EP0601967A1 - Liquid detergent composition - Google Patents
Liquid detergent composition Download PDFInfo
- Publication number
- EP0601967A1 EP0601967A1 EP93810772A EP93810772A EP0601967A1 EP 0601967 A1 EP0601967 A1 EP 0601967A1 EP 93810772 A EP93810772 A EP 93810772A EP 93810772 A EP93810772 A EP 93810772A EP 0601967 A1 EP0601967 A1 EP 0601967A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- hydrogen
- liquid detergent
- formula
- detergent according
- so3m
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 46
- 239000007788 liquid Substances 0.000 title claims abstract description 30
- 239000000203 mixture Substances 0.000 title description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 41
- 239000001257 hydrogen Substances 0.000 claims abstract description 41
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 claims abstract description 21
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims abstract description 21
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 15
- 150000002367 halogens Chemical class 0.000 claims abstract description 15
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims abstract description 14
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- 239000004744 fabric Substances 0.000 claims abstract description 6
- 125000000542 sulfonic acid group Chemical group 0.000 claims abstract description 5
- 239000004753 textile Substances 0.000 claims abstract description 5
- 238000005406 washing Methods 0.000 claims abstract description 4
- 150000002431 hydrogen Chemical class 0.000 claims abstract 13
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 29
- 230000003287 optical effect Effects 0.000 claims description 22
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 16
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 16
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 16
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 16
- 150000001768 cations Chemical class 0.000 claims description 15
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 9
- 229910052801 chlorine Inorganic materials 0.000 claims description 9
- 239000000460 chlorine Substances 0.000 claims description 9
- UCFFGYASXIPWPD-UHFFFAOYSA-N methyl hypochlorite Chemical compound COCl UCFFGYASXIPWPD-UHFFFAOYSA-N 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Chemical group 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000004061 bleaching Methods 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 2
- -1 Methoxy, ethoxy, n-propoxy, iso-propoxy, n-butoxy Chemical group 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 150000004965 peroxy acids Chemical class 0.000 description 4
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002888 zwitterionic surfactant Substances 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical group OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- 238000007046 ethoxylation reaction Methods 0.000 description 2
- 229930182478 glucoside Natural products 0.000 description 2
- 150000008131 glucosides Chemical group 0.000 description 2
- 239000001087 glyceryl triacetate Substances 0.000 description 2
- 235000013773 glyceryl triacetate Nutrition 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 150000004671 saturated fatty acids Chemical class 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229960002622 triacetin Drugs 0.000 description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 2
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- ZMLPKJYZRQZLDA-UHFFFAOYSA-N 1-(2-phenylethenyl)-4-[4-(2-phenylethenyl)phenyl]benzene Chemical group C=1C=CC=CC=1C=CC(C=C1)=CC=C1C(C=C1)=CC=C1C=CC1=CC=CC=C1 ZMLPKJYZRQZLDA-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- LVYAAXIQDDYCMR-UHFFFAOYSA-N Cc1c(-c(cc2)ccc2-c(cc2)ccc2-c([o]c2c3)c(C)c2cc(C)c3N=O)[o]c2c1cc(C)c(N)c2 Chemical compound Cc1c(-c(cc2)ccc2-c(cc2)ccc2-c([o]c2c3)c(C)c2cc(C)c3N=O)[o]c2c1cc(C)c(N)c2 LVYAAXIQDDYCMR-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 241000700196 Galea musteloides Species 0.000 description 1
- 101001096355 Homo sapiens Replication factor C subunit 3 Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 102100037855 Replication factor C subunit 3 Human genes 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000005600 alkyl phosphonate group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229940097407 palm kernel acid Drugs 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229940113115 polyethylene glycol 200 Drugs 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000000249 polyoxyethylene sorbitan monopalmitate Substances 0.000 description 1
- 235000010483 polyoxyethylene sorbitan monopalmitate Nutrition 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- PLQISZLZPSPBDP-UHFFFAOYSA-M sodium;pentadecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCS([O-])(=O)=O PLQISZLZPSPBDP-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
- D06L4/614—Optical bleaching or brightening in aqueous solvents
- D06L4/621—Optical bleaching or brightening in aqueous solvents with anionic brighteners
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
- D06L4/65—Optical bleaching or brightening with mixtures of optical brighteners
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/60—Optical bleaching or brightening
- D06L4/657—Optical bleaching or brightening combined with other treatments, e.g. finishing, bleaching, softening, dyeing or pigment printing
Definitions
- the present invention relates to new, highly concentrated, aqueous and liquid detergents containing specifically disulfonated dibenzfuranylbiphenyls as optical brighteners, their preparation and their use.
- optical brighteners in liquid detergents is known. They soak on the items to be washed during treatment and, due to their special light absorption / emission properties, lead to an elimination of the yellowish tones or an improvement in the degree of whiteness.
- EP-A-167 205 proposes to use monosulfonated stilbene triazolyl, triazine or distyrylbiphenyl brighteners in anionic liquid detergents.
- halogens are fluorine, chlorine and bromine, but especially chlorine.
- C1-C4 alkyl radicals come unbranched or branched alkyl radicals e.g. Methyl, ethyl, n-propyl, iso-propyl, n-butyl and t-butyl.
- C1-C4 alkoxy radicals come unbranched or branched alkoxy radicals e.g. Methoxy, ethoxy, n-propoxy, iso-propoxy, n-butoxy and t-butoxy.
- These alkyl (or alkoxy) residues can in turn be substituted with e.g.
- M in the meaning of a non-chromophoric cation preferably represents alkali metal such as lithium, sodium, potassium and optionally substituted ammonium such as ammonium, mono-, di- or triethanolammonium, mono-, di- or tripropanolammonium or tri- or tetramethylammonium.
- alkali metal such as lithium, sodium, potassium and optionally substituted ammonium such as ammonium, mono-, di- or triethanolammonium, mono-, di- or tripropanolammonium or tri- or tetramethylammonium.
- Sodium, potassium and ammonium are particularly preferred.
- Liquid detergents are known and commercially available detergents, as are described, for example, in EP-A-167 205 or US-4 507 219 or EP-A-293 040.
- Anionic, nonionic, cationic or zwitterionic surfactants can be used as surfactants.
- Useful surfactants are e.g. in U.S. 4,285,841, U.S. 3,929,678, U.S. 4,284,532 and GB 2,041,986.
- the surfactants designated as preferred in EP-A-167 205 are used.
