EP1237974B1 - Stabile pulverlackbeschichtungszusammensetzungen - Google Patents
Stabile pulverlackbeschichtungszusammensetzungen Download PDFInfo
- Publication number
- EP1237974B1 EP1237974B1 EP00966963A EP00966963A EP1237974B1 EP 1237974 B1 EP1237974 B1 EP 1237974B1 EP 00966963 A EP00966963 A EP 00966963A EP 00966963 A EP00966963 A EP 00966963A EP 1237974 B1 EP1237974 B1 EP 1237974B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- powder coating
- coating composition
- component
- cycloaliphatic
- employed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
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- 229910052570 clay Inorganic materials 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000007590 electrostatic spraying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000008397 galvanized steel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 235000019382 gum benzoic Nutrition 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229940086542 triethylamine Drugs 0.000 description 1
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/8064—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with monohydroxy compounds
- C08G18/8067—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with monohydroxy compounds phenolic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/423—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing cycloaliphatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
- C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
- C08G18/8009—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
- C08G18/8012—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203 with diols
- C08G18/8016—Masked aliphatic or cycloaliphatic polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2150/00—Compositions for coatings
- C08G2150/20—Compositions for powder coatings
Definitions
- the present invention relates to powder coating compositions. Prior to being cured, these powder coating compositions possess excellent anti-caking stability. After being cured, these powder coating compositions produce consistent finishes.
- Coating compositions have long been used to provide the surface of articles with certain desired physical characteristics such as color, gloss and durability.
- most coating compositions relied upon a liquid carrier which evaporated after the composition was applied.
- VOCs Volatile Organic Compounds
- an electrostatic charge is often applied between the application device (e.g. , the spray gun) and the item to be painted. This results in the powder coating's attraction and adherence to the desired substrate.
- the powder coating After being applied, the powder coating is cured. Typically, this is achieved by heating the coated substrate to an elevated temperature (e.g. , a temperature between 50°C. and 400°C.). During the curing process, the powder particles melt and spread, while the components of the powder coating crosslink. In addition to not emitting any VOCs into the environment during the application or curing processes, such a powder coating system is extremely efficient since there is essentially no waste (i.e., application yield is approximately 100 percent).
- an elevated temperature e.g. , a temperature between 50°C. and 400°C.
- Powder coating systems are well known to those skilled in the art.
- the term "powder” includes not only materials with a relatively small particle size, but also those with larger sizes, such as granules.
- the average particle size of most power coating systems are in the range from about 0.1 to about 500 microns; and more commonly, from about 0.5 to about 100 microns.
- Powder coating systems have been used commercially to impart high and low gloss finishes to surfaces. Notwithstanding the aforementioned advantages, certain problems encountered by the coating manufacturers, transporters and applicators have hindered their widespread use and acceptance.
- uncured powder coatings have an average particle size distribution ranging from about 0.5 to about 100 microns. Powders with such a particle size distribution are often unstable.
- the term "unstable” as used herein refers to the particles of a powder coating having a tendency to clump or "cake" when exposed to small amounts of moisture, even as low as that resulting merely from elevated humidity conditions. To avoid this phenomenon from occurring, powder coating formulators, transporters and applicators all have to take special, and often costly, handling precautions. Accordingly, coating manufacturers continually strive to formulate powder coating compositions that are more stable (i. e., powder coatings that resist caking)
- US-A-4,404,320 discloses a powder coating composition comprising a film-forming resin system.
- the film-forming resin system comprises a crosslinker component which is a blocked polyisocyanate and a polyester polyol comprising the reaction product of hexahydrophtalic acid and cyclohexane dimethanol.
- a polyester resin composition suitable for preparing a powder paint obtained by mixing a polyester, which is obtained by depolymerizing a polyester having a high degree of polymerization with an intrinsic viscosity of about 0.4 or more with at least one of a substantially non-volatile alcohol and an ester having at least one alcoholic hydroxyl group in the same molecule, melts at a temperature between (about) 45°C and (about) 120°C and has terminal hydroxyl groups and an average degree of polymerization ranging from about 5 to about 50, with a polyisocyanate blocked with an alkyl p-hydroxybenzoate by melting, is known.
- One object of the present invention is to provide powder coating compositions that, when uncured, resists caking.
- Another object of the present invention is to provide powder coating compositions that, when cured, produce consistent low gloss finishes.
- a powder coating composition comprising a film forming resin system, wherein said film forming resin system comprises:
- the powder coating compositions of the present invention include a novel film forming system.
- film forming resin system includes: 1) a polymer component capable of forming a film; 2) a crosslinker component; and optionally, 3) a catalyst component, if necessary, to facilitate the reaction between the polymer component and a crosslinker component.
- the film forming systems' crosslinker component includes a crosslinking agent.
- This crosslinking agent comprises a polyfunctional isocyanate which is at least partially blocked with a mixture a mixture of a polyhydroxy aromatic compound and a hydroxy-functional ester compound. These blocking agents will be described below in more detail.
- Any suitable polyfunctional isocyanates can be employed when practicing this invention, provided that they participate in sufficiently crosslinking the film forming resin's polymer component.
- the polyfunctional isocyanate is derived from a polyisocyanate (i.e., an isocyanate possessing at least two isocyanate functions, advantageously more than two) which is itself typically derive from a precondensation or from a prepolymerization of elemental isocyanates.
- Elemental isocyanates include those made of hydrocarbon skeletons having at least two isocyanate functions. These hydrocarbon skeletons are often an arylene radical, an alkylene radical (including an aralkylene radical) such as the polymethylenes (e.g., hexamethylene), or the necessary to form isophorone diisocyanate (IPDI).
