EP0435483A2 - Composition cosmétique - Google Patents
Composition cosmétique Download PDFInfo
- Publication number
- EP0435483A2 EP0435483A2 EP19900313142 EP90313142A EP0435483A2 EP 0435483 A2 EP0435483 A2 EP 0435483A2 EP 19900313142 EP19900313142 EP 19900313142 EP 90313142 A EP90313142 A EP 90313142A EP 0435483 A2 EP0435483 A2 EP 0435483A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- value
- emulsion
- emulsion according
- acid
- diol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
Definitions
- the invention relates to a water-in-oil emulsion suitable for topical application to human skin and/or hair. More particularly, the invention is concerned with an exceptionally stable water-in-silicone oil emulsion comprising an inorganic electrolyte, which together with the silicone ingredients, and ideally a hydroxyalkanoic acid and an alkane diol provides a product having exceptional cosmetic and sensory properties aimed at improving the quality, particularly the plasticity of skin to which it is applied, either as a beauty aid or in the treatment of damaged or diseased skin.
- a soft, supple and flexible skin has a marked cosmetic appeal and is an attribute of normal functioning epidermis.
- the epidermis can become folded or ridged or furrowed to form wrinkles which signal the loss of youthful appearance and herald the transition to old age. This transition can occur prematurely with young people, especially those who expose themselves to excessive doses of sunlight. Also, the outer layer of the epidermis, that is the stratum corneum, can become dry and flaky following exposure to cold weather, or excessive contact with detergents or solvents which result in loss of skin moisture with the result that the skin loses its soft, supple and flexible characteristics.
- Emollients such as fats, phospholipids and sterols have in the past been used to soften wrinkled or dry skin, but it is apparent that these emollients are only partially effective as a remedy for skin in poor condition.
- EP-A 0 007 785 discloses skin treatment compositions incorporating ⁇ -hydroxycaproic acid or ⁇ -hydroxycaprylic or mixtures thereof, the compositions having a pH value of less than 7, usually from 2 to 4.
- emulsions such as classical oil-in-water emulsions, containing a hydroxyalkanoic acid, such as 2-hydroxyoctanoic acid
- a hydroxyalkanoic acid such as 2-hydroxyoctanoic acid
- This is believed to be due at least partly to the solubilisation of the hydroxyalkanoic acid by the emulsiers conventionally used in such products, with the consequence that separation of oil and water phases can ensue.
- a further consequence of this solubilisation is to release the hydroxyalkanoic acid prematurely from the emulsion, so that its delivery to the skin when the emulsion is applied topically is less efficient and effective.
- the sensory properties of such emulsions can be poor, due to the presence of the hydroxyalkanoic acid in the continuous phase. This then exerts a dominating influence on the sensory profile, with the consequence that residual stickiness on the skin can be experienced.
- the emulsion can provide a stable vehicle for the delivery to skin of other skin benefit materials.
- the emulsion can also provide a matrix which acts as a vehicle for other skin and/or hair benefit substances.
- the invention provides a water-in-silicone oil emulsion, suitable for topical application to mammalian skin or hair, which comprises, in addition to water;
- the emulsion of the invention is a water-in-silicone oil emulsion, which is particularly suitable for topical application to mammalian skin or hair, especially that of the human subject.
- the emulsion is unusual in as much as it is exceptionally stable and retains superior sensory attributes, this being due to the careful choice of an inorganic electrolyte, together with a silicone emulsifier and volatile silicone. Stability during storage over a very long period of time of up to 3 years can be further enhanced by incorporation of a an alkane diol, even in the presence of an hydroxyalkanoic acid
- the emulsion can also provide a vehicle for other skin and/or hair benefit substances which can thereby be applied, with much greater ease and control to the skin or hair at an appropriate concentration suited to their intended benefit.
- the emulsion of the invention comprises a volatile polydimethylsiloxane such as polydimethylcyclosiloxane having a viscosity of less than 5 mm 2s ⁇ 1, examples of which are DOW CORNING 344 Fluid (tetramer) and DOW CORNING 345 Fluid (pentamer), and volatile hexamethyldisiloxane having a viscosity of not more than 0.65 mm2s ⁇ 1, for example DOW CORNING 200 Fluid (0.65 mm2s ⁇ 1).
