EP0909850B1 - Woven glass web - Google Patents

Woven glass web Download PDF

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Publication number
EP0909850B1
EP0909850B1 EP98118639A EP98118639A EP0909850B1 EP 0909850 B1 EP0909850 B1 EP 0909850B1 EP 98118639 A EP98118639 A EP 98118639A EP 98118639 A EP98118639 A EP 98118639A EP 0909850 B1 EP0909850 B1 EP 0909850B1
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EP
European Patent Office
Prior art keywords
fabric web
textile glass
glass fabric
decorative
web according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP98118639A
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German (de)
French (fr)
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EP0909850A2 (en
EP0909850A3 (en
Inventor
Wigbert H. Sauer
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Individual
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Individual
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Publication of EP0909850A3 publication Critical patent/EP0909850A3/en
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0092—Non-continuous polymer coating on the fibrous substrate, e.g. plastic dots on fabrics
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/242—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads inorganic, e.g. basalt
    • D03D15/267—Glass
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/08—Inorganic fibres
    • D06N2201/082—Glass fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/068—Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/08—Properties of the materials having optical properties
    • D06N2209/0807—Coloured
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/08—Properties of the materials having optical properties
    • D06N2209/0861—Transparent
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1657—Printability
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles

Definitions

  • the invention relates to a textile glass fabric web, the 100% fiber consists of textile glass fibers and their Back has a self-adhesive layer.
  • Such a fabric web preferably in the form of a self-adhesive Glass fiber wallpaper, is from the utility model DE-U1-81 24 330 known.
  • this well-known fabric web the warp and weft threads are made with a thin layer Plastic finish wrapped on all sides, the finish preferably has a low permanent tack to resulting fiber particles when cutting the fabric web bind immediately. Otherwise, the all-round wrapping the warp and weft threads achieve that the push resistance of the fabric increases and the workability is facilitated.
  • GB-A-2 249 994 also describes one Glass fiber fabric web. Polyurethane as a carrier for the overprint are not mentioned.
  • Textile glass fabrics are rot-proof, non-flammable, hydrophobic and not hygroscopic, and they make a special one aesthetically appealing surface structure of the occupied areas. Because of this, they will be everywhere there used where increased fire protection requirements and hygienic requirements are made, i.e. in public buildings of all kinds, hospitals, schools, Kindergartens, medical practices, hotels, on ships and the like.
  • the invention has for its object a self-adhesive Provide textile glass fabric sheet that is printable is so that the print is durable and abrasion resistant sticks to the glass fiber material.
  • a textile glass fabric sheet in the form of one with a colored Pattern or motif printed wallpaper or in the form of a self-adhesive, decorative printed tape provided become.
  • the thin layer consisting of the polymeric adhesion promoter can be printed completely in one or more colors.
  • the thin layer is only partially under Formation of a decorative pattern printed because including unprinted areas with the appearance natural textile glass fabric, aesthetically particularly appealing Patterns that can also be achieved in in many different ways through transparent or translucent, if necessary, have colored top coats vary.
  • the from the polymeric adhesion promoter existing thin layer itself be transparent or translucent and / or colored.
  • the polymeric adhesion promoter preferably consists of polyurethane or contains polyurethane.
  • the adhesion promoter will preferably in the form of an aqueous polyurethane dispersion - Before or after applying the self-adhesive layer on the back of the textile glass fabric sheet - at least on those sections of the warp and weft threads, which form the front of the fabric web, sprayed on or rolled on.
  • Hot ironing equipment is recommended especially when for the self-adhesive layer a heat activated glue is used to e.g. Ribbons, borders or borders made of printed textile glass fabric for decoration on walls, doors, shop windows or other suitable surfaces.
  • Wet rubbing equipment is recommended wherever At the same time, high air humidity and heavy traffic the appropriately equipped rooms meet, like when using fiberglass wallpaper in Baths, shower and changing rooms, gyms, club houses, Hospitals, etc.
  • Such additional equipment is carried out using commercially available products, e.g. aqueous emulsions of piperidine derivatives.