- Anionic surfactants are e.g. also
- Nonionic surfactants are e.g. Polyhydroxy fatty acid amides as described in WO 92/06172 and alkylphenols. Furthermore, there are alkyl polyglucosides of C9-C1 Alk alkylene with 1-10 glucoside units such as Nonyl glucoside and allyl (C12-C15) poly (1-10) glucoside, sorbine esters such as e.g. Polyoxyethylene sorbitan monopalmitate, fatty acid ethanolamides such as e.g. Coconut fatty acid diethanolamide and fatty acid ethanolamine oxides such as Tetradecylamine oxide in question.
- alkyl polyglucosides of C9-C1 Alk alkylene with 1-10 glucoside units such as Nonyl glucoside and allyl (C12-C15) poly (1-10) glucoside
- sorbine esters such as e.g. Polyoxyethylene sorbitan monopalmitate
- fatty acid ethanolamides
- Detergent builders or polymers include e.g. the preferably polycarboxylated compounds mentioned in U.S. 4,321,165 and U.S. 4,284,532 such as citric acid or maleic acid / acrylic acid copolymers, as well as e.g. the lignin sulfonates, formaldehyde addition products, polyethylene glycols, polyvinylpyrolidones, polyvinylimidazoles, and Al / Mg silicates.
- the lignin sulfonates e.g. the preferably polycarboxylated compounds mentioned in U.S. 4,321,165 and U.S. 4,284,532 such as citric acid or maleic acid / acrylic acid copolymers, as well as e.g. the lignin sulfonates, formaldehyde addition products, polyethylene glycols, polyvinylpyrolidones, polyvinylimidazoles, and Al / Mg silicates.
- Zwitterionic surfactants are e.g. Aminocarboxylic acids and alkylamine oxides.
- Cationic surfactants are e.g. quaternary ammonium or amine compounds.
- the formulation can contain 1 to 10% of common detergent additives such as, for example, enzymes, enzyme stabilizers, antioxidants, preservatives and disinfectants, emulsifiers, thickeners, foam regulators, stabilizers, antiredeposition agents, fragrances and colorants, complexing agents or sequestering agents and solvents.
- common detergent additives such as, for example, enzymes, enzyme stabilizers, antioxidants, preservatives and disinfectants, emulsifiers, thickeners, foam regulators, stabilizers, antiredeposition agents, fragrances and colorants, complexing agents or sequestering agents and solvents.
- salts e.g. Formates, acetates and sodium chloride can be used.
- Targeted liquid detergents containing sulfonated dibenzofuranylbiphenyls can also be used e.g. also described in EP-A-293 040, contain up to 20% by weight of one or more bleaching agents such as phthalocyanines, peracids such as perborates or diperoxydicarboxylic acids, or peracid precursors and peracid activators or peracid catalysts.
- bleaching agents such as phthalocyanines, peracids such as perborates or diperoxydicarboxylic acids, or peracid precursors and peracid activators or peracid catalysts.
- the formulation is produced by mixing the components with stirring.
- the formulation thus obtained is stable for months and does not sediment.
- optical brighteners used is e.g. in EP-A-394 998.
- the detergents obtained in Examples 1 and 2 are used in a concentration of 7.5 g / l for washing bleached cotton at 60 ° C. After rinsing and drying, high degrees of whiteness are achieved with negligible stain formation.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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Abstract
Beschrieben werden neue hochkonzentrierte, wässrige und flüssige Waschmittel, enthaltend a) 0,01 bis 2 Gew.% Dibenzfuranylbiphenyle der Formel <IMAGE> worin R1, R2, R3, R4 und R5 unabhängig voneinander ein Sulfonsäurerest, Wasserstoff, C1-C4-Alkyl, C1-C4-Alkoxy, Halogen, CN, Phenoxy oder Benzyloxy, mit der Bedingung, dass nur einer der Reste R1 bis R5 ein Sulfonsäurerest ist, bedeuten, b) 6 bis 22 Gew.% Wasser, bezogen auf das Gewicht des Waschmittels, und c) Tenside sowie deren Herstellung und Verwendung zum Vorbehandeln und Waschen von textilen Geweben.Described are new, highly concentrated, aqueous and liquid detergents containing a) 0.01 to 2% by weight of dibenzfuranylbiphenyls of the formula <IMAGE> in which R1, R2, R3, R4 and R5 independently of one another are a sulfonic acid residue, hydrogen, C1-C4-alkyl, C1-C4-alkoxy, halogen, CN, phenoxy or benzyloxy, with the condition that only one of the radicals R1 to R5 is a sulfonic acid radical, b) 6 to 22% by weight of water, based on the weight of the detergent, and c) surfactants and their preparation and use for the pretreatment and washing of textile fabrics.
Description
Die vorliegende Erfindung betrifft neue hochkonzentrierte, wässrige und flüssige Waschmittel enthaltend gezielt disulfonierte Dibenzfuranylbiphenyle als optische Aufheller deren Herstellung und deren Verwendung.The present invention relates to new, highly concentrated, aqueous and liquid detergents containing specifically disulfonated dibenzfuranylbiphenyls as optical brighteners, their preparation and their use.
Die Verwendung von optischen Aufhellern in flüssigen Waschmitteln ist bekannt. Sie ziehen während der Behandlung auf das Waschgut auf und führen durch ihre spezielle Lichtabsorption/Emissionseigenschaft zu einer Elimination der gelblichen Töne bzw. zu einer Verbesserung des Weissgrades.The use of optical brighteners in liquid detergents is known. They soak on the items to be washed during treatment and, due to their special light absorption / emission properties, lead to an elimination of the yellowish tones or an improvement in the degree of whiteness.
Dieser Effekt ist aber auch verantwortlich für das Auftreten von hellen Flecken wenn Textilgewebe z.B. bei einer Vorbehandlung direkt mit dem flüssigen Waschmittel in Kontakt gerät. In der EP-A-167 205 wird zur Lösung dieses Problems vorgeschlagen, monosulfonierte Stilbentriazolyl-, -triazin oder Distyrylbiphenyl-Aufheller in anionischen Flüssigwaschmitteln zu verwenden.This effect is also responsible for the appearance of light spots when textile fabrics e.g. comes into contact with the liquid detergent during pretreatment. To solve this problem, EP-A-167 205 proposes to use monosulfonated stilbene triazolyl, triazine or distyrylbiphenyl brighteners in anionic liquid detergents.
Der Trend zu immer konzentrierteren Waschmittelformulierungen stellt jedoch auch hohe Anforderungen an die Einzelkomponenten bezüglich der Einarbeitbarkeit, Löslichkeit und deren Lagerstabilität. Aus der EP-A-394 998 sind z.B. Flüssigwaschmittel mit einem Gehalt von 25 bis 65 Gew.% Wasser bekannt.However, the trend towards increasingly concentrated detergent formulations also places high demands on the individual components with regard to incorporability, solubility and their storage stability. From EP-A-394 998 e.g. Liquid detergent with a content of 25 to 65 wt.% Water known.
