EP0418300B1 - Method for fusing developed image - Google Patents
Method for fusing developed image Download PDFInfo
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- EP0418300B1 EP0418300B1 EP89906818A EP89906818A EP0418300B1 EP 0418300 B1 EP0418300 B1 EP 0418300B1 EP 89906818 A EP89906818 A EP 89906818A EP 89906818 A EP89906818 A EP 89906818A EP 0418300 B1 EP0418300 B1 EP 0418300B1
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- European Patent Office
- Prior art keywords
- image
- roller
- substrate
- fusing
- fixing
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G13/00—Electrographic processes using a charge pattern
- G03G13/20—Fixing, e.g. by using heat
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G15/00—Apparatus for electrographic processes using a charge pattern
- G03G15/20—Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat
- G03G15/2003—Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat using heat
- G03G15/2014—Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat using heat using contact heat
- G03G15/2053—Structural details of heat elements, e.g. structure of roller or belt, eddy current, induction heating
- G03G15/2057—Structural details of heat elements, e.g. structure of roller or belt, eddy current, induction heating relating to the chemical composition of the heat element and layers thereof
Definitions
- the present invention relates generally to an imaging process and apparatus and specifically to fusing of developed images.
- a light image of an original to be copied may be recorded in the form of an electrostatic latent image upon a photoconductive member.
- a developed image may then be obtained from the latent image by application of toner particles, which may be in the form of a finely powdered solid or in liquid phase.
- liquid toner based electrostatic imaging is known.
- the basic steps of the liquid toner process are:
- the excess liquid toner and particles are removed from the image, by a step often referred to as "metering".
- This step may be carried out by use of an electrically biased reverse roller which also shears off the "fluffy" part of the imaged regions and squeezes or compacts the imaged area to prepare it for transfer.
- the transfer stage there is likely to occur a degree of smudging, smearing or squashing of the image, which detracts from its quality.
- heat and pressure are applied to the liquid toner image, as has been described above for solid toner based processes, the liquid image will be likely to again suffer from smudging, smearing or squashing.
- a degree of squash-resistance is imparted to the developed image by using fibrous toner particles prepared as follows: a thermoplastic polymer (and pigment) is plasticized with a nonpolar liquid, preferably at elevated temperature, to form a sponge, the sponge is shredded, more nonpolar liquid is added, the pieces of shredded sponge are wet-ground into particles and the grinding is continued to pull the particles apart to form fibers extending therefrom (the particles preferably having a diameter less than 5 micrometers). Finally, a charge director may be added to impart a charge of predetermined polarity to the toner particles.
- an imaging process which comprises the steps of developing an image with liquid toner including a liquid carrier and toner particles, transferring the liquid toner image to an image bearing surface of a substrate and fusing and fixing the image thereto by the application of energy and pressure, characterized by selecting at least the energy applied upon fusing and fixing, and the properties of the liquid carrier, such that at least 50% of the liquid carrier in the transferred image remains therein after fixing and fusing.
- an electrostatic imaging process which comprises the steps of developing an electrostatic image with liquid toner including at least pigmented thermoplastic polymer particles and a liquid carrier, transferring the developed liquid toner image to a substrate, transporting the substrate through a nip defined by a portion of the surface of the first roller and a portion of the surface of a second elastomer coated roller, fusing and fixing the substrate-supported developed image by the application of heat thereto from the surface of said first roller, characterized by selecting at least the temperature at which the fusing and fixing is effected, the rate of transport of the substrate, and the properties of the liquid carrier, such that at least 50% of the liquid carrier in the substrate supported image is not evaporated therefrom.
- the step of transferring comprises the sub-steps of transferring the image first to an intermediate surface and from the intermediate surface to the substrate.
- the application of energy and pressure is effected by applying a heated surface to the image.
- the heated surface is the surface of an elastomer coated roller or the surface of a continuous belt.
- the substrate is transported through a nip defined by a portion of the surface of the first elastomer-coated roller facing the image bearing surface and a portion of the surface of a second elastomer-coated roller, the coating of the second roller being softer than the coating of the first roller.
- the coating of the second roller has a thickness greater than that of the coating of the first roller.
- the ratio of the thickness of the coating of the first roller to the ratio of the thickness of the coating of the second roller is smaller than 1:10.
- the toner particles are plasticized by the carrier liquid during fusing and fixing of the image to the substrate.
