EP0932005A1 - Installations combinées d'un four et d'un appareil de distillation d'air et procédé de mise en oeuvre - Google Patents
Installations combinées d'un four et d'un appareil de distillation d'air et procédé de mise en oeuvre Download PDFInfo
- Publication number
- EP0932005A1 EP0932005A1 EP99400149A EP99400149A EP0932005A1 EP 0932005 A1 EP0932005 A1 EP 0932005A1 EP 99400149 A EP99400149 A EP 99400149A EP 99400149 A EP99400149 A EP 99400149A EP 0932005 A1 EP0932005 A1 EP 0932005A1
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- EP
- European Patent Office
- Prior art keywords
- air
- compressor
- column
- line
- turbine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
- F25J3/04018—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of main feed air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
- F25J3/04024—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of purified feed air, so-called boosted air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04048—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of cold gaseous streams, e.g. intermediate or oxygen enriched (waste) streams
- F25J3/04054—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of cold gaseous streams, e.g. intermediate or oxygen enriched (waste) streams of air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04109—Arrangements of compressors and /or their drivers
- F25J3/04115—Arrangements of compressors and /or their drivers characterised by the type of prime driver, e.g. hot gas expander
- F25J3/04121—Steam turbine as the prime mechanical driver
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04109—Arrangements of compressors and /or their drivers
- F25J3/04115—Arrangements of compressors and /or their drivers characterised by the type of prime driver, e.g. hot gas expander
- F25J3/04127—Gas turbine as the prime mechanical driver
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04109—Arrangements of compressors and /or their drivers
- F25J3/04139—Combination of different types of drivers mechanically coupled to the same compressor, possibly split on multiple compressor casings
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04109—Arrangements of compressors and /or their drivers
- F25J3/04145—Mechanically coupling of different compressors of the air fractionation process to the same driver(s)
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/0429—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
- F25J3/04303—Lachmann expansion, i.e. expanded into oxygen producing or low pressure column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04375—Details relating to the work expansion, e.g. process parameter etc.
- F25J3/04381—Details relating to the work expansion, e.g. process parameter etc. using work extraction by mechanical coupling of compression and expansion so-called companders
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/0446—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using the heat generated by mixing two different phases
- F25J3/04466—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using the heat generated by mixing two different phases for producing oxygen as a mixing column overhead gas by mixing gaseous air feed and liquid oxygen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
- F25J3/04527—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general
- F25J3/04551—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the metal production
- F25J3/04557—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the metal production for pig iron or steel making, e.g. blast furnace, Corex
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
- F25J3/04563—Integration with a nitrogen consuming unit, e.g. for purging, inerting, cooling or heating
- F25J3/04575—Integration with a nitrogen consuming unit, e.g. for purging, inerting, cooling or heating for a gas expansion plant, e.g. dilution of the combustion gas in a gas turbine
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
- F25J3/04593—The air gas consuming unit is also fed by an air stream
- F25J3/046—Completely integrated air feed compression, i.e. common MAC
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/04—Processes or apparatus using separation by rectification in a dual pressure main column system
- F25J2200/06—Processes or apparatus using separation by rectification in a dual pressure main column system in a classical double column flow-sheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/42—Processes or apparatus involving steps for increasing the pressure of gaseous process streams the fluid being nitrogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2235/00—Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams
- F25J2235/50—Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams the fluid being oxygen
Definitions
- the present invention relates to combined installations of at least an oven, typically a metal processing oven, supplied with compressed air and at least one air distillation apparatus producing oxygen for enrich the air supplied to the oven.
- the document EP-A-0 531 182 provides for complete separation of the air supplies from the blast furnace, on the one hand, but also of the medium pressure column and the mixing column, on the other hand, to preselect the pressure in the mixing column in a wide pressure range, but at cost price high investment and operating costs for rotating machines feeding the sub-assemblies of the distillation apparatus.
- the object of the present invention is to provide an installation combined of the type mentioned above, with further integration into the site and allowing significantly reduced operating costs.
- the installation combined includes: at least one oven, at least one blower delivering a main compressed air line connected to the oven, at least one air distillation comprising at least one medium pressure column and one mixing column having an oxygen outlet line opening into a downstream part of the main compressed air line, and an air bypass circuit, connected to the main compressed air line via a purification device and supplying air to the medium pressure column and the mixing column and including at least one compressor-turbine group comprising at least one compressor to compress the derived air supplied at least to the column mixture, and at least one turbine arranged in a fluid circuit under pressure available at the installation site.
- the distillation apparatus exploits not only a part of the air flow of the differentiable blower due to reinjection subsequent oxygen in this air flow, but also the extractable energy of a pressurized fluid generally available on site, outside the device distillation, such as steam or process waste gases, possibly valued.