- the hydrocarbon skeletons may also be alkyl(s) or arylic.
- the atomic weight of these elemental isocyanates is advantageously at most 500; and preferably at most 300. Moreover, the average molecular weights of the prepolymers or precondensates is not more than 5000; and more commonly not more than 3000.
- the polyisocyanates that may be used when practicing this invention include those of the biuret type and those for which the di- or trimerization reaction has produced four-, five- or six-membered rings.
- the isocyanuric rings derived from a homo- or hetero- trimerization of various diisocyanates alone, with other isocyanate(s) ( e.g. , mono-, di- or polyisocyanate(s)) or with carbon dioxide. In this latter case, a nitrogen from the isocyanuric ring is replaced by an oxygen.
- the polyisocyanates which can be employed include those which have at least one aliphatic isocyanate function.
- at least one isocyanate function blocked in accordance with this invention is attached to the hydrocarbon skeleton via an sp 3 -type carbon advantageously bearing at least one hydrogen atom, preferably two.
- the preferred isocyanates are those wherein the nitrogen atom is attached to an sp 3 - hybridized carbon; and more particularly, to aliphatic isocyanates; and especially, to polymethylene diisocyanates and the various condensation derivatives thereof (biuret, etc. ) and di- and trimerization derivatives thereof.
- the percentage of residual free isocyanate function is sometimes preferable for the percentage of residual free isocyanate function to be not more than 10 %; preferably, not more than 5 %; and more preferably, not more than 3 %.
- the highest melting points or glass transition temperatures are typically obtained with percentages not exceeding 1 %.
- the polyfunctional isocyanates comprises trimers. If the incorporation of trimers is preferred, examples of such that can be employed include: isocyanurates from isophorone diisocyanate or hexamethylene diisocyanate; and/or biurets from hexamethylene diisocyanate.
- the film forming resin's crosslinker component preferably comprises an isocyanurate from isophorone diisocyanate.
- an isocyanurate from isophorone diisocyanate can be prepared by any suitable manner known to those skilled in the art.
- One example of a manner in which an isocyanurate from isophorone diisocyanate can be prepared includes the trimerization of IPDI in the presence of a suitable catalyst system. Thereafter, the remaining NCO groups are at least partially blocked as set out below.
- a first reaction step of such a process i.e. , the catalytic trimerization
- the catalytic trimerization does not yield a uniform product. Rather, it produces various oligomers of IPDI which contain at least one isocyanurate ring and at least 3 free NCO groups. These products are hereinafter referred to as "IPDI - isocyanurates”.
- One example of a suitable catalyst system that can be used to trimerize the IPDI comprises 1,4-diazabicyclo(2,2,2)-octane/1,2-epoxypropane.
- the trimerization may be carried out with or without inert organic solvents.
- IPDI - isocyanurates are also commercially available.
- IPDI - isocyanurates which can be employed include the following: VESTANAT TM T-1890 isocyanurate commercially available from
- the film forming resin's crosslinker component can predominantly include diisocyanates
- the film forming resin's crosslinker component predominantly includes triisocyanates or a mixture of diisocyanates and triisocyanates, wherein the triisocyanate content is at least 25 percent of the total crosslinker component.
- the triisocyanate content is preferably at least 50 percent; and more preferably at least 75 percent of the total crosslinker component.
- polyfunctional isocyanates are known to those skilled in the art as being able to crosslink polyester polyols used in making powder coating compositions, what is not known to skilled artisans is that these types of crosslinkers can adequately function in this manner when they are at least partially blocked in the manner set out below.
- the polyfunctional isocyanates of the crosslinker component are at least partially blocked with a mixture of a polyhydroxy aromatic compound and a hydroxy-functional ester compound.
- polyhydroxy aromatic compound includes compounds having at least one of the following structures: HO-- ⁇ 1 -- R 1 -- ⁇ 1 --OH (I) where ⁇ 1 consists of a phenylene group and R 1 is an alkylene group having 0 to 4 carbon atoms, or HO-- ⁇ 2 --OH (II) Where ⁇ 2 consists of a phenylene group or a naphthylene group.
- polyhydroxy aromatic compounds which are encompassed by structure (I) include: diphenols such as 4,4'-isopropylidenediphenol (e.g., Bisphenol TM A, commercially available from Dow Chemical Co) and bis(4-hydroxyphenyl) methane (e.g., Bisphenol TM F, also commercially available from Dow Chemical Co).
- diphenols such as 4,4'-isopropylidenediphenol (e.g., Bisphenol TM A, commercially available from Dow Chemical Co) and bis(4-hydroxyphenyl) methane (e.g., Bisphenol TM F, also commercially available from Dow Chemical Co).
- polyhydroxyl aromatic compounds which are encompassed by structure (II) include: dihydroxynaphthalene, hydroxy phenols such as resorcinol, and derivatives thereof.
- the polyhydroxy aromatic compound comprises 4,4'-isopropylidene-diphenol.
- hydroxy-functional ester compound includes compounds having the following structure: COO R 2 -- ⁇ 2 --OH (III) where, R 2 is an alkyl group having from 1 to 4 carbon atoms and ⁇ 2 consists of a phenylene group or a naphthylene group.
- hydroxy-functional ester compounds which are encompassed by structure (III) include: methyl 4-hydroxy benzoate and methyl 3-hydroxy benzoate.
- the hydroxy-functional ester compound comprises methyl 4-hydroxy benzoate.
- the polyfunctional isocyanates of the crosslinker component are at least partially blocked with a blend of the polyhydroxy aromatic compound(s) and the hydroxy-functional ester compound(s) encompassed by the following structures: (I) and (III); (II) and (III); and/or (I), (II) and (III).
