EP1490632A1 - Verfahren und vorrichtung zur regelung der primär- und sekundärlufteinspritzung einer müllverbrennungsanlage - Google Patents

Verfahren und vorrichtung zur regelung der primär- und sekundärlufteinspritzung einer müllverbrennungsanlage

Info

Publication number
EP1490632A1
EP1490632A1 EP03717267A EP03717267A EP1490632A1 EP 1490632 A1 EP1490632 A1 EP 1490632A1 EP 03717267 A EP03717267 A EP 03717267A EP 03717267 A EP03717267 A EP 03717267A EP 1490632 A1 EP1490632 A1 EP 1490632A1
Authority
EP
European Patent Office
Prior art keywords
secondary air
flow
air
nozzles
temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP03717267A
Other languages
English (en)
French (fr)
Other versions
EP1490632B1 (de
Inventor
Bart Adams
Renaat De Proft
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Keppel Seghers Holdings Pte Ltd
Original Assignee
Seghers Keppel Technology Group NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Seghers Keppel Technology Group NV filed Critical Seghers Keppel Technology Group NV
Priority to EP06018526A priority Critical patent/EP1726877B1/de
Priority to EP03717267A priority patent/EP1490632B1/de
Publication of EP1490632A1 publication Critical patent/EP1490632A1/de
Application granted granted Critical
Publication of EP1490632B1 publication Critical patent/EP1490632B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/08Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
    • F23G5/14Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion
    • F23G5/16Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion in a separate combustion chamber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/50Control or safety arrangements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L13/00Construction of valves or dampers for controlling air supply or draught
    • F23L13/02Construction of valves or dampers for controlling air supply or draught pivoted about a single axis but having not other movement
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L9/00Passages or apertures for delivering secondary air for completing combustion of fuel 
    • F23L9/02Passages or apertures for delivering secondary air for completing combustion of fuel  by discharging the air above the fire
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23MCASINGS, LININGS, WALLS OR DOORS SPECIALLY ADAPTED FOR COMBUSTION CHAMBERS, e.g. FIREBRIDGES; DEVICES FOR DEFLECTING AIR, FLAMES OR COMBUSTION PRODUCTS IN COMBUSTION CHAMBERS; SAFETY ARRANGEMENTS SPECIALLY ADAPTED FOR COMBUSTION APPARATUS; DETAILS OF COMBUSTION CHAMBERS, NOT OTHERWISE PROVIDED FOR
    • F23M9/00Baffles or deflectors for air or combustion products; Flame shields
    • F23M9/04Baffles or deflectors for air or combustion products; Flame shields with air supply passages in the baffle or shield
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2900/00Special features of, or arrangements for incinerators
    • F23G2900/55Controlling; Monitoring or measuring
    • F23G2900/55003Sensing for exhaust gas properties, e.g. O2 content
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23NREGULATING OR CONTROLLING COMBUSTION
    • F23N2235/00Valves, nozzles or pumps
    • F23N2235/02Air or combustion gas valves or dampers
    • F23N2235/06Air or combustion gas valves or dampers at the air intake
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23NREGULATING OR CONTROLLING COMBUSTION
    • F23N3/00Regulating air supply or draught
    • F23N3/04Regulating air supply or draught by operation of single valves or dampers by temperature sensitive elements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23NREGULATING OR CONTROLLING COMBUSTION
    • F23N5/00Systems for controlling combustion
    • F23N5/02Systems for controlling combustion using devices responsive to thermal changes or to thermal expansion of a medium