- imaging apparatus comprising means for developing an image with liquid toner including a liquid carrier and toner particles; and transferring and fixing means operative to transfer the liquid toner image to an image bearing surface of a substrate and to fuse and fix the image thereto by the application of energy and pressure, characterized in that the energy applied by the transferring and fixing means that arranged such that the energy applied upon fusing and fixing in combination with the properties of the liquid carrier, are such, that at least 50% of the liquid carrier in the transferred image remains therein after fixing and fusing thereof.
- imaging apparatus comprising means for developing an electrostatic image with liquid toner including at least pigmented thermoplastic polymer particles and a liquid carrier, means for transferring the developed liquid toner image to a substrate, means for transporting the substrate through a nip defined by a portion of the surface of a first roller and a portion of the surface of a second elastomer coated roller and for fusing and fixing the substrate-supported developed image by the application of heat thereto from the surface of said first roller, characterized in that the means for transporting and for fusing and fixing are so arranged such that at the temperature at which the fusing and fixing is effected and at the rate of transport of the substrate, in combination with the properties of the liquid carrier at least 50% of the liquid carrier in the substrate supported image is not evaporated therefrom.
- FIG. 1 in which there is shown electrostatic imaging apparatus employing a liquid toner.
- the apparatus includes a metal drum 2 which carries a photoconductor 4 and which is mounted by disks 6 onto a shaft 8.
- the disks are secured to shaft 8 by a key 10 so that the shown drum assembly, which is provided in a light-proof housing (not shown), is operative to rotate with shaft 8.
- Shaft 8 is driven in any appropriate manner (not shown) in the direction of arrow 9 past a corona discharge device 12 operative to charge the surface of photoconductor 4.
- the image to be reproduced is projected onto the charged photoconductor by an optical system 14. Since shaft 8 is grounded at 15 and disks 6 are conductive, the areas struck by light conduct the charge, or a portion thereof, to ground, thus forming on the photoconductor an electrostatic latent image.
- the liquid toner is circulated from any suitable source (not shown) through a pipe 16 into a development tray 18 from which it is drawn through a pipe 20 for recirculation.
- Development electrodes 22 which may be appropriately biased as known to the art, assist in toning the electrostatic latent image as it passes into contact with the toner.
- a roller 24 whose surface moves in a direction opposite to that of the photoconductor surface, is spaced from the photoconductor surface by a spacer 25 and is operative to shear excess liquid from the developed image without disturbing it.
- An exemplary roller is shown in U.S. Patent No. 3,907,423.
- Roller 24 is driven, typically by a drive belt 26 which is in turn driven by any appropriate, known speed-controllable motor means (not shown).
- the roller is kept clean by a wiper blade 28.
- a pair of register rollers 32 and 34 is operative to feed to a transfer station, referenced generally 44, a carrier sheet 100, which is to receive the developed image.
- a corona discharge device 46 is operative to impress upon the rear of the carrier sheet a charge of polarity opposite to that of the toner particles forming the developed image. The developed image is thus drawn towards the carrier sheet.
- Rollers 32 and 34 are mounted onto and secured for rotation with respective axles 36 and 38.
- the axles are driven in synchronism so that there is no relative motion between the points of closest approach of the rollers 32 and 34 to each other.
- only one of the register rollers need be driven.
- a pick-off member 48 assists in the removal from the photoconductor of the carrier sheet bearing the developed image.
- a roller 50 co-acting with a plurality of flexible bands 52 mounted onto a plurality of rollers 54 delivers the carrier sheet to fusing and fixing apparatus, referenced generally 64. Apparatus 64 is described below in greater detail in conjunction with Fig. 2.
- a cleaning roller 56 formed of an appropriate synthetic resin as known in the art, is driven in a direction opposite to that of photoconductor 4, so as to scrub clean the surface thereof.
- insulating, nonpolar liquid may be fed through a pipe 58 to the surface of the cleaning roller 56.
- a wiper blade 60 completes the cleaning of the photoconductive surface. Any residual charge left on the photoconductive drum is extinguished by flooding the photoconductor surface with light from a lamp 62.
- Carrier sheet 100 is fed in the direction of an arrow 66 and, with the assistance of a guide member 99, between a heated roller 68 and a pressure roller 70 (see also Fig. 1).
- roller 68 is driven by any suitable means (not shown) and, as it rotates in a direction shown by arrow 72, it is also operative to cause rotation of roller 70 by friction.
- Roller 68 typically comprises a hollow metal cylindrical core in which is provided a heat source 69 which helps in fusing the developed image borne by the carrier sheet as it is drawn between rollers 68 and 70.
- the metal core of roller 68 is coated with a thin layer 71 of a synthetic material having a composition as described hereinbelow.
