EP1432841A2 - Verfahren zur wärmebehandlung von werkstücken aus temperaturbeständigen stählen - Google Patents
Verfahren zur wärmebehandlung von werkstücken aus temperaturbeständigen stählenInfo
- Publication number
- EP1432841A2 EP1432841A2 EP02776699A EP02776699A EP1432841A2 EP 1432841 A2 EP1432841 A2 EP 1432841A2 EP 02776699 A EP02776699 A EP 02776699A EP 02776699 A EP02776699 A EP 02776699A EP 1432841 A2 EP1432841 A2 EP 1432841A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- workpiece
- nitriding
- temperature
- atmosphere
- hardening
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 58
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 32
- 239000010959 steel Substances 0.000 title claims abstract description 32
- 230000009467 reduction Effects 0.000 claims abstract description 6
- 238000005121 nitriding Methods 0.000 claims description 36
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 25
- 229910052739 hydrogen Inorganic materials 0.000 claims description 23
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 22
- 239000001257 hydrogen Substances 0.000 claims description 22
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 18
- 239000012298 atmosphere Substances 0.000 claims description 17
- 238000005496 tempering Methods 0.000 claims description 14
- 239000007789 gas Substances 0.000 claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims description 13
- 229910021529 ammonia Inorganic materials 0.000 claims description 11
- 238000004140 cleaning Methods 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 5
- 239000007800 oxidant agent Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000003638 chemical reducing agent Substances 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 238000005554 pickling Methods 0.000 abstract description 19
- 238000006396 nitration reaction Methods 0.000 abstract description 3
- 230000002349 favourable effect Effects 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910000000 metal hydroxide Inorganic materials 0.000 description 3
- 150000004692 metal hydroxides Chemical class 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 208000032544 Cicatrix Diseases 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 238000005555 metalworking Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 231100000241 scar Toxicity 0.000 description 2
- 230000037387 scars Effects 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 230000037390 scarring Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/24—Nitriding
- C23C8/26—Nitriding of ferrous surfaces
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/02—Pretreatment of the material to be coated
Definitions
- the present application relates to a method for the heat treatment of a workpiece made of temperature-resistant steels, in particular made of hot work steels, the workpiece being hardened and nitrided after mechanical processing and electrochemical treatment, and the hardening of the workpiece surface being carried out without prior to the subsequent nitriding pickling treatment must be carried out.
- Nitrided hot-working steels are therefore used in particular to manufacture the nozzle bodies.
- EC Electro Chemical Maschining; electrochemical metalworking
- the ECM processes which are used for the shaping and surface treatment of metallic workpieces, are carried out in an electrical lyt solution carried out, the workpiece to be machined is usually connected as an anode and the tool as a cathode.
- the electrochemical metalworking methods are used in particular for deburring, polishing, grinding and etching the surfaces of a workpiece.
- the results of the pickling process are very difficult to reproduce, since, for example, the length of time between processing, basic heat treatment and nitriding can vary.
- the pickling also causes considerable additional costs, which are due in particular to the costs for the system used for pickling and the labor costs required.
- the gebeiz- 'th workpieces after pickling using have a very elaborate special cleaning equipment to be cleaned.
- the disposal of pickling solutions is complex.
- pickling with sauces re an undesirable burden on the environment and worsens working conditions.
- the technical problem on which the present invention is based is therefore to develop a method for treating workpieces made of hot-working steels, in particular DI nozzle bodies, which in particular improves the nitridability of these workpieces without the workpieces having to be pickled, and therefore the disadvantages known from the prior art and caused by pickling can be avoided.
- the present invention solves the .zugêt technical problem by providing a method of manufacturing a part made of a temperature-resistant steel, • in particular a hot-work steel, wherein the workpiece is hardened and is depassivated thereby, characterized in that the curing step, a reduction treatment, in particular by means of hydrogen includes, and the present invention then nitriding the annealed parts with the active surface in a plurality of steps under different gas at osphDC ird carried out ', in which the nitration first under an atmosphere of ammonia and an oxidizing agent, in particular water vapor or air, and then under an atmosphere from ammonia and a carbon-containing gas, in particular endogas or a mixture with CO and / or C0 2 , is carried out.
- the inventive method is to be compared with the known prior art methods also significantly cheaper, because the required for pickling and subsequent cleaning plant and equipment, and only devices for Wasserstof 'fments on the vacuum hardening system needed. Since no acids are used for pickling in the process according to the invention, this also leads to a significant relief for the environment, in particular also to an improvement in the working conditions.
- the workpiece is hardened from a temperature-resistant steel, in particular from hot-work steel, and is thereby passivated, the hardening step comprising a reduction treatment.
- the reduction removes the metal oxide and / or metal hydroxide layers on the surface of the workpiece, so that the subsequent nitriding is considerably improved without pickling.
