EP1559402A1 - Hairwax product made of silicone wax, a silicone-free wax and oils. - Google Patents
Hairwax product made of silicone wax, a silicone-free wax and oils. Download PDFInfo
- Publication number
- EP1559402A1 EP1559402A1 EP05000097A EP05000097A EP1559402A1 EP 1559402 A1 EP1559402 A1 EP 1559402A1 EP 05000097 A EP05000097 A EP 05000097A EP 05000097 A EP05000097 A EP 05000097A EP 1559402 A1 EP1559402 A1 EP 1559402A1
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- EP
- European Patent Office
- Prior art keywords
- wax
- hair
- waxes
- silicone
- product according
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
Definitions
- the invention relates to a wax product for treatment or creation of the human hairstyle.
- the wax product consists a composition containing one of Room temperature solid, silicone-free wax, one at room temperature liquid oil and a silicone wax with one Melting point near the human body temperature.
- Styling wax compositions are known products for Hair treatment. You will find particular application to short to bring medium-length hair trend-fit in shape and the Hairstyle Hold, stand and strengthen as well as give shine. Also, with hair waxing contours and texture in the Create hairstyle. Conventional hair waxes usually become offered in crucibles and are based on the following principle: The removal of the product mass is done with the fingers. The wax is distributed in the palms and through the Hand heat melted or at least strongly softened. By the softening or melting is the incorporation of the otherwise allows for firm wax in the hair. in the softened or more or less liquid state becomes that Wax incorporated into the hair. It cools down in the hair and regains its initial consistency.
- the task was to a solid hair wax product for To provide, which when rubbed with the hands to a softened or liquid, smooth, not or As low as possible sticky consistency melts and the Hair after application of the product natural and flexible remains and emphasizes curls or single strands of hair can be.
- the product should be good for the packaging material removable and easy to process and good application properties have on the hair, especially good Workability, good distributability and good hairstyle definition and the hairstyle shine, hold, solidification or state to lend.
- the waxy consistency is characterized in that the needle penetration number (unit 0.1 mm, test weight Including guide rod 25 g, test duration 5 s, test temperature 20 ° C; Geometry of the hollow cone as in DIN 51 580) preferably greater than or equal to 10, especially from 10 to 60, from 15 to 55 or from 25 to 50 and that the product has a Has solidification point, which is preferably greater or is equal to 30 ° C, and more preferably in the range of 40 to 55 ° C is.
- the silicone-free waxes are preferably in an amount from 10 to 40% by weight, in particular from 15 to 30 or from 15 used to 25 wt.%. You have a freezing point preferably above 40 ° C or above 55 ° C.
- the Needle penetration number is preferably in the range of 2 to 70, in particular from 3 to 40.
- Suitable silicone-free waxes are e.g. animal waxes, vegetable waxes, mineral waxes, synthetic Waxes, microcrystalline waxes, macrocrystalline waxes, Paraffin waxes, ozokerite, montan waxes, Fischer-Tropsch waxes, Polyolefin waxes (e.g., polyethylene, polybutene, and similar), beeswax, wool wax (lanolin) and its Derivatives such as e.g. Wool wax alcohols, candelilla wax, Carnauba wax, Japan wax, hydrogenated fats, fatty acid esters and fatty acid glycerides.
- a preferred embodiment contains hydrocarbon waxes as silicone-free waxes, e.g. Ozokerite or ceresin, in particular with a needle penetration number less than 20.
- the liquid, hydrophobic oils are preferably in one Amount of 20 to 80% by weight, in particular from 30 to 70 or used from 40 to 55 wt.%. They have a melting point of less than or equal to 25 ° C and a boiling point of preferably above 250 ° C, especially above 300 ° C. Therefor can in principle be any oil well known to the skilled person be used. Preferably, these are silicone compounds. Suitable silicone oils are e.g. linear polydimethylsiloxanes (Dimethicones), cyclic polydimethylsiloxanes (Cyclomethicones), hydroxy-substituted polydimethylsiloxanes (Dimethiconols), amino-substituted silicones (e.g. Amodimethicone) and substituted with aromatic groups Siloxanes (e.g., phenylated silicones, polyphenylmethylsiloxanes, Phenyltrimethicones).
- Suitable silicone oils are e.g
- hydrophobic, silicone-free Oils are used.
- herbal or animal oils mineral oils (Paraffinum liquidum) or their mixtures.
- Suitable are hydrocarbon oils, e.g. Paraffin or isoparaffin oils, squalane, fatty acid oils and polyols, especially triglycerides.
- Suitable herbal Oils are e.g. Sunflower oil, coconut oil, castor oil, Lanolin oil, jojoba oil, corn oil, soybean oil.
- the silicone waxes are preferably used in an amount of from 5 to 40% by weight, in particular from 10 to 25 or from 10 to 20% by weight. They have a melting point in the range of 20 to 45 ° C, preferably in the range of 25 to 40 or to 35 ° C.
- the silicone waxes are preferably selected from alkylmethyl-dimethylsiloxanes, in particular those in which the alkyl group has at least 8 C atoms, for example 16 to 20 C atoms.
- Alkylmethyl-dimethylsiloxanes have the general formula Me 3 SiO- [Si (Me) RO-] x - [SiMe 2 -O-] y -SiMe 3 where Me is a methyl group and R is an alkyl group having preferably 8 to 22 carbon atoms and x and y numbers are greater than 0.
- a preferred embodiment contains stearylmethyl-dimethylsiloxane (INCI: stearyl dimethicone).
- Commercial products include Abil Wax 9800, DC 2503 Wax, SilCare 41M65, Silsoft W-18 and Belsil SDM 5055.
- the emulsifiers can be liquid at room temperature or have firm consistency. In a particular embodiment have the emulsifiers waxy consistency and a Dropping point above 25 ° C.
- the inventive Hair wax product additionally at least one hair-setting polymer.
- the hair-setting polymers are preferably in an amount of 0 to 15 wt.%, 0.1 to 10 % By weight or 0.5 to 5% by weight.
- Suitable hair-fixing polymers are in particular those in International Cosmetic Ingredient Dictionary and Handbook, 9th edition, pages 2920-2921 under the function "Hair Fixatives "listed polymers.
- the hair-fixing polymer may be selected from anionic, cationic, zwitterionic, nonionic and amphoteric polymers. It can be natural or around act synthetic polymers. Among synthetic polymers are understood to mean those polymers which are purely synthetic, are not of natural origin, in particular those produced by radical polymerization of ethylenic unsaturated monomers or by polycondensation can be produced. Among natural polymers are polymers understood of natural origin, which also subsequently may be chemically or physically modified. Prefers are in particular those polymers which have a sufficient Solubility or dispersibility in the carrier medium, especially in water, alcohol or water / alcohol mixtures possess to be dissolved in the carrier medium in or homogeneously dispersed form. Under hair-setting Polymers according to the invention are such polymers when used in 0.01 to 5% aqueous, alcoholic or aqueous-alcoholic solution or dispersion are able to on the hair a polymer film to settle and to strengthen the hair.
- Suitable nonionic polymers are homo- or copolymers, composed of at least one of the following monomers are: vinyllactams, in particular vinylpyrrolidone and vinylcaprolactam, Vinyl esters, e.g. Vinyl acetate, vinyl alcohols, Acrylamides, methacrylamides, alkylacrylamides, dialkylacrylamides, Alkylmethacrylamides, dialkylmethacrylamides, Dialkylaminoalkylmethacrylamides, dialkylaminoalkylacrylamides, Alkyl acrylates, alkyl methacrylates, propylene glycol or ethylene glycol, wherein the alkyl groups of these monomers preferably C1 to C7 alkyl groups, more preferably C1bis C3 alkyl groups are.
- Suitable are e.g. Homopolymers of Vinylcaprolactams, vinylpyrrolidone or N-vinylformamide.
- Other suitable synthetic film-forming, nonionic, Hair-setting polymers are e.g. From copolymers Vinyl pyrrolidone and vinyl acetate, terpolymers of vinyl pyrrolidone, Vinyl acetate and vinyl propionate, polyacrylamides; polyvinyl alcohols as well as polyethylene glycol / polypropylene glycol Copolymers.
- Particularly preferred are polyvinylpyrrolidone, Polyvinylcaprolactam and their copolymers with at least another nonionic monomer, in particular polyvinylpyrrolidone / Vinyl acetate copolymers.
- Suitable anionic hair-fixing polymers are, for example, synthetic homopolymers or copolymers of monomer units containing acid groups, which are optionally copolymerized with comonomers which contain no acid groups.
- the acid groups are preferably selected from -COOH, -SO 3 H, -OSO 3 H, -OPO 2 H and -OPO 3 H 2 , of which the carboxylic acid groups are preferred.
- the acid groups may be unneutralized, partially or completely neutralized. They are preferably present at 50 to 100% in anionic or neutralized form.
- Suitable neutralizing agents may be organic or inorganic bases suitable for cosmetic purposes.
- bases are amino alcohols such as aminomethylpropanol (AMP), triethanolamine, monoethanolamine or tetrahydroxypropylethylenediamine and ammonia, NaOH and others.
- Suitable monomers are unsaturated, free-radically polymerizable compounds which carry at least one acid group, in particular carboxyvinyl monomers.
- Suitable acid group-containing monomers are, for example, acrylic acid, methacrylic acid, crotonic acid, maleic acid or maleic anhydride or their monoesters.
- Non-acid substituted comonomers are e.g. Acrylamide, methacrylamide, alkyl and dialkylacrylamide, Alkyl and dialkyl methacrylamide, alkyl acrylate, alkyl methacrylate, Vinylcaprolactone, vinylpyrrolidone, vinylester, Vinyl alcohol, propylene glycol or ethylene glycol, amine-substituted Vinyl monomers such as e.g.
- dialkylaminoalkyl dialkylaminoalkyl, Dialkylaminoalkyl methacrylate, monoalkylaminoalkyl acrylate and monoalkylaminoalkyl methacrylate, wherein the alkyl groups these monomers preferably C 1 - to C 7 -alkyl groups, particularly preferred are C1 to C3 alkyl groups.
- Suitable anionic polymers are, in particular, copolymers of acrylic acid or methacrylic acid with monomers selected from acrylic or methacrylic esters, acrylamides, Methacrylamides and vinylpyrrolidone, homopolymers of Crotonic acid and copolymers of crotonic acid with monomers selected from vinyl esters, acrylic or methacrylic acid esters, Acrylamides and methacrylamides.
- a suitable one natural polymer is shellac, for example.
- preferred anionic polymers are crosslinked or uncrosslinked vinyl acetate / crotonic acid Copolymers.
- preferred Partially esterified copolymers between vinyl methyl ether and Maleic anhydride are e.g.
- Suitable hair-fixing amphoteric or zwitterionic Polymers are polymers which in addition to acidic or anionic Groups as further functional groups basic or cationic groups, especially primary, secondary, tertiary or quaternary amine groups.
- zwitterionic Polymer are polymers which are composed of at least one type of monomer containing both quaternary amine groups as well as acid groups or of polymers, which are constructed of at least a first type of monomer, which has quaternary amine groups and at least a second type of monomer having acid groups.
- Amphoteric polymers are e.g. built from at least one Type of monomer having acid groups and at least Another type of monomer which basic amine groups having.