- the composition of the synthetic material of which layer 71 is formed is such that the occurrence of offset of a developed image coming into contact with the layer is negligible.
- Roller 70 comprises a cylindrical metal core 74 onto which there is mounted a sleeve 76 of a synthetic material having a hardness value of not greater than about 50 on the Shore A scale.
- a typical synthetic material is silicone rubber.
- the ratio of the thickness of layer 71 to thickness of sleeve 76 is typically in the range of 1 to 30 - 80.
- layer 71 may be 0.4 mm thick and sleeve 76 may be 20 mm thick.
- roller 68 Due to the difference in respective thicknesses of layer 71 and sleeve 76, roller 68 is much harder than roller 70. Consequently, when roller 70 presses against roller 68 along an axis 77, the surface of roller 70 becomes indented and a continuous contact length or 'nip' is formed between the rollers and between two points indicated by arrows A and B.
- roller 70 While roller 68 preferably rotates about a fixed axis, roller 70 is mounted for rotation onto an adjustable axle 78 which is supported by a support arm 80.
- Support arm 80 is rotatably mounted at one end 81 thereof, about a fixed axis 82 and is further supported, at another end 83 thereof, by a spring 84. It will be appreciated that the stronger the spring, the greater the pressure that is imposed by roller 70 onto roller 68.
- the carrier sheet As the carrier sheet is drawn between rollers 68 and 70, heat applied to the sheet from source 69 is effective, in combination with the pressure applied to the sheet by the rollers, to fuse and fix the developed image onto the sheet.
- the sheet is fed between the rollers such that the developed image, shown generally at 101, contacts the surface of roller 68.
- the developed image shown generally at 101
- the layer 71 has a material composition that virtually eliminates offset while not giving rise to squashing, smudging or smearing of the developed image when used in a liquid toner process. While it is expected that offset of the image onto roller 68 is negligible, there is provided, nonetheless, a stripper 85 for removing any slight offset deposits that do occur and for ensuring proper paper removal.
- a composition of matter having a shore A hardness of less than about 50 and comprising a release coating silicone polymer and a soft silicone rubber formulation is used for layer 71 of roller 68.
- the soft silicone rubber compound comprises, for example, an admixture of: (i) about 1 to about 4 parts by weight of a curable silicone oil including curing agent therefor; (ii) about 10 parts by weight of a hard rubber forming room temperature vulcanizable silicone polymer; and (iii) sufficient silicone polymer curing agent to effect a cure of component (ii), the ratio of components (i):(ii):(iii) being preferably about 1-4: about 10: about 0.8-1.2, parts by weight.
- components (i), (ii) and (iii) are Such components may be used in a weight ratio of, for example, about 2: 10: 1.
- a suitable release coating silicone polymer is Syl-Off 7600, an organofunctional siloxane polymer (cross-linkable with Syl-Off 7601 or Syl-Off 7048), manufactured by Dow Corning (U.S.A.), in particular in a ratio of approximately 200 : 1 of Syl-Off 7600 to Syl-Off 7601 or a ratio of approximately 500 : 1 of Syl-Off 7600 to Syl-Off 7048. These ratios are substantially higher than the manufacturers recommendation. For example Dow Corning recommends that 100 parts of Syl-Off 7600 be used with 4.8 parts of Syl-Off 7601 cross linker, a ratio of about 20.8:1.
- weight ratios of release coating silicone polymer to soft silicone rubber formulation in the range of from about 1:1.5 to about 1:20 are believed to be generally operable, ratios of 1 : 3 to 1.6 give good results and it is presently preferred to use a weight ratio of about 1:4.
- the surface of this article has a reduced adhesitivity at elevated temperatures, as compared with the surface of such an article from a soft silicone rubber formulation only.
- Such an article especially when possessing a curved surface, is useful in the form of a roller, such as roller 68, or an endless band, as used in various electrostatic imaging processes.
- the application of heat and pressure in the fusing and fixing step of an electrostatic imaging process utilizing solid powdered toner is subject to the drawback that the developed image may, because of ( inter alia ) partial adhesion to the curved surface of the shaped article which it contacts, be undesirably reproduced by offsetting, as for example on heated roller 68 which, as described above, together with pressure roller 70 provides the required nip.
- the coating on roller 68 is made from the above composition its surface which when heated contacts the toner image is much less liable to offsetting than when using known compositions for this purpose.
- the composition of the present invention now makes possible for the first time, the introduction of a step including the application of heat and pressure, in such liquid phase toner processes, by analogy with a corresponding step in powdered solid toner processes.