  • the decorative imprint of the textile glass fabric web according to the invention can be pigment printing, transfer printing, inkjet printing, Plotter printing and / or rotary printing.
  • Pigment prints are prints that are made using Pigments are made, the individual particles with polymeric binders are encased under the action of pressure and heat stick to the substrate stay.
  • the thin layer and / or the decorative Print additionally an UV stabilizer, for example a commercially available benzotriazole derivative, and / or one Heat stabilizer, for example a piperidine derivative, contain.
  • UV stabilizer for example a commercially available benzotriazole derivative
  • Heat stabilizer for example a piperidine derivative
  • the self-adhesive layer applied on the back can be a continuous, closed layer; prefers however, it is an interrupted layer, at the one between the crossing points of the warp and weft threads gaps located at least partially remain open.
  • the textile glass fabric web according to the invention preferably has the form of a self-adhesive, residue-free removable wallpaper, the form of a self-adhesive, residue-free removable border or border or Form of a self-adhesive, removable without residue Band.
  • Self-adhesive is - in contrast to "self-adhesive” - understood an adhesive property that due to a relatively low adhesion with a high one at the same time Is characterized by cohesion.
  • the decorative print preferably has the shape of a endless in at least one direction (lengthways or crossways) Pattern or motif or the shape of one in at least a direction of a constantly repeating pattern or motif (Rapport).
  • the decorative imprint can take the form of itself repeating name, company, logo, Company or club badge, coat of arms, national emblem, Show test or guarantee mark. These embodiments are particularly advantageous for the commercial sector, if the desire of many companies for "corporate identity" also in the interior of production and office spaces Should be taken into account. But also the needs of sports and other clubs, their respective logo in the premises of the association, but also those of the supporters of the association, permanently in the form of a wallpaper or a Attaching wallpaper-shaped tape is made by the invention met in an ideal way.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The woven web is composed of 100% textile glass fibers, with a self-adhesive layer on the reverse side. At least sections of the filaments in the warps and wefts, forming the front side of the material, are coated with a thin layer of a polymer adhesion primer to carry a single- or multi-color print. The polymer primer is printed as a thin layer only in zones for a decorative pattern. The polymer adhesion primer is transparent or translucent or is colored. The polymer adhesion primer is made of or contains polyurethane. The thin polymer layer is resistant to ironing or wet rubbing. The decorative pattern is applied by dye print, transfer print, ink jet printing, plotter printing or rotary press printing. The thin polymer adhesion primer or the decorative print additionally contains an ultraviolet stabilizer such as a benzotriazol derivative or heat stabilizer such as a piperidine derivative. Open zones are left at the intersections between the warps and wefts. The printed pattern is covered by a transparent or translucent or a colored coating. The material can be finished using aqueous emulsions of piperidine derivatives. The decorative pattern is a continuous patterning or motifs or pattern or motif repeats, in at least one direction.

Description

Die Erfindung betrifft eine Textilglasgewebebahn, deren Faseranteil zu 100 % aus Textilglasfasern besteht und deren Rückseite eine selbsthaftende Kleberschicht aufweist.The invention relates to a textile glass fabric web, the 100% fiber consists of textile glass fibers and their Back has a self-adhesive layer.

Eine solche Gewebebahn, vorzugsweise in Form einer selbsthaftenden Glasfasertapete, ist aus dem Gebrauchsmuster DE-U1-81 24 330 bekannt. Bei dieser bekannten Gewebebahn sind die Kett- und Schußfäden mit einer dünnen Schicht aus Kunststoffappretur allseitig umhüllt, wobei die Appretur vorzugsweise eine geringe Permanentklebrigkeit aufweist, um beim Zuschneiden der Gewebebahn entstehende Faserpartikel sofort zu binden. Im übrigen wird durch die allseitige Umhüllung der Kett- und Schußfäden erreicht, daß die Schiebefestigkeit des Gewebes erhöht und die Verarbeitbarkeit erleichtert wird. GB-A- 2 249 994 beschreibt ebenfalls eine Glasfasergewebebahn. Polyurethane als Träger für den Aufdruck werden nicht erwähnt.Such a fabric web, preferably in the form of a self-adhesive Glass fiber wallpaper, is from the utility model DE-U1-81 24 330 known. With this well-known fabric web the warp and weft threads are made with a thin layer Plastic finish wrapped on all sides, the finish preferably has a low permanent tack to resulting fiber particles when cutting the fabric web bind immediately. Otherwise, the all-round wrapping the warp and weft threads achieve that the push resistance of the fabric increases and the workability is facilitated. GB-A-2 249 994 also describes one Glass fiber fabric web. Polyurethane as a carrier for the overprint are not mentioned.