- Examples of these are copolymers formed from Alkylacrylamide (especially octylacrylamide), Alkylaminoalkylmethacrylat (especially t-butylaminoethyl methacrylate) and two or more monomers selected from acrylic acid, Methacrylic acid or their C1 to C4 alkyl esters, wherein at least one of the monomers has an acid group, such as they e.g. under the trade name Amphomer® or Amphomer® LV-71 are available.
- Alkylacrylamide especially octylacrylamide
- Alkylaminoalkylmethacrylat especially t-butylaminoethyl methacrylate
- two or more monomers selected from acrylic acid, Methacrylic acid or their C1 to C4 alkyl esters wherein at least one of the monomers has an acid group, such as they e.g. under the trade name Amphomer® or Amphomer® LV-71 are available.
- polymers are copolymers of acrylic acid, Methyl acrylate and methacrylamidopropyltrimethylammonium chloride (INCI name: Polyquaternium-47), copolymers from Acrylamidopropyltrimethylammonium chloride and acrylates or Copolymers of acrylamide, acrylamidopropyltrimethylammonium chloride, 2-amidopropylacrylamide sulfonate and dimethylaminopropylamine (INCI name: Polyquaternium-43).
- Suitable are also polymers with beta-groups carrying monomers such as e.g. Copolymers of methacryloylethylbetaine and two or more monomers of acrylic acid or its simple esters, known under the INCI name methacryloyl ethyl Betaine / acrylate copolymer.
- Suitable cationic polymers preferably contain quaternary amine groups.
- the cationic polymers can Homo- or copolymers, wherein the quaternary nitrogen groups either in the polymer chain or preferably as a substituent on one or more of the monomers are included.
- the ammonium group-containing monomers can be copolymerized with non-cationic monomers be.
- Suitable cationic monomers are unsaturated, radically polymerizable compounds which at least carry a cationic group, especially ammonium substituted Vinyl monomers such as e.g.
- the alkyl groups of these monomers are preferably lower alkyl groups such as e.g. C1 to C7 alkyl groups, more preferably C1 to C3 alkyl groups.
- the Ammonium group-containing monomers can not with be cationized cationic monomers.
- suitable Comonomers are, for example, acrylamide, methacrylamide, Alkyl and dialkylacrylamide, alkyl and dialkylmethacrylamide, Alkyl acrylate, alkyl methacrylate, vinyl caprolactone, Vinylcaprolactam, vinylpyrrolidone, vinylester, e.g. vinyl acetate, Vinyl alcohol, propylene glycol or ethylene glycol, wherein the alkyl groups of these monomers preferably C1 to C7 or C1 to C3 alkyl groups.
- Cationic polymers with quaternary amine groups are e.g. in the CTFA Cosmetic Ingredient Dictionary under the Designations Polyquaternium described polymers such as Methylvinylimidazolium chloride / vinylpyrrolidone copolymer (Polyquaternium-16) or quaternized vinyl pyrrolidone / dimethylaminoethyl methacrylate Copolymer (Polyquaternium-11) and quaternary silicone polymers or oligomers, such as For example, silicone polymers with quaternary end groups (Quaternium-80).
- cationic polymers e.g.
- Vinylpyrrolidone / dimethylaminoethyl Copolymer sold under the trade names Gafquat® 755 N and Gafquat® 734 is suitable.
- Further cationic polymers are, for example, that under the Trade name LUVIQUAT® HM 550 sold copolymer Polyvinylpyrrolidone and Imidazoliminmethochlorid, the terpolymer sold under the trade name Merquat® Plus 3300 from dimethyldiallylammonium chloride, sodium acrylate and Acrylamide, under the trade name Gaffix® VC 713 distributed terpolymers of vinyl pyrrolidone, dimethylaminoethyl methacrylate and vinylcaprolactam and that under the Trade names Gafquat® HS 100 sold vinylpyrrolidone / methacrylamidopropyltrimethylammonium chloride Copolymer.
- Suitable cationic polymers derived from natural polymers are cationic derivatives of polysaccharides, for example, cationic derivatives of cellulose, starch or guar. Also suitable are chitosan and chitosan derivatives.
- Cationic polysaccharides have the general formula GOBN + R 1 R 2 R 3 X - G is an anhydroglucose residue, for example starch or cellulose anhydroglucose;
- B is a divalent linking group, for example, alkylene, oxyalkylene, polyoxyalkylene or hydroxyalkylene;
- R 1 , R 2 and R 3 are, independently of one another, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl or alkoxyaryl having in each case up to 18 C atoms, the total number of carbon atoms in R 1 , R 2 and R 3 preferably being at most 20;
- X is a common counter anion X
- a cationic cellulose sold by Amerchol under the name Polymer JR has the INCI name Polyquaternium-10.
- Another cationic cellulose bears the INCI name Polyquaternium-24 and is sold under the trade name Polymer LM-200 by Amerchol.
- a suitable cationic guar derivative is sold under the trade name Jaguar® R and has the INCI name Guar Hydroxypropyltrimonium Chloride.
- Particularly preferred cationic substances are chitosan, chitosan salts and chitosan derivatives. Chitosans are completely or partially deacetylated chitin. The molecular weight of the chitosan can be distributed over a broad spectrum, for example from 20,000 to about 5 million g / mol.
- a low molecular weight chitosan having a molecular weight of from 30,000 to 70,000 g / mol is suitable.
- the molecular weight is above 100,000 g / mol, more preferably from 200,000 to 700,000 g / mol.
- the degree of deacetylation is preferably 10 to 99%, more preferably 60 to 99%.
- a preferred chitosan salt is chitosonium pyrrolidone carboxylate, which is sold, for example, under the name Kytamer® PC by Amerchol, USA.
- the contained chitosan has a molecular weight of about 200,000 to 300,000 g / mol and is deacetylated to 70 to 85%.
- Suitable chitosan derivatives are quaternized, alkylated or hydroxyalkylated derivatives, for example hydroxyethyl, hydroxypropyl or hydroxybutylchitosan.
- the chitosans or chitosan derivatives are preferably in neutralized or partially neutralized form.
- the degree of neutralization of the chitosan or the chitosan derivative is preferably at least 50%, more preferably between 70 and 100%, based on the number of free base groups.
- all cosmetically acceptable inorganic or organic acids can be used such as formic acid, malic acid, lactic acid, pyrrolidonecarboxylic acid, hydrochloric acid, among others, of which the pyrrolidonecarboxylic acid and the lactic acid are particularly preferred.
- the inventive Hair wax product additionally at least one pigment.
- These may be colored pigments, which are the Product compound or give the hair color effects or it can are glossy effect pigments, which are the product mass or give the hair gloss effects.
- the color or gloss effects on the hair are preferably temporary, i. you carry until the next shampooing and can by washing the Hair with usual shampoos are removed again.
- the Pigments are present in the product mass in undissolved form and may be in an amount of 0.01 to 25 wt.%, especially preferably from 5 to 15% by weight.
- the pigments are preferably not Nano-special with micropigments.
- the preferred particle size is 1 to 200 microns, especially 3 to 150 microns, especially preferably 10 to 100 microns.
- the pigments are practically insoluble in the application medium Colorants and may be inorganic or organic. Also Inorganic-organic mixed pigments are possible. Prefers are inorganic pigments. The advantage of inorganic Pigments is their excellent light, weather and temperature resistance.
- the inorganic pigments can be natural Origin, for example made from Chalk, ocher, umber, green earth, burnt Terra di Siena or graphite.
- the pigments can be white pigments such as. Titanium dioxide or zinc oxide to black pigments like e.g. Iron oxide black, colored pigments such as e.g.
- Ultramarine or Iron oxide red, luster pigments, metallic effect pigments, pearlescent pigments as well as fluorescent or phosphorescent pigments act, wherein preferably at least one pigment is colored, non-white pigment.
- Suitable are metal oxides, hydroxides and hydrates, mixed phase pigments, sulphurous silicates, metal sulphides, complex metal cyanides, Metal sulfates, chromates and molybdates, and the Metals themselves (bronze pigments).
- Titanium dioxide CI 77891
- black iron oxide CI 77499
- yellow iron oxide CI 77492
- red and brown iron oxide CI 77491
- manganese violet CI 77742
- ultramarines sodium aluminum sulfosilicates, CI 77007, Pigment Blue 29
- chromium oxide hydrate CI77289
- iron blue Feric Ferrocyanide, CI77510
- Carmine Cochineal
- Pearlescent and color pigments are particularly preferred Mica or mica base which with a metal oxide or a metal oxychloride such as titanium dioxide or bismuth oxychloride and optionally other coloring substances such as iron oxides, Iron blue, ultramarine, carmine etc. are coated and wherein the color is determined by varying the layer thickness can be.
- a metal oxide or a metal oxychloride such as titanium dioxide or bismuth oxychloride and optionally other coloring substances such as iron oxides, Iron blue, ultramarine, carmine etc.
- Such pigments are, for example, among the Trade names Rona®, Colorona®, Dichrona® and Timiron® sold by Merck, Germany.
- Organic pigments are, for example, the natural ones Pigments Sepia, Cambogia, Bone Charcoal, Kasseler Brown, Indigo, chlorophyll and other plant pigments.
- synthetic organic pigments are, for example, azo pigments, Anthraquinoids, indigoids, dioxazine, quinacridone, phthalocyanine, Isoindolinone, perylene and perinone, metal complex, Alkaline blue and diketopyrrolopyrrole pigments.
- the hair wax product according to the invention may also be used instead of or in addition to the pigments dissolved dyes.
- the hair wax product according to the invention is preferably in essentially anhydrous, i. it contains either no or only small amounts of water up to a maximum of 10% by weight or less as 5% by weight.
- suitable hydrophobic, silicone-free, soft waxy substances in amounts of e.g. 0.1 to 10% by weight be used.
- the solidification points of this soft-waxy Substances are usually in the range of about 25 ° C to below 40 ° C, e.g. semi-solid paraffins, in particular products with the INCI name petrolatum, e.g. Vaseline. in this connection it is a semi-solid mixture of petroleum recovered hydrocarbons.
- Hair wax products according to the invention can be produced Be melted by melting the solid wax components and mixed with the remaining, non-volatile ingredients become. It is then cooled and shortly before Solidify, if necessary, volatile additives added and mixed. The still flowable mass is present solidifying into the desired packaging, e.g. Plastic pot bottled.
- the invention is also the use of a according to the invention, a solid composition for hair treatment and a method of hair treatment in which a Inventive hair wax product is provided, the Composition applied to the hair and a hairstyle is created.
- the product is preferably applied to dry hair.
- a lot that vary depending on the hair length can, e.g. from about peas size to about hazelnut size is taken with your fingers.
- the wax is in the Palms and rubbed by the hand warmth and by the Melting shear, or at least melted strongly softened. In the softened or more or less liquid Condition, the wax is incorporated into the hair and the desired hairstyle created. It can also have separate strands of hair or curls are treated individually to this accentuate. In the hair the wax and the formed harden Hairstyle maintains stability, shine, texture and hold.
- the hair wax product of the invention allows due to the waxy consistency and its cohesive properties an individual hairstyle design as well as the targeted Treatment of individual strands of hair.
- the product mass is easily distributed on the hair.
- the treated hair is drawing characterized by a pronounced shine as well as a high Dimensional stability of the created hairstyle.
- the hair will be there not overly stressed and the product mass is easily washed out.
- the product stands out in comparison to conventional ones Products due to reduced stickiness of treated hair out.
- composition A of the invention is in terms of their fürsseingeschaften with the non-inventive Comparative Composition B by Sensory Examination compared by feel. Hair with composition A treated, have a much lower Sticky on as hair, with composition B are treated.
