EP0430330A2 - Suspending liquid detergent compositions - Google Patents
Suspending liquid detergent compositions Download PDFInfo
- Publication number
- EP0430330A2 EP0430330A2 EP90203017A EP90203017A EP0430330A2 EP 0430330 A2 EP0430330 A2 EP 0430330A2 EP 90203017 A EP90203017 A EP 90203017A EP 90203017 A EP90203017 A EP 90203017A EP 0430330 A2 EP0430330 A2 EP 0430330A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- detergent composition
- composition according
- weight
- compositions
- detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/08—Polycarboxylic acids containing no nitrogen or sulfur
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0026—Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Definitions
- the invention relates to aqueous built detergent compositions which are pourable, and have suspending properties.
- Aqueous pourable detergent compositions are well known in the Art, but it is only recently that C10-C16 alk(en)yl substituted succinic acids have been used as builders in these compositions, which have been disclosed in EP-A-0 293 040 and EPA- 0 294 904.
- compositions are very satisfactory in terms of their cleaning performance, but ingredients in the form of solid particles could not be stably suspended in these compositions, and therefore it is recommended to use only liquid ingredients during their manufacture. Indeed, the use of ingredients in the form of solid particles inevitably leads to sedimentation.
- compositions of the prior art tend to collapse also if hydrophilic solvents are incorporated in important amounts; it is another object of the present invention to provide aqueous, pourable detergent compositions, which contain C10-C16 alk(en)yl substituted succinic acids and have suspending properties, and which may further contain hydrophilic solvents, such as ethanol.
- the present invention addresses the problem of formulating an aqueous detergent composition which contains C10-C16 alk(en)yl substituted succinic acids, and which has suspending properties.
- neat phase refers to an essentially lamella-structured or spherulitic composition in which aqueous layers are separated by double layers of hydrophobic materials. Such a lamellar structure can be identified by observing the product through an optical microscope, between crossed Nichol prisms.
- compositions of the invention always contains an anionic surfactant.
- Suitable anionic surfactants can be represented by the general formula R1SO3M wherein R1 represents a hydrocarbon group selected from the group consisting of straight or branched alkyl radicals containing from about 8 to about 24 carbon atoms and alkyl phenyl radicals containing from about 9 to about 15 carbon atoms in the alkyl group.
- M is a salt forming cation which typically is selected from the group consisting of sodium, potassium, ammonium, and mixtures thereof.
- a preferred synthetic anionic surfactant is a water-soluble salt of an alkylbenzene sulfonic acid containing from 9 to 15 carbon atoms in the alkyl group.
- Another preferred synthetic anionic surfactant is a water-soluble salt of an alkyl sulfate or an alkyl polyethoxylate ether sulfate wherein the alkyl group contains from about 8 to 24, preferably from about 10 to about 18 carbon atoms and there are from about 1 to about 20, preferably from about 1 to about 12 ethoxy groups.
- Other suitable anionic surfactants are disclosed in US Patent 4,170,565, Flesher et al., issued October 9, 1979.
- Suitable anionic synthetic surface-active salts are selected from the group of sulfonates and sulfates.
- Preferred anionic synthetic water-soluble sulfonate or sulfate salts have in their molecular structure an alkyl radical containing from about 8 to about 22 carbon atoms.
- Such preferred anionic surfactant salts are the reaction products obtained by sulfating C8-C18 fatty alcohols derived from tallow and coconut oil; alkylbenzene sulfonates wherein the alkyl group contains from about 9 to 15 carbon atoms; sodium alkylglyceryl ether sulfonates; ether sulfates of fatty alcohols derived from tallow and coconut oils; coconut fatty acid monoglyceride sulfates and sulfonates; and water-soluble salts of paraffin sulfonates having from about 8 to about 22 carbon atoms in the alkyl chain.
- Sulfonated olefin surfactants as more fully described in e.g. US Patent Specification 3,332,880 can also be used.
- the neutralizing cation for the anionic synthetic sulfonates and/or sulfates is represented by conventional cations which are widely used in detergent technology such as sodium and potassium.
- a particularly preferred anionic synthetic surfactant component herein is represented by the water-soluble salts of an alkylbenzene sulfonic acid, preferably sodium alkylbenzene sulfonates having from about 10 to 13 carbon atoms in the alkyl group.
- compositions of the invention may additionally contain zwitterionic surfactants which include derivatives of aliphatic quaternary ammonium, phosphonium, and sulphonium compounds in which the aliphatic moiety can be straight or branched chain and wherein one of the aliphatic substituents contains from about 8 to about 24 carbon atoms and another substituent contains, at least, an anionic water-solubilizing group.