Definitions

  • the invention relates to a device for incinerating waste comprising rows of secondary air nozzles divided into segments.
  • the invention relates to a method for controlling several parameters of secondary air injection including at least one of the parameters: flow, speed, turbulence, volume, composition and temperature, for optimizing the incinerating process in an incineration system.
  • the invention relates to a method for controlling primary air injection.
  • the invention also relates to an incineration equipment, functioning in accordance with said methods enabling the control of primary and secondary air injection.
  • the combustion process of waste is a rather complex one because homogeneous and heterogeneous reactions take place, not only on the incineration grate, but also above the grate.
  • the furnace-boiler part comprising a combustion chamber and a post-combustion chamber is a critical part of an incineration installation and needs to be designed with great care.
  • the most important properties for this type of furnace-boiler are good performance, high flexibility, good availability and reliability with an acceptable lifetime of the different pressure parts. Flexibility is of utmost importance, due to the variability of the waste characterized by e.g. its composition and calorific value.
  • the furnace-boiler must be able to perform under these permanent changing conditions and produce steam or heat, in an as stable as possible way.
  • the terms displacement body, bluff body and prisrn body are used interchangeably.
  • one of the main problems of obtaining an efficient combustion is the good mixing of the secondary air.
  • the introduction of secondary air is difficult to fine-tune.
  • the introduction of secondary air is difficult to fine-tune.
  • the introduction of secondary air is often not properly conditioned to take immediately part in the post-combustion process when injected-in the furnace-boiler. Consequently, it will take a longer time for the post- combustion process to reach a complete burnout of the flue gases, and injection of non- conditioned secondary air in the furnace-boiler may even slow down the post-combustion process.
  • Another problem is that the temperature throughout a cross-section of the post- combustion chamber is not constant; pockets of flue gases are sometimes hotter or cooler than the optimum temperature causing undesirable side effects such as corrosion, slagging and fouling.
  • the present invention provides a new device comprising an improvement on the primary air and secondary air injection systems, a method for controlling several parameters of the secondary air, including flow, speed, turbulence, volume, composition and temperature, and a method for controlling primary air injection.
  • a new device comprising an improvement on the primary air and secondary air injection systems, a method for controlling several parameters of the secondary air, including flow, speed, turbulence, volume, composition and temperature, and a method for controlling primary air injection.
  • a primary air supply system capable of differentially distributing air across different grate elements and across the width of the grate
  • each row of secondary air injection nozzles is divided into two or more segments, each segment comprising two or more nozzles, such that the flow of air through any one segment is capable of being different from that of directly adjacent segments.
  • Another embodiment of the present invention is a device as described above wherein each segment and segment opposite thereto form pairs of segments on opposite pairs of rows of secondary air nozzles.
  • Another embodiment of the present invention is a device as described above wherein the air flow to each segment is controlled by one or more valves and/or by modulating one or more air fans and/or according to the selected diameters of the secondary air injection nozzles within said segment.
  • each segment, and segment located opposite thereto contains a larger and smaller diameter of said nozzles
  • the nozzles are aligned in opposing segments such that those of the larger diameter are placed directly opposite nozzles having the smaller diameter.
  • Another embodiment of the present invention is a device as described above further comprising any array of four or more temperature sensors, each sensor located above an area defined by a pair of segments.
  • Another embodiment of the present invention is a device as described above whereby the secondary air is provided via secondary air supply ducts ending in injection nozzles, passing through the front- and rear- wall of said device as well as through the membrane-wall of the displacement body.
  • Another embodiment of the present invention is a device as described above whereby, the secondary air supply duct consists of two or more concentric ducts, inside of the displacement body or along the exterior of the furnace-boiler walls.
  • Another embodiment of the present invention is a device as described above whereby the inner front and rear walls of said device are bent in such shape that, together with the outline of the displacement body, two venturi-shaped flue gas passages with an opening angle ( ⁇ / ⁇ ) between 20° and 40° are created in order to increase the flue gas turbulence in the venturi-shaped mixing zone.
  • Another embodiment of the present invention is a device as described above wherein the displacement body is made in the shape of a distorted rhomboidal prism.
  • Another embodiment of the present invention is a method for incinerating solid materials comprising the use of a device as described above.
  • Another embodiment of the present invention is a method as described above further comprising the steps of a) monitoring the oxygen content of the flue gases, b) determining from step a) the total air flow required by said device, c) distributing air to the primary and secondary air supply systems such that the total air flow is maintained according to step b), d) monitoring the temperature of each temperature sensor, e) averaging the temperature of the temperature sensors located in each flue gas stream, f) comparing the averaged temperatures of step e) to determine the hotter of the two gas streams, g) increasing the flow of secondary air through the secondary air nozzles located below the hotter of the two gas streams, and decreasing the flow of secondary air in the nozzles located below of the cooler of the two gas streams, so maintaining overall the same total of air flow in the secondary air system, and h) not changing the flow of secondary air if both gas streams have the same temperature according to step f), so maintaining overall the same total of air flow in the secondary air system.