- compositions of the invention are characterized through a good dispersibility, a good incorporability in the hair, a good washability, good structure and shine hair, an anti-frizz effect, a natural hold the hair, a smooth grip of the hair, a good one Modelability of curls and good accentuation individual strands of hair.
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Abstract
Description
Gegenstand der Erfindung ist ein Wachsprodukt zur Behandlung oder Erstellung der menschlichen Frisur. Das Wachsprodukt enthält eine Zusammensetzung mit einem Gehalt an einem bei Raumtemperatur festen, silikonfreien Wachs, einem bei Raumtemperatur flüssigen Öl und einem Silikonwachs mit einem Schmelzpunkt in der Nähe der menschlichen Körpertemperatur.The invention relates to a wax product for treatment or creation of the human hairstyle. The wax product Contains a composition containing one of Room temperature solid, silicone-free wax, one at room temperature liquid oil and a silicone wax with one Melting point near the human body temperature.
Stylingwachs-Zusammensetzungen sind bekannte Produkte zur Haarbehandlung. Sie finden insbesondere Anwendung, um kurzes bis mittellanges Haar trendgerecht in Form zu bringen und der Frisur Halt, Stand und Festigung sowie Glanz zu verleihen. Auch lassen sich mit Haarwachsen Konturen und Texture in der Frisur erzeugen. Herkömmliche Haarwachse werden üblicherweise in Tiegeln angeboten und beruhen auf folgendem Wirkungsprinzip: Die Entnahme der Produktmasse erfolgt mit den Fingern. Das Wachs wird in den Handflächen verteilt und durch die Handwärme aufgeschmolzen oder zumindest stark erweicht. Durch die Erweichung oder Aufschmelzung wird die Einarbeitung des ansonsten zu festen Wachses in das Haar ermöglicht. Im erweichten oder mehr oder weniger flüssigen Zustand wird das Wachs in das Haar eingearbeitet. Im Haar kühlt es ab und erreicht wieder seine Ausgangskonsistenz. Dabei erhärtet es und die gestaltete Frisur erhält Stabilität und Halt sowie häufig einen leichten Wet-Look. Herkömmliche Haarwachsprodukte, wie sie derzeit angeboten werden, sind in der Regel auf der Basis von hydrophoben, nicht-silikonhaltigen Wachsen, Fetten und Ölen aufgebaut. Sie enthalten einen großen Anteil an hydrophoben Stoffen wie z.B. pflanzlichen oder tierischen Wachsen, Fettsäureestern, Fettalkoholen etc.. Hauptbestandteile und Hauptwirkstoffe sind hydrophobe Wachse wie z.B. Ozokerit, Candelillawachs, Bienenwachs, Carnaubawachs etc. Derartige Produkte haben den Nachteil, dass sie bei Anwendung auf dem Haar außer den gewünschten Effekten eine relativ hohe, unerwünschte Klebrigkeit hinterlassen.Styling wax compositions are known products for Hair treatment. You will find particular application to short to bring medium-length hair trend-fit in shape and the Hairstyle Hold, stand and strengthen as well as give shine. Also, with hair waxing contours and texture in the Create hairstyle. Conventional hair waxes usually become offered in crucibles and are based on the following principle: The removal of the product mass is done with the fingers. The wax is distributed in the palms and through the Hand heat melted or at least strongly softened. By the softening or melting is the incorporation of the otherwise allows for firm wax in the hair. in the softened or more or less liquid state becomes that Wax incorporated into the hair. It cools down in the hair and regains its initial consistency. It confirms it and the styled hairstyle gets stability and hold as well often a light wet look. Traditional hair wax products, as they are currently offered are usually based on hydrophobic, non-silicone waxes, Built up fats and oils. They contain a large proportion on hydrophobic substances, e.g. vegetable or animal Waxes, fatty acid esters, fatty alcohols etc .. Main Ingredients and main actives are hydrophobic waxes such as e.g. Ozokerite, candelilla wax, beeswax, carnauba wax etc. Such products have the disadvantage that they are in use on the hair besides the desired effects a relative leave high, unwanted stickiness.
Die Aufgabe bestand darin, ein festes Haarwachsprodukt zur Verfügung zu stellen, welches beim Verreiben mit den Händen zu einer erweichten oder flüssigen, glatten, nicht oder möglichst gering klebrigen Konsistenz schmilzt und wobei das Haar nach dem Aufbringen des Produktes natürlich und beweglich bleibt und Locken oder einzelne Haarsträhnen betont werden können.The task was to a solid hair wax product for To provide, which when rubbed with the hands to a softened or liquid, smooth, not or As low as possible sticky consistency melts and the Hair after application of the product natural and flexible remains and emphasizes curls or single strands of hair can be.
Darüberhinaus soll das Produkt gut dem Verpackungsmittel entnehmbar und gut verarbeitbar sein und gute Anwendungseigenschaften auf dem Haar aufweisen, insbesondere gute Einarbeitbarkeit, gute Verteilbarkeit und gute Frisurendefinition und der Frisur Glanz, Halt, Festigung bzw. Stand verleihen.In addition, the product should be good for the packaging material removable and easy to process and good application properties have on the hair, especially good Workability, good distributability and good hairstyle definition and the hairstyle shine, hold, solidification or state to lend.
Es wurde nun gefunden, dass die Anforderungen erfüllt werden
durch ein festes Haarwachsprodukt zur Behandlung oder
Erstellung der menschlichen Frisur, welches ein bei Raumtemperatur
festes, silikonfreies Wachs, eine bei Raumtemperatur
flüssige Ölverbindung und ein Silikonwachs mit einem
Schmelzpunkt in der Nähe der menschlichen Körpertemperatur
enthält. Gegenstand der Erfindung ist daher ein Haarwachsprodukt
mit fester, wachsartiger Konsistenz zur Behandlung
oder Erstellung der menschlichen Frisur mit einem Gehalt an
Die wachsartige Konsistenz ist dadurch gekennzeichnet, dass die Nadelpenetrationszahl (Maßeinheit 0,1 mm, Prüfgewicht inkl. Führungsstange 25 g, Prüfdauer 5 s, Prüftemperatur 20°C; Geometrie des Hohlkonus wie in DIN 51 580) vorzugsweise größer oder gleich 10, insbesondere von 10 bis 60, von 15 bis 55 oder von 25 bis 50 beträgt und dass das Produkt einen Erstarrungspunkt aufweist, welcher vorzugsweise größer oder gleich 30°C ist und besonders bevorzugt im Bereich von 40 bis 55°C liegt.The waxy consistency is characterized in that the needle penetration number (unit 0.1 mm, test weight Including guide rod 25 g, test duration 5 s, test temperature 20 ° C; Geometry of the hollow cone as in DIN 51 580) preferably greater than or equal to 10, especially from 10 to 60, from 15 to 55 or from 25 to 50 and that the product has a Has solidification point, which is preferably greater or is equal to 30 ° C, and more preferably in the range of 40 to 55 ° C is.
Die silikonfreien Wachse werden vorzugsweise in einer Menge von 10 bis 40 Gew,%, insbesondere von 15 bis 30 oder von 15 bis 25 Gew.% eingesetzt. Sie haben einen Erstarrungspunkt von vorzugsweise oberhalb 40°C oder oberhalb 55°C. Die Nadelpenetrationszahl liegt vorzugsweise im Bereich von 2 bis 70, insbesondere von 3 bis 40. Vorzugsweise ist mindestens ein Wachs enthalten, welches eine Nadelpenetrationszahl kleiner 40, besonders bevorzugt kleiner 20 aufweist.The silicone-free waxes are preferably in an amount from 10 to 40% by weight, in particular from 15 to 30 or from 15 used to 25 wt.%. You have a freezing point preferably above 40 ° C or above 55 ° C. The Needle penetration number is preferably in the range of 2 to 70, in particular from 3 to 40. Preferably contain at least one wax, which is a Nadelpenetrationszahl less than 40, more preferably less than 20 having.
Geeignete silikonfreie Wachse sind z.B. tierische Wachse, pflanzliche Wachse, mineralische Wachse, synthetische Wachse, mikrokristalline Wachse, makrokristalline Wachse, Paraffinwachse, Ozokerit, Montanwachsen, Fischer-Tropsch-Wachse, Polyolefinwachse (z.B. Polyethylen, Polybuten und ähnliche), Bienenwachs, Wollwachs (Lanolin) und dessen Derivate wie z.B. Wollwachsalkohole, Candelillawachs, Carnaubawachs, Japanwachs, gehärtete Fette, Fettsäureester und Fettsäureglyceride. Eine bevorzugte Ausführungsform enthält als silikonfreie Wachse Kohlenwasserstoffwachse, z.B. Ozokerit oder Ceresin, insbesondere mit einer Nadelpenetrationszahl kleiner 20.Suitable silicone-free waxes are e.g. animal waxes, vegetable waxes, mineral waxes, synthetic Waxes, microcrystalline waxes, macrocrystalline waxes, Paraffin waxes, ozokerite, montan waxes, Fischer-Tropsch waxes, Polyolefin waxes (e.g., polyethylene, polybutene, and similar), beeswax, wool wax (lanolin) and its Derivatives such as e.g. Wool wax alcohols, candelilla wax, Carnauba wax, Japan wax, hydrogenated fats, fatty acid esters and fatty acid glycerides. A preferred embodiment contains hydrocarbon waxes as silicone-free waxes, e.g. Ozokerite or ceresin, in particular with a needle penetration number less than 20.
Die flüssigen, hydrophoben Öle werden vorzugsweise in einer Menge von 20 bis 80 Gew,%, insbesondere von 30 bis 70 oder von 40 bis 55 Gew.% eingesetzt. Sie haben einen Schmelzpunkt von kleiner oder gleich 25°C und einen Siedepunkt von vorzugsweise über 250 °C, insbesondere über 300 °C. Hierfür kann prinzipiell jedes dem Fachmann allgemein bekannte Öl eingesetzt werden. Vorzugsweise handelt es sich um Silikonverbindungen. Geeignete Silikonöle sind z.B. lineare Polydimethylsiloxane (Dimethicone), cyclische Polydimethylsiloxanen (Cyclomethicone), hydroxysubstituierte Polydimethylsiloxane (Dimethiconole), aminosubstituierte Silikone (z.B. Amodimethicone) und mit aromatischen Gruppen substituierte Siloxane (z.B. phenylierte Silikone, Polyphenylmethylsiloxane, Phenyltrimethicone).The liquid, hydrophobic oils are preferably in one Amount of 20 to 80% by weight, in particular from 30 to 70 or used from 40 to 55 wt.%. They have a melting point of less than or equal to 25 ° C and a boiling point of preferably above 250 ° C, especially above 300 ° C. Therefor can in principle be any oil well known to the skilled person be used. Preferably, these are silicone compounds. Suitable silicone oils are e.g. linear polydimethylsiloxanes (Dimethicones), cyclic polydimethylsiloxanes (Cyclomethicones), hydroxy-substituted polydimethylsiloxanes (Dimethiconols), amino-substituted silicones (e.g. Amodimethicone) and substituted with aromatic groups Siloxanes (e.g., phenylated silicones, polyphenylmethylsiloxanes, Phenyltrimethicones).
