EP1499462A1 - Adaptation du transfert de chaleur sur des coquilles pour coulee continue, en particulier au niveau de la surface du bain - Google Patents
Adaptation du transfert de chaleur sur des coquilles pour coulee continue, en particulier au niveau de la surface du bainInfo
- Publication number
- EP1499462A1 EP1499462A1 EP03727263A EP03727263A EP1499462A1 EP 1499462 A1 EP1499462 A1 EP 1499462A1 EP 03727263 A EP03727263 A EP 03727263A EP 03727263 A EP03727263 A EP 03727263A EP 1499462 A1 EP1499462 A1 EP 1499462A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cooling
- mold
- channels
- mold according
- contact surface
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000012546 transfer Methods 0.000 title claims abstract description 20
- 238000009749 continuous casting Methods 0.000 title claims abstract description 10
- 230000005499 meniscus Effects 0.000 title abstract description 11
- 238000001816 cooling Methods 0.000 claims abstract description 94
- 238000005266 casting Methods 0.000 claims abstract description 18
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 13
- 239000010959 steel Substances 0.000 claims abstract description 13
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims abstract description 8
- 239000000155 melt Substances 0.000 claims abstract description 6
- 150000002739 metals Chemical class 0.000 claims abstract description 3
- 239000002826 coolant Substances 0.000 claims description 15
- 238000013461 design Methods 0.000 claims description 11
- 230000000694 effects Effects 0.000 claims description 11
- 238000006073 displacement reaction Methods 0.000 claims description 3
- 230000009191 jumping Effects 0.000 claims 1
- 238000005553 drilling Methods 0.000 abstract description 2
- 230000004907 flux Effects 0.000 abstract 1
- 238000009826 distribution Methods 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 7
- 239000010949 copper Substances 0.000 description 7
- 229910052802 copper Inorganic materials 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 239000000498 cooling water Substances 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000017525 heat dissipation Effects 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000012549 training Methods 0.000 description 2
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
- B22D11/055—Cooling the moulds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
- B22D11/059—Mould materials or platings
Definitions
- the invention relates to a mold for the continuous casting of molten metals, in particular steel, with cooling channels such as cooling grooves, cooling slots or cooling bores in the mold side facing away from the contact surface with the melt.
- a continuous casting mold in particular a CSP (Compact Strip Production) mold of conventional design in the form of a plate mold, for the continuous casting of ingots or slabs made of steel, is usually formed with side walls, each consisting of a supporting wall and one attached to it, with the metal melt in Conical inner plate exist. Coolant channels which are parallel to one another are preferably provided on the side of the inner plate facing the supporting wall and can be designed as slots which are open to the supporting wall.
- CSP Cosmetic Strip Production
- the heat transfer conditions above the mold height, especially in an area above and below the bath level are variable within limits. For example, the wall temperature of the mold above the bath level is lowered. However, if the heat transfer in the area and / or above the bath level is reduced, the temperature of the mold increases. This has the following advantages:
- the mold which is warmer in the area of the bath level, means that casting powder is melted faster;
- An assignable diagram of the temperature distribution of the melt in the mold corresponds to the curvature of a lying parabola with t ma ⁇ in the area of the increased heat flow density.
- Document DE 38 40 448 C2 describes a continuous casting mold, in particular a plate mold, the side walls of which are each formed by a supporting wall and an inner plate attached to it and coming into contact with molten metal, and wherein coolant channels are provided on the side of the inner plate facing the supporting wall, which are designed as slots open to the supporting wall, the width of which is smaller and the depth of which is greater than the width of the ribs lying between the slots.
- EP 0 551 311 B1 describes a liquid-cooled, width-adjustable plate mold for the continuous casting of steel strands in slab format, in particular for a thickness of less than 100 mm.
- the broad side plates and narrow side plates are designed in the direction of their transverse extension in the sense of an increase in cross section for the strand, the narrow side plates are arranged essentially parallel to one another over the mold height and the broad side plates are concave at least in the area of the smallest slab width designed in such a way that in cross-section the apex height of the mold wall forming an arc compared to an inscribed rectangle on the pouring side of the mold is a maximum of 12 mm per 1000 mm slab width and the shape of the broad side plates at the strand exit end of the mold corresponds to the strand format to be produced.
- the broad side plates are designed as a flat surface in the adjustment range of the narrow side plates and slot-like channels are arranged in the side facing away from the shaping side.