- the ratio of the polyhydroxy aromatic compound(s) to the hydroxy-functional ester compound(s) ranges from 0.01:1 to 1.4:1. In certain embodiments, the ratio of the polyhydroxy aromatic compound(s) to the hydroxy-functional ester compound(s) preferably ranges from 0.05:1 to 1:1.2, and more preferably, from 0.10:1 to 1:1.
- the total amount of the blocking agent(s) employed are such that there exists from 1.5 to 0.6 hydroxyl equivalents of the blocking agent(s) per equivalent of free NCO in the polyfunctional isocyanates.
- the total amount of the blocking agent(s) employed are such that there exists from 1.3 to 0.7 hydroxyl equivalents of the blocking agent(s) per equivalent of free NCO in the polyfunctional isocyanates; and more preferably, from 1.1 to 0.9 hydroxyl equivalents of the blocking agent(s) per equivalent of free NCO in the polyfunctional isocyanates.
- the powder coatings' novel film forming system includes the aforementioned novel crosslinker component.
- the film forming system of these powder coatings further includes a polymer component.
- This polymer component can be any suitable polymer(s) which can be used to make powder coating compositions and which can be crosslinked by the novel crosslinker component.
- Suitable polymer components include those conventionally employed by the coating industry for use in making powder coating compositions.
- Suitable polymer components also include those novel polymer components which will be described below in more detail.
- any suitable polymer component known to those skilled in the art capable of resulting in the formation of a powder coating composition, and capable of being crosslinked by the novel crosslinker component can be employed.
- suitable polymer components which can be employed are those which include at least one of the following compounds, acrylic resins, polyester resins, polyurethane resins, epoxy resins, and the like.
- polystyrene resin typically, however, conventional polymer components employed when practicing this invention include a polyol with at least the following characteristics:
- Polyols which can be employed as part of the polymer component when practicing this invention include those which comprise a cycloaliphatic component.
- This cycloaliphatic component includes the reaction product of at least one cycloaliphatic acid and at least one cyclic polyol.
- Any suitable cycloaliphatic acid can be employed.
- the cycloaliphatic acid can be the 1,2- 1,3- and/or 1,4-isomer of hexahydrophthalic acid, the latter of which is also referred to as 1,4-cyclohexanedicarboxylic acid.
- the esters thereof with short chain alkanols e.g. , dimethyl, diethyl, or dipropyl esters
- hexahydrophthalic anhydride is preferred.
- cycloaliphatic acid also includes those alkyl cycloaliphatic acids or anhydrides where an alkyl group, having up to about seven carbon atoms, is bound to the cycloaliphatic ring. Accordingly, for the purposes of this invention, the term “cycloaliphatic acid " includes not only the examples set out above, but also the esters, anhydrides and ring-alkylated derivatives of each.
- the amount of the cycloaliphatic acid employed is typically at least about 20 weight percent. More typically, the amount of the cycloaliphatic acid employed is at least 30 weight percent; and even more typically, at least 40 weight percent.
- the amount of the cycloaliphatic acid employed is typically not greater than 75 weight percent. More typically, the amount of the cycloaliphatic acid employed is not greater than 65 weight percent; and even more typically, not greater than 55 weight percent. All of the aforementioned weight percentages are based upon the total weight of the resulting polyester polyol.
- the cyclic polyol used in making the cycloaliphatic component can be any suitable cyclic polyol which can react with the aforementioned cycloaliphatic acid.
- suitable cyclic polyols include: cyclohexane dimethanol and cyclohexane diol.
- such a suitable cyclic polyol is cyclohexane dimethanol (CHDM)
- the amount of the cyclic polyol employed is typically at least 10 weight percent. More typically, the amount of the cyclic polyol employed is at least 20 weight percent; and even more typically, at least 30 weight percent.
- the amount of the cyclic polyol employed is typically not greater than 70 weight percent. More typically, the amount of the cyclic polyol employed is not greater than 60 weight percent; and even more typically, not greater than 50 weight percent. All of the aforementioned weight percentages are based upon the total weight of the resulting polyester polyol.
- the amount of the cycloaliphatic component employed is typically at least 60 weight percent. More typically, the amount of the cycloaliphatic component employed is at least 70 weight percent; and even more typically, at least 80 weight percent. On the other hand, when preparing the aforementioned polyester polyol, the amount of the cycloaliphatic component employed is typically not greater than 99 weight percent. More typically, the amount of the cycloaliphatic component employed is not greater than 97 weight percent; and even more typically, not greater than 95 weight percent. All of the aforementioned weight percentages are based upon the total weight of the resulting polyester polyol.
- acrylic resin When the polymer component comprises an acrylic resin, a single binding material is typically used.
- acrylic resins can be obtained by having the unsaturated alpha, beta monomers react in ethylene, in particular aromatic vinyl monomers and alpha, beta carboxylic acid esters unsaturated in ethylene.
- styrene and its derivatives such as methylstyrene or chlorostyrene; in the case of exterior products, they are present in quantities comprised between 5 and 54%, preferably between 10 and 25% of the entire set of monomers. Quantities under 5% may affect corrosion resistance.
- the acrylic and methacrylic acid esters such as methyl acrylate, ethyl acrylate, butyl acrylate, 2-ethylhexyl acrylate, dodecyl acrylate, methyl methacrylate, ethyl methacrylate, butyl methacrylate, 2-ethylhexyl methacrylate, lauric methacrylate should be cited.
- unsaturated esters are present in a quantity between 5 and 8% and correspond to a mixture of alkyl esters with 1 to 3 carbon atoms and 4 to 20 carbon atoms, for example a mixture of methyl methacyrlate and butyl acrylate.
