EP0987315A1 - Compositions de blanchiment - Google Patents

Compositions de blanchiment Download PDF

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Publication number
EP0987315A1
EP0987315A1 EP98870196A EP98870196A EP0987315A1 EP 0987315 A1 EP0987315 A1 EP 0987315A1 EP 98870196 A EP98870196 A EP 98870196A EP 98870196 A EP98870196 A EP 98870196A EP 0987315 A1 EP0987315 A1 EP 0987315A1
Authority
EP
European Patent Office
Prior art keywords
bleach
surfactants
alkyl
bleaching
use according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP98870196A
Other languages
German (de)
English (en)
Inventor
Andrea Briatore (NMN)
Giovanni Grande (NMN)
Michael Alan John Moss
Oreste Todini (Nmn)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to EP98870196A priority Critical patent/EP0987315A1/fr
Priority to CA002341188A priority patent/CA2341188A1/fr
Priority to PCT/US1999/021588 priority patent/WO2000015744A1/fr
Publication of EP0987315A1 publication Critical patent/EP0987315A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0031Carpet, upholstery, fur or leather cleansers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/042Acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3947Liquid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395Bleaching agents
    • C11D3/3956Liquid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/75Amino oxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/90Betaines

Definitions

  • the bleaching compositions are formulated as solids, for example as granules, tablets or powders, they are preferably applied on the fabrics to be bleached according to the present invention in a liquid form, i.e., solid compositions are used in combination with an appropriate solvent, typically water.
  • hypohalite bleaches among those described above are the alkali metal or alkaline earth metal hypochlorites selected from the group consisting of sodium, potassium, magnesium, lithium and calcium hypochlorites, and mixtures thereof.
  • Sodium hypochlorite is the most preferred hypohalite bleach.
  • Exemplary surfactants are C 12 -C 18 alkyl polyethoxylate (1.0) sulphonate, C 12 -C 18 E(1.0)M), C 12 -C 18 alkyl polyethoxylate (2.25) sulphonate, C 12 -C 18 E(2.25)M), C 12 -C 18 alkyl polyethoxylate (3.0) sulphonate C 12 -C 18 E(3.0), and C 12 -C 18 alkyl polyethoxylate (4.0) sulphonate C 12 -C 18 E(4.0)M), wherein M is conveniently selected from sodium and potassium.
  • betaine/sulphobetaine Some common examples of betaine/sulphobetaine are described in U.S. Pat. Nos. 2,082,275, 2,702,279 and 2,255,082, incorporated herein by reference.
  • alkalinity sources include ammonia, ammonium carbonate and hydrogen carbonate.
  • the bleaching compositions of the present invention may further comprise another surfactant in addition to the surfactants which are part of the fabric protective system.
  • Said surfactant may be present in the bleaching compositions according to the present invention in amounts up to 30%, preferably of from 0.1 % to 20% and more preferably of from 0.1 % to 10% by weight of the total composition.
  • optical brighteners which are useful in the present bleaching compositions are those identified in U.S. Patent 4,790,856. These brighteners include the PHORWHITE® series of brighteners from Verona. Other brighteners disclosed in this reference include: Tinopal-UNPA®, Tinopal CBS® and Tinopal 5BM® available from Ciba-Geigy; Artic White CC® and Artic White CWD®; the 2-(4-styryl-phenyl)-2H-naptho[1,2-d]triazoles; 4,4'-bis(1,2,3-triazol-2-yl)-stilbenes; 4,4'-bis(styryl)bisphenyls; and the aminocoumarins.
  • the bleaching compositions according to the present invention may comprise up to 1.0% by weight of the total composition of a brightener or a mixture thereof, preferably from 0.005% to 0.5%, more preferably from 0.005% to 0.3% and most preferably from 0.008% to 0.1%.
  • the process of bleaching fabrics comprises the step of contacting fabrics with a liquid bleaching composition according to the present invention, in its neat form, of allowing said fabrics to remain in contact with said bleaching composition for a period of time sufficient to bleach said fabrics, typically 5 seconds to 30 minutes, preferably 1 minute to 10 minutes and then rinsing said fabrics with water. If said fabrics are to be washed, i.e., with a conventional composition comprising at least one surface active agent, said washing may be conducted before or after that said fabrics have been bleached.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
EP98870196A 1998-09-16 1998-09-16 Compositions de blanchiment Withdrawn EP0987315A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP98870196A EP0987315A1 (fr) 1998-09-16 1998-09-16 Compositions de blanchiment
CA002341188A CA2341188A1 (fr) 1998-09-16 1999-09-16 Compositions de blanchiment
PCT/US1999/021588 WO2000015744A1 (fr) 1998-09-16 1999-09-16 Compositions de blanchiment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP98870196A EP0987315A1 (fr) 1998-09-16 1998-09-16 Compositions de blanchiment

