EP1098725A1 - Verfahren und vorrichtung zur herstellung eines metallischen hohlkörpers - Google Patents
Verfahren und vorrichtung zur herstellung eines metallischen hohlkörpersInfo
- Publication number
- EP1098725A1 EP1098725A1 EP99929074A EP99929074A EP1098725A1 EP 1098725 A1 EP1098725 A1 EP 1098725A1 EP 99929074 A EP99929074 A EP 99929074A EP 99929074 A EP99929074 A EP 99929074A EP 1098725 A1 EP1098725 A1 EP 1098725A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- inner core
- cavity
- mold
- casting mold
- connecting element
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/22—Moulds for peculiarly-shaped castings
- B22C9/24—Moulds for peculiarly-shaped castings for hollow articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C21/00—Flasks; Accessories therefor
- B22C21/12—Accessories
- B22C21/14—Accessories for reinforcing or securing moulding materials or cores, e.g. gaggers, chaplets, pins, bars
Definitions
- the invention relates to a method and a device for producing a metallic hollow body with at least one cavity, in particular a turbine blade with a cooling air duct and a plurality of cooling air openings.
- turbine blades are, for example, metallic hollow bodies, the hollow space of which is designed as a cooling air channel which can be acted upon by cooling air.
- Turbine blades with a so-called film cooling additionally have cooling air openings on their outer surface, which open into the cooling air channel and form a cooling air film on the outer surface of the turbine blade for cooling.
- DE 38 23 287 C2 specifies a casting process in which a core forming the cavity is enclosed by a wax jacket.
- the thickness of the wax jacket corresponds to the wall thickness of the wall of the component to be cast.
- Pins are inserted into the wax jacket, the inner ends of which touch the core, while the outer ends of the pins protrude beyond the wax jacket.
- the wax coat with pins is then dipped into a ceramic paste, enclosed by it and then heated so that the ceramic slurry can harden and form a ceramic outer mold. During the heating process, the wax coating melts, leaving the core held in place by the pins.
- the hardened ceramic slurry with the usually also ceramic core forms the casting mold, which is then filled with molten metal.
- the material of the pins for example platinum, can be melted or melted by the molten metal and diffuse into it.
- the material of the pins is chosen so that there is essentially no local, harmful alloy formation.
- heat retention caps are attached to the pins, which help to avoid heat loss from the pins that is too rapid.
- cooling air openings are then drilled through the outer wall, which open into the cavity.
- a disadvantage of this method is that the pins extend into the outer mold to such an extent that the ends of the pins protrude beyond the surface of the finished component, which makes reworking of the component necessary. Furthermore, the pins could not be chosen to be as wide as possible in order to fix the core in its position, since otherwise undesirable alloys could form locally. In addition, for reasons of cost, any number of platinum pins cannot be used to fix the core.
- DE 33 12 867 A1 specifies a method in which the core forming the cavity is surrounded by a support, the outer dimensions of which do not protrude beyond the surface of the component to be cast.
- the core and its support are then surrounded by a wax coat and dipped in a ceramic paste.
- the core is supported from a material that dissolves in the cast alloy and does not adversely affect the properties of the component.
- cooling air openings have to be drilled in the wall of the turbine blade in an additional machining step.
- Both methods also have the disadvantage that, when the wax jacket is removed, the core can shift with respect to the later outer wall due to the different thermal expansion behavior of the pins or the support and the core, which leads to a fluctuating wall thickness.
- the object of the invention is to provide a method for producing a metallic hollow body.
- a further object of the invention is to provide a device for producing a metallic hollow body, in particular a turbine blade of a gas turbine.
- a device for producing a metallic hollow body having at least one cavity and a wall surrounding the cavity comprising an outer casting mold which has at least one inner core which serves to form the cavity, the outer casting mold in at least two outer parts are designed to be divisible and the inner core is connected to an outer part of the outer mold via at least one connecting element which serves to form a through opening in the wall into the cavity.
- the invention is based on the knowledge that a casting mold which was formed with the aid of a wax-coated core already has deviations in the cavity released by the wax with respect to the desired wall thickness of the component to be cast.