- a volatile polydimethylsiloxane such as polydimethylcyclosiloxane having a viscosity of less than 5 mm 2s ⁇ 1, examples of which are DOW CORNING 344 Fluid (tetramer) and DOW CORNING 345 Fluid (pentamer)
- volatile hexamethyldisiloxane having a viscosity of not more than 0.65 mm2s ⁇ 1, for example DOW CORNING 200 Fluid (0
- the preferred volatile siloxane is polydimethylcyclosiloxane (pentamer).
- the emulsion will normally comprise from 1 to 50%, preferably from 5 to 20% by weight of the volatile siloxane.
- the emulsion of the invention also comprises a high molecular weight silicone surfactant which acts as an emulsifier.
- the silicone surfactant is a high molecular weight polymer of dimethyl polysiloxane with polyoxyethylene and/or polyoxypropylene side chains having a molecular weight of from 10,000 to 50,000 and having the structure:
- the dimethyl polysiloxane polymer is one in which:
- one of groups R′ and R ⁇ being lauryl, and the other having a molecular weight of from 1000 to 5000.
- a particularly preferred dimethyl polysiloxane polymer is one in which:
- the dimethyl polysiloxane polymer is conveniently provided as a dispersion in a volatile siloxane, the dispersion comprising, for example, from 1 to 20% by volume of the polymer and from 80 to 99% by volume of the volatile siloxane.
- the dispersion consists of a 10% by volume of the polymer dispersed in the volatile siloxane.
- volatile siloxanes in which the polysiloxane polymer can be dispersed examples include those given above.
- a particularly preferred silicone surfactant is cyclomethicone and dimethicone copolyol, such as DC 3225C Formulation Aid available from DOW CORNING.
- Another is laurylmethicone copolyol, such as DC Q2-5200, also available from Dow Corning.
- the emulsion according to the invention will normally comprise from 0.1 to 25%, preferably from 0.5 to 15% by weight of the silicone surfactant.
- the emulsion can also, optionally, comprise a non-volatile siloxane such as a polydimethylsiloxane having a viscosity in excess of 5 mm2s ⁇ 1, for example, from 50 to 1000 mm2s ⁇ 1, for example DOW CORNING 200 Fluids (standard viscosities 50-1000 mm2s ⁇ 1).
- a non-volatile siloxane such as a polydimethylsiloxane having a viscosity in excess of 5 mm2s ⁇ 1, for example, from 50 to 1000 mm2s ⁇ 1, for example DOW CORNING 200 Fluids (standard viscosities 50-1000 mm2s ⁇ 1).
- the emulsion of the invention also comprises an inorganic electrolyte which serves to improve the stability of the emulsion, particularly when subjected during storage to extremes of temperature.
- inorganic electrolytes examples include salts, such as alkali metal and ammonium halides, sulphates, nitrates, carbonates and bicarbonates in either anhydrous or hydrated form.
- Particularly preferred salts include sodium chloride, potassium chloride and ammonium chloride.
- the emulsion according to the invention will normally comprise from 0.1 to 10%, preferably from 0.2 to 5% by weight of an inorganic electrolyte.
- the emulsion of the invention also optionally comprises a 2-hydroxyalkanoic acid having from 3 to 28 carbon atoms.
- hydroxyalkanoic acids examples include:
- Particularly preferred hydroxyalkanoic acids are those having from 3 to 8 carbon atoms, especially
- the 2-hydroxyalkanoic acids can also be present in the emulsion in the form of their acid-soap complexes having from 6 to 56 carbon atoms, preferred examples of which have an elemental analysis of: (C m H 2m-1 ⁇ 2 03) (C n H 2n-1 ⁇ 2 03) M
- a particularly preferred example of the acid-soap complex is that derived from two molecules of 2-hydroxyoctanoic acid which has the empirical formula C16H31O6Na, as disclosed in EP A O 348 198.
- the emulsion according to the invention can comprise from 0.1 to 10%, preferably from 0.5 to 5% by weight of the hydroxyalkanoic acid or its acid-soap complex.
