EP0475427B1 - Heizelement und Verfahren zu seiner Herstellung - Google Patents
Heizelement und Verfahren zu seiner Herstellung Download PDFInfo
- Publication number
- EP0475427B1 EP0475427B1 EP91115541A EP91115541A EP0475427B1 EP 0475427 B1 EP0475427 B1 EP 0475427B1 EP 91115541 A EP91115541 A EP 91115541A EP 91115541 A EP91115541 A EP 91115541A EP 0475427 B1 EP0475427 B1 EP 0475427B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- heating element
- nickel
- aluminium
- layers
- base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 238000010438 heat treatment Methods 0.000 title claims description 131
- 238000000034 method Methods 0.000 title claims description 29
- 238000004519 manufacturing process Methods 0.000 title claims description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 78
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 57
- 239000004411 aluminium Substances 0.000 claims description 44
- 229910052782 aluminium Inorganic materials 0.000 claims description 44
- 229910052751 metal Inorganic materials 0.000 claims description 42
- 239000002184 metal Substances 0.000 claims description 42
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 41
- 229910052759 nickel Inorganic materials 0.000 claims description 39
- 229910045601 alloy Inorganic materials 0.000 claims description 18
- 239000000956 alloy Substances 0.000 claims description 18
- 239000005030 aluminium foil Substances 0.000 claims description 18
- 238000005253 cladding Methods 0.000 claims description 14
- 229910000545 Nickel–aluminium alloy Inorganic materials 0.000 claims description 12
- 230000001590 oxidative effect Effects 0.000 claims description 7
- 238000005520 cutting process Methods 0.000 claims description 5
- 230000007797 corrosion Effects 0.000 description 24
- 238000005260 corrosion Methods 0.000 description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 22
- 238000010411 cooking Methods 0.000 description 20
- 230000005855 radiation Effects 0.000 description 19
- 239000000377 silicon dioxide Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 7
- 241000251468 Actinopterygii Species 0.000 description 6
- 239000011888 foil Substances 0.000 description 5
- 239000010445 mica Substances 0.000 description 5
- 229910052618 mica group Inorganic materials 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 238000000151 deposition Methods 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- 239000010953 base metal Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 239000011162 core material Substances 0.000 description 2
- 238000005485 electric heating Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910001005 Ni3Al Inorganic materials 0.000 description 1
- 229910000943 NiAl Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
- H05B3/22—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible
- H05B3/28—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor embedded in insulating material
- H05B3/30—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor embedded in insulating material on or between metallic plates
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47D—FURNITURE SPECIALLY ADAPTED FOR CHILDREN
- A47D13/00—Other nursery furniture
- A47D13/02—Baby-carriers; Carry-cots
- A47D13/025—Baby-carriers; Carry-cots for carrying children in seated position
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/12—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
Definitions
- the present invention relates to a heating element used for a cooking apparatus and a heating apparatus at temperatures of around 800°C, and a method for manufacturing the same.
- a silica tube heater As a heating element for a cooking apparatus and a heating apparatus, a silica tube heater has been conventionally used. A sheath heater and a "mica heater” where a heating wire is wound around a mica strip have also been used for a cooking apparatus.
- the silica tube heater where a heating wire wound in a toroidal shape is inserted into a silica tube
- substances such as salt spattered from an object to be cooked may attach to the surface of the silica tube.
- the silica tube is likely to be devitrified, failing to provide a sufficient amount of extreme infrared radiation required for cooking, or the silica tube may even become broken.
- a temperature of 700°C at highest is obtained from this heater.
- the heater when used for cooking, the heater utilizes secondary radiation from the stainless steel sheath.
- This structure requires a longer time until a predetermined temperature is attained.
- the temperature of the heating wire itself in order to obtain the radiation of 800°C, the temperature of the heating wire itself must be more than 800°C, which will shorten the life of the heating wire.
- the mica heater can easily be formed into a sheet.
- the heater is installed through an insulation on the outer surface of the wall of a cooking apparatus, heat conduction is not effective. Therefore, a longer time is required until a predetermined temperature is attained on the inner surface of wall of the cooking apparatus from which heat is radiated for cooking, and also it is difficult to obtain the radiation of a high temperature of about 800°C.
