EP1215276B1 - Detergent composition comprising microdispersed particles containing silicate - Google Patents
Detergent composition comprising microdispersed particles containing silicate Download PDFInfo
- Publication number
- EP1215276B1 EP1215276B1 EP01128892A EP01128892A EP1215276B1 EP 1215276 B1 EP1215276 B1 EP 1215276B1 EP 01128892 A EP01128892 A EP 01128892A EP 01128892 A EP01128892 A EP 01128892A EP 1215276 B1 EP1215276 B1 EP 1215276B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- detergent
- cleaner
- weight
- laundry
- laundry detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 239000003599 detergent Substances 0.000 title claims description 53
- 239000002245 particle Substances 0.000 title claims description 42
- 239000000203 mixture Substances 0.000 title claims description 37
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 title claims description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 45
- -1 antifoams Substances 0.000 claims description 19
- 238000004851 dishwashing Methods 0.000 claims description 14
- 239000007844 bleaching agent Substances 0.000 claims description 10
- 239000008119 colloidal silica Substances 0.000 claims description 10
- 239000002689 soil Substances 0.000 claims description 9
- 239000004569 hydrophobicizing agent Substances 0.000 claims description 8
- 239000003921 oil Substances 0.000 claims description 8
- 229920002545 silicone oil Polymers 0.000 claims description 8
- 108090000790 Enzymes Proteins 0.000 claims description 7
- 102000004190 Enzymes Human genes 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- 239000004615 ingredient Substances 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 5
- 239000003093 cationic surfactant Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 4
- 239000000499 gel Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 239000012190 activator Substances 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 150000004812 organic fluorine compounds Chemical class 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000008139 complexing agent Substances 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 210000002268 wool Anatomy 0.000 claims description 2
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
- 238000004140 cleaning Methods 0.000 description 22
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 18
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 14
- 239000012459 cleaning agent Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 238000003756 stirring Methods 0.000 description 9
- 238000005406 washing Methods 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- 239000002518 antifoaming agent Substances 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 239000000344 soap Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 229920004482 WACKER® Polymers 0.000 description 6
- 229960004106 citric acid Drugs 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 229940088598 enzyme Drugs 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 239000004667 Diesterquat Substances 0.000 description 5
- 108090001146 Nuclear Receptor Coactivator 1 Proteins 0.000 description 5
- 102100037223 Nuclear receptor coactivator 1 Human genes 0.000 description 5
- 229920002125 Sokalan® Polymers 0.000 description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 239000002304 perfume Substances 0.000 description 5
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 4
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 239000000908 ammonium hydroxide Substances 0.000 description 4
- 229960002303 citric acid monohydrate Drugs 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 4
- 229910000271 hectorite Inorganic materials 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 108010075550 termamyl Proteins 0.000 description 4
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 229940071118 cumenesulfonate Drugs 0.000 description 3
- 239000002979 fabric softener Substances 0.000 description 3
- 229940094522 laponite Drugs 0.000 description 3
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 3
- XMMDVXFQGOEOKH-UHFFFAOYSA-N n'-dodecylpropane-1,3-diamine Chemical compound CCCCCCCCCCCCNCCCN XMMDVXFQGOEOKH-UHFFFAOYSA-N 0.000 description 3
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 3
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 3
- 229920000151 polyglycol Polymers 0.000 description 3
- 239000010695 polyglycol Substances 0.000 description 3
- 235000014347 soups Nutrition 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 235000021185 dessert Nutrition 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 235000013372 meat Nutrition 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 108010020132 microbial serine proteinases Proteins 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229910052615 phyllosilicate Inorganic materials 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- ZLIBICFPKPWGIZ-UHFFFAOYSA-N pyrimethanil Chemical compound CC1=CC(C)=NC(NC=2C=CC=CC=2)=N1 ZLIBICFPKPWGIZ-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N 1-Tetradecanol Natural products CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 1
- MMINFSMURORWKH-UHFFFAOYSA-N 3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical class O=C1OCCOC(=O)C2=CC=C1C=C2 MMINFSMURORWKH-UHFFFAOYSA-N 0.000 description 1
- 235000007173 Abies balsamea Nutrition 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 239000004857 Balsam Substances 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 108010084185 Cellulases Proteins 0.000 description 1
- 102000005575 Cellulases Human genes 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 240000004307 Citrus medica Species 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 241000640882 Condea Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 239000004890 Hydrophobing Agent Substances 0.000 description 1
- 244000018716 Impatiens biflora Species 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 244000300264 Spinacia oleracea Species 0.000 description 1
- 235000009337 Spinacia oleracea Nutrition 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 229940025131 amylases Drugs 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical class CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- ZDGGJQMSELMHLK-UHFFFAOYSA-N m-Trifluoromethylhippuric acid Chemical compound OC(=O)CNC(=O)C1=CC=CC(C(F)(F)F)=C1 ZDGGJQMSELMHLK-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N n-hexadecyl alcohol Natural products CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
- 229910000275 saponite Inorganic materials 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003470 sulfuric acid monoesters Chemical class 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical class CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0013—Liquid compositions with insoluble particles in suspension
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
Definitions
- washing and cleaning compositions containing microdisperse silicate-containing particles and a hydrophobizing agent containing microdisperse silicate-containing particles and a hydrophobizing agent
- the invention relates to detergents and cleaners containing silicate-containing, microdispersed hydrophilic particles, and a hydrophobizing agent having high soil release capacity and less Resistant to soiling of the surfaces to be cleaned.
- EP 368 559 describes the use of finely divided silica as Abrasion agents.
- the aforementioned documents relate to the abrasive action of colloidal Silica and its thickening effect in one formulation.
- silicate-containing particles act as surface coating agents used in the Adhering to the surfaces displace the dirt and at the same time through the Coating the surfaces makes their re-soiling difficult. In the repeated use of detergents and cleaners, the effect occurs amplified on.
- Microdispers refers to the particle size of the silicate-containing particles. Particle, in solution or when applied to surfaces not sufficiently small or do not form particles at all, are not suitable for the invention.
- the invention relates to a washing and cleaning agent, characterized characterized in that it comprises microdisperse, hydrophilic silicate-containing particles having a Particle size of 1 to 500 nm, preferably 9 to 50 nm, wherein the Particles around colloidal silica gels, colloidal silica, hectorites, saponites or Mixtures thereof and additionally at least one hydrophobicizing Agent, where the hydrophobizing agents are silicones, Silicone oils, fluorosilicone oils, soil release polymers, cationic surfactants and / or organic fluorine compounds is.
- the particles are preferably electrically charged on their surface.
- the washing and cleaning agent preferably contains 0.01 to 10% by weight. silicate-containing particles, 0.01 to 10 wt .-% hydrophobizing agents and 80 bis 99.8% by weight of other detergent / cleaner ingredients.
- the washing and cleaning agent also contains 0.01 to 10 wt .-% silicate-containing particles, 0.01 to 10% by weight of hydrophobing agents, 0.5 to 60 Wt .-% surfactants and 20 to 99.48 wt .-% other Detergent ingredients.
- the washing and cleaning agent also contains 0.01 to 10 wt .-% silicate-containing particles, 0.5 to 60% by weight of surfactants and 30 to 99.49 % By weight of other detergent / cleaning agent ingredients.
- the washing and cleaning agent preferably also contains builders, cobuilders, Suppliers of alkali, anionic, nonionic, zwitterionic and nonionic Surfactants, antifoaming agents, dispersants, complexing agents, bleaching agents, Bleach activators and catalysts and / or enzymes.
- the washing and cleaning agent is preferably a heavy-duty detergent, Compact heavy-duty detergent, Compact color detergent, heavy-duty detergent low bulk density, special detergents, such as laundry after-treatment, Fabric softeners, stain salts, bleach boosters, curtain washes, Wool detergents, building block detergents and industrial detergents.
- the washing and cleaning agent is also about Hard surface cleaning agents, e.g. Facade, glass, metal, window, Floor and carpet cleaner.
- Hard surface cleaning agents e.g. Facade, glass, metal, window, Floor and carpet cleaner.
- the washing and cleaning agent is also um Hand dishwashing detergents, machine dishwashing detergents, machine dishwashing detergents and Rinse aid.
- the invention also relates to the use of microdispersed, hydrophilic silicate-containing particles having a particle size of 1 to 500 nm, preferably 9 to 50 nm, wherein the particles are colloidal silica gels, colloidal silica sols, hectorites, saponites or mixtures thereof and additionally at least a hydrophobizing agent, wherein the hydrophobizing agents are silicones, silicone oils, fluorosilicone oils, soil release polymers, cationic surfactants and / or organic fluoro-compounds as surface-coating agents for soil release and reducing the tendency to re-soak in detergents and cleaners.
- the particles are preferably electrically charged on their surface.
- the silicate-containing particles on the Surface ionically charged.
- the electrical charge is the dirt better detached and the re-soiling more difficult.
- the silicate-containing particles negatively charged.
- silicate-containing particles are colloidal Kleselsole that of the Clariant GmbH as ®Klebosol and from Bayer as ®Baykisol to be expelled. Also particularly suitable are the synthetic Clay mineral hectorite and saponite from Laporte (®Laponite types), Südchemie (®Optigel) and Clariant GmbH (®SKS-20 and ®SKS-21).
- the silicate-containing particles become simultaneously used with hydrophobizing agents, which enhances soiling and reduces the re-pollution propensity.
- Preferred hydrophobizing agents are silicones, silicone oils and / or Fluorosilicone oils, e.g. the antifoam emulsions ®SE36 and ®SE39, the Antifoam ®S850 and the antifoam powders ®ASP 8, ®ASP 15, ®ASP16, ® ASP 20 and ® ASP 30 from Wacker.
- polyorganosiloxanes e.g. polydimethylsiloxanes
- Polysiloxanes, alkyl-modified siloxanes and amino-functional siloxanes particularly preferred ®Fish CT 34 E (silicone softener emulsions of the company Wacker).
- hydrophobizing agents are so-called soil release polymers, for example polymers of phthalic acid and / or terephthalic acid or derivatives thereof, in particular oligomeric terephthalate esters, polymers of ethylene terephthalates and polyethylene glycol terephthalates or else anionic and / or nonionic derivatives thereof.
- cationic surfactants consisting of mono- (C 8 -C 16 ) -N-alkyl or alkenyl quaternary ammonium salts whose N-positions are occupied by methyl, hydroxymethyl or hydroxypropyl groups. Particularly preferred are distearyldimethylammonium chloride, ditallowdimethylammonium chloride, diethanolamine diester quat, triethanolamine diester quat and alkylhydroxyethyldimethylammonium chloride.
- hydrophobizing agents are fluoro compounds, e.g. the company 3M.
- the detergents and cleaners preferably contain from 0.01 to 10% by weight, particularly preferably 0.1 to 5 wt .-% of silicate-containing particles.
- concentrates containing up to 80 wt .-% of silicate-containing particles contain.
- the weight ratio of Water to silicate-containing particles between 10000 to 1 and 1: 4.
- Nonionic surfactants are alkyl alkoxylates, gluconamides and alkylpolyglycosides particularly preferred.
- alkyl alkoxylates are preferably ethoxylated alcohols, preferably primary alcohols, preferably having 8 to 22 carbon atoms and preferably 1 to 80 EO units per mole of alcohol used, wherein the alcohol radical is linear or preferably methyl-branched in the 2-position or linear and methyl branched Contains radicals in the mixture, as is usually the case in Oxoalkoholresten.
