EP1379725A1 - Flat textile structures with self-cleaning and water-repellent surfaces - Google Patents
Flat textile structures with self-cleaning and water-repellent surfacesInfo
- Publication number
- EP1379725A1 EP1379725A1 EP02704724A EP02704724A EP1379725A1 EP 1379725 A1 EP1379725 A1 EP 1379725A1 EP 02704724 A EP02704724 A EP 02704724A EP 02704724 A EP02704724 A EP 02704724A EP 1379725 A1 EP1379725 A1 EP 1379725A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- particles
- base material
- textile
- solvent
- fabric according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/10—Processes in which the treating agent is dissolved or dispersed in organic solvents; Processes for the recovery of organic solvents thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B17/00—Methods preventing fouling
- B08B17/02—Preventing deposition of fouling or of dust
- B08B17/06—Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B17/00—Methods preventing fouling
- B08B17/02—Preventing deposition of fouling or of dust
- B08B17/06—Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement
- B08B17/065—Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement the surface having a microscopic surface pattern to achieve the same effect as a lotus flower
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic System; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2164—Coating or impregnation specified as water repellent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2213—Coating or impregnation is specified as weather proof, water vapor resistant, or moisture resistant
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2279—Coating or impregnation improves soil repellency, soil release, or anti- soil redeposition qualities of fabric
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2762—Coated or impregnated natural fiber fabric [e.g., cotton, wool, silk, linen, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2861—Coated or impregnated synthetic organic fiber fabric
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2926—Coated or impregnated inorganic fiber fabric
Definitions
- the present invention relates to textile fabrics with a self-cleaning and water-repellent surface.
- CH-PS-268 258 describes a method in which structured surfaces are produced by applying powders such as kaolin, talc, clay or silica gel. The powders are fixed on the surface by oils and resins based on organosilicon compounds (Examples 1 to 6).
- EP 0 909 747 teaches a method for producing a self-cleaning surface.
- the surface has hydrophobic elevations with a height of 5 to 200 ⁇ m.
- Such a surface is produced by applying a dispersion of powder particles and an inert material in a siloxane solution and then curing. The structure-forming particles are thus fixed to the substrate by an auxiliary medium.
- WO 00/58410 comes to the conclusion that it is technically possible to produce surfaces of To make objects artificially self-cleaning.
- the surface structures of elevations and depressions required for this have a distance between the elevations of the surface structures in the range from 0.1 to 200 ⁇ m and a height of the elevation in the range 0.1 to 100 ⁇ m.
- the materials used for this must consist of hydrophobic polymers or permanently hydrophobized material. Detachment of the particles from the carrier matrix must be prevented.
- hydrophobic materials such as perfluorinated polymers
- hydrophobic surfaces are known.
- a further development of these surfaces consists in structuring the surfaces in the ⁇ m range to the nm range.
- US Pat. No. 5,599,489 discloses a method in which a surface can be given a particularly repellent finish by bombardment with particles of a corresponding size and subsequent perfluorination.
- Another method describes H. Saito et al. in "Service Coatings International", 4, 1997, p.168 ff.
- particles of fluoropolymers are applied to metal surfaces, with a greatly reduced wettability of the surfaces thus produced against water with a significantly reduced tendency to icing.
- WO 00/58410 describes the structures and claims the formation thereof by spraying on hydrophobic alcohols, such as nonacosan-10-ol or alkanediols, such as nonacosan-5,10-diol.
- hydrophobic alcohols such as nonacosan-10-ol or alkanediols, such as nonacosan-5,10-diol.
- the disadvantage here is the poor stability of the self-cleaning surfaces, since detergents lead to the dissolution of the structure.
- the invention relates to textile fabrics with a self-cleaning and water-repellent surface, composed of
- Another object of the invention are textile fabrics with a self-cleaning and water-repellent surface, constructed from
- the textile base material A can be formed by a wide variety of common polymers, such as. B. from polycarbonates, poly (meth) acrylates, polyamides, PVC, polyethylenes, polypropylenes, polystyrenes, polyesters, polyether sulfones or polyalkylene terephthalates, and mixtures or copolymers thereof.
- common polymers such as. B. from polycarbonates, poly (meth) acrylates, polyamides, PVC, polyethylenes, polypropylenes, polystyrenes, polyesters, polyether sulfones or polyalkylene terephthalates, and mixtures or copolymers thereof.
- Natural materials made from parts of plants selected from cotton, kapok, flax, hemp, jute, sisal and coconut, from animal hair, from silk or mineral origin are also suitable as the base material.
- Mixed fabrics made of natural and artificial materials are also suitable.
- the base material A to be used according to the invention is explained in more detail below by way of example.
