat radiation fan (53) and the output of a circulation pump (61), and minimizes the output of the Stirling refrigerating machine (30). If the temperature (Th) of the warm head exceeds a critical temperature (Th2) even after this control, it stops the Stirling refrigerating machine (30). Therefore, as compared with the case of stopping the Stirling refrigerating machine (30) immediately after the temperature (Th) of the warm head has exceeded the critical temperature (Th2), the reliability of the cooling box can be improved.
Description
- The present invention relates to a cooling box, and particularly to a cooling box incorporating a Stirling refrigerating machine.
- In recent years, adverse effects of the chlorofluorocarbons on the global environment have been pointed out, and as a cooling box that does not use the chlorofluorocarbons, one provided with a Stirling refrigerating machine has attracted attention. In this cooling box, the space inside the box is cooled by cold heat of the cold head of the Stirling refrigerating machine, while hot heat of the warm head of the Stirling refrigerating machine is radiated to the environment outside the box (see, for example,
Japanese Patent Laying-Open No. 2002-221384
Patent Document 1:Japanese Patent Laying-Open No. 2002-221384 - In such a cooling box, if the temperature of the warm head of the Stirling refrigerating machine increases by some reason to reach a critical temperature, it may be possible to stop the Stirling refrigerating machine immediately. With this control method, however, the operation of the cooling box will be stopped abruptly, which leads to impairment of reliability of the cooling box.
- Accordingly, a primary object of the present invention is to provide a cooling box of high reliability.
- A cooling box according to the present invention is a cooling box incorporating a Stirling refrigerating machine, which includes: temperature detection means for detecting a temperature of a warm head of the Stirling refrigerating machine; and control means for controlling such that an increase of the temperature of the warm head is restricted before the Stirling refrigerating machine is stopped, in response to the event that the temperature detected by the temperature detection means has exceeded a predetermined reference temperature.
- Preferably, a heat radiator receiving hot heat from the warm head of the Stirling refrigerating machine via a refrigerant and performing heat radiation to an environment outside the box; and a heat radiation fan promoting the heat radiation of the heat radiator are further provided. The control means maximizes the quantity of air supplied by the heat radiation fan in response to the event that the temperature detected by the temperature detection means has exceeded the reference temperature and, thereafter, reduces an output of the Stirling refrigerating machine when the temperature detected by the temperature detection means does not become lower than the reference temperature even after a lapse of a predetermined time.
- Further, preferably, a refrigerant circulation circuit transmitting the hot heat of the warm head to an outer wall surface of the box via the refrigerant to prevent condensation is further provided. The control means maximizes the quantity of the refrigerant circulated in the refrigerant circulation circuit in response to the event that the temperature detected by the temperature detection means has exceeded the reference temperature and, thereafter, reduces an output of the Stirling refrigerating machine when the temperature detected by the temperature detection means does not become lower than the reference temperature even after a lapse of a predetermined time.
- Further, preferably, a heat radiator receiving hot heat from the warm head of the Stirling refrigerating machine via a refrigerant and performing heat radiation to an environment outside the box; a heat radiation fan promoting the heat radiation of the heat radiator; and a refrigerant circulation circuit transmitting the hot heat of the warm head to an outer wall surface of the box via the refrigerant to prevent condensation are further provided. The control means maximizes the quantity of air supplied by the heat radiation fan in response to the event that the temperature detected by the temperature detection means has exceeded the reference temperature and, thereafter, maximizes the quantity of the refrigerant circulated in the refrigerant circulation circuit when the temperature detected by the temperature detection means does not become lower than the reference temperature even after a lapse of a first predetermined time, and reduces an output of the Stirling refrigerating machine when the temperature detected by the temperature detection means does not become lower than the reference temperature even after a lapse of a second predetermined time.
