EP1229141A1 - Alliage d'aluminium de fonderie - Google Patents

Alliage d'aluminium de fonderie Download PDF

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Publication number
EP1229141A1
EP1229141A1 EP01810109A EP01810109A EP1229141A1 EP 1229141 A1 EP1229141 A1 EP 1229141A1 EP 01810109 A EP01810109 A EP 01810109A EP 01810109 A EP01810109 A EP 01810109A EP 1229141 A1 EP1229141 A1 EP 1229141A1
Authority
EP
European Patent Office
Prior art keywords
max
weight
cast alloy
alloy according
cast
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01810109A
Other languages
German (de)
English (en)
Inventor
Hubert Koch
Horst Schramm
Peter Krug
Thomas Gebhardt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aluminium Rheinfelden GmbH
Original Assignee
Aluminium Rheinfelden GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aluminium Rheinfelden GmbH filed Critical Aluminium Rheinfelden GmbH
Priority to EP01810109A priority Critical patent/EP1229141A1/fr
Publication of EP1229141A1 publication Critical patent/EP1229141A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/10Alloys based on aluminium with zinc as the next major constituent

Definitions

  • the invention relates to a cast alloy based on aluminum and their use.
  • AISi cast alloys also have the disadvantage that with this type of alloy, due to the eutectic silicon, which is especially for safety-relevant Components in vehicle construction often require high ductility cannot be reached.
  • the alloys of the AlSi group must therefore to improve the castability and the mechanical properties Sodium or strontium can be refined.
  • These finishing elements work but are disadvantageous in that, on the one hand, they burn quickly (especially Sodium) and on the other hand the tendency of the melt to absorb hydrogen increase strongly (especially strontium). In practice, this leads to increased Gas porosity and thus to reduce ductility and fatigue strength.
  • the invention has for its object to an aluminum casting alloy create the required properties after casting without one Heat treatment already by aging at room temperature at least 14 days or only with limited heat treatment T5, i.e. achieved without solution annealing.
  • the casting alloy should above all suitable for die casting and sand casting.
  • the alloy should also be used in particular for safety-relevant components in vehicle construction, ie the castings made from the alloy must have high strength combined with high ductility.
  • the mechanical properties sought in the casting are defined as follows: yield strength Rp0.2> 170 MPa tensile strenght Rm> 230 MPa elongation A5> 6%
  • the corrosion tendency of the cast alloy should depend on the applications be kept as deep as possible and the alloy must also have a corresponding have good fatigue strength.
  • the castability of the alloy should be comparable be with the currently used AISi casting alloys, and the Alloy must not show any tendency to crack hot.
  • a cast alloy based on aluminum is used to achieve the object according to the invention silicon Max. 0.25 Wt .-% iron Max. 0.2 Wt .-% copper Max. 0.3 Wt .-% manganese 0.05 to 0.5 Wt .-% magnesium 0.2 to 1.0 Wt .-% zinc 4 to 7 Wt .-% titanium Max. 0.2 Wt .-% chrome 0.15 to 0.45 Wt .-% boron Max. 0.0065 Wt .-% nickel Max. 0.25 Wt .-% tin Max. 0.25 Wt .-% silver Max. 0.25 Wt .-% cerium Max. 0.25 Wt .-% zirconium Max. 0.25 Wt .-% scandium Max. 0.25 Wt .-% as well as aluminum as the rest with other elements and manufacturing-related impurities individually max. 0.05% by weight, max. 0.15% by weight.
  • the following content ranges are preferred for the individual alloy elements: silicon Max. 0.15% by weight, in particular max. 0.10% by weight iron Max. 0.15% by weight, in particular max. 0.10% by weight copper Max. 0.1% by weight, in particular max. 0.07% by weight manganese 0.1 to 0.3% by weight, in particular 0.15 to 0.25% by weight magnesium 0.4 to 0.8% by weight zinc 4.5 to 6% by weight, in particular 4.7 to 5.8% by weight titanium 0.03 to 0.15% by weight, in particular 0.05 to 0.10% by weight chrome 0.20 to 0.30% by weight boron 0.0005 to 0.005% by weight
  • the alloy can contain 0.10 to 0.25% by weight Nickel, in particular 0.10 to 0.15 wt .-% nickel.
  • the cast alloy according to the invention has, because of the cold hardening Main alloy element zinc. This type of alloy has next to none Eutectic on the grain boundaries and therefore leads to good ductility but known to be problematic in terms of casting technology because of the pronounced Tendency to heat crack, see e.g. John E. Hatsch, Properties and Physical Metallurgy page 347.
  • a tendency to stress corrosion cracking with a high zinc content and to counteract intergranular corrosion is preferred ensured that the zinc content remains below 6% by weight.
  • Chromium also improves the mechanical properties, especially in Direction of higher ductility, since it is the morphology of the Fe / Mn-containing phases changed from a more angular to a round shape.
  • a certain amount of titanium combined with boron is required for grain refinement. Good grain refinement significantly improves the casting properties at.
  • a preferred area of application of the cast alloy according to the invention is the production of safety-related components in vehicle construction, in particular Handlebars, brackets, frame parts and wheels. Also for roasting and cooking dishes, especially for frying pans, the alloy according to the invention is excellent suitable.
  • Alloys with a composition according to Table 1 based on aluminum with other manufacturing-related impurities individually max. 0.05% by weight, max. 0.15% by weight was cast in a die rod test die according to Diez to give round bars 16 mm in diameter.
  • Alloys Nos. 1 and 2 are compositions according to the invention, and Alloys 3 to 9 are comparative examples.
  • the mechanical properties of the yield strength (Rp0.2), tensile strength (Rm) and elongation at break (A5) in the as-cast state were determined on test bars.
  • the hot crack number as a measure of the hot crack tendency was determined on the basis of a visual assessment of a cast part produced specifically for this determination.
  • This special cast part has a central area, from which 6 arms of different lengths of the same diameter extend in a star shape, with a spherical end piece being formed at the end of each arm.
  • the number of torn arms and the tears that occurred were assessed.
  • the evaluation is carried out using an evaluation scheme with levels 0 to 6.
  • the hot crack number means: 0 no cracks 1 to 5 Increase in cracks, from cracks that can only be seen with a magnifying glass to several torn arms 6 all arms torn off