- Finished textile goods are usually made from polymer threads that have been produced using the spinning process. Textile fabrics are produced from the fibers and yarns. The following procedures can be used:
- Piece goods are subjected to various mechanical and chemical finishing processes in the course of their processing, e.g. B. combing, weighting, impregnation, shrink free u. Anti-crease, mercerization, dyeing and printing, metallization, texturing, etc., which are intended to improve or modify the natural properties of the fibers with a view to later use. Criteria according to which the utility value of a finished textile product is assessed using suitable textile testing methods include: a .: Resistance to tensile and bursting forces as well as to abrasion, crease recovery in dry and wet condition and the associated wash-and-wear behavior, resistance z. B.
- Polymer fabrics / textiles that is to say the base material A in the sense of the invention, can be produced from different fibers.
- the processes mentioned above are suitable for most fibers made of thermoplastics, such as PET, PA66, PE or PP. Fibers are usually traded with protected brand names, examples are Perlon ® , Diolen ® , Trevira ® , Orleon ® , but trivial names such as acrylic fibers, polyester fibers, olefin fibers, aramid fibers etc. are also common.
- the particles used can be those which have at least one material selected from Have silicates, minerals, metal oxides, metal powders, silicas, pigments or polymers.
- particles are used which have a particle diameter of 0.02 to 100 ⁇ m, particularly preferably from 0.1 to 50 ⁇ m and very particularly preferably from 0.1 to 30 ⁇ m.
- particles which are composed of primary particles to form agglomerates or aggregates with a size of 0.2-100 ⁇ m are also suitable.
- the particles are bound to the surface of the polymer fibers in such a way that they are spaced from one another by 0-10 particle diameters.
- the particles on the base material A do not have to be very close to one another. Rather, it is possible that the base material A is only partially covered with particles and free areas of 2-3 diameters of the particles are possible.
- the wetting of solids can be described by the contact angle that a drop of water forms with the surface.
- a contact angle of 0 degrees means complete wetting of the surface.
- the wetting angle on fibers is usually measured using the Wilhelmy method.
- the thread is wetted by a liquid and the force with which the fiber is pulled into the liquid due to the surface tension is measured. The higher the contact angle, the worse the surface can be wetted.
- the aspect ratio is defined as the quotient of the height to the width of the structure of the surface.
- the textile surfaces according to the invention have high contact angles and a high aspect ratio of the elevations.
- the particles used have a structured surface. Particles which have an irregular fine structure in the nanometer range on the surface are preferably used. The use of such particles is new and is the subject of a separate patent application (internal file number: EM 010098).
- particles especially as particles that have an irregular fine structure in the Having nanometers on the surface, those particles are preferably used which have at least one compound selected from pyrogenic silica, precipitated silica, aluminum oxide, silicon dioxide, pyrogenic and / or doped silicates or powdery polymers. It can be advantageous if the particles used have hydrophobic properties.
- hydrophobic properties of the particles may be inherent due to the material used for the particles. However, it is also possible to use hydrophobized particles which, after suitable treatment, have hydrophobic properties, such as, for. B. a treatment with at least one compound from the group of alkylsilanes, fluoroalkylsilanes or disilazanes.
- the particles are provided with hydrophobic properties after being bonded to the base material A.
- the particles are preferably provided with hydrophobic properties by treatment with at least one compound from the group of the alkylsilanes, the fluoroalkylsilanes or the disilazanes.
- the particles preferably used are explained in more detail below.
- the particles used can come from different areas. For example, it can be silicates, doped silicates, minerals, metal oxides, aluminum oxide, silicas or pyrogenic silicates, aerosils or powdered polymers, such as, for. B. spray-dried and agglomerated emulsions or cryomilled PTFE. Particularly suitable as particle systems are hydrophobicized pyrogenic silicas, so-called aerosils. In addition to the structure, a hydrophobicity is necessary to generate the self-cleaning surfaces.
- the particles used can themselves be hydrophobic, such as PTFE.
- the particles can be made hydrophobic, such as the Aerosil VPR 411 or Aerosil R 8200. However, they can also be made hydrophobic afterwards.
- the particles are hydrophobicized before or after application. This, for example for Aeroperl 90/30, Sipernat Silicic acid 350, aluminum oxide C, zirconium silicate, vanadium-doped or Aeroperl P 25/20.
- the hydrophobization is expediently carried out by treatment with perfluoroalkylsilane and subsequent tempering.
- solvents are suitable as solvents for the respective base materials A.
- a list for polymers can be found, for example, in Polymer Handbook, Second Edition; J. Brandrup, E.H. Always good; John Wiley & Sons Verlag, New York - London - Sydney - Toronto, 1975, in Chapter IV, Solvents and Non-Solvents for Polymers.
- Suitable solvents are, in principle, suitable compounds from the group of alcohols, glycols, ethers, glycol ethers, ketones, esters, amides, nitro compounds, halogenated hydrocarbons, aliphatic and aromatic hydrocarbons or a mixture of one or more of these compounds in question, such as. B.
- the solvent used can be used at temperatures from - 30 to 300 ° C.
- the temperature of the solvent is limited by its boiling point and by the Tg of the base material A.