- the emulsion of the invention can also comprise an alkane diol, or a mixture thereof, which serves further to improve and prolong the stability of the emulsion, particularly when a very long period of storage, for example of at least 12 months or even up to 3 years, is anticipated.
- the preferred alkane diols for this purpose are those having from 2 to 10 carbon atoms in the molecule.
- Examples of particularly preferred alkane diols are:
- An especially preferred alkane diol is butane-1,3-diol.
- the emulsion according to the invention will preferably comprise up to 30%, most preferably from 1 to 25% by weight of an alkane diol.
- the emulsion of the invention can optionally comprise a cosmetically acceptable vehicle, in addition to water, to act as a dilutant, dispersant or carrier for other materials present in the emulsion, so as to facilitate their distribution when the emulsion is applied to the skin and/or hair.
- a cosmetically acceptable vehicle in addition to water, to act as a dilutant, dispersant or carrier for other materials present in the emulsion, so as to facilitate their distribution when the emulsion is applied to the skin and/or hair.
- Vehicles other than water can include liquid or solid emollients, solvents, humectants, thickeners and powders. Examples of each of these types of vehicle, which can be used singly or as mixtures of one or more vehicles, are as follows:
- adjuncts examples include preservatives, such as para-hydroxy benzoate esters; antioxidants, such as butyl hydroxy toluene; solvents, such as ethyl alcohol and isopropanol; humectants, such as glycerol, sorbitol, 2-pyrrolidone-5-carboxylate, dibutylphthalate, gelatin, polyethylene glycol, preferably PEG 200-600; buffers, such as lactic acid together with a base such as triethanolamine or sodium hydroxide; waxes, such as beeswax, ozokerite wax, paraffin wax; plant extracts, such as Aloe vera, cornflower, witch hazel, elderflower, cucumber; thickeners; activity enhancers; colourants; perfumes; and sunscreens, such as p-aminobenzoic acid, ethylhexyl p-methoxycinnamate and 2-ethoxyethyl-p-me
- preservatives such
- Cosmetic adjuncts can form up to 50% by weight of the emulsion and can conveniently form the balance of the emulsion.
- the aqueous phase of the emulsion according to the invention should preferably have a pH value of from 3.5 to ⁇ 7.
- the invention also provides a process for the preparation of an emulsion for topical application to skin and/or hair which comprises the step of incorporating into the emulsion a volatile polydimethylsiloxane, a silicone surfactant, and an inorganic electrolyte as herein defined.
- a 2-hydroxyalkanoic acid and an alkane diol are also incorporated into the emulsion.
- the emulsion according to the invention is intended primarily as a product for topical application to human skin, particularly dry skin, when repeated application can alleviate the dry condition, and restore the skin to a more natural, soft, supple, healthy state.
- the emulsion can also be used to treat the hair and the scalp.
- a small quantity of the emulsion for example from 1 to 5 ml, is applied to the affected area of skin or hair, from a suitable container or applicator and, if necessary, it is then spread over and/or rubbed into the skin or hair using the hand or fingers or a suitable device.
- the topical skin and/or hair treatment emulsion of the invention can be formulated as a lotion having a viscosity of from 4,000 to 10,000 mPas, a fluid cream having a viscosity of from 10,000 to 20,000 mPas or a cream having a viscosity of from 20,000 to 100,000 mPas, or above.
- the emulsion can be packaged in a suitable container to suit its viscosity and intended use by the consumer.
- a lotion or a fluid cream can be packaged in a bottle or a roll-ball applicator or a propellant-driven aerosol device or a container fitted with a pump suitable for finger operation.
- a non-deformable bottle or squeeze container such as a tube or a lidded jar.
- the invention accordingly also provides a closed container containing a cosmetically acceptable emulsion as herein defined.
- stable emulsions can be obtained by incorporating certain 2-hydroxyalkanoic acids into an emulsion based on a polydimethylcyclosiloxane and a silicone emulsifier, together with an inorganic electrolyte.
- Such emulsions are satisfactory for use, provided they are not stored for an extended period of, say, more than 3 months, at an elevated temperature of 40°C or above. Accordingly, it is apparent that these emulsions which are subjected to long storage at high temperatures can suffer from partial separation of the water and oily phases.