Es wurden nun überraschenderweise gefunden, dass hochkonzentrierte, wässrige Flüssigwaschmittel, dadurch gekennzeichnet, dass sie
- a) 0,01 bis 2 % und bevorzugt 0,002 bis 0,4 Gew.%, bezogen auf das Gewicht des Waschmittels, eines oder mehrerer disulfonierter optischer Aufheller der Formel (1)
R₁, R₂, R₃, R₄ und R₅ unabhängig voneinander ein Sulfonsäurerest, Wasserstoff, C₁-C₄-Alkyl, C₁-C₄-Alkoxy, Halogen, CN, Phenoxy oder Benzyloxy, mit der Bedingung, dass nur einer der Reste R₁ bis R₅ ein Sulfonsäurerest ist, bedeuten, - b) 6 bis 22 Gew.% und bevorzugt 8 bis 17 Gew.% Wasser, bezogen auf das Gewicht des Waschmittels, und
- c) Tenside
enthalten, eine ausgezeichnete Lagerstabilität besitzen und nicht zur Fleckenbildung neigen.Surprisingly, it has now been found that highly concentrated, aqueous liquid detergents, characterized in that they
- a) 0.01 to 2% and preferably 0.002 to 0.4% by weight, based on the weight of the detergent, of one or more disulfonated optical brighteners of the formula (1)
R₁, R₂, R₃, R₄ and R₅ independently of one another are a sulfonic acid residue, hydrogen, C₁-C₄-alkyl, C₁-C₄-alkoxy, halogen, CN, phenoxy or benzyloxy, with the condition that only one of the residues R₁ to R₅ is a sulfonic acid residue is mean - b) 6 to 22% by weight and preferably 8 to 17% by weight of water, based on the weight of the detergent, and
- c) surfactants
contain, have an excellent storage stability and do not tend to stain.
Als Halogene kommen vor allem Fluor, Chlor und Brom in Frage, insbesondere jedoch Chlor.The most suitable halogens are fluorine, chlorine and bromine, but especially chlorine.
Als C₁-C₄-Alkylreste kommen unverzweigte oder verzweigte Alkylreste z.B. Methyl, Aethyl, n-Propyl, iso-Propyl, n-Butyl und t-Butyl in Betracht. Als C₁-C₄-Alkoxyreste kommen unverzweigte oder verzweigte Alkoxyreste z.B. Methoxy, Aethoxy, n-Propoxy, iso-Propoxy, n-Butoxy und t-Butoxy in Betracht. Diese Alkyl- (bzw. Alkoxy-) reste können ihrerseits substituiert sein mit z.B. Aryl- (Phenyl-oder Naphthyl-), C₁-C₄-Alkyl-(Methyl, Aethyl, n-Propyl, iso-Propyl, n-Butyl oder t-Butyl), C₁-C₄-Alkoxy-(Methoxy, Aethoxy, n-Propoxy, iso-Propoxy, n-Butoxy oder t-Butoxy), OH- oder CN-Gruppen.As C₁-C₄ alkyl radicals come unbranched or branched alkyl radicals e.g. Methyl, ethyl, n-propyl, iso-propyl, n-butyl and t-butyl. As C₁-C₄ alkoxy radicals come unbranched or branched alkoxy radicals e.g. Methoxy, ethoxy, n-propoxy, iso-propoxy, n-butoxy and t-butoxy. These alkyl (or alkoxy) residues can in turn be substituted with e.g. Aryl- (phenyl- or naphthyl-), C₁-C₄-alkyl- (methyl, ethyl, n-propyl, isopropyl, n-butyl or t-butyl), C₁-C₄-alkoxy- (methoxy, ethoxy, n -Propoxy, iso-propoxy, n-butoxy or t-butoxy), OH or CN groups.
Bevorzugte Dibenzfuranylbiphenyle der Formel (1) sind solche
worin
R₁ = SO₃M;
R₂, R₃, R₄ und R₅ unabhängig voneinander Wasserstoff, C₁-C₄-Alkyl, C₁-C₄-Alkoxy. Halogen, CN, Phenoxy oder Benzyloxy, bevorzugt Wasserstoff, Methyl, Aethyl, iso-Propyl, t-Butyl, Methoxy, Chlor, CN, Phenoxy oder Benzyloxy, insbesondere Wasserstoff, Methyl, Aethyl, iso-Propyl, t-Butyl oder Chlor bedeuten; und
M = Wasserstoff oder ein nichtchromophores Kation; sowie Verbindungen der Formel (1) worin
R₁ = Wasserstoff, C₁-C₄-Alkyl, C₁-C₄-Alkoxy, Halogen, CN, Phenoxy oder Benzyloxy;
R₂, R₃, R₄ und R₅ unabhängig voneinander SO₃M, Wasserstoff, C₁-C₄-Alkyl, C₁-C₄-Alkoxy, Halogen, CN, Phenoxy oder Benzyloxy, bevorzugt SO₃M, Wasserstoff, Methyl, Aethyl, iso-Propyl, t-Butyl, Methoxy, Chlor, CN, Phenoxy oder Benzyloxy, insbesondere SO₃M, Wasserstoff, Methyl, Aethyl, iso-Propyl, t-Butyl oder Chlor bedeuten, mit der Bedingung, dass nur einer der Reste R₂ bis R₅ ein Sulfonsäurerest ist, ; und
M = Wasserstoff oder ein nichtchromophores Kation;
bedeuten.Preferred dibenzfuranylbiphenyls of the formula (1) are those
wherein
R₁ = SO₃M;
R₂, R₃, R₄ and R₅ independently of one another hydrogen, C₁-C₄-alkyl, C₁-C₄-alkoxy. Halogen, CN, phenoxy or benzyloxy, preferably hydrogen, methyl, ethyl, isopropyl, t-butyl, methoxy, chlorine, CN, phenoxy or benzyloxy, in particular hydrogen, methyl, ethyl, isopropyl, t-butyl or chlorine ; and
M = hydrogen or a non-chromophoric cation; as well as compounds of formula (1) wherein
R₁ = hydrogen, C₁-C₄ alkyl, C₁-C₄ alkoxy, halogen, CN, phenoxy or benzyloxy;
R₂, R₃, R₄ and R₅ independently of one another SO₃M, hydrogen, C₁-C₄-alkyl, C₁-C₄-alkoxy, halogen, CN, phenoxy or benzyloxy, preferably SO₃M, Is hydrogen, methyl, ethyl, iso-propyl, t-butyl, methoxy, chlorine, CN, phenoxy or benzyloxy, especially SO₃M, hydrogen, methyl, ethyl, iso-propyl, t-butyl or chlorine, with the condition that only one of the radicals R₂ to R₅ is a sulfonic acid radical; and
M = hydrogen or a non-chromophoric cation;
mean.