- Further, preferably, a heat radiator receiving hot heat from the warm head of the Stirling refrigerating machine via a refrigerant and performing heat radiation to an environment outside the box; a heat radiation fan promoting the heat radiation of the heat radiator; and a refrigerant circulation circuit transmitting the hot heat of the warm head to an outer wall surface of the box via the refrigerant to prevent condensation are further provided. The control means maximizes the quantity of the refi-igerant circulated in the refrigerant circulation circuit in response to the event that the temperature detected by the temperature detection means has exceeded the reference temperature and, thereafter, maximizes the quantity of air supplied by the heat radiation fan when the temperature detected by the temperature detection means does not become lower than the reference temperature even after a lapse of a first predetermined time, and reduces an output of the Stirling refrigerating machine when the temperature detected by the temperature detection means does not become lower than the reference temperature even after a lapse of a second predetermined time.
- Preferably, the control means reduces the output of the Stirling refrigerating machine in a stepwise manner in response to the event that the temperature detected by the temperature detection means has exceeded the reference temperature.
- Still preferably, the control means stops the Stirling refrigerating machine in response to the event that the temperature detected by the temperature detection means has exceeded a predetermined critical temperature higher than the reference temperature.
- Still preferably, the cooling box further includes inspection means for inspecting whether the temperature detection means is normal or not in response to the event that the temperature detected by the temperature detection means has exceeded the reference temperature.
- In the cooling box of the present invention, it is controlled to restrict an increase in temperature of the warm head of the Stirling refrigerating machine before stopping the Stirling refrigerating machine in response to the event that the temperature of the warm head has exceeded a reference temperature. Accordingly, it is possible to prevent the cooling box from being stopped abruptly, and thus to increase the reliability of the cooling box.
- Preferably, the quantity of the air supplied by the heat radiation fan is maximized in response to the event that the temperature of the warm head has exceeded the reference temperature, and thereafter, if the temperature of the warm head does not become lower than the reference temperature even after a lapse of a predetermined time, the output of the Stirling refrigerating machine is reduced. In this case, the temperature of the warm head can firstly be lowered without increasing the temperature inside the box. This can increase the reliability of the cooling box.
- Still preferably, the quantity of the refrigerant circulated in the refrigerant circulation circuit is maximized in response to the event that the temperature of the warm head has exceeded the reference temperature, and thereafter, if the temperature of the warm head does not become lower than the reference temperature even after a lapse of a predetermined time, the output of the Stirling refrigerating machine is reduced. In this case as well, the temperature of the warm head can firstly be lowered without increasing the temperature inside the box, and thus, the reliability of the cooling box can be increased.
- Still preferably, the quantity of the air supplied by the heat radiation fan is maximized in response to the event that the temperature of the warm head has exceeded the reference temperature, and thereafter, if the temperature of the warm head does not become lower than the reference temperature even after a lapse of a first predetermined time, the quantity of the refrigerant circulated in the refrigerant circulation circuit is maximized, and further, if the temperature of the warm head does not become lower than the reference temperature even after a lapse of a second predetermined time, the output of the Stirling refrigerating machine is reduced. In this case as well, the temperature of the warm head can firstly be lowered without increasing the temperature inside the box, and thus, the reliability of the cooling box can be increased.
- Still preferably, the quantity of the refrigerant circulated in the refrigerant circulation circuit is maximized in response to the event that the temperature of the warm head has exceeded the reference temperature, and thereafter, if the temperature of the warm head does not become lower than the reference temperature even after a lapse of a first predetermined time, the quantity of the air supplied by the heat radiation fan is maximized, and further, if the temperature of the warm head does not become lower than the reference temperature even after a lapse of a second predetermined time, the output of the Stirling refrigerating machine is reduced. In this case as well, the temperature of the warm head can firstly be lowered without increasing the temperature inside the box, and thus, the reliability of the cooling box can be increased.
- Preferably, the output of the Stirling refrigerating machine is reduced in a stepwise manner. This can restrict the increase in temperature inside the box.
- Still preferably, the Stirling refrigerating machine is stopped in response to the event that the temperature of the warm head has exceeded a critical temperature higher than the reference temperature. This can prevent a failure of the Stirling refrigerating machine.
- Still preferably, there is further provided inspection means for inspecting whether the temperature detection means is normal or not in response to the event that the temperature detected by the temperature detection means has exceeded the reference temperature. This can prevent malfunction of the cooling box due to a failure of the temperature detection means.