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Continuous Casting (AREA)
EP01810109A 2001-02-05 2001-02-05 Alliage d'aluminium de fonderie Withdrawn EP1229141A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP01810109A EP1229141A1 (fr) 2001-02-05 2001-02-05 Alliage d'aluminium de fonderie

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP01810109A EP1229141A1 (fr) 2001-02-05 2001-02-05 Alliage d'aluminium de fonderie

Publications (1)

Publication Number Publication Date
EP1229141A1 true EP1229141A1 (fr) 2002-08-07

Family

ID=8183712

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01810109A Withdrawn EP1229141A1 (fr) 2001-02-05 2001-02-05 Alliage d'aluminium de fonderie

Country Status (1)

Country Link
EP (1) EP1229141A1 (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004079029A1 (fr) * 2003-03-07 2004-09-16 Ae Group Ag Element coule sous pression et procede de fabrication associe
EP1475449A1 (fr) * 2003-03-14 2004-11-10 Miba Gleitlager GmbH Alliage d'aluminium forgeable
DE10352932A1 (de) * 2003-11-11 2005-06-16 Eads Deutschland Gmbh Aluminium-Gusslegierung
WO2005106057A3 (fr) * 2004-04-22 2006-01-26 Alcoa Inc Alliage al-zn-mg apte au traitement thermique pour pieces coulees automobiles et aerospatiaux
WO2005106058A3 (fr) * 2004-04-22 2006-09-14 Alcoa Inc Alliage al-zn-mg-cu a traitement thermique utilise pour des pieces coulees destinees a des applications dans le domaine de l'aerospatiale et de l'automobile
EP1768797A2 (fr) * 2004-07-01 2007-04-04 Alcoa Inc. Roue de vehicule en aluminium forge, procede de production et alliage associes
US8083871B2 (en) 2005-10-28 2011-12-27 Automotive Casting Technology, Inc. High crashworthiness Al-Si-Mg alloy and methods for producing automotive casting
JP2018178246A (ja) * 2017-04-13 2018-11-15 コリア インスティテュート オブ マシーナリー アンド マテリアルズKorea Institute Of Machinery & Materials アルミニウム−亜鉛−銅(Al−Zn−Cu)合金及びその製造方法
CN115449676A (zh) * 2022-10-28 2022-12-09 江苏亚太轻合金科技股份有限公司 一种压铸Al-Zn-Mg-Mn铝合金及其制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1218516A (en) * 1968-12-27 1971-01-06 Aluminum Co Of America Clad aluminum base alloy
JPS59113164A (ja) * 1982-12-18 1984-06-29 Aisin Seiki Co Ltd 自動車用バンパ−の製造方法
US4490189A (en) * 1982-04-13 1984-12-25 Aluminium Pechiney Method of manufacturing stamped-out or forged parts made of aluminum alloys
JPS6263641A (ja) * 1985-09-14 1987-03-20 Showa Alum Corp 低サイクル疲労特性に優れた高強度アルミニウム合金押出材
JPH07310156A (ja) * 1994-05-12 1995-11-28 Mitsubishi Alum Co Ltd 自動車のフレーム構造およびその製造方法
EP0709274A1 (fr) * 1994-10-26 1996-05-01 Alusuisse-Lonza Services AG Colonne de direction de sécurité
JPH09279284A (ja) * 1995-06-14 1997-10-28 Furukawa Electric Co Ltd:The 耐応力腐食割れ性に優れた溶接用高力アルミニウム合金