- an electrostatic imaging process which includes the steps of generating a latent electrostatic image on photoconductor 4, developing the latent image with liquid toner from development tray 18, transferring the developed image to carrier sheet 100 and fusing and fixing the transferred image on the substrate by heat and pressure applied thereto preferably by passing it between rollers 68 and 70, roller 68 being formed from the above composition.
- Fig. 2 there is also provided apparatus for wetting heated roller 68 with silicone oil, such as 350F. It will be appreciated that wetting of roller 68 is important so as to prevent drying out of coating 71 thereon, due to oozing out from the rubber composition of a non-cross-linked silicone oil used therein, for example, RTV 910.
- the shown wetting apparatus comprises a wetting roller 86 which is mounted onto an adjustable axle 88, roller 86 being operative to rotate together with heated roller 68. There is also provided a spring-retained arm 90 which maintains contact between wetting roller 86 and roller 68 by applying pressure onto axle 88 in the direction of roller 68.
- Wetting roller 86 is kept moist by a liquid absorbing element 92 which communicates with a trough 94 and which is maintained in touching contact with roller 86.
- Element 92 may, for example, comprise a layer of velvet mounted on a support.
- Trough 94 is typically supplied with silicone oil to a depth that is sufficient to keep element 92 damp enough so as to moisten wetting roller 86.
- a doctor blade 110 presses against roller 86 to reduce liquid thickness to preferably approximately 7 micrometers.
- Liquid is provided to trough 94 from an external reservoir 96 and is pumped therefrom at a very slow rate, by means of a pump 98 and an entry conduit 102. Excess liquid in trough 94 drains therefrom back into reservoir 96 via an outlet conduit 104.
- a suitable toner solution for the process of the present invention may be prepared as follows.
- ELVAX II 5720 (Dupont) (1000 g.) and ISOPAR L (Exxon) (500 g.) are mixed together at a temperature of 90 ⁇ 10°C for 1 hour, using a Ross Double Planetary mixture.
- Carbon black (Mogul L (Cabot), 250 g.) and ISOPAR L (500 g.) are added, and mixing is continued for 1 hour.
- ISOPAR L 2000 g.
- preheated to 110°C is added, and mixing is continued for a further 1 hour.
- the source of heat is withdrawn, while continuing mixing until the temperature has fallen to less than 40°C.
- Elvax II type 5720 solvates substantial amounts of ISOPAR L (and is thereby plasticized) at temperatures in the range of about 65°C to 100°C. In the method of toner manufacture described above, a temperature of between 70°C and 90°C is used.
- the non-volatile portion of the toner solution has a viscosity of not less than 2x106 centipoise at a temperature of 121 ⁇ 1°C.
- a Savin V45 photocopier which was modified to incorporate at the fixing and fusing stage a hot roller system as described above at an optimum temperature of 120 ⁇ 10°C for minimum offset, was operated with a substrate speed of about 314 mm./sec., with a pressure of 6 kg. applied at each side of the pair of rollers, and using the liquid toner prepared as above.
- the length of the nip was about 4 - 6 mm. Under these conditions the major part of the ISOPAR L in the toner image was retained therein, while fusing and fixing was achieved.
- a Savin 870 photocopier having its internal fuser rendered inoperative, was used to generate copies on paper using the liquid toner prepared as described hereinabove. The copies were then subjected to flash illumination of about 0.75 Joule/cm2 and 400 microsecond pulse duration. Under these conditions the major part of the ISOPAR L in the toner image was retained therein, while fusing and fixing was achieved.
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- General Physics & Mathematics (AREA)
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- Rolls And Other Rotary Bodies (AREA)
- Liquid Developers In Electrophotography (AREA)
Abstract
Description
- The present invention relates generally to an imaging process and apparatus and specifically to fusing of developed images.
- In known processes of electrostatic imaging, a light image of an original to be copied may be recorded in the form of an electrostatic latent image upon a photoconductive member. A developed image may then be obtained from the latent image by application of toner particles, which may be in the form of a finely powdered solid or in liquid phase.
- In 'dry' electrostatic imaging processes which employ powdered solid toners, it is known to pass a substrate having a developed image formed thereon between (for example) a pair of opposed rollers. One or both of the rollers is heated and in consequence heats and thereby fuses and fixes the image on the substrate, insofar as at least to some extent the image particles flow into the fibers or pores of the substrate. For prior patents in the field of fusing and fixing the developed image, reference is made to U.S. Patents Nos. 3,249,738, 3,637,976, 3,667,742, 3,718,116 and 4,689,471.
