EP1274568A2 - Lamine multi-dimensions taille sur mesure - Google Patents

Lamine multi-dimensions taille sur mesure

Info

Publication number
EP1274568A2
EP1274568A2 EP01923434A EP01923434A EP1274568A2 EP 1274568 A2 EP1274568 A2 EP 1274568A2 EP 01923434 A EP01923434 A EP 01923434A EP 01923434 A EP01923434 A EP 01923434A EP 1274568 A2 EP1274568 A2 EP 1274568A2
Authority
EP
European Patent Office
Prior art keywords
skins
structural laminate
recited
structural
fibrous core
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01923434A
Other languages
German (de)
English (en)
Inventor
David D'arcy Clifford
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ArcelorMittal Dofasco Inc
Original Assignee
Dofasco Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dofasco Inc filed Critical Dofasco Inc
Publication of EP1274568A2 publication Critical patent/EP1274568A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J5/00—Doors
    • B60J5/04—Doors arranged at the vehicle sides
    • B60J5/0463—Conceptual assembling of door, i.e. how door frame parts should be fitted together to form door
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J5/00—Doors
    • B60J5/04—Doors arranged at the vehicle sides
    • B60J5/048—Doors arranged at the vehicle sides characterised by the material
    • B60J5/0481—Doors arranged at the vehicle sides characterised by the material plastic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J5/00—Doors
    • B60J5/04—Doors arranged at the vehicle sides
    • B60J5/048—Doors arranged at the vehicle sides characterised by the material
    • B60J5/0483—Doors arranged at the vehicle sides characterised by the material lightweight metal, e.g. aluminum, magnesium