- the present invention also relates to a method of implementing work of a combined installation comprising at least one furnace supplied with air compressed by at least one blower supplying air to a first pressure, and oxygen by an air separation device, comprising at least minus a medium pressure column and a mixing column, supplied with air through the blower, in which we overpress, at a second pressure greater than the first pressure, the air supplied to at least the mixing by at least one compressor driven by at least one turbine relieving at least one compressed fluid generated on site.
- a diagrammatic representation of a metal treatment furnace in this case an FM blast furnace, and an associated air distillation apparatus, essentially comprising, in the examples shown, a main exchange line LE , a double column DC with a medium pressure column MP and a low pressure column BP, and a mixing column CM, the oven and the distillation apparatus being supplied with air by the same blower S delivering in a compressed air line main A supplying the FM oven, a large volume of air (typically greater than 100,000 Nm 3 / h) at a medium pressure P 1 less than 6 x 10 5 Pa, typically between 3 x 10 5 Pa and 5.5 x 10 5 Pa.
- Line A can also supply, simultaneously or alternately, another metal treatment furnace, for example an electric furnace with the AOD process.
- a circuit air bypass D supplying the distillation apparatus with purified air in a purification device E, typically of the adsorption type, after precooling in a cooling device R.
- the cooling circuit bypass D is divided, downstream of the purification device E, into a first line J crossing the exchange line LE to reach the lower part of the medium pressure column MP, and in a second line L crossing also the LE exchange line and opening at the bottom of the column of CM mixture.
- the distillation apparatus is of the conventional double column type DC, with a turbine t for expansion at low pressure of the low pressure column BP of part of the incoming air supplied by the first line M and serving to keep the distillation apparatus cold, and with a pump W compressing the liquid oxygen taken from the tank of the low pressure column BP and sent to the head of the mixing column CM substantially at the pressure P 2 of the air, cooled in the vicinity of its dew point, admitted by the line L.
- this pressure P 2 is chosen to be slightly higher than that P 1 in the main line A for take into account the pressure drops in the hot air / oxygen mixing devices downstream of line A and to optimize the regulation of this injection.
- P 2 - P 1 is between 0.3 x 10 5 Pa and 4 x 10 5 Pa, advantageously between 0.5 x 10 5 Pa and 1.5 x 10 5 Pa.
- the air at this pressure P 2 is obtained by means of at least one compressor / turbine group C i T i compressing the air at least in the line L, the turbine T i expanding a fluid under pressure F available on the installation site, outside the distillation apparatus, typically a process waste gas or an excess process gas.
- the fluid F i will be water vapor, generally generated in abundance on the site to cool its constituents and available at pressures typically varying between 3 ⁇ 10 5 Pa and 15 ⁇ 10 5 Pa and of which only a small part is generally valued, especially for the production of cold or electrical energy.
- the fluid F i can also be a hot residual gas at the outlet of the furnace FM, which can be expanded directly or partially transformed into combustible gas serving as fuel f for a compressor-turbine group with combustion chamber GT, represented in FIG. 3, advantageously exploiting at least one of the gases of the air supplied by the lines N and O and serving for the production of energy, part of the flow compressed by the compressor of this group being transmitted to the turbine T i .
- the compressor-turbine group C 2 -T 2 is arranged in line L and only serves to boost the air flow supplied to the mixing column CM.
- the compressor-turbine group C 1 -T 1 is arranged in line D, upstream of the purification device E, and therefore overpresses all of the air supplied to the distillation apparatus.
- the overpressure, at an intermediate pressure between P 1 and P 2 , of the supply air supplied to the medium pressure column MP is used in the cold maintenance turbine t to cause a booster c disposed in line L and creating the overpressure required to reach the pressure P 2 in the mixing column CM.
- FIG. 3 is a combination of the embodiments of FIGS. 1 and 2: in this variant, a first compressor-turbine group C 1 -T 1 , driven by a first pressurized fluid F 1 , is arranged in line D, upstream of the purification device E, and a second compressor-turbine group C 2 -T 2 , driven by a second pressurized fluid F 2 is disposed in line L dedicated to the mixing column CM .
- the fluid F 2 can be supplied from a gas turbine group GT as mentioned above and the fluid F 1 can be steam.
- the two compressors C 1 , C 2 can be driven by the same turbine or the same group of turbines T 1 / T 2 expanding the same fluid under pressure F i .
- the pressure in line J supplying the double column is exploited by coupling the cold keeping turbine t to a booster c serving to boost one of the fluids entering or leaving the device distillation, for example, as shown in Figure 3, the impure nitrogen in line N to help the recovery of this impure nitrogen, for example introduced as ballast in the combustion chamber of the gas turbine group GT.
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
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Abstract
Description
les figures 1 à 3 représentent schématiquement trois modes de réalisation de l'invention.