- the preferred ethoxylated alcohols include, for example, C 11 alcohols having 3, 5, 7, 8 and 11 EO units, (C 12 -C 15 ) alcohols having 3, 6, 7, 8, 10 and 13 EO units, respectively , (C 14 -C 15 ) -alcohols having 4, 7 or 8 EO units, (C 16 -C 18 ) -alcohols having 8, 11, 15, 20, 25, 50 or 80 EO units and mixtures the same.
- the degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number.
- it is also possible to use fatty alcohol EO / PO adducts for example the ®Genapol types 3970, 2909 and 2822 from Clariant GmbH.
- Suitable surfactants are polyhydroxy fatty acid amides of the formula R 2 -CO-N (R 3 ) -Z, in which R 2 CO is an aliphatic acyl radical having 6 to 22 carbon atoms, R 3 is hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms and Z is a linear or branched polyhydroxyalkyl radical having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups.
- alkyl glycosides of the general formula RO (G) x in which R is a primary straight-chain or methyl-branched, in particular 2-methyl-branched, aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms, and G is a glycose unit having 5 or 6 carbon atoms, preferably glucose.
- the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; preferably x is 1.2 to 1.4.
- Suitable anionic surfactants of the sulfonate type are preferably the known (C 9 -C 13 ) -alkylbenzenesulfonates, alpha-olefinsulfonates and alkanesulfonates. Also suitable are esters of sulfo fatty acids or the disalts of the alpha-sulfo fatty acids. Other suitable anionic surfactants are sulfated Fettklareglycerinester which mono-, di- and triesters and mixtures thereof, as in the preparation by esterification by 1 mole of monoglycerol with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 Mole of glycerol can be obtained.
- alkyl sulfates are the sulfuric acid monoesters of (C 12 -C 18 ) -fatty alcohols, such as lauryl, myristyl, cetyl or stearyl alcohol, and the fatty alcohol mixtures obtained from coconut oil, palm and palm kernel oil, which additionally contain portions of unsaturated alcohols, For example, oleyl alcohol may contain.
- anionic surfactants are particularly soaps into consideration. Suitable are saturated fatty acid soaps, such as the salts of lauric acid, myristic acid, Palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid, as well especially from natural fatty acids, e.g. Coconut, palm kernel or Tallow fatty acids, derived soap mixtures.
- the anionic surfactants can be used in Form their sodium, potassium or ammonium salts, as well as soluble salts organic bases, such as mono-, di- or triethanolamine.
- the anionic surfactants are in the form of their sodium or potassium salts, especially in the form of the sodium salts.
- the buildem are preferably crystalline aluminosilicates, Alkali metal carbonates, alkali ortho, alkali pyro and alkali polyphosphates, crystalline Phyllosilicates, crystalline alkali metal silicates without layer structure and / or X-ray amorphous alkali silicates.
- the co-builders are preferably monomeric, oligomeric, polymeric or copolymeric carboxylic acids.
- the bleaching systems are preferably active chlorine carriers and / or organic or inorganic active oxygen carriers, bleach activators (e.g., TAED), Bleach catalysts, removal of discoloration, perborates and / or Percarbonates.
- bleach activators e.g., TAED
- Bleach catalysts removal of discoloration, perborates and / or Percarbonates.
- the pH regulators are preferably soda, citric acid, Sodium citrate and / or bicarbonate.
- detergents and cleaners may also contain enzymes, such as. Proteases, amylases, lipases and cellulases.
- the detergents and cleaners can be used to treat fiber and fiber Textile surfaces, but also for the treatment of hard surfaces from the various materials, e.g. Metals, glass, ceramics, plastics etc., be used.
- Further preferred cleaning agents are automotive and paint cleaners for the manual application and for automatic use in car washes.
- compositions of the agents according to the invention are specified in percent by weight.
- the Gardnertest is a cleaning test for hard surfaces, mainly floors etc ..
- test strips maximal 45cm long and 5-6 cm wide
- the cleaning solution add 10 g of the cleaning solution to the strip and attach a piece of wipe to a holder.
- the cloth is driven by tensioning cables, driven by an eccentric, back and forth on the prepared sample strip.
- the number of swipes is read on a counter.
- the number of wiping movements is evaluated up to the absolute cleanliness, or after a maximum of 50 wiping movements the rating of the cleaning result on the scale of 1 (clean) to 5.
- the rating 50/3 means here that after the maximum number of 50 wipes the matching gave the grade 3 on the scale of 1 to 5.
- the rating 5/1 means here that after only 5 wipes the matching gave the grade 1 (clean) on the scale from 1 to 5.
- Ceramic wall tiles and PVC floor tiles were used as surfaces. As stains were Edding permanent pen, marking pencil and pencil (Graphite) used.
- the stains were:
- the measurements were arithmetically averaged and averaged Scale spread from 0 to 100%.
- Example 1 As in Example 1, a general-purpose cleaner was prepared. In addition, with the Water Klebosol 30 V 25 added. This can be compared to the Gardner test Example 1, an improvement of the cleaning effect can be achieved.
- Table 1 The Composition and results are shown in Table 1.
- Example 1 As in Example 1, a general-purpose cleaner was prepared. In addition, with the Water hectorite SKS-21 added. This can be compared to the Gardner test Example 1, an improvement of the cleaning effect can be achieved. The Composition and results are shown in Table 1.
- Example 1 As in Example 1, a general-purpose cleaner was prepared. In addition, with the Water Klebosol 30 V 25 and with the cumenesulfonate TexCare SRC-1 dispersion added. This can be in the Gardner test compared to Examples 1 to 3 an improvement of the cleaning effect can be achieved. The composition and the results are shown in Table 1.
- a tile / bathroom cleaner was made by adding isopropanol and water mixed together. Then Genapol UD 080, Hordaphos CC MS and Hostapur SAS 60 with vigorous stirring and finally citric acid monohydrate admixed. The detergency was tested using the Gardner test. The composition and the results are shown in Table 1.
- Example 5 As in Example 5, a tile / bathroom cleaner was made. It was also with Klebosol 20 H 12 was added to the water. This can be seen in the Gardner test in the Compared to Example 5 an improvement of the cleaning effect can be achieved.
- the composition and the results are shown in Table 1.
- Example 5 As in Example 5, a tile / bathroom cleaner was made. It was also with Add to the water Klebosol 20 H 12 and with the Citric Acid Finish CT 34 E. This can be in the Gardner test compared to Examples 5 and 6 a Improvement of the cleaning effect can be achieved. The composition and the results are shown in Table 1.
- a hand dishwashing detergent was prepared by using Hostapur SAS 60 Water and Klebosol 30 R 12 was mixed. Then Genagen CAB 818, Genapol UD 080 and Genapol ZRO liquid mixed with slow stirring. The Composition is listed in Table 2.
- a window cleaner was made by using Genapol LRO liquid with water and Klebosol 30 N 12 was mixed. Then ammonium hydroxide and Isopropanol mixed with stirring. The composition is in Table 2 listed.
- a window cleaner was made by using Genapol LRO liquid with water and Klebosol 30 N 12 was mixed. Then ammonium hydroxide, isopropanol and finish CT 34 E while stirring. The composition is in table 2 listed.
- An all-purpose cleaner was made by using Genapol UD 080 with Hostapur SAS 60 was mixed. Then water, Klebosol 30 R 12 and propylene glycol n-butyl ether mixed with stirring. The composition is in Table 2 listed.
- a flow / bath cleaner was made by adding isopropanol with water was mixed. Then Genapol UD 080, Hordaphos CC MS and Hostapur SAS 60 and finally Klebosol 30H25 mixed with stirring. The Composition is listed in Table 2.
- a cleaner for car washes was manufactured by Genapol UD 110 and Genapol UD 50 were successively dissolved in water. Then, Klebosol became 30 R 12 mixed. The composition is listed in Table 2.
- a desiccant for car washes was made by successively butyldiglycol, acetic acid, conc., Genamin LAP 100 D and Praepagen 4317 were mixed. Then water and Klebosol 30 H 25 were added.
- the Composition is listed in Table 2.
- a machine dishwashing rinse was made by successively Citric acid, cumene sulfonate, Genapol 2908 and Klebosol 30 H 25 in water were solved. According to the general rule implementation of Machine dishwashing tests were dishes with a commercial Rinsed tablet-dishwashing detergent. The rinse aid was the above formulation used. This procedure of cleaning and rinsing was repeated repeated and the dishes are then scrapped. The composition and the Results are listed in Table 3.
- Example 16 As in Example 16, a machine dishwashing rinse aid is prepared. additionally Klebosol 30 H 25 is mixed in. According to the general rule implementation The machine dishwashing tests were dishes twice with a rinsed with commercially available tablet-dishwashing detergent and with the rinse aid treated. The use of silica sol gives clear advantages for the Cleaning effect. The composition and the results are in Table 3 listed.
- Example 19 The composition is listed in Table 4.
- a liquid detergent is prepared by stirring vigorously Alkylbenzenesulfonate, citric acid, Genapol 3070, soap, water, silicone oil, Phosphonate, polyglycol ether and Klebosol 30 V 50 mixes.
- the composition is listed in Table 4.
- a powder detergent is prepared by adding in a Ploughshare mixer Fa. Lödige Antifoam, phyllosilicate, soda, Sokalan CP5 and Zeolite A and Genapol 3070 sprayed on. The remaining components are mixed in for a short time. The composition is listed in Table 4.
- a fabric softener is prepared by stirring at 50 to 60 ° C First Lapnite RD and then Praepagen WK are dissolved in water.
- the Composition is listed in Table 4.
- a fabric softener is prepared by dissolving molten triethanolamine diesterquat (85%) in preheated water at 50 ° C, then stirring Genapol UD 088 and cooling the solution. Finally, TexCare SRC-1 dispersion and Klebosol 30 V 50 are stirred in.
- Genagen CAB 818 10 Genamin LAP 100 D 2 Genapol LRO liquid 0.5 0.5 Genapol O 020 5 Genapol DU 080 3 9 0.5 Genapol DU 110 10 Genapol DU 50 3 Genapol X 080 2 Genapol ZRO liquid 22.9 Hoechst wax KST 4 Hordaphos CC MS 1 Hostapur SAS 60 42.7 8.3 3 isopropanol 29 29 3 Praepagen 4317 10 Praepagen WKT 11 Propylene glycol n-butyl ether 3 spindle oil 6 water 19.4 69 68 75.7 88.5 86 59.2 57 Klebosol 30 R 12 2 2 1 5 Klebosol 30 H 25 1 5 Klebosol 30 N 12 1 1 Finish CT 34 E 1 dosage 1: 1000 1: 1000 1: 500 example 16 17 Components [%] See citric acid 3 3 Cumene sulphonate, 40% 8th 8th Genapol 2908 14 14 water 75 74 Klebosol 30 H 25
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
Wasch- und Reinigungsmittel, enthaltend mikrodisperse silikathaltige Partikel und ein hydrophobierendes AgensWashing and cleaning compositions containing microdisperse silicate-containing particles and a hydrophobizing agent
Die Erfindung betrifft Wasch- und Reinigungsmittel, enthaltend silikathaltige, mikrodisperse hydrophile Partikel, und ein hydrophobierendes Agens mit hohem Schmutzablösevermögen und geringer Wiederanschmutzneigung der zu reinigenden Oberflächen.The invention relates to detergents and cleaners containing silicate-containing, microdispersed hydrophilic particles, and a hydrophobizing agent having high soil release capacity and less Resistant to soiling of the surfaces to be cleaned.
