EP1462719A1 - Foyer et installation de traitement de déchets spéciaux comportant un tel foyer - Google Patents

Foyer et installation de traitement de déchets spéciaux comportant un tel foyer Download PDF

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Publication number
EP1462719A1
EP1462719A1 EP03425192A EP03425192A EP1462719A1 EP 1462719 A1 EP1462719 A1 EP 1462719A1 EP 03425192 A EP03425192 A EP 03425192A EP 03425192 A EP03425192 A EP 03425192A EP 1462719 A1 EP1462719 A1 EP 1462719A1
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EP
European Patent Office
Prior art keywords
furnace
chamber
treated
combustion air
furnace according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP03425192A
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German (de)
English (en)
Inventor
Antonino Guglielmino
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
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Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to EP03425192A priority Critical patent/EP1462719A1/fr
Publication of EP1462719A1 publication Critical patent/EP1462719A1/fr
Withdrawn legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/006General arrangement of incineration plant, e.g. flow sheets
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/08Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
    • F23G5/14Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion
    • F23G5/16Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion in a separate combustion chamber
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/32Incineration of waste; Incinerator constructions; Details, accessories or control therefor the waste being subjected to a whirling movement, e.g. cyclonic incinerators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/44Details; Accessories
    • F23G5/46Recuperation of heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/001Incinerators or other apparatus for consuming industrial waste, e.g. chemicals for sludges or waste products from water treatment installations
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/006Layout of treatment plant
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00Pretreatment
    • F23G2201/70Blending
    • F23G2201/701Blending with additives
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2900/00Special features of, or arrangements for incinerators
    • F23G2900/50008Combustion of waste suspended or lifted by upward gas flows

