EP0871808A4 - Zusammensetzung zur behandlung von wäsche sowie verfahren hierfür - Google Patents
Zusammensetzung zur behandlung von wäsche sowie verfahren hierfürInfo
- Publication number
- EP0871808A4 EP0871808A4 EP96930883A EP96930883A EP0871808A4 EP 0871808 A4 EP0871808 A4 EP 0871808A4 EP 96930883 A EP96930883 A EP 96930883A EP 96930883 A EP96930883 A EP 96930883A EP 0871808 A4 EP0871808 A4 EP 0871808A4
- Authority
- EP
- European Patent Office
- Prior art keywords
- stain
- spot
- cleaning composition
- composition according
- textile fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 65
- 238000000034 method Methods 0.000 title claims abstract description 16
- 239000004744 fabric Substances 0.000 claims abstract description 25
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 24
- 238000004140 cleaning Methods 0.000 claims abstract description 24
- 239000004753 textile Substances 0.000 claims abstract description 22
- 239000002904 solvent Substances 0.000 claims abstract description 21
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 18
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 12
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 9
- 125000000129 anionic group Chemical group 0.000 claims abstract description 8
- 239000007764 o/w emulsion Substances 0.000 claims abstract description 4
- 239000007762 w/o emulsion Substances 0.000 claims abstract description 3
- 239000004094 surface-active agent Substances 0.000 claims description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 20
- 230000002745 absorbent Effects 0.000 claims description 18
- 239000002250 absorbent Substances 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000003599 detergent Substances 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 235000007586 terpenes Nutrition 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229920000151 polyglycol Polymers 0.000 claims description 3
- 239000010695 polyglycol Substances 0.000 claims description 3
- 150000003138 primary alcohols Chemical class 0.000 claims description 3
- 150000003505 terpenes Chemical class 0.000 claims description 3
- JCAYXDKNUSEQRT-UHFFFAOYSA-N 2-aminoethoxyboronic acid Chemical compound NCCOB(O)O JCAYXDKNUSEQRT-UHFFFAOYSA-N 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- 239000000908 ammonium hydroxide Substances 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- 229910021538 borax Inorganic materials 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- 238000007046 ethoxylation reaction Methods 0.000 claims description 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- 238000007711 solidification Methods 0.000 claims description 2
- 230000008023 solidification Effects 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims 1
- -1 peroxide compound Chemical class 0.000 description 24
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 11
- 229910021653 sulphate ion Inorganic materials 0.000 description 6
- 150000008051 alkyl sulfates Chemical class 0.000 description 5
- 238000004061 bleaching Methods 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 3
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 235000015067 sauces Nutrition 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- IIYFAKIEWZDVMP-UHFFFAOYSA-N tridecane Chemical compound CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 description 3
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 238000010409 ironing Methods 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- ODCMOZLVFHHLMY-UHFFFAOYSA-N 1-(2-hydroxyethoxy)hexan-2-ol Chemical compound CCCCC(O)COCCO ODCMOZLVFHHLMY-UHFFFAOYSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 description 1
- QJEINWXAHGQZHL-UHFFFAOYSA-N 2-aminoethanol;2-[bis(2-hydroxyethyl)amino]ethanol Chemical compound NCCO.OCCN(CCO)CCO QJEINWXAHGQZHL-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910003202 NH4 Inorganic materials 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- ZUBJEHHGZYTRPH-KTKRTIGZSA-N [(z)-octadec-9-enyl] hydrogen sulfate Chemical compound CCCCCCCC\C=C/CCCCCCCCOS(O)(=O)=O ZUBJEHHGZYTRPH-KTKRTIGZSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 210000000077 angora Anatomy 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 235000019219 chocolate Nutrition 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- PSLIMVZEAPALCD-UHFFFAOYSA-N ethanol;ethoxyethane Chemical compound CCO.CCOCC PSLIMVZEAPALCD-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- UZABCLFSICXBCM-UHFFFAOYSA-N ethoxy hydrogen sulfate Chemical class CCOOS(O)(=O)=O UZABCLFSICXBCM-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- ZOCHHNOQQHDWHG-UHFFFAOYSA-N hexan-3-ol Chemical compound CCCC(O)CC ZOCHHNOQQHDWHG-UHFFFAOYSA-N 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- CQDGTJPVBWZJAZ-UHFFFAOYSA-N monoethyl carbonate Chemical class CCOC(O)=O CQDGTJPVBWZJAZ-UHFFFAOYSA-N 0.000 description 1
- 229940094933 n-dodecane Drugs 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 238000001935 peptisation Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- IIYFAKIEWZDVMP-NJFSPNSNSA-N tridecane Chemical group CCCCCCCCCCCC[14CH3] IIYFAKIEWZDVMP-NJFSPNSNSA-N 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L25/00—Domestic cleaning devices not provided for in other groups of this subclass
- A47L25/08—Pads or the like for cleaning clothes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0017—Multi-phase liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F43/00—Dry-cleaning apparatus or methods using volatile solvents
- D06F43/002—Spotting apparatus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/40—Specific cleaning or washing processes
- C11D2111/44—Multi-step processes
Definitions
- the present invention relates to compositions for treating stains on laundry items.