Besonders bevorzugt sind dabei Verbindungen der Formel (1), worin
R₄=SO₃M,
R₁, R₂, R₃ und R₅ unabhängig voneinander Wasserstoff, C₁-C₄-Alkyl, C₁-C₄-Alkoxy, Halogen, CN, Phenoxy oder Benzyloxy, bevorzugt Wasserstoff, Methyl, Aethyl, iso-Propyl, t-Butyl, Methoxy, Chlor, CN, Phenoxy oder Benzyloxy, insbesondere Wasserstoff, Methyl, Aethyl, iso-Propyl, t-Butyl oder Chlor; und
M = Wasserstoff oder ein nichtchromophores Kation bedeuten; sowie Verbindungen der Formel (1) worin
R₂=SO₃M
R₁, R₃, R₄ und R₅ unabhängig voneinander Wasserstoff, C₁-C₄-Alkyl, C₁-C₄-Alkoxy, Halogen, CN, Phenoxy oder Benzyloxy, bevorzugt Wasserstoff, Methyl, Aethyl, iso-Propyl, t-Butyl, Methoxy, Chlor, CN, Phenoxy oder Benzyloxy, insbesondere Wasserstoff, Methyl, Aethyl, iso-Propyl, t-Butyl oder Chlor; und
M = Wasserstoff oder ein nichtchromophores Kation bedeuten.Compounds of the formula (1) in which
R₄ = SO₃M,
R₁, R₂, R₃ and R₅ independently of one another hydrogen, C₁-C₄-alkyl, C₁-C₄-alkoxy, halogen, CN, phenoxy or benzyloxy, preferably hydrogen, methyl, ethyl, isopropyl, t-butyl, methoxy, chlorine, CN, phenoxy or benzyloxy, especially hydrogen, methyl, ethyl, iso-propyl, t-butyl or chlorine; and
M = hydrogen or a non-chromophoric cation; as well as compounds of formula (1) wherein
R₂ = SO₃M
R₁, R₃, R₄ and R₅ independently of one another are hydrogen, C₁-C₄-alkyl, C₁-C₄-alkoxy, halogen, CN, phenoxy or benzyloxy, preferably hydrogen, methyl, ethyl, isopropyl, t-butyl, methoxy, chlorine, CN, phenoxy or benzyloxy, especially hydrogen, methyl, ethyl, iso-propyl, t-butyl or chlorine; and
M = hydrogen or a non-chromophoric cation.
M in der Bedeutung eines nichtchromophoren Kations steht vorzugsweise für Alkalimetall wie Lithium, Natrium, Kalium sowie gegebenenfalls substituiertes Ammonium wie Ammonium, Mono-, Di- oder Triethanolammonium, Mono-, Di- oder Tripropanolammonium oder Tri- oder Tetramethylammonium. Besonders bevorzugt sind hierbei Natrium, Kalium und Ammonium.M in the meaning of a non-chromophoric cation preferably represents alkali metal such as lithium, sodium, potassium and optionally substituted ammonium such as ammonium, mono-, di- or triethanolammonium, mono-, di- or tripropanolammonium or tri- or tetramethylammonium. Sodium, potassium and ammonium are particularly preferred.
Unter Flüssigwaschmitteln sind bekannte und handelsübliche Waschmittel, wie sie beispielsweise in der EP-A-167 205 oder US-4 507 219 oder EP-A-293 040 beschrieben werden, zu verstehen.Liquid detergents are known and commercially available detergents, as are described, for example, in EP-A-167 205 or US-4 507 219 or EP-A-293 040.
Als Tenside können anionische, nichtionische, kationische oder zwitterionische Tenside verwendet werden.Anionic, nonionic, cationic or zwitterionic surfactants can be used as surfactants.
Beispielsweise kann die Formulierung
- . 0 bis 40 Gew.%, vorzugsweise 2 bis 10 Gew.% anionische Tenside,
- . 3 bis 78 Gew.%, vorzugsweise 10 bis 60 Gew,% nichtionische Tenside,
- . 3 bis 35 Gew.%, vorzugsweise 5 bis 25 Gew.% Ethoxylierungsprodukte,
- . 0,5 bis 35 Gew.%, vorzugsweise 1 bis 20 Gew.% Aufbaustoffe,
- . 0 bis 10 Gew.%, vorzugsweise 1 bis 8 Gew.% zwitterionische Tenside,
- . 0 bis 3 Gew.%, vorzugsweise 0,7 bis 2 Gew.% kationische Tenside und
- . 0 bis 15 Gew.%, vorzugsweise 0,2 bis 10 Gew.% Polymere
enthalten.For example, the wording
- . 0 to 40% by weight, preferably 2 to 10% by weight, anionic surfactants,
- . 3 to 78% by weight, preferably 10 to 60% by weight, nonionic surfactants,
- . 3 to 35% by weight, preferably 5 to 25% by weight, of ethoxylation products,
- . 0.5 to 35% by weight, preferably 1 to 20% by weight, of building materials,
- . 0 to 10% by weight, preferably 1 to 8% by weight of zwitterionic surfactants,
- . 0 to 3% by weight, preferably 0.7 to 2% by weight, of cationic surfactants and
- . 0 to 15% by weight, preferably 0.2 to 10% by weight, of polymers
contain.
Brauchbare Tenside werden z.B. in der US-4 285 841, US-3 929 678, US-4 284 532 und GB-2 041 986 beschrieben. Insbesondere werden die in der EP-A-167 205 als bevorzugt bezeichneten Tenside eingesetzt.Useful surfactants are e.g. in U.S. 4,285,841, U.S. 3,929,678, U.S. 4,284,532 and GB 2,041,986. In particular, the surfactants designated as preferred in EP-A-167 205 are used.
- . Fettsäuren wie gesättigte und ungesättigte Carbonsäuren wie z.B. Öl-, Caprin-, Myristin-, Kokosnuss-, Palmkernsäure oder deren Salze;. Fatty acids such as saturated and unsaturated carboxylic acids such as e.g. Oleic, capric, myristic, coconut, palm kernel acid or salts thereof;
- . Alkylsulfate;. Alkyl sulfates;
- . Alkylsulfonate wie sie z.B. in der GB-A-2 141 754 genannt sind, wie Natriumpentadecylsulfonat oder Sulfobernsteinsäuredioctylether und besonders die C₉-C₁₅-Alkylbenzolsulfonate;. Alkyl sulfonates as e.g. are mentioned in GB-A-2 141 754, such as sodium pentadecyl sulfonate or sulfosuccinic acid dioctyl ether and especially the C₉-C₁ Alkyl alkylbenzenesulfonates;
- . Alkylphosphonate oder Alkylpolyphosphonate wie sie z.B. in der US-A-4 321 165 beschrieben werden.. Alkyl phosphonates or alkyl polyphosphonates such as e.g. in US-A-4,321,165.