In WO 99/00457 ist eine Fassadenbeschichtung beschrieben, die die Verschmutzungsneigung von Fassaden verringert.In WO 99/00457 a facade coating is described which the Pollution tendency of facades reduced.
In EP 252 708 wird gefunden, dass der Zusatz von kolloider Kieselsäure zu Klarspülmitteln die Abtrocknungszeit verringert.In EP 252 708 it is found that the addition of colloidal silica to Rinse aids reduces the drying time.
EP 368 559 beschreibt den Einsatz von fein verteilter Kieselsäure als Abrasionsmittel.EP 368 559 describes the use of finely divided silica as Abrasion agents.
DE 2 809 371 beschreibt den Einsatz von Polydimethylsiloxan und kolloider Kieselsäure, die als Abrasiv wirkt.DE 2 809 371 describes the use of polydimethylsiloxane and colloids Silica, which acts as an abrasive.
Die vorgenannten Schriften beziehen sich auf die abrasive Wirkung von kolloidaler Kieselsäure und ihre verdickende Wirkung in einer Formulierung.The aforementioned documents relate to the abrasive action of colloidal Silica and its thickening effect in one formulation.
Überraschenderweise wurde nun gefunden, dass der Zusatz von mikrodispersen, hydrophilen silikathaltigen Partikeln zu Wasch- und Reinigungsmitteln die Schmutzablösung erleichtert, die Reinigungswirkung erhöht und die Wiederanschmutzung der so behandelten Oberflächen verringert.Surprisingly, it has now been found that the addition of microdispersed, hydrophilic silicate-containing particles to detergents and cleaners the Facilitates soil removal, increases the cleaning effect and the Reduced soiling of the thus treated surfaces.
Die silikathaltigen Partikeln wirken als Oberflächenbeschichtungsmittel, die bei der Anlagerung an die Oberflächen den Schmutz verdrängen und gleichzeitig durch die Beschichtung der Oberflächen deren Wiederanschmutzung erschweren. Bei der wiederholten Anwendung der Wasch- und Reinigungsmittel tritt der Effekt verstärkt auf.The silicate-containing particles act as surface coating agents used in the Adhering to the surfaces displace the dirt and at the same time through the Coating the surfaces makes their re-soiling difficult. In the repeated use of detergents and cleaners, the effect occurs amplified on.
Wesentlich für die silikathaltigen Partikel ist ihre Fähigkeit in wässriger Dispersion und/oder beim Aufbringen auf Oberflächen hinreichend kleine Teilchen zu bilden. Mikrodispers bezieht sich auf die Teilchengröße der silikathaltigen Partikel. Partikel, die in Lösung bzw. beim Aufbringen auf Oberflächen keine hinreichend kleinen oder gar keine Partikel bilden, eignen sich nicht für die Erfindung.Essential for the silicate-containing particles is their ability in aqueous dispersion and / or to form sufficiently small particles when applied to surfaces. Microdispers refers to the particle size of the silicate-containing particles. Particle, in solution or when applied to surfaces not sufficiently small or do not form particles at all, are not suitable for the invention.
Gegenstand der Erfindung ist ein Wasch- und Reinigungsmittel, dadurch gekennzeichnet, dass es mikrodisperse, hydrophile silikathaltige Partikel mit einer Teilchengröße von 1 bis 500 nm, bevorzugt 9 bis 50 nm, wobei es sich bei den Partikeln um kolloidale Kieselgele, kolloidale Kieselsoie, Hectorite, Saponite oder Mischungen derselben handelt sowie zusätzlich mindestens ein hydrophobierendes Agens enthält, wobei es sich bei den hydrophobierenden Agenzien um Silicone, Siliconöle, Fluorsiliconöle, Soil-release-Polymere, kationische Tenside und/oder organische Fluorverbindungen handelt.The invention relates to a washing and cleaning agent, characterized characterized in that it comprises microdisperse, hydrophilic silicate-containing particles having a Particle size of 1 to 500 nm, preferably 9 to 50 nm, wherein the Particles around colloidal silica gels, colloidal silica, hectorites, saponites or Mixtures thereof and additionally at least one hydrophobicizing Agent, where the hydrophobizing agents are silicones, Silicone oils, fluorosilicone oils, soil release polymers, cationic surfactants and / or organic fluorine compounds is.
Bevorzugt sind die Partikel an ihrer Oberfläche elektrisch geladen.The particles are preferably electrically charged on their surface.
Bevorzugt beträgt das Gewichts-Verhältnis von silicathaltigen Partikeln zu hydrophobierenden Agenzien 100 zu 1 bis 1 zu 100, bezogen auf Aktivsubstanz.Preferably, the weight ratio of silicate-containing particles to hydrophobizing agents 100 to 1 to 1 to 100, based on the active substance.
Bevorzugt enthält das Wasch- und Reinigungsmittel 0,01 bis 10 Gew.-% silicathaltige Partikel, 0,01 bis 10 Gew.-% hydrophobierende Agenzien und 80 bis 99,8 Gew.-% sonstige Waschmittel-/Reinigungsmittelinhaltsstoffe.The washing and cleaning agent preferably contains 0.01 to 10% by weight. silicate-containing particles, 0.01 to 10 wt .-% hydrophobizing agents and 80 bis 99.8% by weight of other detergent / cleaner ingredients.
Bevorzugt enthält das Wasch- und Reinigungsmittel auch 0,01 bis 10 Gew.-% silicathaltige Partikel, 0,01 bis 10 Gew.-% hydrophobierende Agenzien, 0,5 bis 60 Gew.-% grenzflächenaktive Stoffe und 20 bis 99,48 Gew.-% sonstige Waschmittelinhaltsstoffe.Preferably, the washing and cleaning agent also contains 0.01 to 10 wt .-% silicate-containing particles, 0.01 to 10% by weight of hydrophobing agents, 0.5 to 60 Wt .-% surfactants and 20 to 99.48 wt .-% other Detergent ingredients.
Bevorzugt enthält das Wasch- und Reinigungsmittel auch 0,01 bis 10 Gew.-% silicathaltige Partikel, 0,5 bis 60 Gew.-% grenzflächenaktive Stoffe und 30 bis 99,49 Gew.-% sonstige Waschmittel-/Reinigungsmittelinhaltsstoffe.Preferably, the washing and cleaning agent also contains 0.01 to 10 wt .-% silicate-containing particles, 0.5 to 60% by weight of surfactants and 30 to 99.49 % By weight of other detergent / cleaning agent ingredients.
Bevorzugt enthält das Wasch- und Reinigungsmittel weiterhin Builder, Cobuilder, Alkalilieferanten, anionische, nichtionische, zwitterionische und nichtionische Tenside, Antischaummittel, Dispergatoren, Komplexbildner, Bleichmittel, Bleichaktivatoren und -katalysatoren und/oder Enzyme.The washing and cleaning agent preferably also contains builders, cobuilders, Suppliers of alkali, anionic, nonionic, zwitterionic and nonionic Surfactants, antifoaming agents, dispersants, complexing agents, bleaching agents, Bleach activators and catalysts and / or enzymes.
Bevorzugt handelt es sich bei dem Wasch- und Reinigungsmittel um Vollwaschmittel, Compact-Vollwaschmittel, Compact-Colorwaschmittel, Vollwaschmittel geringer Schüttdichte, Spezialwaschmittel, wie Wäschenach-behandlungsmittel, Wäscheweichmacher, Fleckensalze, Bleichbooster, Gardinenwaschmittel, Wollwaschmittel, Baukasten-Waschmittel und gewerbliche Waschmittel.The washing and cleaning agent is preferably a heavy-duty detergent, Compact heavy-duty detergent, Compact color detergent, heavy-duty detergent low bulk density, special detergents, such as laundry after-treatment, Fabric softeners, stain salts, bleach boosters, curtain washes, Wool detergents, building block detergents and industrial detergents.
Bevorzugt handelt es sich bei dem Wasch- und Reinigungsmittel auch um Reinigungsmittel für harte Oberflächen, z.B. Fassaden-, Glas-, Metall, Fenster-, Fußboden- und Teppichbodenreiniger.Preferably, the washing and cleaning agent is also about Hard surface cleaning agents, e.g. Facade, glass, metal, window, Floor and carpet cleaner.
Bevorzugt handelt es sich bei dem Wasch- und Reinigungsmittel aber auch um Handgeschirrspülmittel, Maschinengeschirreiniger, Maschinengeschirrspülmittel und Klarspüler.Preferably, however, the washing and cleaning agent is also um Hand dishwashing detergents, machine dishwashing detergents, machine dishwashing detergents and Rinse aid.
Die Erfindung betrifft auch die Verwendung von mikrodispersen, hydrophilen
silikathaltigen Partikeln mit einer Teilchengröße von 1 bis 500 nm, bevorzugt 9 bis
50 nm, wobei es sich bei den Partikeln um kolloidale Kieselgele, kolloidale
Kieselsole, Hectorite, Saponite oder Mischungen derselben handelt sowie zusätzlich
mindestens ein hydrophobierendes Agens, wobei es sich bei den
hydrophobierenden Agenzien um Silicone, Siliconöle, Fluorsiliconöle, Soil-release-Polymere,
kationische Tenside und/oder organische Fluorverbindungen handelt als
Oberflächenbeschichtungsmittel zur Schmutzablösung und Verringerung der
Wiederanschmutzneigung in Wasch- und Reinigungsmitteln.
Bevorzugt sind bei der vorgenannten Verwendung die Partikel an ihrer Oberfläche
elektrisch geladen. The invention also relates to the use of microdispersed, hydrophilic silicate-containing particles having a particle size of 1 to 500 nm, preferably 9 to 50 nm, wherein the particles are colloidal silica gels, colloidal silica sols, hectorites, saponites or mixtures thereof and additionally at least a hydrophobizing agent, wherein the hydrophobizing agents are silicones, silicone oils, fluorosilicone oils, soil release polymers, cationic surfactants and / or organic fluoro-compounds as surface-coating agents for soil release and reducing the tendency to re-soak in detergents and cleaners.
In the above-mentioned use, the particles are preferably electrically charged on their surface.
In einer bevorzugten Ausführungsform sind die silikathaltigen Partikel an der Oberfläche ionisch geladen. Durch die elektrische Aufladung wird der Schmutz besser abgelöst und die Wiederanschmutzung erschwert. Bevorzugt sind die silikathaltigen Partikel negativ geladen.In a preferred embodiment, the silicate-containing particles on the Surface ionically charged. By the electrical charge is the dirt better detached and the re-soiling more difficult. Preferred are the silicate-containing particles negatively charged.
Besonders bevorzugt als silikathaltige Partikel sind kolloide Kleselsole, die von der Firma Clariant GmbH als ®Klebosol und von der Firma Bayer als ®Baykisol vertrieben werden. Weiterhin besonders geeignet sind auch die synthetischen Tonminerale Hectorit und Saponit der Firmen Laporte (®Laponite-Typen), Südchemie (®Optigel) und Clariant GmbH (®SKS-20 und ®SKS-21).Particularly preferred as silicate-containing particles are colloidal Kleselsole that of the Clariant GmbH as ®Klebosol and from Bayer as ®Baykisol to be expelled. Also particularly suitable are the synthetic Clay mineral hectorite and saponite from Laporte (®Laponite types), Südchemie (®Optigel) and Clariant GmbH (®SKS-20 and ®SKS-21).