- the viscosity of the above emulsion measured on the Brookfield (TC, 10 rpm) was 15,000 mPas.
- This control lotion showed 'thinning' (i.e., a drop in viscosity) after three months storage at 35°C and 45°C, and completed only two freeze/thaw cycles (-22°C) before syneresis set in, instead of the normal four cycles.
- a drop in viscosity is indicative of long-term instability of an emulsion.
- test lotions had the following formulations:
- Viscosities measured on Brookfield (TB, 10 rpm) immediately after manufacture were as follows: ⁇
- Test formulations A, B and C each successfully completed four freeze/thaw cycles at -22°C and six months storage at 45°C (three months storage at this temperature is the industry standard minimum requirement) and at 35°C. No changes in viscosity were observed during storage testing.
- butane-1,3-diol dramatically enhanced the stability of the emulsion according to the invention when stored at a high temperature for an extended period.
- This example illustrates a lotion according to the invention.
- the lotion was subjected to four Freeze/Thaw cycles between +20°C and -22°C, and no syneresis or deteriorative changes were observed. Subsequently the emulsion remained stable for at least six months at storage temperatures of 45°C, 35°C and 20°C.
- This example illustrates a fluid cream according to the invention.
- the viscosity of the above fluid cream measured on the Brookfield (TB, 10 rpm) 24 hr after manufacture was 19,800 mPas.
- the fluid cream was subjected to four Freeze/Thaw cycles between +20°C and -22°C, and no syneresis or deteriorative changes were observed.
- the emulsion will remained stable for a period of six months at storage temperatures of 45°C, 35°C and 20°C.
- This example illustrates a cream according to the invention.
- the viscosity of the above cream measured on the Brookfield (TC, 10 rpm) 24 hr after manufacture was 50,000 mPas.
- the cream was subjected to four Freeze/Thaw cycles between +20°C and -22°C, and no syneresis or deteriorative changes were observed. Subsequently the emulsion remained stable for at least fifteen months at storage temperatures of 45°C, 35°C and 20°C.
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Colloid Chemistry (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB8927703 | 1989-12-07 | ||
GB898927703A GB8927703D0 (en) | 1989-12-07 | 1989-12-07 | Cosmetic composition |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0435483A2 true EP0435483A2 (fr) | 1991-07-03 |
EP0435483A3 EP0435483A3 (en) | 1991-08-07 |
EP0435483B1 EP0435483B1 (fr) | 1994-10-26 |
Family
ID=10667588
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90313142A Expired - Lifetime EP0435483B1 (fr) | 1989-12-07 | 1990-12-04 | Composition cosmétique |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP0435483B1 (fr) |
JP (1) | JPH04159204A (fr) |
AT (1) | ATE113201T1 (fr) |
CA (1) | CA2031285A1 (fr) |
DE (1) | DE69013659T2 (fr) |
DK (1) | DK0435483T3 (fr) |
ES (1) | ES2063933T3 (fr) |
GB (1) | GB8927703D0 (fr) |
Cited By (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0495596A1 (fr) * | 1991-01-17 | 1992-07-22 | Dow Corning Corporation | Alkylméthylsiloxanes pour le soin de la peau |
EP0529848A1 (fr) * | 1991-08-26 | 1993-03-03 | Dow Corning Corporation | Mélanges d'alkylméthylsiloxanes pour le soin de la peau |