Nichtionische Tenside sind z.B. Polyhydroxyfettsäureamide, wie sie in der WO 92/06172 beschrieben sind und Alkylphenole. Desweiteren kommen noch Alkylpolyglucoside von C₉-C₁₅-Alkylen mit 1-10 Glucosideinheiten wie z.B. Nonylglucosid und Allyl(C₁₂-C₁₅)-poly(1-10)-glucosid, Sorbinanester wie z.B. Polyoxyethylensorbitanmonopalmitat, Fettsäureethanolamide wie z.B. Kokosfettsäurediethanolamid und Fettsäureethanolaminoxide wie z.B. Tetradecylaminoxid in Frage.Nonionic surfactants are e.g. Polyhydroxy fatty acid amides as described in WO 92/06172 and alkylphenols. Furthermore, there are alkyl polyglucosides of C₉-C₁ Alk alkylene with 1-10 glucoside units such as Nonyl glucoside and allyl (C₁₂-C₁₅) poly (1-10) glucoside, sorbine esters such as e.g. Polyoxyethylene sorbitan monopalmitate, fatty acid ethanolamides such as e.g. Coconut fatty acid diethanolamide and fatty acid ethanolamine oxides such as Tetradecylamine oxide in question.
Die Ethoxylierungsprodukte erhält man beispielesweise durch Kondensation von Ethylenoxid und/oder Propylenoxid mit einem Kohlenwasserstoff, der ein aktives Wasserstoffatom trägt, so z.B.:
- . einem niedermolekularen, aliphatischen Polyol,
- . einem gesättigten und/oder ungesättigten Fettalkohol mit 8 bis 22 C-Atomen, einem Alkylphenol mit 4 bis 12 C-Atomen im Alkylrest,
- . einem Hydroxybiphenyl,
- . einem gesättigten und/oder ungesättigten Fettamin mit 8 bis 22 C-Atomen,
- . einer gesättigten und/oder ungesättigten Fettsäure mit 8 bis 22 C-Atomen, oder
- . einem gesättigten und/oder ungesättigten Fettsäure-(N,N-bis-hydroxyalkyl)amid,
wobei auf 1 Mol der genannten Verbindungen vorzugsweise 3 bis 100 Mol Ethylenoxid und/oder Propylenoxid kommen. Als Beispiele seien die Alkoholethoxylate genannt. Es können aber auch Gemische dieser Umsetzungsprodukte untereinander verwendet werden. Diese Gemische erhält man durch Mischen der einzelnen Umsetzungsprodukte oder direkt durch Ethoxylierung eines Gemisches der den Umsetzungsprodukten zugrundeliegenden Verbindungen.The ethoxylation products are obtained, for example, by condensing ethylene oxide and / or propylene oxide with a hydrocarbon which carries an active hydrogen atom, for example:
- . a low molecular weight, aliphatic polyol,
- . a saturated and / or unsaturated fatty alcohol with 8 to 22 carbon atoms, an alkylphenol with 4 to 12 carbon atoms in the alkyl radical,
- . a hydroxybiphenyl,
- . a saturated and / or unsaturated fatty amine with 8 to 22 carbon atoms,
- . a saturated and / or unsaturated fatty acid with 8 to 22 carbon atoms, or
- . a saturated and / or unsaturated fatty acid (N, N-bis-hydroxyalkyl) amide,
wherein for 1 mole of the compounds mentioned there are preferably 3 to 100 moles of ethylene oxide and / or propylene oxide. Examples include the alcohol ethoxylates. Mixtures of these reaction products with one another can also be used. These mixtures are obtained by mixing the individual reaction products or directly by ethoxylating a mixture of the compounds on which the reaction products are based.
Als Waschmittelaufbaustoffe oder Polymere kommen z.B. die in der US-4 321 165 und US-4 284 532 erwähnten vorzugsweise polycarboxylierten Verbindungen wie zum Beispiel Zitronensäure oder Maleinsäure/Acrylsäure-Copolymere, sowie z.B. die Ligninsulfonate, Formaldehydadditionsprodukte, Polyethylenglykole, Polyvinylpyrolidone, Polyvinylimidazole, und Al/Mg-Silikate in Betracht.Detergent builders or polymers include e.g. the preferably polycarboxylated compounds mentioned in U.S. 4,321,165 and U.S. 4,284,532 such as citric acid or maleic acid / acrylic acid copolymers, as well as e.g. the lignin sulfonates, formaldehyde addition products, polyethylene glycols, polyvinylpyrolidones, polyvinylimidazoles, and Al / Mg silicates.
Zwitterionische Tenside sind z.B. Aminocarbonsäuren und Alkylaminoxide.Zwitterionic surfactants are e.g. Aminocarboxylic acids and alkylamine oxides.
Kationische Tenside sind z.B. quaternäre Ammonium oder Aminverbindungen.Cationic surfactants are e.g. quaternary ammonium or amine compounds.
Weiterhin kann die Formulierung 1 bis 10 % übliche Waschmittelzusätze wie zum Beispiel Enzyme, Enzymstabilisatoren, Antioxidantien, Konservierungs- und Desinfektionsmittel, Emulgatoren, Verdicker, Schaumregulatoren, Stabilisatoren, Antiredepositionsmittel, Duft- und Farbstoffe, Komplexbildner bzw. Sequestriermittel und Lösungsmittel enthalten.Furthermore, the formulation can contain 1 to 10% of common detergent additives such as, for example, enzymes, enzyme stabilizers, antioxidants, preservatives and disinfectants, emulsifiers, thickeners, foam regulators, stabilizers, antiredeposition agents, fragrances and colorants, complexing agents or sequestering agents and solvents.
Als Salze können z.B. Formiate, Acetate und Natriumchlorid verwendet werden.As salts, e.g. Formates, acetates and sodium chloride can be used.