- Laundry items can be treated either before or after a conventional laundering process by application of the composition in the region of the stain so that the stain is at least partially released and removal of the stain is made easier.
- Emulsions of solvent-aqueous systems are known to be effective as spot pretreating compositions on both hydrophobic and hydrophilic stains .
- GB-A-2 194 547 published on 9th March 1988, discloses mixtures of n-dodecane with both short-chain (Neodol 91-6) and long chain (Neodol 45-1) nonionics.
- the compositions are in the form of liquid solutions; water-in-oil or oil- in-water microemulsions, or gels.
- US-A-4 093 418 issued on 6th June 1978, and US-A-4 178 262, issued on 11th December 1979, disclose isoparaffin (C 11 -C ⁇ _4) in combination with long-chain .C ⁇ _o-C ⁇ _g) nonionics.
- the present invention relates to a cleaning composition which is an oil-in-water or water-in-oil emulsion or a solution comprising non-aqueous hydrophobic solvent; first anionic or nonionic surfactant having an alkyl chain, the length of the alkyl chain being C ⁇ _ ⁇ _ or less; and second anionic or nonionic surfactant having an alkyl chain, the length of the alkyl chain being C]_2 or more -
- Another object of the present invention is to improve the removal of bleachable stains through the application of the composition of the present invention and the application of a bleaching compound, preferably a peroxide compound.
- the objective of the present invention is achieved by providing a cleaning composition which has a pH greater than 8, thereby enhancing cleaning performance for both fatty stains and bleachable stains.
- a cleaning composition which has a pH greater than 8, thereby enhancing cleaning performance for both fatty stains and bleachable stains.
- the pH is greater than 9, and more preferably greater than 10.
- the cleaning composition preferably comprises water from 5% to 95% by weight of the composition.
- the invention also relates to a method for treating a spot or stain on a textile fabric using the cleaning compositions of the invention.
- Hydrophobic solvents are an essential feature of the compostions of the present invention.
- Preferred hydrophobic solvents are defined in terms of Hansen parameters.
- a hydrophobic solvent as defined herein is considered to be a solvent having Hansen hydrogen bonding cohesion parameter dH below 18 (Joule/cm 3 ) 0 - 5 .
- Preferred hydrophobic solvents have a Hansen hydrogen bonding cohesion parameter dH below 12 (Joule/cm 3 ) ⁇ • 5 and a Hansen polar parameter dP below 8 (Joule/cm 3 ) 0 • 5 .
- Preferred solvents for use comprise mixtures of hydrocarbons with a flash point no lower than 70°C, an initial boiling point no lower than 130°C, preferably no lower than 145°C, and a solidification point not above 20°C and aliphatic fatty acid esters. More preferred solvents would be alkanes or alkenes with a chain length above C7, and particularly alkanes and alkenes with an average of C8 to C20 atoms. Particularly preferred hydrophobic solvents are deodorised kerosine; solvent naphta; chlorinated hydrocarbons; and terpenes.
- paraffins Even more preferred are paraffins; isoparaffins; naphthenes; aromatics; olefins; 1, 1, 1-trichloroethane perchloroethylene; methylene chloride; Shellsol SS" mixture (C8-C11 isoparaffin + 5% aliphatic C7 ester) ; D-Limonene; and Glidsafe® supplied by Glidsol.
- Solvents are used in the detergent compositions of the present invention preferably at a level of from 3% to 90%, more preferably from 4% to 45%, and most preferably from 5% to 25% by weight of the detergent composition.
- solvents having a Hansen parameter of dH less than 18 (Joule/cm 3 ) 0 - 5 include glycol ethers, more preferably glycol ethers based upon ethylene oxide, propylene oxide, or mixtures thereof. Particularly preferred are ethylene glycol monoethyl ether; Propylene glycol monomethyl ether; 2-butoxy ethanol; butyl diethylene glycol ether ethanol; butoxytriglycol; butylene glycol; hexylene glycol; and propyl propanol. Such solvents are used in combination with mixtures of short chain surfactants and long chain surfactants .