- In dry electrostatic imaging processes as described above, unintended offsetting of the developed image onto one of the rollers may occur. It is known that the incidence of offsetting may be reduced by employing a roller covered with polytetrafluoroethylene or silicone rubber, to which a release agent such as silicone oil is applied, which release agent apparently forms an interface between the roller surface and the toner images on the support.
- As has been indicated above, liquid toner based electrostatic imaging is known. The basic steps of the liquid toner process are:
- 1. Generating an electrostatic latent image, e.g. on a photoconductive surface such as a plate or drum which has been sensitized by charging with a corona discharge and by exposure to light in the form of an image of an object - the charge is dissipated in exposed areas;
- 2. Developing the latent image by contact with a liquid dispersion ("toner") of fine particles which in a positive process are attracted to the charged areas and which in a reverse process are attracted to the uncharged areas;
- 3. Removal of excess liquid toner and particles from the background areas;
- 4. Transfer of the image, e.g. to a substrate such as paper, under influence of an electrical field;
- 5. Fixing the image by fusing the particles together and to the substrate; and
- 6. Cleaning the plate or drum for re-use.
- In this connection reference is made to the following U.S. patents in the field of electrophotography: 3,990,696, 4,233,381, 4,253,656, 4,256,820, 4,269,504, 4,278,884, 4,286,039, 4,302,093, 4,326,644, 4,326,792, 4,334,762, 4,350,333, 4,355,883, 4,362,297, 4,364,460, 4,364,657, 4,364,661, 4,368,881, 4,378,422, 4,392,742, 4,396,187, 4,400,079, 4,411,976, 4,412,383, 4,413,048, 4,418,903, 4,420,244, 4,435,068, 4,439,035, 4,454,215, 4,460,667, 4,473,865, 4,480,825, 4,501,486, 4,522,484, 4,531,824, 4,538,899, 4,582,774, 4,585,329, 4,586,810, 4,589,761, 4,598,992, 4,603,766, 4,620,699, 4,627,705 and 4,678,317.
- Following development, the excess liquid toner and particles are removed from the image, by a step often referred to as "metering". This step may be carried out by use of an electrically biased reverse roller which also shears off the "fluffy" part of the imaged regions and squeezes or compacts the imaged area to prepare it for transfer. At the transfer stage, there is likely to occur a degree of smudging, smearing or squashing of the image, which detracts from its quality. It will be appreciated that if in the fusing and fixing stage, heat and pressure are applied to the liquid toner image, as has been described above for solid toner based processes, the liquid image will be likely to again suffer from smudging, smearing or squashing.
- In United States Patent 4,794,651 (Landa et al), a degree of squash-resistance is imparted to the developed image by using fibrous toner particles prepared as follows: a thermoplastic polymer (and pigment) is plasticized with a nonpolar liquid, preferably at elevated temperature, to form a sponge, the sponge is shredded, more nonpolar liquid is added, the pieces of shredded sponge are wet-ground into particles and the grinding is continued to pull the particles apart to form fibers extending therefrom (the particles preferably having a diameter less than 5 micrometers). Finally, a charge director may be added to impart a charge of predetermined polarity to the toner particles.
- While the method of the aforementioned United States Patent 4,794,651 includes the imparting of squash resistance to the image, it would nevertheless be desirable to fix a liquid image on a substrate by analogy with the application of heat and pressure in dry electrostatic imaging processes, but, as has been indicated above, this has not been possible hitherto because of the liability of liquid toner based images particularly, to smudging, smearing or squashing.
- It is thus an object of the present invention to provide in an electrostatic imaging process which makes use of liquid toner, a fixing and fusing step which includes the application of heat and pressure to the developed liquid toner image, while minimizing the possibility of smudging, smearing or squashing the developed image.
- Other objects of the invention will become apparent as the description proceeds.
- There is thus provided in accordance with the present invention, an imaging process which comprises the steps of developing an image with liquid toner including a liquid carrier and toner particles, transferring the liquid toner image to an image bearing surface of a substrate and fusing and fixing the image thereto by the application of energy and pressure, characterized by selecting at least the energy applied upon fusing and fixing, and the properties of the liquid carrier, such that at least 50% of the liquid carrier in the transferred image remains therein after fixing and fusing.
- There is also provided in accordance with the present invention an electrostatic imaging process which comprises the steps of developing an electrostatic image with liquid toner including at least pigmented thermoplastic polymer particles and a liquid carrier, transferring the developed liquid toner image to a substrate, transporting the substrate through a nip defined by a portion of the surface of the first roller and a portion of the surface of a second elastomer coated roller, fusing and fixing the substrate-supported developed image by the application of heat thereto from the surface of said first roller, characterized by selecting at least the temperature at which the fusing and fixing is effected, the rate of transport of the substrate, and the properties of the liquid carrier, such that at least 50% of the liquid carrier in the substrate supported image is not evaporated therefrom.