- the deviations in the position of the core with respect to its desired position result, among other things, from the different thermal expansion of the ceramic core, the metallic pins or supports and the wax forming the wax coat. Further deviations can occur when the cavity formed by the casting mold is poured out with molten metal and when the metal subsequently solidifies.
- the different heat effects on the core and the pins or supports of the casting mold can lead to different thermal expansion, which under unfavorable circumstances can cause the core to twist and can therefore lead to an additional, local wall thickness deviation.
- the invention is now based on the idea of forming the casting mold without a lost wax coat and of achieving an improved fixation of the core to the rest of the casting mold, so that no relative movements of the core with respect to the rest of the casting mold, which can lead to an undesirable change in wall thickness, are possible .
- This divisible mold comprises an outer mold that can be divided into several outer parts and at least one inner core with a connecting element.
- the outer mold essentially represents the negative of the outer surface of the hollow body to be cast, while the inner core serves to form the cavity.
- the inner core is firmly connected to at least one outer part of the outer mold via at least one connecting element.
- the connecting elements fix the inner core with respect to its position in relation to the outer casting mold and form the passage openings through the wall of the component to be cast.
- Each connecting element is designed so that its dimensions and its position correspond to the dimensions and the position of a passage opening through the wall of the component to be cast into the cavity formed by the inner core.
- the number of connecting elements preferably corresponds to the number of components provided in the component to be cast Openings.
- the connecting elements extend from the surface of the inner core to the outer mold and touch the outer parts in such a way that no casting material can get between the connecting elements and the outer mold or the inner core during subsequent pouring.
- This has the advantage that the inner core and the outer mold have a defined distance from one another which corresponds to the wall thickness of the component to be cast.
- the mold for the component to be cast consists of the outer parts joined together to form the outer mold, with the inner cores connected via connecting elements and the connecting elements. Since the mold is produced without a wax jacket, there can be no undesirable change in the position of the inner core with respect to the outer mold due to different thermal expansion of the inner core, the outer mold and / or the connecting elements when the wax jacket melts.
- An inner core is advantageously firmly connected to an outer part of the outer casting mold via at least one connecting element. This has the advantage that the inner core does not change its position with respect to the outer mold even when the mold is poured with liquid metal.
- An inner core is preferably connected to exactly one outer part. It is thereby achieved that the finished casting mold can be assembled from at least two individual components, each component consisting of exactly one outer part, which may be firmly connected to an inner core via associated connecting elements. In addition to the connecting elements used for the fixed connection of the inner core and the outer part, further connecting elements can be assigned to the inner core, which serve to form further through openings.
- the outer casting mold is preferably composed of a ceramic material.
- the inner core is preferably made of a ceramic material.
- a plurality of inner cores advantageously serve to form the cavity.
- the geometry of each individual inner core can be made relatively simple, as a result of which the casting mold can be produced economically.
- the inner core forming the supply duct advantageously extends along a main direction of expansion and has a substantially trapezoidal or triangular cross-sectional area perpendicular to the main direction of expansion. This has the advantage that two inner cores, which are used to form two different supply channels and which are attached to two different outer parts, can interlock in the manner of a toothing and thus do not hinder the joining of the outer parts to form the mold.
- the inner core forming the cooler pocket is preferably essentially plate-shaped.
- An inner core, which is used to form a supply duct that supplies the cooling bag with cooling air, is then connected to the outer mold via the plate-shaped inner core.
- a plurality of inner cores advantageously serve to form the various cavities.
- such inner cores are at least a connecting element, in particular via spacer knobs, kept at a distance from one another.
- the device described is preferably used for producing a metallic hollow body having at least one cavity and a wall surrounding the cavity, for producing a turbine blade of a gas turbine, the cavity being designed as a cooling duct of the turbine blade and a plurality of cooling air openings being provided for the cooling duct , wherein each cooling air opening is formed by a passage opening.
- the use of the device has the advantage that the fully poured turbine blade has a defined wall thickness and the amount of cooling air required for cooling the turbine blade can thus be matched to the maximum permissible surface temperature of the turbine blade. Overall, there is an extremely low cooling air requirement, which results in a high efficiency of the gas turbine. Another advantage results from the fact that the turbine blade does not have to be reworked after the casting mold has been removed.