Gezielt sulfonierte Dibenzofuranylbiphenyle enthaltende flüssige Waschmittel können auch, wie z.B. auch in EP-A-293 040 beschrieben, bis zu 20 Gew.% eines oder mehrerer Bleichmittel wie Phthalocyanine, Persäuren wie Perborate oder Diperoxydicarbonsäuren, oder Persäureprecursor sowie Persäureaktivatoren oder Persäurekatalysatoren enthalten.Targeted liquid detergents containing sulfonated dibenzofuranylbiphenyls can also be used e.g. also described in EP-A-293 040, contain up to 20% by weight of one or more bleaching agents such as phthalocyanines, peracids such as perborates or diperoxydicarboxylic acids, or peracid precursors and peracid activators or peracid catalysts.
Hergestellt wird die Formulierung indem man die Komponenten unter Rühren vermischt.The formulation is produced by mixing the components with stirring.
Die so erhaltene Formulierung ist über Monate stabil und sedimentiert nicht.The formulation thus obtained is stable for months and does not sediment.
Die Herstellung der verwendeten optischen Aufheller wird z.B. in der EP-A-394 998 beschrieben.The manufacture of the optical brighteners used is e.g. in EP-A-394 998.
Die folgenden Beispiele dienen zur Erläuterung der Erfindung; Teile bedeuten Gewichtsteile und Prozente Gewichtsprozente; der Fleckentest wird folgendermassen durchgeführt:
- a) Aufheller/Waschmittel-Formulierung: 0,1 % (100 % Aktivsubstanz) optischer Aufheller oder Aufhellergemisch werden in einem flüssigen Waschmittel gelöst. 7,5 g dieses Aufheller enthaltenden Waschmittels (A) werden mit Wasser (10°-12° dH) bei einer Temperatur von 30°C auf 1000 ml verdünnt (Waschflotte B).
- b) Ein 20 g Stück gebleichtes Baumwollgewebe wird auf einem Spannrahmen befestigt.
- c) Auf eine vormarkierte, runde Fläche (5 cm Durchmesser) dieses Baumwollgewebes werden mit einer Pipette 0,6 ml der Waschmittellösung (A) gleichmässig aufgetragen, nach 30 Sekunden Einwirkzeit in die vorbereitete Waschflotte (B) gegeben und während 15 Minuten bei 60°C gewaschen. Anschliessend wird mit kaltem Wasser gespült und bei 70°C getrocknet.
- d) Der Unterschied des Weissgrades nach Ganz zwischen der Auftragsfläche und der Umgebung ist ein Mass für das sogenannte Spotting-Verhalten (Bildung von hellen Flecken) und wird bei einfacher Textillage mit einem RFC3-Photometer von Zeiss bestimmt.
- a) Brightener / detergent formulation: 0.1% (100% active substance) optical brightener or brightener mixture are dissolved in a liquid detergent. 7.5 g of this detergent (A) containing brightener are diluted with water (10 ° -12 ° dH) at a temperature of 30 ° C to 1000 ml (wash liquor B).
- b) A 20 g piece of bleached cotton fabric is attached to a tenter.
- c) 0.6 ml of the detergent solution (A) are evenly applied to a pre-marked, round surface (5 cm in diameter) of this cotton fabric, added to the prepared wash liquor (B) after 30 seconds of exposure and for 15 minutes at 60 ° C washed. It is then rinsed with cold water and dried at 70 ° C.
- d) The difference in whiteness according to Ganz between the application area and the surroundings is a measure of the so-called spotting behavior (formation of light spots) and is determined with a simple textile layer using an RFC3 photometer from Zeiss.
Bei 60°C werden die folgenden Bestandteile unter Rühren bei 60°C vermischt :
- 40
- Teile C₁₂-C₁₅ Polyethoxyfettalkohol (7 EO)
- 15
- Teile Polyethylenglykol 200
- 10
- Teile Ethanol
- 5
- Teile Propandiol
- 3,9
- Teile Triacetin
- 5
- Teile Triethanolamin
- 5
- Teile Phosphonat
- 16
- Teile Wasser deion.
und 0,1 Teile des optischen Aufhellers der Formel (2)
- 40
- Parts of C₁₂-C₁₅ polyethoxy fatty alcohol (7 EO)
- 15
- Parts of polyethylene glycol 200
- 10th
- Parts of ethanol
- 5
- Parts of propanediol
- 3.9
- Share triacetin
- 5
- Parts of triethanolamine
- 5
- Parts of phosphonate
- 16
- Parts of water deion.
and 0.1 part of the optical brightener of formula (2)
Man erhält ein leicht trübes, lagerstabiles Waschmittel.A slightly cloudy, storage-stable detergent is obtained.
Wie Beispiel 1, mit dem Unterschied, das ein optischer Aufheller der Formel (3)
verwendet wird.As example 1, with the difference that an optical brightener of the formula (3)
is used.
Die in den Beispielen 1 und 2 erhaltenen Waschmittel werden in einer Konzentration von 7,5 g/l zum Waschen von gebleichter Baumwolle bei 60°C verwendet. Es werden dabei nach dem Spülen und Trocknen jeweils hohe Weissgrade bei einer vernachlässigbaren Fleckenbildung erzielt.The detergents obtained in Examples 1 and 2 are used in a concentration of 7.5 g / l for washing bleached cotton at 60 ° C. After rinsing and drying, high degrees of whiteness are achieved with negligible stain formation.
Claims (19)
R₁, R₂, R₃, R₄ und R₅ unabhängig voneinander ein Sulfonsäurerest, Wasserstoff, C₁-C₄-Alkyl, C₁-C₄-Alkoxy, Halogen, CN, Phenoxy oder Benzyloxy, mit der Bedingung, dass nur einer der Reste R₁ bis R₅ ein Sulfonsäurerest ist, bedeuten,
R₁, R₂, R₃, R₄ and R₅ independently of one another are a sulfonic acid residue, hydrogen, C₁-C₄-alkyl, C₁-C₄-alkoxy, halogen, CN, phenoxy or benzyloxy, with the condition that only one of the residues R₁ to R₅ is a sulfonic acid residue is mean
R₁ = SO₃M;
M = Wasserstoff oder ein nichtchromophores Kation; und
R₂, R₃, R₄ und R₅ unabhängig voneinander Wasserstoff,
C₁-C₄-Alkyl, C₁-C₄-Alkoxy, Halogen, CN, Phenoxy oder Benzyloxy bedeuten.Liquid detergent according to claim 1, characterized in that it contains an optical brightener of the formula (1), in which
R₁ = SO₃M;
M = hydrogen or a non-chromophoric cation; and
R₂, R₃, R₄ and R₅ are independently hydrogen,
C₁-C₄ alkyl, C₁-C₄ alkoxy, halogen, CN, phenoxy or benzyloxy mean.