  • Another embodiment of the present invention is a method as described above further comprising the steps of: i) decreasing the flow of primary air beneath the grate elements proximal to the feeder system, when the hotter of two gas streams determined in step f) is located proximal to the feeder system, and increasing the flow of primary air in the area beneath the remainder of the grate elements, so maintaining the same total of air flow in the primary air system, j) increasing the flow of primary air beneath the grate elements proximal to the feeder system, when the hotter of two gas streams determined in step f) is located proximal to the output system, and decreasing the flow of primary air in the area beneath the remainder of the grate elements, so maintaining the same total of air flow in the primary air system, k) not changing the flow of primary air if both gas streams have the same temperature according to step f), so maintaining the same total of air flow in the primary air system.
  • Another aspect of the invention relates to a method for the thermal treatment of solid materials in an incinerator comprising a combustion chamber and a post-combustion chamber, said method essentially consisting of: - feeding the solid materials into the combustion chamber, stage combusting of said introduced materials thereby producing flue gases which are directed to said post-combustion chamber, dividing said flue gases into two separated flue gas streams by means of a displacement body present at the entrance of the post-combustion chamber defining two venturi-shaped flue gas passages; characterized by injecting secondary air immediately at the combustion chamber exit and at the entrance of the post-combustion chamber and by controlling said secondary air injection by at least one of the following parameters: flow, turbulence, volume, composition, speed or temperature.
  • Present invention provides a method for controlling several parameters of the primary air and secondary air injection and a device able to perform said method, which will greatly improve the efficiency of the combustion process, which will reduce emissions and will comply with the more severe combustion requirements.
  • Fig. 1 a shows a cross-sectional view of an incineration furnace-boiler or incineration device provided with a displacement body or prism [5] according to the invention.
  • Fig. 1 b represents a partial cross-sectional view of nozzles [30], [31] for the injection of secondary air in the device shown in Figure 1 a.
  • Fig. 2a represents a detailed perspective view of an oscillating flap [20] of Figure 1 b.
  • Fig. 2b to 2d represents schematically three positions in a top view of the flap [20] of Figure 2a.
  • Fig. 3a is a schematic perspective view of a nozzle [30], [31] provided with a rotating valve [20].
  • Fig. 3b is a schematic cross-sectional view of a series of nozzles [30], [31] whereby each nozzle [30], [31] is provided with a separate rotating valve [20].
  • Fig. 3c is a schematic cross-sectional view of a series of nozzle [30], [31] whereby the secondary air supply channel [12], [13], [14] is provided with a rotating valve [20].
  • Fig. 4 shows a fragment of an incinerating system according to above description, and angles formed by the inner walls of the post combustion chamber.
  • Fig. 5 shows a cross-sectional view of two arrays of nozzles both in-line, with alternate and opposite nozzles [42], [43] having a different cross-sectional diameter.
  • Fig. 6 shows a cross-sectional view of a displacement body [5] provided with concentric tubes [47], [48], [49] being supply ducts for guiding the secondary air to the different zones over the width of the incineration system.
  • Fig. 7 shows a three dimensional view of a furnace-boiler comprising an example of one pair of nozzle rows [71] and [72] which have been divided into three sections [73], [74] and [75] in accordance with the invention.
  • Fig. 8 shows a three dimensional view of a furnace-boiler comprising an example of an array of temperature sensors [SA1], [SA2], [SA3], [SB1], [SB2], [SB3], each located above an area defined by the sectioned nozzles [A1], [A2], [A3], [B1], [B2], and [B3].
  • Fig. 9a and 9b demonstrate a method according to the invention for correcting temperature imbalances due to high and low calorific value waste and depending on the heat release profile.
  • Fig. 10 shows a cross-sectional view of an alternative incineration furnace-boiler or incineration device provided with a displacement body or prism [5] according to the invention, having the same features and labels as that of Figure 1 a.
  • Fig 11 shows a three dimensional view of a furnace-boiler comprising an example of an array of temperature sensors [SA1], [SA2], [SA3], [SB1], [SB2], [SB3], and a grate supplied with several primary air injection zones, dependent on the number of grate elements and the with of the furnace-boiler installation [R1 R....R5R], [R1C....R5C], and [R1 L....R5L].
  • One aspect of present invention relates to a combustion device and method, characterized by a specific secondary air injection system in the center of the combustion zone, immediately at the combustion chamber exit and before entering the post-combustion chamber, and controlled by at least one of the following parameters: flow, turbulence, volume, composition, speed, or temperature.
  • the secondary air is supplied into the divided flue gas streams "A" and "B” (see Figure 1a), via a secondary air supply duct [12], [13], [14] to several nozzle inlets [30] and [31] in the furnace-boiler front [6] and rear [7] wall and on both sides of the displacement body [5].
  • the objective of the present invention is to optimize the combustion process in an incineration system and to assure a complete combustion of the flue gases, in order to fulfill the requirements of the EU-directive (2000/076) and increase performance and lifetime of pressure part components of the incineration device.
  • the use of this new, controlled secondary air injection system leads to more effective mixing between the oxygen supplied by the secondary air and the flue gases and will increase combustion performance. Consequently, said device and method results in a much shorter and clearly defined burnout-zone of the flue gases in the post-combustion chamber of the furnace-boiler, a few meters above the displacement body.
  • the listed parameters can be adjusted according to the requirements of the incinerating process.
