EP1414777A1 - Procede de carbonylation en phase vapeur a l'aide de co-catalyseurs iridium-or - Google Patents
Procede de carbonylation en phase vapeur a l'aide de co-catalyseurs iridium-orInfo
- Publication number
- EP1414777A1 EP1414777A1 EP01959524A EP01959524A EP1414777A1 EP 1414777 A1 EP1414777 A1 EP 1414777A1 EP 01959524 A EP01959524 A EP 01959524A EP 01959524 A EP01959524 A EP 01959524A EP 1414777 A1 EP1414777 A1 EP 1414777A1
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- EP
- European Patent Office
- Prior art keywords
- iridium
- gold
- carbonylation
- catalyst
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
Definitions
- the present invention relates to a method for the vapor phase carbonylation of alkyl alcohols, ethers and ester-alcohol mixtures to produce esters and carboxylic acids, and particularly the carbonylation of methanol to produce acetic acid and methyl acetate. More particularly, the present invention relates to a vapor phase carbonylation using a supported catalyst which includes a catalytically effective amount of iridium and gold.
- Acetic acid is used in the manufacture of a variety of intermediary and end-products.
- an important derivative is vinyl acetate which can be used as monomer or co-monomer for a variety of polymers.
- Acetic acid itself is used as a solvent in the production of terephthalic acid, which is widely used in the container industry, and particularly in the formation of PET beverage containers.
- Carbonylation of methanol is a well known reaction and is typically carried out in the liquid phase with a catalyst.
- a thorough review of these commercial processes and other approaches to accomplishing the formation of acetyl from a single carbon source is described by Howard et al. in Catalysis Today, 18 (1993) 325-354.
- liquid phase carbonylation reaction for the preparation of acetic acid using methanol is performed using homogeneous catalyst systems comprising a Group VIII metal and iodine or an iodine-containing compound such as hydrogen iodide and/or methyl iodide.
- Rhodium is the most common Group VIII metal catalyst and methyl iodide is the most common promoter.
- These reactions are conducted in the presence of water to prevent precipitation of the catalyst.
- solid heterogeneous carbonylation catalysts offer the potential advantages of easier product separation, lower cost materials of construction, facile recycle, and even higher rates.
- Rhodium was the first heterogeneous catalyst used in vapor phase carbonylation.
- Schultz in U.S. Patent 3,689,533, discloses using a supported rhodium heterogeneous catalyst for the carbonylation of alcohols to form carboxylic acids in a vapor phase reaction.
- Schultz further discloses the presence of a halide promoter.
- Schultz in U. S . Patent 3,717,670 goes further to describe a similar supported rhodium catalyst in combination with promoters selected from Groups IB, IIIB, IVB, VB, VIB, VE-I, lanthanide and actinide elements of the Periodic Table.
- Iridium is also an active catalyst for methanol carbonylation reactions but normally provides reaction rates lower than those offered by rhodium catalysts when used under otherwise similar conditions.
- European Patent Application EP 0752406 Al teaches that ruthenium, osmium, rhenium, zinc, cadmium, mercury, gallium, indium, or tungsten improve the rate and stability of the liquid phase Ir-I catalyst system.
- the homogeneous carbonylation processes presently being used to prepare acetic acid provide relatively high production rates and selectivity.
- heterogeneous catalysts offer the potential advantages of easier product separation, lower cost materials of construction, facile recycle, and even higher rates.
- EP 0 759419 Al discloses a carbonylation process comprising a first carbonylation reactor wherein an alcohol is carbonylated in the liquid phase in the presence of a homogeneous catalyst system and the off gas from this first reactor is then mixed with additional alcohol and fed to a second reactor containing a supported catalyst.
- the homogeneous catalyst system utilized in the first reactor comprises a halogen component and a Group VIII metal selected from rhodium and iridium.
- the homogeneous catalyst system also may contain an optional co-promoter selected from the group consisting of ruthenium, osmium, rhenium, cadmium, mercury, zinc, indium and gallium.
- the supported catalyst employed in the second reactor comprises a Group VHI metal selected from the group consisting of iridium, rhodium, and nickel, and an optional metal promoter on a carbon support.
- the optional metal promoter may be iron, nickel, lithium and cobalt.
- Nickel on activated carbon has been studied as a heterogeneous catalyst for the halide-promoted vapor phase carbonylation of methanol, and increased rates are observed when hydrogen is added to the feed mixture.
