EP0651728A4 - Process for extracting alumina from bauxite. - Google Patents
Process for extracting alumina from bauxite.Info
- Publication number
- EP0651728A4 EP0651728A4 EP93915547A EP93915547A EP0651728A4 EP 0651728 A4 EP0651728 A4 EP 0651728A4 EP 93915547 A EP93915547 A EP 93915547A EP 93915547 A EP93915547 A EP 93915547A EP 0651728 A4 EP0651728 A4 EP 0651728A4
- Authority
- EP
- European Patent Office
- Prior art keywords
- liquor
- alumina
- bauxite
- digestion
- caustic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
- C01F7/06—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom by treating aluminous minerals or waste-like raw materials with alkali hydroxide, e.g. leaching of bauxite according to the Bayer process
- C01F7/062—Digestion
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
- C01F7/06—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom by treating aluminous minerals or waste-like raw materials with alkali hydroxide, e.g. leaching of bauxite according to the Bayer process
Definitions
- This invention relates to processes for the production of alumina from bauxite.
- alumina is produced using the Bayer process.
- a high volume of caustic liquor is circulated at a controlled concentration.
- the caustic is heated and reacted with bauxite to increase the alumina concentration (pregnant liquor) .
- the caustic liquor is cooled, seeded, and alumina is precipitated as product.
- the spent liquor is recirculated.
- the quantity of circulating liquor can be as high as 20 m 3 /t alumina produced. Expressed in terms of productivity, this is only 50 g/litre. To increase production of existing plants or to reduce the capital cost of new plants, it is important to achieve high yield. Only a few alumina plants are achieving +80 g/1 yield today.
- the digestion step has to achieve a high alumina concentration.
- a degree of supersaturation can be tolerated during the residue separation step.
- the alumina concentration is usually expressed as a ratio on caustic, A/C.
- the pregnant liquor can be 0.72 A/C (gAl 2 0 3 /gNa 2 C0 3 ) at say 105°C for 200 g/1 caustic expressed as Na 2 C0 3 (representing sodium hydroxide associated with the dissolved alumina as well as free sodium hydroxide) .
- the spent liquor A/C will depend on precipitation conditions but can be say 0.37 A/C. Free Caustic
- the spent liquor to digestion is evaporated to some degree and fresh caustic make-up added at this point, such that the concentration may be 240 g/1 caustic at 0.36 A/C.
- Bauxites are minerals rich in alumina and low in silica.
- the usual minerals containing only alumina are gibbsite, boehmite and diaspore. This is their respective order of solubility, for example, to achieve 0.72 A/C at say 200 g/1 caustic, the digestion temperature required would be:
- boehmite can be raised higher for higher A/C, however, if the temperature for gibbsite is raised higher, there is a risk of the dissolved alumina precipitating out as boehmite, which is the stable species above say 150°C. This is particularly so if the gibbsitic bauxite also contains boehmite to act as seed.
- the digestion productivity is a measure of the alumina concentration increase due to xuxite for a given flowrate of liquor. If there is a limit to the flowrate, then potentially the liquor can be evaporated so that the mass flow of caustic is increased and more bauxite can be added in proportion.
- Free caustic is not such a concern for liquor heating in a low temperature plant. It becomes a concern in a high temperature plant processing boehmitic bauxite in which the spent liquor is heated separately and the bauxite added direct to the digester (two stream process). In a two stream process, free caustic will impose a limit to the productivity.
- tube digestion In a high temperature tube digestion design or similar single stream process (liquor plus bauxite slurry heating) free caustic is not a limitation to the productivity. Although tube digestion has desirable process features, there are some mechanical limitations to pumping and slurry heating, and consequently the production rate of such a unit is limited.
- One way of achieving digestion productivity with a boehmitic bauxite is to add a gibbsitic bauxite downstream during flash cooling at say 170 - 150°C, and to increase the achieved boehmite A/C.
- This approach is known as "sweetening" and is practiced by a number of plants in various forms. Sweetening can also incorporate spent liquor trim. Sweetening for some plants can be a convenient retrofit, if the gibbsitic bauxite is available and handling of two bauxites is practical.
- the alumina precipitates out as gibbsite, as the temperature is usually well below 150°C. with good residue settler and washer design and operation, the degree of supersaturation can be as high as 25% of equilibrium solubility of gibbsite. Some alumina loss will occur (known as autoprecipitation) but is usually about 0.015 A/C.
- the digestion conditions of caustic strength and temperature have to be such that the equilibrium solubility of boehmite or gibbsite from the bauxite is
- the object of the invention is to provide an improved process for extracting alumina from bauxite in which the problems discussed above are at least ameliorated.
- the invention provides a process for extracting alumina from bauxite comprising the steps of combining caustic liquor with a bauxite slurry to provide an alumina to caustic ratio (A/C) of greater than about 0.70 in the slurry/liquor mixture, subjecting the mixture to digestion at a temperature below that at which reversion of dissolved gibbsite to boehmite may occur, to extract alumina from the gibbsite bauxite in the slurry, separating the high alumina pregnant liquor from the boehmite containing residue, mixing the residue with caustic liquor and subjecting the mixture to a high temperature digestion process to extract the remaining alumina from the residue, and separating the alumina rich liquor.
