EP1056602A1 - Use of a heat-sensitive recording material as a label - Google Patents
Use of a heat-sensitive recording material as a labelInfo
- Publication number
- EP1056602A1 EP1056602A1 EP99913163A EP99913163A EP1056602A1 EP 1056602 A1 EP1056602 A1 EP 1056602A1 EP 99913163 A EP99913163 A EP 99913163A EP 99913163 A EP99913163 A EP 99913163A EP 1056602 A1 EP1056602 A1 EP 1056602A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- heat
- sensitive recording
- recording material
- protective layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2848—Three or more layers
Definitions
- the present invention relates to the use of a heat-sensitive recording material consisting of a support, a heat-sensitive recording layer arranged on the front of the support, comprising a dye precursor and a color acceptor which undergoes a color formation reaction when in contact with the dye precursor, an intermediate layer arranged between the support and the heat-sensitive recording layer and a protective layer covering the heat-sensitive recording layer and hardened by means of actinic radiation.
- a heat-sensitive recording material of the type specified above is known from DE-C-3312716.
- the protective layer specified there serves to limit harmful influences which act on the recording material through water, plasticizers, oils or organic solvents and impair the stability of the image density.
- a heat-sensitive recording material with a glossy surface which has a protective layer hardened by actinic radiation, which is said to show excellent adaptability to the thermal head without causing pressure drops.
- a heat-sensitive recording material which has a protective layer arranged over the heat-sensitive recording layer and a back coating, both of which are hardened by means of electron beams.
- An intermediate layer of crosslinked polymers, also hardened by means of electron beams, is additionally arranged between the carrier material and the drawing layer. This intermediate layer is intended to limit the influence of the carrier material on the color formation reaction and the contrast of the resulting image with the background of the image.
- DE-A-42 25 419 discloses a heat-sensitive recording material with a cover layer which has a resin curable by ionizable radiation, the cover layer containing a silicone surface active agent and microspheres of low molecular weight olefin polymer resin.
- the known heat-sensitive recording material is intended as a sticker, for. B, can be used in a fully automatic labeling machine, on the one hand avoiding contamination of the recording head by components of the cover layer, but on the other hand that perfect printability should be ensured.
- a process for producing a heat-sensitive layer and a protective layer to be applied to the heat-sensitive layer from the mixture of a water-soluble or water-dispersible binder which can be crosslinked with electron beams and a prepolymer or monomers curable by electron beams is known from EP-B-0 159 659. It is stated that better resistance to water or moisture should be obtained compared to the conventional heat sensitive recording materials. The use of polysiloxane compounds is proposed for this purpose.
- a heat-sensitive recording material is also known from EP-A-0 780 241, the protective layer of which contains a silicone component. This proposal is intended to achieve better behavior of the recording material on the thermal head and to reduce the so-called fogging.
- a heat-sensitive recording material is known from the unpublished DE-A-19757 589, which has two intermediate layers applied to the heat-sensitive recording layer, namely a barrier layer and a release layer provided on the barrier layer, the release layer consisting mainly of silicone-containing compounds.
- Heat-sensitive recording papers the protective layer of which contains a silicone component
- the addition of silicone is intended to prevent the adhesive layer on the back from sticking to the protective layer. This creates the disadvantage that the printability in flexographic and offset printing is impaired by the addition of silicone.
- the invention provides to use a heat-sensitive recording material which comprises:
- a substrate on the front of which a heat-sensitive recording layer is arranged, which contains a dye precursor and a color acceptor, which undergoes a color formation reaction when in contact with the dye precursor
- b) an intermediate layer arranged between the substrate and the heat-sensitive recording layer c) a heat-sensitive recording layer covering and protective layer free of silicone-containing compounds hardened by actinic radiation
- a self-adhesive layer arranged on the back of the layer support, e) label material which can be wound up on a roll and printed on using the offset or flexographic printing process, in which the self-adhesive layer with the protective layer in Contact is there.
- actinic radiation used in claims and description is to be understood as UV or ionizing radiation, such as electron beams. If the top layer is to be hardened by means of UV rays, the monomers or prepolymers used to produce the top layer must contain additives of initiators in a known manner.
- Electron beam hardening was able to achieve a particularly uniform cross-section, i. H. cured top layer can be achieved.
- the formation of the cover layer with a basis weight in the range from 0.5 to 3.5 g / m 2 is preferred.
- the resin component present in the protective layer and hardened by means of actinic radiation is formed from the monomers or prepolymers of acrylate and / or methacrylate.
- pigments and crosslinking aids can be present in a minor amount in the top layer; in any case, however, the cover layer is free of silicone-containing compounds.