Zusätzlich oder alternativ können auch hydrophobe, silikonfreie Öle eingesetzt werden. In Frage kommen pflanzliche oder tierische Öle, Mineralöle (Paraffinum liquidum) oder deren Mischungen. Geeignet sind Kohlenwasserstofföle, z.B. Paraffin- oder Isoparaffinöle, Squalan, Öle aus Fettsäuren und Polyolen, insbesondere Triglyceride. Geeignete pflanzliche Öle sind z.B. Sonnenblumenöl, Kokosöl, Rizinusöl, Lanolinöl, Jojobaöl, Maisöl, Sojaöl.Additionally or alternatively, hydrophobic, silicone-free Oils are used. In question come herbal or animal oils, mineral oils (Paraffinum liquidum) or their mixtures. Suitable are hydrocarbon oils, e.g. Paraffin or isoparaffin oils, squalane, fatty acid oils and polyols, especially triglycerides. Suitable herbal Oils are e.g. Sunflower oil, coconut oil, castor oil, Lanolin oil, jojoba oil, corn oil, soybean oil.
Die Silikonwachse werden vorzugsweise in einer Menge von 5
bis 40 Gew,%, insbesondere von 10 bis 25 oder von 10 bis 20
Gew.% eingesetzt. Sie haben einen Schmelzpunkt im Bereich
von 20 bis 45 °C, vorzugsweise im Bereich von 25 bis 40 oder
bis 35°C.
Die Silikonwachse sind vorzugsweise ausgewählt aus Alkylmethyl-dimethylsiloxanen,
insbesondere solchen, bei denen die
Alkylgruppe mindestens 8 C-Atome, z.B. 16 bis 20 C-Atome
aufweist. Alkylmethyl-dimethylsiloxane haben die allgemeine
Formel
Eine bevorzugte Ausführungsform enthält Stearylmethyl-dimethylsiloxan
(INCI: Stearyl Dimethicone). Handelsprodukte
sind z.B. Abil Wax 9800, DC 2503 Wax, SilCare 41M65, Silsoft
W-18 und Belsil SDM 5055.The silicone waxes are preferably used in an amount of from 5 to 40% by weight, in particular from 10 to 25 or from 10 to 20% by weight. They have a melting point in the range of 20 to 45 ° C, preferably in the range of 25 to 40 or to 35 ° C.
The silicone waxes are preferably selected from alkylmethyl-dimethylsiloxanes, in particular those in which the alkyl group has at least 8 C atoms, for example 16 to 20 C atoms. Alkylmethyl-dimethylsiloxanes have the general formula
A preferred embodiment contains stearylmethyl-dimethylsiloxane (INCI: stearyl dimethicone). Commercial products include Abil Wax 9800, DC 2503 Wax, SilCare 41M65, Silsoft W-18 and Belsil SDM 5055.
In einer bevorzugten Ausführungsform enthält das erfindungsgemäße Haarwachsprodukt zusätzlich mindestens einen Emulgator. Die Emulgatoren sind vorzugsweise in einer Menge von 0,1 bis 30 Gew.%, von 0,5 bis 25 Gew.% oder von 3 bis 20 Gew.% enthalten. Die Emulgatoren können nichtionisch, anionisch, kationisch, amphoter oder zwitterionisch sein, wobei nichtionische Emulgatoren bevorzugt werden. Geeignet sind z.B.
- Ethoxylierungsprodukte von Fettalkoholen, Fettsäuren, Fettsäureglyceriden oder Alkylphenolen, insbesondere Anlagerungsprodukte von 2 bis 30 mol Ethylenoxid und/oder 1 bis 5 mol Propylenoxid an C8- bis C22-Fettalkohole, an C12- bis C22-Fettsäuren oder an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe,
- C12- bis C22-Fettsäuremono- und -diester von Anlagerungsprodukten von 1 bis 30 mol Ethylenoxid an Glycerin,
- Anlagerungsprodukte von 5 bis 60 mol Ethylenoxid an Rizinusöl oder an gehärtetes (hydriertes) Rizinusöl.
- Mono-, Di- und/oder Triester der Phosphorsäure mit Anlagerungsprodukten von 2 bis 30 mol Ethylenoxid an C8bis C22-Fettalkohole
- Fettsäurezuckerester, insbesondere Ester aus Saccharose und ein oder zwei C8- bis C22-Fettsäuren; z.B. Verbindungen mit den INCI-Bezeichnungen Sucrose Cocoate, Sucrose Dilaurate, Sucrose Distearate, Sucrose Laurate, Sucrose Myristate, Sucrose Oleate, Sucrose Palmitate, Sucrose Ricinoleate, Sucrose Stearate
- Ethoxylierte Sorbitanfettsäureester, insbesondere Ester aus Sorbitan und ein, zwei oder drei C8- bis C22-Fettsäuren und einem Ethoxylierungsgrad von 4 bis 20; z.B. Verbindungen mit den INCI-Bezeichnungen Polysorbatex, wobei x den Ethoxylierungsgrad angibt
- Polyglycerylfettsäureester, insbesondere aus ein, zwei oder mehreren C8- bis C22-Fettsäuren und Polyglycerin mit vorzugsweise 2 bis 20 Glyceryleinheiten.
- Ethoxylation products of fatty alcohols, fatty acids, fatty acid glycerides or alkylphenols, in particular addition products of 2 to 30 moles of ethylene oxide and / or 1 to 5 moles of propylene oxide to C8 to C22 fatty alcohols, to C12 to C22 fatty acids or to alkylphenols having 8 to 15 C Atoms in the alkyl group,
- C12 to C22 fatty acid mono- and diesters of addition products of 1 to 30 mol of ethylene oxide with glycerol,
- Addition products of 5 to 60 moles of ethylene oxide to castor oil or to hydrogenated (hydrogenated) castor oil.
- Mono-, di- and / or triesters of phosphoric acid with addition products of 2 to 30 moles of ethylene oxide to C8 to C22 fatty alcohols
- Fatty acid sugar esters, in particular esters of sucrose and one or two C8 to C22 fatty acids; eg compounds with the INCI names Sucrose Cocoate, Sucrose Dilaurate, Sucrose Distearate, Sucrose Laurate, Sucrose Myristate, Sucrose Oleate, Sucrose Palmitate, Sucrose Ricinoleate, Sucrose Stearate
- Ethoxylated sorbitan fatty acid esters, especially esters of sorbitan and one, two or three C8 to C22 fatty acids and a degree of ethoxylation of 4 to 20; eg compounds with the INCI names Polysorbatex, where x indicates the degree of ethoxylation
- Polyglycerylfettsäureester, in particular from one, two or more C8 to C22 fatty acids and polyglycerol having preferably 2 to 20 Glyceryleinheiten.
Die Emulgatoren können bei Raumtemperatur flüssige oder feste Konsisitenz haben. In einer besonderen Ausführungsform haben die Emulgatoren wachsartige Konsistenz und einen Tropfpunkt oberhalb 25°C.The emulsifiers can be liquid at room temperature or have firm consistency. In a particular embodiment have the emulsifiers waxy consistency and a Dropping point above 25 ° C.
In einer bevorzugten Ausführungsform enthält das erfindungsgemäße Haarwachsprodukt zusätzlich mindestens ein haarfestigendes Polymer. Die haarfestigenden Polymere sind vorzugsweise in einer Menge von 0 bis 15 Gew.%, 0,1 bis 10 Gew.% oder 0,5 bis 5 Gew.% enthalten.In a preferred embodiment, the inventive Hair wax product additionally at least one hair-setting polymer. The hair-setting polymers are preferably in an amount of 0 to 15 wt.%, 0.1 to 10 % By weight or 0.5 to 5% by weight.
Geeignete haarfestigende Polymere sind insbesondere die im International Cosmetic Ingredient Dictionary and Handbook, 9. Auflage, Seiten 2920-2921 unter der Funktion "Hair Fixatives" aufgeführten Polymere.Suitable hair-fixing polymers are in particular those in International Cosmetic Ingredient Dictionary and Handbook, 9th edition, pages 2920-2921 under the function "Hair Fixatives "listed polymers.
Das haarfestigende Polymer kann ausgewählt sein aus anionischen, kationischen, zwitterionischen, nichtionischen und amphoteren Polymeren. Es kann sich um natürliche oder um synthetische Polymere handeln. Unter synthetischen Polymeren werden solche Polymere verstanden, welche rein synthetischen, nicht natürlichen Ursprungs sind, insbesondere solche, die durch radikalische Polymerisation aus ethylenisch ungesättigten Monomeren oder durch Polykondensation herstellbar sind. Unter natürlichen Polymeren werden Polymere natürlichen Ursprungs verstanden, die auch nachträglich chemisch oder physikalisch modifiziert sein können. Bevorzugt sind insbesondere solche Polymere, die eine ausreichende Löslichkeit oder Dispergierbarkeit in dem Trägermedium, insbesondere in Wasser, Alkohol oder Wasser/ Alkohol-Gemischen besitzen, um in dem Trägermedium in gelöster oder homogen dispergierter Form vorzuliegen. Unter haarfestigenden Polymeren werden erfindungsgemäß solche Polymere verstanden, die bei Anwendung in 0,01 bis 5%iger wässriger, alkoholischer oder wässrig-alkoholischer Lösung oder Dispersion in der Lage sind, auf dem Haar einen Polymerfilm abzuscheiden und das Haar zu festigen.The hair-fixing polymer may be selected from anionic, cationic, zwitterionic, nonionic and amphoteric polymers. It can be natural or around act synthetic polymers. Among synthetic polymers are understood to mean those polymers which are purely synthetic, are not of natural origin, in particular those produced by radical polymerization of ethylenic unsaturated monomers or by polycondensation can be produced. Among natural polymers are polymers understood of natural origin, which also subsequently may be chemically or physically modified. Prefers are in particular those polymers which have a sufficient Solubility or dispersibility in the carrier medium, especially in water, alcohol or water / alcohol mixtures possess to be dissolved in the carrier medium in or homogeneously dispersed form. Under hair-setting Polymers according to the invention are such polymers when used in 0.01 to 5% aqueous, alcoholic or aqueous-alcoholic solution or dispersion are able to on the hair a polymer film to settle and to strengthen the hair.