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1218516A (en) * 1968-12-27 1971-01-06 Aluminum Co Of America Clad aluminum base alloy
US4490189A (en) * 1982-04-13 1984-12-25 Aluminium Pechiney Method of manufacturing stamped-out or forged parts made of aluminum alloys
JPS59113164A (ja) * 1982-12-18 1984-06-29 Aisin Seiki Co Ltd 自動車用バンパ−の製造方法
JPS6263641A (ja) * 1985-09-14 1987-03-20 Showa Alum Corp 低サイクル疲労特性に優れた高強度アルミニウム合金押出材
JPH07310156A (ja) * 1994-05-12 1995-11-28 Mitsubishi Alum Co Ltd 自動車のフレーム構造およびその製造方法
EP0709274A1 (fr) * 1994-10-26 1996-05-01 Alusuisse-Lonza Services AG Colonne de direction de sécurité
JPH09279284A (ja) * 1995-06-14 1997-10-28 Furukawa Electric Co Ltd:The 耐応力腐食割れ性に優れた溶接用高力アルミニウム合金

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
GRAND L. ET AL: "Etude sur l'alliage léger de fonderie A-Z5G, influence d'additions de chrome et de cuivre sur les propriétés mécaniques et de la résistance à la corrosion", REVUE DE METALLURGIE, vol. LII, no. 10, 1955, pages 821 - 829, XP002970979
HUFNAGEL W: "Key to Aluminium Alloys, 4th Edition", ALUMINIUM-SCHLUESSEL = KEY TO ALUMINIUM ALLOYS, SEITEN 202-204, XP002172555 *
PATENT ABSTRACTS OF JAPAN vol. 008, no. 232 (C - 248) 25 October 1984 (1984-10-25) *
PATENT ABSTRACTS OF JAPAN vol. 011, no. 262 (C - 442) 25 August 1987 (1987-08-25) *
PATENT ABSTRACTS OF JAPAN vol. 1996, no. 03 29 March 1996 (1996-03-29) *
PATENT ABSTRACTS OF JAPAN vol. 1998, no. 02 30 January 1998 (1998-01-30) *

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004079029A1 (fr) * 2003-03-07 2004-09-16 Ae Group Ag Element coule sous pression et procede de fabrication associe
EP1475449A1 (fr) * 2003-03-14 2004-11-10 Miba Gleitlager GmbH Alliage d'aluminium forgeable
DE10352932A1 (de) * 2003-11-11 2005-06-16 Eads Deutschland Gmbh Aluminium-Gusslegierung
DE10352932B4 (de) * 2003-11-11 2007-05-24 Eads Deutschland Gmbh Aluminium-Gusslegierung
WO2005106058A3 (fr) * 2004-04-22 2006-09-14 Alcoa Inc Alliage al-zn-mg-cu a traitement thermique utilise pour des pieces coulees destinees a des applications dans le domaine de l'aerospatiale et de l'automobile
EP1759028A2 (fr) * 2004-04-22 2007-03-07 Alcoa Inc. Alliage al-zn-mg apte au traitement thermique pour pieces coulees automobiles et aerospatiaux
EP1759027A2 (fr) * 2004-04-22 2007-03-07 Alcoa Inc. Alliage al-zn-mg-cu a traitement thermique utilise pour des pieces coulees destinees a des applications dans le domaine de l'aerospatiale et de l'automobile
WO2005106057A3 (fr) * 2004-04-22 2006-01-26 Alcoa Inc Alliage al-zn-mg apte au traitement thermique pour pieces coulees automobiles et aerospatiaux
EP1759027A4 (fr) * 2004-04-22 2007-10-03 Alcoa Inc Alliage al-zn-mg-cu a traitement thermique utilise pour des pieces coulees destinees a des applications dans le domaine de l'aerospatiale et de l'automobile
EP1759028A4 (fr) * 2004-04-22 2007-10-03 Alcoa Inc Alliage al-zn-mg apte au traitement thermique pour pieces coulees automobiles et aerospatiaux
EP1768797A2 (fr) * 2004-07-01 2007-04-04 Alcoa Inc. Roue de vehicule en aluminium forge, procede de production et alliage associes
EP1768797A4 (fr) * 2004-07-01 2010-03-17 Alcoa Inc Roue de vehicule en aluminium forge, procede de production et alliage associes
US8083871B2 (en) 2005-10-28 2011-12-27 Automotive Casting Technology, Inc. High crashworthiness Al-Si-Mg alloy and methods for producing automotive casting
US8721811B2 (en) 2005-10-28 2014-05-13 Automotive Casting Technology, Inc. Method of creating a cast automotive product having an improved critical fracture strain
US9353430B2 (en) 2005-10-28 2016-05-31 Shipston Aluminum Technologies (Michigan), Inc. Lightweight, crash-sensitive automotive component
JP2018178246A (ja) * 2017-04-13 2018-11-15 コリア インスティテュート オブ マシーナリー アンド マテリアルズKorea Institute Of Machinery & Materials アルミニウム−亜鉛−銅(Al−Zn−Cu)合金及びその製造方法
CN115449676A (zh) * 2022-10-28 2022-12-09 江苏亚太轻合金科技股份有限公司 一种压铸Al-Zn-Mg-Mn铝合金及其制备方法

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