- the object directed to a method is achieved according to the invention by a method for producing a metallic hollow body with at least one cavity and a wall surrounding the cavity, which has a passage opening, a casting mold being poured out with metal by an inner core which is used to form a cavity is used to connect at least one connecting element to an outer part of an outer mold divided into at least two outer parts, then the outer parts together to form the outer mold. are added, the existing mold from the outer mold, the connecting elements and the inner core is poured out with metal and the mold is finally removed.
- the mold of a hollow body can be assembled piece by piece.
- Each component of the mold consists of at least one outer part of the outer mold and optionally one or more associated inner cores, which are fastened to the outer parts of a component with connecting elements.
- Each component in turn represents a component that can be composed of smaller units.
- the advantage is that a large number of prefabricated or partially prefabricated elements (e.g. connecting elements, inner cores) can be used to build up the components of the casting mold, which reduces the structural outlay and thus the costs for the production.
- the outer parts of the prefabricated components are then assembled into a mold for the hollow body and firmly connected. Then the finished mold is poured out in a known manner with liquid metal and removed after the metal has solidified.
- FIG. 1 side view of a hollow body
- FIG. 2 cross section of the hollow body from FIG. 1 along the line I-I;
- FIG. 3 split mold for a the hollow body from FIG.l;
- FIG. 4 composite mold for a hollow body from FIG.l;
- FIG. 5 oblique view of a section of FIG. Third
- FIG. 1 as a hollow body 1 is a side view of a turbine blade with a blade area 2 for a
- the turbine blade 1 has a number of cavities 3, 5, 7, 9, 11, 13, 15, 17, 19 and 21 which are surrounded by a wall 23, such as that in cross section through the blade area 2 along the line I-I in FIG. 2 is shown.
- the cavities 3, 5, 7, 9, 11, 13, 15, 17, 19 and 21 form cooling channels 3, 5, 9, 15, 19 and 21 and cooling air pockets 7, 11, 13 and 17 which can be acted upon by cooling air.
- the wall 23 of the turbine blade 1 has a large number of passage openings 25, also referred to as cooling air openings 25, which open into the cooling air pockets 7, 11, 13 and 17 and into the cooling duct 3. Through these cooling air openings 25, cooling air can emerge from the cooling channels within the turbine blade 1 onto the outer surface 24 of the wall 23 and form a cooling air film there.
- FIG. 3 shows a device for producing a turbine blade 1.
- the device consists of a ceramic casting mold 27 which comprises an external casting mold 29 divided into two outer parts 29A and 29B. Furthermore, the mold 27 comprises a number of ceramic inner cores 33, 35, 37, 39, 41, 43, 45, 47, 49 and 51 which serve to form the cavities 3, 5, 9, 15, 19 and 21.
- the inner cores 33, 37, 41 are connected to the outer part 29A via ceramic connecting elements 53 and the inner cores 43, 47 and 51 correspondingly to the outer part 29B.
- the inner cores 35 and 39 are also each connected to the adjacent ones via connecting elements 53 (spacer knobs). beard inner cores 33 and 37 and 37 and 41 connected and spaced, while the remaining inner cores 45 and 49 are each attached to only one further inner core 43 and 47 with connecting elements 53.
- the various inner cores 33 to 51 are shaped differently according to the task of the cavities they form.
- the cooling air pockets 7, 11, 13 and 17 are formed, for example, by plate-shaped inner cores 37, 41, 43 and 47.
- the plate-shaped inner cores have holes 57 (see FIG. 5) which are used to form webs (not shown) in the cooler pockets 7, 11, 13 and 17. These webs reinforce the mechanical stability of the turbine blade 1 in the region of the wall 23.
- Connecting elements 53 are glued to the plate-shaped inner cores 37, 41, 43 and 47, which in turn are glued to one of the outer parts 29A and 29B.
- the ceramic connecting elements 53 correspond in their dimensions and their position to the cooling air openings 25 of the turbine blade 1 formed by them and therefore preferably have a cylindrical cross section.
- FIG. 4 shows a cross section of the mold 27 composed of the outer parts 29A and 29B and the inner cores 33, 35, 37, 39, 41, 43, 45, 47, 49 and 51 and the connecting elements 53.