- Further, in accordance with a preferred embodiment of the present invention, the step of transferring comprises the sub-steps of transferring the image first to an intermediate surface and from the intermediate surface to the substrate.
- Additionally in accordance with a preferred embodiment of the present invention, the application of energy and pressure is effected by applying a heated surface to the image.
- Still further in accordance with a preferred embodiment of the present invention, the heated surface is the surface of an elastomer coated roller or the surface of a continuous belt.
- Further in accordance with a preferred embodiment of the present invention, the substrate is transported through a nip defined by a portion of the surface of the first elastomer-coated roller facing the image bearing surface and a portion of the surface of a second elastomer-coated roller, the coating of the second roller being softer than the coating of the first roller.
- Further in accordance with a preferred embodiment of the present invention, the coating of the second roller has a thickness greater than that of the coating of the first roller. Preferably, the ratio of the thickness of the coating of the first roller to the ratio of the thickness of the coating of the second roller is smaller than 1:10.
- Further in accordance with a preferred embodiment of the invention, the toner particles are plasticized by the carrier liquid during fusing and fixing of the image to the substrate.
- Further, in accordance with the invention, there is provided imaging apparatus comprising means for developing an image with liquid toner including a liquid carrier and toner particles; and transferring and fixing means operative to transfer the liquid toner image to an image bearing surface of a substrate and to fuse and fix the image thereto by the application of energy and pressure, characterized in that the energy applied by the transferring and fixing means that arranged such that the energy applied upon fusing and fixing in combination with the properties of the liquid carrier, are such, that at least 50% of the liquid carrier in the transferred image remains therein after fixing and fusing thereof.
- Further, in accordance with the invention, there is provided imaging apparatus comprising means for developing an electrostatic image with liquid toner including at least pigmented thermoplastic polymer particles and a liquid carrier, means for transferring the developed liquid toner image to a substrate, means for transporting the substrate through a nip defined by a portion of the surface of a first roller and a portion of the surface of a second elastomer coated roller and for fusing and fixing the substrate-supported developed image by the application of heat thereto from the surface of said first roller, characterized in that the means for transporting and for fusing and fixing are so arranged such that at the temperature at which the fusing and fixing is effected and at the rate of transport of the substrate, in combination with the properties of the liquid carrier at least 50% of the liquid carrier in the substrate supported image is not evaporated therefrom.
- The present invention will be understood and appreciated more fully from the following detailed description taken in conjunction with the drawings, in which:
- Fig. 1 is a schematic illustration of electrostatic imaging apparatus, constructed and operative in accordance with a preferred embodiment of the invention; and
- Fig. 2 is a more detailed schematic illustration of apparatus for fusing and fixing a developed image onto a carrier sheet, useful in the apparatus of Fig. 1.
- Reference is made to Fig. 1 in which there is shown electrostatic imaging apparatus employing a liquid toner. The apparatus includes a
metal drum 2 which carries aphotoconductor 4 and which is mounted bydisks 6 onto a shaft 8. The disks are secured to shaft 8 by akey 10 so that the shown drum assembly, which is provided in a light-proof housing (not shown), is operative to rotate with shaft 8. - Shaft 8 is driven in any appropriate manner (not shown) in the direction of arrow 9 past a
corona discharge device 12 operative to charge the surface ofphotoconductor 4. The image to be reproduced is projected onto the charged photoconductor by anoptical system 14. Since shaft 8 is grounded at 15 anddisks 6 are conductive, the areas struck by light conduct the charge, or a portion thereof, to ground, thus forming on the photoconductor an electrostatic latent image. - The liquid toner is circulated from any suitable source (not shown) through a pipe 16 into a
development tray 18 from which it is drawn through apipe 20 for recirculation.Development electrodes 22, which may be appropriately biased as known to the art, assist in toning the electrostatic latent image as it passes into contact with the toner. - As the amount of liquid on the photoconductor surface is normally too great for satisfactory subsequent transfer of the developed image, a
roller 24, whose surface moves in a direction opposite to that of the photoconductor surface, is spaced from the photoconductor surface by aspacer 25 and is operative to shear excess liquid from the developed image without disturbing it. An exemplary roller is shown in U.S. Patent No. 3,907,423. -
Roller 24 is driven, typically by adrive belt 26 which is in turn driven by any appropriate, known speed-controllable motor means (not shown). The roller is kept clean by a wiper blade 28. - A pair of
register rollers carrier sheet 100, which is to receive the developed image. Attransfer station 44, acorona discharge device 46 is operative to impress upon the rear of the carrier sheet a charge of polarity opposite to that of the toner particles forming the developed image. The developed image is thus drawn towards the carrier sheet. -