  • a suitable furnace-boiler geometry can contribute to a more uniform velocity and gas flow distribution and avoid flue gas re- circulation or dead zones throughout the different sections of the furnace-boiler. Therefore, the furnace-boiler has a double venturi-like transition section between combustion and post- combustion chamber, which also promotes the mixing of the partial flue gas flows "A" and "B" with the injected secondary air. Improved mixing of the secondary air and the flue gases increases the efficiency of the combustion process.
  • the method is characterized by the fact that the flow of the secondary air is continuously interrupted, in order to generate an additional pulsation with the secondary airflow when released in the furnace-boiler through the secondary air injection nozzles.
  • the flow of the secondary air is continuously interrupted either in the secondary air supply ducting [12], [13], [14], or in the nozzle [30], [31] or in both (see Figures 1b, 2a, 2b, 2c, 2d, 3a, 3 b, 3c).
  • the device and method are characterized by the fact that the secondary airflow is supplied via nozzles having different cross-sectional diameters and/or by secondary air ducting, permitting different controlled secondary airflow to several zones, spread over the total width of the post-combustion chamber.
  • the diameters of the nozzles conducting the secondary air in the furnace-boiler are alternately of different size ( Figure 5). This results in the injection of alternately different secondary airflow in the post-combustion chamber, initiating additional turbulence in the furnace-boiler.
  • the secondary air is supplied via a combined secondary air supply ducting [12], [13], [14] composed of two or more concentric tubes [47], [48], [49] ( Figure 6).
  • the supply of secondary air via said concentric ducts permits a more accurate control of secondary air to individual zones over the width of the post- combustion chamber.
  • Using concentric tubes fitting in each other allows the supply of different flows of secondary air via only one single supply ducting. Different flows of the secondary air may be required depending on the stage of the combustion process in a specific zone.
  • Another aspect of the present invention relates to a device for waste incineration
  • Figure 1a characterized by the fact that said device supplies secondary air via a secondary air duct [12], [13], [14] ending in several nozzles [30], [31] located immediately at the combustion chamber exit [3] and before entering into the post-combustion chamber [4], with control of the secondary air by at least one of the following parameters: flow, turbulence, volume, composition, speed, or temperature.
  • the device provides secondary air via secondary air ducting [12], [13], [14] to nozzles [30], [31], passing through the front [6] and rear [7] wall of the furnace-boiler and through the front and rear wall of the displacement body (Figure 1a).
  • An important advantage of this design of secondary air injection is the improvement of the flue gas mixing, thanks to the reduction of the necessary penetration depth of the secondary air jet to nearly % of the original furnace-boiler depth. Secondary air injection via a large number of smaller nozzles with lower individual airflow allows a much quicker heating of the secondary air to the required reaction temperature for CO-oxidation (ca. 600°C).
  • the invention relates to said device whereby the secondary air supply ducting is composed of at least two or more concent cal circular ducts. This allows supply of different flows of secondary air via only one single supply ducting. Two or more concentric ducts allow for independently controlled flows of secondary air to individual zones over the width of the post-combustion chamber, e.g. corresponding to the different grate lanes ( Figure 6).
  • the invention relates to said device where unstable flaps [20] are situated inside the secondary air supply duct or injection nozzles or both, able to create a pulsation of the secondary air when injected in the combustion chamber of the incineration device ( Figure 1 b).
  • the frequency of the oscillation can be adjusted by a movable weight on the flaps, changing the position of the gravity center.
  • the length of the flaps can be preferably determined as
  • the invention in another embodiment, relates to said device with pairs of separate secondary air supply ducts ending with nozzles of alternately different diameter.
  • the arrangement is such that the secondary air supply duct with nozzles [12] ( Figure 1 a) located at the furnace-boiler front wall [6] and the secondary air supply duct with nozzles situated in the front wall of the displacement body [14] form one pair.
  • the secondary air supply duct [13] with nozzles located at the furnace-boiler rear wall [7] and the secondary air supply duct with nozzles situated in the rear wall of the displacement body [14] form another pair.
  • the device is characterized by the fact that two opposite nozzles have a different outlet diameter (Figure 5). This means that two opposite, but in-line nozzles have respectively a large [43] and a small [42] inside diameter.
  • the invention-related device includes a displacement body [5] with a profile of a distorted rhombus as in Figures 4 and 6.
  • FIG. 1 a An example of a device and method of how several parameters for secondary air injection are controlled according to the invention is illustrated in Figure 1 a.
  • the system supplies secondary air in the passages "A” and “B” by means of nozzles [30], [31] as shown in Figure 1 b.
  • the secondary air is optimally injected directly into the flow of waste gases, at the combustion chamber exit and at the entrance of the post-combustion chamber.
  • the secondary air is injected into the divided flue gas streams "A” and "B”, via a secondary air supply duct [12], [13], [14] leading to several nozzles [30], [31] located in the furnace-boiler front and rear wall and on both sides of the displacement body [5].
  • furnace-boiler front [6] and rear [7] membrane wall and the membrane wall [19] of the displacement body [5] are provided with refractory materials through which a series of nozzles [30], [31] pass.
  • the total oxygen introduced into furnace-boiler as disclosed herein as primary and secondary air is determined by the oxygen content of the flue gases.
  • the oxygen so introduced is distributed between the primary and secondary inlet systems according to methods of the art.
  • the distribution primary and secondary air is attenuated by monitoring the temperatures in gas flow sections A and B as described below.
  • a flue gas temperature measurement is installed into a furnace-boiler as described herein, a few meters above the outlet of the two flue gas streams "A" and "B,” to measure the actual temperature for each flow section.
