EP1552226B1 - Improvements in and relating to heaters - Google Patents

Improvements in and relating to heaters Download PDF

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Publication number
EP1552226B1
EP1552226B1 EP03763967A EP03763967A EP1552226B1 EP 1552226 B1 EP1552226 B1 EP 1552226B1 EP 03763967 A EP03763967 A EP 03763967A EP 03763967 A EP03763967 A EP 03763967A EP 1552226 B1 EP1552226 B1 EP 1552226B1
Authority
EP
European Patent Office
Prior art keywords
heating element
heater
heat exchange
exchange material
compartment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP03763967A
Other languages
German (de)
French (fr)
Other versions
EP1552226A1 (en
Inventor
Leo Lamb
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
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Filing date
Publication date
Priority claimed from GB0216352A external-priority patent/GB0216352D0/en
Priority claimed from GB0216772A external-priority patent/GB0216772D0/en
Application filed by Individual filed Critical Individual
Publication of EP1552226A1 publication Critical patent/EP1552226A1/en
Application granted granted Critical
Publication of EP1552226B1 publication Critical patent/EP1552226B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D1/00Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
    • F28D1/02Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid
    • F28D1/0226Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with an intermediate heat-transfer medium, e.g. thermosiphon radiators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H3/00Air heaters
    • F24H3/002Air heaters using electric energy supply
    • F24H3/004Air heaters using electric energy supply with a closed circuit for a heat transfer liquid
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F13/00Arrangements for modifying heat-transfer, e.g. increasing, decreasing
    • F28F13/18Arrangements for modifying heat-transfer, e.g. increasing, decreasing by applying coatings, e.g. radiation-absorbing, radiation-reflecting; by surface treatment, e.g. polishing