- a bare metal heating element made of iron-chrome-aluminium, nickel-chrome or iron-nickel-chrome can be used to serve as a heating element which can be formed into a sheet and which can be rapidly and easily heated to provide radiation of 800°C suitable for a cooking apparatus and a heating apparatus.
- the bare metal heating element is highly thermal resistant and will not be damaged when exposed in an atmosphere of high temperature.
- corrosive substances such as salt spattered from an object to be cooked may attach to the metal heating element. If such a contaminated metal heating element is used under the condition of a temperature as high as 800 C, it will easily be corroded and damaged.
- the structures of the afore-mentioned heating elements had originally been developed to prevent such corrosion.
- JP-A-52-108 532 discloses a process for manufacturing an electric heating material in which after reducing an area of a compound material, the core material of which is a Fe-Cr-plate, both sides of it are covered by thin Al-plates by rolling process.
- the Al-plate of the area reduction process material is heated to diffuse into the core material.
- This electric heating material can also be obtained by applying a blanking process.
- thermocouple having an elongate shape which is bent in the plane of the thermocouple.
- This process as known from GB-A-1 222 504 comprises forming by deposition on a metal foil a layer of a different metal, the junction between the two metals constituting the thermo-junction of the thermocouple, and the metal foil being provided with the elongate shape either before or after the deposition.
- This thermocouple may be made from any standard thermocouple materials which allow the deposition of one material on the other.
- the thermocouple may be made by depositing nickel-chrome on nickel-aluminium foil.
- the objective of the present invention is to provide a heating element which is not only highly corrosive resistant at high temperature, but also can be formed into a sheet, and can be rapidly and easily heated to provide heat radiation of about 800°C.
- the heating element of this invention which overcomes the above-discussed and numerous other disadvantages and deficiencies of the prior art, comprises a metal base having nickel-aluminium alloy layers formed on the top and bottom surfaces thereof.
- a further invention is a method for covering the nickel or nickel base alloy with aluminium oxide layers.
- the metal base is nickel or a nickel-base alloy.
- the nickel content in the nickel-base alloy is at least 50 %.
- the heating element of this invention comprises a metal base having nickel layers and aluminium oxide layers formed in this order on the top and bottom surfaces thereof.
- the aluminium layers or the aluminium alloy layers are formed by cladding.
- the method for manufacturing a heating element comprises the steps of forming aluminium layers on the top and bottom surfaces of a nickel or nickel-base alloy base, and oxidising the aluminium layers into aluminium oxide layers.
- the aluminium layers are formed by cladding the nickel or nickel-base alloy base with aluminium foils on both surfaces thereof.
- the method further comprises the step of cutting the nickel or nickel-base alloy base clad with the aluminium foils to a predetermined shape between the step of forming the aluminium layers and the step of oxidising the aluminium layers.
- the aluminium foils are wider than the nickel or nickel-base alloy base.
- the nickel content in the nickel-base alloy base is at least 50%.
- the method of this invention comprises the steps of forming nickel layers on the top and bottom surfaces of a metal base, forming aluminium layers on the nickel layers, and oxidizing the aluminium layers into aluminium oxide layers.
- the nickel layers and the aluminium layers are formed by cladding.
- the method further comprises the step of cutting the metal base clad with the nickel layers and the aluminium layers to a predetermined shape between the step of forming the aluminium layers and the step of oxidizing the aluminium layers.
- the heating element of the present invention with high corrosion resistance at high temperature can be used in a bare form without the necessity of providing a sheath, as required in the conventional heating elements, to protect against, for example, attachment of corrosive substances spattered from an object to be cooked. Further, the heating element without a sheath can easily be formed into a sheet heating element by stamping it into a desired pattern or the like. Also, since the specific heat of the heating element of the present invention can be small without an extra thickness for a sheath, the heating element can rapidly be heated to a high temperature of, for example, 800°C, and thereby radiation of high temperature is easily obtained.
- the present invention makes possible the objective of providing a heating element which can be formed into a sheet and which can be rapidly heated so as to provide radiation of high temperature.
- a heating element 1 comprises a metal base 2 made of nickel or a nickel-base alloy having aluminium oxide layers 3 and nickel-aluminium alloy layers 4 formed in this order on the top and bottom surfaces thereof.