- the outer parts 29A and 29B are firmly connected to one another here.
- the inner cores 35, 39, 45 and 49 intermesh in the manner of a toothing and thus enable the outer parts 29A and 29B to be simply joined together. Due to the fixed connection of each inner core to one of the two outer parts 29A or 29B, the position of each inner core with respect to the neighboring inner cores and with respect to the outer mold formed by the outer parts 29A and 29B is clearly determined.
- FIG. 5 shows an oblique view of a detail from FIG. 3, with the inner cores 37 and 35 not yet having the outer part 29A or the inner core 37 for better illustration are connected.
- the plate-shaped inner core 37 serves to form the cooling pocket 7 which is supplied with cooling air from the cooling air duct 5.
- the inner core 35 which is used to form the cooling air channel 5, extends along a main direction of expansion 55.
- the cross-sectional area 57 perpendicular to the main direction of expansion 55 of the inner core 35 has an essentially triangular shape.
- the connecting elements 53 on the one hand form cooling air openings 25 or connections from the cooling duct 35 to the cooling pocket 37, on the other hand they maintain a fixed distance between the inner cores 37 and 35 or the inner core 37 and the outer part 29A.
- the mold 27 for the turbine blade 1 is assembled in several steps. Since the connecting elements 53 have a cylindrical cross section, they can be cut to the required length from rod-shaped primary material and at the positions of the cooling air openings 25 onto the inner cores 33, 37, 41, 43 and 49 e.g. be glued. Then, the plate-shaped inner cores 37 and 41 or 43 and 47, which are occupied by the connecting elements 53, and the inner cores 33 and 51 are firmly bonded to the outer halves 29A and 29B via the connecting elements 53.
- the inner cores 35, 39, 45 and 49 which form cooling air channels for supplying the cooling air pockets 7, 11, 13 and 17 with cooling air, are glued to the inner cores 37, 41, 43 and 47 assigned to them via connecting elements 53 (spacer knobs) .
- the outer parts 29A and 29B are then assembled into the mold 27 and firmly connected to one another.
- the mold 27 is poured out with liquid metal. After the metal has solidified, the mold 27 is e.g. removed by leaching, and then releases the fully formed turbine blade 1.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19821770 | 1998-05-14 | ||
DE19821770A DE19821770C1 (de) | 1998-05-14 | 1998-05-14 | Verfahren und Vorrichtung zur Herstellung eines metallischen Hohlkörpers |
PCT/DE1999/001289 WO1999059748A1 (de) | 1998-05-14 | 1999-05-03 | Verfahren und vorrichtung zur herstellung eines metallischen hohlkörpers |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1098725A1 true EP1098725A1 (de) | 2001-05-16 |
EP1098725B1 EP1098725B1 (de) | 2003-11-19 |
Family
ID=7867836
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99929074A Expired - Lifetime EP1098725B1 (de) | 1998-05-14 | 1999-05-03 | Verfahren und vorrichtung zur herstellung eines metallischen hohlkörpers |
Country Status (5)
Country | Link |
---|---|
US (1) | US6530416B1 (de) |
EP (1) | EP1098725B1 (de) |
JP (1) | JP2002515338A (de) |
DE (2) | DE19821770C1 (de) |
WO (1) | WO1999059748A1 (de) |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1099825A1 (de) * | 1999-11-12 | 2001-05-16 | Siemens Aktiengesellschaft | Turbinenschaufel und Verfahren zur Herstellung einer Turbinenschaufel |
EP1106280B1 (de) * | 1999-12-08 | 2007-03-07 | General Electric Company | Kern zur Einstellung der Wanddicke einer Turbinenschaufel und Verfahren |
