EP1040228B1 - Plastic permeated porous substrate based product - Google Patents

Plastic permeated porous substrate based product Download PDF

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Publication number
EP1040228B1
EP1040228B1 EP98965776A EP98965776A EP1040228B1 EP 1040228 B1 EP1040228 B1 EP 1040228B1 EP 98965776 A EP98965776 A EP 98965776A EP 98965776 A EP98965776 A EP 98965776A EP 1040228 B1 EP1040228 B1 EP 1040228B1
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EP
European Patent Office
Prior art keywords
polyolefin
porous substrate
plastic
film
paper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP98965776A
Other languages
German (de)
French (fr)
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EP1040228A1 (en
Inventor
Maximilian Zaher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MZE ENGINEERING FUER VERFAHRENSTECHNIK GMBH
Bush Industries Inc
Original Assignee
Mze Engineering fur Verfahrenstechnik GmbH
Bush Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Publication of EP1040228A1 publication Critical patent/EP1040228A1/en
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Anticipated expiration legal-status Critical
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/22—Polyalkenes, e.g. polystyrene
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/35—Polyalkenes, e.g. polystyrene
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/04—Physical treatment, e.g. heating, irradiating
    • D21H25/06—Physical treatment, e.g. heating, irradiating of impregnated or coated paper

Definitions

  • the invention relates to a method for producing a film-like product made of a porous carrier material polyolefin penetrated homogeneously therein.
  • the introduction of the plastic into a porous carrier material is also known from DE-OS 16 19 190.
  • the carrier material is leather is preferred, but can also be a fabric.
  • the plastic that has penetrated is stiffened, for example as a shoe stiffening material (such as Shoe caps).
  • EP 678 619 A1 describes a plastic sheet and a method known for their production, in the porous agglomerates mechanically from at least one hydrophobic thermoplastic powder are anchored in and / or fixed to a carrier material are.
  • the carrier material is preferably porous and exists made of plastic and / glass fibers. Due to the porosity of The plastic sheet has a high plastic and carrier material Water vapor permeability, on the other hand, is under construction site conditions weldable.
  • the invention has for its object to provide a product which is suitable in the manner of a film, in simpler Way on substrates of all kinds, e.g. B. wood, applied, in particular to be glued.
  • the product is said to Belly Can be used as wallpaper or as a covering for products of all kinds.
  • the product should be easy to stick be given on the substrate. Did the article on to which the product according to the invention is to be applied, sharp edges, so should be by coating with the invention A bevel can be reached.
  • the invention Foil is said to be comfortable for a human user feel (so-called "softtouch"). It is said to be high mechanical Stability, in particular high splitting strength, have and be easy to process.
  • the film of the invention is intended to replace a conventional one PVC film serve.
  • the film product according to the invention during manufacture, processing and, if applicable, disposal be as environmentally friendly as possible.
  • the method described above leads to an inventive The simplest type of film. It has one high gap strength and feels for a human user pleasant to the touch; the film has a soft, almost textile-like Surface.
  • Polystyrene and polypropylene can be used in particular as the polyolefin and polyethylene. Derate polyolefins are after slightly milky after hardening. It is therefore intended that sublimable the porous carrier before application of the polyolefin Dispersion paint is applied. If afterwards the polyolefin is applied to the support so printed with color the polyolefin penetrates under the influence of heat porous carrier and at the same time or later diffuses the Color due to heat in the polyolefin. It arises overall a film in which the porous support serves as a "framework", into which the polyolefin penetrated homogeneously is, so fills the porous gaps. Such a slide can be easily applied to a substrate, e.g. B. wood, stick on, because the porous carrier (unlike polyolefins) is easy to glue. As a porous carrier comes in particular Consider paper, especially 80 g paper.
  • the following penetration of the polyolefin into the porous carrier has a layer of lacquer on at least one side applied, preferably a curable by electron radiation Lacquer layer (ESH lacquer).
  • ESH lacquer electron radiation Lacquer layer
  • Textile materials are also suitable as the porous carrier.
  • the single figure schematically shows a porous carrier 10, an emulsion paint 12 applied thereon and one thereon applied polyolefin film 14 in a state during the Manufacturing process of the product.
  • the porous carrier 10 is a paper in the exemplary embodiment (80 g).
  • the paper is porous and permeable to liquids. It is printed with a sublimable emulsion paint.
  • the Color can be homogeneous or represent a graphic motif, a decoration using different colors include.
  • the paper as a porous support 10 can be conventional Way to be printed with the dye motif.
  • the printed paper is placed on a conventional paper coating machine excited and it becomes a polyolefin applied as a coating material.
  • a conventional paper coating machine heated cylinders at temperatures from 200 ° C to 260 ° C. It is about insofar as the polyolefin is applied to the printed paper an extrusion technique.
  • a preferred development of the as described above manufactured film product is achieved in that a Lacquer layer is applied on one or both sides.
  • P refers an electron-curable lacquer (ESH lacquer) used and hardened.
  • ESH lacquer electron-curable lacquer