- the solvent which has the particles is heated to a temperature of 25 to 100 ° C., preferably to a temperature of 50 to 85 ° C., before being applied to the polymer surface.
- the invention also relates to the use of the textile fabrics for the production of objects with a self-cleaning and water-repellent surface, in particular for the production of articles of clothing which are exposed to high loads from dirt and water, such as, for. B. for skiing, alpine sports, motor sports, motorcycle sports, motocross sports, sailing, textiles for the leisure sector and technical textiles such as tents, awnings, umbrellas, tablecloths and convertible tops.
- the subject is also the use for the manufacture of carpets, sewing threads, ropes, wall hangings, textiles, wallpapers, clothing, tents, decorative curtains, stage curtains, seams.
- a polyester fabric, fiber diameter 0 20 ⁇ m, is drawn into a DMSO bath heated to 50 ° C. with a 1% Aeroperl 8200 suspension. The tissue remains in the solution for 10 seconds. Before the fabric is rolled up, the fabric is passed over a heat source to allow the solvent to evaporate. Table 1 shows the static contact angles measured on the tissue before and after the application of the particles.
- Figures 1 and 2 show SEM images of an untreated polyester fabric.
- Figures 3 and 4 show SEM images of a polyester fabric treated with Aerosil R8200.
- Table 1 Static contact angle before and after the application of the particulate systems
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10118346 | 2001-04-12 | ||
DE10118346A DE10118346A1 (en) | 2001-04-12 | 2001-04-12 | Self-cleaning, water-repellent textiles, used e.g. for tents, sports clothing and carpets, made by impregnating textile material with a suspension of hydrophobic particles and then removing the solvent |
PCT/EP2002/002013 WO2002084016A1 (en) | 2001-04-12 | 2002-02-26 | Flat textile structures with self-cleaning and water-repellent surfaces |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1379725A1 true EP1379725A1 (en) | 2004-01-14 |
EP1379725B1 EP1379725B1 (en) | 2006-09-13 |
Family
ID=7681411
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02704724A Expired - Lifetime EP1379725B1 (en) | 2001-04-12 | 2002-02-26 | Flat textile structures with self-cleaning and water-repellent surfaces |
Country Status (7)
Country | Link |
---|---|
US (1) | US8629070B2 (en) |
EP (1) | EP1379725B1 (en) |
AT (1) | ATE339545T1 (en) |
CA (1) | CA2443743A1 (en) |
DE (2) | DE10118346A1 (en) |
ES (1) | ES2272672T3 (en) |
WO (1) | WO2002084016A1 (en) |
Families Citing this family (76)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10134477A1 (en) * | 2001-07-16 | 2003-02-06 | Creavis Tech & Innovation Gmbh | Self-cleaning surfaces through hydrophobic structures and processes for their production |
DE10160055A1 (en) * | 2001-12-06 | 2003-06-18 | Degussa | Diffuse reflecting surfaces for their manufacture |
DE10205007A1 (en) * | 2002-02-07 | 2003-08-21 | Creavis Tech & Innovation Gmbh | Process for the production of protective layers with dirt and water repellent properties |
DE10205783A1 (en) * | 2002-02-13 | 2003-08-21 | Creavis Tech & Innovation Gmbh | Molded articles with self-cleaning properties and process for producing such molded articles |
DE10205782A1 (en) * | 2002-02-13 | 2003-08-21 | Degussa | Shaped body with a self-cleaning surface and a surface structure with hills formed by structure forming particles useful for drinking vessels, storage vessels, storage barrels, spraying protection devices, and textiles |
DE10208208B4 (en) * | 2002-02-26 | 2012-03-08 | Eaton Industries Gmbh | Kit of several kit elements and a shaft |
DE10210027A1 (en) * | 2002-03-07 | 2003-09-18 | Creavis Tech & Innovation Gmbh | Hydrophilic surfaces |
DE10210668A1 (en) * | 2002-03-12 | 2003-09-25 | Creavis Tech & Innovation Gmbh | Device manufactured by injection molding, for storing liquids and processes for the production of this device |
DE10210673A1 (en) * | 2002-03-12 | 2003-09-25 | Creavis Tech & Innovation Gmbh | Injection molded body with self-cleaning properties and method for producing such injection molded body |
DE10210671A1 (en) * | 2002-03-12 | 2003-09-25 | Creavis Tech & Innovation Gmbh | Mold release agent which has hydrophobic, nanoscale particles and use of these mold release agents |
DE10210674A1 (en) * | 2002-03-12 | 2003-10-02 | Creavis Tech & Innovation Gmbh | Surface extrudates with self-cleaning properties and process for producing such extrudates |
DE10210666A1 (en) * | 2002-03-12 | 2003-10-02 | Creavis Tech & Innovation Gmbh | Shaping process for the production of moldings with at least one surface which has self-cleaning properties, and moldings produced using this process |