- Relevant references to the nickel-on-carbon catalyst systems are provided by Fujimoto et al. in Chemistry Letters (1987) 895-898 and in Journal of Catalysis, 133 (1992) 370-382 and in the references contained therein. Liu et al., in
- U.S. Patent 5,218,140 to Wegman, describes a vapor phase process for converting alcohols and ethers to carboxylic acids and esters by the carbonylation of alcohols and ethers with carbon monoxide in the presence of a metal ion exchanged heteropoly acid supported on an inert support.
- the catalyst used in the reaction includes a polyoxometallate anion in which the metal is at least one of a Group V(a) and VI(a) is complexed with at least one Group Vi ⁇ cation such as Fe, Ru, Os, Co, Rh, Ir, Ni, Pd or Pt as catalysts for the halide-free carbonylation of alcohols and other compounds in the vapor phase.
- the present invention is a heterogeneous vapor phase carbonylation process wherein an iridium-gold solid supported catalyst is used.
- the process includes feeding a gaseous mixture of reactants comprising lower alkyl alcohols, ethers and ester-alcohol mixtures and carbon monoxide to a carbonylation zone containing a solid supported catalyst comprising a catalytically effective amount of iridium and gold associated with a solid support material that, desirably, is inert to the carbonylation reaction.
- Another aspect of the invention relates to a carbonylation catalyst for producing esters and carboxylic acids in a vapor phase carbonylation process having a solid supported catalyst component and further includes a halogen and/or halide containing compound, (collectively referred to herein as a "halide"). It is an object of the present invention to provide a solid phase catalyst composition for vapor phase carbonylation of methanol to form acetic acid or methyl acetate.
- It is another object of the invention is to provide a carbonylation method that results in higher yields of acetic acid with minimum formation of ethers, aldehydes, and other undesirable by-products.
- the solid supported catalyst used in the present vapor phase carbonylation process includes a catalytically effective amount of iridium and gold associated with a solid support material.
- the solid supported catalyst of the present invention is particularly useful in the continuous production of carboxylic acids and esters by reacting lower alkyl alcohols, polyols, ethers, esters or a mixture thereof with carbon monoxide during carbonylation, especially vapor-phase carbonylation.
- the vapor phase carbonylation method of the present invention is particularly useful for the continuous production of acetic acid, methyl acetate and mixtures thereof.
- the carbonylation process of the present invention comprises feeding a gaseous mixture of an alkyl alcohol, ether, ester, or mixture thereof and carbon monoxide to a carbonylation zone and recovering a gaseous carboxylic acid, ester, or mixture product.
- the carbonylation zone is maintained under vapor-phase carbonylation conditions of temperature and pressure and contains a supported catalyst comprising a catalytically effective amount of iridium and gold associated with a solid support material.
- a catalytically effective amount of iridium and gold are associated with a solid support material that is inert in a carbonylation reaction environment.
- catalytically effective is used herein to refer to catalysis of the carbonylation of a carbonylatable compound.
- iridium and gold atoms are "associated" with the solid support material when the iridium and gold atoms are disposed on, through, and/or near the solid support as a result of any type of chemical and/or physical relationship.
- a material suitable for use as the solid catalyst support material in the present invention is a porous solid having a size of from about 400 mesh per inch to about 0.5 mesh per inch.
- the shape of the solid support is not particularly important and can be regular or irregular and include extrudates, rods, balls, broken pieces and the like disposed within the reactor.
- the support is preferably carbon, or activated carbon, having a high surface area.
- Activated carbon is well known in the art and may be derived from a variety of sources including coal, peat, and coconut shells having a density of from about 0.03 grams/cubic centimeter (g/cm 3 ) to about 2.25 g/cm 3 .
- the carbon can have a surface area of from about 200 square meters/gram (m 2 /g) to about 1200 m 2 /g.
- solid support materials may be used, either alone or in combination, in accordance with the present invention include pumice, alumina, silica, silica-alumina, magnesia, diatomaceous earth, bauxite, titania, zirconia, clays, magnesium silicate, silicon carbide, zeolites, ceramics, and combinations thereof.
- the compound or form of iridium used to prepare the catalyst is not critical, and the catalyst may be prepared from any of a wide variety of iridium containing compounds. Indeed, iridium compounds containing myriad combinations of halide, trivalent nitrogen, organic compounds of trivalent phosphorous, carbon monoxide, hydrogen, and 2,4-pentane- dione, either alone or in combination. Such materials are available commercially and may be used in the preparation of the catalysts utilized in the present invention. In addition, the oxides of iridium may be used if dissolved in the appropriate medium.