- short-chain what is meant herein is surfactants which comprise a Cg-C ⁇ _ ] _ alkyl chain as their hydrophobic portion.
- Such short-chain surfactants are accordingly those conventionally used in this field, but with a shorter alkyl chain, and can be of any type.
- suitable short chain surfactants for use herein include Cg-C ⁇ _ ⁇ _ alkyl sulfates (Cg-CnS ⁇ 4) , alkyl ether sulfates (C -C ] _ ⁇ (OCH 2 CH 2 ) eS0 4 ) , alkyl sulfonates (Cg-C 11 S0 3 ) / alkyl succinates (Cg-C 11 OOCCH 2 CH 2 COOZ) , alkyl carboxylates (Cg- C 1;L COOM) , alkyl ether carboxylates (Cg-C 1:L (OCH 2 CH 2 )eCOOM) , alkyl sarcosinates (Cg-C ⁇ :L CON(CH 3 )R) , alkyl sulfo succinates (Cg-C 1:L OOCCH(SO3M) CH COOZ) , amine oxides (Cg- CuRR'NO) , glucose
- e and p are independently from 0 to 20 and e+p>0
- Z is M or R
- M is H or any counterion such as those known in the art, including Na, K,Li, NH4, amine
- X is a polyhydroxyhydrocarbyl having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain, or an alkoxylated derivative thereof
- R, R' and R 1 ' are C ⁇ C5 alkyl groups, possibly functionalized with hydroxyl groups
- R and R' are preferably C ⁇ _-C 3 , most preferably methyl
- R' ' is preferably 2-hydroxyethyl or 2 hydroxypropyl
- G is saccharide, preferably glucose, and g is of from 1.5 to 8.
- compositions according to the present invention may comprise any of the above surfactants alone, or any combination thereof.
- Preferred short chain nonionic surfactants for use herein are alkyl alkoxylates according to the formula Cg- C 11 (OCH 2 CH 2 ) e (OCH CH CH 2 )pOH, where e and p representing respectively the degree of ethoxylation and propoxylation, are independently of from 0 to 20, and that e+p>0.
- Most preferred short chain nonionic surfactants for use herein are those where e and p are such that e+p is from 3 to 10, particularly those where p is 0 and e is 3 to 8.
- most preferred short chain nonionic surfactants for use herein are those where said short chain is a hydrocarbon chain comprising from 7 to 11 carbon atoms.
- Said preferred short chain nonionic surfactants for use herein can be manufactured by the processes well known to the man skilled in the art, such as condensation of the corresponding alcohol and alkylene oxide, but such short chain surfactants are more conveniently commercially available for instance from Sidobre under the trade name Mergital ® C 4 (C8E04) , from Kolb under the trade names Imbentin® AG/810/050 and AG/810/080 (respectively C8-10EO5 and C8- 10EO8) ; from Shell under the trade name Dobanol 91-2.5 (Cg- C n E02.5) , Dobanol 91-6 (C 9 -C 1:L E06) , Dobanol 91-4-6; from Vista Chemicals Vista 1012-52, from EXXON Asopol 91-4.6.
- Another preferred class of short chain nonionic surfactants are secondary alcohol ethoxylates according to the formula
- Preferred short chain anionic surfactants for use herein are C -C ] _ ⁇ alkyl sulfates and Cg-Cn alkyl sulfonates, Cg- C ] _ T _ betaines, Cg-C ⁇ _ ⁇ a ⁇ tine oxides and mixtures thereof. Most preferred are the Cg-Cg alkyl sulfates and sulfonates.
- Such short chain anionic surfactants can be made by well known sulphation or sulphonation processes followed by neutralization, but said anionic short chain surfactants are more conveniently commercially available, for instance from Rhone Poulenc under the trade name Rhodapon ® OLS, or from Witco under the trade name Witconate®.
- any alkaline materials is suitable for use in the present invention.
- Preferred alkaline materials are selected from the group consisting of potassium hydroxide, sodium hydroxide, ammonium hydroxide, ammonium silicate, sodium bicarbonate, borax, monoethanolamine borate, monoethanolamine triethanolamine, and mixtures thereof.
- the spot treating composition comprises from 0.1% to 10%, preferably 0.5% to 3% by weight of the alkaline material.
- the pH is greater than 8, more preferably greater than 9, and most preferably greater than 10. pH of the neat compositions was measured by means of a portable pH meter from Knick (Portamess 752) .