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Laminated Bodies (AREA)
  • Paper (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Description

Die Erfindung betrifft ein Verfahren zum Herstellen eines folienartigen Erzeugnisses aus einem porösen Trägermaterial mit darin homogen eingedrungenem Polyolefin.The invention relates to a method for producing a film-like product made of a porous carrier material polyolefin penetrated homogeneously therein.

Aus der Veröffentlichung Data Base WPI, An. 81-389740, XP002099029 ist es bekannt, einen porösen Träger mit Kunststoff zu beschichten und anschließend zu trocknen. Dieses Produkt soll als Stützträger für Tapeten geeignet sein.From the publication Data Base WPI, An. 81-389740, XP002099029 it is known to be a porous support with plastic to coat and then dry. This product should be suitable as a support for wallpapers.

Das Einbringen vom Kunststoff in ein poröses Trägermaterial ist auch aus der DE-OS 16 19 190 bekannt. Das Trägermaterial ist dabei bevorzugt Leder, kann aber auch ein Gewebe sein. Durch den eingedrungenen Kunststoff wird das Trägermaterial versteift, um beispielsweise als Schuhversteifungsmaterial (wie Schuhkappen) zu dienen.The introduction of the plastic into a porous carrier material is also known from DE-OS 16 19 190. The carrier material is leather is preferred, but can also be a fabric. By the plastic that has penetrated is stiffened, for example as a shoe stiffening material (such as Shoe caps).

Aus der EP 678 619 A1 ist eine Kunststoffbahn und ein Verfahren zu deren Herstellung bekannt, bei der poröse Agglomerate aus wenigstens einem hydrophoben Thermoplast-Pulver mechanisch in einem Trägermaterial verankert sind und/oder an diesem fixiert sind. Bevorzugt ist das Trägermaterial porös und besteht aus Kunststoff- und/Glasfasern. Aufgrund der Porosität vom Kunststoff und Trägermaterial hat die Kunststoffbahn eine hohe Wasserdampfdurchlässigkeit, ist aber andererseits unter Baustellenbedingungen verschweißbar.EP 678 619 A1 describes a plastic sheet and a method known for their production, in the porous agglomerates mechanically from at least one hydrophobic thermoplastic powder are anchored in and / or fixed to a carrier material are. The carrier material is preferably porous and exists made of plastic and / glass fibers. Due to the porosity of The plastic sheet has a high plastic and carrier material Water vapor permeability, on the other hand, is under construction site conditions weldable.

Der Erfindung liegt die Aufgabe zugrunde, ein Erzeugnis bereitzustellen, das in der Art einer Folie geeignet ist, in einfacher Weise auf Substrate aller Art, z. B. Holz, aufgebracht, insbesondere verklebt zu werden. Das Erzeugnis soll z. B. auch als Tapete verwendbar sein oder auch als Ummantelung von Produkten aller Art. Dabei soll eine gute Verklebbarkeit des Erzeugnisses auf dem Substrat gegeben sein. Hat der Artikel, auf den das erfindungsgemäße Erzeugnis aufgebracht werden soll, scharfe Kanten, so soll durch die Beschichtung mit der erfindungsgemäßen Folie ein Abkanten erreichbar sein. Die erfindungsgemäße Folie soll sich für einen menschlichen Benutzer angenehm anfühlen (sog. "softtouch"). Sie soll eine hohe mechanische Stabilität, insbesondere hohe Spaltfestigkeit, aufweisen und in einfacher Weise weiterverarbeitbar sein. Insbesondere soll die erfindungsgemäße Folie als Ersatz für eine herkömmliche PVC-Folie dienen. Weiterhin soll das erfindungsgemäße Folienerzeugnis bei Herstellung, Verarbeitung und ggf. der Entsorgung möglichst wenig umweltbelastend sein.The invention has for its object to provide a product which is suitable in the manner of a film, in simpler Way on substrates of all kinds, e.g. B. wood, applied, in particular to be glued. The product is said to Belly Can be used as wallpaper or as a covering for products of all kinds. The product should be easy to stick be given on the substrate. Did the article on to which the product according to the invention is to be applied, sharp edges, so should be by coating with the invention A bevel can be reached. The invention Foil is said to be comfortable for a human user feel (so-called "softtouch"). It is said to be high mechanical Stability, in particular high splitting strength, have and be easy to process. In particular the film of the invention is intended to replace a conventional one PVC film serve. Furthermore, the film product according to the invention during manufacture, processing and, if applicable, disposal be as environmentally friendly as possible.

