EP0576778A1 - Konzentriertes, wässeriges, flüssiges Reinigungsmittel - Google Patents
Konzentriertes, wässeriges, flüssiges Reinigungsmittel Download PDFInfo
- Publication number
- EP0576778A1 EP0576778A1 EP92870098A EP92870098A EP0576778A1 EP 0576778 A1 EP0576778 A1 EP 0576778A1 EP 92870098 A EP92870098 A EP 92870098A EP 92870098 A EP92870098 A EP 92870098A EP 0576778 A1 EP0576778 A1 EP 0576778A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- alkyl
- composition according
- liquid detergent
- anionic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
Definitions
- the present invention relates to concentrated aqueous liquid detergent compositions containing polyvinylpyrrolidone, in which the anionic surfactant majorily consists of an alkyl ethoxy sulfate salt.
- a new trend in the field of detergent compositions is the formulation of so-called concentrated detergents.
- concentrated detergents In the context of liquid aqueous detergents, this refers to products comprising less water and a higher total amount of active ingredients.
- the present invention is directed to liquid detergent compositions comprising an anionic surface-active agent, and from 2% to 35% by weight of the total composition of water, characterized in that the anionic surfactant contains at least 70%, preferably from 75% to 100% by weight of a water-soluble C11 ⁇ 15 alkyl ethoxy sulfate salt containing an average per mole of from 1 to 9 ethoxy groups and that the composition comprises from 0.05% to 5% by weight of the total composition of polyvinylpyrrolidone.
- compositions preferably contain less than 6% by weight of the total composition of alkyl benzene sulfonate salt or non-ethoxylated alkyl sulfate salt.
- compositions according to the present invention are concentrated liquid detergents which comprise from 2% to 35% by weight of the total composition of water.
- compositions according to the present invention comprise from 5% to 25% by weight of the total composition of water.
- compositions according to the invention contain from 0.05% to 5% by weight of polyvinlypyrrolidone, preferably from 0.25% to 2%.
- Preferred polyvinylpyrrolidone for use herein have a molecular weight of from 1000 to 100,000, preferably from 2500 to 30,000, most preferably from 5000 to 15,000.
- compositions according to the present invention comprise a surfactant, and in particular an anionic surface active agent.
- the anionic surfactant (hereafter meant as not including soaps) contains at least 70% by weight of said anionic surfactant, of a water soluble C11 ⁇ 15 alkyl ethoxy sulfate salt containing an average of from 1 to 9 ethoxy groups per mole.
- the C11-C15 alkyl ethoxy sulfate salt herein comprises a primary alkyl ethoxy sulfate derived from the condensation product of a C11-C15 alcohol with an average of up to 9 ethylene oxide groups.
- C13-C15 alkyl ethoxy sulfate with an average of two to three ethoxy groups per mole is preferred.
- the C11-C15 alcohol itself can be obtained from natural or synthetic sources.
- C11-C15 alcohols derived from natural fats, or Ziegler olefin build-up, or OXO synthesis can form suitalbe sources for the alkyl group.
- synthetically derived materials include Dobanol 23 (RTM) sold by Shell Chemicals (UK) Ltd., Ethyl 24 sold by the Ethyl Corporation, a blend of C13-C15 alcohols in the ratio 67% C 13, 33% C15 sold under the trade name Lutensol by BASF GmbH and Synperonic (RTM) by ICI Ltd., and Lial 125 sold by Liquichimica Italiana.
- Naturally occurring materials from which the alcohols can be derived are coconut oil and palm kernel oil and the corresponding fatty acids.
- the alkyl ethoxy sulfate salts are preferably present in the compositions herein at levels of from 75% to 100% by weight of the anionic surfactant system.
- the anionic surfactant system may contain other types of surface-active agents, although in minor quantities; in particular, the present detergent compositions should contain less than 6% by weight of the total composition of alkyl benzene sulfonates and non-ethoxylated alkyl sulfates such as C12 ⁇ 14 primary alkyl sulfate salts;
- Other anionic co-surfactants which may be present in minor quantities in the present compositions include C12-C18 s-alkane sulfonates and alpha-sulphonated methyl fatty acid esters in which the fatty acid is derived from a C12-C18 fatty source.
- Suitable co-anionic surfactants suitable for the compositions herein are the alkali metal sarcosinates of formula R-CON (R) CH2COOM wherein R is a C9-C17 linear or branched alkyl or alkenyl group, R' is a C1-C4 alkyl group and M is an alkali metal ion.