- long-chain what is meant herein is surfactants having an alkyl chain, the alkyl chain comprising 12, or more than 12 carbon atoms.
- Non-limiting examples of long-chain surfactants useful herein include the conventional C ⁇ -C ⁇ alkyl benzene sulfonates ("LAS") and primary, branched-chain and random c 12" c 20 alkyl sulfates (“AS”) , the C 12 -C 18 secondary (2,3) alkyl sulfates of the fomula CH 3 (CH 2 ) x (CH0S0 3 " M + ) CH 3 and CH 3 (CH 2 ) y (CH0S0 3 " M + )CH 2 CH 3 where x and (y+1) are integers of at least about 7, preferably at least about 9, and M is a water-solubilizing cation, especially sodium, unsaturated sulfates such as oleyl sulfate, the C_ -C 1 g alkyl alkoxy sulfates ("AE X S"; especially EO 1-7 ethoxy sulfates) , C 12 - C ⁇ _8 alkyl
- the conventional nonionic and amphoteric surfactants such as the C ⁇ _ 2 -C ⁇ _g alkyl ethoxylates ("AE") particulary preferred are C]_ 2 -C ⁇ g fatty alcohol polyglycol ethers or ethoxylated primary alcohols with EO 2-7 (especially ethoxylates and mixed ethoxy/propoxy) , C ⁇ 2 -C ] _g betaines and sulfobetaines ( "sultaines”) , C ] _ 2 -C; ⁇ _g amine oxides, and the like, can also be included in the overall compositions.
- the C]_ -C; ⁇ g N-alkyl polyhydroxy fatty acid amides can also be used.
- Typical examples include the C ] _ - C ] _ N-methylglucamides. See WO 9,206,154.
- Other sugar- derived surfactants include the N-alkoxy polyhhydroxy fatty acid amides, such as C ⁇ 2 -C ⁇ g N- (3-methoxypropyl) glucamide. The N-propyl through N-hexyl C]_ 2 -C ] _g glucamides can be used for low sudsing.
- C ⁇ -C o conventional soaps may also be used. If high sudsing is desired, the branched-chain C ] _ 2 - C ⁇ soaps may be used.
- Mixtures of anionic and nonionic surfactants are espicially useful. Other conventional useful surfactants are listed in standard texts.
- a particularly preferred composition according to the present invention comprises from 5% to 50% by weight of a mixed nonionic system comprising first, short-chain nonionic surfactant and second, long-chain nonionic surfactant. More preferably the composition comprises from 10% to 40% by weight of the mixed nonionic surfactant, and most preferably from 15% to 30%.
- the nonionic system preferably has an overall HLB value of from 2 to 16, more preferably from 8 to 14, most preferably from 9 to 10. Furthermore it is preferred that the ratio of first surfactant to second surfactant is from 1:10 to 10:1, more preferably from 1:3 to 3:1, and most preferably about 1:1.
- Bleaching agents may also be useful in the method of the present invention for treating bleachable stains.
- the bleaching agents may be incorporated into the compositions described above, or may be added as separate bleaching compositions. Peroxide bleaching agents are most preferred.
- the detergent composition of the present invention is useful in various known and conventional cleaning methods.
- a preferred cleaning method comprises the steps of applying the detergent composition to the spot or stain; placing an absorbent layer adjacent to the textile fabric in the region of the spot or stain; and applying heat, pressure, or heat and pressure to the textile fabric in the region of the spot or stain; so that some or all of the spot or stain is absorbed into the absorbent layer.
- a still more preferred cleaning method comprises the steps of :
- the application of heat or pressure, or both, may be achieved by any means, but is most preferably achieved by a hand-held device such as an iron.
- a conventional iron having a hot-plate fixed to a body is a highly preferred hand held device.
- the hot-plate is heated most commonly by electrical means, and may have a means for controlling the temperature.
- a supply of water or steam may also be provided by the iron.
- the absorbent layer is placed on a flat surface, such as an ironing board, and the stained or soiled textile fabric is laid flat on top of, and in contact with, the absorbent layer.
- the iron can then be easily applied to the textile fabric in the region of the stain or spot in order to ensure complete, or substantially complete, transfer of the stain or spot into the absorbent layer.
- the iron is preferably operated at a temperature of from 40°C to 200°C, more preferably from 40°C to 180°C.
- An alternative device for applying heat or pressure is a heated roller or any other heated applicator.
- the roller or applicator may also be provided with a supply of the detergent composition.