- the iridium used in this invention is preferably an iridium chloride, such as iridium trichloride or hydrated trichloride, hexacholoro-iridate and any of the various salts of hexachloro-iridate (IV).
- the compound or form of gold used to prepare the catalyst generally is not critical, and may be selected from any of a variety of compounds containing gold, their respective salts, and mixtures thereof.
- Particularly useful gold compounds include gold halides, cyanides, hydroxides, oxides, sulfides, and phosphine complexes either alone or in combination. Such materials are available commercially and may be used in the preparation of the catalysts used in the process of the present invention.
- Gold oxide may be used if dissolved in the appropriate medium.
- the compound used to provide the gold component is preferably in a water soluble form.
- Preferred water soluble gold sources include halides, particularly the tetrahaloaurates.
- the most preferred hydrogen tetrahaloaurates are hydrogen tetrachloroaurate (III) and hydrogen tetrabromoaurate (HI).
- the amount of iridium and gold on the support can vary from about 0.01 weight percent to about 10 weight percent, with from about 0.1 weight percent to about 2 weight percent of each component being preferred.
- the weight percent of each said metal is determined as the weight of atoms of that particular metal compared to the total weight of the solid supported catalyst composition.
- the molar ratio of iridium to gold is preferably in a range from about 0.1 : 1 to about 10:1, with a molar ratio of about 0.5:1 to about 3:1 iridium to gold being more preferred.
- the catalyst of the present invention is very effective in carbonylation when there are essentially no other metals associated with the support besides iridium and gold.
- other metals may be associated with the support as part of the catalyst composition, either as promoters, as co-catalysts, or as inert metals, as long as the amount of iridium and gold present is a sufficient amount so that the iridium and gold effectively catalyze carbonylation in the presence of the other associated metal.
- the ratio of the weight of gold to the weight of the metals other than iridium and gold is preferably greater than 1:1, with a ratio of at least about 2: 1 being more preferable.
- Suitable metals for association with the support besides iridium and gold are most likely alkaline or alkaline earth metals, tin, vanadium, molybdenum, and tungsten.
- the present solid supported catalyst may be prepared by depositing iridium and gold on the solid support material to form a composition wherein a catalytically effective amount of iridium and gold are associated with the solid support material.
- the iridium and gold may be deposited concurrently or separately.
- the deposition of iridium and gold may be conducted by any means sufficient to cause the iridium and gold to associate with the support including but not limited to methods employing heat, electrolyzing, physical embedding, sonification, impregnating, co-precipitation.
- the preferred method of depositing the iridium and gold on the support is by dissolving or dispersing iridium and gold compounds in an appropriate solvent, either in one solution together or in two separate solutions, and contacting, preferably impregnating, the support with the iridium and gold containing solutions to provide a wet solid support material.
- the iridium and gold atoms are then associated with the support when the solvent is removed by drying the wet support material.
- Various methods of contacting the support material with the iridium and gold may be employed as long as the contacting method provides association between the iridium and gold atoms and the support.
- an iridium containing solution can be admixed with a gold solution prior to impregnating the support material.
- the respective solutions can be impregnated separately into or associated with the support material prior to impregnating the support material with the second solution.
- the gold component may be deposited on a previously prepared catalyst support having the iridium component already incorporated thereon.
- the support is dried prior to contacting the second solution.
- the iridium and gold may be associated with the support material in a variety of forms. For example, slurries of the iridium and gold can be poured over the support material. Alternatively, the support material may be immersed in excess solutions of the active components with the excess being subsequently removed using techniques known to those skilled in the art. The solvent or liquid is evaporated, i.e.
- the solid support is dried so that at least a portion of the iridium and gold is associated with the solid support. Drying temperatures can range from about 100°C to about 600°C. One skilled in the art will understand that the drying time is dependent upon the temperature, humidity, and solvent. Generally, lower temperatures require longer heating periods to effectively evaporate the solvent from the solid support.
- the liquid used to deliver the iridium and gold in the form of a solution, dispersion, or suspension is a liquid having a low boiling point, i.e., high vapor pressure at a temperature of from about 10°C to about 140°C.