- R is a C9-C17 linear or branched alkyl or alkenyl group
- R' is a C1-C4 alkyl group
- M is an alkali metal ion.
- Preferred examples are the lauroyl, Cocoyl (C12-C14), myristyl and oleyl methyl sarcosinates in the form of their sodium salts.
- compositions preferably also contain a nonionic surfactant in combination with the alkyl ethoxy sulfate salts herein;
- Preferred nonionic surfactants for use herein are polyhydroxy fatty acid amides of the formula wherein R1 is H, C1 ⁇ 4 hydrocarbyl, 2-hydroxy ethyl, 2-hydroxy propyl or a mixture thereof, R2 is C5 ⁇ 31 hydrocarbyl, and Z is a polyhydroxyhydrocarbyl having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain, or an alkoxylated derivative thereof.
- R1 is methyl
- R2 is a straight C11 ⁇ 15 alkyl or alkenyl chain or mixtures thereof
- Z is derived from a reducing sugar such as glucose, fructose, maltose, lactose, in a reductive amination reaction.
- a reducing sugar such as glucose, fructose, maltose, lactose, in a reductive amination reaction.
- Nonionic surfactants suitable for use herein include those produced by condensing ethylene oxide with a hydrocarbon having a reactive hydrogen atom, e.g., a hydroxyl, carboxyl, or amido group, in the presence of an acidic or basic catalyst, and include compounds having the general formula RA(CH2CH20)nH wherein R represents the hydrophobic moiety, A represents the group carrying the reactive hydrogen atom and n represents the average number of ethylene oxide moieties. R typically contains from about 8 to 22 carbon atoms. They can also be formed by the condensation of propylene oxide with a lower molecular weight compound. n usually varies from about 2 to about 24.
- a preferred class of such nonionic ethoxylates is represented by the condensation product of a fatty alcohol having from 12 to 15 carbon atoms and from about 4 to 10 moles of ethylene oxide per mole or fatty alcohol.
- Suitable species of this class of ethoxylates include : the condensation product of C12-C15 oxo-alcohols and 3 to 9 moles of ethylene oxide per mole of alcohol; the condensation product or narrow cut C14-C15 oxo-alcohols and 3 to 9 moles of ethylene oxide per mole of fatty(oxo)alcohol; the condensation product of a narrow cut C12-C13 fatty(oxo)alcohol and 6,5 moles of ethylene oxide per mole of fatty alcohol; and the condensation products of a C10-C14 coconut fatty alcohol with a degree of ethoxylation (moles EO/mole fatty alcohol) in the range from 4 to 8.
- the fatty oxo alcohols while mainly linear can have, depending upon the processing conditions and raw material olefins, a certain degree of branching, particularly short chain such as methyl branching.
- a degree of branching in the range from 15% to 50% (weight%) is frequently found in commercial oxo alcohols.
- Nonionic surfactants comprises alkyl polyglucoside compounds of general formula RO(C n H 2n O) t Z x wherein Z is a moiety derived from glucose; R is a saturated hydrophobic alkyl group that contains from 12 to 18 carbon atoms; t is from 0 to 10 and n is 2 or 3; x is from 1.3 to 4, the compounds including less than 10% unreacted fatty alcohol and less than 50% short chain alkyl polyglucosides.
- Compounds of this type and their use in detergent compositions are disclosed in EP-B 0 070 074, 0 070 077, 0 075 996 and 0 094 118.
- the surfactant system herein may also contain types of surfactants other than anionic and nonionic species.
- Suitable cationic surfactants include quaternary ammonium compounds of the formula R1R2R3R4N+ where R1, R2 and R3 are methyl groups, and R4 is a C12 ⁇ 15 alkyl group, or where R1 is an ethyl or hydroxy ethyl group, R2 and R3 are methyl groups and R4 is a C12 ⁇ 15 alkyl group.
- Zwitterionic surfactants include derivatives of aliphatic quaternary ammonium, phosphonium, and sulfonium compounds in which the aliphatic moiety can be straight or branched chain and wherein one of the aliphatic substituents contains from about 8 to about 24 carbon atoms and another substituent contains, at least, an anionic water-solubilizing group.