Die silikathaltigen Partikel werden gleichzeitig mit hydrophobierenden Agenzien verwendet, was die Schmutzablösung verstärkt und die Wiederanschmutzneigung verringert.The silicate-containing particles become simultaneously used with hydrophobizing agents, which enhances soiling and reduces the re-pollution propensity.
Bevorzugte hydrophobierende Agenzien sind Silicone, Siliconöle und/oder Fluorsiliconöle, z.B. die Antischaumemulsionen ®SE36 und ®SE39, das Antischaummittel ®S850 und die Antischaumpulver ®ASP 8, ®ASP 15, ®ASP16, ®ASP 20 und ®ASP30 der Firma Wacker.Preferred hydrophobizing agents are silicones, silicone oils and / or Fluorosilicone oils, e.g. the antifoam emulsions ®SE36 and ®SE39, the Antifoam ®S850 and the antifoam powders ®ASP 8, ®ASP 15, ®ASP16, ® ASP 20 and ® ASP 30 from Wacker.
Weiterhin bevorzugt geeignet sind Polyorganosiloxane, wie z.B. Polydimethylsiloxane, Polysiloxane, alkylmodifizierte Siloxane und aminofunktionelle Siloxane, besonders bevorzugt ®Finish CT 34 E (Siliconweichmacher-Emulsionen der Firma Wacker).Also preferred are polyorganosiloxanes, e.g. polydimethylsiloxanes Polysiloxanes, alkyl-modified siloxanes and amino-functional siloxanes, particularly preferred ®Fish CT 34 E (silicone softener emulsions of the company Wacker).
Weiterhin geeignet als hydrophobierende Agenzien sind sogenannte Soil-release-Polymere,
z.B. Polymere der Phthalsäure und/oder der Terephthalsäure bzw. deren
Derivaten, insbesondere oligomere Terephthalatester, Polymere aus
Ethylenterephthalaten und Polyethylenglykolterephthalaten oder auch anionische
und/oder nichtionische Derivate derselben.
Als hydrophobierende Agenzien weiterhin geeignet sind kationische Tenside
bestehend aus quaternären Mono-(C8-C16)-N-Alkyl oder -Alkenyl Ammoniumsalzen,
deren N-Positionen mit Methyl-, Hydroxymethyl- oder Hydroxypropylgruppen besetzt
sind. Besonders bevorzugt sind Distearyldimethylammoniumchlorid,
Ditalgdimethylammoniumchlorid, Diethanolamindiesterquat,
Triethanolamindiesterquat und Alkylhydroxyethyldimethylammoniumchlorid.Also suitable as hydrophobizing agents are so-called soil release polymers, for example polymers of phthalic acid and / or terephthalic acid or derivatives thereof, in particular oligomeric terephthalate esters, polymers of ethylene terephthalates and polyethylene glycol terephthalates or else anionic and / or nonionic derivatives thereof.
Also suitable as hydrophobizing agents are cationic surfactants consisting of mono- (C 8 -C 16 ) -N-alkyl or alkenyl quaternary ammonium salts whose N-positions are occupied by methyl, hydroxymethyl or hydroxypropyl groups. Particularly preferred are distearyldimethylammonium chloride, ditallowdimethylammonium chloride, diethanolamine diester quat, triethanolamine diester quat and alkylhydroxyethyldimethylammonium chloride.
Als hydrophobierenden Agenzien ebenfalls geeignet sind Fluorverbindungen, z.B. die der Firma 3M.Also suitable as hydrophobizing agents are fluoro compounds, e.g. the company 3M.
Bevorzugt enthalten die Wasch- und Reinigungsmittel 0,01 bis 10 Gew.-%, besonders bevorzugt 0,1 bis 5 Gew.-%an silikathaltigen Partikeln.The detergents and cleaners preferably contain from 0.01 to 10% by weight, particularly preferably 0.1 to 5 wt .-% of silicate-containing particles.
Bevorzugt sind auch Konzentrate, die bis zu 80 Gew.-% an silikathaltigen Partikeln enthalten. In den Wasch- und Reinigungsmitteln beträgt das Gewichtsverhältnis von Wasser zu silikathaltigen Partikeln zwischen 10000 zu 1 und 1:4.Also preferred are concentrates containing up to 80 wt .-% of silicate-containing particles contain. In the detergents and cleaning agents, the weight ratio of Water to silicate-containing particles between 10000 to 1 and 1: 4.
Als nichtionische Tenside sind Alkylalkoxylate, Gluconamide und Alkylpolyglycoside besonders bevorzugt.Nonionic surfactants are alkyl alkoxylates, gluconamides and alkylpolyglycosides particularly preferred.
Unter den Alkylalkoxylaten werden bevorzugt ethoxylierte Alkohole, bevorzugt
primäre Alkohole, mit bevorzugt 8 bis 22 C-Atomen und bevorzugt 1 bis 80 EO-Einheiten
pro Mol Alkohol, eingesetzt, wobei der Alkoholrest linear oder bevorzugt in
2-Stellung methylverzweigt ist oder lineare und methylverzweigte Reste im Gemisch
enthält, so wie dies üblicherweise in Oxoalkoholresten der Fall ist. Zu den
bevorzugten ethoxylierten Alkoholen gehören beispielsweise C11-Alkohole mit 3, 5,
7, 8 und 11 EO-Einheiten, (C12-C15)-Alkohole mit 3, 6, 7, 8, 10 bzw. 13 EO-Einheiten,
(C14-C15)-Alkohole mit 4, 7 bzw. 8 EO-Einheiten, (C16-C18)-Alkohole mit 8,
11, 15, 20, 25, 50 bzw. 80 EO-Einheiten und Mischungen derselben. Die
angegebenen Ethoxylierungsgrade stellen statistische Mittelwerte dar, die für ein
spezielles Produkt eine ganze oder eine gebrochene Zahl sein können. Zusätzlich
zu diesen können auch Fettalkohol-EO/PO-Addukte eingesetzt werden, wie z.B. die
®Genapol-Typen 3970, 2909 und 2822 der Fa. Clariant GmbH.
Weitere geeignete Tenside sind Polyhydroxyfettsäureamide der Formel R2-CO-N(R3)-Z,
in der R2CO für einen aliphatischen Acylrest mit 6 bis 22
Kohlenstoffatomen, R3 für Wasserstoff, einen Alkyl oder Hydroxyalkylrest mit 1 bis 4
Kohlenstoffatomen und Z für einen linearen oder verzweigten Polyhydroxyalkylrest
mit 3 bis 10 Kohlenstoffatomen und 3 bis 10 Hydroxylgruppen steht.
Bevorzugt können Alkylglykoside der allgemeinen Formel RO(G)x eingesetzt
werden, in der R einen primären geradkettigen oder methylverzweigten,
insbesondere in 2-Stellung methylverzweigten aliphatischen Rest mit 8 bis 22,
vorzugsweise 12 bis 18 Kohlenstoffatomen, bedeutet und G für eine Glykoseeinheit
mit 5 oder 6 Kohlenstoffatomen, vorzugsweise für Glucose, steht. Der
Oligomerisierungsgrad x, der die Verteilung von Monoglykosiden und
Oligoglykosiden angibt, ist eine beliebige Zahl zwischen 1 und 10; vorzugsweise liegt
x bei 1,2 bis 1,4.Among the alkyl alkoxylates are preferably ethoxylated alcohols, preferably primary alcohols, preferably having 8 to 22 carbon atoms and preferably 1 to 80 EO units per mole of alcohol used, wherein the alcohol radical is linear or preferably methyl-branched in the 2-position or linear and methyl branched Contains radicals in the mixture, as is usually the case in Oxoalkoholresten. The preferred ethoxylated alcohols include, for example, C 11 alcohols having 3, 5, 7, 8 and 11 EO units, (C 12 -C 15 ) alcohols having 3, 6, 7, 8, 10 and 13 EO units, respectively , (C 14 -C 15 ) -alcohols having 4, 7 or 8 EO units, (C 16 -C 18 ) -alcohols having 8, 11, 15, 20, 25, 50 or 80 EO units and mixtures the same. The degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number. In addition to these, it is also possible to use fatty alcohol EO / PO adducts, for example the ®Genapol types 3970, 2909 and 2822 from Clariant GmbH.
Further suitable surfactants are polyhydroxy fatty acid amides of the formula R 2 -CO-N (R 3 ) -Z, in which R 2 CO is an aliphatic acyl radical having 6 to 22 carbon atoms, R 3 is hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms and Z is a linear or branched polyhydroxyalkyl radical having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups.
Preference is given to using alkyl glycosides of the general formula RO (G) x in which R is a primary straight-chain or methyl-branched, in particular 2-methyl-branched, aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms, and G is a glycose unit having 5 or 6 carbon atoms, preferably glucose. The degree of oligomerization x, which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; preferably x is 1.2 to 1.4.
Bevorzugt sind auch alkoxylierte, vorzugsweise ethoxylierte oder ethoxylierte und propoxylierte, Fettsäurealkylester, vorzugsweise mit 1 bis 4 Kohlenstoffatomen in der Alkylkette, insbesondere Fettsäuremethylester, wie sie beispielsweise in der japanischen Patentanmeldung JP 58/217598 beschrieben sind, oder vorzugsweise solche wie sie nach dem in der internationalen Patentanmeldung WO A 90/13533 beschriebenen Verfahren hergestellt werden.Also preferred are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated, fatty acid alkyl esters, preferably having 1 to 4 carbon atoms in the alkyl chain, in particular fatty acid methyl ester, as described for example in the Japanese Patent Application JP 58/217598, or preferably such as those described in International patent application WO A 90/13533 be prepared described methods.
Als anionische Tenside vom Sulfonat-Typ kommen vorzugsweise die bekannten (C9-C13)-Alkylbenzolsulfonate, alpha-Olefinsulfonate und Alkansulfonate in Betracht. Geeignet sind auch Ester von Sulfofettsäuren bzw. die Disalze der alpha-Sulfofettsäuren. Weitere geeignete anionische Tenside sind sulfierte Fettsäureglycerinester, welche Mono-, Di- und Triester sowie deren Gemische darstellen, wie sie bei der Herstellung durch Veresterung durch 1 Mol Monoglycerin mit 1 bis 3 Mol Fettsäure oder bei der Umesterung von Triglyceriden mit 0,3 bis 2 Mol Glycerin erhalten werden. Als Alkylsulfate eignen sich insbesondere die Schwefelsäuremonoester der (C12-C18)-Fettalkohole, wie Lauryl-, Myristyl-, Cetyl- oder Stearylalkohol, und die aus Kokosöl, Palm- und Palmkernöl gewonnenen Fettalkoholgemische, die zusätzlich noch Anteile an ungesättigten Alkoholen, z.B. Oleylalkohol, enthalten können.Suitable anionic surfactants of the sulfonate type are preferably the known (C 9 -C 13 ) -alkylbenzenesulfonates, alpha-olefinsulfonates and alkanesulfonates. Also suitable are esters of sulfo fatty acids or the disalts of the alpha-sulfo fatty acids. Other suitable anionic surfactants are sulfated Fettsäureglycerinester which mono-, di- and triesters and mixtures thereof, as in the preparation by esterification by 1 mole of monoglycerol with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 Mole of glycerol can be obtained. Particularly suitable as alkyl sulfates are the sulfuric acid monoesters of (C 12 -C 18 ) -fatty alcohols, such as lauryl, myristyl, cetyl or stearyl alcohol, and the fatty alcohol mixtures obtained from coconut oil, palm and palm kernel oil, which additionally contain portions of unsaturated alcohols, For example, oleyl alcohol may contain.