- suitable solvents include carbon tetrachloride, benzene, acetone, methanol, ethanol, isopropanol, isobutanol, pentane, hexane, cyclohexane, heptane, toluene, pyridine, diethylamine, acetaldehyde, acetic acid, tetrahydrofuran and water.
- the carbonylation catalyst further includes a halide promoter.
- halide is used generically and interchangeably with “halogen”, “halide” or “halide containing compound” and includes both the singular or plural forms. It is preferable that the halide is promoter is present as a vapor. However, the halide may also be present as a liquid or as a solid, as long as the halide component is in sufficient contact with the iridium and gold components so as to provide iridium-halide and gold-halide complex formation.
- the halide promoter is a catalyst component instead of a reactant, in that it is essentially non-consumed in the present carbonylation process.
- the halide may be introduced at the catalyst preparation step or, preferably, is introduced into the carbonylation reactor with the gaseous reactants.
- the halide promoter may include one or more of chlorine, bromine and/or iodine compounds and is preferably vaporous under vapor-phase carbonylation conditions of temperature and pressure.
- Suitable halides include hydrogen halides such as hydrogen iodide and gaseous hydriodic acid; alkyl and aryl halides having up to 12 carbon atoms such as, methyl iodide ethyl iodide, 1-iodopropane, 2-iodobutane, 1-iodobutane, methyl bromide, ethyl bromide, and benzyl iodide.
- the halide is a hydrogen halide or an alkyl halide having up to 6 carbon atoms.
- preferred halides are hydrogen iodide, methyl bromide and methyl iodide.
- the halide may also be a molecular halide such as I 2 , Br 2 , or Cl 2 .
- the vapor phase carbonylation process of the present invention is conducted by contacting the vapor phase reactants with the catalyst by flowing them through or over the catalyst. This is accomplished by feeding a gaseous mixture comprising the reactants to a carbonylation zone containing the solid supported iridium-gold catalyst of the present invention.
- the present heterogeneous vapor-phase process preferably operates entirely in the gas phase, i.e., none of the compounds or materials present in the carbonylation zone or reactor exists in a mobile liquid phase.
- a gaseous product comprising a carboxylic acid, an ester thereof, or a mixture thereof are recovered from the carbonylation zone.
- Vapor-phase carbonylation is typically operated at temperatures above the dew point of the product mixture, i.e., the temperature at which condensation occurs.
- the dew point is a complex function of dilution, product composition and pressure, and particularly with respect to non-condensable gases such as unreacted carbon monoxide, hydrogen, or inert diluent gas
- the process may still be operated over a wide range of temperatures, provided the temperature exceeds the dew point of the product effluent. In practice, this generally dictates a temperature range of about 100°C to 500°C, with temperatures in the range of 100°C to 325°C being preferred and temperature of about 150°C to 275°C being particularly useful.
- the useful pressure range is limited by the dew point of the product mixture.
- a wide range of pressures may be used, e.g., pressures in the range of about 0.1 to 100 bars absolute.
- the process preferably is carried out at a pressure in the range of about 1 to 50 bars absolute, most preferably, about 3 to 30 bar absolute.
- Suitable feedstocks for carbonylation using the present catalyst include lower alkyl alcohols, ethers, ester and esters-alcohol mixtures which may be carbonylated using the catalyst of the present invention.
- feedstocks include alcohols and ethers in which an aliphatic carbon atom is directly bonded to an oxygen atom of either an alcoholic hydroxyl group in the compound or an ether oxygen in the compound and may further include aromatic moieties.
- the feedstock is one or more lower alkyl alcohols having from 1 to 10 carbon atoms and preferably having from 1 to 6 carbon atoms, alkane polyols having 2 to 6 carbon atoms, alkyl alkylene polyethers having 3 to 20 carbon atoms and alkoxyalkanols having from 3 to 10 carbon atoms.
- the most preferred reactant is methanol.
- methanol is the preferred feedstock to use with the solid supported catalyst of the present invention and is normally fed as methanol, it can be supplied in the form of a combination of materials which generate methanol. Examples of such materials include (i) methyl acetate and water and (ii) dimethyl ether and water.
- both methyl acetate and dimethyl ether are formed within the reactor and, unless methyl acetate is the desired product, they are recycled with water to the reactor where they are converted to acetic acid. Accordingly, one skilled in the art will further recognize that it is possible to utilize the catalyst of the present invention to produce a carboxylic acid from an ester feed material.
- the molar ratio ofwaterto methanol can be 0:1 to 10:1, but preferably is in the range of 0.01:1 to 1:1.