Geeignete nichtionische Polymere sind Homo- oder Copolymere, die aus mindestens einem der folgenden Monomere aufgebaut sind: Vinyllactamen, insbesondere Vinylpyrrolidon und Vinylcaprolactam, Vinylestern wie z.B. Vinylacetat, Vinylalkoholen, Acrylamiden, Methacrylamiden, Alkylacrylamiden, Dialkylacrylamiden, Alkylmethacrylamiden, Dialkylmethacrylamiden, Dialkylaminoalkylmethacrylamiden, Dialkylaminoalkylacrylamiden, Alkylacrylaten, Alkylmethacrylaten, Propylenglykol oder Ethylenglykol, wobei die Alkylgruppen dieser Monomere vorzugsweise C1- bis C7-Alkylgruppen, besonders bevorzugt C1bis C3-Alkylgruppen sind. Geeignet sind z.B. Homopolymere des Vinylcaprolactams, des Vinylpyrrolidons oder des N-Vinylformamids. Weitere geeignete synthetische filmbildende, nichtionische, haarfestigende Polymere sind z.B. Copolymerisate aus Vinylpyrrolidon und Vinylacetat, Terpolymere aus Vinylpyrrolidon, Vinylacetat und Vinylpropionat, Polyacrylamide; Polyvinylalkohole sowie Polyethylenglykol/Polypropylenglykol Copolymere. Besonders bevorzugt sind Polyvinylpyrrolidon, Polyvinylcaprolactam und deren Copolymere mit mindestens einem weiteren nichtionischen Monomer, insbesondere Polyvinylpyrrolidon/ Vinylacetat Copolymere.Suitable nonionic polymers are homo- or copolymers, composed of at least one of the following monomers are: vinyllactams, in particular vinylpyrrolidone and vinylcaprolactam, Vinyl esters, e.g. Vinyl acetate, vinyl alcohols, Acrylamides, methacrylamides, alkylacrylamides, dialkylacrylamides, Alkylmethacrylamides, dialkylmethacrylamides, Dialkylaminoalkylmethacrylamides, dialkylaminoalkylacrylamides, Alkyl acrylates, alkyl methacrylates, propylene glycol or ethylene glycol, wherein the alkyl groups of these monomers preferably C1 to C7 alkyl groups, more preferably C1bis C3 alkyl groups are. Suitable are e.g. Homopolymers of Vinylcaprolactams, vinylpyrrolidone or N-vinylformamide. Other suitable synthetic film-forming, nonionic, Hair-setting polymers are e.g. From copolymers Vinyl pyrrolidone and vinyl acetate, terpolymers of vinyl pyrrolidone, Vinyl acetate and vinyl propionate, polyacrylamides; polyvinyl alcohols as well as polyethylene glycol / polypropylene glycol Copolymers. Particularly preferred are polyvinylpyrrolidone, Polyvinylcaprolactam and their copolymers with at least another nonionic monomer, in particular polyvinylpyrrolidone / Vinyl acetate copolymers.
Geeignete anionische haarfestigende Polymere sind z.B. synthetische Homo- oder Copolymere aus Säuregruppen enthaltenden Monomereinheiten, welche gegebenenfalls mit Comonomeren, die keine Säuregruppen enthalten, copolymerisiert sind. Die Säuregruppen sind vorzugsweise ausgewählt aus -COOH, -SO3H, -OSO3H, -OPO2H und -OPO3H2, von denen die Carbonsäuregruppen bevorzugt sind. Die Säuregruppen können unneutralisiert, teilweise oder vollständig neutralisiert vorliegen. Sie liegen vorzugsweise zu 50 bis 100% in anionischer bzw. neutralisierter Form vor. Als Neutralisationsmittel können für kosmetische Zwecke geeignete organische oder anorganische Basen verwendet werden. Beispiele für Basen sind Aminoalkohole wie z.B. Aminomethylpropanol (AMP), Triethanolamin, Monoethanolamin oder Tetrahydroxypropylethylendiamin und Ammoniak, NaOH und andere. Geeignete Monomere sind ungesättigte, radikalisch polymerisierbare Verbindungen, welche mindestens eine Säuregruppe tragen, insbesondere Carboxyvinylmonomere. Geeignete Säuregruppen enthaltende Monomere sind z.B. Acrylsäure, Methacrylsäure, Crotonsäure, Maleinsäure bzw. Maleinsäureanhydrid oder deren Monoester.Suitable anionic hair-fixing polymers are, for example, synthetic homopolymers or copolymers of monomer units containing acid groups, which are optionally copolymerized with comonomers which contain no acid groups. The acid groups are preferably selected from -COOH, -SO 3 H, -OSO 3 H, -OPO 2 H and -OPO 3 H 2 , of which the carboxylic acid groups are preferred. The acid groups may be unneutralized, partially or completely neutralized. They are preferably present at 50 to 100% in anionic or neutralized form. Suitable neutralizing agents may be organic or inorganic bases suitable for cosmetic purposes. Examples of bases are amino alcohols such as aminomethylpropanol (AMP), triethanolamine, monoethanolamine or tetrahydroxypropylethylenediamine and ammonia, NaOH and others. Suitable monomers are unsaturated, free-radically polymerizable compounds which carry at least one acid group, in particular carboxyvinyl monomers. Suitable acid group-containing monomers are, for example, acrylic acid, methacrylic acid, crotonic acid, maleic acid or maleic anhydride or their monoesters.
Nicht mit Säuregruppen substituierte Comonomere sind z.B. Acrylamid, Methacrylamid, Alkyl- und Dialkylacrylamid, Alkyl- und Dialkylmethacrylamid, Alkylacrylat, Alkylmethacrylat, Vinylcaprolacton, Vinylpyrrolidon, Vinylester, Vinylalkohol, Propylenglykol oder Ethylenglykol, amin-substituierte Vinylmonomere wie z.B. Dialkylaminoalkylacrylat, Dialkylaminoalkylmethacrylat, Monoalkylaminoalkylacrylat und Monoalkylaminoalkylmethacrylat, wobei die Alkylgruppen dieser Monomere vorzugsweise C1- bis C7-Alkylgruppen, besonders bevorzugt C1- bis C3-Alkylgruppen sind. Non-acid substituted comonomers are e.g. Acrylamide, methacrylamide, alkyl and dialkylacrylamide, Alkyl and dialkyl methacrylamide, alkyl acrylate, alkyl methacrylate, Vinylcaprolactone, vinylpyrrolidone, vinylester, Vinyl alcohol, propylene glycol or ethylene glycol, amine-substituted Vinyl monomers such as e.g. dialkylaminoalkyl, Dialkylaminoalkyl methacrylate, monoalkylaminoalkyl acrylate and monoalkylaminoalkyl methacrylate, wherein the alkyl groups these monomers preferably C 1 - to C 7 -alkyl groups, particularly preferred are C1 to C3 alkyl groups.
Geeignete anionische Polymere sind insbesondere Copolymere der Acrylsäure oder Methacrylsäure mit Monomeren ausgewählt aus Acrylsäure- oder Methacrylsäureestern, Acrylamiden, Methacrylamiden und Vinylpyrrolidon, Homopolymere der Crotonsäure sowie Copolymere der Crotonsäure mit Monomeren ausgewählt aus Vinylestern, Acrylsäure- oder Methacrylsäureestern, Acrylamiden und Methacrylamiden. Ein geeignetes natürliches Polymer ist beispielsweise Schellack. Bevorzugte anionische Polymere sind vernetzte oder unvernetzte Vinylacetat/Crotonsäure Copolymere. Ebenso bevorzugt sind partialveresterte Copolymere zwischen Vinylmethylether und Maleinsäureanhydrid. Weitere bevorzugte anionische Polymere sind z.B. Terpolymere aus Acrylsäure, Alkylacrylat und N-Alkylacrylamid, insbesondere Acrylsäure/ Ethylacrylat/N-t-Butylacrylamid Terpolymere oder Terpolymere aus Vinylacetat, Crotonat und Vinylalkanoat, insbesondere Vinylacetat/Crotonat/Vinylneodecanoat Copolymere; Copolymere aus Acryl- oder Methacrylsäure und Acryl- oder Methacrylsäurealkylestern, wobei die Alkylgruppen vorzugsweise 1 bis 7 C-Atome enthalten sowie Polystyrolsulfonate.Suitable anionic polymers are, in particular, copolymers of acrylic acid or methacrylic acid with monomers selected from acrylic or methacrylic esters, acrylamides, Methacrylamides and vinylpyrrolidone, homopolymers of Crotonic acid and copolymers of crotonic acid with monomers selected from vinyl esters, acrylic or methacrylic acid esters, Acrylamides and methacrylamides. A suitable one natural polymer is shellac, for example. preferred anionic polymers are crosslinked or uncrosslinked vinyl acetate / crotonic acid Copolymers. Likewise preferred Partially esterified copolymers between vinyl methyl ether and Maleic anhydride. Further preferred anionic polymers are e.g. Terpolymers of acrylic acid, alkyl acrylate and N-alkylacrylamide, in particular acrylic acid / ethyl acrylate / N-t-butylacrylamide Terpolymers or terpolymers of vinyl acetate, Crotonate and vinyl alkanoate, in particular vinyl acetate / crotonate / vinyl neodecanoate copolymers; Copolymers of acrylic or methacrylic acid and acrylic or methacrylic acid alkyl esters, wherein the alkyl groups preferably 1 to 7 carbon atoms contained as well as polystyrene sulfonates.
Geeignete haarfestigende amphotere oder zwitterionische Polymere sind Polymere, welche neben sauren oder anionischen Gruppen als weitere funktionelle Gruppen basische oder kationische Gruppen, insbesondere primäre, sekundäre, tertiäre oder quaternäre Amingruppen enthalten. Zwitterionische Polymer sind Polymere, welche aufgebaut sind aus mindestens einer Monomerart, welche sowohl quaternäre Amingruppen als auch Säuregruppen aufweist oder aus Polymeren, welche aufgebaut sind aus mindestens einer ersten Monomerart, welche quaternäre Amingruppen aufweist und mindestens einer zweiten Monomerart, welche Säuregruppen aufweist. Amphotere Polymere sind z.B. aufgebaut aus mindestens einer Monomerart, welche Säuregruppen aufweist und mindestens einer weiteren Monomerart, welche basische Amingruppen aufweist. Beispiele hierfür sind Copolymere gebildet aus Alkylacrylamid (insbesondere Octylacrylamid), Alkylaminoalkylmethacrylat (insbesondere t-Butylaminoethylmethacrylat) und zwei oder mehr Monomeren ausgewählt aus Acrylsäure, Methacrylsäure oder deren C1- bis C4-Alkylestern, wobei mindestens eines der Monomere eine Säuregruppe aufweist, wie sie z.B. unter dem Handelsnamen Amphomer® oder Amphomer® LV-71 erhältlich sind.Suitable hair-fixing amphoteric or zwitterionic Polymers are polymers which in addition to acidic or anionic Groups as further functional groups basic or cationic groups, especially primary, secondary, tertiary or quaternary amine groups. zwitterionic Polymer are polymers which are composed of at least one type of monomer containing both quaternary amine groups as well as acid groups or of polymers, which are constructed of at least a first type of monomer, which has quaternary amine groups and at least a second type of monomer having acid groups. Amphoteric polymers are e.g. built from at least one Type of monomer having acid groups and at least Another type of monomer which basic amine groups having. Examples of these are copolymers formed from Alkylacrylamide (especially octylacrylamide), Alkylaminoalkylmethacrylat (especially t-butylaminoethyl methacrylate) and two or more monomers selected from acrylic acid, Methacrylic acid or their C1 to C4 alkyl esters, wherein at least one of the monomers has an acid group, such as they e.g. under the trade name Amphomer® or Amphomer® LV-71 are available.
Weitere geeignete Polymere sind Copolymere von Acrylsäure, Methylacrylat und Methacrylamidopropyltrimethylammoniumchlorid (INCI-Bezeichnung: Polyquaternium-47), Copolymere aus Acrylamidopropyltrimethylammoniumchlorid und Acrylaten oder Copolymere aus Acrylamid, Acrylamidopropyltrimethylammoniumchlorid, 2-Amidopropylacrylamidsulfonat und Dimethylaminopropylamin (INCI-Bezeichnung: Polyquaternium-43). Geeignet sind auch Polymere mit Betaingruppen tragenden Monomeren wie z.B. Copolymere aus Methacryloylethylbetain und zwei oder mehr Monomeren von Acrylsäure oder deren einfachen Estern, bekannt unter der INCI-Bezeichnung Methacryloyl Ethyl Betaine/Acrylates Copolymer.Further suitable polymers are copolymers of acrylic acid, Methyl acrylate and methacrylamidopropyltrimethylammonium chloride (INCI name: Polyquaternium-47), copolymers from Acrylamidopropyltrimethylammonium chloride and acrylates or Copolymers of acrylamide, acrylamidopropyltrimethylammonium chloride, 2-amidopropylacrylamide sulfonate and dimethylaminopropylamine (INCI name: Polyquaternium-43). Suitable are also polymers with beta-groups carrying monomers such as e.g. Copolymers of methacryloylethylbetaine and two or more monomers of acrylic acid or its simple esters, known under the INCI name methacryloyl ethyl Betaine / acrylate copolymer.