- the reduction treatment is particularly preferably carried out using hydrogen.
- a hot-work steel is understood to be a steel which is constantly exposed to an elevated temperature, in particular a temperature of more than 200 ° C., during its use. No structural changes may occur in the hot-work steel during use, but the structure must be sufficiently stable and temper-resistant. Depending on the desired use, hot work tool steels must have different properties. Important desired characteristics' are particular hardness and strength that determine themselves the wear resistance.
- Hot-work steels have to meet certain special requirements with regard to performance properties, such as heat resistance, which is achieved in particular through molybdenum, tungsten and grain-fine vanadium, temper resistance, which is generated by chromium, which together with molybdenum, nickel and manganese, increases the hardenability, and heat-wear resistance, which through the The heat resistance of the matrix and the type and amount of special carbides is determined. DI nozzle bodies made of hot-work steel, for example, must have very high wear resistance.
- the workpiece can be machined from a temperature-resistant steel, in particular hot-work steel, before hardening and an electrochemical see processing to be subjected, that is, an ECM process for shaping and surface treatment running in electrolyte solution.
- an ECM process for shaping and surface treatment running in electrolyte solution.
- the workpiece can be deburred, polished in particular; be ground and / or etched.
- an ECM process can be used to produce inner holes that are then rounded.
- the workpiece is subjected to a cleaning step in an aqueous cleaning medium, in particular a neutral cleaner, according to the ECM method.
- the cleaning step according to the invention prevents the formation of thick Me x O y [OH] -.- layers on the surface of the workpiece.
- the workpiece is dried.
- the workpiece can then be hardened immediately.
- the workpiece if it is to be stored for a longer period of time after the ECM processing, is first preserved using suitable methods and, after storage, immediately before hardening, again in a liquid Cleaning medium is cleaned.
- the hardening which leads to a structural change of the hot-work steel described above, is carried out in a single- or multi-chamber vacuum furnace.
- Hardening initially involves convective heating of the workpiece under nitrogen.
- the workpiece is preferably convectively heated under a nitrogen pressure of more than 0.8 bar.
- the workpiece can also be heated in a vacuum. It is provided according to the invention that the workpiece is heated at least up to the hardening temperature of the hot-work steel.
- the hardening temperature of hot-work steel is around 1040 ° C.
- the nitrogen atmosphere or the vacuum is replaced by hydrogen after a desired temperature has been reached.
- the hydrogen introduced which serves as a reducing agent for reducing the metal oxide and / or metal hydroxide layers present on the tool surface, is introduced according to the invention at a temperature of at least 400 ° C.
- the temperatures at which hydrogen is introduced are preferably in the range of the hardening temperature.
- the partial hydrogen pressure is approximately 1 to 100 mbar.
- the flow rate for the hydrogen to be added is preferably 100 to 2000 Nl / h.
- the austenitization is preferably carried out over a period of 10 to 40 minutes.
- the gas exchange takes place pulsating over a period of 1 to 10 minutes.
- the hydrogen is pumped out before the austenitization is ended in order to avoid contamination of the gas used in the subsequent step for quenching with hydrogen.
- the austenitized workpiece is quenched in nitrogen at a pressure of 1 to 10 bar.
- the workpiece is subjected to at least one tempering step.
- the workpiece is tempered at a temperature of up to 650 ° C., the workpiece being tempered either in a nitrogen atmosphere or under a nitrogen-hydrogen atmosphere. When using a nitrogen-hydrogen atmosphere, this contains up to 5% hydrogen.
- the workpiece is tempered in a vacuum furnace or an evacuable tempering furnace. The tempering step according to the invention becomes approximately 1 to. 2 hours.
- the workpiece is subjected to not just one, but several tempering steps.
- the workpiece is subjected to a first tempering step, which takes approximately 1 to 2 hours takes and is heated to a temperature of 520 ° C, and then subjected to a second tempering step, which also takes about 1 to 2 hours and which is heated to a temperature of 610 ° C.
- the workpiece is nitrided immediately after tempering.
- the nitriding leads to hardening of the hot-work steel from which the workpiece is made. This is due to a diffusion of nitrogen into the steel. This leads to the incorporation of nitrogen in interstitial sites and the formation of nitrides, as well as nitrogen deposition on carbides with the formation of carbonitrides. Nitriding creates hard surface layers, which increases the hardness, wear resistance and fatigue strength of the hot-work steel.
- the workpiece is transferred immediately to a nitriding furnace after hardening and tempering.
- the nitriding furnace used according to the invention is preferably a rinsed chamber furnace or an evacuable retort furnace.
- the workpieces are heated in the nitriding furnace in a first step from room temperature to a temperature of approximately 400 ° C.
- the workpieces are preferably heated in the nitriding furnace under an ammonia atmosphere.
- the workpiece is in a second step up to the nitriding temperature, which is between about 500 D C and 600 ° C, heated.