Das erfindungsgemäße Verfahren zum Herstellen eines solchen folienartigen Erzeugnisses ist im Patentanspruch 1 beschrieben. Bevorzugte Ausgestaltungen des Verfahrens lehren die abhängigen Ansprüche.The method according to the invention for producing such a film-like Product is described in claim 1. The dependent teach preferred embodiments of the method Expectations.

Das vorstehend beschriebene Verfahren führt zu einem erfindungsgemäßen Folienerzeugnis der einfachsten Art. Es hat eine hohe Spaltfestigkeit und fühlt sich für einen menschlichen Benutzer angenehm an; die Folie hat eine weiche, fast textilartige Oberfläche.The method described above leads to an inventive The simplest type of film. It has one high gap strength and feels for a human user pleasant to the touch; the film has a soft, almost textile-like Surface.

Als Polyolefin sind insbesondere verwendbar Polystyrol, Polypropylen und Polyethylen. Deratige Polyolefine werden nach dem Härten leicht milchig. Es ist deshalb vorgesehen, daß auf den porösen Träger vor Aufbringung des Polyolefins eine sublimierbare Dispersionsfarbe aufgebracht wird. Wenn anschließend das Polyolefin auf den so mit Farbe bedruckten Träger aufgebracht wird, dringt das Polyolefin unter Wärmeeinwirkung in den porösen Träger und gleichzeitig oder später diffundiert die Farbe durch Wärmeeinwirkung im Polyolefin. Es entsteht insgesamt eine Folie, bei der der poröse Träger als "Gerüst" dient, in welches das Polyolefin homogen eingedrungen ist, also die porösen Lücken auffüllt. Eine solche Folie läßt sich in einfacher Weise auf ein Substrat, z. B. Holz, aufkleben, da der poröse Träger (im Unterschied zu Polyolefinen) leicht verklebbar ist. Als poröser Träger kommt insbesondere in Betracht ein Papier, insbesondere ein 80 g Papier.Polystyrene and polypropylene can be used in particular as the polyolefin and polyethylene. Derate polyolefins are after slightly milky after hardening. It is therefore intended that sublimable the porous carrier before application of the polyolefin Dispersion paint is applied. If afterwards the polyolefin is applied to the support so printed with color the polyolefin penetrates under the influence of heat porous carrier and at the same time or later diffuses the Color due to heat in the polyolefin. It arises overall a film in which the porous support serves as a "framework", into which the polyolefin penetrated homogeneously is, so fills the porous gaps. Such a slide can be easily applied to a substrate, e.g. B. wood, stick on, because the porous carrier (unlike polyolefins) is easy to glue. As a porous carrier comes in particular Consider paper, especially 80 g paper.

Nach Herstellen des Erzeugnisses in der vorstehend beschriebenen Weise kann das Polyolefin nachvernetzt werden, ohne daß das Erzeugnis die vorstehend geschilderten vorteilhaften Eigenschaften verliert.After manufacturing the product in the manner described above The polyolefin can be post-crosslinked without this Product has the advantageous properties described above loses.