Definitions

  • the present invention relates to a furnace for the heat treatment of special waste, for example the sludge produced by waste-water purification plants.
  • the present invention also relates to a plant comprising said furnace, in particular a plant for treatment of the sludge produced by waste-water purification plants.
  • the problem forming the basis of the present invention is that of devising a heat treatment furnace and a sludge processing plant containing said furnace, which have structural and functional characteristics such as to satisfy the abovementioned requirements and overcome at the same time the drawbacks mentioned with reference to the known art.
  • Figure 1 shows a diagram of the sludge processing plant comprising a heat treatment furnace
  • Figure 2 shows a longitudinal schematic view of the heat treatment furnace according to Figure 1;
  • Figure 3 shows a cross-sectional diagram of the furnace according to Figure 1;
  • Figure 4 shows a longitudinal schematic view of means for extraction of inert matter and blowing means of the furnace according to Figure 1.
  • 1 denotes in its entirety a plant for the treatment of sludge and special waste F resulting from recycled waste water, in particular resulting from the biological treatment of waste water.
  • Said treatment plant 1 comprises a storage zone in which said sludge F is stored, preferably in a closed warehouse which is kept under vacuum conditions by means of fans which draw out air contained therein.
  • the sludge F is conveyed away from said storage zone, preferably by means of a feeding bin, to a kneading machine 2.
  • Said kneading machine 2 is also fed with fume dust Pf obtained from fumes E produced during the heat treatment owing to the separation performed by sleeve filters 4.
  • a reaction agent R is also fed to said kneading machine 2.
  • said reaction agent R is calcium carbonate in powder form.
  • the sludge F is kneaded together with the reaction agent R and with the fume dust Pf, producing kneaded sludge Fi.
  • the kneaded sludge Fi forms a mass which is less cohesive than the initial sludge, i.e. is less sticky than the sludge F and basically suitable for subsequent handling.
  • the kneaded sludge Fi is conveyed away to a dehydrator 6 which is suitable for dehydrating said kneaded sludge.
  • said dehydrator 6 is a rotating-drum dehydrator in which the water contained in the kneaded sludge Fi evaporates owing to action of heating of said sludge by the fumes E produced inside the furnace.
  • Dehydrated sludge Fd emerges from said dehydrator 6 and is preferably conveyed away to means suitable for separating any foreign bodies from said dehydrated sludge.
  • said separation means comprise a sieve or rotating drum 8.
  • the dehydrated sludge Fd is conveyed to an atomisation system 10.
  • said atomisation system 10 is a compressed-air atomisation system comprising at least one diffuser 12 able to introduce atomised sludge Fn into a furnace 14.
  • Treatment of the atomised sludge Fn is performed inside the furnace 14, resulting in the formation of inert matter I discharged from the furnace.
  • the details of treatment of said atomised sludge will be illustrated in detail in the remainder of the description.
  • the furnace 14 comprises a chamber 16 which preferably extends substantially along a horizontal axis X-X, between at least one supply inlet 18 from where said atomised sludge Fn is introduced into the chamber 16 and a discharge opening 19 for the fumes E produced during the heat treatment.
  • the atomisation means introduce the atomised sludge Fn into the furnace 14 in the region of said supply inlet 18 of the chamber 16.
  • the chamber 16 of the furnace 14 also comprises an extraction zone 20 from where said inert matter I resulting from treatment of the atomised sludge Fn is extracted and conveyed outside of the furnace 14.
  • the furnace 14 also comprises extraction means able to extract said inert matter I from the furnace 14 and convey it outside of the furnace.
  • said extraction means comprise at least one feeder screw 22 arranged at a lower height than the supply inlet 18 for the atomised sludge Fn.
  • said extraction means comprise a plurality of feeder screws 22, 22a, 22b arranged in succession along said horizontal axis X-X of the furnace chamber 16.
  • a following feeder screw is arranged at a lower height than the preceding feeder screw, extending from the supply inlet 18 for the atomised sludge Fn to the discharge opening 19 for the fumes E.
  • the first feeder screw 22 is arranged higher than the second feeder screw 22a and said second feeder screw 22a is arranged higher than the third feeder screw 22b, resulting in a stepped configuration.
  • the furnace 14 also comprises burner means suitable for performing the combustion of a fuel in order to provide a predetermined process temperature inside said chamber 16 of the furnace 14.
  • said burner means comprise burners arranged in pairs, for example a first burner 24a, a second burner 24b and a third burner 24c.
  • said fuel is methane.
  • said fuel is waste-derived fuel (CDR) or organic dust resulting from the demolition of cars (fluff) or carbon coke.
  • said furnace 14 comprises conveying means able to convey the atomised sludge Fn along a path between said supply inlet 18 and said discharge opening 19 for the fumes.
  • said path is substantially horizontal, along said horizontal axis X-X of said chamber 16.
  • said path is substantially helical. In a further variation of embodiment, said path is undulating or, alternatively, labyrinth-like.
  • said path extends from the inlet to the discharge opening along a path which may be a combination of one or more of the abovementioned paths, for example helical or also undulating.
  • the conveying means comprise means which generate a flow of combustion air Ac suitable for drawing the atomised sludge Fn along said path.
  • said conveying means comprise means for sucking combustion air Ac from an air inlet 26 arranged in the vicinity of the supply inlet 18 for the atomised sludge Fn, from where said combustion air enters into the chamber 16, towards the discharge opening 19 for the fumes E.