- Suitable applicators include a steam iron with suction brush attachment, such as that disclosed in EP-A-0 493 348, and a thermoelectric applicator, such as that disclosed in EP-A-0 552 397. Also suitable is a steam iron with atomiser, such as that disclose in EP-A-0 629 736 wherein the detergent composition may optionally be stored in the iron and delivered directly onto the textile fabrics by means of the atomiser.
- hydrophobic stains are first rendered hydrophilic by applying a detergent composition, optionally with a gentle rubbing action.
- Greasy stains which contain hydroxyl groups are deprotoneated at high pH and are thus rendered more easy to solubilize in the detergent solution. Higher pH can also induce soil peptization on some food stains. The stains are in effect broken down, and rendered easier to remove.
- the benefits of high pH can be particularly observed when before or after application of the detergent composition, another composition containing a bleaching species is applied on the stain. Indeed, conventional peroxide bleaching technologies have an increased reactivity with pH. Water is then applied to the stain, again, optionally with a gentle rubbing action. The stain is removed by laying the stained fabric adjacent to an absorbent layer. The stain, which has been rendered more hydrophilic by the treatment, is transferred to the absorbent layer.
- Textile fabrics are any materials made from cloth, including garments such as shirts, blouses, socks, skirts, trousers, jackets, underwear etc, and also including tablecloths, towels, curtains etc.
- the definition of textile fabrics as used herein does not include carpets and similar floor coverings.
- Textile fabrics which are to be used in the present invention are commonly made by weaving or knitting. Many different fibres may be used to produce woven, knitted or other types of textile fabric including synthetic fibres (such as polyester, polyamide, etc.) and natural fibres from plants (such as cotton, hemp) and from animals (such as wool, angora, silk) . Blends of different fibres are also commonly used.
- Example 1 Example 2 Example 3 Example 4
- Shellsol ® is a mixture of C -Cn isoparaffins with 5% aliphatic C7 ester.
- Dehydol is a fatty alcohol polyglycol ether octyl with an average of 4E0, supplied by Henkel.
- Dobanol is a ethoxylated primary alcohol with an average of 3E0, supplied by Shell.
- Alkyl sulphate, C8AS has an average of 8 carbon atoms in the alkyl chain.
- emulsions were prepared by mixing the components in the following order : Dobanol 25E3 was first mixed with the Shellsol solvent. The short-chain surfactant (alkyl sulphate or Dehydol) was then added followed by an aqueous solution of sodium hydroxide. Mixing was continued until a stable oil-in-water emulsion was formed.
- the short-chain surfactant alkyl sulphate or Dehydol
- Isopar K® which is a C]_Q _C 12 isoparaffinic hydrocarbon from Exxon
- Glidsol 66-2 which is a mixture of terpene hydrocarbon from
- Glidsol 100 which is a mixture of terpene hydrocarbon from
- Invert 2000 which is a citrus terpene/water emulsion from
- a set of polycotton swatches (50mm square) were soiled with make-up, chocolate sauce and tomato sauce. The stain was left to age for a day, in the dark, at normal room temperature (ca. 20°C, 60%RH) . Each soiled swatch was cleaned by the following method:
- the stained area was placed directly upon a strip of absorbent paper (the paper used was the absorbent core of a diaper) .
- Example 2 1 ml of the composition of Example 1 was dripped on to the stained area.
- the stained area was brushed with a conventional electrical toothbrush for 10 seconds (the toothbrush used, a Braun" dental d3 , was one normally intended for daily oral care) .