Rollers respective axles rollers - A pick-
off member 48 assists in the removal from the photoconductor of the carrier sheet bearing the developed image. Aroller 50 co-acting with a plurality offlexible bands 52 mounted onto a plurality ofrollers 54 delivers the carrier sheet to fusing and fixing apparatus, referenced generally 64.Apparatus 64 is described below in greater detail in conjunction with Fig. 2. - A cleaning
roller 56, formed of an appropriate synthetic resin as known in the art, is driven in a direction opposite to that ofphotoconductor 4, so as to scrub clean the surface thereof. To assist in this action, insulating, nonpolar liquid may be fed through apipe 58 to the surface of the cleaningroller 56. A wiper blade 60 completes the cleaning of the photoconductive surface. Any residual charge left on the photoconductive drum is extinguished by flooding the photoconductor surface with light from alamp 62. - Reference is now made to Fig. 2 in which there is shown fusing and fixing apparatus, constructed and operative in accordance with a preferred embodiment of the invention.
Carrier sheet 100 is fed in the direction of anarrow 66 and, with the assistance of a guide member 99, between aheated roller 68 and a pressure roller 70 (see also Fig. 1). - In the shown embodiment,
roller 68 is driven by any suitable means (not shown) and, as it rotates in a direction shown byarrow 72, it is also operative to cause rotation ofroller 70 by friction.Roller 68 typically comprises a hollow metal cylindrical core in which is provided aheat source 69 which helps in fusing the developed image borne by the carrier sheet as it is drawn betweenrollers - The metal core of
roller 68 is coated with athin layer 71 of a synthetic material having a composition as described hereinbelow. The composition of the synthetic material of whichlayer 71 is formed is such that the occurrence of offset of a developed image coming into contact with the layer is negligible. -
Roller 70 comprises acylindrical metal core 74 onto which there is mounted asleeve 76 of a synthetic material having a hardness value of not greater than about 50 on the Shore A scale. A typical synthetic material is silicone rubber. According to a preferred embodiment of the invention, the ratio of the thickness oflayer 71 to thickness ofsleeve 76 is typically in the range of 1 to 30 - 80. For example,layer 71 may be 0.4 mm thick andsleeve 76 may be 20 mm thick. - Due to the difference in respective thicknesses of
layer 71 andsleeve 76,roller 68 is much harder thanroller 70. Consequently, whenroller 70 presses againstroller 68 along an axis 77, the surface ofroller 70 becomes indented and a continuous contact length or 'nip' is formed between the rollers and between two points indicated by arrows A and B. - It is appreciated that as the carrier sheet is drawn into the nip, it is of great importance in ensuring that effective fusing and fixing of the image on the sheet takes place without the image being squashed, smeared or smudged. There is provided, therefore, apparatus for adjusting the pressure between
rollers - While
roller 68 preferably rotates about a fixed axis,roller 70 is mounted for rotation onto anadjustable axle 78 which is supported by asupport arm 80.Support arm 80 is rotatably mounted at oneend 81 thereof, about a fixedaxis 82 and is further supported, at anotherend 83 thereof, by aspring 84. It will be appreciated that the stronger the spring, the greater the pressure that is imposed byroller 70 ontoroller 68. - As the carrier sheet is drawn between
rollers source 69 is effective, in combination with the pressure applied to the sheet by the rollers, to fuse and fix the developed image onto the sheet. According to the shown embodiment, the sheet is fed between the rollers such that the developed image, shown generally at 101, contacts the surface ofroller 68. In known electrostatic imaging processes, it is expected that some offset ontoroller 68 of the developed image will occur. - The
layer 71 has a material composition that virtually eliminates offset while not giving rise to squashing, smudging or smearing of the developed image when used in a liquid toner process. While it is expected that offset of the image ontoroller 68 is negligible, there is provided, nonetheless, astripper 85 for removing any slight offset deposits that do occur and for ensuring proper paper removal. - A composition of matter having a shore A hardness of less than about 50 and comprising a release coating silicone polymer and a soft silicone rubber formulation is used for
layer 71 ofroller 68. The soft silicone rubber compound comprises, for example, an admixture of: (i) about 1 to about 4 parts by weight of a curable silicone oil including curing agent therefor; (ii) about 10 parts by weight of a hard rubber forming room temperature vulcanizable silicone polymer; and (iii) sufficient silicone polymer curing agent to effect a cure of component (ii), the ratio of components (i):(ii):(iii) being preferably about 1-4: about 10: about 0.8-1.2, parts by weight. -
- An example of a suitable release coating silicone polymer is Syl-Off 7600, an organofunctional siloxane polymer (cross-linkable with Syl-Off 7601 or Syl-Off 7048), manufactured by Dow Corning (U.S.A.), in particular in a ratio of approximately 200 : 1 of Syl-Off 7600 to Syl-Off 7601 or a ratio of approximately 500 : 1 of Syl-Off 7600 to Syl-Off 7048. These ratios are substantially higher than the manufacturers recommendation. For example Dow Corning recommends that 100 parts of Syl-Off 7600 be used with 4.8 parts of Syl-Off 7601 cross linker, a ratio of about 20.8:1.