- the hydroxyl functionality of the acrylic polymer is conferred by the copolymerization of monomers having hydroxyl groups, such as hydroxethyl methacrylate, hydroxypropyl acrylate and methacrylate in quantities between 5 and 80%, this percentage, involving the entire set of monomers, is necessary to obtain the indicated hydroxyl index.
- the acrylic polymer can have a certain acidity index generally less than 15 by adding acrylic, methacrylic, itaconic or fumaric acid and/or maleic anhydride or acid.
- the various monomers are mixed and made to react by polymerization of free radicals.
- the initiators capable of being used in particular, it is possible to cite benzoyle peroxide, tertiobutyl hydroperoxide, ditertiobytyl peroxide, azo-bis-isobutyronitirile.
- link transfer agents can be used such as mercaptopropionic, docecyl and lauric mercaptan acid.
- the polymerization is carried out in a solution, by using a solvent in which the monomers are soluble such as toluene, xylene, butyl acetate, propyleneglycolmethyl-ether acetate, among others.
- the reaction mixture is volatized under vacuum to eliminate the organic solvent and recover the solid polymer.
- the residual content in solvents or volatile compounds should be less than 0.5%.
- the acidity index of the polymer in accordance with the present invention makes it possible to make the carboxyl groups react with aliphatic, aromatic polyepoxides and/or beta-hydroxyallcylamides, and thus a double cross-linking is obtained.
- polyester polyol includes the reaction product of a cycloaliphatic component, or the reactants making up the same, and a polyfunctional isocyanurate component.
- the cycloaliphatic component of the polyester polyol is the same as described above.
- the novel polyester polyol can be made by reacting a polyfunctional isocyanurate component, described below in detail, with the aforementioned cycloaliphatic component, it can also be made by reacting the polyfunctional isocyanurate component with the reactants which make up the cycloaliphatic component. If this latter approach is used, the amounts of the cycloaliphatic acid and the cyclic polyol which should be employed are those amounts set out above for the respective reactants.
- the polyfunctional isocyanurate component used in making the novel polyester polyol includes at least one compound that has at least two groups reactive towards carboxylic groups.
- Examples of compounds which can be used as the polyfunctional isocyanurate component include: tris(hydroxyethyl) isocyanurate (THEIC) and triglycidyl isocyanurate.
- TEEIC tris(hydroxyethyl) isocyanurate
- triglycidyl isocyanurate triglycidyl isocyanurate.
- the polyfunctional isocyanurate component comprises THEIC.
- the amount of the polyfunctional isocyanurate component employed is typically at least about 1 weight percent. More typically, the amount of the polyfunctional isocyanurate component employed is at least 3 weight percent; and even more typically, at least 5 weight percent.
- the amount of the polyfunctional isocyanurate component employed is typically not greater than 40 weight percent. More typically, the amount of the polyfunctional isocyanurate component employed is not greater than 30 weight percent; and even more typically, not greater than 20 weight percent. All of the aforementioned weight percentages are based upon the total weight of the resulting polyester polyol.
- the polyester polyol used when practicing this invention has a hydroxyl value of at least 5 mg KOH per gram of resin.
- the polyester polyol has a hydroxyl value of at least 10; and more typically, of at least 15 mg KOH per gram of resin.
- the polyester polyol has a hydroxyl value which is not greater than 200 mg KOH per gram of resin.
- the polyester polyol has a hydroxyl value which is not greater than 150; and more typically, which is not greater than 100 mg KOH per gram of resin.
- the film forming system's novel polymer component can also include at least one of the following optional components: additional film forming resins such as neopentyl glycol, 1,6-hexanediol, 2-methyl propanediol, ethylene glycol, propylene glycol, diethylene glycol, butanediol, trimethyl pentanediol dipropylene glycol 2,2-dimetlhyl-3-hydroxypropyl-2,2,-dimethyl-3-hydroxypropionate, trimethylol propane trimethylol ethane and other additives known to those skilled in the art.
- additional film forming resins such as neopentyl glycol, 1,6-hexanediol, 2-methyl propanediol, ethylene glycol, propylene glycol, diethylene glycol, butanediol, trimethyl pentanediol dipropylene glycol 2,2-dimetlhyl-3-hydroxypropyl-2,2,-
- optional components in the film forming system's polymer component can affect the properties of the powder coating and/or any film resulting therefrom. Therefore, the type and/or amount of optional components employed, if any, depend in part on the powder coating's desired end use.
- the total amount of these optional components should not exceed 30 weight percent.
- the amount of the optional component employed should not exceed 20 weight percent; more preferably, not more than 10 weight percent; and even more preferably, not more than 5 weight percent. These weight percentages are based upon the total weight of the film forming system's polymer component.
- the novel film forming system in addition to a crosslinker component and a polymer component, it is within the scope of this invention for the novel film forming system to further include an optional catalyst component. If present, the catalyst component is typically used to increase the reaction rate between the polymer component and the crosslinker component.
- the catalyst component When employed, the catalyst component is typically present at levels ranging from 0.001% to 15%. Typically, the amount of the catalyst component employed ranges from 0.01% to 10%; and more typically, from 0.1% to 5%. These percentages are based upon the total weight of the film forming resin system.
- Any suitable catalyst composition(s) which can catalyze the reaction between the film forming system's polymer component and crosslinker component can be employed when practicing this invention.
- suitable catalysts include: dibutyl tin dilaurate, zinc compounds such as zinc acetate, and/or amines such as triethyl amine, imidazoles, cyclic amidine, alkyl/aryl ammonium halides, and zinc alkyl/aryl thiocarbamates.
- the novel film forming systems employed when practicing this invention can further include other optional additives known to those skilled in the art.