Aus der europäischen Patentschrift EP-B1-0 562 066 sind selbstklebende Tapeten auf Basis eines hydrophilen Fasermaterials, vorzugsweise auf Zellulosebasis, bekannt, wobei den hydrophilen Fasern zusätzlich mindestens 3 und höchstens 60 Gew.-% hydrophobe Fasern, z.B. Glasfasern, beigemischt sein können. Das Substrat dieser bekannten Gewebebahn kann zu 100 % aus hydrophilen Fasern oder einem Gemisch aus hydrophilen und hydrophoben Fasern bestehen, es kann aber auch zusätzlich ein polymeres Bindemittel wie z.B. Polyvinylacetat oder einen Styrol-Butadien-Kautschuk-Latex neben weiteren üblichen Füll- und Zusatzstoffen enthalten. Damit soll eine Verbesserung der Dimensionsstabilität selbstklebender Tapeten erreicht werden, insbesondere in Räumen mit hoher Luftfeuchtigkeit, in denen herkömmliche Tapeten häufig Ablösungserscheinungen zeigen und zur Blasenbildung neigen.From the European patent EP-B1-0 562 066 are self-adhesive wallpapers based on a hydrophilic fiber material, preferably known on a cellulose basis, wherein the hydrophilic fibers additionally at least 3 and at most 60% by weight of hydrophobic fibers, e.g. Glass fibers, added could be. The substrate of this known fabric web can 100% hydrophilic fibers or a mixture of hydrophilic and hydrophobic fibers exist, but it can also a polymeric binder, e.g. polyvinyl acetate or a styrene-butadiene rubber latex in addition to other common fillers and additives. This is supposed to improve dimensional stability self-adhesive wallpapers can be achieved, especially in Rooms with high humidity, in which conventional Wallpaper often show signs of detachment and to Blistering tend to occur.

Textilglasgewebe sind unverrottbar, unbrennbar, hydrophob und nicht hygroskopisch, und sie ergeben eine besonders ästhetisch ansprechende Oberflächenstruktur der damit belegten Flächen. Aus diesem Grunde werden sie überall dort eingesetzt, wo erhöhte Brandschutzanforderungen und hygienische Anforderungen gestellt werden, also in öffentlichen Gebäuden aller Art, Krankenhäusern, Schulen, Kindergärten, Arztpraxen, Hotels, auf Schiffen und dgl..Textile glass fabrics are rot-proof, non-flammable, hydrophobic and not hygroscopic, and they make a special one aesthetically appealing surface structure of the occupied areas. Because of this, they will be everywhere there used where increased fire protection requirements and hygienic requirements are made, i.e. in public buildings of all kinds, hospitals, schools, Kindergartens, medical practices, hotels, on ships and the like.

Ein Nachteil der bisher bekannt gewordenen Glasfasertapeten war allerdings, daß sie nur farblos bzw. in milchig-weißem Farbton zur Verfügung standen und in der Fachwelt als unbedruckbar galten, weil herkömmliche Druckfarben auf Glasfaseroberflächen sehr schlecht haften. Daher besteht in der Fachwelt seit vielen Jahren großes Interesse an der Entwicklung von Textilglasgewebebahnen, die mit ein- oder mehrfarbigen Mustern, ähnlich wie Papiertapeten, bedruckbar bzw. bedruckt sind. Trotz intensiver und langjähriger Bemühungen konnte diesem Bedürfnis bisher nicht Rechnung getragen werden.A disadvantage of the previously known glass fiber wallpapers was, however, that they were only colorless or in milky white Hue were available and considered in the professional world were considered unprintable because of conventional printing inks Glass fiber surfaces adhere very poorly. Therefore in the professional world has been very interested in the Development of textile glass fabric webs with one or Multi-colored patterns, similar to paper wallpapers, can be printed or printed. Despite intense and longstanding Efforts have so far failed to meet this need be worn.