- the amount of water fed usually is increased to account for the mole of water required for hydrolysis of the methanol alternative. Accordingly, when using either methyl acetate or dimethyl ether, the mole ratio of water to ester or ether is in the range of 1 : 1 to 10 : 1 , but preferably in the range of 1 : 1 to 3 : 1.
- the mole ratio of water to ester or ether is in the range of 1 : 1 to 10 : 1 , but preferably in the range of 1 : 1 to 3 : 1.
- acetic acid it is apparent that combinations of methanol, methyl ester, and/or dimethyl ether are equivalent, provided the appropriate amount of water is added to hydrolyze the ether or ester to provide the methanol reactant.
- a gaseous mixture having at least one of lower alkyl alcohol, ether and ester-alcohol mixture, either alone or in combination; carbon monoxide; and a halide are fed to a carbonylation reactor containing the iridium and gold supported catalyst described above.
- the reactant in the vapor phase, is allowed to contact the solid supported catalyst.
- the reactor is maintained under carbonylation conditions of temperature and pressure. If acetic acid is the desired product, the feedstock may consist of methyl alcohol, dimethyl ether, methyl acetate, a methyl halide or any combination thereof. If it is desired to increase the proportion of acid produced, the ester may be recycled to the reactor together with water or introduced into a separate reactor with water to produce the acid in a separate zone.
- the carbon monoxide can be a purified carbon monoxide or include other gases.
- the carbon monoxide need not be of a high purity and may contain from about 1 % by volume to about 99 % by volume carbon monoxide, and preferably from about 70 % by volume to about 99 % by volume carbon monoxide.
- the remainder of the gas mixture may include such gases as nitrogen, hydrogen, carbon dioxide, water and paraffinic hydrocarbons having from one to four carbon atoms.
- hydrogen is not part of the reaction stoichiometry, hydrogen may be useful in maintaining optimal catalyst activity.
- the preferred ratio of carbon monoxide to hydrogen generally ranges from about 99: 1 to about 2: 1, but ranges with even higher hydrogen levels are also likely to be useful.
- the amount of halide present in the gaseous feed to produce an effective carbonylation is based on the amount of alcohol or alcohol equivalents.
- the molar ratio of alcohol to halide ranges from about 1:1 to about 10,000:1, with the preferred range being from about 5:1 to about 1000:1.
- the vapor-phase carbonylation catalyst of the present invention may be used for making acetic acid, methyl acetate or a mixture thereof.
- the process includes the steps of contacting a gaseous mixture comprising methanol and carbon monoxide with the iridium-gold catalyst described above in a carbonylation zone and recovering a gaseous product from the carbonylation zone.
- the main gaseous products recovered include methyl acetate, acetic acid, unreacted methanol, and methyl iodide.
- the present invention is illustrated in greater detail by the specific examples present below. It is to be understood that these examples are illustrative embodiments and are not intended to be limiting of the invention, but rather are to be construed broadly within the scope and content of the appended claims.
- the iridium-gold catalyst was prepared using a sequential impregnation technique. The steps are described below.
- Hydrogen tetrachloroaurate (III) hydrate (50.11% gold, 0.458 grams, 1.16 mmol) was dissolved in 30 mL of distilled water. The solution was then added to 20 grams of 12 X 40 mesh activated carbon granules (20.0 g, obtained from Calgon) having a BET surface area in excess of 800 m 2 /g contained in an evaporating dish. The mixture was heated on the steam bath with continuous stirring until it became free flowing and then transferred to a quartz tube measuring 106 cm long by 25 mm outer diameter. The quartz tube containing the mixture was placed in a three-element electric tube furnace so that the mixture was located in the approximate center of the 61 cm long heated zone of the furnace.
- Nitrogen 100 standard cubic centimeters per minute was continuously passed through the catalyst bed, and the tube was heated from ambient temperature to 300°C over a 2 hour period, held at 300°C for 2 hours and then allowed to cool back to ambient temperature.
- the gold on carbon thus prepared was used in the subsequent step.
- Iridium (HI) chloride hydrate (0.412 g, 1.16 mmol) was dissolved in 30 mL of distilled water and the solution was then added to the gold/activated carbon pellets (from the above step) in an evaporating dish.
- the mixture was heated on the steam bath with continuous stirring until it became free flowing and then transferred to a quartz tube measuring 106 cm long by 25 mm outer diameter.