DE10231757A1 (en) | 2002-07-13 | 2004-01-22 | Creavis Gesellschaft Für Technologie Und Innovation Mbh | Process for the preparation of a surfactant-free suspension on an aqueous basis of nanostructured, hydrophobic particles and their use |
DE10242560A1 (en) * | 2002-09-13 | 2004-03-25 | Creavis Gesellschaft Für Technologie Und Innovation Mbh | Process for preparation of self-cleaning surfaces on coated flat textile structures useful for cladding technical textiles and structures obtained from these and production of raincoats and safety clothing with signaling effect |
DE10250328A1 (en) * | 2002-10-29 | 2004-05-13 | Creavis Gesellschaft Für Technologie Und Innovation Mbh | Production of suspensions of hydrophobic oxide particles |
DE10308379A1 (en) * | 2003-02-27 | 2004-09-09 | Creavis Gesellschaft Für Technologie Und Innovation Mbh | Dispersion of water in hydrophobic oxides for the production of hydrophobic nanostructured surfaces |
DE10315128A1 (en) * | 2003-04-03 | 2004-10-14 | Creavis Gesellschaft Für Technologie Und Innovation Mbh | Process for suppressing mold formation using hydrophobic substances and an anti-mold agent for parts of buildings |
DE50305348D1 (en) | 2003-04-24 | 2006-11-23 | Goldschmidt Gmbh | Process for the production of removable dirt and water repellent flat coatings |
DE10321851A1 (en) * | 2003-05-15 | 2004-12-02 | Creavis Gesellschaft Für Technologie Und Innovation Mbh | Use of particles hydrophobized with fluorosilanes for the production of self-cleaning surfaces with lipophobic, oleophobic, lactophobic and hydrophobic properties |
DE10347569A1 (en) * | 2003-10-14 | 2005-06-02 | Degussa Ag | Ceramic, flexible membrane with improved adhesion of the ceramic on the carrier fleece |
US8974590B2 (en) | 2003-12-18 | 2015-03-10 | The Armor All/Stp Products Company | Treatments and kits for creating renewable surface protective coatings |
US8034173B2 (en) | 2003-12-18 | 2011-10-11 | Evonik Degussa Gmbh | Processing compositions and method of forming the same |
US7828889B2 (en) * | 2003-12-18 | 2010-11-09 | The Clorox Company | Treatments and kits for creating transparent renewable surface protective coatings |
DE102004006612A1 (en) * | 2004-02-10 | 2005-08-25 | Degussa Ag | Compound ceramic wall coating comprises a carrier layer and at least one ceramic layer containing ceramic particles which are chosen from a group of oxides, nitrides, borides or carbides of metal or semi-metals |
US9096041B2 (en) | 2004-02-10 | 2015-08-04 | Evonik Degussa Gmbh | Method for coating substrates and carrier substrates |
US7517819B2 (en) | 2004-02-18 | 2009-04-14 | Milliken & Company | Dual function fabrics and method of making same |
US7213309B2 (en) | 2004-02-24 | 2007-05-08 | Yunzhang Wang | Treated textile substrate and method for making a textile substrate |
DE102004030202A1 (en) * | 2004-06-22 | 2006-01-19 | Polo Expressversand Gesellschaft für Motorradbekleidung & Sportswear mbH & Co. KG | Clothing for motorcyclists and textile accessories for motorcyclists |
DE102004036073A1 (en) | 2004-07-24 | 2006-02-16 | Degussa Ag | Process for sealing natural stones |
IL165219A (en) * | 2004-11-15 | 2008-12-29 | Delta Galil Ind Ltd | Moisture-management in hydrophilic fibers |
DE102004062740A1 (en) * | 2004-12-27 | 2006-07-13 | Degussa Ag | Process for increasing the water-tightness of textile fabrics, textile fabrics treated in this way and their use |
DE102004062743A1 (en) * | 2004-12-27 | 2006-07-06 | Degussa Ag | Process for increasing the water-tightness of textile fabrics, textile fabrics treated in this way and their use |
DE102004062742A1 (en) * | 2004-12-27 | 2006-07-06 | Degussa Ag | Textile substrates with self-cleaning properties (lotus effect) |
DE102004062739A1 (en) * | 2004-12-27 | 2006-07-06 | Degussa Ag | Self-cleaning surfaces with protrusions formed by hydrophobic particles, with improved mechanical strength |
US7757340B2 (en) | 2005-03-25 | 2010-07-20 | S.C. Johnson & Son, Inc. | Soft-surface remediation device and method of using same |
US7776108B2 (en) | 2005-06-07 | 2010-08-17 | S.C. Johnson & Son, Inc. | Composition for application to a surface |
US20080282642A1 (en) * | 2005-06-07 | 2008-11-20 | Shah Ketan N | Method of affixing a design to a surface |
US8061269B2 (en) | 2008-05-14 | 2011-11-22 | S.C. Johnson & Son, Inc. | Multilayer stencils for applying a design to a surface |
US7727289B2 (en) | 2005-06-07 | 2010-06-01 | S.C. Johnson & Son, Inc. | Composition for application to a surface |
US8557758B2 (en) | 2005-06-07 | 2013-10-15 | S.C. Johnson & Son, Inc. | Devices for applying a colorant to a surface |
US8846154B2 (en) * | 2005-06-07 | 2014-09-30 | S.C. Johnson & Son, Inc. | Carpet décor and setting solution compositions |