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Theoretical Computer Science (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19806433 | 1998-02-17 | ||
DE19806433A DE19806433B4 (en) | 1998-02-17 | 1998-02-17 | Use of a heat-sensitive recording material as a label |
PCT/EP1999/000964 WO1999042298A1 (en) | 1998-02-17 | 1999-02-13 | Use of a heat-sensitive recording material as a label |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1056602A1 true EP1056602A1 (en) | 2000-12-06 |
EP1056602B1 EP1056602B1 (en) | 2002-05-15 |
Family
ID=7857943
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99913163A Expired - Lifetime EP1056602B1 (en) | 1998-02-17 | 1999-02-13 | Use of a heat-sensitive recording material as a label |
Country Status (8)
Country | Link |
---|---|
US (1) | US6623852B1 (en) |
EP (1) | EP1056602B1 (en) |
JP (1) | JP2002503573A (en) |
AT (1) | ATE217583T1 (en) |
DE (2) | DE19806433B4 (en) |
ES (1) | ES2177266T3 (en) |
NO (1) | NO20000768L (en) |
WO (1) | WO1999042298A1 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10051294C1 (en) * | 2000-10-16 | 2002-04-18 | Mitsubishi Hitec Paper Flensbu | Thermographic material useful for ticket, especially lottery ticket, has protective coating of water-insoluble, self-crosslinking acrylic polymer and crosslinker pigmented (mainly) with highly purified, alkali-treated bentonite |
DE20117479U1 (en) * | 2001-10-25 | 2003-03-06 | Hummel GmbH & Co., 71106 Magstadt | Non-top-coated thermopaper printable by wet offset to give e.g. railway or airline tickets has an acrylic protective layer containing a transparent filler |
DE10341168A1 (en) | 2003-09-06 | 2005-04-07 | Mitsubishi Hitec Paper Flensburg Gmbh | Heat-sensitive recording material and its use |
PL3109059T3 (en) | 2015-06-24 | 2018-10-31 | Mitsubishi Hitec Paper Europe Gmbh | Heat sensitive recording material |
WO2021011939A1 (en) * | 2019-07-18 | 2021-01-21 | Isp Investments Llc | Flexible self-adhesive label comprising a radiation-sensitive indicator for a syringe |
ES2926007T3 (en) | 2020-03-23 | 2022-10-21 | Koehler Innovation & Tech Gmbh | Use of N-(p-toluenesulfonyl)-N¿-(3-p-toluenesulfonyloxyphenyl)urea as a color developer in a heat-sensitive recording material |
WO2024078971A1 (en) | 2022-10-11 | 2024-04-18 | Koehler Innovation & Technology Gmbh | Heat-sensitive recording material |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4484204A (en) | 1982-04-10 | 1984-11-20 | Kanzaki Paper Manufacturing Co., Ltd. | Heat-sensitive record material |
JPS60220786A (en) * | 1984-04-17 | 1985-11-05 | Kanzaki Paper Mfg Co Ltd | Manufacture of thermal recording medium |
DE3529781A1 (en) * | 1984-08-20 | 1986-02-20 | Ricoh Co., Ltd., Tokio/Tokyo | HEAT-SENSITIVE ADHESIVE RECORDING MATERIAL |
US4717709A (en) | 1984-11-02 | 1988-01-05 | Tomoegawa Paper Manufacturing Co., Ltd. | Thermosensitive recording material |
US4833116A (en) | 1986-10-16 | 1989-05-23 | Kanzaki Paper Mfg. Co., Ltd. | Heat-sensitive recording material |
DE3935070A1 (en) | 1988-10-21 | 1990-04-26 | Dainippon Ink & Chemicals | Thermographic material with photocured top coat - contains poly:unsatd. heterocyclic cpd., pref. modified tris:hydroxy-alkyl isocyanurate (meth)acrylate |
US5061677A (en) | 1988-12-12 | 1991-10-29 | Tomoegawa Paper Co., Ltd. | Thermo-sensitive recording label paper |
DE4012185C1 (en) * | 1990-04-14 | 1991-05-23 | Renker Gmbh & Co Kg, 5160 Dueren, De | |
JPH0532051A (en) | 1991-07-31 | 1993-02-09 | Kanzaki Paper Mfg Co Ltd | Thermal recording material |
US5840657A (en) * | 1994-02-18 | 1998-11-24 | The Standard Register Company | Imagable linerless pressure sensitive adhesive |
JP3071130B2 (en) * | 1994-09-13 | 2000-07-31 | 株式会社巴川製紙所 | Reversible thermosensitive recording medium |
US5658661C1 (en) * | 1995-08-29 | 2002-06-11 | Media Solutions Inc | Matted release coat for self-wound thermal printable facestock |
JPH09183270A (en) | 1995-09-21 | 1997-07-15 | Ricoh Co Ltd | Thermal recording type release label |
EP0780241B1 (en) | 1995-12-21 | 2001-08-01 | Ricoh Company, Ltd | Thermosensitive recording material with protective layer |
US5977021A (en) * | 1996-12-24 | 1999-11-02 | Oji Paper Co., Ltd | Heat-sensitive recording adhesive sheet |
-
1998
- 1998-02-17 DE DE19806433A patent/DE19806433B4/en not_active Expired - Fee Related
-
1999
- 1999-02-13 EP EP99913163A patent/EP1056602B1/en not_active Expired - Lifetime
- 1999-02-13 JP JP2000532280A patent/JP2002503573A/en active Pending
- 1999-02-13 WO PCT/EP1999/000964 patent/WO1999042298A1/en active IP Right Grant
- 1999-02-13 ES ES99913163T patent/ES2177266T3/en not_active Expired - Lifetime
- 1999-02-13 DE DE59901445T patent/DE59901445D1/en not_active Expired - Lifetime
- 1999-02-13 AT AT99913163T patent/ATE217583T1/en not_active IP Right Cessation
- 1999-02-13 US US09/622,494 patent/US6623852B1/en not_active Expired - Lifetime
-
2000
- 2000-02-16 NO NO20000768A patent/NO20000768L/en not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO9942298A1 * |
Also Published As
Publication number | Publication date |
---|---|
ES2177266T3 (en) | 2002-12-01 |
JP2002503573A (en) | 2002-02-05 |
DE19806433B4 (en) | 2004-11-11 |
WO1999042298A1 (en) | 1999-08-26 |
DE59901445D1 (en) | 2002-06-20 |
NO20000768L (en) | 2000-03-24 |
EP1056602B1 (en) | 2002-05-15 |
ATE217583T1 (en) | 2002-06-15 |
US6623852B1 (en) | 2003-09-23 |
DE19806433A1 (en) | 1999-08-19 |
NO20000768D0 (en) | 2000-02-16 |
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