Geeignete kationische Polymere enthalten vorzugsweise quaternäre Amingruppen. Die kationischen Polymere können Homo- oder Copolymere sein, wobei die quaternären Stickstoffgruppen entweder in der Polymerkette oder vorzugsweise als Substituent an einem oder mehreren der Monomeren enthalten sind. Die Ammoniumgruppen enthaltenden Monomere können mit nicht kationischen Monomeren copolymerisiert sein. Geeignete kationische Monomere sind ungesättigte, radikalisch polymerisierbare Verbindungen, welche mindestens eine kationische Gruppe tragen, insbesondere ammoniumsubstituierte Vinylmonomere wie z.B. Trialkylmethacryloxyalkylammonium, Trialkylacryloxyalkylammonium, Dialkyldiallylammonium und quaternäre Vinylammoniummonomere mit cyclischen, kationische Stickstoffe enthaltenden Gruppen wie Pyridinium, Imidazolium oder quaternäre Pyrrolidone, z.B. Alkylvinylimidazolium, Alkylvinylpyridinium, oder Alkylvinylpyrrolidon Salze. Die Alkylgruppen dieser Monomere sind vorzugsweise niedere Alkylgruppen wie z.B. C1- bis C7-Alkylgruppen, besonders bevorzugt C1- bis C3-Alkylgruppen. Die Ammoniumgruppen enthaltenden Monomere können mit nicht kationischen Monomeren copolymerisiert sein. Geeignete Comonomere sind beispielsweise Acrylamid, Methacrylamid, Alkyl- und Dialkylacrylamid, Alkyl- und Dialkylmethacrylamid, Alkylacrylat, Alkylmethacrylat, Vinylcaprolacton, Vinylcaprolactam, Vinylpyrrolidon, Vinylester, z.B. Vinylacetat, Vinylalkohol, Propylenglykol oder Ethylenglykol, wobei die Alkylgruppen dieser Monomere vorzugsweise C1- bis C7- oder C1- bis C3-Alkylgruppen sind.Suitable cationic polymers preferably contain quaternary amine groups. The cationic polymers can Homo- or copolymers, wherein the quaternary nitrogen groups either in the polymer chain or preferably as a substituent on one or more of the monomers are included. The ammonium group-containing monomers can be copolymerized with non-cationic monomers be. Suitable cationic monomers are unsaturated, radically polymerizable compounds which at least carry a cationic group, especially ammonium substituted Vinyl monomers such as e.g. trialkylmethacryloxyalkylammonium, Trialkylacryloxyalkylammonium, dialkyldiallylammonium and quaternary vinyl ammonium monomers with cyclic, cationic nitrogen containing groups such as Pyridinium, imidazolium or quaternary pyrrolidones, e.g. Alkylvinylimidazolium, Alkylvinylpyridinium, or Alkylvinylpyrrolidone Salts. The alkyl groups of these monomers are preferably lower alkyl groups such as e.g. C1 to C7 alkyl groups, more preferably C1 to C3 alkyl groups. The Ammonium group-containing monomers can not with be cationized cationic monomers. suitable Comonomers are, for example, acrylamide, methacrylamide, Alkyl and dialkylacrylamide, alkyl and dialkylmethacrylamide, Alkyl acrylate, alkyl methacrylate, vinyl caprolactone, Vinylcaprolactam, vinylpyrrolidone, vinylester, e.g. vinyl acetate, Vinyl alcohol, propylene glycol or ethylene glycol, wherein the alkyl groups of these monomers preferably C1 to C7 or C1 to C3 alkyl groups.
Kationische Polymere mit quaternären Amingruppen sind z.B. die im CTFA Cosmetic Ingredient Dictionary unter den Bezeichnungen Polyquaternium beschriebenen Polymere wie Methylvinylimidazoliumchlorid/Vinylpyrrolidon Copolymer (Polyquaternium-16) oder quaternisiertes Vinylpyrrolidon/Dimethylaminoethylmethacrylat Copolymer (Polyquaternium-11) sowie quaternäre Silikonpolymere bzw. -oligomere wie beispielsweise Silikonpolymere mit quaternären Endgruppen (Quaternium-80). Von den kationischen Polymeren ist z.B. Vinylpyrrolidon/Dimethylaminoethylmethacrylatmethosulfat Copolymer, das unter den Handelsbezeichnungen Gafquat® 755 N und Gafquat® 734 vertrieben wird, geeignet. Weitere kationische Polymere sind beispielsweise das unter dem Handelsnamen LUVIQUAT® HM 550 vertriebene Copolymer aus Polyvinylpyrrolidon und Imidazoliminmethochlorid, das unter dem Handelsnamen Merquat® Plus 3300 vertriebene Terpolymer aus Dimethyldiallylammoniumchlorid, Natriumacrylat und Acrylamid, das unter dem Handelsnamen Gaffix® VC 713 vertriebene Terpolymer aus Vinylpyrrolidon, Dimethylaminoethylmethacrylat und Vinylcaprolactam und das unter dem Handelsnamen Gafquat® HS 100 vertriebene Vinylpyrrolidon/Methacrylamidopropyltrimethylammoniumchlorid Copolymer.Cationic polymers with quaternary amine groups are e.g. in the CTFA Cosmetic Ingredient Dictionary under the Designations Polyquaternium described polymers such as Methylvinylimidazolium chloride / vinylpyrrolidone copolymer (Polyquaternium-16) or quaternized vinyl pyrrolidone / dimethylaminoethyl methacrylate Copolymer (Polyquaternium-11) and quaternary silicone polymers or oligomers, such as For example, silicone polymers with quaternary end groups (Quaternium-80). Of the cationic polymers, e.g. Vinylpyrrolidone / dimethylaminoethyl Copolymer sold under the trade names Gafquat® 755 N and Gafquat® 734 is suitable. Further cationic polymers are, for example, that under the Trade name LUVIQUAT® HM 550 sold copolymer Polyvinylpyrrolidone and Imidazoliminmethochlorid, the terpolymer sold under the trade name Merquat® Plus 3300 from dimethyldiallylammonium chloride, sodium acrylate and Acrylamide, under the trade name Gaffix® VC 713 distributed terpolymers of vinyl pyrrolidone, dimethylaminoethyl methacrylate and vinylcaprolactam and that under the Trade names Gafquat® HS 100 sold vinylpyrrolidone / methacrylamidopropyltrimethylammonium chloride Copolymer.
Geeignete kationische Polymere, die von natürlichen
Polymeren abgeleitet sind, sind kationische Derivate von
Polysacchariden, beispielsweise kationische Derivate von
Cellulose, Stärke oder Guar. Geeignet sind weiterhin
Chitosan und Chitosanderivate. Kationische Polysaccharide
haben die allgemeine Formel
B ist eine divalente Verbindungsgruppe, beispielsweise
Alkylen, Oxyalkylen, Polyoxyalkylen oder Hydroxyalkylen;
R1, R2 und R3 sind unabhängig voneinander Alkyl, Aryl,
Alkylaryl, Arylalkyl, Alkoxyalkyl oder Alkoxyaryl mit
jeweils bis zu 18 C-Atomen, wobei die Gesamtzahl der C-Atome
in R1, R2 und R3 vorzugsweise maximal 20 ist;
X ist ein übliches Gegenanion X-, beispielsweise ein Halogen,
Acetat, Phosphat, Nitrat oder Alkylsulfat, vorzugsweise ein
Chlorid. Eine kationische Cellulose wird unter der
Bezeichnung Polymer JR von Amerchol vertrieben und hat die
INCI-Bezeichnung Polyquaternium-10. Eine weitere kationische
Cellulose trägt die INCI-Bezeichnung Polyquaternium-24 und
wird unter dem Handelsnamen Polymer LM-200 von Amerchol
vertrieben. Ein geeignetes kationisches Guarderivat wird
unter der Handelsbezeichnung Jaguar® R vertrieben und hat die
INCI-Bezeichnung Guar Hydroxypropyltrimonium Chloride.
Besonders bevorzugte kationaktive Stoffe sind Chitosan,
Chitosansalze und Chitosan-Derivate. Chitosane sind
vollständig oder partiell deacetylierte Chitine. Das
Molekulargewicht des Chitosans kann über ein breites Spektrum
verteilt sein, beispielsweise von 20.000 bis ca. 5 Millionen
g/mol. Geeignet ist beispielsweise ein niedermolekulares
Chitosan mit einem Molekulargewicht von 30.000 bis 70.000
g/mol. Vorzugsweise liegt das Molekulargewicht jedoch über
100.000 g/mol, besonders bevorzugt von 200.000 bis 700.000
g/mol. Der Deacetylierungsgrad beträgt vorzugsweise 10 bis
99%, besonders bevorzugt 60 bis 99%. Ein bevorzugtes
Chitosansalz ist Chitosoniumpyrrolidoncarboxylat, welches
beispielsweise unter der Bezeichnung Kytamer® PC von der
Firma Amerchol, USA, vertrieben wird. Das enthaltene Chitosan
hat ein Molekulargewicht von ca. 200.000 bis 300.000 g/mol
und ist zu 70 bis 85% entacetyliert. Als Chitosanderivate
kommen quaternisierte, alkylierte oder hydroxyalkylierte
Derivate, beispielsweise Hydroxyethyl-, Hydroxypropyl- oder
Hydroxybutylchitosan in Betracht. Die Chitosane oder
Chitosanderivate liegen vorzugsweise in neutralisierter oder
partiell neutralisierter Form vor. Der Neutralisationsgrad
für das Chitosan oder das Chitosanderivat liegt vorzugsweise
bei mindestens 50%, besonders bevorzugt zwischen 70 und 100%,
bezogen auf die Anzahl der freien Basengruppen. Als Neutralisationsmittel
können prinzipiell alle kosmetisch verträglichen
anorganischen oder organischen Säuren verwendet werden
wie beispielsweise Ameisensäure, Äpfelsäure, Milchsäure,
Pyrrolidoncarbonsäure, Salzsäure u.a., von denen die Pyrrolidoncarbonsäure
und die Milchsäure besonders bevorzugt sind.Suitable cationic polymers derived from natural polymers are cationic derivatives of polysaccharides, for example, cationic derivatives of cellulose, starch or guar. Also suitable are chitosan and chitosan derivatives. Cationic polysaccharides have the general formula
B is a divalent linking group, for example, alkylene, oxyalkylene, polyoxyalkylene or hydroxyalkylene;
R 1 , R 2 and R 3 are, independently of one another, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl or alkoxyaryl having in each case up to 18 C atoms, the total number of carbon atoms in R 1 , R 2 and R 3 preferably being at most 20;
X is a common counter anion X - , for example a halogen, acetate, phosphate, nitrate or alkyl sulfate, preferably a chloride. A cationic cellulose sold by Amerchol under the name Polymer JR has the INCI name Polyquaternium-10. Another cationic cellulose bears the INCI name Polyquaternium-24 and is sold under the trade name Polymer LM-200 by Amerchol. A suitable cationic guar derivative is sold under the trade name Jaguar® R and has the INCI name Guar Hydroxypropyltrimonium Chloride. Particularly preferred cationic substances are chitosan, chitosan salts and chitosan derivatives. Chitosans are completely or partially deacetylated chitin. The molecular weight of the chitosan can be distributed over a broad spectrum, for example from 20,000 to about 5 million g / mol. For example, a low molecular weight chitosan having a molecular weight of from 30,000 to 70,000 g / mol is suitable. Preferably, however, the molecular weight is above 100,000 g / mol, more preferably from 200,000 to 700,000 g / mol. The degree of deacetylation is preferably 10 to 99%, more preferably 60 to 99%. A preferred chitosan salt is chitosonium pyrrolidone carboxylate, which is sold, for example, under the name Kytamer® PC by Amerchol, USA. The contained chitosan has a molecular weight of about 200,000 to 300,000 g / mol and is deacetylated to 70 to 85%. Suitable chitosan derivatives are quaternized, alkylated or hydroxyalkylated derivatives, for example hydroxyethyl, hydroxypropyl or hydroxybutylchitosan. The chitosans or chitosan derivatives are preferably in neutralized or partially neutralized form. The degree of neutralization of the chitosan or the chitosan derivative is preferably at least 50%, more preferably between 70 and 100%, based on the number of free base groups. As a neutralizing agent, in principle, all cosmetically acceptable inorganic or organic acids can be used such as formic acid, malic acid, lactic acid, pyrrolidonecarboxylic acid, hydrochloric acid, among others, of which the pyrrolidonecarboxylic acid and the lactic acid are particularly preferred.