- Particularly preferred zwitterionic materials are the ethoxylated ammonium sulfonates and sulfates disclosed in US Patents 3,925,262, Laughlin et al., issued December 9, 1975 and 3,929,678, Laughlin et al., issued December 30, 1975.
- compositions may also contain small amounts, i.e. below 1% by weight of the total composition, of cationic surfactants.
- suitable cationic surfactants include quaternary ammonium compounds of the formula R1R2R3R4N+X ⁇ , wherein R1 is C12-C20 alkyl or hydroxyalkyl; R2 is C1-C4 alkyl or C12-C20 alkyl or hydroxyalkyl or C1-C4 hydroxyalkyl; R3 and R4 are each C1-C4 alkyl or hydroxyalkyl, or C6-C8 aryl or alkylaryl; and X ⁇ is halogen.
- Preferred are mono-long chain quaternary ammonium compounds (i. e., compounds of the above formula wherein R2 is C1-C4 alkyl or hydroxyalkyl).
- the total amount of surfactant in the compositions is of from 5% to 60%, preferably 15% to 40% by weight of the total composition.
- Preferred compounds according to this definition are condensation products of ethylene oxide with a fatty alcohol in the presence of an acidic or basic catalyst.
- fatty alcohols having from 13 to 15 carbon atoms are used to make such condensation product.
- solvents as butanol, butoxyethanol, benzylalcohol, hexyl diglycol ether, butyl diglycolether, and mixtures thereof.
- the compounds are present in the compositions of the invention in an amount of at least 7,5% by weight of the total composition, preferably from 8% to 15% by weight.
- compositions of the invention also contain as a builder system, from 5% to 20% by weight of the total composition of a C10-C16 alk(en)yl substituted succinic acid, preferably from 8% to 15% by weight of the total composition.
- the preferred builder for use herein is dodecenyl substituted succinic acid.
- compositions of the invention contain water, in an amount of from 20% tp 60% by weight of the composition.
- compositions of the invention may contain an electrolyte such as sodium bromide, chloride, iodide, nitrate or acetate, preferably sodium chloride.
- an electrolyte such as sodium bromide, chloride, iodide, nitrate or acetate, preferably sodium chloride.
- Suitable enzymes include the detergent proteases, amylases, lipases and cellulases.
- Enzymatic stabilizing agents for use in aqueous liquid detergents which are well known, can also be used herein; preferred is a salt of formic acid, e.g., sodium formate. The amount of this stabilizing agent typically ranges from 0.5% to 2%.
- organic builders are represented by polyacids such as citric acid, nitrilotriacetic acid, and mixtures of tartrate monosuccinate with tartrate disuccinate.
- Preferred builders for use herein are citric acid.
- Polymeric carboxylate builders inclusive of polyacrylates, polydydroxy acrylates and polyacrylates/polymaleates copolymers can also be used.
- compositions of the invention may also contain chelants, such as ethylenediaminotetracetic acid, diethylenetriaminopentacetic acid, ethylenediamino disuccinic acid or the water-soluble alkali metals thereof.
- chelants such as ethylenediaminotetracetic acid, diethylenetriaminopentacetic acid, ethylenediamino disuccinic acid or the water-soluble alkali metals thereof.
- Other additives include organo-phosphonic acids; particularly preferred are ethylenediamino tetramethylenephosphonic acid, hexamethylenediamino tetramethylenephosphonic acid, diethylenetriamino pentamethylenephosphonic acid, aminotrimethylenephosphonic acid and hydroxyethylidene 1,1 diphosphonic acid.
- compositions herein can contain further optional ingredients which are mostly used in additive levels, usually below about 5%.
- additives include : Suds regulants, opacifiers, agents to improve the machine compatibility in relation to enamel-coated surfaces, bactericides, dyes, perfumes, brighteners and the like.
- compositions under various usage conditions can require the utilization of a suds regulant like polysiloxanes such as dimethylpolysiloxane, also frequently termed silicones. These silicones are frequently used in a level not exceeding 1.5%, most preferably between 0.1% and 1.0%.
- opacifiers can also be desirable to utilize opacifiers inasmuch as they contribute to create a uniform appearance of the concentrated liquid detergent compositions.
- suitable opacifiers include : polystyrene commercially known as LYTRON 621 manufactured by MONSANTO CHEMICAL CORPORATION. The opacifiers are frequently used in an amount from 0.3% to 1.5%.