Definitions

  • the present invention relates to an improved heater and to a method of manufacturing the same.
  • Heaters that include an electrical heating element as their heat source are commonplace.
  • the heating element is screwed into a boss at one side of the heater and extends into a compartment that contains oil for transferring heat through the heater.
  • the compartment may be partially evacuated and contain a small amount of working fluid, such as water, whereby the working fluid is heated by means of the heat that is transferred from the heating element.
  • the working fluid is always in its liquid phase around the heating element but turns to vapour further up the compartment as it is heated.
  • rapid heating of the fluid by the heating element can cause kettling to occur in the system. Kettling is undesirable because it is extremely noisy.
  • EP 0 668 479 (British Gas plc) describes a themosyphon radiator having a hot water pipe that may be surrounded by a covering.
  • GB 2 099 980 (Ssurrah) describes a hot water pipe surrounded by a metal gauze wick.
  • GB 695628 (Richings) discloses a method for manufacturing a heater by attaching a first part of an enclosure unit to a second part to form a sealed enclosure around a heat transfer medium.
  • a further aim of the present invention is to provide a method of manufacturing an improved heater that retards kettling.
  • a first aspect of the present invention provides a heater comprising a partially evacuated sealed enclosure containing a working fluid and an electrical heating element, characterised in that the electrical heating element is surrounded by a porous or perforated heat exchange material contained within a compartment, said working fluid being provided in an amount such that in normal use the heating element and heat exchange material are always immersed in the liquid phase of the working fluid.
  • the heat exchange material increases the area of heat transfer from the element to the fluid thereby retarding kettling.
  • the heat exchange material should have pores or perforations to allow fluid to pass therethrough whilst acting as a damper to aid dissipation of heat from the heating element.
  • the heat exchange material is a fibrous material, such as a metal wool. More preferably, the heat exchange material is wire wool of non-corrosive metal, such as, for example, of stainless steel.
  • a second aspect of the present invention provides a method of manufacturing a heater that retards kettling, the method comprising attaching a first part of an enclosure unit to a second part of an enclosure unit to form a sealed enclosure, characterised by attaching a porous or perforated heat exchange material to the first part of an enclosure unit prior to its attachment to the second part creating a bore though said heat exchange material and inserting an electrical heating element through said bore.
  • the second part is pressed onto the first part of the enclosure.
  • the heat exchange material is compressed or compacted either before or during its installation in the heater.
  • the heat exchange material is preferably provided across a lower part of the enclosure unit corresponding in position to the location of the electrical heating element.
  • the bore is preferable for the bore to be created through the compacted heat exchange material by insertion of the heating element therethrough.
  • a cartridge having a tapered or pointed end may be inserted through the compacted medium to create the bore.
  • the working fluid is water and is provided in an amount such that the heating element and heat exchange material are always immersed in liquid.
  • the working fluid may be vapour elsewhere in the enclosure.
  • the heat exchange material may be contained within a compartment that covers the heating element
  • the compartment may be in the form of a sleeve, more preferably a tubular sleeve.
  • one end of the sleeve is attachable to a boss of the heater to which the heating element is connected and the other end of the sleeve is closed.
  • the compartment may be single or multiple walled. A twin-walled sleeve may be useful in the present invention.
  • the compartment may be provided with fins.
  • the fins may be attached to the compartment or may be pressed therein.
  • the invention further provides a heating element in the form of a cartridge comprising an electrical heating element and a porous or perforated heat exchange material in contact with the heating element characterised in that the heating element is contained within an inner space defining component and the heat exchange material is contained within an outer space defining component surrounding the inner component.
  • the inner space defining component may comprise a pair of spaced rings connected by rods to provide a space to receive a heating element.
  • the outer component may comprise a pair of spaced rings connected by rods.
  • both a wire wool heat transfer medium such as of stainless steel wire wool and a particulate heat transfer medium, such as aluminium oxide.
  • a twin-walled sleeve defining inner and outer compartments is desirably used, with one medium in the inner compartment and the other medium in the outer compartment.
  • the wire wool is preferably placed in the inner compartment and the particulate medium in the outer compartment.
  • the compartment may be made of any suitable heat conducting material, such as steel, brass or chromium.
  • the walls of the compartment may be solid or may be made from gauze.
  • a pressure release valve is provided within the compartment, preferably being countersunk into the compartment walls at the end opposite the boss.
  • a heater 2 comprises a partially evacuated self-contained enclosure or unit 4 containing a heating element 8 towards the base thereof and a small amount of working fluid 6, such as water. Means 18 for evacuation of the unit, such as a valve, is also provided.
  • the water 6 covers the region of the enclosure that contains the heating element.
  • the heating element is contained within a region of compressed stainless steel wire wool 10.
  • a gauze (not shown) may be provided around the heating element.
  • the wire wool provides a greater area for dissipation of the heat energy that is released from the heating element and prevents kettling of the water that surrounds the element whilst being lightweight and allowing heat to be transferred to the water.
  • Such an arrangement has been found to reduce the wattage being dispersed from the heating element from around 217000 watts per m 2 (140 watts per sq. inch) to around 4.6 7131 watts per m 2 (watts per sq. inch) thereby reducing kettling. It is believed that air is able to travel up the fibres thereby preventing the explosion of trapped air that causes kettling.
  • the heater is manufactured by the compressed wire wool being attached to a first half of the enclosure unit and a second half of the unit is then pressed onto the first half. A bore is then inserted through the wool to create a passage for receiving the heating element. The bore is dimensioned such that the heating element fits snugly therein.
  • the heating element is a cartridge having a tapered or pointed end that is pushed through the compressed wire wool thereby creating the bore as the element is inserted therethrough. This ensures there is close contact between the element and the wire wool which is important to provide the necessary heat transfer. This provides an anti-kettling device that has minimal, if any, effect on the wattage of the device.
  • a heating element 20 is enclosed within a twin-walled metal gauze sleeve 22.
  • the sleeve 22 has an inner compartment 24 and an outer compartment 26 surrounding the inner compartment.
  • Within the inner compartment 24 is stainless steel wire wool and within the outer compartment 26 is an aluminium oxide paste.
  • a pressure release valve (not shown) may be provided in the sleeve to prevent pressure build up.
  • FIG. 3 of the accompanying drawings shows an anti-kettling cartridge 30 for use in a heating system of the type shown in Figure 1 of the drawings.
  • the cartridge is designed to be slid onto a longitudinal heating element, such as element 8 of Figure 1.
  • the cartridge comprises a pair of smaller rings 32 connected by rods 34.
  • the rings 32 are internally screw-threaded so as to be connectable to an externally screw-threaded ring of the heating element.
  • the rings 32 and rods 34 provide a space to receive the heating element.
  • Stainless steel wire wool (not shown) is packed around the rings 32 and rods 34, so that it contains the heating element.
  • the wire wool is contained by spaced larger outer rings 36 connected by rods 38.
  • Each of the larger rings 36 is in the same place as one of the smaller rings 32.
  • the outer rings 36 and rods 38 may be replaced by a perforated cylinder.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical & Material Sciences (AREA)
  • Resistance Heating (AREA)
  • Instantaneous Water Boilers, Portable Hot-Water Supply Apparatuses, And Control Of Portable Hot-Water Supply Apparatuses (AREA)
  • Cookers (AREA)
  • Heat-Pump Type And Storage Water Heaters (AREA)
  • Electrodes For Cathode-Ray Tubes (AREA)
  • Electric Stoves And Ranges (AREA)

Abstract

A heater (2) comprises a sealed enclosure (4) containing a heating element (8) and a heat transfer fluid (6) wherein the heating element is surrounded by a confined transfer medium (10).