Definitions

  • the present invention relates to laminate structural panels and, more specifically, to light-weight laminates having desirable structural characteristics.
  • Vehicle bodies commonly include metal panels which are selected for properties such as strength and stiffness, formability, corrosion resistance, weldability, impact resistance, and the like, according to the intended location of the panel on a vehicle.
  • the selected metal panel may be a specialized alloy, have had custom heat treatments and may have to be joined, for example by welding or with fasteners to other metals in order to provide the desired properties in selected zones.
  • steel is used extensively in motor vehicles to form panels and other structures. It will be appreciated by those skilled in the art that the required structural characteristics, such as stiffness, vary depending upon the specific application. When higher stiffness values are required for steel, the thickness is typically increased. Increasing steel thickness, however, produces a panel or part which is not only heavier, but is also more expensive.
  • the inventor of the present invention discloses structural panels which are laminate structures having metals skins separated by and bonded to an intervening fibrous core.
  • the laminates described therein have very high specific stiffness and are comparatively light weight. As described therein, however, the placement of the fibrous core is continuous with the metal skins. In some applications, the presence of the core may interfere with fasteners, welds or clearance openings and their methods of formation. It would be desirable to provide a light weight structural laminate which could be customized to accommodate specific fastening, welding and clearance opening operations. The present invention meets these and other desirable goals.
  • a structural laminate having a profile which varies compositionally along the laminate body.
  • the laminate has first and second skins of sheet metal.
  • a fibrous paper core layer is provided between the sheet metal skins and is bonded to the skins.
  • the fibrous paper core layer is impregnated with an adhesive resin which bonds the core layer directly to the skins.
  • layers of adhesive are placed between the core material and the skins to bond the core to the skins.
  • the core is non-uniform in cross- section, having a profile which is "tailored" for a desired application.
  • this non-uniform profile may allow fasteners or fixtures to pass through the laminate or facilitate the placement of clearance holes.
  • the resulting tailored laminate structure is ext remely lightweight compared to a single steel sheet of comparable thickness and strength.
  • a method of forming a tailored structural laminate includes the steps of placing a fibrous core of paper material between two metal skins, the fibrous core covering less than the entire adjacent skin surfaces, i.e., along the edge of the laminates there is a gap or space between the two metal skins as described in the preceding paragraph. Pressure is applied to the tailored laminate to promote bonding between the core and the metal skins. In one aspect a number of laminates are prepared which are then stacked one upon another and are then pressed to simultaneously bond the individual layers.
  • Figure 1 is a cross-section of the laminate of the present invention.
  • Figure 2 is a plan view of the laminate of Figure 1.
  • Figure 3 is the laminate of the invention in another configuration.
  • Figure 4 is a diagram depicting a die press forming the laminate of the invention.
  • Figure 5 illustrates a door panel
  • non-uniform or tailored laminate panel 20 is shown having metal skins 22 and intervening region 23 in which fibrous core 24 is seen.
  • fibrous core 24 in this embodiment, is recessed from each edge 25 of panel 20.
  • an unfilled gap or space 27 exists between portions of opposed metal skins 22.
  • the space is in the shape of a channel extending completely around the perimeter of panel 20.
  • the area oi space 27 may vary widely, but will typically be at least 1 square inch. It will be seen that the composition of panel 20 varies along axis 21 as indicated by arrows A and B.
  • gap 27 in panel 20 will vary depending on the intended application for the laminate panel or part; gap 27 may occur at one or more edges of panel 20, may be located solely in the interior regions of panel 20 (i.e., as a hole cut in the center of core 24 or may have an irregular shape to accommodate a specific application. Core 24 may be discontinous, for example forming separate strips or the like.
  • metal skins 22 generally will be flat having planar surfaces on each side.
  • Metals which may be utilized to form skins 22 are preferably selected from the group consisting of steel, aluminum, copper alloys and various combinations thereof. Metals which provide adequate structural and (if required) corrosion resistance properties in the specific environment in which panel 20 is used, at the lowest cost, are most desirable.
  • skins 22 are most preferably formed of zinc coated steel, with each layer 22 having a thickness of about .005 inch or greater, preferably from between about .005 inch and about .030 inch and more preferably from about .005 inch to about 0.012 inch in thickness.
  • interveningfibrous layer 24 preferably has a thickness of from about .01 inch and greater and preferably from about .01 inch to about .05 inch.
  • the overall thickness of panel 20 in one embodiment will typically be between about 0.020 inch and about 0.1 10 inch.
  • a panel having the dimensions set forth above in the description of Figure 1 of the drawings and having the preferred layer thicknesses just described will typically have weight that is about 40 - 70% of the weight of a single sheet of steel of comparable dimensions and stiffness.
  • steel comes in a number of grades based on the amount of carbon and other elements which it contains. Broadly these grades can be described as low carbon steel, medium steel and high carbon steel. Preferred for use herein are low carbon steel and low carbon micro-alloyed high- strength steel (HSLA).