Als weitere anionische Tenside kommen insbesondere Seifen in Betracht. Geeignet sind gesättigte Fettsäureseifen, wie die Salze der Laurinsäure, Myristinsäure, Palmitinsäure, Stearinsäure, hydrierten Erucasäure und Behensäure, sowie insbesondere aus natürlichen Fettsäuren, z.B. Kokos-, Palmkern- oder Talgfettsäuren, abgeleitete Seifengemische. Die anionischen Tenside können in Form ihrer Natrium-, Kalium- oder Ammoniumsalze, sowie als lösliche Salze organischer Basen, wie Mono-, Di- oder Triethanolamin, vorliegen. Vorzugsweise liegen die anionischen Tenside in Form ihrer Natrium- oder Kaliumsalze, insbesondere in Form der Natriumsalze, vor.As further anionic surfactants are particularly soaps into consideration. Suitable are saturated fatty acid soaps, such as the salts of lauric acid, myristic acid, Palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid, as well especially from natural fatty acids, e.g. Coconut, palm kernel or Tallow fatty acids, derived soap mixtures. The anionic surfactants can be used in Form their sodium, potassium or ammonium salts, as well as soluble salts organic bases, such as mono-, di- or triethanolamine. Preferably the anionic surfactants are in the form of their sodium or potassium salts, especially in the form of the sodium salts.
Bei den Buildem handelt es sich bevorzugt um kristalline Aluminosilikate, Alkalicarbonate, Alkaliortho-, Alkalipyro- und Alkalipolyphosphate, kristalline Schichtsilikate, kristalline Alkalisilikate ohne Schichtstruktur und/oder röntgenamorphe Alkalisilikate.The buildem are preferably crystalline aluminosilicates, Alkali metal carbonates, alkali ortho, alkali pyro and alkali polyphosphates, crystalline Phyllosilicates, crystalline alkali metal silicates without layer structure and / or X-ray amorphous alkali silicates.
Bei den Cobuildem handelt es sich bevorzugt um monomere, oligomere, polymere oder copolymere Carbonsäuren.The co-builders are preferably monomeric, oligomeric, polymeric or copolymeric carboxylic acids.
Bei den Bleichsystemen handelt es sich bevorzugt um Aktivchlorträger und/oder organische oder anorganische Aktivsauerstoffträger, Bleichaktivatoren (z.B. TAED), Bleichkatalysatoren, Enzyme zur Entfernung von Verfärbungen, Perborate und/oder Percarbonate.The bleaching systems are preferably active chlorine carriers and / or organic or inorganic active oxygen carriers, bleach activators (e.g., TAED), Bleach catalysts, removal of discoloration, perborates and / or Percarbonates.
Bei den pH-Regulatoren handelt es sich bevorzugt um Soda, Zitronensäure, Natriumcitrat und/oder Bicarbonat.The pH regulators are preferably soda, citric acid, Sodium citrate and / or bicarbonate.
Schließlich können die Wasch- und Reinigungsmittel gegebenenfalls noch Enzyme, wie z.B. Proteasen, Amylasen, Lipasen und Cellulaseen, enthalten.Finally, the detergents and cleaners may also contain enzymes, such as. Proteases, amylases, lipases and cellulases.
Die Wasch- und Reinigungsmittel können zur Behandlung von Faser- und Textiloberflächen, aber auch zur Behandlung harter Oberflächen aus den verschiedensten Materialien, z.B. Metallen, Glas, Keramiken, Kunststoffen etc., eingesetzt werden.The detergents and cleaners can be used to treat fiber and fiber Textile surfaces, but also for the treatment of hard surfaces from the various materials, e.g. Metals, glass, ceramics, plastics etc., be used.
Weiterhin bevorzugte Reinigungsmitteln sind Automobil- und Lackreiniger für die manuelle Anwendung und für die automatische Anwendung in Waschstraßen. Further preferred cleaning agents are automotive and paint cleaners for the manual application and for automatic use in car washes.
Die nachfolgenden Beispiele dienen der Erläuterung der Erfindung, ohne sie jedoch einzuschränken. Die Zusammensetzungen der erfindungsgemäßen Mittel werden dabei in Gewichtsprozent angegeben.The following examples serve to illustrate the invention, but without it limit. The compositions of the agents according to the invention are specified in percent by weight.
Der Gardnertest ist ein Reinigungstest für harte Oberflächen, vorwiegend Fußböden
etc.. Dabei weren Probestreifen (maximal 45cm lang und 5-6 cm breit) mit der
Untersuchungslösung behandelt, getrocknet und dann angeschmutzt. Zur
Untersuchung des Reinigungsprozesses werden 10 g der Reinigungslösung auf den
Streifen gegeben und ein Stück Wischtuch an einer Halterung befestigt. Das Tuch
wird mittels Spannseilen, über einen Exzenter angetrieben, auf dem präparierten
Probenstreifen hin- und herbewegt. Die Anzahl der Wischbewegungen wird an
einem Zählwerk abgelesen. Ausgewertet wird die Anzahl der Wischbewegungen bis
zur absoluten Sauberkeit, oder nach maximal 50 Wischbewegungen die Benotung
des Reinigungsergebnisses auf der Skala von 1 (sauber) bis 5.
Die Bewertung 50/3 bedeutet hierbei, daß nach der Maximalanzahl von 50
Wischgängen die Abmusterung die Note 3 auf der Skala von 1 bis 5 ergab.
Die Bewertung 5/1 bedeutet hierbei, daß schon nach 5 Wischgängen die
Abmusterung die Note 1 (sauber) auf der Skala von 1 bis 5 ergab.The Gardnertest is a cleaning test for hard surfaces, mainly floors etc .. Here are test strips (maximum 45cm long and 5-6 cm wide) treated with the test solution, dried and then soiled. To investigate the cleaning process, add 10 g of the cleaning solution to the strip and attach a piece of wipe to a holder. The cloth is driven by tensioning cables, driven by an eccentric, back and forth on the prepared sample strip. The number of swipes is read on a counter. The number of wiping movements is evaluated up to the absolute cleanliness, or after a maximum of 50 wiping movements the rating of the cleaning result on the scale of 1 (clean) to 5.
The rating 50/3 means here that after the maximum number of 50 wipes the matching gave the grade 3 on the scale of 1 to 5.
The rating 5/1 means here that after only 5 wipes the matching gave the grade 1 (clean) on the scale from 1 to 5.
Als Oberflächen wurden Keramik-Wandfließen und PVC-Bodenplatten eingesetzt. Als Anschmutzungen wurden Edding permanent Stift, Signierkreidestift und Bleistift (Graphit) verwendet.Ceramic wall tiles and PVC floor tiles were used as surfaces. As stains were Edding permanent pen, marking pencil and pencil (Graphite) used.
Anlehnend an IEC-Norm 436 und IKW-Methode wurden Tests in 4 Haushaltsgeschirrspülmaschinen (2 Miele G 688 SC und 2 Bosch 6902) bei 55°C Spültemperatur und 20g Dosierung durchgeführt.Based on IEC standard 436 and the IKW method, tests were carried out in 4 Domestic dishwashers (2 Miele G 688 SC and 2 Bosch 6902) at 55 ° C Rinsing temperature and 20g dosage performed.
Die Messwerte wurden arithmetisch zu einem Durchschnitt gemittelt und auf einen Maßstab von 0 bis 100 % gespreizt.The measurements were arithmetically averaged and averaged Scale spread from 0 to 100%.
Es wurde ein Allzweckreiniger hergestellt, indem Genapol UD 080 und Hostapur SAS 60 miteinander gemischt wurden. Dann wurde Wasser und schließlich Cumolsulfonat zugemischt. Mit Hilfe des Gardnertests wurde die Reinigungswirkung untersucht. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.An all-purpose cleaner was made by Genapol UD 080 and Hostapur SAS 60 were mixed together. Then there was water and finally Added cumene sulfonate. With the help of the Gardnertests was the cleaning effect examined. The composition and the results are shown in Table 1.
Wie in Beispiel 1 wurde ein Allzweckreiniger hergestellt. Außerdem wurde mit dem Wasser Klebosol 30 V 25 zugefügt. Dadurch kann im Gardner-Test im Vergleich zu Beispiel 1 eine Verbesserung der Reinigungswirkung erzielt werden. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.As in Example 1, a general-purpose cleaner was prepared. In addition, with the Water Klebosol 30 V 25 added. This can be compared to the Gardner test Example 1, an improvement of the cleaning effect can be achieved. The Composition and results are shown in Table 1.
Wie in Beispiel 1 wurde ein Allzweckreiniger hergestellt. Außerdem wurde mit dem Wasser Hectorit SKS-21 zugefügt. Dadurch kann im Gardner-Test im Vergleich zu Beispiel 1 eine Verbesserung der Reinigungswirkung erzielt werden. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.As in Example 1, a general-purpose cleaner was prepared. In addition, with the Water hectorite SKS-21 added. This can be compared to the Gardner test Example 1, an improvement of the cleaning effect can be achieved. The Composition and results are shown in Table 1.
Wie in Beispiel 1 wurde ein Allzweckreiniger hergestellt. Außerdem wurde mit dem Wasser Klebosol 30 V 25 und mit dem Cumolsulfonat TexCare SRC-1 Dispersion zugefügt. Dadurch kann im Gardner-Test im Vergleich zu den Beispielen 1 bis 3 eine Verbesserung der Reinigungswirkung erzielt werden. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.As in Example 1, a general-purpose cleaner was prepared. In addition, with the Water Klebosol 30 V 25 and with the cumenesulfonate TexCare SRC-1 dispersion added. This can be in the Gardner test compared to Examples 1 to 3 an improvement of the cleaning effect can be achieved. The composition and the results are shown in Table 1.
Es wurde ein Fliesen-/Badreiniger hergestellt, indem Isopropanol und Wasser miteinander gemischt wurden. Dann wurden Genapol UD 080, Hordaphos CC MS und Hostapur SAS 60 unter starkem Rühren und zuletzt Zitronensäuremonohydrat zugemischt. Mit Hilfe des Gardner-Tests wurde die Reinigungswirkung untersucht. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.A tile / bathroom cleaner was made by adding isopropanol and water mixed together. Then Genapol UD 080, Hordaphos CC MS and Hostapur SAS 60 with vigorous stirring and finally citric acid monohydrate admixed. The detergency was tested using the Gardner test. The composition and the results are shown in Table 1.
Wie in Beispiel 5 wurde ein Fliesen-/Badreiniger hergestellt. Außerdem wurde mit dem Wasser Klebosol 20 H 12 zugefügt. Dadurch kann im Gardner-Test im Vergleich zu Beispiel 5 eine Verbesserung der Reinigungswirkung erzielt werden. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.As in Example 5, a tile / bathroom cleaner was made. It was also with Klebosol 20 H 12 was added to the water. This can be seen in the Gardner test in the Compared to Example 5 an improvement of the cleaning effect can be achieved. The composition and the results are shown in Table 1.