Description

  • The present invention relates to an improved heater and to a method of manufacturing the same.
  • A wide range of heaters exist that use different types of heat transfer media as their source of heat. Heaters that include an electrical heating element as their heat source are commonplace. Generally, the heating element is screwed into a boss at one side of the heater and extends into a compartment that contains oil for transferring heat through the heater. Alternatively, the compartment may be partially evacuated and contain a small amount of working fluid, such as water, whereby the working fluid is heated by means of the heat that is transferred from the heating element. The working fluid is always in its liquid phase around the heating element but turns to vapour further up the compartment as it is heated. However, rapid heating of the fluid by the heating element can cause kettling to occur in the system. Kettling is undesirable because it is extremely noisy.
  • EP 0 668 479 (British Gas plc) describes a themosyphon radiator having a hot water pipe that may be surrounded by a covering. GB 2 099 980 (Ssurrah) describes a hot water pipe surrounded by a metal gauze wick. GB 695628 (Richings) discloses a method for manufacturing a heater by attaching a first part of an enclosure unit to a second part to form a sealed enclosure around a heat transfer medium.
  • It is an aim of the present invention to provide an improved heater that retards kettling.
  • A further aim of the present invention is to provide a method of manufacturing an improved heater that retards kettling.
  • Accordingly, a first aspect of the present invention provides a heater comprising a partially evacuated sealed enclosure containing a working fluid and an electrical heating element, characterised in that the electrical heating element is surrounded by a porous or perforated heat exchange material contained within a compartment, said working fluid being provided in an amount such that in normal use the heating element and heat exchange material are always immersed in the liquid phase of the working fluid.
  • The heat exchange material increases the area of heat transfer from the element to the fluid thereby retarding kettling. The heat exchange material should have pores or perforations to allow fluid to pass therethrough whilst acting as a damper to aid dissipation of heat from the heating element. Preferably, the heat exchange material is a fibrous material, such as a metal wool. More preferably, the heat exchange material is wire wool of non-corrosive metal, such as, for example, of stainless steel.
  • A second aspect of the present invention provides a method of manufacturing a heater that retards kettling, the method comprising attaching a first part of an enclosure unit to a second part of an enclosure unit to form a sealed enclosure, characterised by attaching a porous or perforated heat exchange material to the first part of an enclosure unit prior to its attachment to the second part creating a bore though said heat exchange material and inserting an electrical heating element through said bore.
  • Preferably, the second part is pressed onto the first part of the enclosure. Preferably, the heat exchange material is compressed or compacted either before or during its installation in the heater. The heat exchange material is preferably provided across a lower part of the enclosure unit corresponding in position to the location of the electrical heating element.
  • It is preferable for the bore to be created through the compacted heat exchange material by insertion of the heating element therethrough. For example, a cartridge having a tapered or pointed end may be inserted through the compacted medium to create the bore.
  • Preferably, the working fluid is water and is provided in an amount such that the heating element and heat exchange material are always immersed in liquid. However, the working fluid may be vapour elsewhere in the enclosure.
  • The heat exchange material may be contained within a compartment that covers the heating element The compartment may be in the form of a sleeve, more preferably a tubular sleeve. Preferably, one end of the sleeve is attachable to a boss of the heater to which the heating element is connected and the other end of the sleeve is closed. The compartment may be single or multiple walled. A twin-walled sleeve may be useful in the present invention.
  • The compartment may be provided with fins. The fins may be attached to the compartment or may be pressed therein.
  • The invention further provides a heating element in the form of a cartridge comprising an electrical heating element and a porous or perforated heat exchange material in contact with the heating element characterised in that the heating element is contained within an inner space defining component and the heat exchange material is contained within an outer space defining component surrounding the inner component. The inner space defining component may comprise a pair of spaced rings connected by rods to provide a space to receive a heating element. The outer component may comprise a pair of spaced rings connected by rods.