JP2008545897A (en) | 2005-06-07 | 2008-12-18 | エス.シー. ジョンソン アンド サン、インコーポレイテッド | How to remove stains on the surface |
US20070277849A1 (en) | 2006-06-06 | 2007-12-06 | Shah Ketan N | Method of neutralizing a stain on a surface |
DE102006001641A1 (en) * | 2006-01-11 | 2007-07-12 | Degussa Gmbh | Coating substrate, particularly wall paper, comprises e.g. applying composition containing inorganic compound comprising metal/half metal, silane-containg coating, coating containing biocidal and/or anti-microbial substances, and drying |
US8258206B2 (en) | 2006-01-30 | 2012-09-04 | Ashland Licensing And Intellectual Property, Llc | Hydrophobic coating compositions for drag reduction |
US20080221263A1 (en) * | 2006-08-31 | 2008-09-11 | Subbareddy Kanagasabapathy | Coating compositions for producing transparent super-hydrophobic surfaces |
IL175477A (en) * | 2006-05-08 | 2013-09-30 | Efraim Kfir | Assembly for lifting the sinus membrane for use in dental implant surgery |
DE102006027480A1 (en) * | 2006-06-14 | 2008-01-10 | Evonik Degussa Gmbh | Scratch and abrasion resistant coatings on polymeric surfaces |
IL178239A (en) * | 2006-09-21 | 2012-02-29 | Eduard Bormashenko | Method of manufacturing superhydrophobic nanotextured polymer or metal surfaces |
DE102007009590A1 (en) * | 2007-02-26 | 2008-08-28 | Evonik Degussa Gmbh | Shiny and scratch-resistant nail polish by adding sol-gel systems |
DE102007009589A1 (en) * | 2007-02-26 | 2008-08-28 | Evonik Degussa Gmbh | Shiny and scratch-resistant nail polish by addition of silanes |
US20090064894A1 (en) * | 2007-09-05 | 2009-03-12 | Ashland Licensing And Intellectual Property Llc | Water based hydrophobic self-cleaning coating compositions |
DE602008006450D1 (en) * | 2007-11-19 | 2011-06-01 | Du Pont | WORKED PLASTIC SURFACES WITH IMPROVED CLEANING PROPERTIES |
US8153834B2 (en) * | 2007-12-05 | 2012-04-10 | E.I. Dupont De Nemours And Company | Surface modified inorganic particles |
US8870839B2 (en) | 2008-04-22 | 2014-10-28 | The Procter & Gamble Company | Disposable article including a nanostructure forming material |
US11786036B2 (en) | 2008-06-27 | 2023-10-17 | Ssw Advanced Technologies, Llc | Spill containing refrigerator shelf assembly |
US8286561B2 (en) | 2008-06-27 | 2012-10-16 | Ssw Holding Company, Inc. | Spill containing refrigerator shelf assembly |
WO2010042191A1 (en) | 2008-10-07 | 2010-04-15 | Ross Technology Corporation | Highly durable superhydrophobic, oleophobic and anti-icing coatings and methods and compositions for their preparation |
KR101126195B1 (en) | 2009-08-14 | 2012-03-23 | 한국원자력연구원 | Kapok-polyethylene woven enhanced tensile strength and preparation method thereof |
US8147607B2 (en) * | 2009-10-26 | 2012-04-03 | Ashland Licensing And Intellectual Property Llc | Hydrophobic self-cleaning coating compositions |
WO2011056742A1 (en) | 2009-11-04 | 2011-05-12 | Ssw Holding Company, Inc. | Cooking appliance surfaces having spill containment pattern and methods of making the same |
US20110118686A1 (en) * | 2009-11-13 | 2011-05-19 | The Procter & Gamble Company | Substrate with adherence for feces and menses |
MX2012010669A (en) | 2010-03-15 | 2013-02-07 | Ross Technology Corp | Plunger and methods of producing hydrophobic surfaces. |
BR112013021231A2 (en) | 2011-02-21 | 2019-09-24 | Ross Tech Corporation | superhydrophobic and oleophobic coatings with low voc bonding systems |
DE102011085428A1 (en) | 2011-10-28 | 2013-05-02 | Schott Ag | shelf |
WO2013090939A1 (en) | 2011-12-15 | 2013-06-20 | Ross Technology Corporation | Composition and coating for superhydrophobic performance |
CA2878189C (en) | 2012-06-25 | 2021-07-13 | Ross Technology Corporation | Elastomeric coatings having hydrophobic and/or oleophobic properties |
US11840797B1 (en) | 2014-11-26 | 2023-12-12 | Microban Products Company | Textile formulation and product with odor control |
DE102015211634A1 (en) * | 2015-06-24 | 2016-12-29 | Aktiebolaget Skf | Injection molded part and method for producing an injection molded part |
US11098444B2 (en) | 2016-01-07 | 2021-08-24 | Tommie Copper Ip, Inc. | Cotton performance products and methods of their manufacture |
US11297888B2 (en) | 2016-01-15 | 2022-04-12 | Nike, Inc. | Garment with integral wipe zones |
US11412796B2 (en) | 2016-11-16 | 2022-08-16 | Nike, Inc. | Garment with wipe zones |
CN108642869B (en) * | 2018-04-12 | 2020-08-18 | 华南理工大学 | Preparation method of super-hydrophobic anti-ultraviolet fabric |
CA3128649A1 (en) * | 2019-03-05 | 2020-09-10 | Engineered Floors LLC | Stabilization of fabric surfaces |
US11730398B2 (en) | 2019-07-05 | 2023-08-22 | The Board Of Regents, The University Of Texas Syst | Motion powered wearable devices and uses thereof in health monitoring |