- Step 5. was repeated with a further 2ml of distilled water.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Treatment Of Fiber Materials (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96930883A EP0871808B1 (de) | 1995-11-27 | 1996-09-16 | Zusammensetzung zur behandlung von wäsche sowie verfahren hierfür |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP95118617 | 1995-11-27 | ||
EP95118617 | 1995-11-27 | ||
EP96930883A EP0871808B1 (de) | 1995-11-27 | 1996-09-16 | Zusammensetzung zur behandlung von wäsche sowie verfahren hierfür |
PCT/US1996/014766 WO1997020094A1 (en) | 1995-11-27 | 1996-09-16 | Composition for treating stains on laundry items and method of treatment |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0871808A1 EP0871808A1 (de) | 1998-10-21 |
EP0871808A4 true EP0871808A4 (de) | 1999-04-28 |
EP0871808B1 EP0871808B1 (de) | 2003-02-19 |
Family
ID=8219839
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96932226A Withdrawn EP0866893A4 (de) | 1995-11-27 | 1996-09-16 | Zusammensetzung zur behandlung von wäsche sowie verfahren hierfür |
EP96930883A Expired - Lifetime EP0871808B1 (de) | 1995-11-27 | 1996-09-16 | Zusammensetzung zur behandlung von wäsche sowie verfahren hierfür |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96932226A Withdrawn EP0866893A4 (de) | 1995-11-27 | 1996-09-16 | Zusammensetzung zur behandlung von wäsche sowie verfahren hierfür |
Country Status (14)
Country | Link |
---|---|
EP (2) | EP0866893A4 (de) |
JP (2) | JP3412111B2 (de) |
AR (3) | AR004772A1 (de) |
AT (2) | ATE232919T1 (de) |
AU (4) | AU7109896A (de) |
BR (3) | BR9612283A (de) |
CA (2) | CA2238620C (de) |
DE (1) | DE69626311T2 (de) |
EG (1) | EG20922A (de) |
ES (1) | ES2188785T3 (de) |
MX (3) | MX9804177A (de) |
NO (2) | NO982359D0 (de) |
WO (3) | WO1997020094A1 (de) |
ZA (2) | ZA969921B (de) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5891197A (en) * | 1996-08-02 | 1999-04-06 | The Proctor & Gamble Company | Stain receiver for dry cleaning process |
US6855172B2 (en) | 1998-10-13 | 2005-02-15 | Dry, Inc. | Dry-cleaning article, composition and methods |
JP4005092B2 (ja) * | 2004-08-20 | 2007-11-07 | 東京応化工業株式会社 | 洗浄除去用溶剤 |
US7757340B2 (en) | 2005-03-25 | 2010-07-20 | S.C. Johnson & Son, Inc. | Soft-surface remediation device and method of using same |
TWI400330B (zh) | 2005-12-28 | 2013-07-01 | Kao Corp | Liquid detergent |
PT2404988T (pt) | 2010-07-07 | 2018-03-15 | Dalli Werke Gmbh & Co Kg | Composição para o pré-tratamento local da roupa |
JP5544256B2 (ja) * | 2010-09-21 | 2014-07-09 | 花王株式会社 | 硬質表面の洗浄方法 |
GB201021822D0 (en) * | 2010-12-23 | 2011-02-02 | Reckitt & Colman Overseas | Cleaning composition and method |
JP2012131949A (ja) * | 2010-12-24 | 2012-07-12 | Idemitsu Kosan Co Ltd | イソパラフィン含有エマルジョン組成物 |
ES2622230T3 (es) | 2011-06-17 | 2017-07-06 | Dalli-Werke Gmbh & Co. Kg | Composición de detergente que comprende polímeros de liberación de suciedad con estabilidad en almacenamiento mejorada |
JP6673831B2 (ja) * | 2013-09-06 | 2020-03-25 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 水溶性壁材を含むパウチとその同一物を作製する方法 |
FR3047488B1 (fr) * | 2016-02-05 | 2020-02-28 | Laboratoires Anios | Compositions detergentes pour le nettoyage dans l'industrie cosmetique et pharmaceutique. |
RU2751765C2 (ru) * | 2018-12-21 | 2021-07-16 | Светлана Борисовна Узенькова | Способ чистки изделий из натуральной и искусственной кожи, натурального и искусственного меха и подкладочной ткани изделий |
JP7332286B2 (ja) * | 2018-12-26 | 2023-08-23 | 花王株式会社 | 繊維製品の処理方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3748268A (en) * | 1972-03-27 | 1973-07-24 | Minnesota Mining & Mfg | Spot and stain removing composition |
EP0026422A1 (de) * | 1979-10-01 | 1981-04-08 | Henkel Kommanditgesellschaft auf Aktien | Zur Textilbehandlung geeignetes Sprühreinigungsmittel |
EP0036833A1 (de) * | 1980-02-22 | 1981-09-30 | Airwick AG | Verfahren zur Reinigung von Textilmaterial |
EP0216355A2 (de) * | 1985-09-24 | 1987-04-01 | S.C. Johnson & Son, Inc. | Wässrige Zusammensetzung zur Fleckenbeseitigung von Wäsche |
GB2194547A (en) * | 1986-09-02 | 1988-03-09 | Colgate Palmolive Co | Laundry pre-spotter composition providing oily soil removal |
US5002684A (en) * | 1987-04-08 | 1991-03-26 | Harris Research, Inc. | Composition and method for removal of stains from fibers |
DE4303454A1 (de) * | 1993-02-05 | 1994-08-11 | Nouvelle Cosmetic Gmbh | Verfahren zum Entfernen von Flecken und Fleckentfernungsset |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US495428A (en) * | 1893-04-11 | Furnace-mouth feed-water heater | ||