  • In one embodiment of the invention it may be possible to use both a wire wool heat transfer medium, such as of stainless steel wire wool and a particulate heat transfer medium, such as aluminium oxide. When using both types of heat transfer media, a twin-walled sleeve defining inner and outer compartments is desirably used, with one medium in the inner compartment and the other medium in the outer compartment. The wire wool is preferably placed in the inner compartment and the particulate medium in the outer compartment.
  • The compartment may be made of any suitable heat conducting material, such as steel, brass or chromium. The walls of the compartment may be solid or may be made from gauze.
  • Preferably, a pressure release valve is provided within the compartment, preferably being countersunk into the compartment walls at the end opposite the boss.
  • For a better understanding of the present invention and to show more clearly how it may be carried into effect reference will now be made by way of example only to the accompanying drawings, in which:
    • Figure 1 is a cross-sectional longitudinal view of a heating system according to one embodiment of the present invention;
    • Figure 2 shows a heating system according to a second embodiment of the invention; and
    • Figure 3 shows an anti-kettling cartridge.
  • Referring to Figure 1 of the accompanying drawings a heater 2 comprises a partially evacuated self-contained enclosure or unit 4 containing a heating element 8 towards the base thereof and a small amount of working fluid 6, such as water. Means 18 for evacuation of the unit, such as a valve, is also provided. The water 6 covers the region of the enclosure that contains the heating element. The heating element is contained within a region of compressed stainless steel wire wool 10. A gauze (not shown) may be provided around the heating element.
  • The wire wool provides a greater area for dissipation of the heat energy that is released from the heating element and prevents kettling of the water that surrounds the element whilst being lightweight and allowing heat to be transferred to the water. Such an arrangement has been found to reduce the wattage being dispersed from the heating element from around 217000 watts per m2 (140 watts per sq. inch) to around 4.6 7131 watts per m2 (watts per sq. inch) thereby reducing kettling. It is believed that air is able to travel up the fibres thereby preventing the explosion of trapped air that causes kettling.
  • The heater is manufactured by the compressed wire wool being attached to a first half of the enclosure unit and a second half of the unit is then pressed onto the first half. A bore is then inserted through the wool to create a passage for receiving the heating element. The bore is dimensioned such that the heating element fits snugly therein. This provides a very simple method of manufacturing of a heater, removing the need to manually coat/cover the heating element with a material prior to its insertion in the enclosure.
  • The heating element is a cartridge having a tapered or pointed end that is pushed through the compressed wire wool thereby creating the bore as the element is inserted therethrough. This ensures there is close contact between the element and the wire wool which is important to provide the necessary heat transfer. This provides an anti-kettling device that has minimal, if any, effect on the wattage of the device.
  • Turning to Figure 2 of the accompanying drawings, a heating element 20 is enclosed within a twin-walled metal gauze sleeve 22. The sleeve 22 has an inner compartment 24 and an outer compartment 26 surrounding the inner compartment. Within the inner compartment 24 is stainless steel wire wool and within the outer compartment 26 is an aluminium oxide paste. A pressure release valve (not shown) may be provided in the sleeve to prevent pressure build up.
  • Figure 3 of the accompanying drawings shows an anti-kettling cartridge 30 for use in a heating system of the type shown in Figure 1 of the drawings. The cartridge is designed to be slid onto a longitudinal heating element, such as element 8 of Figure 1.
  • The cartridge comprises a pair of smaller rings 32 connected by rods 34. The rings 32 are internally screw-threaded so as to be connectable to an externally screw-threaded ring of the heating element. The rings 32 and rods 34 provide a space to receive the heating element.
  • Stainless steel wire wool (not shown) is packed around the rings 32 and rods 34, so that it contains the heating element. The wire wool is contained by spaced larger outer rings 36 connected by rods 38. Each of the larger rings 36 is in the same place as one of the smaller rings 32.
  • The outer rings 36 and rods 38 may be replaced by a perforated cylinder.