  • the purpose of this temperature measurement is to maintain, during the combustion process, nearly the same flue gas temperature (ca.
  • the temperature measurement is linked to the capability of the secondary air injection system to respond to modified furnace conditions such as a shift in the heat-release profile on the grate. For instance, when high calorific waste suddenly enters the furnace, combustion of the waste will start on the first element of the grate and the flue gas temperature in section A will rise above the temperature setpoint, so shifting the heat release profile towards the feeding hopper.
  • the setpoint may be any temperature defined by the user.
  • the set point temperature may be a value in the range of 900 to 1100 °C, 950 to 1050 °C, 920 to 1020 ° C, 970 to 1070 ° C, 980 to 1080 ° C, 970 to 1030 "C, 980 to 1020 ° C or 990 to 1010 ° C,
  • the system recognizes the over-temperature and the temperature imbalance and reacts accordingly as described above. A similar process, but in the opposite direction will occur when low calorific waste is introduced and combustion on the grate is delayed. This is exemplified in Figure 9a, wherein a temperature sensor [91], [92] is placed in each of the flue gas streams above the displacement body [5].
  • the detection of the temperature in the gas flow sections A and B is used as a pre-indication of the type of waste entering the furnace, and may be connected to the process control of the grate speed and primary air distribution along the different grate elements.
  • the process control of the grate speed and primary air distribution along the different grate elements For instance, as in Figure 9a, when high calorific waste [93] enters a furnace as disclosed herein, combustion of the waste will start on the first element of the grate and the heat release profile of the grate will be shifted towards the waste input (hopper) end [99] of the grate. The consequence is that waste will be incinerated towards the waste input end of the grate [99].
  • the shift of heat release profile is detected by the flue gas temperature sensor in section A [91], which would rise above the temperature setpoint.
  • the setpoint may be any temperature defined as described above.
  • the system detects the over-temperature and recognizes the temperature imbalance between section A and section B, and reacts by decreasing the supply of primary air beneath or proximal to the high calorific waste [R1 to R2] so as to shift the heat-release profile back towards to the region of the post-combustion chamber.
  • the primary airflow in the remaining positions of the grate [R3 to R5] is increased in order to keep the total primary airflow constant.
  • a similar process, but in the opposite direction will occur when low calorific waste is introduced, and combustion on the grate is delayed, so shifting the heat release profile in the direction of the waste output [901] ( Figure 9b).
  • each row of secondary air nozzles is divided into two or more segments, each segment comprising two or more nozzles, such that the flow of air through any one segment can be the same or different from that of directly adjacent segments.
  • An air flow in one segment may be controlled by one or more valves, by modulating one or more air fans, by controlling the nozzle diameters within a certain range, or a combination of these.
  • the diameters of the nozzles belonging to a segment are the same or are alternately of different sizes such as that shown in Figure 5. It is within the scope of the invention that the diameters of the nozzles belonging to a segment are placed opposite to nozzles of the same diameter on the corresponding opposing wall. It is further within the scope of the invention that the diameters of the nozzles belonging to a segment are placed opposite to nozzles of a different diameter on the corresponding opposing wall. When placed opposite nozzles of a different diameter, it is within the scope of the invention that the nozzles of small diameter nozzles are placed opposite to nozzles having a larger diameters.
  • Figure 7 shows one pair of rows of secondary nozzles
  • an array of temperature sensors is installed a few meters above the outlet of the two gas flow sections "A" and “B” to measure the actual temperature for each flow section.
  • the number of temperature sensors installed is equal to the number of segments that each pair of rows of nozzles is divided into.
  • FIG. 8 shows an example of a furnace-boiler according to the present invention having an array of temperature sensors [81] placed above the displacement body [5].
  • the segment injection areas as described above are labeled [A1], [A2] and [A3], defined by the nozzle segments [73], [74], [75].
  • Temperature sensors [SA1], [SA2] and [SA3] are placed above and in the vicinity of the respective segment injection areas [A1], [A2] and [A3].
  • a similar arrangement of temperature sensors [SB1], [SB2] and [SB3] is placed above and in the vicinity of the segment injection areas of the other passage ("B"), said segment injection areas labeled by [B1], [B2] and [B3].
  • the "vicinity" of the segment injection areas may be determined by extrapolating the positions and sizes of the segment injection areas at the narrowed entrance of the post-combustion chamber to the cross-section of the post-combustion chamber. This extrapolation is performed using methods of the art.
  • a precise control of the temperature of the air in the post-combustion chamber is important for minimizing the effects of corrosion, slagging and fouling.
  • the inventors have found that differences in temperature exists within each section of the post-combustion chamber, e.g. the temperature across section A might be found to be hotter in the middle compared with the edges.
  • the inventors have found that the differences can be partially or completely modulated by changing the rate of injection (flow) of secondary air in the region below the local temperature difference, so leading to a reduction in corrosion, slagging and fouling in the post-combustion chamber and in the boiler.
  • each pair of rows of nozzles is divided into one or more segments as described above, and each temperature sensor of the array is placed above and in the vicinity of each segment injection area; in this arrangement, the temperature detected by each sensor determines the rate at which air is injected by the corresponding segments of nozzles.
  • the air flow from nozzles [74] in an indicated segment injection area [A2] is determined by the reading of sensor [SA2]; the air flow from nozzles [73] in an indicated segment injection area [A1] is determined by the reading of sensor [SA1]; the air flow from nozzles [75] in an indicated segment injection area [A3] is determined by the reading of sensor [SA3].