Gemäß einer bevorzugten Ausgestaltung der Erfindung wird im Anschluß an das Eindringen des Polyolefins in den porösen Träger eine Lackschicht auf zumindest einer Seite aufgetragen, bevorzugt eine durch Elektronenstrahlung härtbare Lackschicht (ESH-Lack). Die Aushärtung der Lackschicht bewirkt insgesamt eine Verbesserung der Stabilität und Haftung der Systemkomponenten.According to a preferred embodiment of the invention, the following penetration of the polyolefin into the porous carrier has a layer of lacquer on at least one side applied, preferably a curable by electron radiation Lacquer layer (ESH lacquer). The coating layer hardens overall an improvement in the stability and liability of the system components.

Als poröser Träger kommen auch textilartige Materialien in Betracht.Textile materials are also suitable as the porous carrier.

Nachfolgend wird ein Ausführungsbeispiel der Erfindung anhand der Zeichnung näher erläutert.An exemplary embodiment of the invention is described below the drawing explained in more detail.

Die einzige Figur zeigt schematisch einen porösen Träger 10, eine darauf aufgetragene Dispersionsfarbe 12 und einen darauf aufgebrachten Polyolefinfilm 14 in einem Zustand während des Herstellungsverfahrens des Erzeugnisses.The single figure schematically shows a porous carrier 10, an emulsion paint 12 applied thereon and one thereon applied polyolefin film 14 in a state during the Manufacturing process of the product.

Der poröse Träger 10 ist beim Ausführungsbeispiel ein Papier (80 g). Das Papier ist porös und flüssigkeitsdurchlässig. Es wird mit einer sublimierbaren Dispersionsfarbe bedruckt. Die Farbe kann homogen sein oder auch ein grafisches Motiv darstellen, also unter Verwendung verschiedener Farben eine Dekoration beinhalten. Das Papier als poröser Träger 10 kann in herkömmlicher Weise mit dem Farbstoffmotiv bedruckt werden.The porous carrier 10 is a paper in the exemplary embodiment (80 g). The paper is porous and permeable to liquids. It is printed with a sublimable emulsion paint. The Color can be homogeneous or represent a graphic motif, a decoration using different colors include. The paper as a porous support 10 can be conventional Way to be printed with the dye motif.

Das bedruckte Papier wird auf eine als solche herkömmliche Papierbeschichtungsmaschine gespannt und es wird ein Polyolefin als Beschichtungsmaterial aufgetragen. Hierfür können bei der herkömmlichen Beschichtungsmaschine geheizte Zylinder bei Temperaturen von 200° C bis 260° C dienen. Es handelt sich insoweit beim Aufbringen des Polyolefins auf das bedruckte Papier um eine Extrusionstechnik.The printed paper is placed on a conventional paper coating machine excited and it becomes a polyolefin applied as a coating material. For this, at conventional coating machine heated cylinders at temperatures from 200 ° C to 260 ° C. It is about insofar as the polyolefin is applied to the printed paper an extrusion technique.

Gute Ergebnisse wurden erzielt durch Aufbringung von 50 g bis 500 g Polyolefin pro qm, optimal waren die Ergebnisse bei etwa 250 g/qm. Durch die Wärmeeinwirkung sickert das Polyolefin durch das Papier und durchdringt dieses homogen. Gleichzeitig diffundieren aufgrund der Wärmeeinwirkung die Dispersionsfarbstoffe in allen Richtungen durch das Polyolefin. Hierfür werden Temperaturen von 220° C bis 280° C, insbesondere etwa 260° C eingesetzt.Good results have been achieved by applying 50 g to 500 g polyolefin per square meter, the results were optimal at around 250 gsm. The polyolefin seeps through the action of heat through the paper and penetrates it homogeneously. simultaneously the disperse dyes diffuse due to the effect of heat in all directions through the polyolefin. For this be Temperatures from 220 ° C to 280 ° C, especially about 260 ° C used.

Nach dem Abkühlen entsteht ein weiches, hervorragend verarbeitbares Folienprodukt mit hoher Stabilität und insbesondere Spaltfestigkeit. Ggf. kann eine Nachvernetzung des Polyolefins durchgeführt werden. Das beim Bedrucken des Papiers erzeugte farbige Motiv geht beim vorstehend beschriebenen Prozeß nicht verloren, d. h. das Folienerzeugnis hat eine dem bedruckten Papier entsprechende farbige Dekoration.After cooling, a soft, excellently workable is created Film product with high stability and in particular Cleavage strength. Possibly. can post-crosslink the polyolefin be performed. What was created when printing on the paper colored motif does not work in the process described above lost, d. H. the film product has one of the printed paper corresponding colored decoration.