- additives include : sodium carboxymethylcellulose; hydroxy-C1 ⁇ 6-alkylcellulose; polycarboxylic homo- or copolymeric ingredients, such as : polymaleic acid; a copolymer of maleic anhydride and methylvinylether in a molar ratio of 2:1 to 1:2; and a copolymer of an ethylenically unsaturated monocarboxylic acid monomer, having not more than 5, preferably 3 or 4 carbon atoms, for example (meth)acrylic acid, and an ethylenically unsaturated dicarboxylic acid monomer having not more than 6, preferably 4 carbon atoms, whereby the molar ratio of the monomers is in the range from 1:4 to 4:1, said copolymer being described in more detail in EUROPEAN Patent Application 0 066 915, filed May 17, 1982.
- compositions of the invention have acquired suspending properties, due to the formulation as a neat phase, it is possible to use ingredients which are in the form of solid particles. There is no restriction as to the nature of the ingredient, but these ingredients are preferably in the form of solid particles having an average diameter size in the range of from 1 micrometer to 350 micrometers.
- Such ingredients can be zeolites, clays, suds suppressors such as silica waxes, any encapsulated material, and a highly preferred ingredient to be suspended in the compositions are solid, water-soluble peroxygen bleaching compounds, preferably perborates, persulfates, peroxydisulfates, perphosphates and the crystalline peroxyhydrates formed by reacting hydrogen peroxide with sodium carbonate or urea.
- perborates preferably perborates, persulfates, peroxydisulfates, perphosphates and the crystalline peroxyhydrates formed by reacting hydrogen peroxide with sodium carbonate or urea.
- Preferred are sodium perborate, monohydrate and tetrahydrate, and sodium percarbonate.
- the compositions preferably contain water miscible organic solvents including ethanol, n-propanol, isopropanol polyethylene glycol, dipropylene glycol, hexylene glycol, methoxyethanol, ethoxyethanol, ethyldiglycolether, and mixtures thereof.
- the compositions will contain from 4% to 10% of the total composition of ethanol, as a stabilizing system for the peroxygen compounds.
- the pH as is of the compositions should be in the range of from 8 to 12, preferably 9 to 11.
- composition obtained by mixing together the listed ingredients in the listed proportions.
- a premix which is made with water, diethylene triamine pentamethylene phosphonic acid and citric acid is neutralized to pH 7 with sodium hydroxide.
- the solvents ethanol and hexyl diglycolether
- the linear alkyl benzene sulfonate and the dodecenyl substituted succinic acid are added while cooling the mixture; the pH is then trimmed to 10 with sodium hydroxide.
- the composition at this point is not yet a neat phase, but an isotropic solution characterized by its low viscosity and transparency.
- the neat phase which is formed on adding the C14alcohol 3 times ethoxylated can be identified by a higher viscosity and a translucent appearance; to confirm the formation of the neat phase structure, the composition can be examined with an optical microscope, between crossed Nichol prisms.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
- The invention relates to aqueous built detergent compositions which are pourable, and have suspending properties.
- Aqueous pourable detergent compositions are well known in the Art, but it is only recently that C₁₀-C₁₆ alk(en)yl substituted succinic acids have been used as builders in these compositions, which have been disclosed in EP-A-0 293 040 and EPA- 0 294 904.
- These compositions are very satisfactory in terms of their cleaning performance, but ingredients in the form of solid particles could not be stably suspended in these compositions, and therefore it is recommended to use only liquid ingredients during their manufacture. Indeed, the use of ingredients in the form of solid particles inevitably leads to sedimentation.
- Pourable compositions having such suspending properties have been disclosed for instance in EP-A -0 151 884, EP-A-0 120 638, EP-A-0 092 363, GB-A-2 023 637, US-A-4 692 271; all the compositions disclosed in these documents do not contain C₁₀-C₁₆ alk(en)yl substituted succinic acids, and it has been found that said compositions would lose their suspending properties upon incorporation of said substituted succinic acids.
- It is an object of the present invention to provide aqueous, pourable detergent compositions, which contain C₁₀-C₁₆ alk(en)yl substituted succinic acids and which further have suspending properties.
- Further, the compositions of the prior art tend to collapse also if hydrophilic solvents are incorporated in important amounts; it is another object of the present invention to provide aqueous, pourable detergent compositions, which contain C₁₀-C₁₆ alk(en)yl substituted succinic acids and have suspending properties, and which may further contain hydrophilic solvents, such as ethanol.