- EP 0 968 779 A1 relates to the formation of a broad side of a slab mold, with a casting plate with an inner surface and an outer surface opposite this, the broad side having an upper and a lower partial region, and at least the upper partial region having a central region and two laterally has side areas arranged therefrom.
- the document proposes that the inner surface of the pouring plate has grooves with undercuts to form cooling channels, and that the grooves are covered by filler pieces that are inserted into the undercuts.
- U.S. Patent 5,207,266 relates to a water-cooled copper mold comprising a copper plate with a rear frame attached thereto to form cooling channels, wherein widths of main channels in the region of the mounting bolts are wider than those in other regions.
- the mold includes the formation of larger channels between right-hand and left-hand channels in the region of the fastening bolts, excluding the bolt connections.
- Branch channels are provided between the main channels and the enlarged channels, wherein at least branch channels and areas of the main channels have more water surface areas than the main and enlarged channels.
- the contact plate of the mold which usually consists of a copper alloy, is in "direct contact” with the liquid and solidified metal.
- the contact plate which is also referred to as a copper plate, is a wearing part and is attached to a carrier element, usually made of steel.
- the recyclable support element is called a water box.
- the mold itself acts as a crystallizer, i.e. H. So much energy is withdrawn from the liquid steel that it is brought in that a stable strand shell is created which can then be continuously pulled out of the mold.
- a first strand shell is formed at the fill level in the mold on the so-called meniscus.
- meniscus stands for the early development area of the strand shell, in which the contact surface of the mold, solid and molten pouring agent as well as liquid steel and strand shell meet. Casting powder and oils are used as pouring aids. These separate metal and copper from one another by lubrication and control the local heat transfer (Fig. 8).
- the first strand shell volume element formed on the meniscus migrates with it
- the cooling channels formed in the mold construction can be made completely within the copper plate or within the water box element. Mixed constructions are also known. In addition, variants are widespread in which filler pieces are arranged between the water tank and the copper plate in such a way that suitable cooling channels are created.
- Cooling ducts with rectangular or circular cross sections are widely used for manufacturing reasons. Corner areas can be rounded. Suitable fillers also produce U, L and T shapes of any orientation with respect to the contact surface.
- the typical arrangement of the cooling channels follows the casting direction individually or in groups, i. H. from top to bottom, and usually equidistant from the contact surface to the metal. The aim of the efforts is to achieve the most homogeneous possible cooling effect via the contact surface of the mold, which is often only possible to a limited extent in the area of fastening points. Often, differently designed cooling channels are combined side by side in cross-sectional area and / or geometric shape in order to further optimize the uniformity of the cooling effect across the casting width (FIG. 10).
- the conventional design of the cooling ducts hitherto aims for a homogeneous cooling effect, whereby the actually existing, inhomogeneous thermal load distribution on the mold plate is not taken into account. Due to the necessary multi-dimensional consideration, two inhomogeneities in the thermal load distribution can be distinguished.
- the local values in the area of the mold level can be higher by a factor of 1.5 to 3, whereas the values at the mold base can be lower by a factor of 0.3 to 0.6.
- the location of the maximum is 20 to 70 mm below the actual mold level, depending on the system and process parameters.
- the absolute values of the average heat flow densities depend on the one hand on casting powder, but in particular also on the casting speed. In the literature, mean heat flow densities of 1.0 MW / m 2 at 0.9 m / min, 2.0 MW / m 2 at 3.0 m / min and 3.0 MW / m 2 at 5.5 m / min are mentioned.
- the expected local heat flow densities can at least be estimated from the factors mentioned.
- the uneven distribution of the heat flow density in the casting direction means that the main thermal wear on the mold plate takes place almost without exception in the area of the casting surface. This manifests itself in striations, cracks, deformations and even flaking of any previously applied layers.
- the load on the mold plate also varies in the width direction. Inhomogeneities usually result from the flow field of the liquid steel that forms in the mold.
- the processes are closely linked to the geometrical design of the steel feed plunger, the contact surface geometry and other process variables. Stationary and transient processes on the mold level formation result in a mostly plant-specific inhomogeneous formation of the meniscus. Inhomogeneous meniscus formation is also associated with an inhomogeneous heat distribution, so that the main damage does not develop evenly over the mold width, but begins concentrated at certain points.
- the invention is based on the object of adapting the heat transfer which is decisive for the cooling effect of the cooling channels by a special geometric configuration of the heat-transferring surface areas of a cooling channel or a group thereof to the local heat flow density of the contact surface of the mold in contact with the melt ,
- the effective heat exchange surfaces on the channel base or on the side walls may be enlarged or reduced.