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- Fig. 1 is a cross sectional view showing a configuration of a cooling box according to an embodiment of the present invention.
- Fig. 2 is a piping configuration diagram of the cooling box shown in Fig. 1.
- Fig. 3 is a block diagram showing a configuration of a part related to operation control of the cooling box shown in Fig. 1.
- Fig. 4 is a part of a flowchart showing an operation of the controller shown in Fig. 3.
- Fig. 5 is the other part of the flowchart shown in Fig. 4.
- 1: cooling box; 10: housing; 11, 12, 13: cooling compartment; 14, 15, 16: heat insulating door; 17: packing; 18: shelf; 19: machine room; 20: duct; 21: cool air blowoff port; 22: cooling fan; 30: Stirling refrigerating machine; 40: low-temperature side refrigerant circulation circuit; 41: low-temperature side condenser; 42: low-temperature side evaporator; 50, 60: high-temperature side refrigerant circulation circuit; 51: high-temperature side evaporator, 52: high-temperature side condenser; 53: heat radiation fan; 61: circulation pump; 62: condensation preventing section; 70: electric heater; 80: box interior temperature sensor; 81: cold head temperature sensor; 82: warm head temperature sensor; 83: inspection section; 84: reference value storage section; 85: alarm lamp; 86: controller; and 87:
timer 87. - Fig. 1 is a schematic cross sectional view showing a configuration of a
cooling box 1 according to an embodiment of the present invention. Fig. 2 is a piping configuration diagram ofcooling box 1. Referring to Figs. 1 and 2,cooling box 1 is for storing food, and is provided with ahousing 10 of heat insulating structure.Cooling compartments housing 10.Cooling compartments housing 10, and the openings are closed byheat insulating doors packing 17 is provided on the back surface of each ofheat insulating doors cooling boxes cooling compartments shelves 18 are arranged as appropriate in accordance with the types of food to be stored. - A cooling system and a heat radiation system having Stirling refrigerating
machine 30 as the main element are arranged from the top surface through the back surface to the bottom surface ofhousing 10. Amachine room 19 is provided at a corner on the upper back surface ofhousing 10, and Stirling refrigeratingmachine 30 is installed therein. - A part of Stirling refrigerating
machine 30 forms a cold head when driven. A low-temperature side condenser 41 is attached to the cold head. Further, a low-temperature side evaporator 42 is arranged on the back ofcooling box 13. Low-temperature side condenser 41 and low-temperature side evaporator 42 are connected via a refrigerant pipe, to constitute a low-temperature siderefrigerant circulation circuit 40. Low-temperature siderefrigerant circulation circuit 40 has a natural refrigerant such as CO2 sealed therein, and heat is given and received by low-temperature side evaporator 42 and low-temperature side condenser 41. - A
duct 20 is provided insidehousing 10 for distributing cool air obtained by low-temperature side evaporator 42 tocooling compartments Duct 20 has coolair blowoff ports 21 at appropriate positions for communication with coolingcompartments fans 22 are arranged insideduct 20 at appropriated positions to forcibly send out the cool air. - Although not shown in the figure, a duct for collecting the air from cooling
compartments housing 10. The duct has a blowoff port at the bottom of low-temperature side evaporator 42, to supply low-temperature side evaporator 42 with the air to be cooled, as shown by an arrow of broken line in Fig. 1. - Another part of
Stirling refrigerating machine 30 forms a warm head when driven. A high-temperature side evaporator 51 is attached to the warm head. Further, at the upper surface ofhousing 10, a high-temperature side condenser (heat radiator) 52 and aheat radiation fan 53 are provided for performing heat radiation to the environment outside the box. High-temperature side evaporator 51 and high-temperature side condenser 52 are connected via a refrigerant pipe, to constitute a high-temperature siderefrigerant circulation circuit 50. High-temperature siderefrigerant circulation circuit 50 has water (including solution) or hydrocarbon-based natural refrigerant sealed therein, and the refrigerant flows within high-temperature siderefrigerant circulation circuit 50 by natural circulation. - High-
temperature side evaporator 51 is connected to a high-temperature siderefrigerant circulation circuit 60 as well. High-temperature siderefrigerant circulation circuit 60 has acirculation pump 61 forcibly circulating the refrigerant, and acondensation preventing section 62.Circulation pump 61 may be a piezoelectric pump, for example.Condensation preventing section 62 is formed with a part of the refrigerant pipe routed through the openings of coolingcompartments housing 10, i.e., the boundary area between the interior and the outside of the box) with the hot heat of the refrigerant to thereby prevent condensation. Anelectric heater 70 generating heat when energized is attached to the place where occurrence of condensation is expected but high-temperature siderefrigerant circulation circuit 60 cannot be placed for the reasons of manufacture. - Hereinafter, an operation of