  • Said suction means are suitable for conveying, by means of the air flow, the atomised sludge along said longitudinal axis X-X of the chamber 16 for carrying out the heat treatment.
  • Said conveying means also comprise blowing means suitable for performing swirled and turbulent conveying of said atomised sludge Fn along said longitudinal axis X-X of the chamber 16.
  • Said blowing means comprise at least one blowing plate.
  • said blowing means comprise a first right-hand plate 28a and a first left-hand plate 30a.
  • Said plates 28a, 30a extend along the path of the chamber, namely along the horizontal axis X-X of the chamber 16, each on one side of the chamber 16, that is so as to be facing each other along said horizontal axis X-X.
  • said blowing means comprise a second right-hand plate 28b and a second left-hand plate 30b.
  • Said plates 28b, 30b extend along the horizontal axis X-X of the chamber 16, each on one side of the chamber 16, i.e. so as to be facing each other along said horizontal axis X-X, at a height closer to that of the feeder screws than to the height of the first right-hand plate 28a and the first left-hand plate 30a.
  • Said plates 28a, 28b, 30a, 30b have a respective main surface 32 which extends along the path of the chamber 16, namely along the horizontal axis X-X, and which is directed towards the inside of the chamber 16, namely towards the middle of the latter.
  • Said main surface 32 is inclined with respect to the horizontal reference surface Z-Z.
  • first left-hand plate and said first right-hand plate have respective main surfaces lying in planes which, intersecting each other, form an acute angle, preferably equal to 60°.
  • said second left-hand plate and said second right-hand plate have respective main surfaces lying in planes which, intersecting each other, form an acute angle, preferably equal to 60°.
  • Said main surfaces have at least one blowing opening, from where further combustion air is blown towards the middle of the chamber.
  • said main surfaces have at least one plurality of blowing holes 33.
  • the combustion air blown through said blowing holes of the plates is heated beforehand, preferably using the heat of the feeder screws and blowing said air by means of fans 34a, 34b.
  • Said perforated plates 28a, 28b, 30a, 30b of the furnace 14 define, together with the side walls 35a, 35b of the chamber 16, a central region 36 of the chamber 16 which, transversely, has a substantially trapezoidal cross-section.
  • said main surfaces 32 of the perforated plates and the internal surfaces of the side walls 35a, 35b of the furnace chamber 16 have a relative inclination such as to define said substantially trapezoidal central region 36.
  • said furnace 14 comprises separating means for the chamber 16 able to define combustion zones inside said chamber 16.
  • said separating means comprise a first wall 38, arranged substantially perpendicular to said horizontal axis X-X of the chamber 16.
  • the wall 38 is suitable for defining inside said chamber 16 a preliminary combustion zone 40a and a post-combustion zone 40b.
  • the first burner 24a is arranged in the preliminary combustion zone 40a, in the vicinity of the supply inlet 18 of the chamber 16, and the second burner 24b is arranged in the preliminary combustion zone 40a, situated substantially in the middle of said zone and at height higher than that of the first burner 24a.
  • the third burner 24c is preferably arranged at a free end 38a of the wall 38.
  • the free end 38a of the wall 38 and the third feeder screw 22b define a forced through-opening 42 for the atomised sludge being treated, opposite which the third burner 24c is arranged.
  • Said separator means also comprise a second wall 44 arranged closer to the discharge opening 19 for the fumes E than the first wall 38, in the direction of the horizontal axis X-X.
  • the second wall 44 is able to define, between said post-combustion zone 40b and said discharge opening 19 for the fumes E, an exchange zone 40c for the heat of the fumes.
  • the second wall 44 forms, together with an upper wall 46 of the chamber 16 of the furnace, a through-opening 48 for the fumes between said post-combustion zone 40b and said exchange zone 40c for the heat of the fumes.
  • the furnace 14 also comprises a heat exchanger 50 arranged in said heat exchange zone 40c and able to extract the heat from the fumes E and transfer it to a working fluid so as to convert said fluid into a condition for supplying, for example, a plant for the production of energy.
  • said heat exchanger is able to generate steam for supplying a turbine of a plant 60 for the production of electrical energy.
  • said plant for the production of energy uses a cycle of the Rankine type.
  • the fumes E after passing through the heat exchanger 50, emerge from the discharge opening 19 for the fumes and then enter into the dehydrator; after passing through said sleeve filters 4 for separation of the fume dust Pf, they then pass into a plant 70 for treating the fumes.
  • Said plant 70 for treating the fumes comprises, in a preferred embodiment, a spray column for cooling and basic washing of the fumes.
  • said plant 70 comprises columns with polypropylene filled bodies for washing with water and automatic control of the acidity by means of the introduction of soda, a washing tank for adding oxygenated water for sterilisation, and an expansion chamber for condensation of the water present in the fumes and separation of the water droplets by means of gravity.
  • said plant 70 comprises final absorbers for final purification of the fumes by means of adsorption.
  • said fumes Prior to emission of the fumes into the atmosphere, for example from a chimney, said fumes are monitored, for example by controlling the level of the nitrogen oxides (NOx), the carbon monoxide (CO), water vapour (H2O), acids (HCl and HF), sulphur dioxide (SO2), total organic components (COT), dust levels and throughput.
  • NOx nitrogen oxides
  • CO carbon monoxide
  • H2O water vapour
  • acids HCl and HF
  • SO2 sulphur dioxide
  • COT total organic components