- Particularly preferred zwitterionic materials are the ethoxylated ammonium sulfonates and sulfates disclosed in U.S. Patents 3,925,262, Laughlin et al., issued December 9, 1975 and 3,929,678, Laughlin et al., issued December 30, 1975.
- Semi-polar nonionic surfactants include water-soluble amine oxides containing one alkyl or hydroxy alkyl moiety of from about 8 to about 28 carbon atoms and two moieties selected from the group consisting of alkyl groups and hydroxy alkyl groups, containing from 1 to about 3 carbon atoms which can optionally be joined into ring structures.
- the present concentrated detergent compositions typically contain from 25% to 45%, preferably 30% to 40% by weight of surfactant of which the weight ratio of anionic surfactant to nonionic surfactant is typically of 3:1 to 1:1, more preferably 2:1 to 1:1.
- compositions according to the present invention may further comprise a builder.
- a builder Any conventional builder system is suitable for use herein including polycarboxylates and fatty acids, materials such as ethylenediamine tetraacetate, metal ion sequestrants such as aminopolyphosphonates, particularly ethylenediamine tetramethylene phosphonic acid and diethylene triamine pentamethylenephosphonic acid.
- phosphate builders can also be used herein.
- Suitable polycarboxylates builders for use herein include citric acid, preferably in the form of a water-soluble salt, derivatives of succinic acid of the formula R-CH(COOH)CH2(COOH) wherein R is C10 ⁇ 20 alkyl or alkenyl, preferably C12 ⁇ 16, or wherein R can be substituted with hydroxyl, sulfo sulfoxyl or sulfone substituents.
- Specific examples include lauryl succinate, myristyl succinate, palmityl succinate, 2-dodecenylsuccinate, 2-tetradecenyl succinate.
- Succinate builders are preferably used in the form of their water-soluble salts, including sodium, potassium, ammonium, and alkanolammonium salts.
- polycarboxylates are oxodisuccinates and mixtures of tartrate monosuccinic and tartrate disuccinic acid such as described in US 4,663,071.
- Suitable fatty acid builders for use herein are saturated or unsaturated C10 ⁇ 18 fatty acids, as well as the corresponding soaps.
- Preferred saturated species have from 12 to 16 carbon atoms in the alkyl chain.
- the preferred unsaturated fatty acid is oleic acid.
- a preferred builder system for use herein consists of a mixture of citric acid, fatty acids and succinic acid derivatives described hereinabove.
- the builder system according to the present invention preferably represents from 5% to 35% by weight of the total composition.
- compositions according to the invention preferably comprise enzymes.
- Suitable enzymes for use herein are protease, lipases, cellulases, and amylases and mixtures thereof.
- compositions according to the present invention may still advantageously comprise an enzyme stabilizing system, although at reduced levels as compared to compositions where alkyl benzene sulfonate and/or non-ethoxylated alkyl sulfate salts are present in majority.
- Any conventional enzyme stabilizing system is suitable for use herein, and preferred enzyme stabilizing systems are based on boric acid or derivatives thereof, 1,2-propanediol, carboxylic acids such as formic acid/formate, and mixtures thereof.
- anionic surfactant system of the present invention provides improved stability of enzymes such as cellulase in presence of a protease.
- compositions herein can also advantageously contain a terphtalate-based soil release polymer at levels of from 0.05% to 2% of the total composition.
- compositions herein can contain a series of fruther, optional ingredients.
- the like additives include solvents, alkanolamines, pH adjusting agents, suds regulants, opacifiers, agents to improve the machine compatibility in relation to enamel-coated surfaces, perfumes, dyes, bactericides, brighteners, softening agents and the like.