- the heating element 1 of the above structure is formed by the following procedure.
- aluminium layers 5 are formed on both surfaces of the metal base 2 by spraying, plating, evaporation, spattering, cladding or any other appropriate method.
- spraying or cladding is employed, a thicker layer is comparatively easily obtained.
- an aluminium layer which is free from pinholes can be formed.
- the aluminium layers 5 are oxidized into the aluminium oxide layers 3 with high corrosion resistance.
- the aluminium layers 5 can be oxidized by various methods such as anodic oxidation. Most practically, it is heated at high temperature in the atmosphere.
- the nickel-aluminium alloy layers 4 which are also highly corrosive resistant can easily be formed between the metal base 2 and the aluminium oxide layers 3, thereby providing the resultant heating element with the property of high corrosion resistance.
- a heating element of the above structure was manufactured to assess the corrosion resistance as follows.
- a nickel or an alloy containing a varying content of nickel (chrome content: 21 ⁇ 2%) was used as the metal base 2. Then, the metal base 2 was clad with aluminium foils on both surfaces thereof. The resultant aluminium-clad base was cut into a size required, and then heated at 900°C in the atmosphere for five hours so as to produce the aluminum oxide layers 3 on both surfaces thereof. In this way, the heating element 1 having a width of 6 mm and a thickness of 50 ⁇ was obtained. Electricity was applied to the heating element 1 to raise the temperature of the surfaces thereof to 800°C.
- each two-direction arrow shows the range of the numbers of drops counted for the samples of each nickel content
- each mark ⁇ shows the average thereof.
- Each mark X shows a result obtained from a sample of the metal base without cladding of an aluminium foil.
- the corrosion resistance sharply increases when the nickel content exceeds 50%. This is because, with such a high nickel content, the corrosive resistant nickel-aluminium alloy layers 4 were further formed between the metal base 2 and the aluminium oxide layers 3. This formation was confirmed by analyzing the heating element 1 by an X-ray diffraction method, where NiAl and Ni3Al were detected.
- the aluminium layers 5 were formed on the top and the bottom surfaces of the metal base 2, but not on the side faces thereof (in the direction of the thickness thereof).
- the formation of the nickel-aluminium alloy layer 4 was also observed on the side faces. This is probably because burrs of the aluminium foils produced at the aforementioned cutting process after the cladding of the aluminium foils were spread onto the side faces of the metal base 2.
- most of the sample heating elements were finally cut apart by corrosion in the portions except the cut side ends thereof, which shows that the cut side ends are not especially inferior in corrosion resistance.
- the aluminium foils can be slightly wider than the metal base, so that the nickel-aluminium alloy layer can also be formed on the side faces of the base metal as in the case described above.
- FIG 4 shows a microwave oven 6 which has a structure of a sheet heating element 7 comprising the heating element 1 of the invention being disposed on support members 9 placed on a microwave shielding plate 8.
- a control panel and other components of the microwave oven 6 not directly relating to this invention are not shown in the figure for simplicity.
- the microwave shielding plate 8 is made of a corrosive resistant stainless steel plate having a number of bores of a diameter of about 3 mm so that the total area of the bores should occupy about 60% of the total area of the plate.
- the microwave shielding plate 8 has two functions; shielding the sheet heating element 7 from receiving microwave radiated during microwave cooking and passing radiation from the heating element directly onto an object to be cooked during heat cooking.
- a nickel-chrome strip (NCHRW1) for heating was used as the metal base 2, which was clad with aluminium foils on both surfaces thereof. Then, the resultant strip was stamped into a meander shape and heated at 900°C in the atmosphere for five hours to produce the sheet heating element 7 having an output of 1.2 KW. When a rated voltage of 100 V was applied to the heating element 7, the temperature of the heating element reached 700°C in about one minute, and further rose to 800°C in three minutes,
- An object to be cooked for example, a fish
- the fish was uniformly broiled under the radiation of 800°C for fifteen minutes.
- a conventional sheet heating element for example the mica heater
- the sheath heater and the silica tube heater uniform browning as attained in the heating element of the invention was not possible.