EP0556660A1 (fr) * | 1992-02-13 | 1993-08-25 | Beiersdorf Aktiengesellschaft | Utilisation d'acides gras alpha-hydroxyliques ainsi que les compositions les contenant |
EP0583130A2 (fr) * | 1992-08-10 | 1994-02-16 | Dow Corning Corporation | Composition de silicone dispersable dans l'eau |
EP0596304A1 (fr) * | 1992-10-31 | 1994-05-11 | Th. Goldschmidt AG | Compositions cosmétiques et pharmaceutiques |
EP0610014A1 (fr) * | 1993-02-05 | 1994-08-10 | Dow Corning Corporation | Compositions pour le soin de la peau à base de silicone |
WO1995031978A1 (fr) * | 1994-05-19 | 1995-11-30 | The Procter & Gamble Company | Compositions anti-acne |
US5534246A (en) * | 1994-08-29 | 1996-07-09 | Helene Curtis, Inc. | Topically-effective compositions |
DE19518815A1 (de) * | 1995-05-23 | 1996-11-28 | Beiersdorf Ag | Kosmetische oder dermatologische Zubereitungen mit einem Gehalt an alpha-Hydroxyfettsäuren |
WO1997021423A1 (fr) * | 1995-12-11 | 1997-06-19 | The Procter & Gamble Company | Composition topique de retinoide |
EP0568102B1 (fr) * | 1992-05-01 | 1997-08-27 | Dow Corning Toray Silicone Company, Limited | Composition de gel de silicone |
FR2754176A1 (fr) * | 1996-10-07 | 1998-04-10 | Roche Posay Lab Pharma | Emulsion e/h a forte teneur en electrolytes et leur utilisation en dermo-cosmetique, notamment pour traiter les phenomenes d'irritation et/ou de peaux sensibles |
EP0855178A2 (fr) * | 1997-01-27 | 1998-07-29 | Kao Corporation | Produits de soins capillaires contenant un alpha-hydroxyacide et un silicone élastomérique |
WO1999000103A1 (fr) * | 1997-06-27 | 1999-01-07 | Unilever Plc | Compositions cosmetiques sous forme d'emulsions translucides |
WO1999009950A1 (fr) * | 1997-08-22 | 1999-03-04 | The Procter & Gamble Company | Compositions de lavage |
WO1999009951A1 (fr) * | 1997-08-22 | 1999-03-04 | The Procter & Gamble Company | Compositions de lavage |
WO1999009947A1 (fr) * | 1997-08-22 | 1999-03-04 | The Procter & Gamble Company | Compositions de lavage |
EP0914814A1 (fr) * | 1997-03-04 | 1999-05-12 | Shiseido Company Limited | Composition d'emulsion |
WO2000037036A1 (fr) * | 1998-12-18 | 2000-06-29 | Kao Corporation | Composition desodorisante |
US6235275B1 (en) | 1999-06-25 | 2001-05-22 | Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. | Water-in-oil hair conditioner with lamellar dispersion in water phase |
EP1149872A2 (fr) * | 2000-04-13 | 2001-10-31 | Clariant Life Science Molecules (Florida) Inc. | Copolymère d'alkylméthylsiloxane, de diméthylsiloxane et de polyalkylèneoxide |
USH2043H1 (en) | 1997-05-23 | 2002-08-06 | The Procter & Gamble Company | Skin care compositions |
WO2003007892A2 (fr) * | 2001-07-07 | 2003-01-30 | Beiersdorf Ag | Preparations cosmetiques et dermatologiques contenant un electrolyte pour le traitement et la prevention active de la peau seche et d'autres modifications negatives de l'homeostase de la peau |
EP1336644A1 (fr) * | 2000-10-26 | 2003-08-20 | Shiseido Company, Ltd. | Composition d'emulsion eau dans l'huile et produits cosmetiques prepares au moyen de cette composition |
US6685952B1 (en) | 1999-06-25 | 2004-02-03 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Personal care compositions and methods-high internal phase water-in-volatile silicone oil systems |
EP1062936B2 (fr) † | 1999-06-18 | 2009-02-25 | L'oreal | Composition de cosmétique capillaire sous forme d'émulsion d'eau-dans-silicone comprenant au moins un polymère fixant |