- It has now been found that aqueous, pourable detergent composition containing an anionic surfactant and C₁₀-C₁₆ alk(en)yl substituted succinic acid could acquire suspending properties by formulating them as neat phases, by incorporating at least 7.5% by weight of the total composition of a compound of the formula
RO(CH₂CH₂O)yH
wherein:
-R is a Cn alkyl, alkenyl, alkynyl, aryl or alkyl aryl group
-and n is an integer of from 4 to 22
-and y = 0 to 4
-and n/y ≧ 2 if y 0 - The present invention addresses the problem of formulating an aqueous detergent composition which contains C₁₀-C₁₆ alk(en)yl substituted succinic acids, and which has suspending properties.
- It has been found that such composition can be formulated as a neat phase as follows. In the following, the expression neat phase (or G-phase) refers to an essentially lamella-structured or spherulitic composition in which aqueous layers are separated by double layers of hydrophobic materials.
Such a lamellar structure can be identified by observing the product through an optical microscope, between crossed Nichol prisms. - The neat phases are characterized by specific textures which are described for instance by F.B. Rosevear, journal of the American Oil Chemists Society, vol. 3, page 628, 1954.
- The compositions of the invention always contains an anionic surfactant.
- Suitable anionic surfactants can be represented by the general formula R¹SO³M wherein R¹ represents a hydrocarbon group selected from the group consisting of straight or branched alkyl radicals containing from about 8 to about 24 carbon atoms and alkyl phenyl radicals containing from about 9 to about 15 carbon atoms in the alkyl group. M is a salt forming cation which typically is selected from the group consisting of sodium, potassium, ammonium, and mixtures thereof.
- A preferred synthetic anionic surfactant is a water-soluble salt of an alkylbenzene sulfonic acid containing from 9 to 15 carbon atoms in the alkyl group. Another preferred synthetic anionic surfactant is a water-soluble salt of an alkyl sulfate or an alkyl polyethoxylate ether sulfate wherein the alkyl group contains from about 8 to 24, preferably from about 10 to about 18 carbon atoms and there are from about 1 to about 20, preferably from about 1 to about 12 ethoxy groups. Other suitable anionic surfactants are disclosed in US Patent 4,170,565, Flesher et al., issued October 9, 1979.
- Suitable anionic synthetic surface-active salts are selected from the group of sulfonates and sulfates. Preferred anionic synthetic water-soluble sulfonate or sulfate salts have in their molecular structure an alkyl radical containing from about 8 to about 22 carbon atoms.
- Exemples of such preferred anionic surfactant salts are the reaction products obtained by sulfating C₈-C₁₈ fatty alcohols derived from tallow and coconut oil; alkylbenzene sulfonates wherein the alkyl group contains from about 9 to 15 carbon atoms; sodium alkylglyceryl ether sulfonates; ether sulfates of fatty alcohols derived from tallow and coconut oils; coconut fatty acid monoglyceride sulfates and sulfonates; and water-soluble salts of paraffin sulfonates having from about 8 to about 22 carbon atoms in the alkyl chain. Sulfonated olefin surfactants as more fully described in e.g. US Patent Specification 3,332,880 can also be used. The neutralizing cation for the anionic synthetic sulfonates and/or sulfates is represented by conventional cations which are widely used in detergent technology such as sodium and potassium.
- A particularly preferred anionic synthetic surfactant component herein is represented by the water-soluble salts of an alkylbenzene sulfonic acid, preferably sodium alkylbenzene sulfonates having from about 10 to 13 carbon atoms in the alkyl group.
- The compositions of the invention may additionally contain zwitterionic surfactants which include derivatives of aliphatic quaternary ammonium, phosphonium, and sulphonium compounds in which the aliphatic moiety can be straight or branched chain and wherein one of the aliphatic substituents contains from about 8 to about 24 carbon atoms and another substituent contains, at least, an anionic water-solubilizing group. Particularly preferred zwitterionic materials are the ethoxylated ammonium sulfonates and sulfates disclosed in US Patents 3,925,262, Laughlin et al., issued December 9, 1975 and 3,929,678, Laughlin et al., issued December 30, 1975.
- The compositions may also contain small amounts, i.e. below 1% by weight of the total composition, of cationic surfactants. Examples of suitable cationic surfactants include quaternary ammonium compounds of the formula R₁R₂R₃R₄N⁺X⁻, wherein R₁ is C₁₂-C₂₀ alkyl or hydroxyalkyl; R₂ is C₁-C₄ alkyl or C₁₂-C₂₀ alkyl or hydroxyalkyl or C₁-C₄ hydroxyalkyl; R₃ and R₄ are each C₁-C₄ alkyl or hydroxyalkyl, or C₆-C₈ aryl or alkylaryl; and X⁻ is halogen. Preferred are mono-long chain quaternary ammonium compounds (i. e., compounds of the above formula wherein R₂ is C₁-C₄ alkyl or hydroxyalkyl).