- the sheet heating element 7 of the invention effects uniform browning over the object to be cooked, because the heating element 7 is formed as a sheet and the radiation from the sheet heating element 7 to the object is intensive. That is, since the radiation is sent in the direction vertical to the surface of the heating element 7, in the case of a strip heating element as shown in Figure 5, the radiation is theoretically sent only to an area right below the width A of the heating element 7. (The radiation in the horizontal direction along the heating element is not counted in this case since the thickness of the heating element is negligibly small compared with the width thereof.) Actually, however, the radiation is somewhat diffused since the surface of the heating element is uneven, which as a result, enables the uniform browning of the object to be cooked. Thus, in the case of a strip heating element, radiation is more intensive in the direction vertical to the heating element, and therefore effective heating can be accomplished by placing the object to be cooked in this direction.
- the sheath heater or the silica heater where a heating element with a sheath is round in section, heat is radiated to every direction in the space. Therefore, the amount of radiation reaching the object to be cooked is small, that is, the heating efficiency is low when the sheath heater or the silica heater is used compared with when the strip heating element is used, under the condition that both heating elements have the same output and the same temperature of radiation.
- the heating element of this example had high corrosion resistance and was little deteriorated after a long period of usage.
- a heating element 11 comprises a metal base 12 having nickel-base layers 13 and aluminium oxide layers 14 formed in this order on the top and bottom surfaces thereof.
- the metal base 12 is made of iron-chrome, iron-chrome-aluminium or stainless steel such as SUS 430, SUS 430A or SUS 444.
- the heating element 11 of the above structure is formed in the following procedure. First nickel layers 15 and then aluminium layers 16 are formed on both surfaces of the metal base 12 by spraying, plating, evaporation, spattering, cladding or any other suitable method, as described in Example 1. Then, the aluminium layers 16 are oxidized into the aluminium oxide layers 14 most practically by heating at high temperature in the atmosphere. At the same time, layers of the nickel-aluminium alloy can be formed, as described in Example 1. The nickel-aluminium alloy layers can be sufficiently formed by heating at 500 to 700°C in an environment of an inactive gas, not in the atmosphere, and then heating at a temperature of 800°C or higher in the atmosphere.
- the nickel-base layers 13 of this example are the nickel layers 15 wholly or partly changed to the nickel-aluminium alloy.
- the aluminium layers 16 should be completely oxidized because, during the use of the heating element, any unoxidized aluminium which is conductive remaining in the heating element is exposed to high temperature and oxidized into aluminium oxide which is insulating, causing a gradual increase of resistance of the heating element.
- the heating element of the above structure was manufactured to assess the corrosion resistance as follows.
- the metal base 12 made of iron-chrome (FCHRW1) was clad with nickel foils and then aluminium foils on both surfaces thereof.
- the total thickness of the clad base was 50 ⁇ with 42 ⁇ for the metal base 12, 4 ⁇ for the two nickel layers and 4 ⁇ for the two aluminium layers, and the width thereof was 6 mm.
- the clad base was then heated at 900°C in the atmosphere for five hours so as to produce the aluminum oxide layers 14 on both surfaces.
- the formation of the nickel-aluminium alloy layers between the metal base 12 and the aluminium oxide layers 14 was confirmed by an X-ray diffraction method. Electricity was applied to the thus obtained heating element 11 to raise the surface temperature thereof to 800°C.
- Example 2 The same corrosion resistance test as that in Example 1 was performed. As a result, the number of drops applied to the above heating element 11 until it was corroded and cut apart was 80. The same test was also performed on the following three comparative samples; a heating element made of iron-chrome and heated at 900°C in the atmosphere for five hours, a heating element made of SUS 430 and SUS 444 on which the same steps of cladding of nickel and aluminium and of thermally oxidizing the aluminium as in Example 2 were performed, and a heating element made of the same material as the above on which the step of cladding of nickel and aluminium was not performed but the step of heating was performed. The results were 10, 80, and 10, respectively. These results indicate that the corrosion resistance at high temperature shown in the heating element of this invention is irrespective of the type of the base metal.