WO2011092119A3 (fr) * | 2010-02-01 | 2011-12-15 | Beiersdorf Ag | Préparations stabilisées à base d'une émulsion eau dans le silicone ou silicone dans l'eau comprenant des butylène glycols |
KR101359810B1 (ko) * | 2007-09-04 | 2014-02-07 | 주식회사 엘지생활건강 | 겔상 화장료 조성물 및 이를 포함하는 모발용 화장품 |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07110807B2 (ja) * | 1990-12-07 | 1995-11-29 | 花王株式会社 | 皮膚保護剤組成物 |
KR19990038862A (ko) * | 1997-11-07 | 1999-06-05 | 성재갑 | 안료를 함유한 수중실리콘 유화형 화장료 조성물 |
GB0007139D0 (en) * | 1999-09-29 | 2000-05-17 | Dow Corning Sa | Method for forming a silicone coating on a substrate |
KR100327709B1 (ko) * | 1999-12-23 | 2002-03-09 | 성재갑 | 왁스를 함유하지 않는 오일-프리형 실리콘중수 유화형화장료 조성물 |
JP2002212021A (ja) * | 2001-01-12 | 2002-07-31 | Naris Cosmetics Co Ltd | 化粧料 |
DE10123771B4 (de) * | 2001-05-16 | 2019-01-10 | Beiersdorf Ag | Verwendung von Elektrolyten zur Stärkung der Barrierefunktion der Haut |
EP1523300B1 (fr) * | 2002-07-22 | 2007-10-03 | Unilever N.V. | Procédé de soin des cheveux caractérisé par l'application d'acide 2-hydroxyalcanoïque |
DE10234885B4 (de) * | 2002-07-31 | 2005-03-10 | Beiersdorf Ag | Kosmetische und/oder dermatologische Silikon-in Wasser-Emulsionen und transparentes Packmittel enthaltend diese Sonnenschutzzubereitungen |
DE10341179A1 (de) * | 2003-09-06 | 2005-03-31 | Beiersdorf Ag | Wirkstoffkombination gegen Akne |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0007785A2 (fr) * | 1978-07-24 | 1980-02-06 | Unilever Plc | Compositions de traitement de la peau, procédé pour leur préparation et applicateur contenant lesdites compositions |
EP0271925A2 (fr) * | 1986-12-19 | 1988-06-22 | Revlon Consumer Products Corporation | Compositions cosmétiques comprenant une émulsion eau-dans-l'huile contenant du pigment |
JPH01236936A (ja) * | 1988-03-15 | 1989-09-21 | Kobayashi Kose Co Ltd | 乳化組成物 |
EP0347198A1 (fr) * | 1988-06-16 | 1989-12-20 | Unilever Plc | Composition cosmétique |
EP0373661A2 (fr) * | 1988-12-14 | 1990-06-20 | Kao Corporation | Emulsion cosmétique de type eau dans huile |
-
1989
- 1989-12-07 GB GB898927703A patent/GB8927703D0/en active Pending
-
1990
- 1990-11-30 CA CA002031285A patent/CA2031285A1/fr not_active Abandoned
- 1990-12-04 DK DK90313142.3T patent/DK0435483T3/da active
- 1990-12-04 ES ES90313142T patent/ES2063933T3/es not_active Expired - Lifetime
- 1990-12-04 DE DE69013659T patent/DE69013659T2/de not_active Expired - Fee Related
- 1990-12-04 AT AT90313142T patent/ATE113201T1/de not_active IP Right Cessation
- 1990-12-04 EP EP90313142A patent/EP0435483B1/fr not_active Expired - Lifetime
- 1990-12-07 JP JP2407354A patent/JPH04159204A/ja active Pending
Patent Citations (5)
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EP0007785A2 (fr) * | 1978-07-24 | 1980-02-06 | Unilever Plc | Compositions de traitement de la peau, procédé pour leur préparation et applicateur contenant lesdites compositions |
EP0271925A2 (fr) * | 1986-12-19 | 1988-06-22 | Revlon Consumer Products Corporation | Compositions cosmétiques comprenant une émulsion eau-dans-l'huile contenant du pigment |
JPH01236936A (ja) * | 1988-03-15 | 1989-09-21 | Kobayashi Kose Co Ltd | 乳化組成物 |
EP0347198A1 (fr) * | 1988-06-16 | 1989-12-20 | Unilever Plc | Composition cosmétique |