cooling box 1 having the above configuration will be described. Incooling box 1 configured as described above, whenStirling refrigerating machine 30 is driven, the temperature of the cold head decreases. Thus, low-temperature side condenser 41 is cooled, and the refrigerant therein is condensed. - The refrigerant condensed at low-
temperature side condenser 41 flows through low-temperature siderefrigerant circulation circuit 40 into low-temperature side evaporator 42. The refrigerant flowing into low-temperature side evaporator 42 evaporates with the heat of the air flowing along the outer side of low-temperature side evaporator 42, to thereby reduce the surface temperature of low-temperature side evaporator 42. Thus, the air flowing through low-temperature side evaporator 42 becomes cool air, which is blown into coolingcompartments air blowoff ports 21 ofduct 20, so that the temperatures in coolingcompartments - The refrigerant evaporated at low-temperature side evaporator 42 returns via low-temperature side
refrigerant circulation circuit 40 to low-temperature side condenser 41, where it condenses again with its heat deprived. The above-described heat exchange operation is repeated. - Meanwhile, the heat produced by driving of
Stirling refrigerating machine 30 and the heat collected from the interior of the box by the cold head are dissipated from the warm head as exhaust heat. Thus, high-temperature side evaporator 51 is heated, and the refrigerant therein evaporates. - The refrigerant in the gas phase heated at high-temperature side evaporator 51 flows through high-temperature side
refrigerant circulation circuit 50 and enters into high-temperature side condenser 52 provided on the top. The refrigerant flowing into high-temperature side condenser 52 condenses as its heat is deprived by the airflow introduced from the exterior of the box into high-temperature side condenser 52 byheat radiation fan 53. The refrigerant condensed at high-temperature side condenser 52 flows through high-temperature siderefrigerant circulation circuit 50 back to high-temperature side evaporator 51, where it evaporates again by receiving the heat. The above-described heat exchange operation is repeated. - Of the refrigerant saturated inside high-
temperature side evaporator 51, the refrigerant in the liquid phase is forcibly circulated bycirculation pump 61 to high-temperature siderefrigerant circulation circuit 60, and is guided tocondensation preventing section 62. Thus, the vicinity of the openings of coolingcompartments refrigerant circulation circuit 60 cannot be routed,electric heater 70 is applied with electricity, so that the temperature at the portion can be kept at a level not lower than the dew point to thereby prevent condensation. - Fig. 3 is a block diagram showing a portion of
cooling box 1 related to operation control. In Fig. 3,cooling box 1 includes a boxinterior temperature sensor 80, a coldhead temperature sensor 81, a warmhead temperature sensor 82, aninspection section 83, a referencevalue storage section 84, analarm lamp 85, and acontroller 86.Controller 86 includes atimer 87. - Box
interior temperature sensor 80 is arranged at a prescribed position on a surface ofduct 20 on the box interior side, for example, and detects the temperature of the space inside the box and provides a signal indicating the detected value tocontroller 86. Coldhead temperature sensor 81 is provided at the cold head ofStirling refrigerating machine 30, and detects the temperature of the cold head and provides a signal indicating the detected value tocontroller 86. Warmhead temperature sensor 82 is provided at the warm head ofStirling refrigerating machine 30, and detects the temperature Th of the warm head and provides a signal indicating the detected value tocontroller 86. -
Inspection section 83 carries out an inspection as to whether warmhead temperature sensor 82 is normal or not, and provides a signal indicating the result of inspection tocontroller 86. Referencevalue storage section 84 is formed of a read only memory such as a ROM, and stores a reference temperature of the space inside the box, a reference temperature of the cold head, a reference temperature Th1 of the warm head, and a critical temperature Th2 of the warm head. -