CN114134723A (en) * | 2021-12-08 | 2022-03-04 | 宜兴市伟业印染有限公司 | Dyed fabric with anti-fouling and self-cleaning functions and preparation process thereof |
Family Cites Families (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2350696A (en) * | 1941-06-12 | 1944-06-06 | British Cotton Ind Res Assoc | Woven structure resistant to penetration by water under pressure |
US3354022A (en) * | 1964-03-31 | 1967-11-21 | Du Pont | Water-repellant surface |
US4519410A (en) * | 1983-10-14 | 1985-05-28 | Kubacki Steven R | Tent construction |
GB2171484B (en) * | 1985-02-21 | 1989-11-29 | Ashimori Ind Co Ltd | A tubular lining material |
US5432000A (en) * | 1989-03-20 | 1995-07-11 | Weyerhaeuser Company | Binder coated discontinuous fibers with adhered particulate materials |
EP0772514B1 (en) * | 1994-07-29 | 1998-12-23 | Wilhelm Barthlott | Self-cleaning surfaces of objects and process for producing same |
US5908663A (en) | 1996-02-01 | 1999-06-01 | Minnesota Mining And Manufacturing Company | Topical carpet treatment |
DE19726802C1 (en) * | 1997-06-24 | 1998-06-10 | Dyneon Gmbh | Aqueous dispersion of different fluoro-polymers giving compact, thick film with high dielectric strength |
KR100228233B1 (en) * | 1997-07-25 | 1999-11-01 | 이윤재 | A fabric for tents and a process for preparing the same |
DE19913601C1 (en) * | 1999-03-25 | 2000-08-10 | Wilhelm Barthlott | Apparatus for transporting or discharging hydrophilic liquids has hydrophobic peaks or recesses on the side facing the liquid |
EP1171529B1 (en) * | 1999-03-25 | 2003-07-23 | Wilhelm Barthlott | Method of producing self-cleaning detachable surfaces |
DE19952383A1 (en) * | 1999-10-30 | 2001-05-17 | Henkel Kgaa | Detergents and cleaning agents |
DE20006010U1 (en) | 2000-03-31 | 2000-07-13 | Creavis Tech & Innovation Gmbh | Containers with structured liquid-repellent and liquid-wetting parts of the inner surface |
JP4097136B2 (en) * | 2000-06-14 | 2008-06-11 | ザ プロクター アンド ギャンブル カンパニー | Long-term durability coating for modifying hard surfaces and method of application |
US6455158B1 (en) * | 2000-06-16 | 2002-09-24 | Crompton Corporation | Treatment of minerals with alkylsilanes and alkylsilane copolymers |
DE10061920A1 (en) | 2000-12-13 | 2002-06-20 | Creavis Tech & Innovation Gmbh | Cation- / proton-conducting ceramic membrane based on a hydroxysilyl acid, process for its production and the use of the membrane |
DE10065797A1 (en) | 2000-12-30 | 2002-07-04 | Creavis Tech & Innovation Gmbh | Device for accelerating condensation using structured surfaces |
DE10100383A1 (en) | 2001-01-05 | 2002-07-11 | Degussa | Process for applying a fluoroalkyl functional organopolysiloxane coating with stable water and oil repellent properties to polymeric substrates |
DE10110589A1 (en) | 2001-03-06 | 2002-09-12 | Creavis Tech & Innovation Gmbh | Geometric shaping of surfaces with lotus effect |
DE10118352A1 (en) | 2001-04-12 | 2002-10-17 | Creavis Tech & Innovation Gmbh | Self-cleaning surfaces through hydrophobic structures and processes for their production |
DE10118349A1 (en) | 2001-04-12 | 2002-10-17 | Creavis Tech & Innovation Gmbh | Self-cleaning surfaces through hydrophobic structures and processes for their production |
DE10118351A1 (en) | 2001-04-12 | 2002-10-17 | Creavis Tech & Innovation Gmbh | Self-cleaning surfaces through hydrophobic structures and processes for their production |
DE10118345A1 (en) | 2001-04-12 | 2002-10-17 | Creavis Tech & Innovation Gmbh | Properties of structure formers for self-cleaning surfaces and the production of the same |
DE10134477A1 (en) | 2001-07-16 | 2003-02-06 | Creavis Tech & Innovation Gmbh | Self-cleaning surfaces through hydrophobic structures and processes for their production |
DE10139574A1 (en) | 2001-08-10 | 2003-02-20 | Creavis Tech & Innovation Gmbh | Maintaining the lotus effect by preventing microbial growth on self-cleaning surfaces |
DE10159767A1 (en) | 2001-12-05 | 2003-06-18 | Degussa | Process for the manufacture of articles with anti-allergic surfaces |
DE10160055A1 (en) | 2001-12-06 | 2003-06-18 | Degussa | Diffuse reflecting surfaces for their manufacture |
CN100335081C (en) * | 2002-01-26 | 2007-09-05 | Mst有限公司 | Composition containing moutan root bark extract as active ingredient |
DE10205007A1 (en) | 2002-02-07 | 2003-08-21 | Creavis Tech & Innovation Gmbh | Process for the production of protective layers with dirt and water repellent properties |
DE10205783A1 (en) | 2002-02-13 | 2003-08-21 | Creavis Tech & Innovation Gmbh | Molded articles with self-cleaning properties and process for producing such molded articles |
DE10208208B4 (en) | 2002-02-26 | 2012-03-08 | Eaton Industries Gmbh | Kit of several kit elements and a shaft |
DE10210027A1 (en) | 2002-03-07 | 2003-09-18 | Creavis Tech & Innovation Gmbh | Hydrophilic surfaces |