Publications (1)

Publication Number Publication Date
EP0987315A1 true EP0987315A1 (fr) 2000-03-22

Family

ID=8237094

Family Applications (1)

Application Number Title Priority Date Filing Date
EP98870196A Withdrawn EP0987315A1 (fr) 1998-09-16 1998-09-16 Compositions de blanchiment

Country Status (3)

Country Link
EP (1) EP0987315A1 (fr)
CA (1) CA2341188A1 (fr)
WO (1) WO2000015744A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3045662B1 (fr) 2015-12-21 2020-10-02 Eurotab Composition solide chloree blanchissante protegeant la fibre

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4083795A (en) * 1975-01-24 1978-04-11 Rhone-Poulenc Industries Solid, non-corrosive detergent compositions
SU1189877A1 (ru) * 1984-01-06 1985-11-07 Закавказский Комплексный Отдел Московского Филиала Всесоюзного Научно-Исследовательского И Проектного Института Химической Промышленности Дезинфицирующее отбеливающее средство "дезбел
US4568477A (en) * 1983-12-06 1986-02-04 Lever Brothers Company Detergent bleach compositions
US4686063A (en) * 1986-09-12 1987-08-11 The Procter & Gamble Company Fatty peroxyacids or salts thereof having amide moieties in the fatty chain and low levels of exotherm control agents
EP0396341A2 (fr) * 1989-05-01 1990-11-07 The Procter & Gamble Company Granulé de blanchiment aggloméré à base de peroxyacide et procédé de préparation
EP0431747A2 (fr) * 1989-11-30 1991-06-12 The Clorox Company Détergent oxydant aqueux stable
WO1991012309A2 (fr) * 1990-02-08 1991-08-22 Unilever N.V. Composition de blanchissage liquide
WO1996033258A1 (fr) * 1995-04-20 1996-10-24 Albright & Wilson Uk Limited Suspensions aqueuses stabilisees d'agent de blanchiment contenant des particules de perborate
EP0825250A1 (fr) * 1996-08-21 1998-02-25 The Procter & Gamble Company Compositions de blanchiment

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0937772A1 (fr) * 1998-02-23 1999-08-25 The Procter & Gamble Company Compositions de blanchiment

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4083795A (en) * 1975-01-24 1978-04-11 Rhone-Poulenc Industries Solid, non-corrosive detergent compositions
US4568477A (en) * 1983-12-06 1986-02-04 Lever Brothers Company Detergent bleach compositions
SU1189877A1 (ru) * 1984-01-06 1985-11-07 Закавказский Комплексный Отдел Московского Филиала Всесоюзного Научно-Исследовательского И Проектного Института Химической Промышленности Дезинфицирующее отбеливающее средство "дезбел
US4686063A (en) * 1986-09-12 1987-08-11 The Procter & Gamble Company Fatty peroxyacids or salts thereof having amide moieties in the fatty chain and low levels of exotherm control agents
EP0396341A2 (fr) * 1989-05-01 1990-11-07 The Procter & Gamble Company Granulé de blanchiment aggloméré à base de peroxyacide et procédé de préparation
EP0431747A2 (fr) * 1989-11-30 1991-06-12 The Clorox Company Détergent oxydant aqueux stable
WO1991012309A2 (fr) * 1990-02-08 1991-08-22 Unilever N.V. Composition de blanchissage liquide
WO1996033258A1 (fr) * 1995-04-20 1996-10-24 Albright & Wilson Uk Limited Suspensions aqueuses stabilisees d'agent de blanchiment contenant des particules de perborate
EP0825250A1 (fr) * 1996-08-21 1998-02-25 The Procter & Gamble Company Compositions de blanchiment

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 8621, Derwent World Patents Index; Class D25, AN 86-136703, XP002092499 *

Also Published As

Publication number Publication date
WO2000015744A1 (fr) 2000-03-23
CA2341188A1 (fr) 2000-03-23

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