  • An automatic system which is operated by a computer, interrupts the supply of sludge during the production cycle should the emission values of any one of the environmental parameters exceed the values stipulated by the regulations governing protection of the environment.
  • the atomised sludge Fn is introduced into the chamber 16 of the furnace 14 via the supply inlet 18.
  • the suction and blowing means produce currents of combustion air Ac which convey said atomised sludge Fn along the chamber 16 in the direction of the horizontal axis X-X.
  • Said air current travels from the air suction inlet, close to the supply inlet for the atomised sludge, to the fume discharge opening 19.
  • the suction means assist said air current by substantially imparting an axial movement, in the direction of the horizontal axis X-X, to the air current.
  • the blowing means assist said air current by substantially imparting a transverse movement due to the combustion air blown through the plates.
  • the atomised sludge Fn is transported by the resultant air current from the supply inlet to the fume discharge opening.
  • Said atomised sludge has, owing to the combined action of said suction and blowing means, a vortical, i.e. substantially helical, motion.
  • said atomised sludge Fn moves towards the fume discharge opening along a fluid-vortex path.
  • said atomised sludge owing to the combined action of said suction and blowing means, undergoes continuous remixing inside the chamber, gradually being conveyed towards the fume discharge opening.
  • Said separating means also form means for directing the flow of the combustion air current.
  • the first wall constitutes an obstacle to the exclusively axial advancing movement of the air current, so that said current is deviated towards said forced through-opening, passing in the vicinity of the third burner 24c.
  • said second wall constitutes a further obstacle to the exclusively axial advancing movement of the current, causing it to pass through the forced through-opening.
  • the atomised sludge Fn which is conveyed by the air current, has an undulating movement with an overall progression which is approximately sinusoidal.
  • the atomised sludge Fn is thoroughly mixed with the reaction agent R, namely the calcium carbonate in powder form, together with said sludge inside the kneading machine 2.
  • the calcium carbonate owing to the high temperatures, produces caustic lime (CaO) and free carbon dioxide (CO2) as a result of the reaction: CaCO3 ⁇ CaO + C02.
  • the sludge contains calcium hydroxide (Ca(OH)2) the latter results in the reactive formation of caustic lime and released water vapour as a result of the reaction: Ca(OH)2 ⁇ CaO + H2O.
  • Ca(OH)2 calcium hydroxide
  • the intermixing of the sludge dust and the basic dust resulting from calcination eliminates the acid components of said sludge dust.
  • the caustic lime which forms is basic and is highly reactive to the polluting acids which are present in the sludge dust and are due, for example, to the sulphur, chlorine, fluorine and nitrogen oxides.
  • Said polluting acids combine with the caustic lime, forming inert calcium salts.
  • said vortical remixing movement facilitates the production of the reactions as a result of elimination of the acid components from the sludge dust.
  • the lime resulting from the abovementioned reactions in some cases together with the inert material already formed, the ashes and the heavy dust, forms the inert matter I which is deposited on the feeder screws and conveyed by them outside of the furnace chamber.
  • the furnace according to the present invention and the sludge treatment plant comprising said furnace result in the production of an effective sludge treatment action and the transformation of the said sludge into inert matter.
  • the furnace extends in a substantially horizontal direction, which arrangement is able to ensure the deposition of the inert matter formed by the combusted sludge in the region of the extraction zone despite the conveying action of the combustion air flow.
  • the dehydrated sludge is combined with a reaction agent which, during the course of the heat treatment inside the furnace chamber, produces an agent able to be combined with the pollutants present in the sludge dust, for example with the acid pollutants, resulting in inert matter.
  • conveying of the atomised sludge inside the furnace chamber occurs by means of an air current which disperses the sludge dust, resulting in a more effective combustion action.
  • said combustion air current is vortical, resulting in a movement of the sludge dust and the basic dust which improves the intermixing of the latter and the formation of inert matter from the pollutants present in said sludge.
  • said vortical movement is obtained by perforated plates arranged axially, substantially parallel to the feeder screws for extraction of the inert matter, resulting in efficient extraction of the inert matter which is gradually formed, from the furnace chamber.
  • a further advantage consists in the provision of separating means inside the furnace chamber, which, in addition to defining zones where combustion occurs according to different parameters, for example with higher temperatures in the post-combustion zone, form guide means for the stream of dust which is advantageously directed into zones close to the burner means or to the feeder screws for extraction of the inert matter.
  • the fumes produced inside the furnace chamber are used to heat the dust inside the dehydrator and are suitably treated before being introduced into the atmosphere.
  • sludge having components with a low flash point is supplied directly into the furnace chamber without passing through the dehydrator.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Treatment Of Sludge (AREA)
EP03425192A 2003-03-27 2003-03-27 Foyer et installation de traitement de déchets spéciaux comportant un tel foyer Withdrawn EP1462719A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP03425192A EP1462719A1 (fr) 2003-03-27 2003-03-27 Foyer et installation de traitement de déchets spéciaux comportant un tel foyer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP03425192A EP1462719A1 (fr) 2003-03-27 2003-03-27 Foyer et installation de traitement de déchets spéciaux comportant un tel foyer