- compositions were prepared :
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP19920870098 EP0576778B1 (de) | 1992-07-03 | 1992-07-03 | Konzentriertes, wässeriges, flüssiges Reinigungsmittel |
PCT/US1993/006086 WO1994001520A1 (en) | 1992-07-03 | 1993-06-28 | Concentrated aqueous liquid detergent comprising polyvinylpyrrolidone |
CA 2139359 CA2139359A1 (en) | 1992-07-03 | 1993-06-28 | Concentrated aqueous liquid detergent comprising polyvinylpyrrolidone |
JP6503360A JPH07508788A (ja) | 1992-07-03 | 1993-06-28 | ポリビニルピロリドンを含む濃縮水性液体洗剤 |
TR00549/93A TR26910A (tr) | 1992-07-03 | 1993-06-30 | Konsantre, sulu sivi deterjan bilesimleri. |
IE930498A IE930498A1 (en) | 1992-07-03 | 1993-07-02 | Concentrated aqueous liquid detergent compositions. |
MX9304037A MX9304037A (es) | 1992-07-03 | 1993-07-05 | Composiciones detergentes liquidas, acuosas, concentradas. |
US08/699,175 US5723425A (en) | 1992-07-03 | 1996-08-19 | Concentrated aqueous liquid detergent comprising polyvinylpyrrolidone |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP19920870098 EP0576778B1 (de) | 1992-07-03 | 1992-07-03 | Konzentriertes, wässeriges, flüssiges Reinigungsmittel |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0576778A1 true EP0576778A1 (de) | 1994-01-05 |
EP0576778B1 EP0576778B1 (de) | 1998-02-04 |
Family
ID=8212258
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19920870098 Expired - Lifetime EP0576778B1 (de) | 1992-07-03 | 1992-07-03 | Konzentriertes, wässeriges, flüssiges Reinigungsmittel |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0576778B1 (de) |
JP (1) | JPH07508788A (de) |
CA (1) | CA2139359A1 (de) |
IE (1) | IE930498A1 (de) |
MX (1) | MX9304037A (de) |
TR (1) | TR26910A (de) |
WO (1) | WO1994001520A1 (de) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1995033025A1 (en) * | 1994-06-01 | 1995-12-07 | The Procter & Gamble Company | Oleoyl sarcosinate containing detergent compositions |
WO1995033026A1 (en) * | 1994-06-01 | 1995-12-07 | The Procter & Gamble Company | Dye transfer inhibiting compositions containing oleoyl sarcosinate |
WO1995033034A1 (en) * | 1994-06-01 | 1995-12-07 | The Procter & Gamble Company | Oleoyl sarcosinate with polyhydroxy fatty acid amides in cleaning products |
WO1995033030A1 (en) * | 1994-06-01 | 1995-12-07 | The Procter & Gamble Company | Liquid detergent composition containing oleoyl sarcosinates and anionic surfactants |
WO1997004064A1 (en) * | 1995-07-20 | 1997-02-06 | Colgate-Palmolive Company | Liquid cleaning compositions |
EP0781837A1 (de) * | 1995-12-29 | 1997-07-02 | Colgate-Palmolive Company | Waschmittelzusammensetzung mit verbesserter Reinigungsleistung |
DE19626338A1 (de) * | 1996-07-01 | 1998-01-08 | Vorwerk Co Interholding | Teppich-Fleckentfernungsmittel |
US5723425A (en) * | 1992-07-03 | 1998-03-03 | Cauwberghs; Serge Gabriel Pierre | Concentrated aqueous liquid detergent comprising polyvinylpyrrolidone |
US5880081A (en) * | 1997-04-07 | 1999-03-09 | Gopalkrishnan; Sridhar | Concentrated built liquid detergents containing a dye-transfer inhibiting additive |
WO1999033942A1 (en) * | 1997-12-29 | 1999-07-08 | Colgate-Palmolive Company | Detergent composition having improved cleaning power |
WO1999033941A1 (en) * | 1997-12-29 | 1999-07-08 | Colgate-Palmolive Company | Detergent composition having improved cleaning power |
EP0763086B1 (de) * | 1994-06-01 | 1999-12-08 | The Procter & Gamble Company | Waschmittelzusammensetzungen mit oleoylsarcosinate und polymeres dispergiermittel |
WO2011001173A1 (en) * | 2009-06-30 | 2011-01-06 | Reckitt Benckiser N.V. | Composition |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2287949A (en) * | 1994-03-31 | 1995-10-04 | Procter & Gamble | Laundry detergent composition |
US5935922A (en) * | 1994-03-31 | 1999-08-10 | The Procter & Gamble Company | Detergent composition containing zeolite map for washing a mixture of white and colored fabrics |