In einer bevorzugten Ausführungsform enthält das erfindungsgemäße Haarwachsprodukt zusätzlich mindestens ein Pigment. Hierbei kann es sich um farbige Pigmente handeln, welche der Produktmasse oder dem Haar Farbeffekte verleihen oder es kann sich um Glanzeffektpigmente handeln, welche der Produktmasse oder dem Haar Glanzeffekte verleihen. Die Farb- oder Glanzeffekte am Haar sind vorzugsweise temporär, d.h. sie halten bis zur nächsten Haarwäsche und können durch Waschen der Haare mit üblichen Shampoos wieder entfernt werden. Die Pigmente liegen in der Produktmasse in ungelöster Form vor und können in einer Menge von 0,01 bis 25 Gew.%, besonders bevorzugt von 5 bis 15 Gew.% enthalten sein.In a preferred embodiment, the inventive Hair wax product additionally at least one pigment. These may be colored pigments, which are the Product compound or give the hair color effects or it can are glossy effect pigments, which are the product mass or give the hair gloss effects. The color or gloss effects on the hair are preferably temporary, i. you carry until the next shampooing and can by washing the Hair with usual shampoos are removed again. The Pigments are present in the product mass in undissolved form and may be in an amount of 0.01 to 25 wt.%, especially preferably from 5 to 15% by weight.
Bei den Pigmenten handelt es sich vorzugsweise nicht um Nano- sonder um Mikropigmente. Die bevorzugte Teilchengröße beträgt 1 bis 200 µm, insbesondere 3 bis 150 µm, besonders bevorzugt 10 bis 100 µm. The pigments are preferably not Nano-special with micropigments. The preferred particle size is 1 to 200 microns, especially 3 to 150 microns, especially preferably 10 to 100 microns.
Die Pigmente sind im Anwendungsmedium praktisch unlösliche Farbmittel und können anorganisch oder organisch sein. Auch anorganisch-organische Mischpigmente sind möglich. Bevorzugt sind anorganische Pigmente. Der Vorteil der anorganischen Pigmente ist deren ausgezeichnete Licht-, Wetter- und Temperaturbeständigkeit. Die anorganischen Pigmente können natürlichen Ursprungs sein, beispielsweise hergestellt aus Kreide, Ocker, Umbra, Grünerde, gebranntem Terra di Siena oder Graphit. Bei den Pigmenten kann es sich um Weißpigmente wie z.B. Titandioxid oder Zinkoxid, um Schwarzpigmente wie z.B. Eisenoxidschwarz, Buntpigmente wie z.B. Ultramarin oder Eisenoxidrot, um Glanzpigmente, Metalleffekt-Pigmente, Perlglanzpigmente sowie um Fluoreszenz- oder Phosphoreszenzpigmente handeln, wobei vorzugsweise mindestens ein Pigment ein farbiges, nicht-weißes Pigment ist. Geeignet sind Metalloxide, -hydroxide und -oxidhydrate, Mischphasenpigmente, schwefelhaltige Silicate, Metallsulfide, komplexe Metallcyanide, Metallsulfate, -chromate und -molybdate sowie die Metalle selbst (Bronzepigmente). Geeignet sind insbesondere Titandioxid (CI 77891), schwarzes Eisenoxid (CI 77499), gelbes Eisenoxid (CI 77492), rotes und braunes Eisenoxid (CI 77491), Manganviolett (CI 77742), Ultramarine (Natrium-Aluminiumsulfosilikate, CI 77007, Pigment Blue 29), Chromoxidhydrat (CI77289), Eisenblau (Ferric Ferrocyanide, CI77510), Carmine (Cochineal).The pigments are practically insoluble in the application medium Colorants and may be inorganic or organic. Also Inorganic-organic mixed pigments are possible. Prefers are inorganic pigments. The advantage of inorganic Pigments is their excellent light, weather and temperature resistance. The inorganic pigments can be natural Origin, for example made from Chalk, ocher, umber, green earth, burnt Terra di Siena or graphite. The pigments can be white pigments such as. Titanium dioxide or zinc oxide to black pigments like e.g. Iron oxide black, colored pigments such as e.g. Ultramarine or Iron oxide red, luster pigments, metallic effect pigments, pearlescent pigments as well as fluorescent or phosphorescent pigments act, wherein preferably at least one pigment is colored, non-white pigment. Suitable are metal oxides, hydroxides and hydrates, mixed phase pigments, sulphurous silicates, metal sulphides, complex metal cyanides, Metal sulfates, chromates and molybdates, and the Metals themselves (bronze pigments). In particular are suitable Titanium dioxide (CI 77891), black iron oxide (CI 77499), yellow iron oxide (CI 77492), red and brown iron oxide (CI 77491), manganese violet (CI 77742), ultramarines (sodium aluminum sulfosilicates, CI 77007, Pigment Blue 29), chromium oxide hydrate (CI77289), iron blue (Ferric Ferrocyanide, CI77510), Carmine (Cochineal).
Besonders bevorzugt sind Perlglanz- und Farbpigmente auf Mica- bzw. Glimmerbasis welche mit einem Metalloxid oder einem Metalloxychlorid wie Titandioxid oder Wismutoxychlorid sowie gegebenenfalls weiteren farbgebenden Stoffen wie Eisenoxiden, Eisenblau, Ultramarine, Carmine etc. beschichtet sind und wobei die Farbe durch Variation der Schichtdicke bestimmt sein kann. Derartige Pigmente werden beispielsweise unter den Handelsbezeichnungen Rona® , Colorona®, Dichrona® und Timiron® von der Firma Merck, Deutschland vertrieben.Pearlescent and color pigments are particularly preferred Mica or mica base which with a metal oxide or a metal oxychloride such as titanium dioxide or bismuth oxychloride and optionally other coloring substances such as iron oxides, Iron blue, ultramarine, carmine etc. are coated and wherein the color is determined by varying the layer thickness can be. Such pigments are, for example, among the Trade names Rona®, Colorona®, Dichrona® and Timiron® sold by Merck, Germany.
Organische Pigmente sind beispielsweise die natürlichen Pigmente Sepia, Gummigutt, Knochenkohle, Kasseler Braun, Indigo, Chlorophyll und andere Pflanzenpigmente. Synthetische organische Pigmente sind beispielsweise Azo-Pigmente, Anthrachinoide, Indigoide, Dioxazin-, Chinacridon-, Phtalocyanin-, Isoindolinon-, Perylen- und Perinon-, Metallkomplex-, Alkaliblau- und Diketopyrrolopyrrol-Pigmente.Organic pigments are, for example, the natural ones Pigments Sepia, Cambogia, Bone Charcoal, Kasseler Brown, Indigo, chlorophyll and other plant pigments. synthetic organic pigments are, for example, azo pigments, Anthraquinoids, indigoids, dioxazine, quinacridone, phthalocyanine, Isoindolinone, perylene and perinone, metal complex, Alkaline blue and diketopyrrolopyrrole pigments.
Das erfindungsgemäße Haarwachsprodukt kann auch anstelle von oder zusätzlich zu den Pigmenten gelöste Farbstoffe enthalten.The hair wax product according to the invention may also be used instead of or in addition to the pigments dissolved dyes.
Das erfindungsgemäße Haarwachsprodukt ist vorzugsweise im wesentlichen wasserfrei, d.h. es enthält entweder kein oder nur geringe Mengen Wasser bis maximal 10 Gew.% oder weniger als 5 Gew.%.The hair wax product according to the invention is preferably in essentially anhydrous, i. it contains either no or only small amounts of water up to a maximum of 10% by weight or less as 5% by weight.
Zusätzlich können auch geeignete hydrophobe, silikonfreie, weichwachsartige Stoffe in Mengen von z.B. 0,1 bis 10 Gew.% eingesetzt werden. Die Erstarrungspunkte dieser weichswachsartigen Stoffe liegen in der Regel im Bereich von ca. 25°C bis unter 40°C, z.B. halbfeste Paraffine, insbesondere Produkte mit der INCI-Bezeichnung Petrolatum, z.B. Vaseline. Hierbei handelt es sich um eine halbfeste Mischung von aus Petroleum gewonnenen Kohlenwasserstoffen.In addition, suitable hydrophobic, silicone-free, soft waxy substances in amounts of e.g. 0.1 to 10% by weight be used. The solidification points of this soft-waxy Substances are usually in the range of about 25 ° C to below 40 ° C, e.g. semi-solid paraffins, in particular products with the INCI name petrolatum, e.g. Vaseline. in this connection it is a semi-solid mixture of petroleum recovered hydrocarbons.
Zusätzlich zu den vorstehend genannten Inhaltsstoffen kann die Zusammensetzung weitere Zusatzstoffe enthalten:
- Lösungsmittel wie ein- oder mehrwertige C1- bis C4-Alkohole, insbesondere Ethanol, Isopropanol, Glycerine oder Glykole in einer Menge bis zu 15 Gew.%, vorzugsweise 0,1 bis 8 Gew.%
- Gelöste kosmetische Farbstoffe in einer Menge bis zu 6 Gew.%, vorzugsweise 0,1 bis 4 Gew.%
- Parfüm- und Duftstoffe in einer Menge von bis zu 2 Gew.%, vorzugsweise 0,01 bis 1 Gew.% oder 0,2 bis 0,5 Gew.%
- Konservierungsmittel in einer Menge von bis zu 1 Gew.%, vorzugsweise 0,01 bis 0,5 Gew.%, insbesondere Parahydroxybenzoesäureester, Benzoesäure, Salicylsäure, Sorbinsäure, Mandelsäure, Polyhexamethylen-biguanid-hydrochlorid oder Isothiazolinonderivate
- Haarpflegende Zusätze wie z.B. Betain, Panthenol, Menthol, Vitamine oder ähnliche Stoffe in einer Menge von bis zu 5 Gew.%, vorzugsweise 0,01 bis 4 Gew.% oder 0,1 bis 0,5 Gew.%;
- Lichtschutzstoffe, UV-Filter etc. in einer Menge von bis zu 5 Gew.%, vorzugsweise 0,01 bis 4 Gew.%.