- The total amount of surfactant in the compositions is of from 5% to 60%, preferably 15% to 40% by weight of the total composition.
-
- Preferred compounds according to this definition are condensation products of ethylene oxide with a fatty alcohol in the presence of an acidic or basic catalyst.
- Preferably, fatty alcohols having from 13 to 15 carbon atoms are used to make such condensation product.
- Also preferred are such solvents as butanol, butoxyethanol, benzylalcohol, hexyl diglycol ether, butyl diglycolether, and mixtures thereof.
- The compounds are present in the compositions of the invention in an amount of at least 7,5% by weight of the total composition, preferably from 8% to 15% by weight.
- The compositions of the invention also contain as a builder system, from 5% to 20% by weight of the total composition of a C₁₀-C₁₆ alk(en)yl substituted succinic acid, preferably from 8% to 15% by weight of the total composition. The preferred builder for use herein is dodecenyl substituted succinic acid.
- Importantly, the compositions of the invention contain water, in an amount of from 20% tp 60% by weight of the composition.
- All the hereinbefore mentioned ingredients are mixed together so as to obtain a compositon which is structured as a neat phase.
- Optionally, the compositions of the invention may contain an electrolyte such as sodium bromide, chloride, iodide, nitrate or acetate, preferably sodium chloride.
- Other optionals include detergent enzymes. Suitable enzymes include the detergent proteases, amylases, lipases and cellulases. Enzymatic stabilizing agents for use in aqueous liquid detergents which are well known, can also be used herein; preferred is a salt of formic acid, e.g., sodium formate. The amount of this stabilizing agent typically ranges from 0.5% to 2%.
- Examples of organic builders are represented by polyacids such as citric acid, nitrilotriacetic acid, and mixtures of tartrate monosuccinate with tartrate disuccinate. Preferred builders for use herein are citric acid. Polymeric carboxylate builders inclusive of polyacrylates, polydydroxy acrylates and polyacrylates/polymaleates copolymers can also be used.
- The compositions of the invention may also contain chelants, such as ethylenediaminotetracetic acid, diethylenetriaminopentacetic acid, ethylenediamino disuccinic acid or the water-soluble alkali metals thereof. Other additives include organo-phosphonic acids; particularly preferred are ethylenediamino tetramethylenephosphonic acid, hexamethylenediamino tetramethylenephosphonic acid, diethylenetriamino pentamethylenephosphonic acid, aminotrimethylenephosphonic acid and hydroxyethylidene 1,1 diphosphonic acid.
- The compositions herein can contain further optional ingredients which are mostly used in additive levels, usually below about 5%. Examples of the like additives include : Suds regulants, opacifiers, agents to improve the machine compatibility in relation to enamel-coated surfaces, bactericides, dyes, perfumes, brighteners and the like.
- The beneficial utilization of the claimed compositions under various usage conditions can require the utilization of a suds regulant like polysiloxanes such as dimethylpolysiloxane, also frequently termed silicones. These silicones are frequently used in a level not exceeding 1.5%, most preferably between 0.1% and 1.0%.
- It can also be desirable to utilize opacifiers inasmuch as they contribute to create a uniform appearance of the concentrated liquid detergent compositions. Examples of suitable opacifiers include : polystyrene commercially known as LYTRON 621 manufactured by MONSANTO CHEMICAL CORPORATION. The opacifiers are frequently used in an amount from 0.3% to 1.5%.
- It can further be desirable to add from 0.1% to 5% of known antiredeposition and/or compatibilizing agents. Examples of the like additives include : sodium carboxymethylcellulose; hydroxy-C₁₋₆-alkylcellulose; polycarboxylic homo- or copolymeric ingredients, such as : polymaleic acid; a copolymer of maleic anhydride and methylvinylether in a molar ratio of 2:1 to 1:2; and a copolymer of an ethylenically unsaturated monocarboxylic acid monomer, having not more than 5, preferably 3 or 4 carbon atoms, for example (meth)acrylic acid, and an ethylenically unsaturated dicarboxylic acid monomer having not more than 6, preferably 4 carbon atoms, whereby the molar ratio of the monomers is in the range from 1:4 to 4:1, said copolymer being described in more detail in EUROPEAN Patent Application 0 066 915, filed May 17, 1982.