EP1127635A1 (de) * | 2000-02-25 | 2001-08-29 | Siemens Aktiengesellschaft | Vorrichtung und Verfahren zum Giessen eines Werkstücks und Werkstück |
US7162040B2 (en) | 2000-03-30 | 2007-01-09 | Siemens Vdo Automotive, Inc. | Mounting assembly for active noise attenuation system |
EP1145784A1 (de) * | 2000-04-12 | 2001-10-17 | Siemens Aktiengesellschaft | Gussvorrichtung, insbesondere zur Herstellung von Turbinenschaufeln |
DE50013334D1 (de) | 2000-09-14 | 2006-09-28 | Siemens Ag | Vorrichtung und Verfahren zur Herstellung einer Schaufel für eine Turbine sowie entsprechend hergestellte Schaufel |
EP1245785B1 (de) | 2001-03-26 | 2005-06-01 | Siemens Aktiengesellschaft | Verfahren zur Herstellung einer Turbinenschaufel |
ES2301504T3 (es) * | 2001-04-04 | 2008-07-01 | Siemens Aktiengesellschaft | Procedimiento para producir un alabe de turbina. |
US6511293B2 (en) * | 2001-05-29 | 2003-01-28 | Siemens Westinghouse Power Corporation | Closed loop steam cooled airfoil |
US6637500B2 (en) * | 2001-10-24 | 2003-10-28 | United Technologies Corporation | Cores for use in precision investment casting |
DE10346366A1 (de) * | 2003-09-29 | 2005-04-28 | Rolls Royce Deutschland | Turbinenschaufel für ein Flugzeugtriebwerk und Gießform zu deren Herstellung |
EP1529580B1 (de) * | 2003-10-29 | 2009-01-07 | Siemens Aktiengesellschaft | Gussform |
US6929054B2 (en) * | 2003-12-19 | 2005-08-16 | United Technologies Corporation | Investment casting cores |
US7216689B2 (en) * | 2004-06-14 | 2007-05-15 | United Technologies Corporation | Investment casting |
US7172012B1 (en) | 2004-07-14 | 2007-02-06 | United Technologies Corporation | Investment casting |
FR2874186B1 (fr) * | 2004-08-12 | 2008-01-25 | Snecma Moteurs Sa | Procede de fabrication par moulage a cire perdue de pieces comportant au moins une cavite. |
ES2289613T3 (es) * | 2005-02-24 | 2008-02-01 | Vestas Wind Systems A/S | Metodo para fabricar una pala de turbina eolica, instalacion de fabricacion de pala de turbina eolica y uso de la misma. |
US7569172B2 (en) * | 2005-06-23 | 2009-08-04 | United Technologies Corporation | Method for forming turbine blade with angled internal ribs |
US20080005903A1 (en) * | 2006-07-05 | 2008-01-10 | United Technologies Corporation | External datum system and film hole positioning using core locating holes |
DE102006042647A1 (de) * | 2006-09-12 | 2008-03-27 | Mtu Aero Engines Gmbh | Turbine einer Gasturbine |
US8087447B2 (en) * | 2006-10-30 | 2012-01-03 | United Technologies Corporation | Method for checking wall thickness of hollow core airfoil |
JP4991755B2 (ja) * | 2006-12-01 | 2012-08-01 | 新東工業株式会社 | 鋳造方法、上鋳型組立体、および上鋳型に対する中子の固定方法 |
US20100034662A1 (en) * | 2006-12-26 | 2010-02-11 | General Electric Company | Cooled airfoil and method for making an airfoil having reduced trail edge slot flow |
US9272324B2 (en) | 2009-12-08 | 2016-03-01 | Siemens Energy, Inc. | Investment casting process for hollow components |
US20110132562A1 (en) * | 2009-12-08 | 2011-06-09 | Merrill Gary B | Waxless precision casting process |
FR2966067B1 (fr) | 2010-10-19 | 2017-12-08 | Snecma | Moule d'injection pour modele en cire d'une aube de turbine a support du noyau isostatique |
US9649686B2 (en) * | 2012-02-22 | 2017-05-16 | General Electric Company | Casting preforms and methods of use thereof |
US20130280081A1 (en) * | 2012-04-24 | 2013-10-24 | Mark F. Zelesky | Gas turbine engine airfoil geometries and cores for manufacturing process |
US9835035B2 (en) * | 2013-03-12 | 2017-12-05 | Howmet Corporation | Cast-in cooling features especially for turbine airfoils |