Alarm lamp 85 is provided on the external surface ofheat insulating door 14, for example, and turns on when coolingbox 1 fails to operate properly to notify the user of the failure ofcooling box 1.Controller 86 controlsStirling refrigerating machine 10,heat radiation fan 53,circulation pump 61 andalarm lamp 85 based on various kinds of information from temperature sensors 80-82,inspection section 83 and referencevalue storage section 84. - Figs. 4 and 5 are flowcharts illustrating an operation of
controller 86.Controller 86 controls the output ofStirling refrigerating machine 10 such that the detected values of temperature sensors 80-82 coincide with the reference values stored in referencevalue storage section 84, and also controls the rotation speed ofheat radiation fan 53, i.e., the quantity of air supplied thereby.Controller 86 further controls the output ofcirculation pump 61, i. e., the quantity of the refrigerant circulated in high-temperature siderefrigerant circulation circuit 60. - Further, in step S1,
controller 86 determines whether the temperature Th of the warm head is higher than the reference temperature Th1 stored in referencevalue storage section 84, and if it is not Th > Th1, it carries out step S1 again. If Th > Th1, it proceeds to step S2. In step S2,controller 86causes inspection section 83 to carry out an inspection as to whether warmhead temperature sensor 82 is normal or not.Inspection section 83 checks whether warmhead temperature sensor 82 is normal or not, and provides a signal indicating the result of inspection tocontroller 86. - In step S3,
controller 86 determines whether warmhead temperature sensor 82 is normal or not based on the signal frominspection section 83, and if warmhead temperature sensor 82 is not normal, it performs temperature sensor abnormality notification processing in step S4, such as turning on ofalarm lamp 85, while it proceeds to step S5 if it is normal. - In step S5,
controller 86 determines whether the rotation speed ofheat radiation fan 53 is maximum or not, and if it is not maximum, it maximizes the rotation speed ofheat radiation fan 53 in step S6. In step S7, it awaits a lapse of a predetermined time, and then proceeds to step S12. If the rotation speed ofheat radiation fan 53 is maximum, it proceeds to step S8.Timer 87 is used to count the predetermined time. - In step S8,
controller 86 determines whether the output ofcirculation pump 61 is maximum or not, and if it is not maximum, it maximizes the output ofcirculation pump 61 in step S9. In step S10, it awaits a lapse of a predetermined time, and then proceeds to step S12. If the output ofcirculation pump 61 is maximum, it reduces the output ofStirling refrigerating machine 30 in step S11, and then proceeds to step S12. Instep S 11,controller 86 reduces the output ofStirling refrigerating machine 30 from the current value to the minimum value stepwise over a plurality of number of times. - In
step S 12,controller 86 determines whether temperature Th of the warm head is higher than reference temperature Th1 stored in referencevalue storage section 84, and if Th > Th1 does not hold, it returns to step S1. If Th > Th1, it proceeds to stepS 13. Instep S 13,controller 86 determines whether the output ofStirling refrigerating machine 30 is minimum or not. If it is not minimum, it returns to step S8. If it is minimum, it proceeds to stepS 14. - In
step S 14,controller 86 determines whether temperature Th of the warm head is higher than critical temperature Th2 stored in referencevalue storage section 84. If Th > Th2 does not hold, it returns to step S8. If Th > Th1, it proceeds to step S15. - In
step S 15,controller 86 performs the warm head abnormality display processing, such as turning on ofalarm lamp 85 or the like. In step S16, it stopsStirling refrigerating machine 30, and returns to step S1. - In the present embodiment, when temperature Th of the warm head exceeds reference temperature Th1, the rotation speed of
heat radiation fan 53 is maximized, the output ofcirculation pump 61 is maximized, and the output ofStirling refrigerating machine 30 is minimized. If temperature Th of the warm head still exceeds critical temperature Th2,Stirling refrigerating machine 30 is stopped. As such, compared to the case whereStirling refrigerating machine 30 is stopped immediately after temperature Th of the warm head exceeds critical temperature Th2, the reliability ofcooling box 1 can be increased. - Although the rotation speed of
heat radiation fan 53 has been maximized after maximization of the output ofcirculation pump 61 in the present embodiment, it is possible to maximize the output ofheat radiation fan 53 after maximization of the output ofcirculation pump 61. - It should be understood that the embodiments disclosed herein are illustrative and non-restrictive in every respect. The scope of the present invention is defined by the terms of the claims, rather than the description and example above, and is intended to include any modifications and changes within the scope and meaning equivalent to the terms of the claims.