  • the furnace comprises a two dimensional matrix of primary air input zones, along the grate and across the width of the grate.
  • the temperature change detected by the array of temperature sensors in the post-combustion chamber influences the primary air flow across the width of the grate.
  • a temperature sensor that indicates an increase in temperature causes a reduction in flow in one or more the primary air input zones located below the position of said sensor. For example, should sensor [SA1] detect an increase in temperature, the corresponding primary air entrance zone located below [SA1] would respond by reducing the flow of air [R1 L] and/or [R2L] and/or [R3L]. The air flow in the remaining primary air entrance zones is increased so as to maintain the correct total air supply.
  • the device and method as disclosed herein also reduces the corrosion potential, by minimizing the CO-concentration (reducing atmosphere) in the flue gas flow in presence of HCI, CI and Cl-combination.
  • a considerable reduction of dust carry-over from a furnace according to the invention into the combustion and post-combustion chamber of the incineration device is obtained using this method and device, because overall less primary air is required under the grate.
  • An additional advantage of the system is that the combustion process is fully completed 2-3 m above the displacement body and no flame breakouts occur in the upper section of the post-combustion chamber.
  • the refractory lining extent in the first pass can be reduced to the strict minimum, just enough to comply with the two seconds/850°C rule. Furthermore, as the burnout is fully completed a few meters above the displacement body, there is no further need to protect the membrane walls of the post-combustion chamber and first pass above this level.
  • the supply of secondary air is continuously disturbed with the purpose of creating a pulsation of the secondary air before entering the furnace-boiler.
  • this pulsation can be produced by means of unstable flap [20], placed in the secondary air supply ducts [12], [13], [14] as shown in Figure 1b.
  • a main secondary air duct [16] feeds said secondary air supply ducts [12], [13], [14].
  • the permanent movement of the flap 20 will create a pulsating secondary air flow in the area of both restrictions of section "A" and "B".
  • Figures 2a, 2b, 2c and 2d explain in detail the action of the constant moving flap 20 in a hinged configuration.
  • FIG 2a shows a self-moving oscillating flap [20] without external drive.
  • the oscillation amplitude of these self-moving flaps is depending upon the length, the shape and the weight of the flaps.
  • an oscillating impulse strength can be realized in a single nozzle as explained in Figure 3a, with an external driven (such as an electric motor M) rotating circular valve [20].
  • Externally driven valves [20] can be located within the individual nozzles [30], [31], as shown in Figure 3b, or within the common secondary air supply ducts [12], [13], [14] as shown in Figure 3c.
  • valves [20] respectively in the secondary air supply ducts [12], [13], [14] as shown on Figure 3c, or in each individual nozzle [30], [31], as shown in Figure 3b, has a different influence on the oscillation impulse of the nozzles.
  • the means to pulsate air as described above may be installed in any furnace-boiler according to the present invention.
  • Figure 1a shows the cross section of the furnace-boiler, combustion and post- combustion chamber of a typical incinerator arrangement, particularly designed for incineration of solid waste or biomass, consisting of a furnace [2] with an incineration grate [25], receiving the solid materials through a feeding hopper with pusher [1].
  • the produced flue gases are conducted in a combustion chamber [3] and a post-combustion chamber [4].
  • Hoppers [22] underneath the grate [25] are placed for collection of the sittings of the grate and serving at the same time as primary air supply channels.
  • the primary air is supplied via several air ducts [23].
  • the ashes fall via a shaft [21] into an ash extractor (not shown).
  • the produced flue gases, not yet completely burned out, are divided in two streams by a displacement body [5], installed at the entrance of the post-combustion chamber [4].
  • a displacement body [5] installed at the entrance of the post-combustion chamber [4].
  • the flue gases passage is divided in two flow channels "A" and "B”.
  • Secondary air is injected through four rows of nozzles located at the entrance of the post-combustion chamber [4] where the displacement body [5] is located.
  • the secondary air is conducted via nozzles [30] in the front [6] and rear wall [7] of the furnace- boiler as well as via nozzles [31] of the displacement body [5].
  • the flue gases are mixed with secondary air, resulting in an almost complete burnout of the flue gases a few meters above the displacement body [5] and also resulting in shorter flames and more uniform oxygen concentrations.
  • the secondary air is supplied by a secondary air fan [9] via secondary air ducts [11], provided with secondary air regulating valves [15], to the secondary air supply ducts [12], [13], [14] into the injection nozzles [30], [31].
  • Figures 5, 6, 7, 8 , 11 and 12 disclose two secondary air supply ducts, aligned in parallel, and nozzles [42], [43] with alternate different diameter. Two opposite nozzles have respectively a large [43] and a small diameter [42] in order to improve the mixing of the injected secondary air with the flue gases.
  • Figure 6 illustrates the use of different concentric ducts [47], [48], [49], to supply secondary air to duct [14]. Due to the fact that three concentric tubes [47], [48], [49] are provided, three different flows of secondary air can be independently controlled and injected over the total width of the furnace-boiler.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Incineration Of Waste (AREA)
  • Exhaust Gas After Treatment (AREA)
EP03717267A 2002-04-03 2003-04-03 Verfahren und vorrichtung zur regelung der primär- und sekundärlufteinspritzung einer müllverbrennungsanlage Expired - Lifetime EP1490632B1 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP06018526A EP1726877B1 (de) 2002-04-03 2003-04-03 Verfahren und vorrichtung zur regelung der primär- und sekundärlufteinspritzung einer müllverbrennungsanlage
EP03717267A EP1490632B1 (de) 2002-04-03 2003-04-03 Verfahren und vorrichtung zur regelung der primär- und sekundärlufteinspritzung einer müllverbrennungsanlage