Wie in Beispiel 5 wurde ein Fliesen-/Badreiniger hergestellt. Außerdem wurde mit dem Wasser Klebosol 20 H 12 und mit der Zitronensäure Finish CT 34 E zugefügt. Dadurch kann im Gardner-Test im Vergleich zu den Beispielen 5 und 6 eine Verbesserung der Reinigungswirkung erzielt werden. Die Zusammensetzung und die Ergebnisse sind in Tabelle 1 aufgeführt.As in Example 5, a tile / bathroom cleaner was made. It was also with Add to the water Klebosol 20 H 12 and with the Citric Acid Finish CT 34 E. This can be in the Gardner test compared to Examples 5 and 6 a Improvement of the cleaning effect can be achieved. The composition and the results are shown in Table 1.
Es wurde ein Handgeschirrspülmittel hergestellt, indem Hostapur SAS 60 mit Wasser und Klebosol 30 R 12 gemischt wurde. Dann wurden Genagen CAB 818, Genapol UD 080 und Genapol ZRO liquid unter langsamem Rühren zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A hand dishwashing detergent was prepared by using Hostapur SAS 60 Water and Klebosol 30 R 12 was mixed. Then Genagen CAB 818, Genapol UD 080 and Genapol ZRO liquid mixed with slow stirring. The Composition is listed in Table 2.
Es wurde ein Fensterreiniger hergestellt, indem Genapol LRO liquid mit Wasser und Klebosol 30 N 12 gemischt wurde. Dann wurden Ammoniumhydroxid und Isopropanol unter Rühren zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A window cleaner was made by using Genapol LRO liquid with water and Klebosol 30 N 12 was mixed. Then ammonium hydroxide and Isopropanol mixed with stirring. The composition is in Table 2 listed.
Es wurde ein Fensterreiniger hergestellt, indem Genapol LRO liquid mit Wasser und Klebosol 30 N 12 gemischt wurde. Dann wurden Ammoniumhydroxid, Isopropanol und Finish CT 34 E unter Rühren zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A window cleaner was made by using Genapol LRO liquid with water and Klebosol 30 N 12 was mixed. Then ammonium hydroxide, isopropanol and finish CT 34 E while stirring. The composition is in table 2 listed.
Es wurde ein Allzweckreiniger hergestellt, indem Genapol UD 080 mit Hostapur SAS 60 gemischt wurde. Dann wurden Wasser, Klebosol 30 R 12 und Propylenglykol n-Butylether unter Rühren zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt. An all-purpose cleaner was made by using Genapol UD 080 with Hostapur SAS 60 was mixed. Then water, Klebosol 30 R 12 and propylene glycol n-butyl ether mixed with stirring. The composition is in Table 2 listed.
Es wurde ein Fließen-/Badreiniger hergestellt, indem Isopropanol mit Wasser gemischt wurde. Dann wurden Genapol UD 080, Hordaphos CC MS und Hostapur SAS 60 und zum Schluss Klebosol 30H25 unter Rühren zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A flow / bath cleaner was made by adding isopropanol with water was mixed. Then Genapol UD 080, Hordaphos CC MS and Hostapur SAS 60 and finally Klebosol 30H25 mixed with stirring. The Composition is listed in Table 2.
Es wurde ein Reiniger für Autowaschanlagen hergestellt, indem Genapol UD 110 und Genapol UD 50 nacheinander in Wasser gelöst wurden. Dann wurde Klebosol 30 R 12 zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A cleaner for car washes was manufactured by Genapol UD 110 and Genapol UD 50 were successively dissolved in water. Then, Klebosol became 30 R 12 mixed. The composition is listed in Table 2.
Es wurde ein Trocknungsmittel für Autowaschanlagen hergestellt, indem nacheinander Butyldiglykol, Essigsäure, conc., Genamin LAP 100 D und Praepagen 4317 gemischt wurden. Dann wurde Wasser und Klebosol 30 H 25 zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.A desiccant for car washes was made by successively butyldiglycol, acetic acid, conc., Genamin LAP 100 D and Praepagen 4317 were mixed. Then water and Klebosol 30 H 25 were added. The Composition is listed in Table 2.
Es wurde ein Heißwachs für Autowaschanlagen hergestellt, indem nacheinander Balsamterpentinöl, Spindelöl, Butyldiglykol, Genapol X 080 und Hoechst-Wachs KST gemischt wurden. Dann wurden Praepagen WKT, Wasser und Klebosol 30 H 25 zugemischt. Die Zusammensetzung ist in Tabelle 2 aufgeführt.It was made a hot wax for car washes by successively Balsam turpentine, spindle oil, butyl diglycol, Genapol X 080 and Hoechst wax KST were mixed. Then were preks WKT, water and Klebosol 30 H 25 mixed. The composition is listed in Table 2.
Es wurde ein Maschinengeschirrreinerklarspüler hergestellt, indem nacheinander Zitronensäure, Cumolsulfonat, Genapol 2908 und Klebosol 30 H 25 in Wasser gelöst wurden. Nach der allgemeinen Vorschrift Durchführung der Maschinengeschirrreinigertests wurde Geschirr mit einem handelsüblichen Tabletten-Geschirrreiniger gespült. Als Klarspüler wurde obige Formulierung eingesetzt. Diese Prozedur aus Reinigen und Klarspülen wurde noch einmal wiederholt und das Geschirr danach abgemustert. Die Zusammensetzung und die Ergebnisse sind in Tabelle 3 aufgeführt. A machine dishwashing rinse was made by successively Citric acid, cumene sulfonate, Genapol 2908 and Klebosol 30 H 25 in water were solved. According to the general rule implementation of Machine dishwashing tests were dishes with a commercial Rinsed tablet-dishwashing detergent. The rinse aid was the above formulation used. This procedure of cleaning and rinsing was repeated repeated and the dishes are then scrapped. The composition and the Results are listed in Table 3.
Wie in Beispiel 16 wird ein Maschinengeschirrreinerklarspüler hergestellt. Zusätzlich wird Klebosol 30 H 25 untergemischt. Nach der allgemeinen Vorschrift Durchführung der Maschinengeschirrreinigertests wurde Geschirr zweimal mit einem handelsüblichen Tabletten-Geschirrreiniger gespült und mit dem Klarspüler behandelt. Die Verwendung von Kieselsol ergibt klare Vorteile für die Reinigungswirkung. Die Zusammensetzung und die Ergebnisse sind in Tabelle 3 aufgeführt.As in Example 16, a machine dishwashing rinse aid is prepared. additionally Klebosol 30 H 25 is mixed in. According to the general rule implementation The machine dishwashing tests were dishes twice with a rinsed with commercially available tablet-dishwashing detergent and with the rinse aid treated. The use of silica sol gives clear advantages for the Cleaning effect. The composition and the results are in Table 3 listed.
In einem Pflugscharmischer der Fa. Lödige wird ein pulverförmiger Maschinengeschirreiniger dadurch hergestellt dass die festen Komponenten, außer Enzyme, Bleiche und Parfüm, vorgelegt und gut gemischt werden. Dann werden das Alkylethoxylat und das Klebosol 30 V 50 aufgesprüht. Enzyme, Parfüm und Bleichsystem werden zum Schluss untergemischt. Die Zusammensetzung ist in Tabelle 4 aufgeführt.In a ploughshare mixer Fa. Lödige is a powdered Machinery dishes made by the fact that the solid components, except Enzymes, bleach and perfume, are submitted and mixed well. Then that will be Alkyl ethoxylate and the Klebosol 30 V 50 sprayed on. Enzymes, perfume and Bleach system are finally mixed in. The composition is in Table 4 listed.
Ein Flüssigwaschmittel wird dadurch hergestellt, dass man unter kräftigem Rühren Alkylbenzolsulfonat, Zitronensäure, Genapol 3070, Seife, Wasser, Siliconöl, Phosphonat, Polyglykolether und Klebosol 30 V 50 mischt. Die Zusammensetzung ist in Tabelle 4 aufgeführt.A liquid detergent is prepared by stirring vigorously Alkylbenzenesulfonate, citric acid, Genapol 3070, soap, water, silicone oil, Phosphonate, polyglycol ether and Klebosol 30 V 50 mixes. The composition is listed in Table 4.
Ein Pulverwaschmittel wird dadurch hergestellt, dass man in einem Pflugscharmischer der Fa. Lödige Antischaum, Schichtsilicat, Soda, Sokalan CP5 und Zeolith A mischt und Genapol 3070 aufsprüht. Die restlichen Komponenten werden kurz untergemischt. Die Zusammensetzung ist in Tabelle 4 aufgeführt. A powder detergent is prepared by adding in a Ploughshare mixer Fa. Lödige Antifoam, phyllosilicate, soda, Sokalan CP5 and Zeolite A and Genapol 3070 sprayed on. The remaining components are mixed in for a short time. The composition is listed in Table 4.
Ein Wäscheweichspüler wird dadurch hergestellt, dass bei 50 bis 60°C unter Rühren zunähst Lapnite RD und danach Praepagen WK in Wasser gelöst werden. Die Zusammensetzung ist in Tabelle 4 aufgeführt.A fabric softener is prepared by stirring at 50 to 60 ° C First Lapnite RD and then Praepagen WK are dissolved in water. The Composition is listed in Table 4.
Ein Wäscheweichspüler wird dadurch hergestellt, dass bei 50°C geschmolzenes
Triethanolamin diesterquat (85 %) in vorgeheiztes Wasser gelöst wird, dann wird
Genapol UD 088 eingerührt und die Lösung abgekühlt. Zum Schluss wird TexCare
SRC-1 Dispersion und Klebosol 30 V 50 eingerührt.
- Alkylbenzolsulfonatalkylbenzenesulfonate
- Marlon ARL, Fa. HülsMarlon ARL, Fa. Huls
- Ammoniumhydroxid (w= 25 %)Ammonium hydroxide (w = 25%)
- Fa. Riedel de HaenFa. Riedel de Haen
- Antischaumantifoam
- Fa. WackerFa. Wacker
- BalsamterpentinölGum
- --
- Butyldiglycoldiglycol
- Fa. MerckFa. Merck
- Citronensäurecitric acid
- Fa. JungbunzlauerFa. Jungbunzlauer
- Citronensäure monohydratCitric acid monohydrate
- Fa. JungbunzlauerFa. Jungbunzlauer
- Cumol sulphonatCumene sulphonate
- Fa.CondeaFa.Condea
- Essigsäure, conc.Acetic acid, conc.