  • the most preferred metal skins for use in the present invention are cold rolled steel, galvanized steel, tin coated steel, and stainless steel. It may be desirable to utilize single sided galvanized sheet with a galvanized surface comprising the outer surface of skins 22 with the inner surfaces of the skins being bare metal for adhesion purposes.
  • differential zinc coating is preferred, i.e. a light zinc coating on the inside surface and a heavier zinc coating on the outer surface.
  • zinc coated steel is cold rolled with zinc on the surface to the final thickness.
  • layer 24 is a fibrous material.
  • fibrous As used herein, the term "fibrous,” without limiting its scope in the context of the invention, is intended to mean a generally homogeneous collection of fibers, either natural or synthetic, which can be formed into a sheet product.
  • paper As will be appreciated by those skilled in the art, paper is essentially a matted or felted structure of fibrous material formed into a relatively thin sheet through the medium of a dilute suspension of pulp and water. It is composed essentially of cellulose fibers. Pulp for paper making can be prepared by grinding wood or other plant matter mechanically, by chemical processing (sulfite, kraft, or soda) and also by chemically treating cotton, linen and hemp rags, waste, straw, and the like.
  • paper formed using the kraft process is most preferred. It will be appreciated by those skilled in the art that the kraft process (which may also be referred to as sulphate pulping or alkaline process) results in papers of high physical strength and bulk.
  • One preferred paper is sold as saturating kraft paper, by Westvaco, of Charleston, S.C.
  • the average alignment of cellulose fibers in paper is controlled somewhat by the "machine direction" during production of the paper. It is believed that in the present invention the orientation of the paper in the laminates is a factor which may affect the stiffness and strength of the laminate. Most preferred are laminates where the machine direction of the kraft paper is a line parallel to a neutral axis of bending of the laminate.
  • Another class of fibrous materials for use herein is plastic-fiber paper.
  • layer 24 is provided as a resin-impregnated fibrous material. Where layer 24 is kraft paper, the paper is saturated with a resin which is then dried. Most preferred for use herein is phenolic resin-impregnated kraft paper.
  • Polyester resin impregnation may also be suitable in some applications.
  • Methods of impregnating paper with resin will be well-known to those skilled in the art.
  • the preferred resin-impregnated paper is formed by immersing a substrate paper web in liquid phenolic resin.
  • layers of saturated impregnated paper are layered together to form a single layer of semi-cured impregnated paper.
  • resin constitutes from about 15% to about 45% by weight of resin-impregnated layer 24.
  • thermosetting resins are preferred for use in impregnating paper layer 24, although in some applications thermoplastic resins may be acceptable.
  • the resin will generally be cured to B-stage prior to forming panel 20, but it may be possible to fully cure the impregnated paper prior to the laminate pressing operation (controlled heat and pressure) described below.
  • the resin is cured to B-stage prior to lamination. It is then fully cured as skins 22 and impregnated paper core 24 are laminated together using the press. It may be suitable in some applications to include a number of standard additives in the resin such as curing agents, fillers and the like.
  • a layer of adhesive to bond skins 22 to fibrous core 24.
  • a number of adhesives may be suitable in specific applications, including epoxies, phenolics, isocyanates, polyurethanes, and hot-melts.
  • a particularly preferred adhesive for this purpose is a nitrile phenolic sold as "Arofene 1 166" from Ashland Chemical.
  • the adhesive may be applied directly to layer 24 or to metal skins 22 or both by any number of methods. It is preferred to pretreat the steel with a conversion coating such as a complex oxide or zinc phosphate to improve bond integrity and corrosion resistance.
  • edge strips 28 are provided which are of a different material than that of fibrous core
  • Strips 28 may constitute a single strip aroundthe outer perimeter of panel 20.
  • fibrous layer 24 may have a plurality of holes (not shown) extending therethrough; these holes may provide adhesive "bridges" as more fully described in the aforereferenced U.S. Patent No. 5,985,457.
  • Press 30 includes platens 32 which move towards one another in the customary manner using hydraulics or the like. Platens 32 are preferably heatable so both heat and pressure can be applied to the laminates to cure the resin and bond the adhesive as more fully described in copending United States Patent Application Serial No. 09/373,298 filed August 12, 1999, entitled, "IMPROVED STRUCTURAL PANEL AND METHOD OF MANUFACTURE", the entire disclosure of which is incorporated herein by reference.
  • metal/fiber/metal laminates may be stacked and pressed as described in the immediately preceding U.S. Patent Application Serial No. 373,298. After the pressed stack has cooled, it is removed from the press, individual panels are then separated.
  • the laminate panels of the present invention may substitute for a metal section which is not a flat sheet. Therefore, as described in the immediately preceding U.S. Patent Application Serial No. 373,298, parts having non-planar geometries my benefit from the tailored laminate approach of the present invention.
  • Such a multi-dimensional laminate 20 may find application for use as a door panel 34 shown in Figure 4.
  • the body of the door panel 34 designated by numeral 36 may comprise a stiff, lightweight composite material comprising outer metal skins made of steel and an inner core made of paper of the kind described herein.
  • the door panel 34 has forward and rear edge portions designated 38, 40 which comprise outer skins of steel and an inner core made of high strength steel suitable for welding. Adjacent to an opening 42 formed in the door panel 34 to create a window, there is an area designated by reference numeral 44 which will be deformed to create a recess associated with a door handle (not shown) and comprises outer skins of steel and an inner core made of thermoplastic material which may sustain strains of up to 30%.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