EP0373661A2 (fr) * | 1988-12-14 | 1990-06-20 | Kao Corporation | Emulsion cosmétique de type eau dans huile |
Non-Patent Citations (2)
Title |
---|
December 1989, abstract no. 124942j, Columbus, Ohio, US; & JP-A-1 236 936 (KOBAYASHI KASEI, CO., LTD) 21-09-1989 (Cat. X,Y) (Claims 1,3,6-10,13,15) * |
STN, FILE SUPPLIER KARLSRUHE, FILE CHEMICAL ABSTRACT, vol. 112, no. 14, 15th December 1989, abstract no. 124942j, Columbus, Ohio, US; & JP-A-1 236 936 (KOBAYASHI KASEI, CO., LTD) 21-09-1989 (Cat. X,Y) (Claims 1,3,6-10,13,15) * |
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EP0495596A1 (fr) * | 1991-01-17 | 1992-07-22 | Dow Corning Corporation | Alkylméthylsiloxanes pour le soin de la peau |
EP0529848A1 (fr) * | 1991-08-26 | 1993-03-03 | Dow Corning Corporation | Mélanges d'alkylméthylsiloxanes pour le soin de la peau |
EP0556660A1 (fr) * | 1992-02-13 | 1993-08-25 | Beiersdorf Aktiengesellschaft | Utilisation d'acides gras alpha-hydroxyliques ainsi que les compositions les contenant |
EP0568102B1 (fr) * | 1992-05-01 | 1997-08-27 | Dow Corning Toray Silicone Company, Limited | Composition de gel de silicone |
EP0583130A2 (fr) * | 1992-08-10 | 1994-02-16 | Dow Corning Corporation | Composition de silicone dispersable dans l'eau |
EP0583130A3 (en) * | 1992-08-10 | 1994-06-01 | Dow Corning | Water dispersible silicone composition |
EP0596304A1 (fr) * | 1992-10-31 | 1994-05-11 | Th. Goldschmidt AG | Compositions cosmétiques et pharmaceutiques |
EP0610014A1 (fr) * | 1993-02-05 | 1994-08-10 | Dow Corning Corporation | Compositions pour le soin de la peau à base de silicone |
WO1995031978A1 (fr) * | 1994-05-19 | 1995-11-30 | The Procter & Gamble Company | Compositions anti-acne |
CN1079669C (zh) * | 1994-05-19 | 2002-02-27 | 赫英尔柯特赫尔曼两合公司 | 防痤疮组合物 |
US5534246A (en) * | 1994-08-29 | 1996-07-09 | Helene Curtis, Inc. | Topically-effective compositions |
DE19518815A1 (de) * | 1995-05-23 | 1996-11-28 | Beiersdorf Ag | Kosmetische oder dermatologische Zubereitungen mit einem Gehalt an alpha-Hydroxyfettsäuren |
WO1997021423A1 (fr) * | 1995-12-11 | 1997-06-19 | The Procter & Gamble Company | Composition topique de retinoide |
FR2754176A1 (fr) * | 1996-10-07 | 1998-04-10 | Roche Posay Lab Pharma | Emulsion e/h a forte teneur en electrolytes et leur utilisation en dermo-cosmetique, notamment pour traiter les phenomenes d'irritation et/ou de peaux sensibles |
AU694702B2 (en) * | 1996-10-07 | 1998-07-23 | La Roche Posay Laboratoire Pharmaceutique | W/O emulsion with a high electrolyte content, and its use in dermo-cosmetics, in particular for treating phenomena of irritation and/or of sensitive skin |
US6599512B1 (en) | 1996-10-07 | 2003-07-29 | La Roche Posay-Laboratoire Pharmaceutique | Electrolyte content w/o emulsions for treating irritated/sensitive skins |
EP0855178A2 (fr) * | 1997-01-27 | 1998-07-29 | Kao Corporation | Produits de soins capillaires contenant un alpha-hydroxyacide et un silicone élastomérique |
EP0855178A3 (fr) * | 1997-01-27 | 1999-05-06 | Kao Corporation | Produits de soins capillaires contenant un alpha-hydroxyacide et un silicone élastomérique |
EP0914814A1 (fr) * | 1997-03-04 | 1999-05-12 | Shiseido Company Limited | Composition d'emulsion |
EP0914814A4 (fr) * | 1997-03-04 | 2004-12-08 | Shiseido Co Ltd | Composition d'emulsion |
USH2043H1 (en) | 1997-05-23 | 2002-08-06 | The Procter & Gamble Company | Skin care compositions |
