EP1035194A3 - Use of comb polymers as soil release polymers - Google Patents

Use of comb polymers as soil release polymers Download PDF

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Publication number
EP1035194A3
EP1035194A3 EP00102085A EP00102085A EP1035194A3 EP 1035194 A3 EP1035194 A3 EP 1035194A3 EP 00102085 A EP00102085 A EP 00102085A EP 00102085 A EP00102085 A EP 00102085A EP 1035194 A3 EP1035194 A3 EP 1035194A3
Authority
EP
European Patent Office
Prior art keywords
oder
bis
und
aryl
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP00102085A
Other languages
German (de)
French (fr)
Other versions
EP1035194B1 (en
EP1035194A2 (en
Inventor
Johannes Dr. Becherer
Frank-Peter Di. Lang
Bernhard Dr. Mees
Roman Dr. Morschhäuser
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clariant Produkte Deutschland GmbH
Original Assignee
Clariant GmbH
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Filing date
Publication date
Application filed by Clariant GmbH filed Critical Clariant GmbH
Publication of EP1035194A2 publication Critical patent/EP1035194A2/en
Publication of EP1035194A3 publication Critical patent/EP1035194A3/en
Application granted granted Critical
Publication of EP1035194B1 publication Critical patent/EP1035194B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds

Abstract

Verwendung von Kammpolymeren, erhalten durch Kondensation von

  • a) einer Polycarbonsäure oder einem Polyalkohol,
  • b) einem oder mehreren gegebenenfalls durch Sulfogruppen substituierten Polyalkoholen mit 2 bis 4 OH-Gruppen oder Polyglykolen der Formel HO-(XO)a-H, worin X C2H4 und/oder C3H7 und a eine Zahl von 2 bis 35, vorzugsweise 2 bis 5 bedeutet,
  • c) einer oder mehreren gegebenenfalls sulfonierten C2-C10-Dicarbonsäuren und
  • d) einer oder mehreren Verbindungen der Formeln NH2R, NHR2, ROH, R1COOH, HO(XO)b-H, HO(CH2CH2)dSO3K worin R C1-C22-Alkyl oder C6-C10-Aryl, R1 C1-C22-Alkyl, C1-C22-Sulfoalkyl, C6-C10-Aryl oder C6-C10-Sulfoaryl, X C2H4 und/oder C3H7, b eine Zahl von 3 bis 40, vorzugsweise 3 bis 20, d eine Zahl von 1 bis 10, vorzugsweise 1 bis 4 und K ein Kation bedeuten, als Schmutzlösepolymere.
    • Use of comb polymers obtained by condensing
  • a) a polycarboxylic acid or a polyalcohol,
  • b) one or more polyalcohols which are optionally substituted by sulfo groups and have 2 to 4 OH groups or polyglycols of the formula HO- (XO) a -H, where XC 2 H 4 and / or C 3 H 7 and a is a number from 2 to 35 , preferably means 2 to 5,
  • c) one or more optionally sulfonated C 2 -C 10 dicarboxylic acids and
  • d) one or more compounds of the formulas NH 2 R, NHR 2 , ROH, R 1 COOH, HO (XO) b -H, HO (CH 2 CH 2 ) d SO 3 K in which RC 1 -C 22 alkyl or C 6 -C 10 aryl, R 1 C 1 -C 22 alkyl, C 1 -C 22 sulfoalkyl, C 6 -C 10 aryl or C 6 -C 10 sulfoaryl, XC 2 H 4 and / or C 3 H 7 , b is a number from 3 to 40, preferably 3 to 20, d is a number from 1 to 10, preferably 1 to 4 and K is a cation, as soil release polymers.

    • EP00102085A 1999-02-16 2000-02-03 Use of comb polymers as soil release polymers Expired - Lifetime EP1035194B1 (en)

    Applications Claiming Priority (2)

    Application Number Priority Date Filing Date Title
    DE19906367 1999-02-16
    DE19906367A DE19906367A1 (en) 1999-02-16 1999-02-16 Soil release polymer, useful in laundry detergent, aid or conditioner or detergent for hard surface, is comb oligoester obtained by condensing polycarboxylic acid or polyol, polyol or polyglycol and monofunctional compound

    Publications (3)

    Publication Number Publication Date
    EP1035194A2 EP1035194A2 (en) 2000-09-13
    EP1035194A3 true EP1035194A3 (en) 2002-01-02
    EP1035194B1 EP1035194B1 (en) 2004-09-15

    Family

    ID=7897617

    Family Applications (1)