- Fa. Riedel de HaenFa. Riedel de Haen
- Finish CT 34 EFinish CT 34 E
- Fa. WackerFa. Wacker
- Genagen CAB 818Genagen CAB 818
- Fa. ClariantFa. Clariant
- Genamin LAP 100 DGenamin LAP 100 D
- Fa. ClariantFa. Clariant
- Genapol 2822Genapol 2822
- Fa. ClariantFa. Clariant
- Genapol 2908Genapol 2908
- Fa. ClariantFa. Clariant
- Genapol 3070Genapol 3070
- Fa. ClariantFa. Clariant
- Genapol LRO liquidGenapol LRO liquid
- Fa. ClariantFa. Clariant
- Genapol O 020Genapol O 020
- Fa. ClariantFa. Clariant
- Genapol UD 080Genapol UD 080
- Fa. ClariantFa. Clariant
- Genapol UD 088Genapol UD 088
- Fa. ClariantFa. Clariant
- Genapol UD 110Genapol UD 110
- Fa. ClariantFa. Clariant
- Genapol UD 50Genapol UD 50
- Fa. ClariantFa. Clariant
- Genapol X 080Genapol X 080
- Fa. ClariantFa. Clariant
- Genapol ZRO liquidGenapol ZRO liquid
- Fa. ClariantFa. Clariant
- Hectorit SKS-21Hectorite SKS-21
- Fa. ClariantFa. Clariant
- Hoechst-Wachs KSTHoechst wax KST
- Fa. ClariantFa. Clariant
- Hordaphos CC MSHordaphos CC MS
- Fa. ClariantFa. Clariant
- Hostapur SAS 60Hostapur SAS 60
- Fa. ClariantFa. Clariant
- Isopropanolisopropanol
- Fa. Riedel de HaenFa. Riedel de Haen
- Klebosol 20 H 12Klebosol 20H 12
- Fa. ClariantFa. Clariant
- Klebosol 30 H 25Klebosol 30 H 25
- Fa. ClariantFa. Clariant
- Klebosol 30 N 12Klebosol 30 N 12
- Fa. Clariant Fa. Clariant
- Klebosol 30 R 12Klebosol 30 R 12
- Fa. ClariantFa. Clariant
- Klebosol 30 V 25Klebosol 30 V 25
- Fa. ClariantFa. Clariant
- Klebosol 30 V 50Klebosol 30 V 50
- Fa. ClariantFa. Clariant
- Laponite RDLaponite RD
- Fa. LaporteFa. Laporte
- Makrophos 1018Macrophos 1018
- Fa. BK GiuliniFa. BK Giulini
- ParfümPerfume
- Citronenparfüm 78122D, Fa OrissaCitron perfume 78122D, Fa Orissa
- Peractive AC WhitePeractive AC White
- Fa. ClariantFa. Clariant
- Peractive ANPeractive AN
- Fa. ClariantFa. Clariant
- Perborat mhPerborate mh
- Fa. DegussaDegussa
- Percarbonatpercarbonate
- Oxyper C, Fa. Solvay InteroxOxyper C, Solvay Interox
- Phosphonatphosphonate
- Dequest 2041, Fa. MonsantoDequest 2041, Monsanto
- Polyglycoletherpolyglycol
- Fa. ClariantFa. Clariant
- Praepagen 4317Praepagen 4317
- Fa. ClariantFa. Clariant
- Praepagen WKPraepagen WK
- Fa. ClariantFa. Clariant
- Praepagen WKTPraepagen WKT
- Fa. ClariantFa. Clariant
- Propylenglycol n-butyletherPropylene glycol n-butyl ether
- Fa. MerckFa. Merck
- Savinase 6.0 TWSavinase 6.0 TW
- Fa. Solvay EnzymesFa. Solvay Enzymes
- Schichtsilicatlayered
- Fa. ClariantFa. Clariant
- SeifeSoap
- Liga Grundseife HM11ELeague Soap HM11E
- Sodasoda
- Schwersoda, Fa. Matthes&WeberSchwersoda, Fa. Matthes & Weber
- Sokalan CP45Sokalan CP45
- Fa. BASFFa. BASF
- Sokalan CP5Sokalan CP5
- Fa. BASFFa. BASF
- Spindelölspindle oil
- --
- Termamyl 120TTermamyl 120T
- Fa. Solvay EnzymesFa. Solvay Enzymes
- Termamyl 60TTermamyl 60T
- Fa. Solvay EnzymesFa. Solvay Enzymes
- TexCare SRC-1 DispersionTexCare SRC-1 dispersion
- Fa. ClariantFa. Clariant
- Triethanolamin diesterquatTriethanolamine diesterquat
- Fa. ClariantFa. Clariant
- Wacker SiliconölWacker silicone oil
- Fa. WackerFa. Wacker
- Wasserwater
- --
- Zeolith AZeolite A
- Wessalith P, Fa. DegussaWessalith P, Degussa
Claims (12)
- A laundry detergent or cleaner comprising microdisperse, hydrophilic silicate-containing particle with a particle size of from 1 to 500 nm, preferably 9 to 50 nm, the particles being colloidal silica gels, colloidal silica sols, hectorites, saponites or mixtures thereof as well as additionally at least one hydrophobicizing agent, the hydrophobicizing agents being silicones, silicone oils, fluorosilicone oils, soil release polymers, cationic surfactants and/or organic fluorine compounds.
- The laundry detergent or cleaner as claimed in claim 1, wherein the surface of the particles is electrically charged.
- The laundry detergent or cleaner as claimed in claim 1 and/or 2, wherein the weight ratio of silicate-containing particles to hydrophobicizing agents is 100:1 to 1:100, based on active substance.
- The laundry detergent or cleaner as claimed in one or more of claims 1 to 3, which comprises 0.01 to 10% by weight of silicate-containing particles, 0.01 to 10% by weight of hydrophobicizing agents and 80 to 99.8% by weight of other laundry detergent/cleaner ingredients.
- The laundry detergent or cleaner as claimed in one or more of claims 1 to 3, which comprises 0.01 to 10% by weight of silicate-containing particles, 0.01 to 10% by weight of hydrophobicizing agents, 0.5 to 60% by weight of interface-active substances and 20 to 99.48% by weight of other laundry detergent ingredients.
- The laundry detergent or cleaner as claimed in one or more of claims 1 to 3, which comprises 0.01 to 10% by weight of silicate-containing particles, 0.5 to 60% by weight of interface-active substances and 30 to 99.49% by weight of other laundry detergent/cleaner ingredients.
- The laundry detergent or cleaner as claimed in one or more of claims 1 to 6, which further comprises builders, cobuilders, alkali suppliers, anionic, zwitterionic and nonionic surfactants, antifoams, dispersants, complexing agents, bleaches, bleach activators and bleach catalysts and/or enzymes.
- The laundry detergent or cleaner as claimed in one or more of claims 1 to 7, in the form of a heavy-duty detergent, compact heavy-duty detergent, compact color detergent, heavy-duty detergent of low bulk density, special detergent, such as laundry after-treatment composition, laundry softener, stain-removal salts, bleach booster, net curtain detergent, wool detergent, modular detergent or industrial detergent.
- The laundry detergent or cleaner as claimed in one or more of claims 1 to 7, in the form of a cleaner for hard surfaces, e.g. facade, glass, metal, window, floor or carpet cleaner.
- The laundry detergent or cleaner as claimed in claim 9, in the form of a hand dishwashing detergent, machine dishwashing detergent, machine dishwashing cleaner or rinse aid.
- The use of microdisperse, hydrophilic silicate-containing particles with a particle size of from 1 to 500 nm, preferably 9 to 50 nm, the particles being colloidal silica gels, colloidal silica sols, hectorites, saponites or mixtures thereof as well as additionally at least one hydrophobicizing agent, the hydrophobicizing agents being silicones, silicone oils, fluorosilicone oils, soil release polymers, cationic surfactants and/or organic fluorine compounds as surface-coating agents for releasing soil and reducing the tendency for resoiling in laundry detergents and cleaners.
- The use as claimed in claim 11, wherein the surface of the particles is electrically charged.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10061897 | 2000-12-12 | ||
DE10061897A DE10061897A1 (en) | 2000-12-12 | 2000-12-12 | Washing or cleaning composition, useful for fabrics or hard surfaces, contains microdisperse, hydrophilic silicate particles that improve soil removal and prevent resoiling |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1215276A1 EP1215276A1 (en) | 2002-06-19 |
EP1215276B1 true EP1215276B1 (en) | 2005-08-03 |
Family
ID=7666852
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01128892A Revoked EP1215276B1 (en) | 2000-12-12 | 2001-12-05 | Detergent composition comprising microdispersed particles containing silicate |
Country Status (4)
Country | Link |
---|---|
US (1) | US6784149B2 (en) |
EP (1) | EP1215276B1 (en) |
JP (1) | JP2002285194A (en) |
DE (2) | DE10061897A1 (en) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2431780C (en) | 2001-01-30 | 2009-01-27 | The Procter & Gamble Company | Coatings for modifying hard surfaces and processes for applying the same |
US6764988B2 (en) * | 2001-04-18 | 2004-07-20 | Kimberly-Clark Worldwide, Inc. | Skin cleansing composition incorporating anionic particles |
US6596682B1 (en) * | 2002-04-16 | 2003-07-22 | Colgate-Palmolive Company | Cleaning compositions in the form of a tablet |
DE50210858D1 (en) * | 2002-11-02 | 2007-10-18 | Dalli Werke Gmbh & Co Kg | Water-soluble builder of specific particle size in detergents and cleaners |
DE10258831A1 (en) * | 2002-12-17 | 2004-07-08 | Henkel Kgaa | Hard surface cleaner |
US8361946B2 (en) * | 2004-04-08 | 2013-01-29 | Akzo Nobel N.V. | Detergent composition |
EP1733015B1 (en) * | 2004-04-08 | 2010-06-16 | Akzo Nobel N.V. | Detergent composition |
DE102004019022A1 (en) * | 2004-04-16 | 2005-11-17 | Henkel Kgaa | Hydrophilic cleaner for hard surfaces |
DE102004046495B4 (en) * | 2004-09-23 | 2009-04-09 | Deutsches Zentrum für Luft- und Raumfahrt e.V. | Airgel-containing composite material and process for its production |
ATE483009T1 (en) * | 2005-03-30 | 2010-10-15 | Basf Se | USE OF HYDROPHOBINS FOR THE DIRT-REPELLENT TREATMENT OF HARD SURFACES |
DE502006007035D1 (en) * | 2005-03-30 | 2010-07-08 | Basf Se | USE OF HYDROPHOBINS FOR SURFACE TREATMENT OF CURED MINERAL BUILDINGS, NATURAL STONE, ARTIFICIAL PINE AND CERAMICS |
US20060269441A1 (en) * | 2005-05-25 | 2006-11-30 | Ochomogo Maria G | Nanosilica-based food contact sanitizer |
US20060281807A1 (en) * | 2005-06-13 | 2006-12-14 | Tapestry Pharmaceuticals, Inc. | Quassinoid compositions for the treatment of cancer and other proliferative diseases |
US8093195B2 (en) | 2005-11-09 | 2012-01-10 | Ecolab Usa Inc. | Composition with surface modifying properties |
US20070130694A1 (en) * | 2005-12-12 | 2007-06-14 | Michaels Emily W | Textile surface modification composition |
US7655609B2 (en) * | 2005-12-12 | 2010-02-02 | Milliken & Company | Soil release agent |
US20070131892A1 (en) * | 2005-12-12 | 2007-06-14 | Valenti Dominick J | Stain repellant and release fabric conditioner |
US20070199157A1 (en) * | 2006-02-28 | 2007-08-30 | Eduardo Torres | Fabric conditioner enhancing agent and emulsion and dispersant stabilizer |
EP2045315A1 (en) * | 2007-09-24 | 2009-04-08 | The Procter and Gamble Company | Dishwashing method |
EP2045316A1 (en) * | 2007-09-24 | 2009-04-08 | The Procter and Gamble Company | Detergent particle |
JP2009191128A (en) * | 2008-02-13 | 2009-08-27 | Lion Corp | Liquid detergent composition |
US20090280252A1 (en) * | 2008-05-06 | 2009-11-12 | Andrew Armstrong | Method for Extending and Improving the Functionality of a Hard Surface |
KR101891228B1 (en) | 2010-12-16 | 2018-09-28 | 아크조 노벨 케미칼즈 인터내셔널 비.브이. | Low streak degreasing composition |
WO2013004302A1 (en) * | 2011-07-05 | 2013-01-10 | Ecolab Inc. | Acid marble cleaner |