- the surface area is substantially enlarged or almost doubled, which leads to a higher heat flow density with a considerably more intensive cooling effect at the same flow rate of the cooling medium, with the significant advantage that the temperatures of the mold be significantly reduced, so that in addition to the lower load on the mold If necessary, the water pressure for the cooling water can also be reduced.
- the cooling channel surface is not artificially enlarged above the bath level, because in this area of the mold the heat transfer should rather be reduced in order to support the melting of the mold powder.
- the heat transfer above the bath level is reduced by:
- the measure that the heat dissipation of the heat-transferring surface areas of the cooling channels is carried out by adapting to the heat flow density distribution over the height of the mold has proven to be particularly expedient.
- the temperature profiles along the mold height in the mold are made even more uniform and larger material tensions in the strand shell being created are avoided and their formation of cracks is prevented.
- FIG. 1 shows a section of a mold wall, in an enlarged section, perpendicular to its course
- FIG. 2 another section of the mold wall according to FIG. 1, also in section,
- FIG. 3 cooling channel bores with grooves on their inner surfaces
- FIGS. 4 and 5 comparative parts of heat exchange surfaces without and with an enlarged base surface
- FIG. 6 shows the course of the heat flow density q over the height H of the mold below the bath level
- FIG. 7 shows a diagram of the depth of the grooves R above the height of the mold with an associated profile of a temperature curve T, likewise below the bath level with T max above and below the meniscus area
- FIG. 9 shows two diagrams for comparison, with the mean or global heat flow density or temperature
- FIG. 11 further forms of training of heat exchanger plates
- FIG. 12 shows a distribution of the over the mold height
- FIG. 1 shows an enlarged section 10 of a side 2 of a mold wall facing away from the melt with a slot-like cooling groove 1 arranged therein.
- This has a width B and a depth T.
- the bottom region of the cooling groove 1 has a profile 3 with grooves - Forms, whereby its area compared to a flat design, eg. B. according to Figure 4, is approximately doubled.
- the heat transfer of the heat-transferring surface areas of the cooling groove slots or bores can be carried out by varying the height of the mold to its heat flow density distribution, as is shown, for example, in FIG. 6.
- the grooves 3 have a variable depth 4, for example between 1 and 4 mm, for the purpose of varying the intensity of the heat transfer, and are each formed with an opening angle between 30 ° and 60 °, as shown purely by way of example in FIG. 7 is.
- the grooves 3 can be formed with an opening angle of up to approx. 60 ° and a height of up to approx. 4 mm at intervals "A" and resemble the profile of a thread.
- other shapes such as corrugated, trapezoidal, tooth-shaped or the like, can be provided, which lead to an enlargement of the cooling surface.
- FIG. 2 shows a section 10 of a mold wall, each comprising a piece of a support wall 5 with a piece of an inner plate 6, which are connected tightly to one another, in particular are screwed together.
- the inner plate 6 is penetrated by cooling channels 7, which are designed as slots that are open against the supporting wall 5 and covered by the supporting wall 5.
- the slots are provided on their bottoms with heat exchanger surfaces 3 penetrated by grooves, which result in an artificially increased heat flow density.
- FIG. 3 shows any section 10 of a mold wall with cooling channel bores 8 arranged therein with inner walls 9 designed in the form of grooves or grooves 3.
- FIGS. 4 and 5 show a smooth 11 and a configuration consisting of grooves 12 and the associated temperature values on the basis of indicated parts of coolant channels 7, 7 ', with the formation of heat exchanger plates 11 and 12 to be compared with one another.
- FIG. 6 shows a heat flow density distribution according to the invention, adjusted over the height of the mold, with q ma ⁇ in a limited area below the bath level (bath).
- the temperature curve T in FIG. 7 shows a temperature maximum T max within a range 13 to 17 of variable depth R of the heat-exchanging grooves with Rm ax between points 14 and 15.
- the heat exchanger grooves (3) start at 13 at the level of the bath level.
- the maximum groove depth (4) is reached at 14. This maximum groove depth goes up to 15 and is reduced again to the original level on the way over 16.
- FIG. 8 shows in section a broad side wall of a mold, comprising a support plate 20 with a contact plate 18 fastened to it, a layer of pouring aid and indicated coolant channel 7, a strand shell 19 building up in the casting direction and an assignable heat flow.
- FIG. 9 represents a supplement to FIGS. 6 and 7, with the course of the local heat flow density / temperature as shown in diagrams in comparison to the heat-transferring cooling channel surface as a function of the position of the meniscus.