DE19601365A1 (de) * | 1996-01-16 | 1997-07-17 | Planttec Biotechnologie Gmbh | Nucleinsäuremoleküle aus Pflanzen codierend Enzyme, die an der Stärkesynthese beteiligt sind |
WO2007025549A1 (en) * | 2005-09-02 | 2007-03-08 | Novozymes A/S | Stabilization of concentrated liquid enzyme additives |
CA2910875C (en) | 2013-05-24 | 2018-11-06 | The Procter & Gamble Company | Low ph detergent composition |
CN105209587A (zh) | 2013-05-24 | 2015-12-30 | 宝洁公司 | 包含非离子表面活性剂的低ph洗涤剂组合物 |
BR112015028824A2 (pt) | 2013-05-24 | 2017-07-25 | Procter & Gamble | composição de tensoativo concentrada |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0013585A1 (de) * | 1979-01-12 | 1980-07-23 | Unilever N.V. | Milde flüssige Reinigungsmittelzusammensetzung |
EP0359491A2 (de) * | 1988-09-12 | 1990-03-21 | Unilever Plc | Flüssige Reinigungsmittel |
EP0372291A1 (de) * | 1988-11-28 | 1990-06-13 | Henkel Kommanditgesellschaft auf Aktien | Verfahren zum Waschen von verfärbungsempfindlichen Textilien |
EP0508034A1 (de) * | 1991-04-12 | 1992-10-14 | The Procter & Gamble Company | Polyvinylpyrrolidon enthaltendes Kompaktwaschmittel |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3860536A (en) * | 1970-01-02 | 1975-01-14 | Cpc International Inc | Enzyme-detergent combination |
US4304680A (en) * | 1973-02-05 | 1981-12-08 | Colgate-Palmolive Company | Laundry soap |
US3979339A (en) * | 1975-03-18 | 1976-09-07 | The Procter & Gamble Company | Hard surface cleaning compositions |
US4368146A (en) * | 1979-01-12 | 1983-01-11 | Lever Brothers Company | Light duty hand dishwashing liquid detergent composition |
GB8618635D0 (en) * | 1986-07-30 | 1986-09-10 | Unilever Plc | Detergent composition |
US4954292A (en) * | 1986-10-01 | 1990-09-04 | Lever Brothers Co. | Detergent composition containing PVP and process of using same |
-
1992
- 1992-07-03 EP EP19920870098 patent/EP0576778B1/de not_active Expired - Lifetime
-
1993
- 1993-06-28 CA CA 2139359 patent/CA2139359A1/en not_active Abandoned
- 1993-06-28 WO PCT/US1993/006086 patent/WO1994001520A1/en active Application Filing
- 1993-06-28 JP JP6503360A patent/JPH07508788A/ja active Pending
- 1993-06-30 TR TR00549/93A patent/TR26910A/xx unknown
- 1993-07-02 IE IE930498A patent/IE930498A1/en not_active IP Right Cessation
- 1993-07-05 MX MX9304037A patent/MX9304037A/es unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0013585A1 (de) * | 1979-01-12 | 1980-07-23 | Unilever N.V. | Milde flüssige Reinigungsmittelzusammensetzung |
EP0359491A2 (de) * | 1988-09-12 | 1990-03-21 | Unilever Plc | Flüssige Reinigungsmittel |
EP0372291A1 (de) * | 1988-11-28 | 1990-06-13 | Henkel Kommanditgesellschaft auf Aktien | Verfahren zum Waschen von verfärbungsempfindlichen Textilien |
EP0508034A1 (de) * | 1991-04-12 | 1992-10-14 | The Procter & Gamble Company | Polyvinylpyrrolidon enthaltendes Kompaktwaschmittel |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5723425A (en) * | 1992-07-03 | 1998-03-03 | Cauwberghs; Serge Gabriel Pierre | Concentrated aqueous liquid detergent comprising polyvinylpyrrolidone |
EP0763086B1 (de) * | 1994-06-01 | 1999-12-08 | The Procter & Gamble Company | Waschmittelzusammensetzungen mit oleoylsarcosinate und polymeres dispergiermittel |
WO1995033026A1 (en) * | 1994-06-01 | 1995-12-07 | The Procter & Gamble Company | Dye transfer inhibiting compositions containing oleoyl sarcosinate |
WO1995033034A1 (en) * | 1994-06-01 | 1995-12-07 | The Procter & Gamble Company | Oleoyl sarcosinate with polyhydroxy fatty acid amides in cleaning products |
WO1995033030A1 (en) * | 1994-06-01 | 1995-12-07 | The Procter & Gamble Company | Liquid detergent composition containing oleoyl sarcosinates and anionic surfactants |
WO1995033025A1 (en) * | 1994-06-01 | 1995-12-07 | The Procter & Gamble Company | Oleoyl sarcosinate containing detergent compositions |
WO1997004064A1 (en) * | 1995-07-20 | 1997-02-06 | Colgate-Palmolive Company | Liquid cleaning compositions |