DE10210671A1 (en) | 2002-03-12 | 2003-09-25 | Creavis Tech & Innovation Gmbh | Mold release agent which has hydrophobic, nanoscale particles and use of these mold release agents |
DE10210666A1 (en) | 2002-03-12 | 2003-10-02 | Creavis Tech & Innovation Gmbh | Shaping process for the production of moldings with at least one surface which has self-cleaning properties, and moldings produced using this process |
DE10235758A1 (en) | 2002-08-05 | 2004-02-26 | Degussa Ag | Doped zinc oxide powder in aggregate form for use in e.g. electrically conductive lacquers and coatings, comprises doping component, e.g. aluminum oxide |
DE10311645A1 (en) | 2003-03-14 | 2004-09-23 | Degussa Ag | Mixed indium and tin oxide powder, used in coatings, solar cells, UV absorbers and medical technology, has increased electrical conductivity |
DE50305348D1 (en) | 2003-04-24 | 2006-11-23 | Goldschmidt Gmbh | Process for the production of removable dirt and water repellent flat coatings |
DE202006015495U1 (en) | 2006-10-09 | 2007-02-01 | Degussa Ag | Electroluminescence unit for articles equipped with electroluminescence unit e.g. articles of daily use and means of transport, has energy source, electronic control and electroluminescent foil in transparent casing |
DE102007009589A1 (en) | 2007-02-26 | 2008-08-28 | Evonik Degussa Gmbh | Shiny and scratch-resistant nail polish by addition of silanes |
-
2001
- 2001-04-12 DE DE10118346A patent/DE10118346A1/en not_active Ceased
-
2002
- 2002-02-26 ES ES02704724T patent/ES2272672T3/en not_active Expired - Lifetime
- 2002-02-26 CA CA002443743A patent/CA2443743A1/en not_active Abandoned
- 2002-02-26 AT AT02704724T patent/ATE339545T1/en active
- 2002-02-26 EP EP02704724A patent/EP1379725B1/en not_active Expired - Lifetime
- 2002-02-26 US US10/474,624 patent/US8629070B2/en not_active Expired - Fee Related
- 2002-02-26 DE DE50208141T patent/DE50208141D1/en not_active Expired - Lifetime
- 2002-02-26 WO PCT/EP2002/002013 patent/WO2002084016A1/en active IP Right Grant
Non-Patent Citations (1)
Title |
---|
See references of WO02084016A1 * |
Also Published As
Publication number | Publication date |
---|---|
DE50208141D1 (en) | 2006-10-26 |
US8629070B2 (en) | 2014-01-14 |
US20040154106A1 (en) | 2004-08-12 |
ES2272672T3 (en) | 2007-05-01 |
ATE339545T1 (en) | 2006-10-15 |
WO2002084016A1 (en) | 2002-10-24 |
CA2443743A1 (en) | 2002-10-24 |
EP1379725B1 (en) | 2006-09-13 |
DE10118346A1 (en) | 2002-10-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1379725B1 (en) | Flat textile structures with self-cleaning and water-repellent surfaces | |
EP1674611A1 (en) | Process for increasing the water impermeability of textile fabrics, so treated products and use thereof | |
EP1472011A1 (en) | Method for the production of protective layers with dirt and water repelling properties | |
EP1674609A1 (en) | Process for increasing the water impermeability of textile fabrics, so treated products and use thereof | |
DE10159767A1 (en) | Process for the manufacture of articles with anti-allergic surfaces | |
EP2444545B1 (en) | Water, oil and dirt repellent finishing on fibres and textile area-measured material | |
DE10205783A1 (en) | Molded articles with self-cleaning properties and process for producing such molded articles | |
EP1623066B1 (en) | Use of particles hydrophobized by fluorosilanes for the production of self-cleaning surfaces having lipophobic, oleophobic, lactophobic and hydrophobic properties | |
WO2004033788A1 (en) | Production of self-cleaning surfaces on textile coatings | |
WO2009027432A1 (en) | Photoactive tio2 in coating materials | |
EP1525285A1 (en) | Method for the flame spray coating of surfaces with powder to create the lotus effect | |
WO2002084013A2 (en) | Polymer fiber having a self-cleaning and water-repellent surface | |
WO2003008697A2 (en) | Method for applying a self-cleaning coating to textile materials | |
EP1989353B1 (en) | Non-wettable surfaces | |
Kim | Nanotechnology-based advanced coatings and functional finishes for textiles | |
EP3697958B1 (en) | Method for producing a textile article with hydrophobised textile surface using plasma treatment and wet chemical processing | |
DE102012002954B4 (en) | Use of a microfilament nonwoven fabric as a textile UV light protection material | |
EP2061926B1 (en) | Textile product and production thereof | |
DE10129116A1 (en) | Polymer fibers containing surface particles and having very good self-cleaning properties, useful for the preparation of covering elements subjected to high loads, e.g. dirt and water | |
WO2004014575A1 (en) | Method for powder coating surfaces in order to produce the lotus effect | |
WO2003106061A1 (en) | Method for producing surfaces having coagulation-inhibiting properties | |