- Solvents such as mono- or polyhydric C 1 - to C 4 -alcohols, in particular ethanol, isopropanol, glycerols or glycols in an amount of up to 15% by weight, preferably 0.1 to 8% by weight.
- Dissolved cosmetic dyes in an amount of up to 6% by weight, preferably 0.1 to 4% by weight
- Perfumes and fragrances in an amount of up to 2% by weight, preferably 0.01 to 1% by weight or 0.2 to 0.5% by weight.
- Preservatives in an amount of up to 1% by weight, preferably 0.01 to 0.5% by weight, in particular parahydroxybenzoic acid esters, benzoic acid, salicylic acid, sorbic acid, mandelic acid, polyhexamethylene biguanide hydrochloride or isothiazolinone derivatives
- Hair care additives such as betaine, panthenol, menthol, vitamins or similar substances in an amount of up to 5% by weight, preferably 0.01 to 4% by weight or 0.1 to 0.5% by weight;
- Light stabilizers, UV filters, etc. in an amount of up to 5 wt.%, Preferably 0.01 to 4 wt.%.
Eine bevorzugte Ausführungsform ist ein Haarwachsprodukt mit
einem Gehalt an
Erfindungsgemäße Haarwachsprodukte können hergestellt werden, indem die festen Wachskomponenten aufgeschmolzen und mit den übrigen, nicht-flüchtigen Inhaltsstoffen vermischt werden. Anschließend wird abgekühlt und kurz vor dem Erstarren werden gegebenenfalls leichtflüchtige Zusatzstoffe zugegeben und vermischt. Die noch fließfähige Masse wird vor dem Erstarren in die gewünschte Verpackung, z.B. Kunststofftiegel abgefüllt.Hair wax products according to the invention can be produced Be melted by melting the solid wax components and mixed with the remaining, non-volatile ingredients become. It is then cooled and shortly before Solidify, if necessary, volatile additives added and mixed. The still flowable mass is present solidifying into the desired packaging, e.g. Plastic pot bottled.
Gegenstand der Erfindung ist auch die Verwendung einer erfindungsgemäßen, festen Zusammensetzung zur Haarbebehandlung sowie ein Verfahren zur Haarbehandlung, bei welchem ein erfindungsgemäßes Haarwachsprodukt bereit gestellt wird, die Zusammensetzung auf das Haar aufgebracht und eine Frisur erstellt wird.The invention is also the use of a According to the invention, a solid composition for hair treatment and a method of hair treatment in which a Inventive hair wax product is provided, the Composition applied to the hair and a hairstyle is created.
Das Produkt wird bevorzugt auf trockenem Haar angewendet. Eine Menge, die in Abhängigkeit der Haarlänge varriieren kann, z.B. von ungefähr Erbsengröße bis ungefähr Haselnussgröße wird mit den Fingern entnommen. Das Wachs wird in den Handflächen verrieben und durch die Handwärme und durch die Verreibung erfolgende Scherung aufgeschmolzen oder zumindest stark erweicht. Im erweichten oder mehr oder weniger flüssigen Zustand wird das Wachs in das Haar eingearbeitet und die gewünschte Frisur erstellt. Es können auch separate Haarsträhnen oder Locken einzeln behandelt werden, um diese zu akzentuieren. Im Haar erhärtet das Wachs und die gestaltete Frisur erhält Stabilität, Glanz, Texture und Halt.The product is preferably applied to dry hair. A lot that vary depending on the hair length can, e.g. from about peas size to about hazelnut size is taken with your fingers. The wax is in the Palms and rubbed by the hand warmth and by the Melting shear, or at least melted strongly softened. In the softened or more or less liquid Condition, the wax is incorporated into the hair and the desired hairstyle created. It can also have separate strands of hair or curls are treated individually to this accentuate. In the hair the wax and the formed harden Hairstyle maintains stability, shine, texture and hold.
Das erfindungsgemäße Haarwachsprodukt ermöglicht aufgrund der wachsartigen Konsistenz und seiner kohäsiven Eigenschaften eine individuelle Frisurengestaltung sowie die gezielte Behandlung einzelner Haarsträhnen. Die Produktmasse ist leicht auf dem Haar verteilbar. Das behandelte Haar zeichnet sich durch einen ausgeprägten Glanz sowie durch eine hohe Formstabilität der erstellten Frisur aus. Das Haar wird dabei nicht übermäßig belastet und die Produktmasse ist leicht auswaschbar. Das Produkt zeichnet sich im Vergleich zu herkömmlichen Produkten durch eine reduzierte Klebrigkeit der behandelten Haare aus. The hair wax product of the invention allows due to the waxy consistency and its cohesive properties an individual hairstyle design as well as the targeted Treatment of individual strands of hair. The product mass is Easily distributed on the hair. The treated hair is drawing characterized by a pronounced shine as well as a high Dimensional stability of the created hairstyle. The hair will be there not overly stressed and the product mass is easily washed out. The product stands out in comparison to conventional ones Products due to reduced stickiness of treated hair out.
Die nachfolgenden Beispiele sollen den Gegenstand der Erfindung näher erläutern.The following examples are intended to illustrate the subject matter of Explain the invention in more detail.
Die erfindungsgemäße Zusammenstzung A wird hinsichtlich ihrer Anwendungseingeschaften mit der nicht erfindungsgemäßen Vergleichszusammensetzung B durch eine sensorische Überprüfung durch Anfühlen verglichen. Haare, die mit Zusammensetzung A behandelt sind, weisen eine deutlich geringere Klebrigkeit auf als Haare, die mit Zusammensetzung B behandelt sind.The composition A of the invention is in terms of their Anwendungsseingeschaften with the non-inventive Comparative Composition B by Sensory Examination compared by feel. Hair with composition A treated, have a much lower Sticky on as hair, with composition B are treated.
Die erfindungsgemäßen Zusammensetzungen zeichnen sich aus durch eine gute Verteilbarkeit, eine gute Einarbeitbarkeit in das Haar, eine gute Auswaschbarkeit, gute Struktur und Glanz der Haare, einen anti-Frizz Effekt, einen natürlichen Halt der Haare, einen glatten Griff der Haare, eine gute Modellierbarkeit von Locken und eine gute Akzentuierbarkeit einzelner Haarsträhnen.The compositions of the invention are characterized through a good dispersibility, a good incorporability in the hair, a good washability, good structure and shine hair, an anti-frizz effect, a natural hold the hair, a smooth grip of the hair, a good one Modelability of curls and good accentuation individual strands of hair.
Claims (16)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004004155A DE102004004155A1 (en) | 2004-01-28 | 2004-01-28 | Hair wax product made of silicone wax, silicone-free wax and oils |
DE102004004155 | 2004-01-28 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1559402A1 true EP1559402A1 (en) | 2005-08-03 |
EP1559402B1 EP1559402B1 (en) | 2007-08-15 |
Family
ID=34638767
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05000097A Not-in-force EP1559402B1 (en) | 2004-01-28 | 2005-01-05 | Hairwax product made of silicone wax, a silicone-free wax and oils. |
Country Status (6)
Country | Link |
---|---|
US (1) | US7758849B2 (en) |
EP (1) | EP1559402B1 (en) |
JP (1) | JP2005213252A (en) |
AT (1) | ATE369838T1 (en) |
BR (1) | BRPI0500242A (en) |
DE (2) | DE102004004155A1 (en) |
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WO2006082102A2 (en) * | 2005-02-04 | 2006-08-10 | Schwan-Stabilo Cosmetics Gmbh & Co. Kg | Preparation, especially cosmetic preparation, and production and use thereof |
EP1800648A1 (en) | 2005-12-13 | 2007-06-27 | Beiersdorf AG | Hair styling composition in the form of a microemulsion |
FR3021538A1 (en) * | 2014-05-27 | 2015-12-04 | Oreal | ANHYDROUS COSMETIC COMPOSITION IN SOLID FORM AND USES THEREOF |
WO2016062480A1 (en) * | 2014-10-21 | 2016-04-28 | Henkel Ag & Co. Kgaa | Hair styling product with improved applicability |
WO2016083001A1 (en) * | 2014-11-28 | 2016-06-02 | Henkel Ag & Co. Kgaa | Hair styling product with improved applicability and cooling effect |
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DE602005010101D1 (en) * | 2005-12-01 | 2008-11-13 | Wella Ag | Use of di- or oligosaccharide polyesters in hairstyling products |
EP1908456A1 (en) * | 2006-10-04 | 2008-04-09 | Wella Aktiengesellschaft | Non-fluid hair treatment product comprising hair fixative absorbed on waxy carrier |
JP5362179B2 (en) * | 2006-10-20 | 2013-12-11 | 日清オイリオグループ株式会社 | Polyoxyethylene sorbitol fatty acid ester and aqueous wax dispersion containing the same |
JP2007063295A (en) * | 2006-12-12 | 2007-03-15 | Kao Corp | Hair treatment method |
EP2220156A4 (en) * | 2007-11-09 | 2013-01-23 | Pacific Polymers Pty Ltd | Hydrophobic modification of mineral fillers and mixed polymer systems |
JP5574621B2 (en) * | 2009-05-21 | 2014-08-20 | 株式会社マンダム | Hairdressing cosmetics |
JP5663753B2 (en) * | 2010-09-08 | 2015-02-04 | 株式会社サイエンスリン | Hair treatment composition |
JP5890962B2 (en) * | 2011-02-28 | 2016-03-22 | 中野製薬株式会社 | Oily styling cosmetic |
FR2996760B1 (en) * | 2012-10-15 | 2016-07-15 | Oreal | METHOD FOR THE COSMETIC TREATMENT OF HAIR USING A COMPOSITION COMPRISING PARTICLE DISPERSION COMPRISING A STATE-CHANGING MATERIAL UNDER THE EFFECT OF A STIMULUS |
WO2014202559A1 (en) * | 2013-06-17 | 2014-12-24 | L'oreal | Cosmetic composition including a mineral wax, a fatty acid, a mineral oil, a surfactant, a fatty acid and/or fatty alcohol ester, and a fixing polymer |
JP6995473B2 (en) * | 2016-12-08 | 2022-01-14 | ロレアル | Composition suitable for cleansing |
EP3597172A1 (en) * | 2018-07-16 | 2020-01-22 | Kao Germany GmbH | Hair treatment composition |
WO2020215300A1 (en) | 2019-04-26 | 2020-10-29 | Beiersdorf Daily Chemical (Wuhan) Co. Ltd. | A Hair Wax Composition |
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- 2005-01-05 EP EP05000097A patent/EP1559402B1/en not_active Not-in-force
- 2005-01-05 AT AT05000097T patent/ATE369838T1/en not_active IP Right Cessation
- 2005-01-25 US US11/042,231 patent/US7758849B2/en active Active
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Also Published As
Publication number | Publication date |
---|---|
DE102004004155A1 (en) | 2005-08-18 |
EP1559402B1 (en) | 2007-08-15 |
JP2005213252A (en) | 2005-08-11 |
DE502005001201D1 (en) | 2007-09-27 |
BRPI0500242A (en) | 2006-04-11 |
US7758849B2 (en) | 2010-07-20 |
ATE369838T1 (en) | 2007-09-15 |
US20050163738A1 (en) | 2005-07-28 |
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