- Figures 10 and 11 show different design options in the design of cooling slots, and in particular of their bottom region.
- FIG. 12 shows in the form of a table:
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Continuous Casting (AREA)
Abstract
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10218956 | 2002-04-27 | ||
DE10218956 | 2002-04-27 | ||
DE10253735 | 2002-11-19 | ||
DE10253735A DE10253735A1 (de) | 2002-04-27 | 2002-11-19 | Intensivierung des Wärmeüberganges bei Stranggießkokillen |
PCT/EP2003/002384 WO2003092931A1 (fr) | 2002-04-27 | 2003-03-08 | Adaptation du transfert de chaleur sur des coquilles pour coulee continue, en particulier au niveau de la surface du bain |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1499462A1 true EP1499462A1 (fr) | 2005-01-26 |
Family
ID=29403559
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP03727263A Ceased EP1499462A1 (fr) | 2002-04-27 | 2003-03-08 | Adaptation du transfert de chaleur sur des coquilles pour coulee continue, en particulier au niveau de la surface du bain |
Country Status (12)
Country | Link |
---|---|
US (1) | US20050115695A1 (fr) |
EP (1) | EP1499462A1 (fr) |
JP (1) | JP2005529750A (fr) |
CN (1) | CN1318164C (fr) |
AU (1) | AU2003233795A1 (fr) |
BR (1) | BR0307901A (fr) |
CA (1) | CA2483784A1 (fr) |
MX (1) | MXPA04010647A (fr) |
PL (1) | PL371553A1 (fr) |
RU (1) | RU2310543C2 (fr) |
TW (1) | TWI268821B (fr) |
WO (1) | WO2003092931A1 (fr) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005026329A1 (de) | 2005-06-07 | 2006-12-14 | Km Europa Metal Ag | Flüssigkeitsgekühlte Kokille zum Stranggießen von Metallen |
WO2010015399A1 (fr) * | 2008-08-06 | 2010-02-11 | Sms Siemag Ag | Lingotière de coulée continue pour métal en fusion, en particulier pour acier en fusion |
EP2292350A1 (fr) * | 2009-08-04 | 2011-03-09 | Siemens VAI Metals Technologies S.r.l. | Moule pour le moulage en continu de produits longs ou plats, gaine de refroidissement conçue pour coopérer avec un tel moule et ensemble comprenant un tel moule et une telle gaine de refroidissement |
DE102010007812B4 (de) | 2010-02-11 | 2017-04-20 | Ksm Castings Group Gmbh | Verfahren und Vorrichtung zur Herstellung von Kraftfahrzeug-Fahrwerksteilen |
IT1403036B1 (it) * | 2010-11-25 | 2013-09-27 | Danieli Off Mecc | Cristallizzatore per colata continua |
CN102078947B (zh) * | 2011-02-23 | 2012-12-19 | 中冶南方工程技术有限公司 | 用于连铸结晶器凝固传热过程热流密度的计算方法 |
JP6105296B2 (ja) | 2013-01-11 | 2017-03-29 | 株式会社神戸製鋼所 | チタンまたはチタン合金からなる鋳塊の連続鋳造方法 |
AT515566A1 (de) * | 2014-03-06 | 2015-10-15 | Inteco Special Melting Technologies Gmbh | Verfahren zur Kühlung von flüssigkeitsgekühlten Kokillen für metallurgische Prozesse |
ITUB20154787A1 (it) * | 2015-11-06 | 2017-05-06 | Milorad Pavlicevic | Cristallizzatore perfezionato e lingottiera adottante detto cristallizzatore |
US11020794B2 (en) | 2016-10-19 | 2021-06-01 | Jfe Steel Corporation | Continuous casting mold and method for continuously casting steel |
DE102017206914A1 (de) | 2017-04-25 | 2018-10-25 | Sms Group Gmbh | Stranggießkokille mit strömungsoptimierter Kühlung |
EP3406368A1 (fr) * | 2017-05-23 | 2018-11-28 | SMS Concast AG | Lingotière pour la coulée en continu de produits métalliques |
RU2678556C1 (ru) * | 2017-09-18 | 2019-01-29 | Акционерное общество "Первоуральский новотрубный завод" (АО "ПНТЗ") | Гильза кристаллизатора для непрерывной разливки сталей |