- A/C alumina to caustic ratio
- the strong caustic liquor to the gibbsite digestion may be concentrated by evaporation and/or by the addition of fresh caustic to achieve the desired high A/C.
- the bauxite slurry may be subjected to a known predesilication process prior to heating. Alternatively, two stage post-desilication using lime has been found to be satisfactory.
- the atmospheric settler or pressure decanter following the high temperature digestion step is preferably operated at an A/C which is lower than that of the low temperature decanter to minimize autoprecipitation during subsequent residue washing.
- the invention also provides alumina when produced by the process defined in the preceding paragraphs. Brief description of the drawings
- Figure 1 is a schematic flow chart of a bauxite digestion process embodying the invention.
- FIG. 2 is a similar schematic flow diagram of a modified . bauxite digestion process embodying the invention. Description of Preferred Embodiments
- the preferred processes are applicable to mixed bauxit s containing a high proportion of gibbsite together with less soluble boehmite and diaspore.
- the processes can also be applied to a mixed bauxite of boehmite and diaspore.
- the processes can also be applied to gibbsite bauxite where an over-charged digestion (for high A/C) can be followed by a re-digestion for complete extraction.
- the following description relates to gibbsitic-boehmitic bauxite and refers to Figs. 1 and 2 of the drawings, but the process is equally applicable to other bauxites.
- the preferred process involves two sequential bauxite digestion steps 1 and 2 to extract gibbsite at low temperature and high caustic, followed by boehmite at high temperature and low caustic to produce alumina at high liquor productivity.
- the process is particularly suited to retrofitting a two stream high temperature digestion plant, as will be described further below.
- the low temperature digestion step 1 is designed to extract essentially all the gibbsite from the bauxite feed, and the process is therefore particularly beneficial to bauxites having a high proportion of gibbsite (eg Comalco bauxite containing about 75% of available alumina as gibbsite) .
- the conditions are designed to achieve a very high A/C liquor with minimal reversion and without free caustic limitations.
- bauxite slurry 3 is fed with spent liquor 18 and caustic make-up 4 to a heat exchanger 5, fed with flash and low pressure live steam 6.
- the low temperature digestion conditions are controlled to limit the temperature to below 150°C to avoid reversion of dissolved gibbsite to boehmite.
- To achieve the required high A/C of greater than 0.70 A/C strong caustic liquor is required. This is achieved by evaporation 21 of the spent liquor 18 and by indirect heating in 5.
- Caustic make-up 4 can also be added.
- the strong spent liquor after evaporation can then be heated up to the free caustic limitation, which depending on heater design can range from 130 - 150°C. If for example the limitation is 130°C, then the spent liquor can be heated from 85"C say to 130°C in shell and tube heat exchangers (not shown) using flashed steam.
- the bauxite slurry at 70°C say can be heated up to a similar temperature in slurry heaters. Both streams can then be combined for further heating using flash and indirect low pressure live steam (not shown) .
- both liquor and bauxite slurry can be combined for all the heating as a single stream in suitable heaters 5 as shown.
- the heated slurry from the heat exchangers 5 is held at temperature in a well stirred vessel 7 or holding tube to achieve the required alumina extraction.
- predesilication may be necessary prior to heating the slurry. This requires heating the ground bauxite caustic liquor slurry up to say 100°C and holding it in stirred vessels (not shown) to allow any silica such as kaoiinite to dissolve and then to reprecipitate as desilication product (sodium aluminium silicate) . Without predesilication, there is the risk of desilication product scaling out and fouling the heaters. As indicated in the Example, the process has been successfully operated using a post- desilication step in which about 96% of the silica is removed.
- some of the digestion holding time may be required for further desilication so as to avoid excessive silica levels remaining in liquor.
- the boehmite containing residue is separated in a pressure decanter 8 at digestion temperature using a suitable synthetic flocculent.
- a suitable synthetic flocculent such as US Patent 5080803 and elsewhere. High underflow density and good overflow clarity can be achieved.
- the underflow at high density and temperature is pumped with suitable pumps (not shown) to the high temperature digestion step 2.
- the pressure decanter overflow 9 at high A/C pregnant liquor is flash cooled in flash tanks 13 to atmospheric boiling point for dilution, filtering, cooling and seeding to produce alumina product. If required, post-desilication can be carried out on the overflow at temperature before flash cooling.
- Some of the desilicated decanter overflow may be diverted to the remaining unconcentrated spent liquor via a free caustic trim line 10 to control the free caustic to allow high temperature heating for the high temperature digestion step 2.
- the low temperature digestion pressure decanter underflow is pumped direct to a high temperature digester vessel 11, with or without further heating. Alternatively it can be mixed with the incoming unconcentrated spent liquor after an appropriate spent liquor heating and final pumping stage. The single stream can then be further heated in suitable heaters by flash steam and high pressure live steam or other heat transfer medium (not shown) . High pressure steam 12 is added direct to the digester as required.