AU722006B2 (en) * | 1995-07-20 | 2000-07-20 | Colgate-Palmolive Company, The | Liquid cleaning compositions |
EP0781837A1 (de) * | 1995-12-29 | 1997-07-02 | Colgate-Palmolive Company | Waschmittelzusammensetzung mit verbesserter Reinigungsleistung |
DE19626338A1 (de) * | 1996-07-01 | 1998-01-08 | Vorwerk Co Interholding | Teppich-Fleckentfernungsmittel |
US5880081A (en) * | 1997-04-07 | 1999-03-09 | Gopalkrishnan; Sridhar | Concentrated built liquid detergents containing a dye-transfer inhibiting additive |
WO1999033941A1 (en) * | 1997-12-29 | 1999-07-08 | Colgate-Palmolive Company | Detergent composition having improved cleaning power |
WO1999033942A1 (en) * | 1997-12-29 | 1999-07-08 | Colgate-Palmolive Company | Detergent composition having improved cleaning power |
WO2011001173A1 (en) * | 2009-06-30 | 2011-01-06 | Reckitt Benckiser N.V. | Composition |
Also Published As
Publication number | Publication date |
---|---|
EP0576778B1 (de) | 1998-02-04 |
CA2139359A1 (en) | 1994-01-20 |
JPH07508788A (ja) | 1995-09-28 |
IE930498A1 (en) | 1994-01-12 |
MX9304037A (es) | 1994-05-31 |
WO1994001520A1 (en) | 1994-01-20 |
TR26910A (tr) | 1994-08-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0576778B1 (de) | Konzentriertes, wässeriges, flüssiges Reinigungsmittel | |
US5916862A (en) | Detergent compositions containing amines and anionic surfactants | |
EP0615542B1 (de) | Fluessige waschmittel mit zitronensaeure, cellulase und bor-diol-komplex um proteolytisches enzym zu inhibieren | |
EP0342177B1 (de) | Flüssige Universalwaschmittel, welche anionische und nichtionische oberflächenaktive Mittel, Gerüststoffe und proteolytisches Enzym enthalten | |
JPS63213598A (ja) | セルラーゼを含有する洗剤組成物 | |
AU682668B2 (en) | Detergent composition with suds suppressing system | |
EP0785978A1 (de) | Waschmittel enthaltend amine und anionische tenside | |
CA2165766C (en) | Low sudsing liquid detergent compositions | |
US5981466A (en) | Detergent compositions containing amines and anionic surfactants | |
WO1997000929A1 (en) | Detergent compositions containing amines and anionic surfactants | |
US6087321A (en) | Detergent compositions containing amines, alkyl sulfates, and other anionic surfactants | |
EP0576777B1 (de) | Polyvinylpyrrolidon und schmutzabweisendes Polymer auf Basis von Polyterephthalate enthaltende konzentrierte wässrig-flüssige Waschmittelzusammensetzungen | |
WO1997006235A1 (en) | Detergent compositions containing amine and specially selected perfumes | |
CA2233332C (en) | Liquid laundry detergents containing selected alkyl amidoalkoyl quaternary ammonium compounds | |
US5723425A (en) | Concentrated aqueous liquid detergent comprising polyvinylpyrrolidone | |
NZ318989A (en) | Heavy duty detergent containing an alpha-sulphonated alkyl ester of a fatty acid; inhibition of soil redeposition | |
US5858950A (en) | Low sudsing liquid detergent compositions | |
US5668095A (en) | Detergent composition with suds suppressing system | |
GB2211864A (en) | Stilbene derivatives for use in detergent compositions | |
CA2225458A1 (en) | Detergent compositions containing amines and anionic surfactants |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FR GB GR IT LI LU NL PT SE |
|
17P | Request for examination filed |
Effective date: 19940630 |
|
17Q | First examination report despatched |
Effective date: 19960910 |
|
GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
RBV | Designated contracting states (corrected) |
Designated state(s): GB |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: 8566 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): GB |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
REG | Reference to a national code |
Ref country code: GB Ref legal event code: IF02 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20020613 Year of fee payment: 11 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20030703 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20030703 |