Der Erfindung liegt die Aufgabe zugrunde, eine selbsthaftende Textilglasgewebebahn bereitzustellen, die bedruckbar ist, und zwar so, daß der Aufdruck dauerhaft und abriebfest auf dem Glasfasermaterial haften bleibt. Insbesondere soll eine Textilglasgewebebahn in Form einer mit einem farbigen Muster oder Motiv bedruckten Tapete oder in Form eines selbsthaftenden, dekorativ bedruckten Bandes bereitgestellt werden.The invention has for its object a self-adhesive Provide textile glass fabric sheet that is printable is so that the print is durable and abrasion resistant sticks to the glass fiber material. In particular, should a textile glass fabric sheet in the form of one with a colored Pattern or motif printed wallpaper or in the form of a self-adhesive, decorative printed tape provided become.

Diese Aufgabe wird erfindungsgemäß durch eine Textilglasgewebebahn gelöst, deren Faseranteil zu 100 % aus Textilglasfasern besteht und deren Rückseite eine selbsthaftende Kleberschicht aufweist, bei der mindestens diejenigen Abschnitte der Kett- und Schußfäden, die die Vorderseite der Gewebebahn bilden, mit einer Dünnschicht aus einem polymeren Haftvermittler beschichtet sind und die Dünnschicht einen ein- oder mehrfarbigen dekorativen Aufdruck trägt.This object is achieved by a textile glass fabric web solved, their fiber content 100% from textile glass fibers and the back is self-adhesive Has adhesive layer in which at least those sections of the warp and weft threads that make up the front of the Form fabric web with a thin layer of a polymer Adhesion promoters are coated and the thin layer one single or multi-colored decorative print.

Durch das Aufbringen einer dünnen Schicht aus einem polymeren Haftvermittler und das Bedrucken der so aufgebrachten dünnen Polymerschicht wurde das Vorurteil überwunden, daß Textilglasgewebe, insbesondere Glasfasertapeten, nur schlecht oder überhaupt nicht bedruckt werden könnten. Es hat sich überraschenderweise gezeigt, daß die auf der Rückseite der Textilglasgewebebahn aufgebrachte selbsthaftende Kleberschicht, die die Konturenschärfe eines später aufgebrachten Aufdrucks infolge der Migration flüchtiger Bestandteile wie z.B. von Weichmachern und Lösungsmitteln nachteilig beeinflussen kann, gemeinsam mit dem vorderseitig aufgebrachten polymeren Haftvermittler zu einem unerwarteten synergistischen Effekt führt, nämlich dazu, daß der polymere Haftvermittler zusätzliche Verankerungspunkte auf bzw. in der selbsthaftenden Kleberschicht findet und der so geschaffene Schichtenverbund gleichzeitig die Migration flüchtiger Bestandteile aus der Kleberschicht in den Aufdruck verhindert.By applying a thin layer of a polymer Adhesion promoter and printing on the so applied thin layer of polymer overcomes the prejudice that Textile glass fabrics, especially glass fiber wallpapers, only could be printed poorly or not at all. It has surprisingly been shown that the on the Back of the textile glass fabric sheet applied self-adhesive Adhesive layer, the sharpness of the contours later applied imprint due to migration more volatile Components such as of plasticizers and solvents can adversely affect, together with the front applied polymeric bonding agent to an unexpected synergistic effect leads to the fact that the polymer Adhesion promoter additional anchor points on or in the self-adhesive layer and the so created Stratified network at the same time makes migration more volatile Prevents components from the adhesive layer in the print.