- the nitriding of the workpieces carried out after the heating comprises the following steps according to the invention:
- Step 1 nitriding out under an atmosphere
- Step 2 nitriding under an atmosphere of ammonia and a carbon carrier
- Step 3 nitriding under an atmosphere of ammonia or a gas additive to reduce the nitriding index.
- the workpiece is nitrided by gradually changing the gas atmosphere used.
- 0.5 to 10% by volume of water vapor or up to 15% of air are preferably used as the oxidizing agent in step 1.
- the carbon carrier used in step 2 is preferably 1 to 10% by volume of endogas.
- Endogas which is obtained by endothermic conversion of hydrocarbons, for example propane, is a mixture of 23.7 vol.% CO, 31.5 vol.% H 2 and 44.8 vol.% N 2 .
- 00 and / or CO 2 in equivalent proportions can also be used as a carbon carrier.
- the nitriding in step 2 is referred to as gas oxycarburizing and, according to the invention, takes more than 4 hours, preferably about 10 to 60 hours.
- step 3 treatment according to the invention is carried out with ammonia or a gas additive to reduce the nitriding index in order to limit the growth of the connecting layer.
- the flow rate of the gases during nitriding is dependent on the volume of the furnace usable space and is preferably three times the volume of the furnace usable space in Nl / h.
- the workpieces are cooled after nitriding using nitrogen.
- the workpiece treated and manufactured using the method according to the invention can then be hard machined using conventional methods.
- the method according to the invention can be used in particular for the production of temperature-resistant DI nozzle bodies from hot-work steels, the nozzle bodies being produced from high-strength and temperature-resistant hot-work steels, in particular the steel brands X40CrMoV51 and X38CrMoV51.
- the pressure chamber is further processed in a production cycle, including the soft machining, ECM machining and subsequent directly linked cleaning in an aqueous cleaning medium, but none according to the invention
- the DI nozzle bodies are then in a vacuum furnace in the temperature range between 1000 ° C and 1070 ° C under a pulsed partial hydrogen pressure of 1 to 100 mbar hardened and then quenched in a nitrogen gas stream at a pressure of 1 to 10 bar.
- the tempering takes place at a temperature of up to 650 ° C in a nitrogen or nitrogen-hydrogen atmosphere.
- the subsequent nitriding is preferably carried out at 510 to 590 ° C. over a period of 10 to 60 hours using the gas oxinitrocarburization process described above in a chamber furnace or evacuable retort furnace.
- Heat-resistant DI nozzle bodies treated in this way have more favorable strengthening properties, since the nitriding layer is formed uniformly and the pickling scars described in the prior art are dispensed with.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
- Heat Treatment Of Strip Materials And Filament Materials (AREA)
- Heat Treatment Of Articles (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10147205 | 2001-09-25 | ||
DE10147205A DE10147205C1 (de) | 2001-09-25 | 2001-09-25 | Verfahren zur Wärmebehandlung von Werkstücken aus temperaturbeständigen Stählen |
PCT/DE2002/003582 WO2003027349A2 (de) | 2001-09-25 | 2002-09-24 | Verfahren zur wärmebehandlung von werkstücken aus temperaturbeständigen stählen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1432841A2 true EP1432841A2 (de) | 2004-06-30 |
EP1432841B1 EP1432841B1 (de) | 2008-01-23 |
Family
ID=7700199
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02776699A Expired - Lifetime EP1432841B1 (de) | 2001-09-25 | 2002-09-24 | Verfahren zur wärmebehandlung von werkstücken aus temperaturbeständigen stählen |
Country Status (6)
Country | Link |
---|---|
US (1) | US7108756B2 (de) |
EP (1) | EP1432841B1 (de) |
JP (1) | JP2005503488A (de) |
BR (1) | BR0206051B1 (de) |
DE (1) | DE10147205C1 (de) |
WO (1) | WO2003027349A2 (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10156006B2 (en) | 2009-08-07 | 2018-12-18 | Swagelok Company | Low temperature carburization under soft vacuum |