CA965913A (en) * | 1971-02-03 | 1975-04-15 | Paul A. Boulus | Thick covering textile cleaning process and cleaning pad |
GB1518676A (en) * | 1975-10-30 | 1978-07-19 | Procter & Gamble Ltd | Detergent compositions |
US4199482A (en) * | 1977-03-31 | 1980-04-22 | Colgate-Palmolive Company | Laundry pre-spotter composition and method of using same |
DE2903061A1 (de) * | 1979-01-26 | 1980-08-07 | Heliotronic Gmbh | Verfahren zur herstellung grosskristalliner vorzugsorientierter siliciumfolien |
US4412934A (en) * | 1982-06-30 | 1983-11-01 | The Procter & Gamble Company | Bleaching compositions |
DE3465334D1 (en) * | 1983-04-14 | 1987-09-17 | Interox Chemicals Ltd | Peroxygen compounds |
US4634551A (en) * | 1985-06-03 | 1987-01-06 | Procter & Gamble Company | Bleaching compounds and compositions comprising fatty peroxyacids salts thereof and precursors therefor having amide moieties in the fatty chain |
US4915854A (en) * | 1986-11-14 | 1990-04-10 | The Procter & Gamble Company | Ion-pair complex conditioning agent and compositions containing same |
US5205960A (en) * | 1987-12-09 | 1993-04-27 | S. C. Johnson & Son, Inc. | Method of making clear, stable prespotter laundry detergent |
US4954286A (en) * | 1988-04-14 | 1990-09-04 | Lever Brothers Company | Fabric pretreatment cleaning compositions |
EP0634476B1 (de) * | 1993-07-12 | 1999-10-13 | The Procter & Gamble Company | Stabile, wässrige Emulsionen aus nichtionischen oberflächenaktiven Mitteln mit einem viskositätskontrollierendem Mittel |
EP0779357A1 (de) * | 1995-12-16 | 1997-06-18 | The Procter & Gamble Company | Stabile Emulsionen enthaltend einen hydrophobischen flüssigen Bestandteil |
-
1996
- 1996-09-16 WO PCT/US1996/014766 patent/WO1997020094A1/en active IP Right Grant
- 1996-09-16 JP JP52045797A patent/JP3412111B2/ja not_active Expired - Fee Related
- 1996-09-16 WO PCT/US1996/014821 patent/WO1997020098A1/en active Application Filing
- 1996-09-16 BR BR9612283A patent/BR9612283A/pt not_active Application Discontinuation
- 1996-09-16 EP EP96932226A patent/EP0866893A4/de not_active Withdrawn
- 1996-09-16 BR BR9611791A patent/BR9611791A/pt not_active Application Discontinuation
- 1996-09-16 JP JP09520456A patent/JP3085986B2/ja not_active Expired - Fee Related
- 1996-09-16 AU AU71098/96A patent/AU7109896A/en not_active Abandoned
- 1996-09-16 AT AT96930883T patent/ATE232919T1/de not_active IP Right Cessation
- 1996-09-16 AU AU69787/96A patent/AU6978796A/en not_active Abandoned
- 1996-09-16 ES ES96930883T patent/ES2188785T3/es not_active Expired - Lifetime
- 1996-09-16 DE DE69626311T patent/DE69626311T2/de not_active Expired - Fee Related
- 1996-09-16 WO PCT/US1996/014772 patent/WO1997020095A1/en not_active Application Discontinuation
- 1996-09-16 MX MX9804177A patent/MX9804177A/es unknown
- 1996-09-16 CA CA002238620A patent/CA2238620C/en not_active Expired - Fee Related
- 1996-09-16 EP EP96930883A patent/EP0871808B1/de not_active Expired - Lifetime
- 1996-09-16 CA CA002238482A patent/CA2238482C/en not_active Expired - Fee Related
- 1996-09-16 AU AU69783/96A patent/AU6978396A/en not_active Abandoned
- 1996-11-26 ZA ZA969921A patent/ZA969921B/xx unknown
- 1996-11-26 EG EG104796A patent/EG20922A/xx active
- 1996-11-26 ZA ZA9609925A patent/ZA969925B/xx unknown
- 1996-11-27 AR ARP960105353A patent/AR004772A1/es unknown
- 1996-11-27 AU AU12766/97A patent/AU1276697A/en not_active Abandoned
- 1996-11-27 AT AT96943549T patent/ATE241691T1/de not_active IP Right Cessation
- 1996-11-27 AR ARP960105352A patent/AR004771A1/es unknown
- 1996-11-27 BR BR9611771A patent/BR9611771A/pt not_active Application Discontinuation
- 1996-11-27 AR ARP960105354A patent/AR004773A1/es unknown
-
1998
- 1998-05-25 NO NO982359A patent/NO982359D0/no not_active Application Discontinuation
- 1998-05-25 NO NO982360A patent/NO982360L/no not_active Application Discontinuation
- 1998-05-26 MX MX9804179A patent/MX9804179A/es not_active Application Discontinuation
- 1998-05-26 MX MX9804178A patent/MX9804178A/es unknown
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3748268A (en) * | 1972-03-27 | 1973-07-24 | Minnesota Mining & Mfg | Spot and stain removing composition |
EP0026422A1 (de) * | 1979-10-01 | 1981-04-08 | Henkel Kommanditgesellschaft auf Aktien | Zur Textilbehandlung geeignetes Sprühreinigungsmittel |
EP0036833A1 (de) * | 1980-02-22 | 1981-09-30 | Airwick AG | Verfahren zur Reinigung von Textilmaterial |
EP0216355A2 (de) * | 1985-09-24 | 1987-04-01 | S.C. Johnson & Son, Inc. | Wässrige Zusammensetzung zur Fleckenbeseitigung von Wäsche |