Die aus dem polymeren Haftvermittler bestehende Dünnschicht kann vollständig ein- oder mehrfarbig bedruckt sein. Vorzugsweise ist die Dünnschicht aber nur bereichsweise unter Bildung eines dekorativen Musters bedruckt, weil sich so, unter Einschluß unbedruckter Bereiche mit dem Aussehen natürlicher Textilglasgewebe, ästhetisch besonders ansprechende Muster erzielen lassen, die sich zusätzlich in vielfältigster Weise durch transparente oder transluzente, ggf. farbige Deckanstriche variieren lassen.The thin layer consisting of the polymeric adhesion promoter can be printed completely in one or more colors. Preferably but the thin layer is only partially under Formation of a decorative pattern printed because including unprinted areas with the appearance natural textile glass fabric, aesthetically particularly appealing Patterns that can also be achieved in in many different ways through transparent or translucent, if necessary, have colored top coats vary.

Bei einer anderen Ausführungsform kann auch die aus dem polymeren Haftvermittler bestehende Dünnschicht selbst transparent oder transluzent und/oder eingefärbt sein.In another embodiment, the from the polymeric adhesion promoter existing thin layer itself be transparent or translucent and / or colored.

Vorzugsweise besteht der polymere Haftvermittler aus Polyurethan oder enthält Polyurethan. Der Haftvermittler wird vorzugsweise in Form einer wäßrigen Polyurethandispersion - vor oder nach dem Aufbringen der selbsthaftenden Kleberschicht auf die Rückseite der Textilglasgewebebahn - mindestens auf diejenigen Abschnitte der Kett- und Schußfäden, die die Vorderseite der Gewebebahn bilden, aufgesprüht oder aufgewalzt.The polymeric adhesion promoter preferably consists of polyurethane or contains polyurethane. The adhesion promoter will preferably in the form of an aqueous polyurethane dispersion - Before or after applying the self-adhesive layer on the back of the textile glass fabric sheet - at least on those sections of the warp and weft threads, which form the front of the fabric web, sprayed on or rolled on.

Zusätzlich kann die aus einem polymeren Haftvermittler bestehende Dünnschicht heißbügelecht und/oder naßreibecht ausgerüstet sein. Eine Heißbügelecht-Ausrüstung empfiehlt sich vor allem dann, wenn für die selbsthaftende Kleberschicht ein wärmeaktivierbarer Kleber verwendet wird, um z.B. Bänder, Borten oder Bordüren aus bedrucktem Textilglasgewebe zu Dekorationszwecken auf Wände, Türen, Schaufenster oder sonstigen geeignete Oberflächen aufzubringen. Eine Naßreibecht-Ausrüstung empfiehlt sich überall dort, wo gleichzeitig hohe Luftfeuchtigkeit und starke Frequentierung der entsprechend ausgestatteten Räumlichkeiten aufeinandertreffen, wie bei der Verwendung von Glasfasertapeten in Bädern, Dusch- und Umkleideräumen, Turnhallen, Vereinsheimen, Krankenhäusern usw. Eine solche zusätzliche Ausrüstung erfolgt unter Verwendung handelsüblicher Produkte, z.B. wäßriger Emulsionen von Piperidin-Derivaten. In addition, it can be made from a polymeric adhesion promoter existing thin layer hot ironing and / or wet rubbing resistance be equipped. Hot ironing equipment is recommended especially when for the self-adhesive layer a heat activated glue is used to e.g. Ribbons, borders or borders made of printed textile glass fabric for decoration on walls, doors, shop windows or other suitable surfaces. Wet rubbing equipment is recommended wherever At the same time, high air humidity and heavy traffic the appropriately equipped rooms meet, like when using fiberglass wallpaper in Baths, shower and changing rooms, gyms, club houses, Hospitals, etc. Such additional equipment is carried out using commercially available products, e.g. aqueous emulsions of piperidine derivatives.

