EP1375430A4 - Refractory material, method for production thereof and refractory using the material - Google Patents

Refractory material, method for production thereof and refractory using the material

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Publication number
EP1375430A4
EP1375430A4 EP02702769A EP02702769A EP1375430A4 EP 1375430 A4 EP1375430 A4 EP 1375430A4 EP 02702769 A EP02702769 A EP 02702769A EP 02702769 A EP02702769 A EP 02702769A EP 1375430 A4 EP1375430 A4 EP 1375430A4
Authority
EP
European Patent Office
Prior art keywords
refractory
carbon black
refractories
raw material
grains
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP02702769A
Other languages
German (de)
French (fr)
Other versions
EP1375430A1 (en
EP1375430B1 (en
Inventor
Tsunemi Ochiai
Shigeyuki Takanaga
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
OCHIAI, TSUNEMI EN KYUSHU REFRACTORIES CO., LTD.
Original Assignee
Kyushu Refractories Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2001065369A external-priority patent/JP4227734B2/en
Priority claimed from JP2001118216A external-priority patent/JP3971899B2/en
Application filed by Kyushu Refractories Co Ltd filed Critical Kyushu Refractories Co Ltd
Publication of EP1375430A1 publication Critical patent/EP1375430A1/en
Publication of EP1375430A4 publication Critical patent/EP1375430A4/en
Application granted granted Critical
Publication of EP1375430B1 publication Critical patent/EP1375430B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/52Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
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    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64Burning or sintering processes
    • C04B35/65Reaction sintering of free metal- or free silicon-containing compositions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
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    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/013Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics containing carbon
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    • C04B35/03Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite
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Abstract

Refractories obtained by molding a refractory raw material composition containing a refractory raw material including graphite grains having an average grain size of 500 nm or less or a refractory raw material including graphite grains obtained by graphitizing carbon black and a refractory filler, Or refractories containing carbonaceous grains (A) selected from carbon black or graphite grains obtained by graphitizing carbon black and having a DBP absorption (x) of 80 ml/100 g or more, carbonaceous grains (B) selected from carbon black and graphite grains obtained by graphitizing carbon black and having a DBP absorption (x) of less than 80 ml/100 g, and a refractory filler. Refractories excellent in corrosion resistance, oxidation resistance and thermal shock resistance, especially carbon-contained refractories having a low carbon content are thereby provided. <IMAGE>
EP02702769A 2001-03-08 2002-03-06 Refractory material Expired - Lifetime EP1375430B1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP2001065369A JP4227734B2 (en) 2001-03-08 2001-03-08 Refractory raw material, refractory raw material composition, refractory, and method for producing graphite particles usable for them
JP2001065369 2001-03-08
JP2001118216A JP3971899B2 (en) 2001-04-17 2001-04-17 Refractory raw material composition, method for producing the same, and refractory formed by molding the same
JP2001118216 2001-04-17
PCT/JP2002/002086 WO2002072476A1 (en) 2001-03-08 2002-03-06 Refractory material, method for production thereof and refractory using the material

Publications (3)

Publication Number Publication Date
EP1375430A1 EP1375430A1 (en) 2004-01-02
EP1375430A4 true EP1375430A4 (en) 2005-04-20
EP1375430B1 EP1375430B1 (en) 2007-06-13

Family

ID=26610893

Family Applications (1)

Application Number Title Priority Date Filing Date
EP02702769A Expired - Lifetime EP1375430B1 (en) 2001-03-08 2002-03-06 Refractory material