- the temperature and time of the high temperature digestion vessel 11, or holding tube, is selected so as to extract the remaining boehmite, at the caustic concentration prevailing to achieve a medium to normal pregnant liquor A/C.
- Slurry from the high temperature digestion vessel 11 is flash cooled in flash tanks 13 to atmospheric conditions for residue removal by settling in a settler or separator 14 followed by washing and disposal of red mud via 16.
- the settler overflow pregnant liquor 15 is diluted, filtered, cooled and seeded in a known manner not shown for alumina production.
- a pressure decanter 17 can be applied at the appropriate temperature down the flash train 13. The overflow can then join the overflow of the main low temperature digestion decanter for common flash cooling.
- the pressure decanter underflow of final residue or "red mud” can be cooled indirectly or directly by wash water prior to washing and disposal.
- the high temperature digestion pressure decanter 17 will normally be at a lower A/C than for the main decanter. This will minimise autoprecipitation during subsequent red mud washing.
- the high A/C and normal A/C pregnant liquor streams 9 and 15 can be cooled and diluted separately for a more optimised precipitation of alumina.
- flash tank sweetening and spent liquor trim can still be applied to the high temperature digestion step (not shown) .
- the above embodiments of the invention are particularly suitable for retrofitting of existing alumina plants processing a high gibbsite, moderate boehmite bauxite using a two stream digestion process.
- the bulk of the digestion is carried out at low temperature freeing up the high temperature equipment for potentially greater capacity and efficiency.
- the high A/C pregnant liquor from the low temperature digestion has the potential to replace part or all of any sweetening bauxite previously used.
- the aim was to find conditions for high A/C from gibbsite dissolution with minimal reversion (autoprecipitation) to boehmite or gibbsite.
- the following results were obtained from one of the tests:-
- Pregnant liquor after lime treatment 306.0 g/1 caustic soda (C) 1.5% CaO/ 0.735 A/C bauxite 0.848 C/S
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AUPL3754/92 | 1992-07-24 | ||
AUPL375492 | 1992-07-24 | ||
PCT/AU1993/000369 WO1994002416A1 (en) | 1992-07-24 | 1993-07-22 | Process for extracting alumina from bauxite |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0651728A1 EP0651728A1 (en) | 1995-05-10 |
EP0651728A4 true EP0651728A4 (en) | 1995-09-27 |
Family
ID=3776319
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP93915547A Withdrawn EP0651728A4 (en) | 1992-07-24 | 1993-07-22 | Process for extracting alumina from bauxite. |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0651728A4 (en) |
KR (1) | KR950702506A (en) |
BR (1) | BR9306780A (en) |
CA (1) | CA2140773A1 (en) |
WO (1) | WO1994002416A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AUPM761194A0 (en) * | 1994-08-23 | 1994-09-15 | Comalco Aluminium Limited | Improved process for the extraction of alumina from bauxite |
US6528028B2 (en) * | 1999-12-28 | 2003-03-04 | Showa Denko K.K. | Process for treating bauxite in which a desilication product and an insoluble residure are separately precipitated |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0389061A2 (en) * | 1989-03-21 | 1990-09-26 | Shell Internationale Researchmaatschappij B.V. | Process for the production of aluminium hydroxide from bauxite |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4324769A (en) * | 1979-10-01 | 1982-04-13 | Alumina Development Corporation | Extraction and production of alumina containing less than 0.03 percent iron oxide |
JPS57145029A (en) * | 1981-02-27 | 1982-09-07 | Sumitomo Alum Smelt Co Ltd | Extracting method of alumina from mixed type bauxite |
AU551019B2 (en) * | 1981-05-15 | 1986-04-17 | James W. McDaniel | Reducing iron content of bayer process solutions |
US4446117A (en) * | 1983-04-04 | 1984-05-01 | Alumina Development Corporation | Double digestion system to reduce formation of ferrous iron |
-
1993
- 1993-07-22 CA CA002140773A patent/CA2140773A1/en not_active Abandoned
- 1993-07-22 BR BR9306780A patent/BR9306780A/en not_active Application Discontinuation
- 1993-07-22 KR KR1019950700276A patent/KR950702506A/en not_active Application Discontinuation
- 1993-07-22 WO PCT/AU1993/000369 patent/WO1994002416A1/en not_active Application Discontinuation
- 1993-07-22 EP EP93915547A patent/EP0651728A4/en not_active Withdrawn
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0389061A2 (en) * | 1989-03-21 | 1990-09-26 | Shell Internationale Researchmaatschappij B.V. | Process for the production of aluminium hydroxide from bauxite |
Also Published As
Publication number | Publication date |
---|---|
WO1994002416A1 (en) | 1994-02-03 |
CA2140773A1 (en) | 1994-02-03 |
BR9306780A (en) | 1998-12-08 |
EP0651728A1 (en) | 1995-05-10 |
KR950702506A (en) | 1995-07-29 |
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