- the quartz tube containing the mixture was placed in a three- element electric tube furnace so that the mixture was located in the approximate center of the
- Hydrogen tetrachloroaurate (LTE) hydrate (50.11% gold, 0.458 grams, 1.16 mmol) was dissolved in 30 mL of distilled water. The solution was then added to 20 grams of 12 X 40 mesh activated carbon granules (20.0 g, obtained from Calgon) having a BET surface area in excess of 800 m 2 /g contained in an evaporating dish. The mixture was heated on the steam bath with continuous stirring until it became free flowing and then transferred to a quartz tube measuring 106 cm long by 25 mm outer diameter. The quartz tube containing the mixture was placed in a three-element electric tube furnace so that the mixture was located in the approximate center of the 61 cm long heated zone of the furnace. Nitrogen (100 standard cubic centimeters per minute) was continuously passed through the catalyst bed, and the tube was heated from ambient temperature to 300°C over a 2 hour period, held at 300°C for 2 hours and then allowed to cool back to ambient temperature.
- LTE Hydrogen tetrachloroaurate
- the catalyst prepared in this manner contained 1.10% iridium and had a density of 0.57 g per mL.
- An iridium-copper catalyst was prepared using a co-impregnation technique as described below.
- Iridium (III) chloride hydrate (0.419 g, 1.16 mmol) was dissolved in 30 mL of distilled water. Copper (H) chloride (0.157 g, 1.16 mmol) was then added and allowed to dissolve. The copper-iridium solution was then added to 20 grams of 12 X 40 mesh activated carbon granules (20.0 g, obtained from Calgon) having a BET surface area in excess of 800 m /g contained in an evaporating dish. The mixture was heated on the steam bath with continuous stirring until it became free flowing and then transferred to a quartz tube measuring 106 cm long by 25 mm outer diameter.
- the quartz tube containing the mixture was placed in a three-element electric tube furnace so that the mixture was located in the approximate center of the 61 cm long heated zone of the furnace. Nitrogen (100 standard cubic centimeters per minute) was continuously passed through the catalyst bed, and the tube was heated from ambient temperature to 300°C over a 2 hour period, held at 300°C for 2 hours and then allowed to cool back to ambient temperature.
- the reactor system consisted of a 800 to 950 mm (31.5 and 37 inch) section of 6.35 mm (V inch) diameter tubing constructed of Hastelloy alloy.
- the upper portion of the tube constituted the preheat and reaction (carbonylation) zones which were assembled by inserting a quartz wool pad 410 mm from the top of the reactor to act as support for the catalyst, followed sequentially by (1) a 0.7 g bed of fine quartz chips (840 microns), (2) 0.5 g of one of the catalysts prepared as described in the preceding examples, and (3) an additional 6 g of fine quartz chips.
- the top of the tube was attached to an inlet manifold for introducing liquid and gaseous feeds.
- the gases were fed using Brooks flow controllers and liquids were fed using a high performance liquid chromatography pump.
- the gaseous products leaving the reaction zone were condensed using a vortex cooler operating at 0-5°C.
- the product reservoir was a tank placed downstream from the reactor system.
- the pressure was maintained using a Tescom 44-2300 Regulator on the outlet side of the reactor system and the temperature of the reaction section was maintained using heating tape on the outside of the reaction system.
- Feeding of hydrogen and carbon monoxide to the reactor was commenced while maintaining the reactor at a temperature of 240°C and a pressure of 17.2 bara (250 psia).
- the flow rate of hydrogen was set at 25 standard cubic cm.
- EXAMPLE 1 The composition and weight of the samples taken periodically during the procedure described above in which Catalyst 1 was used are set forth in Table 1 wherein “Time” is the total time of operation (in hours) of the carbonylation commencing with the feeding of the methanol until a particular sample was taken.
- “Time” is the total time of operation (in hours) of the carbonylation commencing with the feeding of the methanol until a particular sample was taken.
- the values set forth below “Mel” (methyl iodide), “MeOAc” (methyl acetate), “MeOH” (methanol) and “HOAc” (acetic acid) are the weight percentages of each of those compounds present in the sample. The weight of each sample is given in grams.
- “Production Rate” is the moles of Acetyl Produced per liter of catalyst volume per hour during each increment of Time (Time Increment), i.e., the time of operation between samples.
- the formula for determining moles of Acetyl Produced per liter of catalyst volume per hour is:
- the catalyst produced 8.07 moles of acetyl. This represents a rate of 227 moles of acetyl/kg cat -h or, 130 mol of acetyl L cat -h.