- additives include: benzoin, waxes, plasticizers, flow control agents, and the like. It is important to note, however, that the addition of such additives will probably affect the cured and/or uncured states of the resulting powder coating composition. Accordingly, the types and amount of such additives employed, if any, depend in part upon the desired use of the powder coating composition.
- the powder coating compositions encompassed by the present invention can also include a pigment system. If present, such a system can be used to impart a color to and/or reduce the gloss of the resulting cured film.
- a pigment system can be used to impart a color to and/or reduce the gloss of the resulting cured film.
- the terms "pigment system” and “pigment” refer not only to color-producing pigments, but also to gloss-affecting agents which may or may not alter the color of the cured film, and/or fillers. It should be noted that, it is within the scope of this invention for the pigment system to include compositions which produce more than one of the aforementioned results. It is also within the scope of this invention for the pigment system to include only one of the aforementioned types of compositions, or any combination thereof.
- the pigment system typically comprises pigments having an average minimum particle size of at least 0.1 ⁇ m.
- the pigments employed have an average minimum particle size of at least 0.5 ⁇ m; more typically of at least 1 ⁇ m and even more typically of at least 3 ⁇ m.
- the pigment system typically comprises pigments having an average maximum particle size of at most about 100 ⁇ m.
- the pigments employed have an average minimum particle size of at most 75 ⁇ m; more typically of at most 50 ⁇ m; and even more typically of at most 25 ⁇ m.
- any suitable gloss altering pigments can be employed.
- suitable gloss altering pigments include: silicas, barytes, calcium carbonate, talcs, magnesium silicate and/or aluminum silicate. If the desired result is to lower the gloss of the resulting finish, the pigment component typically includes at least one silica.
- any suitable color altering pigments can be employed.
- suitable color altering pigments include: titanium dioxide, lithopone, zinc white, organic red lake pigment, black mixed metal oxides, red oxide, carbon black, phthalocyanine blue, or aluminum powder paste.
- titanium dioxide can play a neutral role or favor the matte-finish aspect according to the chosen pre-treatment. It has appeared that the titanium oxides undergoing a silica treatment (and possibly aluminum) significantly increases the matte-finish quality, that having the most significant effect is that sold under the name TITAFRAN TM RL68. Titanium dioxides treated with zirconium oxide only have a minor effect on the matte-finish quality. However, those skilled in the art can easily vary the dull-glazed or matte characteristic by adjusting the amount of titanium dioxide employed.
- any suitable filler(s) can be employed.
- suitable fillers include: calcium carbonate, barium sulfate, clay, mica, talc, wollastonite, silica, alumina, or alumino silicates.
- the amount of the pigment system employed is typically at least 0.1 weight percent. More typically, the amount of the pigment system employed is at least 1 weight percent; and even more typically, at least 3 weight percent. These weight percentages are based upon the total weight of the resulting powder coating composition.
- the amount of the pigment system is typically not greater than 50 weight. More typically, the amount of the pigment system is typically not greater than 40 weight percent; and even more typically, not greater than 30 weight percent. These weight percentages are based upon the total weight of the resulting powder coating composition.
- the concentration of powder coatings' film forming system will vary depending on whether or not the powder coating includes a pigment system. Typically, if a pigment system is not employed, the film forming system is typically present in an amount of at least 70 weight percent; more typically at least 80 weight percent; and more typically at least 90 weight percent. On the other hand, if a pigment system is employed, the film forming system is typically present in an amount of at least 40 weight percent; more typically, at least 50 weight percent; and more typically, at least 60 weight percent.
- the powder coatings of the present invention can also include other additives known to those skilled in the art.
- these powder coating compositions can include various types of additives, such as degassing leveling agents, antioxidants and UV absorbing (anti-UV) agents. They can also contain the various additives of matte-finish quality known to improve the latter quality.
- benzoine can be cited as a recommended degassing agent, in particular with a quantity between 0.5 and 3% which allows volatile compounds to be released from the film during the hardening phase and makes it possible to prevent defects such as the formation of pits or small holes.
- Standard spreading additives are acrylic polymers, fluorinated polymers or polymer siloxanes, in quantities between 0.5 and 5% added directly in the master-batch in appropriate polymers or absorbed in silica.
- UV-absorbing and/or phenolic-type primary and/or secondary antioxidants or alkyl/aryl phosphite compositions be added to the formulations.
- Said additives can be present in the formulation in a quantity between 0.5 and 2% of the entire paint.
- urethane catalysts such as DBTDL (stannous dibutyldilaurate), added directly in the pre-mixing] or as far as master batch.
- the aforementioned components can be combined in any suitable manner known to those skilled in the art.
- one possible means of formulating such a composition includes the preparation of the polyester component. Thereafter, mixing the pigment system with the polyester. Thereafter, adding the crosslinking component, the optional catalyst component, as well as any other desired additives.
- the powder coating compositions of this invention can be applied to any suitable substrate: Examples of suitable substrates include: metal, coated metal, paper, leather, cloth or plastics.
- suitable substrates include: metal, coated metal, paper, leather, cloth or plastics.
- the powder coating compositions prepared in accordance with this invention can be applied over any of the aforementioned substrates by any suitable means known to those skilled in the art, their properties make them especially useful for application over metal by electrostatic spraying.
- the coating compositions of the present invention are especially useful for coating metal such as aluminum, steel, tin plated steel, electrogalvanized steel, zinc-aluminum coated steel, zinc-nickel coated steel, hot dipped galvanized steel, and electrodeposition primed versions of the above. If applied over such metal, the substrates are usually cleaned, chemically treated and/or primed to improve the adhesion of subsequent coating compositions prepared in accordance with the present invention.