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US (1) US7060642B2 (en)
EP (1) EP1375430B1 (en)
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Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002265211A (en) * 2001-03-08 2002-09-18 Tsunemi Ochiai Production process of graphite particle and refractory using the same
CN100416710C (en) * 2004-11-26 2008-09-03 比亚迪股份有限公司 Carbon oil for producing carbon impedance, its production and carbon impedance component
BRPI0608165B8 (en) 2005-04-19 2021-04-20 Krosaki Harima Corp refractory and its production method, materials of the refractory
EP1912101B1 (en) * 2005-07-21 2016-11-16 Canon Kabushiki Kaisha Developer carrier and developing device
DE102007011133B4 (en) * 2007-03-07 2013-02-28 Refratechnik Holding Gmbh Refractory carbonaceous magnesia brick and process for its preparation
WO2009002586A2 (en) 2007-04-13 2008-12-31 Cornerstone Research Group, Inc. Composite self-healing system
CN109153862B (en) 2016-05-19 2021-05-11 锡克拜控股有限公司 Method and formulation for impregnation of porous materials
CN107244924B (en) * 2017-03-23 2019-08-20 武汉科技大学 A kind of high micropore electric forging coal base brick fuel of high thermal conductivity and preparation method thereof
CN107884153B (en) * 2017-10-24 2020-05-12 中国运载火箭技术研究院 Structure for simulating high-speed pneumatic denudation process
CN113773673A (en) * 2021-10-25 2021-12-10 江西威尔士科技发展有限公司 Carbon black graphitization modification method

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1516718A (en) * 1963-02-22 1968-02-05 Pechiney Prod Chimiques Sa Very low permeability carbon products
US3926857A (en) * 1971-11-08 1975-12-16 Atomic Energy Authority Uk Electrically conducting material containing silicon carbide in a matrix of silicon nitride
JPH04367556A (en) * 1991-06-13 1992-12-18 Harima Ceramic Co Ltd Magnesia-carbon brick
US5246897A (en) * 1991-08-09 1993-09-21 Asahi Glass Company Ltd. Powder mixture for monolithic refractories containing graphite and a method of making thereof
JPH05301772A (en) 1992-04-24 1993-11-16 Kyushu Refract Co Ltd Carbon-containing brick
JP2596700B2 (en) * 1993-06-30 1997-04-02 黒崎窯業株式会社 Specific carbon-containing irregular refractories
JP3390773B2 (en) * 1994-03-30 2003-03-31 黒崎播磨株式会社 Conductive antioxidant for graphite electrodes
JP3224990B2 (en) * 1996-07-23 2001-11-05 品川白煉瓦株式会社 Blast furnace taphole plugging material
US6037400A (en) * 1997-08-25 2000-03-14 Hitachi Maxell, Ltd Composition for prevention of electric wave in wide range and electric wave absorber coping with all directions using same
JP3638081B2 (en) 1998-05-12 2005-04-13 品川白煉瓦株式会社 Refractory material containing low carbonaceous carbon and method for producing the same
JP2000086334A (en) 1998-09-09 2000-03-28 Kurosaki Refract Co Ltd Brick for sliding nozzle apparatus
JP2000192120A (en) 1998-12-24 2000-07-11 Shinagawa Refract Co Ltd Plugging material in iron tapping hole
JP2000273351A (en) * 1999-03-23 2000-10-03 Osaka Gas Co Ltd Preparation of graphitized carbon black
US6780388B2 (en) * 2000-05-31 2004-08-24 Showa Denko K.K. Electrically conducting fine carbon composite powder, catalyst for polymer electrolyte fuel battery and fuel battery

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
No further relevant documents disclosed *

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KR100914788B1 (en) 2009-09-02
DE60220656D1 (en) 2007-07-26
US20040106509A1 (en) 2004-06-03
WO2002072476A1 (en) 2002-09-19
US7060642B2 (en) 2006-06-13
CN1262516C (en) 2006-07-05
ATE364578T1 (en) 2007-07-15
RU2003129806A (en) 2005-04-10
BR0204468B1 (en) 2011-05-17
RU2294945C2 (en) 2007-03-10
BR0204468A (en) 2003-04-01
DE60220656T2 (en) 2008-02-21
KR20030004386A (en) 2003-01-14
EP1375430A1 (en) 2004-01-02
CN1461284A (en) 2003-12-10
EP1375430B1 (en) 2007-06-13

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