DD150765A1 (en) | METHOD FOR PRODUCING IMPROVED BICOMPONENT FIBROUSES ON ACRYLNITRILE POLYME BASE |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20030912 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR |
|
AX | Request for extension of the european patent |
Extension state: AL LT LV MK RO SI |
|
17Q | First examination report despatched |
Effective date: 20040506 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: DEGUSSA AG |
|
GRAJ | Information related to disapproval of communication of intention to grant by the applicant or resumption of examination proceedings by the epo deleted |
Free format text: ORIGINAL CODE: EPIDOSDIGR1 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED. Effective date: 20060913 Ref country code: IE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20060913 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20060913 |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: NV Representative=s name: SCHMAUDER & PARTNER AG PATENTANWALTSBUERO Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
REF | Corresponds to: |
Ref document number: 50208141 Country of ref document: DE Date of ref document: 20061026 Kind code of ref document: P |
|
GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) |
Effective date: 20061102 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20061213 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20061213 |
|
RAP2 | Party data changed (patent owner data changed or rights of a patent transferred) |
Owner name: DEGUSSA GMBH |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20070228 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070302 |
|
ET | Fr: translation filed | ||
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FD4D |
|
NLT2 | Nl: modifications (of names), taken from the european patent patent bulletin |
Owner name: DEGUSSA GMBH Effective date: 20070221 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2272672 Country of ref document: ES Kind code of ref document: T3 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20070614 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20061214 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PCAR Free format text: SCHMAUDER & PARTNER AG PATENT- UND MARKENANWAELTE VSP;ZWAENGIWEG 7;8038 ZUERICH (CH) |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20060913 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20060913 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PFA Owner name: EVONIK DEGUSSA GMBH Free format text: DEGUSSA AG#BENNIGSENPLATZ 1#40474 DUESSELDORF (DE) -TRANSFER TO- EVONIK DEGUSSA GMBH#RELLINGHAUSER STRASSE 1-11#45128 ESSEN (DE) |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: CD Ref country code: FR Ref legal event code: CA |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: SD Effective date: 20100223 Ref country code: NL Ref legal event code: TD Effective date: 20100223 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: LU Payment date: 20140220 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 20140218 Year of fee payment: 13 Ref country code: DE Payment date: 20140219 Year of fee payment: 13 Ref country code: NL Payment date: 20140218 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20140226 Year of fee payment: 13 Ref country code: IT Payment date: 20140225 Year of fee payment: 13 Ref country code: FR Payment date: 20140219 Year of fee payment: 13 Ref country code: AT Payment date: 20140212 Year of fee payment: 13 Ref country code: BE Payment date: 20140218 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20140218 Year of fee payment: 13 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150228 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 50208141 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: V1 Effective date: 20150901 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150226 Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150901 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MM01 Ref document number: 339545 Country of ref document: AT Kind code of ref document: T Effective date: 20150226 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20150226 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150228 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150228 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST Effective date: 20151030 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150226 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150226 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150901 Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150226 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150302 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20160331 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150227 |