Claims (26)

  1. A heater comprising a partially evacuated sealed enclosure (4) containing a working fluid and an electrical heating element (8) characterised in that the electric heating element is surrounded by a porous or perforated heat exchange material (10) contained within a compartment, said working fluid being provided in an amount such that in normal use the heating element and heat exchange material are always immersed in the liquid phase of the working fluid.
  2. A heater as claimed in claim 1, characterised in that the heat exchange material (10) has pores or perforations.
  3. A heater as claimed in claim 1 or 2, characterised in that the heat exchange material (10) is a fibrous material.
  4. A heater as claimed in claim 3, characterised in that the heat exchange material (10) is a metal wool.
  5. A heater as claimed in claim 4, characterised in that the heat exchange material (10) is a wire wool of non-corrosive metal.
  6. A heater as claimed in claim 5, characterised in that the wire wool is of stainless steel.
  7. A heater as claimed in claims 1 to 6, characterised in that the compartment is a sleeve (22).
  8. A heater as claimed in claim 7, characterised in that one end of the sleeve is attached to a boss of the heater to which the heating element is connected and the other end of the sleeve is closed.
  9. A heater as claimed in claim 7 or 8, characterised in that the sleeve (22) is twin-walled.
  10. A heater as claimed in any one of claims 1 to 9, characterised in that the compartment has fins.
  11. A heater as claimed in any one of claims 1 to 10, characterised in that the heat exchange material (10) comprises a wire wool and a particulate heat transfer medium.
  12. A heater as claimed in claim 11, characterised in that the particulate heat transfer medium is aluminium oxide.
  13. A heater as claimed in claim 11 or 12, characterised in that the core heat exchange material is in an inner compartment (24) and the other is in an outer compartment (26).
  14. A heater as claimed in any one of the preceding claims, characterised in that the compartment is made of a heat conductive material.
  15. A heater as claimed in any one of the preceding claims, characterised in that the compartment includes a pressure release valve.
  16. A method of manufacturing a heater that retards kettling comprising attaching a first part of an enclosure unit to a second part of an enclosure unit to form a sealed enclosure, characterised by attaching a porous or perforated heat exchange material (10) to the first part of the enclosure unit prior to its attachment to the second part, creating a bore through said heat exchange material and inserting a heating element (8) through said bore.
  17. A method as claimed in claim 16, characterised in that the second part is pressed onto the first part of the enclosure.
  18. A method as claimed in claim 17, characterised in that the heat exchange material (10) is compressed or compacted either before or during its installation in the heater.
  19. A method as claimed in claims 16,17 or 18, characterised in that the heat exchange material is provided across a lower part of the enclosure unit (4) corresponding in position to the location of the heating element (8).
  20. A heating element in the form of a cartridge (30) comprising an electrical heating element and a porous or perforated heat exchange material in contact with the heating element characterised in that the heating element is contained within an inner space defining component and the heat exchange material is contained within an outer space defining component surrounding the inner component.
  21. A heating element as claimed in claim 20, characterised in that the inner space defining component comprises a pair of spaced rings (32) connected by rods (34).
  22. A, heating element as claimed in claim 20 or 21, characterised in that the outer space defining component comprises a pair of spaced rings (36) connected by bars (38).
  23. A heating element as claimed in claim 20 or 21, characterised in that the outer space defining component is a perforated or apertured cylinder.
  24. A heating element as claimed in any one of claims 20 to 23, characterised by inclusion of a metal wool heat exchange material.
  25. A heating element a claimed in claim 24, characterised in that the metal wool is of stainless steel.
  26. A heating element as claimed in any one of claims 20 to 24, characterised by the inner space defining component having means for screw-threadingly fixing the heating element (8) therein.
EP03763967A 2002-07-13 2003-07-04 Improvements in and relating to heaters Expired - Lifetime EP1552226B1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB0216352A GB0216352D0 (en) 2002-07-13 2002-07-13 Improvements in and relating to heaters
GB0216352 2002-07-13
GB0216772A GB0216772D0 (en) 2002-07-19 2002-07-19 Improvements in and relating to heaters
GB0216772 2002-07-19
PCT/GB2003/002877 WO2004008040A1 (en) 2002-07-13 2003-07-04 Improvements in and relating to heaters

Publications (2)

Publication Number Publication Date
EP1552226A1 EP1552226A1 (en) 2005-07-13
EP1552226B1 true EP1552226B1 (en) 2007-02-14

Family

ID=30117113

Family Applications (1)

Application Number Title Priority Date Filing Date
EP03763967A Expired - Lifetime EP1552226B1 (en) 2002-07-13 2003-07-04 Improvements in and relating to heaters

Country Status (5)

Country Link
EP (1) EP1552226B1 (en)
AT (1) ATE354066T1 (en)
AU (1) AU2003251157A1 (en)
DE (1) DE60311854T2 (en)
WO (1) WO2004008040A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100513271B1 (en) * 2003-01-11 2005-09-09 김형곤 Hite Pipe using Porous Fire Retardancy Compressed Fiber
GB0501163D0 (en) * 2005-01-20 2005-03-02 Lamb Leo An improved radiator

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2099980B (en) * 1981-05-06 1985-04-24 Scurrah Norman Hugh Heat transfer panels
GB2286881B (en) * 1994-02-22 1998-09-16 British Gas Plc Thermosyphon radiators
EP1352198A1 (en) * 2000-12-19 2003-10-15 Lambco Holdings Ltd An improved heater

Also Published As

Publication number Publication date
DE60311854T2 (en) 2007-10-31
WO2004008040A1 (en) 2004-01-22
AU2003251157A1 (en) 2004-02-02
DE60311854D1 (en) 2007-03-29
ATE354066T1 (en) 2007-03-15
EP1552226A1 (en) 2005-07-13

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