Eine bevorzugte Weiterbildung des wie vorstehend beschrieben hergestellten Folienproduktes wird dadurch erreicht, daß eine Lackschicht auf einer oder beiden Seiten aufgetragen wird. Bevorzugt wird ein durch Elektronenstrahl härtbarer Lack (ESH-Lack) verwendet und gehärtet. Hierdurch werden die mechanischen Eigenschaften und auch die Verarbeitbarkeit des Folienproduktes wesentlich verbessert.A preferred development of the as described above manufactured film product is achieved in that a Lacquer layer is applied on one or both sides. Prefers an electron-curable lacquer (ESH lacquer) used and hardened. As a result, the mechanical Properties and also the processability of the film product significantly improved.

Claims (6)

  1. A process for the production of a film-type product comprising the following steps:
    a sublimable dispersion dye (12) is applied to a porous substrate (10);
    a polyolefin (14) is applied to the porous substrate (10) and the disperse dye;
    the substrate, the dye and the polyolefin are heated to 220°C to 280°C so that the polyolefin penetrates into the porous substrate homogeneously and diffuses the disperse dye.
  2. The process according to claim 1,
    characterised in that
    a paper is used as porous substrate (10).
  3. The process according to claim 2,
    characterised in that
    the paper is coated with the polyolefin by means of heated cylinders.
  4. The process according to one of the preceding claim,
    characterised in that
    50 g/m2 to 500 g/m2 polyolefin are applied to the porous substrate (10).
  5. The process according to one of the preceding claims,
    characterised in that
    after the polyolefin has penetrated into the porous substrate and the dye has diffused, the polyolefin is subjected to post-crosslinking.
  6. The process according to one of the preceding claims,
    characterised in that
    a lacquer film is applied to the plastic-permeated, especially polyolefin-permeated substrate and is cured.
EP98965776A 1997-12-09 1998-12-07 Plastic permeated porous substrate based product Expired - Lifetime EP1040228B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19754619 1997-12-09
DE19754619A DE19754619A1 (en) 1997-12-09 1997-12-09 Product made of a porous carrier, which is penetrated by a plastic
PCT/EP1998/007936 WO1999029959A1 (en) 1997-12-09 1998-12-07 Plastic permeated porous substrate based product

Publications (2)

Publication Number Publication Date
EP1040228A1 EP1040228A1 (en) 2000-10-04
EP1040228B1 true EP1040228B1 (en) 2003-03-05

Family

ID=7851257

Family Applications (1)

Application Number Title Priority Date Filing Date
EP98965776A Expired - Lifetime EP1040228B1 (en) 1997-12-09 1998-12-07 Plastic permeated porous substrate based product

Country Status (6)

Country Link
EP (1) EP1040228B1 (en)
JP (1) JP2001526332A (en)
CA (1) CA2314183C (en)
DE (2) DE19754619A1 (en)
ES (1) ES2190138T3 (en)
WO (1) WO1999029959A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10046550B2 (en) 2013-08-22 2018-08-14 Massachusetts Institute Of Technology Carrier-substrate adhesive system
US9359198B2 (en) 2013-08-22 2016-06-07 Massachusetts Institute Of Technology Carrier-substrate adhesive system

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1154582A (en) * 1965-05-26 1969-06-11 Vik Supplies Ltd Improvements in or relating to Stiffening of Shoe Components.
GB1116992A (en) * 1965-12-13 1968-06-12 Exxon Research Engineering Co Process and apparatus for coating and impregnating
JPS5637371A (en) * 1979-08-31 1981-04-11 Mitsui Petrochemical Ind Nonwoven fabric
CH686370A5 (en) * 1994-04-19 1996-03-15 Sarna Patent & Lizenz Ag Plastic sheet.

Also Published As

Publication number Publication date
CA2314183C (en) 2006-10-03
DE59807413D1 (en) 2003-04-10
EP1040228A1 (en) 2000-10-04
WO1999029959A1 (en) 1999-06-17
JP2001526332A (en) 2001-12-18
DE19754619A1 (en) 1999-06-24
CA2314183A1 (en) 1999-06-17
ES2190138T3 (en) 2003-07-16

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