Der dekorative Aufdruck der erfindungsgemäßen Textilglasgewebebahn kann ein Pigmentdruck, Transferdruck, Tintenstrahldruck, Plotterdruck und/oder Rotationsdruck sein. Pigmentdrucke sind Drucke, die unter Verwendung von Pigmenten hergestellt sind, deren einzelne Teilchen mit polymeren Bindemitteln umhüllt sind, die unter der Einwirkung von Druck und Wärme auf dem Bedruckstoff haften bleiben.The decorative imprint of the textile glass fabric web according to the invention can be pigment printing, transfer printing, inkjet printing, Plotter printing and / or rotary printing. Pigment prints are prints that are made using Pigments are made, the individual particles with polymeric binders are encased under the action of pressure and heat stick to the substrate stay.

Die Anwendung des Rotationsdrucks erfordert eine gewisse Schiebefestigkeit der Textilglasgewebebahn, die erfindungsgemäß gewährleistet ist durch die selbsthaftende Kleberschicht auf der Rückseite und die Dünnschicht aus polymerem Haftvermittler auf der Vorderseite der Gewebebahn. Es stellt einen unschätzbaren Vorteil dar, daß die erfindungsgemäße Textilglasgewebebahn im Rotationsdruck endlos bedruckbar ist.The use of rotary printing requires a certain amount Slip resistance of the textile glass fabric web, the invention is guaranteed by the self-adhesive layer of adhesive on the back and the thin layer of polymer Adhesion promoter on the front of the fabric web. It puts an invaluable advantage that the invention Textile glass fabric web can be printed endlessly in rotary printing is.

Schließlich kann die Dünnschicht und/oder der dekorative Aufdruck zusätzlich einen UV-Stabilisator, beispielsweise ein handelsübliches Benzotriazol-Derivat, und/oder einen Wärmestabilisator, beispielsweise ein Piperidin-Derivat, enthalten.Finally, the thin layer and / or the decorative Print additionally an UV stabilizer, for example a commercially available benzotriazole derivative, and / or one Heat stabilizer, for example a piperidine derivative, contain.

Die rückseitig aufgebrachte selbsthaftende Kleberschicht kann eine durchgehende, geschlossene Schicht sein; bevorzugt handelt es sich jedoch um eine unterbrochene Schicht, bei der die zwischen den Kreuzungspunkten der Kett- und Schußfäden befindlichen Zwischenräume mindestens teilweise offenbleiben.The self-adhesive layer applied on the back can be a continuous, closed layer; prefers however, it is an interrupted layer, at the one between the crossing points of the warp and weft threads gaps located at least partially remain open.

Die erfindungsgemäße Textilglasgewebebahn besitzt vorzugsweise die Form einer selbsthaftenden, rückstandsfrei wiederablösbaren Tapete, die Form einer selbsthaftenden, rückstandsfrei wiederablösbaren Borte oder Bordüre oder die Form eines selbsthaftenden, rückstandsfrei wiederablösbaren Bandes. Unter "selbsthaftend" wird - im Gegensatz zu "selbstklebend" - eine Klebereigenschaft verstanden, die durch eine relativ geringe Adhäsion bei gleichzeitig hoher Kohäsion gekennzeichnet ist.The textile glass fabric web according to the invention preferably has the form of a self-adhesive, residue-free removable wallpaper, the form of a self-adhesive, residue-free removable border or border or Form of a self-adhesive, removable without residue Band. "Self-adhesive" is - in contrast to "self-adhesive" - understood an adhesive property that due to a relatively low adhesion with a high one at the same time Is characterized by cohesion.