GB2194547A (en) * | 1986-09-02 | 1988-03-09 | Colgate Palmolive Co | Laundry pre-spotter composition providing oily soil removal |
US5002684A (en) * | 1987-04-08 | 1991-03-26 | Harris Research, Inc. | Composition and method for removal of stains from fibers |
DE4303454A1 (de) * | 1993-02-05 | 1994-08-11 | Nouvelle Cosmetic Gmbh | Verfahren zum Entfernen von Flecken und Fleckentfernungsset |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6277808B1 (en) | Composition for treating stains on laundry items and method of treatment | |
US6020300A (en) | Composition for treating stains on laundry items and methods of treatment | |
EP0843603B1 (de) | Fleckenputzmittel | |
EP0871808B1 (de) | Zusammensetzung zur behandlung von wäsche sowie verfahren hierfür | |
US6048368A (en) | Cleaning method for textile fabrics | |
US4295845A (en) | Pretreatment composition for stain removal | |
US4363756A (en) | Pretreatment composition for stain removal | |
US5908473A (en) | Spot pretreatment compositions for home dry cleaning | |
EP0910619B1 (de) | Reinigungsverfahren für stoffe | |
JP2002506924A (ja) | 液体多相洗剤 | |
CA2247902A1 (en) | Liquid crystal detergent compositions | |
ES2234672T3 (es) | Composiciones limpiadoras fluidas que tienen elevados niveles de oxido de amina. | |
WO2001079415A1 (en) | Fabric treatment article and composition | |
EP0835340A1 (de) | Chemischreinigung mit enzymen | |
EP2404988B1 (de) | Zusammensetzung zur Fleckenvorbehandlung von Wäsche | |
WO2001007708A1 (en) | Dry-cleaning processes and components therefor | |
EP0833975A1 (de) | Chemischreinigungszusammensetzung mit anti-statischen eigenschaften | |
JPH11116999A (ja) | 補強された泡からなる汚れ受容体 | |
EP3224335A1 (de) | Verfahren zur behandlung von gewebe mit öligen flecken | |
MXPA97009069A (en) | Dry cleaning composition on a better vehicle |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 19980427 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LI LU NL PT SE |
|
A4 | Supplementary search report drawn up and despatched |
Effective date: 19990311 |
|
AK | Designated contracting states |
Kind code of ref document: A4 Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LI LU NL PT SE |
|
17Q | First examination report despatched |
Effective date: 20010725 |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LI LU NL PT SE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030219 Ref country code: LI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030219 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030219 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030219 Ref country code: CH Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030219 Ref country code: BE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030219 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030219 |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
REF | Corresponds to: |
Ref document number: 69626311 Country of ref document: DE Date of ref document: 20030327 Kind code of ref document: P |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030519 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030519 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030519 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2188785 Country of ref document: ES Kind code of ref document: T3 |
|
NLV1 | Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act | ||
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20030916 Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20030916 |
|
ET | Fr: translation filed | ||
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20031120 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20050916 Year of fee payment: 10 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20060804 Year of fee payment: 11 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20060906 Year of fee payment: 11 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20060929 Year of fee payment: 11 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20060930 Year of fee payment: 11 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20070916 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20080401 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST Effective date: 20080531 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20071001 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20070916 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20070917 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20070917 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20070916 |