US10022790B2 (en) | 2014-06-18 | 2018-07-17 | Siemens Aktiengesellschaft | Turbine airfoil cooling system with leading edge impingement cooling system turbine blade investment casting using film hole protrusions for integral wall thickness control |
FR3030333B1 (fr) * | 2014-12-17 | 2017-01-20 | Snecma | Procede de fabrication d'une aube de turbomachine comportant un sommet pourvu d'une baignoire de type complexe |
FR3046736B1 (fr) * | 2016-01-15 | 2021-04-23 | Safran | Noyau refractaire comprenant un corps principal et une coque |
US10605091B2 (en) | 2016-06-28 | 2020-03-31 | General Electric Company | Airfoil with cast features and method of manufacture |
US10683762B2 (en) * | 2016-07-12 | 2020-06-16 | Rolls-Royce North American Technologies Inc. | Gas engine component with cooling passages in wall |
US10392944B2 (en) * | 2016-07-12 | 2019-08-27 | General Electric Company | Turbomachine component having impingement heat transfer feature, related turbomachine and storage medium |
US10315248B2 (en) * | 2016-11-17 | 2019-06-11 | General Electric Company | Methods and apparatuses using cast in core reference features |
US20180238175A1 (en) * | 2017-02-21 | 2018-08-23 | General Electric Company | Method and Device for Retaining Position of a Consumable Core |
US11098595B2 (en) * | 2017-05-02 | 2021-08-24 | Raytheon Technologies Corporation | Airfoil for gas turbine engine |
US10934854B2 (en) * | 2018-09-11 | 2021-03-02 | General Electric Company | CMC component cooling cavities |
US12042848B2 (en) | 2022-12-13 | 2024-07-23 | General Electric Company | Casting assembly |
Family Cites Families (11)
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US3662816A (en) * | 1968-10-01 | 1972-05-16 | Trw Inc | Means for preventing core shift in casting articles |
US3965963A (en) * | 1973-11-16 | 1976-06-29 | United Technologies Corporation | Mold and process for casting high temperature alloys |
FR2731639A1 (de) * | 1976-12-07 | 1996-09-20 | Rolls Royce Plc | |
GB2080165B (en) * | 1980-07-17 | 1984-10-24 | Rolls Royce | Making article having internal passages eg turbine blade |
US4487246A (en) * | 1982-04-12 | 1984-12-11 | Howmet Turbine Components Corporation | System for locating cores in casting molds |
US4596281A (en) * | 1982-09-02 | 1986-06-24 | Trw Inc. | Mold core and method of forming internal passages in an airfoil |
GB2150875B (en) * | 1983-12-07 | 1986-07-02 | Rolls Royce | Investment casting |
GB2205261B (en) * | 1987-06-03 | 1990-11-14 | Rolls Royce Plc | Method of manufacture and article manufactured thereby |
DE3823287A1 (de) | 1988-07-08 | 1990-01-11 | Draenert Klaus | Markhoehlenabdichtvorrichtung |
US5820774A (en) * | 1996-10-28 | 1998-10-13 | United Technologies Corporation | Ceramic core for casting a turbine blade |
US5950705A (en) * | 1996-12-03 | 1999-09-14 | General Electric Company | Method for casting and controlling wall thickness |
-
1998
- 1998-05-14 DE DE19821770A patent/DE19821770C1/de not_active Expired - Fee Related
-
1999
- 1999-03-05 US US09/700,501 patent/US6530416B1/en not_active Expired - Fee Related
- 1999-05-03 DE DE59907814T patent/DE59907814D1/de not_active Expired - Fee Related
- 1999-05-03 JP JP2000549401A patent/JP2002515338A/ja active Pending
- 1999-05-03 WO PCT/DE1999/001289 patent/WO1999059748A1/de active IP Right Grant
- 1999-05-03 EP EP99929074A patent/EP1098725B1/de not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
---|
See references of WO9959748A1 * |
Also Published As
Publication number | Publication date |
---|---|
DE19821770C1 (de) | 1999-04-15 |
WO1999059748A1 (de) | 1999-11-25 |
DE59907814D1 (de) | 2003-12-24 |
US6530416B1 (en) | 2003-03-11 |
JP2002515338A (ja) | 2002-05-28 |
EP1098725B1 (de) | 2003-11-19 |
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