gekennzeichnet, dass es einen optischen
Aufheller der Formel (1) enthält, worin
R₁ = SO₃M;
M = Wasserstoff oder ein nichtchromophores Kation; und
R₂, R₃, R₄ und R₅ unabhängig voneinander Wasserstoff, Methyl, Aethyl, iso-Propyl, t-Butyl, Methoxy, Chlor, CN, Phenoxy oder Benzyloxy bedeuten.Liquid detergent according to claim 2, characterized
characterized that there is an optical
Contains brightener of formula (1), wherein
R₁ = SO₃M;
M = hydrogen or a non-chromophoric cation; and
R₂, R₃, R₄ and R₅ independently represent hydrogen, methyl, ethyl, isopropyl, t-butyl, methoxy, chlorine, CN, phenoxy or benzyloxy.
gekennzeichnet, dass es einen optischen
Aufheller der Formel (1) enthält, worin
R₁=SO₃M;
M = Wasserstoff oder ein nichtchromophores Kation; und
R₂, R₃, R₄ und R₅ unabhängig voneinander Wasserstoff, Methyl, Aethyl, iso-Propyl, t-Butyl oder Chlor bedeuten.Liquid detergent according to claim 3, characterized
characterized that there is an optical
Contains brightener of formula (1), wherein
R₁ = SO₃M;
M = hydrogen or a non-chromophoric cation; and
R₂, R₃, R₄ and R₅ independently represent hydrogen, methyl, ethyl, iso-propyl, t-butyl or chlorine.
R₁ = Wasserstoff, C₁-C₄-Alkyl, C₁-C₄-Alkoxy, Halogen, CN,
Phenoxy oder Benzyloxy;
R₂, R₃, R₄ und R₅ unabhängig voneinander SO₃M, Wasserstoff, C₁-C₄-Alkyl, C₁-C₄-Alkoxy, Halogen, CN, Phenoxy oder Benzyloxy, mit der Bedingung, dass nur einer der Reste R₂ bis R₅ SO₃M ist; und
M = Wasserstoff oder ein nichtchromophores Kation bedeuten.Liquid detergent according to claim 1, characterized in that it contains an optical brightener of the formula (1), in which
R₁ = hydrogen, C₁-C₄-alkyl, C₁-C₄-alkoxy, halogen, CN,
Phenoxy or benzyloxy;
R₂, R₃, R₄ and R₅ are independently SO₃M, hydrogen, C₁-C-alkyl, C₁-C₄ alkoxy, halogen, CN, phenoxy or benzyloxy, with the condition that only one of the radicals R₂ to R₅ is SO₃M; and
M = hydrogen or a non-chromophoric cation.
R₄=SO₃M
R₁, R₂, R₃ und R₅ unabhängig voneinander Wasserstoff, C₁-C₄-Alkyl, C₁-C₄-Alkoxy, Halogen, CN, Phenoxy oder Benzyloxy; und
M = Wasserstoff oder ein nichtchromophores Kation bedeuten.Liquid detergent according to claim 1, characterized in that it contains an optical brightener of the formula (1), in which
R₄ = SO₃M
R₁, R₂, R₃ and R₅ independently of one another hydrogen, C₁-C₄-alkyl, C₁-C₄-alkoxy, halogen, CN, phenoxy or benzyloxy; and
M = hydrogen or a non-chromophoric cation.
R₄=SO₃M
R₁, R₂, R₃ und R₅ unabhängig voneinander Wasserstoff, Methyl, Aethyl, iso-Propyl, t-Butyl, Methoxy, Chlor, CN, Phenoxy oder Benzyloxy; und
M = Wasserstoff oder ein nichtchromophores Kation bedeuten.Liquid detergent according to claim 6, characterized in that it contains an optical brightener of the formula (1), in which
R₄ = SO₃M
R₁, R₂, R₃ and R₅ independently of one another hydrogen, methyl, ethyl, isopropyl, t-butyl, methoxy, chlorine, CN, Phenoxy or benzyloxy; and
M = hydrogen or a non-chromophoric cation.
R₄=SO₃M R₁, R₂, R₃ und R₅ unabhängig voneinander Wasserstoff, Methyl, Aethyl, iso-Propyl, t-Butyl oder Chlor; und
M = Wasserstoff oder ein nichtchromophores Kation bedeuten.Liquid detergent according to claim 7, characterized in that it contains an optical brightener of the formula (1), in which
R₄ = SO₃M R₁, R₂, R₃ and R₅ independently of one another hydrogen, methyl, ethyl, iso-propyl, t-butyl or chlorine; and
M = hydrogen or a non-chromophoric cation.
R₂ = SO₃M;
R₁, R₃, R₄ und R₅ unabhängig voneinander Wasserstoff, C₁-C₄-Alkyl, C₁-C₄-Alkoxy, Halogen, CN, Phenoxy oder Benzyloxy; und
M = Wasserstoff oder ein nichtchromophores Kation bedeuten.Liquid detergent according to claim 1, characterized in that it contains an optical brightener of the formula (1), in which
R₂ = SO₃M;
R₁, R₃, R₄ and R₅ independently of one another are hydrogen, C₁-C₄-alkyl, C₁-C₄-alkoxy, halogen, CN, phenoxy or benzyloxy; and
M = hydrogen or a non-chromophoric cation.
R₂=SO₃M;
R₁, R₃, R₄ und R₅ unabhängig voneinander Wasserstoff, Methyl, Aethyl, iso-Propyl, t-Butyl, Methoxy, Chlor, CN, Phenoxy oder Benzyloxy; und
M = Wasserstoff oder ein nichtchromophores Kation bedeuten.Liquid detergent according to claim 9, characterized in that it contains an optical brightener of the formula (1), in which
R₂ = SO₃M;
R₁, R₃, R₄ and R₅ independently of one another are hydrogen, methyl, ethyl, isopropyl, t-butyl, methoxy, chlorine, CN, phenoxy or benzyloxy; and
M = hydrogen or a non-chromophoric cation.