CN109822065B (zh) * | 2019-04-11 | 2024-03-22 | 安徽工业大学 | 一种连铸结晶器的宽面铜板及具有该铜板的连铸结晶器 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1082988A (en) * | 1964-12-22 | 1967-09-13 | British Iron Steel Research | Moulds |
US3595302A (en) * | 1967-05-11 | 1971-07-27 | Schloemann Ag | Cooling structure for continuous-casting mold |
JPS5731449A (en) * | 1980-07-31 | 1982-02-19 | Kouka Kuroomu Kogyo Kk | Mold for continuous casting of steel |
US4493361A (en) * | 1981-12-07 | 1985-01-15 | Gus Sevastakis | Continuous casting apparatus |
CH685865A5 (de) * | 1991-09-05 | 1995-10-31 | Concast Standard Ag | Kokille zum Stranggiessen von Stahl |
US5207266A (en) * | 1992-01-03 | 1993-05-04 | Chuetsu Metal Works Co., Ltd. | Water-cooled copper casting mold |
JP2950152B2 (ja) * | 1994-06-28 | 1999-09-20 | 住友金属工業株式会社 | スラブ用連続鋳造鋳型 |
DE19508169C5 (de) * | 1995-03-08 | 2009-11-12 | Kme Germany Ag & Co. Kg | Kokille zum Stranggießen von Metallen |
JPH09174200A (ja) * | 1995-12-26 | 1997-07-08 | Nippon Steel Corp | 連続鋳造用鋳型 |
JPH11179492A (ja) * | 1997-12-24 | 1999-07-06 | Sumitomo Metal Ind Ltd | 連続鋳造用鋳型 |
JPH11207442A (ja) * | 1998-01-21 | 1999-08-03 | Sumitomo Heavy Ind Ltd | 連続鋳造設備の鋳型およびそれを用いた鋳造方法 |
US20010017199A1 (en) * | 1998-05-26 | 2001-08-30 | Rama Bommaraju | Continuous casting mold and processes for making and retrofitting |
DE19852473C5 (de) * | 1998-11-13 | 2005-10-06 | Sms Demag Ag | Kokillenplatte einer Stranggießanlage |
WO2002016061A1 (fr) * | 2000-08-23 | 2002-02-28 | Sms Demag Aktiengesellschaft | Coquille refroidie pour coulee continue permettant la coulee de metal |
DE10056910A1 (de) * | 2000-11-16 | 2002-05-29 | Sms Demag Ag | Knüppel- und Blockkokille mit partiell geregelter Wärmeabfuhr über Kokillenumfang und Kokillenhöhe |
-
2003
- 2003-03-04 TW TW092104510A patent/TWI268821B/zh not_active IP Right Cessation
- 2003-03-08 BR BR0307901-5A patent/BR0307901A/pt not_active Application Discontinuation
- 2003-03-08 AU AU2003233795A patent/AU2003233795A1/en not_active Abandoned
- 2003-03-08 US US10/509,861 patent/US20050115695A1/en not_active Abandoned
- 2003-03-08 MX MXPA04010647A patent/MXPA04010647A/es not_active Application Discontinuation
- 2003-03-08 EP EP03727263A patent/EP1499462A1/fr not_active Ceased
- 2003-03-08 CN CNB038095203A patent/CN1318164C/zh not_active Expired - Fee Related
- 2003-03-08 CA CA002483784A patent/CA2483784A1/fr not_active Abandoned
- 2003-03-08 PL PL03371553A patent/PL371553A1/xx not_active Application Discontinuation
- 2003-03-08 WO PCT/EP2003/002384 patent/WO2003092931A1/fr active Application Filing
- 2003-03-08 JP JP2004501101A patent/JP2005529750A/ja active Pending
- 2003-03-08 RU RU2004134598/02A patent/RU2310543C2/ru active
Non-Patent Citations (1)
Title |
---|
See references of WO03092931A1 * |
Also Published As
Publication number | Publication date |
---|---|
RU2310543C2 (ru) | 2007-11-20 |
CN1318164C (zh) | 2007-05-30 |
TW200400093A (en) | 2004-01-01 |
RU2004134598A (ru) | 2005-06-10 |
JP2005529750A (ja) | 2005-10-06 |
PL371553A1 (en) | 2005-06-27 |
CA2483784A1 (fr) | 2003-11-13 |
CN1649685A (zh) | 2005-08-03 |
WO2003092931A1 (fr) | 2003-11-13 |
US20050115695A1 (en) | 2005-06-02 |
MXPA04010647A (es) | 2005-02-17 |
BR0307901A (pt) | 2004-12-21 |
TWI268821B (en) | 2006-12-21 |
AU2003233795A1 (en) | 2003-11-17 |
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