KR100394424B1 (ko) * | 1997-06-27 | 2003-08-09 | 유니레버 엔.브이. | 투명 에멀젼 코스메틱 조성물 |
AU726848B2 (en) * | 1997-06-27 | 2000-11-23 | Unilever Plc | Clear emulsion cosmetic compositions |
WO1999000103A1 (fr) * | 1997-06-27 | 1999-01-07 | Unilever Plc | Compositions cosmetiques sous forme d'emulsions translucides |
WO1999009951A1 (fr) * | 1997-08-22 | 1999-03-04 | The Procter & Gamble Company | Compositions de lavage |
WO1999009950A1 (fr) * | 1997-08-22 | 1999-03-04 | The Procter & Gamble Company | Compositions de lavage |
WO1999009947A1 (fr) * | 1997-08-22 | 1999-03-04 | The Procter & Gamble Company | Compositions de lavage |
WO2000037036A1 (fr) * | 1998-12-18 | 2000-06-29 | Kao Corporation | Composition desodorisante |
US6605288B1 (en) | 1998-12-18 | 2003-08-12 | Kao Corporation | Deodorant composition |
EP1062936B2 (fr) † | 1999-06-18 | 2009-02-25 | L'oreal | Composition de cosmétique capillaire sous forme d'émulsion d'eau-dans-silicone comprenant au moins un polymère fixant |
US6685952B1 (en) | 1999-06-25 | 2004-02-03 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Personal care compositions and methods-high internal phase water-in-volatile silicone oil systems |
US6235275B1 (en) | 1999-06-25 | 2001-05-22 | Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. | Water-in-oil hair conditioner with lamellar dispersion in water phase |
EP1149872A3 (fr) * | 2000-04-13 | 2002-03-06 | Clariant Life Science Molecules (Florida) Inc. | Copolymère d'alkylméthylsiloxane, de diméthylsiloxane et de polyalkylèneoxide |
EP1149872A2 (fr) * | 2000-04-13 | 2001-10-31 | Clariant Life Science Molecules (Florida) Inc. | Copolymère d'alkylméthylsiloxane, de diméthylsiloxane et de polyalkylèneoxide |
EP1336644A1 (fr) * | 2000-10-26 | 2003-08-20 | Shiseido Company, Ltd. | Composition d'emulsion eau dans l'huile et produits cosmetiques prepares au moyen de cette composition |
EP1336644A4 (fr) * | 2000-10-26 | 2007-10-31 | Shiseido Co Ltd | Composition d'emulsion eau dans l'huile et produits cosmetiques prepares au moyen de cette composition |
WO2003007892A2 (fr) * | 2001-07-07 | 2003-01-30 | Beiersdorf Ag | Preparations cosmetiques et dermatologiques contenant un electrolyte pour le traitement et la prevention active de la peau seche et d'autres modifications negatives de l'homeostase de la peau |
WO2003007892A3 (fr) * | 2001-07-07 | 2003-12-11 | Beiersdorf Ag | Preparations cosmetiques et dermatologiques contenant un electrolyte pour le traitement et la prevention active de la peau seche et d'autres modifications negatives de l'homeostase de la peau |
KR101359810B1 (ko) * | 2007-09-04 | 2014-02-07 | 주식회사 엘지생활건강 | 겔상 화장료 조성물 및 이를 포함하는 모발용 화장품 |
WO2011092119A3 (fr) * | 2010-02-01 | 2011-12-15 | Beiersdorf Ag | Préparations stabilisées à base d'une émulsion eau dans le silicone ou silicone dans l'eau comprenant des butylène glycols |
Also Published As
Publication number | Publication date |
---|---|
ATE113201T1 (de) | 1994-11-15 |
GB8927703D0 (en) | 1990-02-07 |
EP0435483A3 (en) | 1991-08-07 |
CA2031285A1 (fr) | 1991-06-08 |
DE69013659D1 (de) | 1994-12-01 |
DE69013659T2 (de) | 1995-03-23 |
DK0435483T3 (da) | 1995-02-27 |
EP0435483B1 (fr) | 1994-10-26 |
JPH04159204A (ja) | 1992-06-02 |
ES2063933T3 (es) | 1995-01-16 |
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