EP0838517B1 - Bougie - Google Patents

Bougie Download PDF

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Publication number
EP0838517B1
EP0838517B1 EP97112397A EP97112397A EP0838517B1 EP 0838517 B1 EP0838517 B1 EP 0838517B1 EP 97112397 A EP97112397 A EP 97112397A EP 97112397 A EP97112397 A EP 97112397A EP 0838517 B1 EP0838517 B1 EP 0838517B1
Authority
EP
European Patent Office
Prior art keywords
paraffin
ester
fraction
candle
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP97112397A
Other languages
German (de)
English (en)
Other versions
EP0838517A1 (fr
Inventor
Norbert Matzat
Michael Matthäi
Gernot Meyer
Günther Hildebrand
Rolf Laudi
Claus Starke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Schuemann Sasol GmbH and Co KG
Original Assignee
Schuemann Sasol GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Schuemann Sasol GmbH and Co KG filed Critical Schuemann Sasol GmbH and Co KG
Publication of EP0838517A1 publication Critical patent/EP0838517A1/fr
Application granted granted Critical
Publication of EP0838517B1 publication Critical patent/EP0838517B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C5/00—Candles
    • C11C5/002—Ingredients

Definitions

  • the invention relates to a candle made of a wax-like substance based on paraffin and with an ester component, the candle having a freezing point having.
  • the invention further relates to a method for producing a such a candle.
  • Such candles are already known in various embodiments.
  • the aim is to have a melting behavior that is as favorable as possible to reach such a candle. That means that even with candles with relative large diameter, melting as possible over the entire Diameter takes place so that none during the candle burning Hollow structures arise which lead to the extinguishing of the candle or a It is very difficult to re-light the candle.
  • DD-A-224 334 describes candles which have an ester component and one Paraffin component with a solidification point of 47 ° C to 50 ° C exhibit.
  • the candles formed from this have a freezing point of 47 up to 63 ° C.
  • the invention deals with the technical problem, specify a suitable candle when using low-baked paraffin, which still has good melting behavior even with a large diameter shows, and a related manufacturing process.
  • paraffin With regard to the paraffin, one also speaks of low-boned paraffin.
  • the paraffin content mentioned has a very low hardness in the temperature range of a solidification point of 20 to 45 ° C. At approx. 40 ° C, for example, there is only a paste-like substance.
  • the proportion of organic ester or the ester-wax acid mixture already has a very considerable hardness at temperatures of 30 ° C. or less. For example. shows both hardened palm oil and hardened beef tallow, both substances that fall under the terms mentioned, a penetration of 6 mm -1 at 30 ° C.
  • paraffin here refers to technical paraffin, which is known to be obtained from petroleum, tars, in a partial synthesis or also by means of the Fischer-Tropsch synthesis. These are usually mixtures consisting of n-alkanes and isoalkanes of different carbon chain lengths, and the isoalkanes additionally have different structures.
  • the proportion of iso-paraffins in the mixture is more preferably 40% or more, particularly preferably 50% or more.
  • These iso-paraffins suitably have a C chain length of approximately C 16 to approximately C 45, with a maximum between C 26 and C 34. Such a paraffin portion has a solidification point below 45 ° C.
  • the above-mentioned mixture of paraffin with an organic ester and / or an ester-waxic acid mixture leads to a waxy substance which on the one hand has a hardness that is still acceptable for the desired products, but on the other hand also shows very good melting behavior.
  • Candles can be produced which, even with large dimensions in cross-section, lead to a uniform melting behavior across the cross-section. They then have an advantageous burning behavior.
  • the proportion of organic ester and / or ester-wax acid mixture in the waxy substance can be composed individually or as a mixture of the palm oil already mentioned, further of palm stearin, palm kernel oil, rapeseed oil, animal tallow, etc.
  • the compound class of the ester-wax acid mixture includes especially montan waxes, beeswax, carnauba wax, etc. These are long-chain esters. It is important that both the organic esters and the ester-wax acid mixtures have a high oil-binding capacity. However, this is designed differently in each case.
  • This property of the substance classes mentioned is particularly advantageous with regard to the substance described here, since the paraffin component with a solidification point of 20 to 45 ° C. has a certain oil proportion which increases with decreasing solidification points.
  • the paraffin portion can have a solidification point down to about 30 ° C. A solidification point of the paraffin portion in the range from 30 to 45 ° C. is preferred.
  • the proportion of paraffin in the waxy substance described here is in the range from 45 to 95%.
  • organic esters For example, fatty acid glycerides, wax acid esters or the montan waxes mentioned are also used.
  • the organic esters or montan waxes can also be saponified his.
  • Another example is triglycerides. As is known, these contain glycerin as alcohol. Such Alcohols with few carbon atoms, below 10 C atoms are preferred in the context of the invention (glycerol: 3 carbon atoms).
  • esters or Ester / wax acid mixtures all have a content of C-16 compounds, for example a palmite content of at least 5%, preferably more than 25%.
  • the invention also relates to a method for Making a candle in one of the previously described embodiments in this connection is based on the fact that in the course of paraffin refining preserved low-boned paraffin with a solidification point of 45 ° C with an organic Ester or an ester-wax acid mixture added with the organic ester or ester-wax acid mixture a solidification point of 35 to 70 ° C having.
  • the proportion of organic Esters or ester-wax acid mixture which further include individual substances already mentioned above.
  • a mixture of 80% paraffinic, paste-like content with 20% palm oil which has a penetration at 30 ° C of 6 mm -1 , resulted in a waxy substance with a solidification point of 37 ° C and a penetration at 30 ° C of 134 mm -1 .
  • a mixture of 80% paraffinic, paste-like content with 20% palm oil which has a penetration at 30 ° C of 6 mm -1 , resulted in a waxy substance with a solidification point of 37 ° C and a penetration at 30 ° C of 134 mm -1 .