Claims (15)
- Installation combinée comprenant : au moins un four (FM), au moins une soufflante (S) débitant dans une ligne d'air comprimé principale (A) reliée au four, au moins un appareil de distillation d'air comportant au moins une colonne moyenne pression (MP) et une colonne de mélange (CM) ayant une ligne de sortie d'oxygène (O) débouchant dans une partie aval de la ligne d'air comprimé principale (A), et un circuit de dérivation d'air, relié à la ligne d'air comprimé principale via un appareil d'épuration (E) et fournissant de l'air à la colonne moyenne pression (MP) et à la colonne de mélange (CM) et incluant au moins un groupe compresseur-turbine (C,T) comprenant au moins un compresseur (C1) pour comprimer l'air dérivé fourni au moins à la colonne de mélange (CM), et au moins une turbine (Ti) disposée dans un circuit (Fi) de fluide sous pression disponible sur le site de l'installation.
- Installation selon la revendication 1, caractérisée en ce qu'elle comprend au moins un compresseur (C1) de groupe compresseur-turbine (Ci-Ti) disposé dans une partie amont du circuit de dérivation (D), avant l'appareil d'épuration (E).
- Installation selon la revendication 1 ou 2, caractérisée en ce qu'elle comprend au moins un compresseur (C2) de groupe compresseur-turbine (Ci-Ti) disposé dans la ligne d'alimentation en air (L) de la colonne de mélange (CM).
- Procédé de mise en oeuvre d'une installation combinée comprenant au moins un four (FM) alimenté en air comprimé par au moins une soufflante (S) fournissant de l'air à une première pression P1 et en oxygène par un appareil de séparation de l'air, comprenant une colonne moyenne pression (MP) et une colonne de mélange (CM), alimenté en air par la soufflante, dans lequel on surpresse, à une seconde pression P2, supérieure à la première pression P1, l'air fourni à au moins la colonne de mélange (CM) par au moins un compresseur (Ci) entraíné par au moins une turbine (Ti) détendant au moins un fluide comprimé (Fi) généré sur le site.
- Procédé selon la revendication 4, caractérisé en ce que P1 est inférieure à 6 x 105 Pa.
- Procédé selon la revendication 5, caractérisé en ce que P2 - P1 est supérieur à 0,3 x 105 Pa.
- Procédé selon la revendication 6, caractérisé en ce que P2 - P1 est inférieur à 4 x 105 Pa.
- Procédé selon l'une des revendications 4 à 7, caractérisé en ce que la totalité du flux d'air fourni à l'appareil de séparation est surpressé dans un dit compresseur (C1).
- Procédé selon la revendication 8, caractérisé en ce que le flux d'air transmis à la colonne de mélange (CM) est de nouveau surpressé (C, C2).
- Procédé selon la revendication 9, caractérisé en ce que le flux d'air transmis à la colonne de mélange (CM) est de nouveau surpressé dans un dit compresseur (C2).
- Procédé selon l'une des revendications 4 à 7, caractérisé en ce que seul le flux d'air transmis à la colonne de mélange (CM) est surpressé par un dit compresseur (C2).
- Procédé selon l'une des revendications 4 à 10, caractérisé en ce que le fluide comprimé (Fi) est de la vapeur.
- Procédé selon l'une des revendications 4 à 11, caractérisé en ce que le fluide comprimé (Fi) est un gaz provenant du four (FM).
- Procédé selon l'une des revendications 4 à 11, caractérisé en ce que le fluide comprimé (Fi) est comprimé par un groupe compresseur-turbine à gaz (GT) utilisant un carburant (f) disponible sur site.