Vorzugsweise besitzt der dekorative Aufdruck die Form eines in mindestens einer Richtung (längs oder quer) endlosen Musters oder Motivs oder die Form eines sich in mindestens einer Richtung ständig wiederholenden Musters oder Motivs (Rapport). Der dekorative Aufdruck kann die Form eines sich ständig wiederholenden Namens, einer Firma, eines Logos, Firmen- oder Vereinsabzeichens, Wappens, Hoheitszeichens, Prüf- oder Gewährzeichens aufweisen. Diese Ausführungsformen sind besonders für den gewerblichen Bereich von Vorteil, wenn dem Wunsch vieler Unternehmen nach "corporate identity" auch bei der Innenausstattung von Produktions- und Büroräumen Rechnung getragen werden soll. Aber auch den Bedürfnissen von Sport- und anderen Vereinen, ihr jeweiliges Logo in den Räumen des Vereins, aber auch in denjenigen der Anhänger des Vereins, dauerhaft in Form einer Tapete oder eines tapetenförmigen Bandes anzubringen, wird durch die Erfindung in idealer Weise entsprochen.The decorative print preferably has the shape of a endless in at least one direction (lengthways or crossways) Pattern or motif or the shape of one in at least a direction of a constantly repeating pattern or motif (Rapport). The decorative imprint can take the form of itself repeating name, company, logo, Company or club badge, coat of arms, national emblem, Show test or guarantee mark. These embodiments are particularly advantageous for the commercial sector, if the desire of many companies for "corporate identity" also in the interior of production and office spaces Should be taken into account. But also the needs of sports and other clubs, their respective logo in the premises of the association, but also those of the supporters of the association, permanently in the form of a wallpaper or a Attaching wallpaper-shaped tape is made by the invention met in an ideal way.

Zur Ausprüfung der erfindungsgemäßen Textilglasgewebebahn wurden Bürstwäscheprüfungen wie für bedruckte Textilien durchgeführt, die Reibechtheit wurde trocken und naß getestet, die Lichtechtheit wurde geprüft, ein Bügeltest, Warm- und Heißlagertests durchgeführt und die Entflammbarkeit geprüft.To test the textile glass fabric web according to the invention were brush wash tests as for printed textiles carried out, the fastness to rubbing became dry and wet tested, the light fastness was tested, an ironing test, Warm and hot storage tests carried out and flammability checked.

Alle Tests wurden problemlos bestanden. Im Bügeltest wurden bei Bügeleisentemperaturen von 104°, 121° und 182°C, jeweils für die Dauer von 10 Sekunden, keinerlei Abfärbungen oder Abfleckungen festgestellt. Im Warmlagertest (bei 40°C über Nacht gelagert und mit 5 kg Gewicht belastet) und beim Heißlagertest (bei 90°C mehrere Tage gelagert und mit 5 kg Gewicht belastet) wurden keine Abfleckungen festgestellt und keine negativen Auswirkungen auf die Reibechtheit.All tests passed without any problems. In the ironing test at iron temperatures of 104 °, 121 ° and 182 ° C, respectively for the duration of 10 seconds, no discoloration or Stains found. In a warm storage test (at 40 ° C above Stored at night and loaded with 5 kg weight) and in the hot storage test (stored at 90 ° C for several days and with 5 kg Weight), no stains were found and no negative effects on rub fastness.

Claims (11)

  1. A textile glass fabric web, the fiber content of which consists at 100 % of textile glass fibers and the rear side of which has a self-adhesive glue layer, characterized in that it comprises open interspaces between the crossing points of the warp- and weft threads and that at least those sections of the warp- and weft threads which define the front side of the fabric web are coated with a thin layer of a polymeric adhesion promoter consisting of polyurethane or containing polyurethane, and that the thin layer is provided with a single-colored or multi-colored, decorative surprint.
  2. The textile glass fabric web according to claim 1, characterized in that only portions of the thin layer consisting of a polymeric adhesion promoter are provided with a surprint to form a decorative pattern.
  3. The textile glass fabric web according to claim 1 or 2, characterized in that the thin layer consisting of a polymeric adhesion promoter is transparent or translucent and/or pigmented.
  4. The textile glass fabric web according to any one of claims 1 to 3, characterized in that the thin layer consisting of a polymeric adhesion promoter has undergone a finishing so as to have fastness to hot ironing and wet rubbing.
  5. The textile glass fabric web according to any one of claims 1 to 4, characterized in that the decorative surprint is a pigment print, transfer print, inkjet print, plotter print and/or rotary machine print.
  6. The textile glass fabric web according to any one of claims 1 to 5, characterized in that the thin layer and/or the decorative surprint additionally comprises a UV stabilizer and/or a heat stabilizer.
  7. The textile glass fabric web according to any one of claims 1 to 6, characterized in that it has a transparent or translucent and/or colored finishing coat provided over the decorative surprint.
  8. The textile glass fabric web according to any one of claims 1 to 7 in the form of a self-adhesive wall paper adapted to be peeled off free from residue.
  9. The textile glass fabric web according to any one of claims 1 to 8 in the form of a self-adhesive braid or border adapted to be peeled off free from residue, or in the form of a self-adhesive band adapted to be peeled off free from residue.
  10. The textile glass fabric web according to claim 8 or 9, characterized in that the decorative surprint has the form of a pattern or picture which is endless in at least one direction, or the form of a pattern or picture continuously repeating in at least one direction (pattern repeat).
  11. The textile glass fabric web according to claim 10, characterized in that the decorative surprint has the form of a continuously repeating name, company, logo, firm's or club emblem, coat of arms, national emblem, quality or guarantee mark.
EP98118639A 1997-10-14 1998-10-02 Woven glass web Expired - Lifetime EP0909850B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE29718222U DE29718222U1 (en) 1997-10-14 1997-10-14 Textile glass fabric sheet
DE29718222U 1997-10-14