- FCHRW1 Iron-chrome strip
- FCHRW1 iron-chrome strip
- FCHRW1 iron-chrome strip for heating was used as the metal base 12, which was clad with nickel foils and aluminium foils on both surfaces thereof. Then, the resultant strip was stamped into a meander shape and heated at 900°C in the atmosphere for five hours to produce a sheet heating element 7′ having an output of 1.2 KW. When a rated voltage of 100 V was applied to the heating element 7′, the temperature of the heating element reached 700°C in about one minute, and further rose to 800°C in three minutes. An object to be cooked, for example, a fish, was put in the oven chamber 10 for heat cooking. The fish was broiled with uniform browning under the radiation of 800°C for fifteen minutes.
- Example 1 The same corrosion resistance test as in Example 1 was performed on the microwave oven comprising the sheet heating element 7′ of this example, and the same favorable results as in Example 1 were obtained.
- the heating element of this example had high corrosion resistance and was little deteriorated after a long period of usage.
- the strip-shaped metal base was used.
- the metal base applicable to the present invention is not limited to the strip shape, but a linear metal base can also be used to obtain the same high corrosion resistance when the structure and the method of the present invention is applied thereto.
- a metal base made of iron-chrome, iron-chrome-aluminium or stainless steel such as SUS 430, SUS 430A or SUS 444 was used.
- On the top and bottom surfaces of the metal base were formed aluminium layers in the same manner as shown in Example 1.
- the aluminium layers were then oxidized into aluminium oxide layers in the same manner as shown in Example 1.
- the same test as in Example 1, that is, dropping a 5% saline solution was performed on the resultant heating element, and the result was 20 drops until the heating element was corroded and cut apart, indicating that the corrosion resistance of the heating element of this example was about twice as high as that of a heating element lacking an aluminium oxide layer.
- the heating element obtained in this example was formed into a sheet heating element in the same manner as in Example 1 for the application to a microwave oven, and the same test as in Example 1 was performed. After 500 cycles, some small corrosion was observed on the surface of the heating element, but such corrosion did not cause inferiority in the cooking ability nor any other practical problems.
- the aluminium layer was formed and oxidized in order to obtain the aluminium oxide layer. It should be appreciated that an aluminium-base alloy can also be used instead of aluminium to attain the above objective.
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- Resistance Heating (AREA)
- Cookers (AREA)
- Surface Heating Bodies (AREA)
Claims (13)
- Heizelement mit einer Metallbasis (2, 12) mit Schichten aus einer Nickel-Aluminium-Legierung (4), die an ihren oberen und unteren Oberflächen ausgebildet sind.
- Heizelement nach Anspruch 1, dadurch gekennzeichnet, daß die Schichten aus der Nickel-Aluminium-Legierung (4) mit Aluminiumoxid-Schichten (3, 14) bedeckt sind.
- Heizelement nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß die Metallbasis (2, 12) Nickel oder eine Nickelbasis-Legierung ist.
- Heizelement nach Anspruch 3, dadurch gekennzeichnet, daß der Nickelanteil in der Nickelbasis-Legierung mindestens 50 % ist.
- Verfahren zur Herstellung eines Heizelements (1, 7, 7′, 11) mit den folgenden Schritten:- Bildung von Aluminium-Schichten (5, 16) an den oberen und unteren Oberflächen einer Nickel- oder Nickelbasis-Legierung-Basis (2, 12), und- Oxidierung der Aluminiumschichten (5, 16) zu Aluminiumoxidschichten (3, 14).
- Verfahren zur Herstellung eines Heizelements (1, 7, 7′ 11) nach Anspruch 5, dadurch gekennzeichnet, daß die Aluminiumschichten (5, 16) durch Umhüllung der Nickel- oder Nickelbasis-Legierung-Basis mit Aluminiumfolien gebildet werden.
- Verfahren zur Herstellung eines Heizelements (1, 7, 7′ 11) nach Anspruch 6, mit dem weiteren Schritt des Zuschneidens der mit den Aluminiumfolien umhüllten Nickel- oder Nickelbasis-Legierung-Basis auf eine vorgegebene Form, zwischen dem Schritt der Bildung der Aluminiumschichten (5, 16) und dem Schritt der Oxidierung der Aluminiumschichten (5, 16).
- Verfahren zur Herstellung eines Heizelements (1, 7, 7′ 11) nach Anspruch 6, dadurch gekennzeichnet, daß die Aluminiumfolien breiter als die Nickel- oder Nickelbasis-Legierung-Basis sind.