US10246766B2 (en) | 2012-01-20 | 2019-04-02 | Swagelok Company | Concurrent flow of activating gas in low temperature carburization |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1612290A1 (de) * | 2004-07-02 | 2006-01-04 | METAPLAS IONON Oberflächenveredelungstechnik GmbH | Verfahren zum Gasnitrieren eines Werkstücks eine Gasnitriervorrichtung zur Durchfürung des Verfahrens sowie ein Werkstück |
EP1795622A1 (de) * | 2005-12-12 | 2007-06-13 | METAPLAS IONON Oberflächenveredelungstechnik GmbH | Verfahren zum verbindungsschichtfreien Gasnitrieren einer Oberfläche eines Werkstücks, sowie ein entsprechendes Werkstück |
US8057309B1 (en) * | 2008-12-18 | 2011-11-15 | Hasbro, Inc. | Versatile toy capable of activating electronics and launching components thereof |
CN102399987A (zh) * | 2010-09-15 | 2012-04-04 | 涂嘉晋 | 金属氧化物脱氧技术 |
JP5835256B2 (ja) | 2013-03-21 | 2015-12-24 | 株式会社デンソー | フェライト系ステンレス鋼製品の製造方法 |
DE102014213510A1 (de) | 2014-07-11 | 2016-02-18 | Robert Bosch Gmbh | Verfahren zum Nitrieren eines Bauteils eines Kraftstoffeinspritzsystems |
DE102014220866B3 (de) * | 2014-10-15 | 2016-03-17 | Atlanta Antriebssysteme E. Seidenspinner Gmbh & Co. Kg | Verfahren zum Herstellen von Funktionsflächen, insbesondere Verzahnungen, und nach diesem Verfahren hergestellte Funktionsflächen |
NL1041658B1 (en) * | 2015-12-30 | 2017-07-11 | Bosch Gmbh Robert | Method for austenitizing and/or carburizing steel transverse elements for a drive belt for a continuously variable transmission. |
DE102018102095B3 (de) | 2018-01-31 | 2019-02-14 | Atlanta Antriebssysteme E. Seidenspinner Gmbh & Co. Kg | Verfahren zum Herstellen von Funktionsflächen, insbesondere Verzahnungen, und nach diesem Verfahren hergestellte Funktionsflächen |
CN115074500B (zh) * | 2022-07-08 | 2024-04-02 | 重庆红江机械有限责任公司 | 一种甲醇机喷嘴的热处理方法 |
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US2851387A (en) * | 1957-05-08 | 1958-09-09 | Chapman Valve Mfg Co | Method of depassifying high chromium steels prior to nitriding |
CH402032A (de) * | 1962-06-29 | 1965-11-15 | Saurer Ag Adolph | Verfahren zur Herstellung von verschleissfesten, temperaturbeständigen Teilen aus Stahl |
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JPS5383940A (en) * | 1976-12-29 | 1978-07-24 | Suzuki Motor Co | Heat insulating material and its preparation |
US4235857A (en) * | 1979-07-02 | 1980-11-25 | Ford Motor Company | Method of nitriding silicon |
JPS6280253A (ja) * | 1985-10-02 | 1987-04-13 | Toyoda Autom Loom Works Ltd | 紡機用トラベラ |
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DE4208848C2 (de) | 1991-12-04 | 2001-08-30 | Ald Vacuum Techn Ag | Verfahren zur thermochemischen Nachbehandlung von Stählen und Metallen |
JP2916751B2 (ja) | 1995-09-08 | 1999-07-05 | 鹿児島県 | オーステナイト系ステンレス鋼表面の窒化処理方法 |
JP3685901B2 (ja) * | 1997-03-19 | 2005-08-24 | 本田技研工業株式会社 | Al基複合体の製造方法 |
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2001
- 2001-09-25 DE DE10147205A patent/DE10147205C1/de not_active Expired - Lifetime
-
2002
- 2002-09-24 US US10/432,751 patent/US7108756B2/en not_active Expired - Lifetime
- 2002-09-24 WO PCT/DE2002/003582 patent/WO2003027349A2/de active IP Right Grant
- 2002-09-24 EP EP02776699A patent/EP1432841B1/de not_active Expired - Lifetime
- 2002-09-24 JP JP2003530909A patent/JP2005503488A/ja active Pending
- 2002-09-24 BR BRPI0206051-5A patent/BR0206051B1/pt active IP Right Grant
Non-Patent Citations (1)
Title |
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See references of WO03027349A3 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10156006B2 (en) | 2009-08-07 | 2018-12-18 | Swagelok Company | Low temperature carburization under soft vacuum |
US10934611B2 (en) | 2009-08-07 | 2021-03-02 | Swagelok Company | Low temperature carburization under soft vacuum |
US10246766B2 (en) | 2012-01-20 | 2019-04-02 | Swagelok Company | Concurrent flow of activating gas in low temperature carburization |
US11035032B2 (en) | 2012-01-20 | 2021-06-15 | Swagelok Company | Concurrent flow of activating gas in low temperature carburization |
Also Published As
Publication number | Publication date |
---|---|
US7108756B2 (en) | 2006-09-19 |
BR0206051A (pt) | 2003-09-23 |
JP2005503488A (ja) | 2005-02-03 |
WO2003027349A2 (de) | 2003-04-03 |
DE10147205C1 (de) | 2003-05-08 |
WO2003027349A3 (de) | 2003-12-04 |
BR0206051B1 (pt) | 2011-02-08 |
EP1432841B1 (de) | 2008-01-23 |
US20040055670A1 (en) | 2004-03-25 |
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