- Since the compositions of the invention have acquired suspending properties, due to the formulation as a neat phase, it is possible to use ingredients which are in the form of solid particles. There is no restriction as to the nature of the ingredient, but these ingredients are preferably in the form of solid particles having an average diameter size in the range of from 1 micrometer to 350 micrometers.
- Such ingredients can be zeolites, clays, suds suppressors such as silica waxes, any encapsulated material, and a highly preferred ingredient to be suspended in the compositions are solid, water-soluble peroxygen bleaching compounds, preferably perborates, persulfates, peroxydisulfates, perphosphates and the crystalline peroxyhydrates formed by reacting hydrogen peroxide with sodium carbonate or urea. Preferred are sodium perborate, monohydrate and tetrahydrate, and sodium percarbonate.
- If a peroxygen bleaching compound is used, the compositions preferably contain water miscible organic solvents including ethanol, n-propanol, isopropanol polyethylene glycol, dipropylene glycol, hexylene glycol, methoxyethanol, ethoxyethanol, ethyldiglycolether, and mixtures thereof. Preferably, the compositions will contain from 4% to 10% of the total composition of ethanol, as a stabilizing system for the peroxygen compounds.
- Also, in such a case, the pH as is of the compositions should be in the range of from 8 to 12, preferably 9 to 11.
- The following examples will illustrate and facilitate the understanding of the invention, but are not meant to restrict its scope.
- The following composition are obtained by mixing together the listed ingredients in the listed proportions.
- The order in which the ingredients are mixed plays no role in the achievement of the neat phase structure; it is however particularly convenient to proceed as follows, referring to example IV.
- A premix which is made with water, diethylene triamine pentamethylene phosphonic acid and citric acid is neutralized to pH 7 with sodium hydroxide. The solvents (ethanol and hexyl diglycolether) are then added.The linear alkyl benzene sulfonate and the dodecenyl substituted succinic acid are added while cooling the mixture; the pH is then trimmed to 10 with sodium hydroxide. The composition at this point is not yet a neat phase, but an isotropic solution characterized by its low viscosity and transparency. The neat phase which is formed on adding the C₁₄alcohol 3 times ethoxylated can be identified by a higher viscosity and a translucent appearance; to confirm the formation of the neat phase structure, the composition can be examined with an optical microscope, between crossed Nichol prisms.
- The sodium chloride and all minor ingredients are finally incorporated in the composition.
-
Claims (14)
RO(CH₂CH₂O)yH wherein :
- R is a Cn alkyl, alkenyl, alkynyl, aryl or alkyl aryl group
- and n is an integer of from 4 to 22
- and y = 0 to 4
- and n/y ≧ 2 if y 0
and mixtures thereof.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB8926620 | 1989-11-24 | ||
GB898926620A GB8926620D0 (en) | 1989-11-24 | 1989-11-24 | Suspending liquid detergent compositions |
GB9009823 | 1990-04-27 | ||
GB909009823A GB9009823D0 (en) | 1990-04-27 | 1990-04-27 | Suspending liquid detergent compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0430330A2 true EP0430330A2 (en) | 1991-06-05 |
EP0430330A3 EP0430330A3 (en) | 1991-12-18 |
Family
ID=26296252
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19900203017 Withdrawn EP0430330A3 (en) | 1989-11-24 | 1990-11-14 | Suspending liquid detergent compositions |
Country Status (11)
Country | Link |
---|---|
EP (1) | EP0430330A3 (en) |
JP (1) | JPH03210400A (en) |
AR (1) | AR245207A1 (en) |
AU (1) | AU650247B2 (en) |
BR (1) | BR9005930A (en) |
CA (1) | CA2030205C (en) |
IE (1) | IE904243A1 (en) |
MX (1) | MX172443B (en) |
NZ (1) | NZ236205A (en) |
PE (1) | PE31191A1 (en) |
TR (1) | TR25074A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0530708A2 (en) * | 1991-08-30 | 1993-03-10 | ALBRIGHT & WILSON UK LIMITED | Liquid laundry detergent compositions |