    Application Number Title Priority Date Filing Date
    EP00102085A Expired - Lifetime EP1035194B1 (en) 1999-02-16 2000-02-03 Use of comb polymers as soil release polymers

    Country Status (5)

    Country Link
    US (1) US6255274B1 (en)
    EP (1) EP1035194B1 (en)
    JP (1) JP4731656B2 (en)
    DE (2) DE19906367A1 (en)
    ES (1) ES2228311T3 (en)

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    DE10131371A1 (en) * 2001-06-28 2003-01-16 Clariant Gmbh Use of quaternized (meth) acrylic acid dialkylaminoalkyl esters as soil release polymers for hard surfaces, and a process for their preparation
    JP2002505360A (en) * 1998-03-07 2002-02-19 バイヤースドルフ・アクチエンゲゼルシヤフト Sulphonated comb polymers and preparations based on such sulphonated comb polymers, in particular hair cosmetic preparations
    US7390432B2 (en) * 1998-06-30 2008-06-24 Sandia Corporation Enhanced formulations for neutralization of chemical, biological and industrial toxants
    DE19942302A1 (en) * 1999-09-04 2001-03-08 Beiersdorf Ag Sulfonated comb polymers with selected lithium / sodium ratio and preparations, in particular hair cosmetic preparations based on such sulfonated comb polymers
    WO2002018475A1 (en) * 2000-08-31 2002-03-07 Beiersdorf Ag Silicon-modified, sulphonated comb polymers and preparations, especially hair care preparations based on said silicon-modified, sulphonated comb polymers
    DE10104991A1 (en) * 2001-02-03 2002-08-08 Clariant Gmbh Microencapsulated biologically active ingredients containing a water-soluble or water-dispersible comb polymer
    JP2002265996A (en) * 2001-03-14 2002-09-18 Toyo Riken Kk Agent for cleaning stainproof treatment of hydrophobic hard surface and method for cleaning stainproof treatment
    JP2002292329A (en) * 2001-04-02 2002-10-08 Toyo Riken Kk Method for lustering and stainproofing treatment of hard surface
    US20050000031A1 (en) * 2003-06-27 2005-01-06 The Procter & Gamble Company Fabric article treating system
    DE102005027604A1 (en) * 2005-06-15 2006-12-28 Clariant Produkte (Deutschland) Gmbh Cleaning agent for hard surfaces
    GB0704933D0 (en) * 2007-03-15 2007-04-25 Reckitt Benckiser Nv Detergent composition
    DE102007013217A1 (en) 2007-03-15 2008-09-18 Clariant International Ltd. Anionic Soil Release Polymers
    US7828907B2 (en) * 2007-05-09 2010-11-09 Ecolab Inc. Detergent component for preventing precipitation of water hardness and providing soil removal properties
    US8361953B2 (en) * 2008-02-08 2013-01-29 Evonik Goldschmidt Corporation Rinse aid compositions with improved characteristics
    US8614053B2 (en) 2009-03-27 2013-12-24 Eastman Chemical Company Processess and compositions for removing substances from substrates
    US8309502B2 (en) * 2009-03-27 2012-11-13 Eastman Chemical Company Compositions and methods for removing organic substances
    US8444768B2 (en) * 2009-03-27 2013-05-21 Eastman Chemical Company Compositions and methods for removing organic substances
    DE102009020299A1 (en) 2009-05-07 2010-11-11 Clariant International Ltd. Comb polymers and their use in detergents and cleaners
    UA106790C2 (en) 2010-04-01 2014-10-10 Евонік Дегусса Гмбх fabric softener active composition
    CN102834496B (en) 2010-04-01 2014-01-15 赢创德固赛有限公司 Fabric softener active composition
    EP2563889B1 (en) 2010-04-28 2017-03-15 Evonik Degussa GmbH Textile softening composition
    US8507425B2 (en) 2010-06-29 2013-08-13 Evonik Degussa Gmbh Particulate fabric softener comprising ethylenediamine fatty acid amides and method of making
    CA2821989A1 (en) * 2010-12-17 2012-06-21 The Procter & Gamble Company Cleaning compositions with polyoxyalkylene-oxide capped polyalkylene-oxide-polycarboxylate comb polymers
    US8846599B2 (en) 2011-06-15 2014-09-30 Basf Se Branched polyesters with sulfonate groups
    WO2012171849A1 (en) 2011-06-15 2012-12-20 Basf Se Branched polyesters with sulfonate groups
    WO2013113453A1 (en) 2012-01-30 2013-08-08 Evonik Industries Ag Fabric softener active composition
    MX366465B (en) 2012-05-07 2019-07-10 Evonik Degussa Gmbh Star Fabric softener active composition and method for making it.
    US9029268B2 (en) 2012-11-21 2015-05-12 Dynaloy, Llc Process for etching metals
    DE102013207778A1 (en) * 2013-04-29 2014-10-30 Cht R. Beitlich Gmbh Comb polymers as detergency booster for detergents and cleaners
    BR102014025172B1 (en) 2013-11-05 2020-03-03 Evonik Degussa Gmbh METHOD FOR MANUFACTURING A TRIS- (2-HYDROXYETHYL) -METHYLMETHYL ESTER OF FATTY ACID AND ACTIVE COMPOSITION OF SOFTENING CLOTHES
    UA119182C2 (en) 2014-10-08 2019-05-10 Евонік Дегусса Гмбх Fabric softener active composition
    US9828571B2 (en) * 2015-06-05 2017-11-28 Illinois Tool Works, Inc. Heavy duty laundry detergent
    DE102016003544A1 (en) 2016-03-22 2017-09-28 Weylchem Wiesbaden Gmbh Polyester, process for their preparation and their use
    EP3489340A1 (en) 2017-11-28 2019-05-29 Clariant International Ltd Renewably sourced soil release polyesters
    DE102020006977A1 (en) 2020-11-13 2022-05-19 WeylChem Performance Products GmbH Aqueous-alcoholic polyester compositions, detergents and cleaning agents containing these and their use