R₂=SO₃M;
R₁, R₃, R₄ und R₅ unabhängig voneinander Wasserstoff, Methyl, Aethyl, iso-Propyl, t-Butyl oder Chlor; und
M = Wasserstoff oder ein nichtchromophores Kation bedeuten.Liquid detergent according to claim 10, characterized in that it contains an optical brightener of the formula (1), in which
R₂ = SO₃M;
R₁, R₃, R₄ and R₅ independently of one another are hydrogen, methyl, ethyl, isopropyl, t-butyl or chlorine; and
M = hydrogen or a non-chromophoric cation.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH3528/92A CH684485A5 (en) | 1992-11-17 | 1992-11-17 | Liquid detergent. |
| CH3528/92 | 1992-11-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0601967A1 true EP0601967A1 (en) | 1994-06-15 |
| EP0601967B1 EP0601967B1 (en) | 1996-10-09 |
Family
ID=4257953
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP93810772A Expired - Lifetime EP0601967B1 (en) | 1992-11-17 | 1993-11-09 | Liquid detergent composition |
| EP94901548A Expired - Lifetime EP0672099B1 (en) | 1992-11-17 | 1993-11-16 | Stable liquid detergent compositions inhibiting dye transfer |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP94901548A Expired - Lifetime EP0672099B1 (en) | 1992-11-17 | 1993-11-16 | Stable liquid detergent compositions inhibiting dye transfer |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5468884A (en) |
| EP (2) | EP0601967B1 (en) |
| JP (2) | JPH08503509A (en) |
| KR (1) | KR940011622A (en) |
| AU (2) | AU664123B2 (en) |
| BR (1) | BR9304741A (en) |
| CA (1) | CA2103097A1 (en) |
| CH (1) | CH684485A5 (en) |
| DE (2) | DE59304117D1 (en) |
| ES (1) | ES2092800T3 (en) |
| MX (1) | MX9307033A (en) |
| TW (1) | TW237475B (en) |
| WO (1) | WO1994011480A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999027059A1 (en) * | 1997-11-22 | 1999-06-03 | Henkel-Ecolab Gmbh & Co. Ohg | Washing method and preparation for carrying out the same |
| EP2711413B2 (en) † | 2012-09-25 | 2022-04-13 | Miele & Cie. KG | Washing agent and method for metering a washing agent |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH684485A5 (en) * | 1992-11-17 | 1994-09-30 | Ciba Geigy Ag | Liquid detergent. |
| US5776878A (en) * | 1994-01-13 | 1998-07-07 | The Procter & Gamble Company | Liquid detergent compositions containing brighteners and polymers for preventing fabric spotting |
| CN1145093A (en) * | 1994-03-30 | 1997-03-12 | 普罗格特-甘布尔公司 | Laundry detergent bars with improved whitening and dye transfer inhibition |
| GB9409465D0 (en) * | 1994-05-12 | 1994-06-29 | Ciba Geigy Ag | Protective use |
| ES2225833T3 (en) * | 1994-05-12 | 2005-03-16 | Ciba Specialty Chemicals Holding Inc. | TEXTILE TREATMENT |
| US5922083A (en) * | 1995-04-03 | 1999-07-13 | Procter & Gamble Company | Detergent composition comprising a mutant amylase enzyme and oxygen bleaching agent |
| EP0736594A1 (en) * | 1995-04-03 | 1996-10-09 | The Procter & Gamble Company | Soaker compositions |
| EP0756001A1 (en) * | 1995-07-24 | 1997-01-29 | The Procter & Gamble Company | Detergent compositions comprising specific amylase and a specific surfactant system |
| JP5396707B2 (en) * | 2007-11-07 | 2014-01-22 | ライオンハイジーン株式会社 | Cleaning composition |
| BR112017019942A2 (en) | 2015-04-02 | 2018-06-12 | Unilever Nv | liquid laundry detergent composition and polymer release for dirt release |
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| DE3900651A1 (en) * | 1988-01-14 | 1989-07-27 | Ciba Geigy Ag | Stable bleaching composition containing optical brighteners |
| EP0364027A2 (en) * | 1988-10-14 | 1990-04-18 | Unilever N.V. | Bleaching and detergent composition |
| EP0394998A2 (en) * | 1989-04-28 | 1990-10-31 | Ciba-Geigy Ag | Liquid detergent |
| EP0548019A2 (en) * | 1991-12-19 | 1993-06-23 | Ciba-Geigy Ag | Storage-stable bleach dispersion |
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-
1993
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- 1993-11-09 EP EP93810772A patent/EP0601967B1/en not_active Expired - Lifetime
- 1993-11-09 DE DE59304117T patent/DE59304117D1/en not_active Expired - Fee Related
- 1993-11-09 ES ES93810772T patent/ES2092800T3/en not_active Expired - Lifetime
- 1993-11-11 MX MX9307033A patent/MX9307033A/en not_active IP Right Cessation
- 1993-11-12 US US08/152,331 patent/US5468884A/en not_active Expired - Fee Related
- 1993-11-15 KR KR1019930024178A patent/KR940011622A/en not_active Application Discontinuation
- 1993-11-15 CA CA002103097A patent/CA2103097A1/en not_active Abandoned
- 1993-11-16 AU AU50741/93A patent/AU664123B2/en not_active Ceased
- 1993-11-16 WO PCT/US1993/011141 patent/WO1994011480A1/en active IP Right Grant
- 1993-11-16 DE DE69309488T patent/DE69309488T2/en not_active Expired - Fee Related
- 1993-11-16 BR BR9304741A patent/BR9304741A/en not_active Application Discontinuation
- 1993-11-16 AU AU56097/94A patent/AU5609794A/en not_active Abandoned
- 1993-11-16 EP EP94901548A patent/EP0672099B1/en not_active Expired - Lifetime
- 1993-11-16 JP JP6512469A patent/JPH08503509A/en active Pending
- 1993-11-17 JP JP5287141A patent/JPH06200292A/en active Pending
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| US4002423A (en) * | 1971-08-13 | 1977-01-11 | Hoechst Aktiengesellschaft | Benzofuran derivatives process for their preparation and their use as optical brighteners |
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| EP2711413B2 (en) † | 2012-09-25 | 2022-04-13 | Miele & Cie. KG | Washing agent and method for metering a washing agent |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0601967B1 (en) | 1996-10-09 |
| ES2092800T3 (en) | 1996-12-01 |
| TW237475B (en) | 1995-01-01 |
| KR940011622A (en) | 1994-06-21 |
| DE69309488D1 (en) | 1997-05-07 |
| AU664123B2 (en) | 1995-11-02 |
| WO1994011480A1 (en) | 1994-05-26 |
| EP0672099A4 (en) | 1995-08-03 |
| DE69309488T2 (en) | 1997-11-06 |
| AU5609794A (en) | 1994-06-08 |
| JPH08503509A (en) | 1996-04-16 |
| JPH06200292A (en) | 1994-07-19 |
| MX9307033A (en) | 1994-06-30 |
| CH684485A5 (en) | 1994-09-30 |
| CA2103097A1 (en) | 1994-05-18 |
| EP0672099B1 (en) | 1997-04-02 |
| EP0672099A1 (en) | 1995-09-20 |
| DE59304117D1 (en) | 1996-11-14 |
| AU5074193A (en) | 1994-06-02 |
| BR9304741A (en) | 1994-07-05 |
| US5468884A (en) | 1995-11-21 |
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