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Fats And Perfumes (AREA)
  • Eye Examination Apparatus (AREA)

Claims (7)

  1. Bougie réalisée à partir d'une substance cireuse à base de paraffine, dans laquelle bougie la partie paraffinique présente un point de solidification de 20 à 45°C (partie de paraffine présentant le point de fusion le plus bas) et en outre une partie ester organique et/ou un mélange ester-acide de pataffine, l'ester organique et/ou le mélange ester-acide de paraffine est réalisé isolément ou comme mélange combiné d'huile de palme, de stéarine de palme, d'huile de noix de palmiste, d'huile de colza ou de suif animal ou de substances telles que des glycérides d'acide gras, des esters d'acide paraffinique, de cires minérales, dans laquelle bougie la partie de paraffine à bas point de fusion présente un pourcentage en volume dans la bougie de 45 à 95%, la partie d'ester présente en tant que telle un point de solidification de 35 à 70°C et la bougie présente un point de solidification de 40°C ou moins.
  2. Bougie selon la revendication 1, caractérisée en ce que la partie de paraffinique se compose d'un mélange d'iso-et de n-alcanes.
  3. Bougie selon la revendication 2, caractérisée en ce que la partie d'iso-alcanes atteint au moins 40%.
  4. Bougie selon la revendication 3, caractérisée en ce que la partie d'iso-alcanes atteint au moins 50%.
  5. Bougie selon l'une des revendications 2 à 4, caractérisée en ce que l'iso-alcane présente une longueur de chaíne carbonée de C16 à C45.
  6. Bougie selon la revendication 5, caractérisée en ce que l'iso-alcane présente, en ce qui concerne la longueur de chaíne carbonée, un maximum compris entre C26 et C34.
  7. Procédé de fabrication d'une bougie selon l'une des revendications 1 à 6, dans lequel au cours du raffinage de la paraffine, la paraffine obtenue présente un point de solidification compris entre 20 et 45°C avec un ester organique et/ou un mélange ester-acide de paraffine, dans lequel procédé, la partie d'ester en tant que telle, présente un point de solidification de 35°C à 70°C, et dans lequel procédé en
EP97112397A 1996-01-20 1997-07-18 Bougie Expired - Lifetime EP0838517B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19601998 1996-01-20
DE19644737 1996-10-28
DE19644737A DE19644737A1 (de) 1996-01-20 1996-10-28 Kerze

Publications (2)

Publication Number Publication Date
EP0838517A1 EP0838517A1 (fr) 1998-04-29
EP0838517B1 true EP0838517B1 (fr) 2003-03-12

Family

ID=7783257

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97112397A Expired - Lifetime EP0838517B1 (fr) 1996-01-20 1997-07-18 Bougie

Country Status (7)

Country Link
EP (1) EP0838517B1 (fr)
AT (1) ATE234349T1 (fr)
DE (2) DE19644737A1 (fr)
IT (1) IT1289175B1 (fr)
NL (1) NL1005033C2 (fr)
SI (1) SI0838517T1 (fr)
ZA (1) ZA976385B (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19751351A1 (de) * 1997-11-20 1999-05-27 Schuemann Sasol Gmbh & Co Kg Kerzengrundstoff und Verfahren zur Herstellung eines Kerzengrundstoffes
DE10021953B4 (de) * 1999-08-27 2011-10-27 SCHÜMANN SASOL GmbH Brennbare Masse
CA3012701C (fr) 2016-02-26 2024-01-02 Exxonmobil Research And Engineering Company Compositions de revetement pour panneaux de copeaux orientes et procedes d'utilisation associes

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR644651A (fr) * 1926-12-23 1928-10-12 Ig Farbenindustrie Ag Procédé pour durcir les paraffines, les cires, l'osokérite, la stéarine, le suif et les produits similaires
FR893371A (fr) * 1942-01-24 1944-06-07 Procédé pour améliorer la résistance à la flexion de bougies de paraffine
US2825635A (en) * 1956-01-23 1958-03-04 Exxon Research Engineering Co Paraffin wax composition
GB1006403A (en) * 1963-09-27 1965-09-29 W & F Mfg Co Inc Wax granules and method of making candles therefrom
US4002706A (en) * 1974-02-25 1977-01-11 Dirk Jacobus Pretorius Wax and wax blends
GB1490547A (en) * 1975-12-09 1977-11-02 Craft Candles Ltd Method of making candles
DD212530A1 (de) * 1982-12-16 1984-08-15 Leuna Werke Veb Tauchmasse fuer kerzen
DD224334A1 (de) * 1984-06-12 1985-07-03 Zeitz Hydrierwerk Wachskombination zur herstellung von dauerbrennern
US4855098A (en) * 1987-12-16 1989-08-08 Ted Taylor Method of forming candles and candle composition therefor
DE19601521B4 (de) * 1996-01-17 2005-03-31 Schümann Sasol Gmbh & Co. Kg Verfahren zur Herstellung eines wachsartigen Stoffes und wachsartiger Stoff zur Kerzenherstellung

Also Published As

Publication number Publication date
NL1005033C2 (nl) 1998-07-15
ZA976385B (en) 1998-02-10
DE59709476D1 (de) 2003-04-17
EP0838517A1 (fr) 1998-04-29
NL1005033A1 (nl) 1997-07-22
DE19644737A1 (de) 1997-07-24
SI0838517T1 (en) 2003-08-31
ITMI970091A1 (it) 1998-07-17
IT1289175B1 (it) 1998-09-29
ATE234349T1 (de) 2003-03-15

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