- Verfahren zur Herstellung eines Heizelements (1, 7, 7′ 11) nach einem der Ansprüche 5 bis 8, dadurch gekennzeichnet, daß der Nickelanteil in der Nickelbasis-Legierung-Basis mindestens 50 % ist.
- Heizelement mit einer Metallbasis (2, 12) mit Nickelschichten (15) und Aluminiumoxidschichten (3, 14), die in dieser Reihenfolge auf ihren oberen und unteren Oberflächen ausgebildet sind.
- Verfahren zur Herstellung eines Heizelements (1, 7, 7′ 11) mit den folgenden Schritten:- Bildung von Nickelschichten (15) auf den oberen und unteren Oberflächen einer Metallbasis (2, 12),- Bildung von Aluminiumschichten (5, 16) auf den Nickelschichten (15), und- Oxidierung der Aluminiumschichten (5, 16) zu Aluminiumoxidschichten (3, 14).
- Verfahren zur Herstellung eines Heizelements (1, 7, 7′ 11) nach Anspruch 11, dadurch gekennzeichnet, daß die Nickelschichten (15) und die Aluminiumschichten (5, 16) durch Umhüllung gebildet werden.
- Verfahren zur Herstellung eines Heizelements (1, 7, 7′ 11) nach Anspruch 12 mit dem weiteren Schritt des Zuschneidens der mit den Nickelschichten (15) und den Aluminiumschichten (5, 16) umhüllten Metallbasis (3, 12) auf eine vorgegebene Form zwischen dem Schritt der Bildung der Aluminiumschichten (5, 16) und dem Schritt der Oxidierung der Aluminiumschichten (5, 16).
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2244357A JPH04123785A (ja) | 1990-09-14 | 1990-09-14 | 発熱体 |
JP244357/90 | 1990-09-14 | ||
JP259669/90 | 1990-09-27 | ||
JP2259669A JPH04137385A (ja) | 1990-09-27 | 1990-09-27 | 発熱体およびその製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0475427A1 EP0475427A1 (de) | 1992-03-18 |
EP0475427B1 true EP0475427B1 (de) | 1994-11-30 |
Family
ID=26536702
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP91115541A Expired - Lifetime EP0475427B1 (de) | 1990-09-14 | 1991-09-13 | Heizelement und Verfahren zu seiner Herstellung |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0475427B1 (de) |
KR (1) | KR940005461B1 (de) |
AU (1) | AU630306B2 (de) |
BR (1) | BR9103944A (de) |
CA (1) | CA2051231A1 (de) |
DE (1) | DE69105419T2 (de) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5976708A (en) * | 1995-11-06 | 1999-11-02 | Isuzu Ceramics Research Institute Co., Ltd. | Heat resistant stainless steel wire |
KR101416170B1 (ko) * | 2007-09-10 | 2014-07-11 | 주식회사 아모그린텍 | 세탁물 건조용 히팅 유니트 |
WO2009035241A2 (en) * | 2007-09-10 | 2009-03-19 | Amo Co., Ltd. | Drying heater, heating unit for drying laundry using the same, drying control system and control method thereof |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1222504A (en) * | 1967-03-03 | 1971-02-17 | Transystems Ltd | Foil thermocouples |
-
1991
- 1991-09-12 CA CA002051231A patent/CA2051231A1/en not_active Abandoned
- 1991-09-12 AU AU83843/91A patent/AU630306B2/en not_active Ceased
- 1991-09-13 BR BR919103944A patent/BR9103944A/pt not_active IP Right Cessation
- 1991-09-13 DE DE69105419T patent/DE69105419T2/de not_active Expired - Fee Related
- 1991-09-13 EP EP91115541A patent/EP0475427B1/de not_active Expired - Lifetime
- 1991-09-14 KR KR1019910016044A patent/KR940005461B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
AU8384391A (en) | 1992-06-11 |
KR940005461B1 (ko) | 1994-06-18 |
CA2051231A1 (en) | 1992-03-15 |
DE69105419T2 (de) | 1995-06-29 |
AU630306B2 (en) | 1992-10-22 |
BR9103944A (pt) | 1992-05-26 |
EP0475427A1 (de) | 1992-03-18 |
DE69105419D1 (de) | 1995-01-12 |
KR920007494A (ko) | 1992-04-28 |
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