- Comparative Catalysts C-I, C-II, C-IH and C-IV were utilized in the carbonylation of methanol according to the above-described procedure.
- the Production Rate expressed in terms of moles of Acetyl Produced per kilogram of catalyst per hour and moles per liter of catalyst volume per hour, provided by each of Catalysts 1 and Comparative Catalysts C-1, C- 2, C-3, and C-4 is shown in Table 3.
- Table 3 shows that the rate of reaction of the (1.16 mol)iridium-(1.16 mol)gold catalyst is significantly more (49% more) than the summation of the reaction rates of a 1.17 mol iridium catalyst and a 1.16 mol gold catalyst.
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Abstract
L'invention concerne un procédé de carbonylation en phase vapeur utilisé pour produire des acides carboxyliques, des esters et des mélanges de ceux-ci à partir d'alcools aliphatiques inférieurs, d'éthers, d'ester, et de mélanges ester-alcool. Ledit procédé de carbonylation en phase vapeur est caractérisé en ce qu'il utilise un catalyseur à support solide comprenant une quantité efficace d'iridium et d'or associés à un matériau de support solide.
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PCT/US2001/024512 WO2003018524A1 (fr) | 2001-08-03 | 2001-08-03 | Procede de carbonylation en phase vapeur a l'aide de co-catalyseurs iridium-or |
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EP1414777A1 true EP1414777A1 (fr) | 2004-05-06 |
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EP01959524A Withdrawn EP1414777A1 (fr) | 2001-08-03 | 2001-08-03 | Procede de carbonylation en phase vapeur a l'aide de co-catalyseurs iridium-or |
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EP (1) | EP1414777A1 (fr) |
WO (1) | WO2003018524A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7396048B2 (en) * | 2002-10-15 | 2008-07-08 | Ncr Corporation | Internet stamp |
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US7838708B2 (en) | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
WO2005021468A1 (fr) | 2003-07-15 | 2005-03-10 | Grt, Inc. | Synthese d'hydrocarbures |
US20050171393A1 (en) | 2003-07-15 | 2005-08-04 | Lorkovic Ivan M. | Hydrocarbon synthesis |
US7674941B2 (en) | 2004-04-16 | 2010-03-09 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US20060100469A1 (en) | 2004-04-16 | 2006-05-11 | Waycuilis John J | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
US20080275284A1 (en) | 2004-04-16 | 2008-11-06 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US7244867B2 (en) | 2004-04-16 | 2007-07-17 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
EP1993979A4 (fr) | 2006-02-03 | 2011-07-06 | Grt Inc | Procede continu de conversion de gaz naturel en hydrocarbures liquides |
UA95943C2 (ru) | 2006-02-03 | 2011-09-26 | ДжиАрТи, ИНК. | Отделение легких газов от галогенов |
EA017699B1 (ru) | 2007-05-24 | 2013-02-28 | Грт, Инк. | Зонный реактор с обратимым захватыванием и высвобождением галогеноводородов |
US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
SG192538A1 (en) | 2008-07-18 | 2013-08-30 | Grt Inc | Continuous process for converting natural gas to liquid hydrocarbons |
US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
CN114539056B (zh) * | 2020-11-24 | 2023-03-14 | 中国科学院大连化学物理研究所 | 一种甲醇羰基化制备乙酸甲酯的方法 |
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US3816337A (en) * | 1970-09-01 | 1974-06-11 | Toa Nenryo Kogyo Kk | Process for preparing a catalytic cobalt carbonyl reaction product |
DE4424710A1 (de) * | 1994-07-13 | 1996-01-18 | Basf Ag | Verfahren zur Carbonylierung von Olefinen |
DE19706876A1 (de) * | 1997-02-21 | 1998-08-27 | Basf Ag | Verfahren zur Herstellung von Carbonsäuren oder deren Estern durch Carbonylierung von Olefinen |
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2001
- 2001-08-03 WO PCT/US2001/024512 patent/WO2003018524A1/fr not_active Application Discontinuation
- 2001-08-03 EP EP01959524A patent/EP1414777A1/fr not_active Withdrawn
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See references of WO03018524A1 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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US7396048B2 (en) * | 2002-10-15 | 2008-07-08 | Ncr Corporation | Internet stamp |
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WO2003018524A1 (fr) | 2003-03-06 |
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