GB2259519A (en) * | 1991-08-30 | 1993-03-17 | Albright & Wilson | Liquid laundry detergent compositions |
EP0619368A1 (en) * | 1993-04-06 | 1994-10-12 | The Procter & Gamble Company | Concentrated liquid detergent compositions |
US5445756A (en) * | 1990-10-22 | 1995-08-29 | The Procter & Gamble Company | Stable liquid detergent compositions containing peroxygen bleach suspended by a hydropholic silica |
WO2000027190A1 (en) * | 1998-11-10 | 2000-05-18 | Menno Chemie Vertriebsges. Mbh | Agents for eliminating the adhesive capacity of helminth eggs |
US6194364B1 (en) | 1996-09-23 | 2001-02-27 | The Procter & Gamble Company | Liquid personal cleansing compositions which contain soluble oils and soluble synthetic surfactants |
US6897188B2 (en) | 2001-07-17 | 2005-05-24 | Ecolab, Inc. | Liquid conditioner and method for washing textiles |
US7682403B2 (en) | 2004-01-09 | 2010-03-23 | Ecolab Inc. | Method for treating laundry |
US8110537B2 (en) | 2003-01-14 | 2012-02-07 | Ecolab Usa Inc. | Liquid detergent composition and methods for using |
US10494591B2 (en) | 2017-06-22 | 2019-12-03 | Ecolab Usa Inc. | Bleaching using peroxyformic acid and an oxygen catalyst |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4864598B2 (en) * | 2006-08-11 | 2012-02-01 | 花王株式会社 | Cleaning composition for hard surface |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2153838A (en) * | 1984-02-13 | 1985-08-29 | Kao Corp | Liquid abrasive detergent composition |
EP0200263A2 (en) * | 1985-05-03 | 1986-11-05 | The Procter & Gamble Company | Homogeneous concentrated liquid detergent compositions containing ternary surfactant system |
EP0223306A2 (en) * | 1985-11-20 | 1987-05-27 | The Procter & Gamble Company | Liquid detergent compositions containing binary anionic surfactant system |
EP0293040A1 (en) * | 1987-05-27 | 1988-11-30 | The Procter & Gamble Company | Liquid detergent containing solid peroxygen bleach |
EP0294904A2 (en) * | 1987-06-12 | 1988-12-14 | The Procter & Gamble Company | Process for making an aqueous liquid detergent composition containing a perborate bleach |
EP0295021A2 (en) * | 1987-06-10 | 1988-12-14 | Albright & Wilson Limited | Liquid detergent compositions |
EP0385522A2 (en) * | 1989-02-27 | 1990-09-05 | Unilever N.V. | Liquid detergent composition |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE69260T1 (en) * | 1986-03-31 | 1991-11-15 | Procter & Gamble | LIQUID DETERGENTS CONTAINING AN ANIONIC SURFACE ACTIVE AGENT, A Succinic Acid Builder SALT AND A FATTY ACID. |
-
1990
- 1990-11-14 EP EP19900203017 patent/EP0430330A3/en not_active Withdrawn
- 1990-11-16 CA CA2030205A patent/CA2030205C/en not_active Expired - Lifetime
- 1990-11-16 TR TR90/1102A patent/TR25074A/en unknown
- 1990-11-22 AR AR90313443A patent/AR245207A1/en active
- 1990-11-22 PE PE1990178009A patent/PE31191A1/en unknown
- 1990-11-23 AU AU66956/90A patent/AU650247B2/en not_active Ceased
- 1990-11-23 BR BR909005930A patent/BR9005930A/en not_active Application Discontinuation
- 1990-11-23 IE IE424390A patent/IE904243A1/en unknown
- 1990-11-23 MX MX023455A patent/MX172443B/en unknown
- 1990-11-23 NZ NZ236205A patent/NZ236205A/en unknown
- 1990-11-26 JP JP2322226A patent/JPH03210400A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2153838A (en) * | 1984-02-13 | 1985-08-29 | Kao Corp | Liquid abrasive detergent composition |
EP0200263A2 (en) * | 1985-05-03 | 1986-11-05 | The Procter & Gamble Company | Homogeneous concentrated liquid detergent compositions containing ternary surfactant system |
EP0223306A2 (en) * | 1985-11-20 | 1987-05-27 | The Procter & Gamble Company | Liquid detergent compositions containing binary anionic surfactant system |
EP0293040A1 (en) * | 1987-05-27 | 1988-11-30 | The Procter & Gamble Company | Liquid detergent containing solid peroxygen bleach |
EP0295021A2 (en) * | 1987-06-10 | 1988-12-14 | Albright & Wilson Limited | Liquid detergent compositions |
EP0294904A2 (en) * | 1987-06-12 | 1988-12-14 | The Procter & Gamble Company | Process for making an aqueous liquid detergent composition containing a perborate bleach |