- Coating thickness will vary depending upon the application desired. Typically, the coatings of the present invention will be applied over substrates at coating thicknesses ranging from 1.57-3810 ⁇ m (0.05 to 150 mils); more typically, from 2.54 ⁇ m to 2590 ⁇ m (0.1 to 100 mils); and even more typically, from 25.4-1270 ⁇ m (1 to about 50 mils).
- the coatings are cured.
- Curing is usually conducted by subjecting the coated substrate to elevated temperatures.
- the elevated temperatures employed range from 30°C. to 400°C., and more typically from 50°C. to 200°C. Higher curing temperatures with correspondingly shorten curing times.
- the preferred curing process depends upon the nature of the substrate as well as the particular components used in formulating the coating compositions.
- powder coating compositions of the present invention make them useful for a wide variety of applications. For example, they are especially useful for coating metal used in the manufacture of automotive trim parts, architectural panels, playground equipment, metal office furniture, vending machines and appliances.
- IPDI - isocyanurate employed in the examples was VESTANAT TM T-1890 isocyanurate commercially available from Creanova Corporation.
- a blocked isocyanate was prepared by mixing 1.7 moles of the IPDI trimer with 4.0 moles methyl p-hydroxybenzoate and 0.7 moles Bisphenol A. These materials were mixed as an 80% solids solution in butyl acetate and in the presence of 0.04 wt. % of dibutyl tin dilaurate. The mixing was carried out at 90° C under a nitrogen atmosphere. The solvent was removed by distillation under reduced pressure to yield the desired product hereinafter referred to as " Crosslinker A ".
- a blocked isocyanate was prepared by mixing 2.4 moles of the HDI isocyanurate (commercially available as DESMODUR TM N-3300) with 4.8 moles methyl p-hydroxybenzoate and 1.4 moles Bisphenol A. These materials were mixed as a 70% solids solution in butyl acetate and in the presence of 0.04 wt. % of dibutyl tin dilaurate. The mixing was carried out at 90° C under a nitrogen atmosphere. The solvent was removed by distillation under reduced pressure to yield the desired product hereinafter referred to as " Crosslinker B ".
- a blocked isocyanate was prepared by mixing 1.0 moles of the HDI Biuret (commercially available as DESMODUR TM N-100) with 2.3 moles methyl p-hydroxybenzoate and 0.4 moles Bisphenol A. These materials were mixed as an 70% solids solution in butyl acetate and in the presence of 0.04 wt. % of dibutyl tin dilaurate. The mixing was carried out at 90° C under a nitrogen atmosphere. The solvent was removed by distillation under reduced pressure to yield the desired product hereinafter referred to as " Crosslinker C ".
- Polymer A a novel polyester polyol
- Polymer B another polymer component includes a conventional polyester polyol
- Polymer C a conventional acrylic
- Polymer C is a hydroxyfunctional acrylic commercially available from S.C. Johnson under the tradename SCX-804.
- a nitrogen stream was passed over the top of the compounds while the temperature was raised to about 230°C. After the compounds had melted, the nitrogen stream was placed below the surface of the mixture. The mixture was held at about 230°C for about 18 hours. During this period, the water of condensation was removed from the mixture through the distillation column.
- Polymer A had the following properties: an acid value of 3.0, a hydroxyl value of 33.4, a solids content of 99.7%, and a melt viscosity of 6273 cps.
- the percent solids was determined by placing a sample of the resin in a weighing dish and heating in an oven to about 150°C and maintaining the oven at that temperature for about 2 hours.
- the melt viscosity was determined by using a Brookfield CAP 2000 viscometer with cone #5 run at 175°C. and 200 RPM.
- a nitrogen stream was passed over the top of the compounds while the temperature was raised to about 230°C. After the compounds had melted, the nitrogen stream was placed below the surface of the mixture. The mixture was held at about 230°C for about 11 hours. During this period, the water of condensation was removed from the mixture through the distillation column.
- Polymer B had the following properties: an acid value of 4.3, a hydroxyl value of 34.8, a solids content of 99.8%, and a melt viscosity of 11,417 cps.
- the percent solids was determined by placing a sample of the resin in a weighing dish and heating in an oven to about 150°C and maintaining the oven at that temperature for about 2 hours.
- the melt viscosity was determined by using a Brookfield CAP 2000 viscometer with cone #6 run at 200° C. and 200 RPM.
- This Example demonstrates the preparation of several powder coating compositions.
- the following compounds were place into four separate 5-liter flasks, each being equipped with a stirrer, thermometer, nitrogen inlet tube, and distillation column: Powder A Powder B Powder C Powder D Powder E Powder F COMPONENT Amount (grams) Amount (grams) Amount (grams) Amount (grams) Amount (grams) Amount (grams) Crosslinker A -- 71 71 -- Crosslinker B 71 -- -- 71 71 Crosslinker C 71 Polymer A 336 336 -- -- 336 Polymer B 336 Polymer C -- -- 260 260 Flow additive 1 4 4 4 4 4 4 4 Degassing agent 2 4 4 4 4 4 4 Carbon black pigment 6 6 6 -- 6 Calcium carbonate flattener 180 180 180 180 180 -- 180 1 A conventional acrylic flow additive commercially available from Solutia under the tradename PL 200 TM . 2 A conventional degassing agent commercially available from SNIA UK under the tradename BEAIZOIN TM .
- Powders A - F were all prepared in essentially the same manner. Specifically, all materials were weighed out and ground to a sand-like consistency with a PRISM TM high speed mixer. The ground material was then extruded on a 19mm BAKER-PERKINS TM extruder at 100°C. After the extrudate was permitted to cool, it was ground to an average particle size of about 30 microns on a HOSAKAWA TM ACM 1 grinder.
- This Example demonstrates the results of testing and evaluating Powders A - F.