Une matière à noyau fibreux est disposée entre une partie de deux peaux métalliques opposées et y est liée pour former un laminé structurel dont la résistance est comparable à celle des feuilles d'acier ayant un poids plus important et possédant un profil dont la composition varie dans les différentes régions du laminé.
EP01923434A 2000-04-07 2001-04-09 Lamine multi-dimensions taille sur mesure Withdrawn EP1274568A2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US54496300A 2000-04-07 2000-04-07
US544963 2000-04-07
PCT/CA2001/000497 WO2001076864A2 (fr) 2000-04-07 2001-04-09 Lamine multi-dimensions taille sur mesure

Publications (1)

Publication Number Publication Date
EP1274568A2 true EP1274568A2 (fr) 2003-01-15

Family

ID=24174310

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01923434A Withdrawn EP1274568A2 (fr) 2000-04-07 2001-04-09 Lamine multi-dimensions taille sur mesure

Country Status (9)

Country Link
EP (1) EP1274568A2 (fr)
JP (1) JP2003530246A (fr)
KR (1) KR20020084298A (fr)
CN (1) CN1422209A (fr)
AU (2) AU5020701A (fr)
BR (1) BR0109888A (fr)
CA (1) CA2405410A1 (fr)
MX (1) MXPA02009899A (fr)
WO (1) WO2001076864A2 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102844178B (zh) * 2010-02-15 2015-09-16 多产研究有限责任公司 可成型的轻质复合材料体系及方法
JP6622563B2 (ja) * 2015-10-29 2019-12-18 京セラ株式会社 積層体
CN105690918A (zh) * 2016-04-06 2016-06-22 华精密机械（昆山）有限公司 一种汽车车门冲压件
SE541379C2 (en) * 2017-03-17 2019-09-10 Lamera Ab Composite material and method for production of the same
CN107757320A (zh) * 2017-10-17 2018-03-06 奇瑞汽车股份有限公司 一种车门防撞板及制备方法、车门
KR102031448B1 (ko) * 2017-12-24 2019-10-11 주식회사 포스코 복합재료 강판

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US3783082A (en) * 1971-03-31 1974-01-01 E Almog Panels and method of making same
US4514450A (en) * 1983-11-01 1985-04-30 Union Carbide Corporation Peg supported thermal insulation panel
US5030488A (en) * 1988-11-23 1991-07-09 Chemical And Polymer Technology, Inc. Laminates, panels and means for joining them
US5402615A (en) * 1992-11-13 1995-04-04 International Copper Association, Ltd. Fire retardant barrier system and method
DE4434217A1 (de) * 1994-09-26 1996-03-28 Duerrwaechter E Dr Doduco Halbzeug oder Fertigteil aus einem Schichtwerkstoff für Zwecke der elektrischen Stromleitung und/oder elektrischen Kontaktgabe
DE29518473U1 (de) * 1995-11-21 1996-01-25 Promat Gmbh Plattenförmiges Hochtemperatur-Wärmedämmelement
US6021220A (en) * 1997-02-11 2000-02-01 Silicon Biology, Inc. System and method for pattern recognition
EP1196281B1 (fr) * 1999-06-29 2007-03-21 Dofasco Inc. Paroi de vehicule de charge

Non-Patent Citations (1)

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Title
See references of WO0176864A2 *

Also Published As

Publication number Publication date
WO2001076864A2 (fr) 2001-10-18
MXPA02009899A (es) 2004-02-26
KR20020084298A (ko) 2002-11-04
WO2001076864A3 (fr) 2002-02-28
JP2003530246A (ja) 2003-10-14
BR0109888A (pt) 2003-06-03
CA2405410A1 (fr) 2001-10-18
CN1422209A (zh) 2003-06-04
AU2001250207B2 (en) 2006-11-09
AU5020701A (en) 2001-10-23

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