- Procédé selon la revendication 14, caractérisé en ce que le groupe compresseur-turbine à gaz exploite au moins un des gaz séparés de l'air (O; N) fournis par l'appareil de séparation d'air.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9800724A FR2774159B1 (fr) | 1998-01-23 | 1998-01-23 | Installation combinee d'un four et d'un appareil de distillation d'air et procede de mise en oeuvre |
FR9800724 | 1998-01-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0932005A1 true EP0932005A1 (fr) | 1999-07-28 |
Family
ID=9522094
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99400149A Ceased EP0932005A1 (fr) | 1998-01-23 | 1999-01-22 | Installations combinées d'un four et d'un appareil de distillation d'air et procédé de mise en oeuvre |
Country Status (7)
Country | Link |
---|---|
US (1) | US6119482A (fr) |
EP (1) | EP0932005A1 (fr) |
KR (1) | KR100573530B1 (fr) |
AR (1) | AR014473A1 (fr) |
BR (1) | BR9917589A (fr) |
CA (1) | CA2259857A1 (fr) |
FR (1) | FR2774159B1 (fr) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6803890B1 (en) * | 1999-03-24 | 2004-10-12 | Imaging Systems Technology | Electroluminescent (EL) waveform |
FR2801963B1 (fr) * | 1999-12-02 | 2002-03-29 | Air Liquide | Procede et installation de separation d'air par distillation cryogenique |
EP1197717A1 (fr) * | 2000-10-12 | 2002-04-17 | Linde Aktiengesellschaft | Dispositif et procédé de séparation de l'air |
EP1202012B1 (fr) * | 2000-10-30 | 2005-12-07 | L'AIR LIQUIDE, Société Anonyme à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des | Procédé et installation de séparation cryogénique d'air intégré à un procédé associé |
US6568207B1 (en) * | 2002-01-18 | 2003-05-27 | L'air Liquide-Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude | Integrated process and installation for the separation of air fed by compressed air from several compressors |
US6536234B1 (en) * | 2002-02-05 | 2003-03-25 | Praxair Technology, Inc. | Three column cryogenic air separation system with dual pressure air feeds |
FR2862004B3 (fr) * | 2003-11-10 | 2005-12-23 | Air Liquide | Procede et installation d'enrichissement d'un flux gazeux en l'un de ses constituants |
FR2864214B1 (fr) * | 2003-12-22 | 2017-04-21 | Air Liquide | Appareil de separation d'air, appareil integre de separation d'air et de production d'un metal et procede de demarrage d'un tel appareil de separation d'air |
US20050256335A1 (en) * | 2004-05-12 | 2005-11-17 | Ovidiu Marin | Providing gases to aromatic carboxylic acid manufacturing processes |
DE102016107468B9 (de) * | 2016-04-22 | 2017-12-21 | Fritz Winter Eisengiesserei Gmbh & Co. Kg | Verfahren und Anlage zur Nutzung eines von einer Gaszerlegeeinrichtung bereitgestellten Zielgases |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4022030A (en) * | 1971-02-01 | 1977-05-10 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Thermal cycle for the compression of a fluid by the expansion of another fluid |
EP0531182A1 (fr) * | 1991-08-07 | 1993-03-10 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procédé et installation de distillation d'air, et application a l'alimentation en gaz d'une aciérie |
US5244489A (en) * | 1991-06-12 | 1993-09-14 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process for supplying a blast furnace with air enriched in oxygen, and corresponding installation for the reduction of iron ore |
EP0636845A1 (fr) * | 1993-04-30 | 1995-02-01 | The BOC Group plc | Séparation d air |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4382366A (en) * | 1981-12-07 | 1983-05-10 | Air Products And Chemicals, Inc. | Air separation process with single distillation column for combined gas turbine system |
US5251450A (en) * | 1992-08-28 | 1993-10-12 | Air Products And Chemicals, Inc. | Efficient single column air separation cycle and its integration with gas turbines |
GB9425484D0 (en) * | 1994-12-16 | 1995-02-15 | Boc Group Plc | Air separation |
-
1998
- 1998-01-23 FR FR9800724A patent/FR2774159B1/fr not_active Expired - Fee Related
-
1999
- 1999-01-22 US US09/236,271 patent/US6119482A/en not_active Expired - Fee Related
- 1999-01-22 CA CA002259857A patent/CA2259857A1/fr not_active Abandoned
- 1999-01-22 BR BR9917589-4A patent/BR9917589A/pt not_active IP Right Cessation
- 1999-01-22 AR ARP990100271A patent/AR014473A1/es unknown
- 1999-01-22 KR KR1019990001890A patent/KR100573530B1/ko not_active IP Right Cessation
- 1999-01-22 EP EP99400149A patent/EP0932005A1/fr not_active Ceased
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4022030A (en) * | 1971-02-01 | 1977-05-10 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Thermal cycle for the compression of a fluid by the expansion of another fluid |
US5244489A (en) * | 1991-06-12 | 1993-09-14 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process for supplying a blast furnace with air enriched in oxygen, and corresponding installation for the reduction of iron ore |
EP0531182A1 (fr) * | 1991-08-07 | 1993-03-10 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procédé et installation de distillation d'air, et application a l'alimentation en gaz d'une aciérie |
EP0636845A1 (fr) * | 1993-04-30 | 1995-02-01 | The BOC Group plc | Séparation d air |
Also Published As
Publication number | Publication date |
---|---|
KR100573530B1 (ko) | 2006-04-26 |
CA2259857A1 (fr) | 1999-07-23 |
KR19990068066A (ko) | 1999-08-25 |
FR2774159B1 (fr) | 2000-03-17 |
US6119482A (en) | 2000-09-19 |
AR014473A1 (es) | 2001-02-28 |
BR9917589A (pt) | 2002-07-30 |
FR2774159A1 (fr) | 1999-07-30 |
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