- One test was the determination of the cured film's percent of light reflectance (i.e., gloss) at a 20° incident angle and at a 60° incident angle.
- Another test was the film's level of cure.
- Powders A - F were all applied to a metal substrate, cured and tested in essentially the same manners. Specifically, Powders A - F were individually applied to separate metal substrates by electrostatic spray application at 80 kV with a NORDSON TM II Versa spray system to a thickness of 2.5 mil. After being applied, the coatings were all cured at 380°F for about 20 minutes. Finally, the resulting films' gloss and durability were evaluated as set out above. The results of the evaluation are set out in the following table.
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Claims (18)
- Pulverbeschichtungszusammensetzung, die ein filmbildendes Harzsystem enthält, wobei dieses filmbildende Harzsystem enthält:a. eine Vernetzerkomponente, die ein polyfunktionelles Isocyanat enthält, das wenigstens teilweise mit einer Mischung der Folgenden blockiert ist:i. einer aromatischen Polyhydroxyverbindung, die wenigstens eine Verbindung mit wenigstens einer der folgenden Strukturen enthält:
HO--Φ1--R 1--Φ1--OH,
worin Φ1 aus einer Phenylengruppe besteht und R 1 eine Alkylengruppe mit 0 bis 4 Kohlenstoffatomen ist, oder
HO--Φ2--OH,
worin Φ2 aus einer Phenylengruppe oder einer Naphthylengruppe besteht, undii. einer hydroxyfunktionellen Esterverbindung, die die folgende Struktur enthält:
COOR2--Φ2--OH,
worin R2 eine Alkylgruppe mit 1 bis 4 Kohlenstoffatomen ist und Φ2 aus einer Phenylengruppe oder einer Naphthylengruppe besteht, wobei das Verhältnis der aromatischen Polyhydroxyverbindung zu der hydroxyfunktionellen Esterverbindung im Bereich von 0,01:1 bis 1,4:1 liegt, undb. eine polymere Komponente. - Pulverbeschichtungszusammensetzung nach Anspruch 1, wobei die Polymerkomponente ein Polyesterpolyol enthält, das eine cycloaliphatische Komponente enthält, wobei diese cycloaliphatische Komponente das Reaktionsprodukt von:i. einer cycloaliphatischen Säure, die wenigstens eine Verbindung enthält, die aus der Gruppe bestehend aus dem 1,2-Isomer von Hexahydrophthalsäure, dem 1,3-Isomer von Hexahydrophthalsäure und dem 1,4-Isomer von Hexahydrophthalsäure ausgewählt ist, undii. einem cyclischen Polyol, das wenigstens eine Verbindung, ausgewählt aus der Gruppe bestehend aus Cyclohexandimethanol und Cyclohexandiol, enthält,enthält.
- Pulverbeschichtungszusammensetzung nach Anspruch 1, wobei die Vernetzerkomponente Triisocyanate oder eine Mischung von Diisocyanaten und Triisocyanaten enthält.
- Pulverbeschichtungszusammensetzung nach Anspruch 1, wobei die aromatische Polyhydroxyverbindung wenigstens eine Verbindung enthält, die ausgewählt ist aus der Gruppe bestehend aus Diphenolen, Dihydroxynaphthalin, Hydroxyphenolen und Derivaten davon.
- Pulverbeschichtungszusammensetzung nach Anspruch 1, wobei die hydroxyfunktionelle Esterverbindung wenigstens eine Verbindung enthält, die ausgewählt ist aus der Gruppe bestehend aus Methyl-4-hydroxybenzoat und Methyl-3-hydroxybenzoat.
- Pulverbeschichtungszusammensetzung nach Anspruch 1, wobei die polymere Komponente ein Polyol mit wenigstens den folgenden Eigenschaften enthält:a. einer Glasübergangstemperatur von wenigstens 25°C,b. einem Hydroxylwert im Bereich von 5 bis 500 mg KOH/g undc. einem mittleren Molekulargewicht im Bereich von 500 bis 25000 g/mol, wobei das Molekulargewicht durch Gelpermeationschromatographie mit einem Polystyrolstandard bestimmt ist.
- Pulverbeschichtungszusammensetzung nach Anspruch 1, wobei die polymere Komponente ein Polyesterpolyol enthält und dieses Polyesterpolyol eine cycloaliphatische Komponente enthält.
- Pulverbeschichtungszusammensetzung nach Anspruch 7, wobei die cycloaliphatische Komponente das Reaktionsprodukt von:a. einer cycloaliphatischen Säure undb. einem cyclischen Polyolenthält.
- Pulverbeschichtungszusammensetzung nach Anspruch 8, wobei die cycloaliphatische Säure wenigstens eine Verbindung enthält, die ausgewählt ist aus der Gruppe bestehend aus dem 1,2-Isomer von Hexahydrophthalsäure, dem 1,3-Isomer von Hexahydrophthalsäure und dem 1,4-Isomer von Hexahydrophthalsäure.
- Pulverbeschichtungszusammensetzung nach Anspruch 8, wobei die cycloaliphatische Säure Hexahydrophthalsäureanhydrid enthält.
- Pulverbeschichtungszusammensetzung nach Anspruch 8, wobei die Menge der eingesetzten cycloaliphatischen Säure wenigstens 40 Gew.-% beträgt, wobei diese Gewichtsprozentangabe sich auf das Gesamtgewicht des Polyesterpolyols bezieht.
- Pulverbeschichtungszusammensetzung nach Anspruch 8, wobei die Menge der eingesetzten cycloaliphatischen Säure höchsten 55 Gew.-% beträgt, wobei diese Gewichtsprozentangabe sich auf das Gesamtgewicht des Polyesterpolyols bezieht.