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
EP02447055 2002-04-03
EP02447055 2002-04-03
US37199202P 2002-04-11 2002-04-11
US371992P 2002-04-11
EP03717267A EP1490632B1 (de) 2002-04-03 2003-04-03 Verfahren und vorrichtung zur regelung der primär- und sekundärlufteinspritzung einer müllverbrennungsanlage
PCT/EP2003/003495 WO2003083370A1 (en) 2002-04-03 2003-04-03 Method and device for controlling injection of primary and secondary air in an incineration system

Related Child Applications (1)

Application Number Title Priority Date Filing Date
EP06018526A Division EP1726877B1 (de) 2002-04-03 2003-04-03 Verfahren und vorrichtung zur regelung der primär- und sekundärlufteinspritzung einer müllverbrennungsanlage

Publications (2)

Publication Number Publication Date
EP1490632A1 true EP1490632A1 (de) 2004-12-29
EP1490632B1 EP1490632B1 (de) 2006-10-25

Family

ID=28676409

Family Applications (2)

Application Number Title Priority Date Filing Date
EP03717267A Expired - Lifetime EP1490632B1 (de) 2002-04-03 2003-04-03 Verfahren und vorrichtung zur regelung der primär- und sekundärlufteinspritzung einer müllverbrennungsanlage
EP06018526A Expired - Lifetime EP1726877B1 (de) 2002-04-03 2003-04-03 Verfahren und vorrichtung zur regelung der primär- und sekundärlufteinspritzung einer müllverbrennungsanlage

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP06018526A Expired - Lifetime EP1726877B1 (de) 2002-04-03 2003-04-03 Verfahren und vorrichtung zur regelung der primär- und sekundärlufteinspritzung einer müllverbrennungsanlage

Country Status (7)

Country Link
EP (2) EP1490632B1 (de)
CN (1) CN100402925C (de)
AT (2) ATE343766T1 (de)
AU (1) AU2003221547A1 (de)
DE (2) DE60309301T2 (de)
ES (1) ES2275086T3 (de)
WO (1) WO2003083370A1 (de)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005009957B4 (de) * 2005-03-04 2007-02-01 Martin GmbH für Umwelt- und Energietechnik Verfahren zum Verbrennen von Brennstoffen, insbesondere Abfall
DE102006031900A1 (de) * 2006-07-07 2008-01-10 Rwe Power Ag Verfahren zur Regelung der Verbrennungsluftzufuhr an einem mit fossilen Brennstoffen befeuerten Dampferzeuger
DE102011002205A1 (de) * 2011-04-20 2012-10-25 Alstom Technology Ltd. Abhitze-Dampferzeuger sowie ein Verfahren zum Betreiben eines Abhitze-Dampferzeugers
CN103032885B (zh) * 2012-12-20 2016-08-03 北京中煤神州节能环保技术开发有限公司 波形分离旋转飞灰燃烬装置
FI126836B (fi) * 2013-09-18 2017-06-15 Outotec Finland Oy Menetelmä ja järjestely pyrometallurgisesta uunista jätelämpökattilaan virtaavan prosessikaasun käsittelemiseksi
CN204153784U (zh) * 2014-04-03 2015-02-11 山东威澳环保科技有限公司 一种炉内强化燃烧装置
DE102015117718A1 (de) * 2015-10-19 2017-04-20 Karlsruher Institut für Technologie Feuerungssystem und Verfahren zu dessen Betrieb
CN105536372B (zh) * 2016-01-08 2017-07-11 江苏新中环保股份有限公司 烟气自动均衡分配装置
DE102017008123A1 (de) * 2017-08-30 2019-02-28 Martin GmbH für Umwelt- und Energietechnik Feuerungsanlage und Verfahren zum Betreiben einer Feuerungsanlage
JP7131900B2 (ja) * 2017-11-14 2022-09-06 クボタ環境エンジニアリング株式会社 焼却炉及び焼却炉の排ガス処理方法
FR3104683B1 (fr) * 2019-12-13 2022-07-29 Cnim Groupe Procédé de régulation d’une installation de combustion, ainsi qu’installation de combustion correspondante
EP3896337A1 (de) * 2020-04-16 2021-10-20 General Electric Company Verbrennungssystem für einen kessel mit brennstoffstromverteilungsmitteln in einem brenner und verfahren zur verbrennung

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3038875C2 (de) * 1980-10-15 1990-05-31 Vereinigte Kesselwerke AG, 4000 Düsseldorf Müllverbrennungsanlage
CH673149A5 (de) * 1987-10-23 1990-02-15 Kuepat Ag
CA1308964C (en) * 1988-04-15 1992-10-20 Brian Robin Blackwell Method and apparatus for improving fluid flow and gas mixing in boilers
SE9102546L (sv) * 1991-09-05 1992-09-07 Goetaverken Energy Ab Foerbraenning av avfallsvaetskor
DE4220149C2 (de) * 1992-06-19 2002-06-13 Steinmueller Gmbh L & C Verfahren zum Regelung der Verbrennung von Müll auf einem Rost einer Feuerungsanlage und Vorrichtung zur Durchführung des Verfahrens
SG47890A1 (en) * 1993-04-20 1998-04-17 Martin Umwelt & Energietech Method for burning fuels particularly for incinerating garbage
DE4401821C2 (de) 1994-01-22 1998-01-15 Joachim Dipl Ing Kuemmel Verfahren zum Verbrennen von Stoffen, insbesondere von Müll und Biomassen, und Vorrichtung zur Durchführung des Verfahrens
DE19705938A1 (de) * 1997-02-17 1998-08-20 Abb Research Ltd Verfahren zum Eindüsen von Sekundärluft und/oder Tertiärluft sowie von rezirkulierenden Rauchgasen in einem Kessel sowie Vorrichtung zur Durchführung des Verfahrens
CH694305A5 (de) * 1999-08-30 2004-11-15 Von Roll Umwelttechnik Ag Vorrichtung zur Erzeugung einer rotierenden Stroemung.
US6279495B1 (en) * 1999-10-22 2001-08-28 Pulp And Paper Research Institute Of Canada Method and apparatus for optimizing the combustion air system in a recovery boiler
DE10012895A1 (de) * 2000-03-16 2001-09-20 Krc Umwelttechnik Gmbh Verbrennungsverfahren für Brennstoffe beliebiger Art mittels einer Rostfeuerung