Claims (6)
- A cooling box incorporating a Stirling refrigerating machine (30), comprising:temperature detection means (82) for detecting a temperature of a warm head of said Stirling refrigerating machine (30); andcontrol means (86) for controlling such that an increase of the temperature of said warm head is restricted before stopping of said Stirling refrigerating machine (30), in response to the event that a detected temperature (Th) of said temperature detection means (82) has exceeded a predetermined reference temperature (Th1).
- The cooling box according to claim 1, further comprising:a heat radiator (42) receiving hot heat from the warm head of said Stirling refi-igerating machine (30) via a refi-igerant and performing heat radiation to an environment outside the box; anda heat radiation fan (53) promoting the heat radiation of said heat radiator (42), whereinsaid control means (86) is adapted tomaximize (S6) the quantity of air supplied by said heat radiation fan (53) in response to the event that the detected temperature (Th) of said temperature detection means (82) has exceeded said reference temperature (Th1), andthereafter, reduce (S11) an output of said Stirling refrigerating machine (30) when the detected temperature (Th) of said temperature detection means (82) does not become lower than said reference temperature (Th1) even after a lapse of a predetermined time.
- The cooling box according to claim 1, further comprising a refrigerant circulation circuit (60) transmitting hot heat of said warm head via a refrigerant to an outer wall surface of the box to prevent condensation, wherein
said control means (86) is adapted to
maximize (S9) the quantity of the refrigerant circulated in said refrigerant circulation circuit (60) in response to the event that the detected temperature (Th) of said temperature detection means (82) has exceeded said reference temperature (Th1), and
thereafter, reduce (S11) an output of said Stirling refrigerating machine (30) when the detected temperature (Th) of said temperature detection means (82) does not become lower than said reference temperature (Th1) even after a lapse of a predetermined time. - The cooling box according to claim 1, further comprising:a heat radiator (42) receiving hot heat from the warm head of said Stirling refrigerating machine (30) via a refrigerant and performing heat radiation to an environment outside the box;a heat radiation fan (53) promoting the heat radiation of said heat radiator (42); anda refrigerant circulation circuit (60) transmitting the hot heat of said warm head via the refrigerant to an outer wall surface of the box to prevent condensation, whereinsaid control means (86) is adapted tomaximize (S6) the quantity of air supplied by said heat radiation fan (53) in response to the event that the detected temperature (Th) of said temperature detection means (82) has exceeded said reference temperature (Th1), andthereafter, maximize (S9) the quantity of the refrigerant circulated in said refrigerant circulation circuit (60) when the detected temperature (Th) of said temperature detection means (82) does not become lower than said reference temperature (Th1) even after a lapse of a first predetermined time, andfurther, reduce (S11) an output of said Stirling refrigerating machine (30) when the detected temperature (Th) of said temperature detection means (82) does not become lower than said reference temperature (Th1) even after a lapse of a second predetermined time.