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EP1462719A1 true EP1462719A1 (fr) 2004-09-29

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2979138A1 (fr) * 2011-08-16 2013-02-22 Degremont Installation de cogeneration a partir de biomasse
JP6129372B1 (ja) * 2016-02-27 2017-05-17 三久股ふん有限公司 自動灰排出装置

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3861330A (en) * 1974-03-13 1975-01-21 Trane Co Incinerator for aqueous waste material
US4335663A (en) * 1979-11-19 1982-06-22 Conservation Technologies, Inc. Thermal processing system
DE3244123A1 (de) * 1982-11-29 1984-05-30 Deutsche Babcock Anlagen Ag, 4200 Oberhausen Vorrichtung zur herstellung eines granulats
US4509435A (en) * 1982-12-10 1985-04-09 Energy Recovery Group, Inc. Waste material incineration system and method
US5566625A (en) * 1993-08-06 1996-10-22 Young; Bob W. Combustion apparatus including pneumatically suspended combustion zone for waste material incineration and energy production
WO1997008495A1 (fr) * 1995-08-26 1997-03-06 Hugo Petersen Ges. Für Verfahrenstechnischen Anlagenbau Mbh & Co. Kg Procede d'incineration de boues d'epuration et installation correspondante
US5727482A (en) * 1996-06-19 1998-03-17 Young; Bob W. Suspended vortex-cyclone combustion zone for waste material incineration and energy production
US6405664B1 (en) * 2001-04-23 2002-06-18 N-Viro International Corporation Processes and systems for using biomineral by-products as a fuel and for NOx removal at coal burning power plants

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3861330A (en) * 1974-03-13 1975-01-21 Trane Co Incinerator for aqueous waste material
US4335663A (en) * 1979-11-19 1982-06-22 Conservation Technologies, Inc. Thermal processing system
DE3244123A1 (de) * 1982-11-29 1984-05-30 Deutsche Babcock Anlagen Ag, 4200 Oberhausen Vorrichtung zur herstellung eines granulats
US4509435A (en) * 1982-12-10 1985-04-09 Energy Recovery Group, Inc. Waste material incineration system and method
US5566625A (en) * 1993-08-06 1996-10-22 Young; Bob W. Combustion apparatus including pneumatically suspended combustion zone for waste material incineration and energy production
WO1997008495A1 (fr) * 1995-08-26 1997-03-06 Hugo Petersen Ges. Für Verfahrenstechnischen Anlagenbau Mbh & Co. Kg Procede d'incineration de boues d'epuration et installation correspondante
US5727482A (en) * 1996-06-19 1998-03-17 Young; Bob W. Suspended vortex-cyclone combustion zone for waste material incineration and energy production
US6405664B1 (en) * 2001-04-23 2002-06-18 N-Viro International Corporation Processes and systems for using biomineral by-products as a fuel and for NOx removal at coal burning power plants

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2979138A1 (fr) * 2011-08-16 2013-02-22 Degremont Installation de cogeneration a partir de biomasse
JP6129372B1 (ja) * 2016-02-27 2017-05-17 三久股ふん有限公司 自動灰排出装置
JP2017150792A (ja) * 2016-02-27 2017-08-31 三久股ふん有限公司 自動灰排出装置

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