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO03083370A1 *

Also Published As

Publication number Publication date
DE60322986D1 (de) 2008-09-25
EP1490632B1 (de) 2006-10-25
EP1726877A1 (de) 2006-11-29
EP1726877B1 (de) 2008-08-13
WO2003083370A1 (en) 2003-10-09
CN1646859A (zh) 2005-07-27
ATE343766T1 (de) 2006-11-15
ATE404820T1 (de) 2008-08-15
ES2275086T3 (es) 2007-06-01
DE60309301D1 (de) 2006-12-07
CN100402925C (zh) 2008-07-16
AU2003221547A1 (en) 2003-10-13
DE60309301T2 (de) 2007-06-06

Similar Documents

Publication Publication Date Title
US6843185B1 (en) Burner with oxygen and fuel mixing apparatus
CA1267601A (en) Fluid fuel fired burner
KR100821124B1 (ko) 열회수용 연소장치
US4838183A (en) Apparatus and method for incinerating heterogeneous materials
CN101371077A (zh) 燃烧煤粉的锅炉和煤粉燃烧方法
EP1726877A1 (de) Verfahren und vorrichtung zur regelung der primär- und sekundärlufteinspritzung einer müllverbrennungsanlage
US4566393A (en) Wood-waste burner system
CN105276574A (zh) 带有内部烟道气再循环的炉***
SE0001606L (sv) Anordning för förbränning av granulärt fast bränsle
EP2588809B1 (de) Verfahren und vorrichtung zur emissionsarmen verbrennung von abgas mit niedrigem heizwert
KR20030019364A (ko) 폐기물 소각로 및 그 조업방법
US6733278B1 (en) Variable heat output burner assembly
CN214840828U (zh) 一种烟道动态配风协同sncr脱硝的控制***
GB1585410A (en) Burner
JP6551927B2 (ja) 燃焼炉の燃えカス、及び灰の処理とクリンカ対策方法
WO2020189394A1 (ja) 焼却炉
JP3223994B2 (ja) 焼却炉およびその火炎制御方法
CN115516249A (zh) 在燃烧器中带有燃料流分配装置的锅炉的燃烧***以及燃烧的方法
JPH1061929A (ja) 燃焼装置に於ける二次燃焼用空気の供給制御方法
JP2007232328A (ja) 二段燃焼用空気ポートとその運用方法及びボイラ
FI100355B (fi) Menetelmä ja laitteisto kaasun polttamiseksi tulipesässä
JP2019174059A (ja) 廃棄物焼却炉
US4132179A (en) Burning apparatus
US4210995A (en) Method of constructing a burner
RU2373457C2 (ru) Топка парогенератора

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20041021

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL LT LV MK

17Q First examination report despatched

Effective date: 20050405

REG Reference to a national code

Ref country code: HK

Ref legal event code: DE

Ref document number: 1076857

Country of ref document: HK

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: KEPPEL SEGHERS HOLDINGS PTE LTD

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RIC1 Information provided on ipc code assigned before grant

Ipc: F23L 9/04 20060101ALI20060523BHEP

Ipc: F23G 5/16 20060101ALI20060523BHEP

Ipc: F23L 13/02 20060101ALI20060523BHEP

Ipc: F23M 9/04 20060101ALI20060523BHEP

Ipc: F23G 5/50 20060101AFI20060523BHEP

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20061025

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20061025

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20061025

Ref country code: LI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20061025

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20061025

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20061025

Ref country code: CH

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20061025

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20061025

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 60309301

Country of ref document: DE

Date of ref document: 20061207

Kind code of ref document: P

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070125

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070125

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070125

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070326

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2275086

Country of ref document: ES

Kind code of ref document: T3

EN Fr: translation not filed
PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20070726

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070608

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070126

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20061025

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20061025

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070430

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070403

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20061025

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070426

REG Reference to a national code

Ref country code: HK

Ref legal event code: WD

Ref document number: 1076857

Country of ref document: HK

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IE

Payment date: 20140428

Year of fee payment: 12

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FI

Payment date: 20140411

Year of fee payment: 12

Ref country code: NL

Payment date: 20140418

Year of fee payment: 12

Ref country code: DE

Payment date: 20140418

Year of fee payment: 12

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 60309301

Country of ref document: DE

REG Reference to a national code

Ref country code: NL

Ref legal event code: MM

Effective date: 20150501

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150403

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151103

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150501

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150403

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: TR

Payment date: 20220331

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20220420

Year of fee payment: 20

Ref country code: GB

Payment date: 20220420

Year of fee payment: 20

Ref country code: ES

Payment date: 20220629

Year of fee payment: 20

REG Reference to a national code

Ref country code: GB

Ref legal event code: PE20

Expiry date: 20230402

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20230504

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20230402

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20230404