- Pulverbeschichtungszusammensetzung nach Anspruch 8, wobei das cyclische Polyol wenigstens eine Verbindung enthält, die ausgewählt ist aus der Gruppe bestehend aus Cyclohexandimethanol und Cyclohexandiol.
- Pulverbeschichtungszusammensetzung nach Anspruch 8, wobei die Menge des eingesetzten cyclischen Polyols wenigstens 10 Gew.-% beträgt, wobei diese Gewichtsprozentangabe sich auf das Gesamtgewicht des Polyesterpolyols bezieht.
- Pulverbeschichtungszusammensetzung nach Anspruch 8, wobei die Menge des eingesetzten cyclischen Polyols höchstens 70 Gew.-% beträgt, wobei diese Gewichtsprozentangabe sich auf das Gesamtgewicht des Polyesterpolyols bezieht.
- Pulverbeschichtungszusammensetzung nach Anspruch 8, wobei die Menge der eingesetzten cycloaliphatischen Komponente wenigstens 60 Gew.-% beträgt, wobei diese Gewichtsprozentangabe sich auf das Gesamtgewicht des Polyesterpolyols bezieht.
- Pulverbeschichtungszusammensetzung nach Anspruch 8, wobei die Menge der eingesetzten cycloaliphatischen Komponente höchstens 99 Gew.-% beträgt, wobei diese Gewichtsprozentangabe sich auf das Gesamtgewicht des Polyesterpolyols bezieht.
- Pulverbeschichtungszusammensetzung nach Anspruch 1, wobei die polymere Komponente wenigstens eine Verbindung, ausgewählt aus der Gruppe bestehend aus Acrylharzen, Polyesterharzen, Polyurethanharzen und Epoxyharzen, enthält.
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PCT/US2000/026564 WO2001032733A1 (en) | 1999-11-02 | 2000-09-27 | Stable powder coating compositions |
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EP (1) | EP1237974B1 (de) |
AT (1) | ATE346874T1 (de) |
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US9156996B2 (en) * | 2005-10-21 | 2015-10-13 | Valspar Sourcing, Inc. | Powder coloring system |
JP5420212B2 (ja) * | 2007-10-31 | 2014-02-19 | アクゾ ノーベル コーティングス インターナショナル ビー ヴィ | スチール用耐薄チップパウダートップコート |
US20090162543A1 (en) * | 2007-12-19 | 2009-06-25 | Giora Topaz | Concentrated powdered colors composition for a powder coating and method of manufacture |
EP2240544B1 (de) * | 2008-01-25 | 2016-07-13 | Akzo Nobel Coatings International B.V. | Pulverlacke mit einem im wesentlichen nicht zinkhaltigen grundiermittel |
EP2236563A3 (de) * | 2009-04-03 | 2010-12-08 | Rohm and Haas Company | Revêtement en poudre résistant aux éclats et à la corrosion |
WO2011012627A2 (en) * | 2009-07-29 | 2011-02-03 | Akzo Nobel Coatings International B.V. | Powder coating compositions capable of having a substantially non-zinc containing primer |
EP3197678B1 (de) * | 2014-09-26 | 2020-04-08 | Covestro Deutschland AG | Farblose, transparente und hitzebeständige polyurethanfilme und verfahren zur herstellung davon |
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US5777061A (en) | 1996-02-14 | 1998-07-07 | Bayer Corporation | Blocked polyisocyanate crosslinkers for providing improved flow properties to coating compositions |
JP3943162B2 (ja) | 1996-02-28 | 2007-07-11 | 旭化成ケミカルズ株式会社 | 接着性付与剤組成物及びそれを含有するプラスチゾル組成物 |
EP0822210A1 (de) | 1996-07-30 | 1998-02-04 | Rhone-Poulenc Chimie | Zusammensetzung für die Herstellung einer Matten oder seidigen Beschichtung, Verwendung dieser Zusammensetzung sowie daraus hergestellte Beschichtung |
US5925698A (en) | 1997-03-14 | 1999-07-20 | The Lubrizol Corporation | Powder coating composition and method for coating a substrate using said powder coating composition |
JPH1157615A (ja) | 1997-08-26 | 1999-03-02 | Kansai Paint Co Ltd | 塗膜形成方法 |
EP0985607A1 (de) | 1998-07-28 | 2000-03-15 | Guala Closures S.P.A. | Sicherheitsverschluss |
-
1999
- 1999-11-02 US US09/431,789 patent/US6284846B1/en not_active Expired - Lifetime
-
2000
- 2000-09-27 WO PCT/US2000/026564 patent/WO2001032733A1/en active IP Right Grant
- 2000-09-27 CA CA002387987A patent/CA2387987A1/en not_active Abandoned
- 2000-09-27 AT AT00966963T patent/ATE346874T1/de not_active IP Right Cessation
- 2000-09-27 DE DE60032174T patent/DE60032174D1/de not_active Expired - Lifetime
- 2000-09-27 EP EP00966963A patent/EP1237974B1/de not_active Expired - Lifetime
- 2000-09-27 AU AU77231/00A patent/AU7723100A/en not_active Abandoned
- 2000-09-27 BR BR0014999-3A patent/BR0014999A/pt active Pending
Also Published As
Publication number | Publication date |
---|---|
ATE346874T1 (de) | 2006-12-15 |
AU7723100A (en) | 2001-05-14 |
CA2387987A1 (en) | 2001-05-10 |
WO2001032733A1 (en) | 2001-05-10 |
DE60032174D1 (de) | 2007-01-11 |
EP1237974A1 (de) | 2002-09-11 |
BR0014999A (pt) | 2002-06-25 |
US6284846B1 (en) | 2001-09-04 |
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