    Citations (6)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    WO1995002029A1 (en) * 1993-07-08 1995-01-19 The Procter & Gamble Company Detergent compositions comprising soil release agents
    US5691298A (en) * 1994-12-14 1997-11-25 The Procter & Gamble Company Ester oligomers suitable as soil release agents in detergent compositions
    US5700386A (en) * 1996-08-08 1997-12-23 The Procter & Gamble Company Process for making soil release polymer granules
    US5843878A (en) * 1993-07-08 1998-12-01 Procter & Gamble Company Detergent compositions comprising soil release agents
    DE19735715A1 (en) * 1997-08-18 1999-02-25 Huels Chemische Werke Ag Amphiphilic polymer useful as soil-release polymer
    DE19909757A1 (en) * 1998-03-07 1999-09-16 Beiersdorf Ag Water-soluble or -dispersible comb polymers used in hair cosmetics, e.g. hair spray, lacquer, setting foam or styling gel

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    JPH07505670A (en) 1992-04-13 1995-06-22 ザ、プロクター、エンド、ギャンブル、カンパニー Applications of modified polyester for cleaning cotton-containing fabrics
    ES2129077T3 (en) 1992-07-31 1999-06-01 Procter & Gamble USE OF MODIFIED POLYESTERS FOR THE ELIMINATION OF GREASE FROM TEXTILE GENERES.
    ES2096479T3 (en) 1993-07-08 1997-03-01 Procter & Gamble DETERGENT COMPOSITIONS INCLUDING AGENTS TO RELEASE DIRT.
    JPH08208830A (en) * 1995-02-03 1996-08-13 Sanyo Chem Ind Ltd Hydrophilic elastomer and resin composition for molding

    Patent Citations (6)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    WO1995002029A1 (en) * 1993-07-08 1995-01-19 The Procter & Gamble Company Detergent compositions comprising soil release agents
    US5843878A (en) * 1993-07-08 1998-12-01 Procter & Gamble Company Detergent compositions comprising soil release agents
    US5691298A (en) * 1994-12-14 1997-11-25 The Procter & Gamble Company Ester oligomers suitable as soil release agents in detergent compositions
    US5700386A (en) * 1996-08-08 1997-12-23 The Procter & Gamble Company Process for making soil release polymer granules
    DE19735715A1 (en) * 1997-08-18 1999-02-25 Huels Chemische Werke Ag Amphiphilic polymer useful as soil-release polymer
    DE19909757A1 (en) * 1998-03-07 1999-09-16 Beiersdorf Ag Water-soluble or -dispersible comb polymers used in hair cosmetics, e.g. hair spray, lacquer, setting foam or styling gel

    Also Published As

    Publication number Publication date
    JP4731656B2 (en) 2011-07-27
    ES2228311T3 (en) 2005-04-16
    DE19906367A1 (en) 2000-08-17
    JP2000239365A (en) 2000-09-05
    EP1035194B1 (en) 2004-09-15
    US6255274B1 (en) 2001-07-03
    DE50007720D1 (en) 2004-10-21
    EP1035194A2 (en) 2000-09-13

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