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EP0909850A2 EP0909850A2 (en) 1999-04-21
EP0909850A3 EP0909850A3 (en) 2000-12-13
EP0909850B1 true EP0909850B1 (en) 2004-01-07

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DE (2) DE29718222U1 (en)

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DE60130283T2 (en) * 2000-04-07 2008-05-29 Johns Manville Europe Gmbh Peelable fiberglass wall hanging
US6337104B1 (en) 2000-06-07 2002-01-08 Johns Manville Europe Gmbh Pre-glued glass fabric wallcovering
DE60143111D1 (en) 2001-05-04 2010-11-04 Johns Manville Europe Gmbh Glass fiber wall coverings with volumetric effect
DK1262591T3 (en) 2001-06-02 2012-02-13 Johns Manville Europe Gmbh Removable glued wall coverings
DE202005018324U1 (en) * 2005-11-22 2006-02-23 Vitrulan Textilglas Gmbh Wall or surface clothing
DE102007009619A1 (en) 2007-02-26 2008-08-28 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Antimicrobial textile glass fiber material, includes nanoparticulate silver in base coating, adhesive layer and antimicrobial coating
DE102009053062A1 (en) * 2009-11-16 2011-05-19 Erfurt & Sohn Kg Flat wall covering comprises a carrier layer and front-side pattern in the form of a coating from hydrophobic material, where the carrier layer is a fleece from cellulose fibers or the carrier layer has cellulose fibers
DE102009059172B4 (en) 2009-12-16 2017-04-06 Certoplast Vorwerk & Sohn Gmbh Method for producing a self-adhesive surface on a wall or floor covering and associated wall or floor covering
FR2991358B1 (en) 2012-06-04 2014-06-13 Saint Gobain Adfors AUTOADHESIVE AND WATER-ACTIVATED GLASS CANVAS
DE102015113674A1 (en) 2015-08-18 2017-02-23 Surtech Gmbh Wigbert H. Sauer Painting fleece and process for its production

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FR2528896A1 (en) * 1982-06-18 1983-12-23 Gerland Sa CONTINUOUS PROCESS FOR OBTAINING DECORATED PLASTIC COATINGS FOR FLOORS OR WALLS AND INSTALLATION PROVIDED FOR THE IMPLEMENTATION OF THIS PROCESS AND COATINGS OBTAINED
JPS59146956A (en) * 1983-02-07 1984-08-23 Dynic Corp Production of woven glass fiber fabric having pattern
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JPH05261860A (en) * 1992-03-18 1993-10-12 Hiroshi Tsutsumi Interior reinforced plastic

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ATE257526T1 (en) 2004-01-15
EP0909850A2 (en) 1999-04-21
DE59810538D1 (en) 2004-02-12
DE29718222U1 (en) 1999-02-18
EP0909850A3 (en) 2000-12-13

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