EP0385522A2 (en) * | 1989-02-27 | 1990-09-05 | Unilever N.V. | Liquid detergent composition |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5445756A (en) * | 1990-10-22 | 1995-08-29 | The Procter & Gamble Company | Stable liquid detergent compositions containing peroxygen bleach suspended by a hydropholic silica |
GB2259519B (en) * | 1991-08-30 | 1996-03-06 | Albright & Wilson | Concentrated aqueous surfactant compositions |
GB2259519A (en) * | 1991-08-30 | 1993-03-17 | Albright & Wilson | Liquid laundry detergent compositions |
EP0530708A3 (en) * | 1991-08-30 | 1993-06-09 | Albright & Wilson Limited | Liquid laundry detergent compositions |
EP0530708A2 (en) * | 1991-08-30 | 1993-03-10 | ALBRIGHT & WILSON UK LIMITED | Liquid laundry detergent compositions |
TR27553A (en) * | 1991-08-30 | 1995-06-08 | Albright & Wilson Uk Ltd | Concentrated aqueous surfactant compositions. |
EP0619368A1 (en) * | 1993-04-06 | 1994-10-12 | The Procter & Gamble Company | Concentrated liquid detergent compositions |
US6194364B1 (en) | 1996-09-23 | 2001-02-27 | The Procter & Gamble Company | Liquid personal cleansing compositions which contain soluble oils and soluble synthetic surfactants |
WO2000027190A1 (en) * | 1998-11-10 | 2000-05-18 | Menno Chemie Vertriebsges. Mbh | Agents for eliminating the adhesive capacity of helminth eggs |
US6579836B1 (en) | 1998-11-10 | 2003-06-17 | Menno Chemie Vertriebsges, Mbh | Agents for eliminating the adhesive capacity of helminth eggs |
US6897188B2 (en) | 2001-07-17 | 2005-05-24 | Ecolab, Inc. | Liquid conditioner and method for washing textiles |
US8110537B2 (en) | 2003-01-14 | 2012-02-07 | Ecolab Usa Inc. | Liquid detergent composition and methods for using |
US7682403B2 (en) | 2004-01-09 | 2010-03-23 | Ecolab Inc. | Method for treating laundry |
US10494591B2 (en) | 2017-06-22 | 2019-12-03 | Ecolab Usa Inc. | Bleaching using peroxyformic acid and an oxygen catalyst |
Also Published As
Publication number | Publication date |
---|---|
NZ236205A (en) | 1993-10-26 |
MX172443B (en) | 1993-12-16 |
PE31191A1 (en) | 1991-11-09 |
TR25074A (en) | 1992-11-01 |
AR245207A1 (en) | 1993-12-30 |
AU650247B2 (en) | 1994-06-16 |
JPH03210400A (en) | 1991-09-13 |
AU6695690A (en) | 1991-05-30 |
EP0430330A3 (en) | 1991-12-18 |
BR9005930A (en) | 1991-09-24 |
IE904243A1 (en) | 1991-06-05 |
CA2030205C (en) | 1995-11-21 |
CA2030205A1 (en) | 1991-05-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0293040B2 (en) | Liquid detergent containing solid peroxygen bleach | |
US5597790A (en) | Liquid detergent compositions containing a suspended peroxygen bleach | |
AU662501B2 (en) | Liquid detergent compositions containing a suspended peroxygen bleach | |
US4265777A (en) | Detergent compositions containing an aluminosilicate detergency builder and an unsaturated fatty acid soap | |
US5445756A (en) | Stable liquid detergent compositions containing peroxygen bleach suspended by a hydropholic silica | |
US5275753A (en) | Stabilized alkaline liquid detergent compositions containing enzyme and peroxygen bleach | |
EP0468103B1 (en) | Stabilized, bleach containing, liquid detergent compositions | |
CA1122094A (en) | Built liquid detergent composition | |
EP0378262B1 (en) | Liquid detergent composition containing enzyme and enzyme stabilization system | |
AU650247B2 (en) | Suspending liquid detergent compositions | |
US5250212A (en) | Liquid detergent containing solid peroxygen bleach and solvent system comprising water and lower aliphatic monoalcohol | |
EP0429124A1 (en) | Chlorine-free liquid automatic dishwashing compositions | |
US5229028A (en) | Liquid detergent compositions | |
EP0619368A1 (en) | Concentrated liquid detergent compositions | |
EP0506874A1 (en) | Concentrated aqueous liquid bleach compositions |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE CH DE DK ES FR GB GR IT LI LU NL SE |
|
PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
|
AK | Designated contracting states |
Kind code of ref document: A3 Designated state(s): AT BE CH DE DK ES FR GB GR IT LI LU NL SE |
|
17P | Request for examination filed |
Effective date: 19920603 |
|
17Q | First examination report despatched |
Effective date: 19941010 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 19950523 |