- The cooling box according to claim 1, further comprising:a heat radiator (42) receiving hot heat from the warm head of said Stirling refrigerating machine (30) via a refrigerant and performing heat radiation to an environment outside the box;a heat radiation fan (53) promoting the heat radiation of said heat radiator (42); anda refrigerant circulation circuit (60) transmitting the hot heat of said warm head via the refrigerant to an outer wall surface of the box to prevent condensation, whereinsaid control means (86) is adapted tomaximize (S9) the quantity of the refrigerant circulated in said refrigerant circulation circuit (60) in response to the event that the detected temperature (Th) of said temperature detection means (82) has exceeded said reference temperature (Th1), andthereafter, maximize (S6) the quantity of air supplied by said heat radiation fan (53) when the detected temperature (Th) of said temperature detection means (82) does not become lower than said reference temperature (Th1) even after a lapse of a first predetermined time, andfurther, reduce (S11) an output of said Stirling refrigerating machine (30) when the detected temperature (Th) of said temperature detection means (82) does not become lower than said reference temperature (Th1) even after a lapse of a second predetermined time.
- The cooling box according to claim 1, wherein said control means (86) reduces (S11) the output of said Stirling refrigerating machine (30) in a stepwise manner.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004221611A JP3796505B2 (en) | 2004-07-29 | 2004-07-29 | Refrigerator |
PCT/JP2005/012556 WO2006011344A1 (en) | 2004-07-29 | 2005-07-07 | Cooling box |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1780483A1 true EP1780483A1 (en) | 2007-05-02 |
Family
ID=35786095
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05758333A Withdrawn EP1780483A1 (en) | 2004-07-29 | 2005-07-07 | Cooling box |
Country Status (6)
Country | Link |
---|---|
US (1) | US20070245747A1 (en) |
EP (1) | EP1780483A1 (en) |
JP (1) | JP3796505B2 (en) |
KR (1) | KR20070042561A (en) |
CN (1) | CN1993590A (en) |
WO (1) | WO2006011344A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010082828A2 (en) * | 2009-01-18 | 2010-07-22 | Matthijs Dirk Meulenbelt | Cooling device |
CN115218602B (en) * | 2022-06-27 | 2023-08-11 | 青岛海尔生物医疗股份有限公司 | Method and device for controlling temperature of refrigerator, refrigerator and storage medium |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW426798B (en) * | 1998-02-06 | 2001-03-21 | Sanyo Electric Co | Stirling apparatus |
JP2000018746A (en) * | 1998-06-30 | 2000-01-18 | Sanyo Electric Co Ltd | Stirling chiller |
JP2002079828A (en) * | 2000-09-07 | 2002-03-19 | Suzuki Motor Corp | Air-conditioner for electric vehicle |
JP4070499B2 (en) * | 2002-04-19 | 2008-04-02 | シャープ株式会社 | Operation method of Stirling cooling device and Stirling refrigerator using the same |
US6550270B2 (en) * | 2002-05-24 | 2003-04-22 | The Coca-Cola Company | Seal compression mechanism for a refrigeration device |
JP2004101050A (en) * | 2002-09-09 | 2004-04-02 | Sharp Corp | Cooling warehouse |
US20050166601A1 (en) * | 2004-02-03 | 2005-08-04 | The Coleman Company, Inc. | Portable insulated container incorporating stirling cooler refrigeration |
-
2004
- 2004-07-29 JP JP2004221611A patent/JP3796505B2/en not_active Expired - Fee Related
-
2005
- 2005-07-07 US US11/628,656 patent/US20070245747A1/en not_active Abandoned
- 2005-07-07 EP EP05758333A patent/EP1780483A1/en not_active Withdrawn
- 2005-07-07 CN CNA2005800256229A patent/CN1993590A/en active Pending
- 2005-07-07 KR KR1020077004616A patent/KR20070042561A/en not_active Application Discontinuation
- 2005-07-07 WO PCT/JP2005/012556 patent/WO2006011344A1/en not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO2006011344A1 * |
Also Published As
Publication number | Publication date |
---|---|
JP3796505B2 (en) | 2006-07-12 |
KR20070042561A (en) | 2007-04-23 |
US20070245747A1 (en) | 2007-10-25 |
WO2006011344A1 (en) | 2006-02-02 |
CN1993590A (en) | 2007-07-04 |
JP2006038384A (en) | 2006-02-09 |
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