US20140023814A1 (en) * | 2011-12-28 | 2014-01-23 | Frank M. Fosco, JR. | Potable water containers having surfaces including heat labile component/carrier combinations and methods for their preparation |
ITMI20130782A1 (en) | 2013-05-13 | 2014-11-14 | Fra Ber S R L | PRODUCTS FOR ENZYMATIC BASED SELF-WASHING |
DE102014213311A1 (en) * | 2014-07-09 | 2016-01-14 | Henkel Ag & Co. Kgaa | Novel washing process with electrochemically activatable mediator compound |
DE102015203041B4 (en) * | 2015-02-20 | 2022-02-10 | Thomas Lutgen | Process and gel for removing dirt particles from the pores of a surface |
CN106047507A (en) * | 2016-05-31 | 2016-10-26 | 太仓协大申泰羊毛衫有限公司 | Woolen sweater washing liquid containing phytagel |
GB2581142A (en) * | 2019-01-23 | 2020-08-12 | Linkage Tech Switzerland Sa | Compositions and their use |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ZA734721B (en) * | 1972-07-14 | 1974-03-27 | Procter & Gamble | Detergent compositions |
US3884826A (en) * | 1973-07-20 | 1975-05-20 | Barnes Hind Pharm Inc | Thixotropic cleaning agent for hard contact lenses |
AU499736B2 (en) * | 1975-01-24 | 1979-05-03 | American Cyanamid Company | Non-caustic oven cleaner |
US4124523A (en) | 1977-03-07 | 1978-11-07 | Dow Corning Corporation | Silicone-containing acidic cleaner and conditioner |
EP0050887B1 (en) * | 1980-10-16 | 1984-05-02 | Unilever N.V. | Stable liquid detergent suspensions |
DE3310684A1 (en) * | 1983-03-24 | 1984-10-11 | Henkel KGaA, 4000 Düsseldorf | USE OF A PASTOUS DETERGENT IN DISHWASHER |
GB8328075D0 (en) * | 1983-10-20 | 1983-11-23 | Unilever Plc | Dishwashing compositions |
GB8328076D0 (en) * | 1983-10-20 | 1983-11-23 | Unilever Plc | Dishwashing compositions |
US4595520A (en) * | 1984-10-18 | 1986-06-17 | Economics Laboratory, Inc. | Method for forming solid detergent compositions |
DE3603471A1 (en) * | 1986-02-05 | 1987-08-06 | Wfk Testgewebe Gmbh | Low-phosphorus or phosphorus-free detergent and/or cleaner |
GB8616615D0 (en) | 1986-07-08 | 1986-08-13 | Unilever Plc | Rinse aid |
DE3628406A1 (en) * | 1986-08-21 | 1988-02-25 | Henkel Kgaa | TABLET SHAPED GLASS CLEANER |
US4842758A (en) * | 1986-10-31 | 1989-06-27 | Colgate-Palmolive Company | Stabilized enzyme system for use in aqueous liquid built detergent compositions |
US4911851A (en) * | 1987-11-06 | 1990-03-27 | The Procter & Gamble Company | Detergent compatible, dryer released fabric softening/antistatic agents |
US5160448A (en) * | 1987-12-30 | 1992-11-03 | Lever Brothers Company, Division Of Conopco, Inc. | Gel detergent compositions containing a clay and a cross-linked polycarboxylic polymer |
US5002762A (en) * | 1988-03-16 | 1991-03-26 | The Procter & Gamble Company | Volatile silicons in household and cosmetic products |
GB2224743B (en) | 1988-11-10 | 1992-02-19 | Trico Folberth Ltd | Glass cleaning preparation |
DE3914131A1 (en) | 1989-04-28 | 1990-10-31 | Henkel Kgaa | USE OF CALCINATED HYDROTALCITES AS CATALYSTS FOR ETHOXYLATION OR PROPOXYLATION OF FATTY ACID ESTERS |
US5213706A (en) * | 1991-11-08 | 1993-05-25 | Lever Brothers Company, Division Of Conopco, Inc. | Homogeneous detergent gel compositions for use in automatic dishwashers |
DE4227277A1 (en) * | 1992-08-18 | 1994-02-24 | Hoechst Ag | Stable granules for detergents, cleaning agents and disinfectants |
GB9414572D0 (en) * | 1994-07-19 | 1994-09-07 | Unilever Plc | Soap composition |
US5709815A (en) * | 1995-12-28 | 1998-01-20 | Colgate Palmolive Company | Peroxygen bleach composition activated by oxo-piperidinium salts |
GB2311996A (en) * | 1996-04-12 | 1997-10-15 | Reckitt & Colman Inc | Hard surface scouring cleansers ` |
US5679877A (en) * | 1996-06-14 | 1997-10-21 | Colgate-Palmolive Co. | Thickened liquid cleaning composition containing an abrasive |
US6287346B1 (en) * | 1996-07-24 | 2001-09-11 | The Procter & Gamble Company | Method for stain removal on fabric with detergent compositions containing bleach |
DE19726814A1 (en) | 1997-06-25 | 1999-01-07 | Murjahn Amphibolin Werke | Coating agent to reduce the tendency to soiling on facades |
US6194372B1 (en) * | 1998-11-20 | 2001-02-27 | Beaumont Products, Inc. | Solvent based sprayable gel |
DE19854960A1 (en) * | 1998-11-29 | 2000-05-31 | Clariant Gmbh | Dishwasher detergent |
DE19948859A1 (en) * | 1999-10-08 | 2001-11-08 | Henkel Kgaa | Thixotropic aqueous detergent |
DE19952383A1 (en) * | 1999-10-30 | 2001-05-17 | Henkel Kgaa | Detergents and cleaning agents |
DE10021726A1 (en) * | 2000-05-04 | 2001-11-15 | Henkel Kgaa | Nanoparticles are used for loosening dirt and/or reducing resoiling of hard surface or textile, especially in a textile finish, washing, pretreatment or after-treatment agent |
US20020028288A1 (en) * | 2000-06-14 | 2002-03-07 | The Procter & Gamble Company | Long lasting coatings for modifying hard surfaces and processes for applying the same |
-
2000
- 2000-12-12 DE DE10061897A patent/DE10061897A1/en not_active Withdrawn
-
2001
- 2001-09-28 JP JP2001301439A patent/JP2002285194A/en not_active Withdrawn
- 2001-12-05 DE DE50106965T patent/DE50106965D1/en not_active Revoked
- 2001-12-05 EP EP01128892A patent/EP1215276B1/en not_active Revoked
- 2001-12-12 US US10/021,596 patent/US6784149B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE10061897A1 (en) | 2002-06-13 |
US6784149B2 (en) | 2004-08-31 |
EP1215276A1 (en) | 2002-06-19 |
US20020111287A1 (en) | 2002-08-15 |
JP2002285194A (en) | 2002-10-03 |
DE50106965D1 (en) | 2005-09-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1215276B1 (en) | Detergent composition comprising microdispersed particles containing silicate | |
DE69203473T2 (en) | Detergent compositions. | |
US3936537A (en) | Detergent-compatible fabric softening and antistatic compositions | |
EP3444325B1 (en) | Method of cleaning household surfaces | |
EP0384715B1 (en) | Light duty microemulsion liquid detergent composition | |
DE2124526C3 (en) | Detergent and cleaning agent mixtures with controlled foam behavior | |
US7632793B2 (en) | Washing and cleaning agents containing acetals as organic solvents | |
DE69830186T2 (en) | COMPOSITIONS FOR THE PROTECTION OF TISSUE COLORS AND METHOD THEREFOR | |
EP0262897A2 (en) | Detergent composition | |
DE69330446T2 (en) | Particulate laundry softeners and detergents | |
GB2092610A (en) | Laundry detergent substrate articles | |
DE69603162T3 (en) | CLEANING AGENTS CONTAINING A QUATERNIZED POLYDIMETHYLSILOXANE AND A NON-IONIC SURFACTANT | |
AU624577B2 (en) | Detergent compositions | |
JPS63400A (en) | Softening detergent composition containing amide softener | |
DE2948921A1 (en) | LOW PHOSPHATE LAUNDRY DETERGENTS | |
WO2016069452A1 (en) | Hard surface premoistened wipes, cleaning implements and methods thereof | |
EP3015540A2 (en) | Hard surface cleaners comprising ethoxylated alkoxylated nonionic surfactants | |
DE69101467T2 (en) | Non-aqueous liquid detergent composition for dishwashers. | |
DE2857181C2 (en) | ||
DE19853720A1 (en) | Aqueous cleaners for hard surfaces, e.g. floors in public areas, contain surfactant, including anionic surfactant, and diquaternary polysiloxane to reduce drying time | |
JPH08500377A (en) | Pourable liquid aqueous detergent concentrate | |
DE2857157C2 (en) | ||
DE2857164A1 (en) | LAUNDRY DETERGENT | |
HUT67495A (en) | Rinse-active foam control particles, process for producing thereof and detergent compositions containing the particles | |
EP1685224B1 (en) | Soluble builder system |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR |
|
AX | Request for extension of the european patent |
Free format text: AL;LT;LV;MK;RO;SI |
|
17P | Request for examination filed |
Effective date: 20021219 |
|
AKX | Designation fees paid |
Designated state(s): AT BE CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR |
|
17Q | First examination report despatched |
Effective date: 20030415 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
RBV | Designated contracting states (corrected) |
Designated state(s): BE DE FR GB IT |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): BE DE FR GB IT |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REF | Corresponds to: |
Ref document number: 50106965 Country of ref document: DE Date of ref document: 20050908 Kind code of ref document: P |
|
GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) |
Effective date: 20050927 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20051019 Year of fee payment: 5 |
|
RAP2 | Party data changed (patent owner data changed or rights of a patent transferred) |
Owner name: CLARIANT PRODUKTE (DEUTSCHLAND) GMBH |
|
ET | Fr: translation filed | ||
PLBI | Opposition filed |
Free format text: ORIGINAL CODE: 0009260 |
|
PLAX | Notice of opposition and request to file observation + time limit sent |
Free format text: ORIGINAL CODE: EPIDOSNOBS2 |
|
26 | Opposition filed |
Opponent name: HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN Effective date: 20060428 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20061024 Year of fee payment: 6 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20061120 Year of fee payment: 6 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20061231 Year of fee payment: 6 |
|
PLBB | Reply of patent proprietor to notice(s) of opposition received |
Free format text: ORIGINAL CODE: EPIDOSNOBS3 |
|
RDAF | Communication despatched that patent is revoked |
Free format text: ORIGINAL CODE: EPIDOSNREV1 |
|
RDAD | Information modified related to despatch of communication that patent is revoked |
Free format text: ORIGINAL CODE: EPIDOSCREV1 |
|
APBP | Date of receipt of notice of appeal recorded |
Free format text: ORIGINAL CODE: EPIDOSNNOA2O |
|
APAH | Appeal reference modified |
Free format text: ORIGINAL CODE: EPIDOSCREFNO |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20061205 |
|
APBU | Appeal procedure closed |
Free format text: ORIGINAL CODE: EPIDOSNNOA9O |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20061205 |
|
RDAG | Patent revoked |
Free format text: ORIGINAL CODE: 0009271 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: PATENT REVOKED |
|
BECN | Be: change of holder's name |
Owner name: *CLARIANT PRODUKTE DEUTSCHLAND G.M.B.H. Effective date: 20050803 |
|
27W | Patent revoked |
Effective date: 20070823 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20061016 Year of fee payment: 6 |