- While in general, weight ratios of release coating silicone polymer to soft silicone rubber formulation in the range of from about 1:1.5 to about 1:20 are believed to be generally operable, ratios of 1 : 3 to 1.6 give good results and it is presently preferred to use a weight ratio of about 1:4.
- It has been found that when the composition of matter as defined herein is formed into a shaped article, the surface of this article has a reduced adhesitivity at elevated temperatures, as compared with the surface of such an article from a soft silicone rubber formulation only. Such an article, especially when possessing a curved surface, is useful in the form of a roller, such as
roller 68, or an endless band, as used in various electrostatic imaging processes. - As has already been indicated above, the application of heat and pressure in the fusing and fixing step of an electrostatic imaging process utilizing solid powdered toner is subject to the drawback that the developed image may, because of (inter alia) partial adhesion to the curved surface of the shaped article which it contacts, be undesirably reproduced by offsetting, as for example on
heated roller 68 which, as described above, together withpressure roller 70 provides the required nip. - If the coating on
roller 68 is made from the above composition its surface which when heated contacts the toner image is much less liable to offsetting than when using known compositions for this purpose. - Also, whereas the application of heat and pressure in the fusing and fixing step of an electrostatic imaging process utilizing liquid phase toner has to the knowledge of the inventors proved to be impractical hitherto because of liability of the liquid toner image to smudging, smearing or squashing, the composition of the present invention now makes possible for the first time, the introduction of a step including the application of heat and pressure, in such liquid phase toner processes, by analogy with a corresponding step in powdered solid toner processes.
- Thus, in accordance with an embodiment of the invention and with reference to Figs. 1 and 2, an electrostatic imaging process is provided which includes the steps of generating a latent electrostatic image on
photoconductor 4, developing the latent image with liquid toner fromdevelopment tray 18, transferring the developed image tocarrier sheet 100 and fusing and fixing the transferred image on the substrate by heat and pressure applied thereto preferably by passing it betweenrollers roller 68 being formed from the above composition. - With further reference to Fig. 2, there is also provided apparatus for wetting
heated roller 68 with silicone oil, such as 350F. It will be appreciated that wetting ofroller 68 is important so as to prevent drying out of coating 71 thereon, due to oozing out from the rubber composition of a non-cross-linked silicone oil used therein, for example, RTV 910. - The shown wetting apparatus comprises a wetting
roller 86 which is mounted onto anadjustable axle 88,roller 86 being operative to rotate together withheated roller 68. There is also provided a spring-retainedarm 90 which maintains contact between wettingroller 86 androller 68 by applying pressure ontoaxle 88 in the direction ofroller 68. - Wetting
roller 86 is kept moist by aliquid absorbing element 92 which communicates with atrough 94 and which is maintained in touching contact withroller 86.Element 92 may, for example, comprise a layer of velvet mounted on a support.Trough 94 is typically supplied with silicone oil to a depth that is sufficient to keepelement 92 damp enough so as to moisten wettingroller 86. Adoctor blade 110 presses againstroller 86 to reduce liquid thickness to preferably approximately 7 micrometers. Liquid is provided totrough 94 from anexternal reservoir 96 and is pumped therefrom at a very slow rate, by means of apump 98 and anentry conduit 102. Excess liquid intrough 94 drains therefrom back intoreservoir 96 via anoutlet conduit 104. - A suitable toner solution for the process of the present invention may be prepared as follows. ELVAX II 5720 (Dupont) (1000 g.) and ISOPAR L (Exxon) (500 g.) are mixed together at a temperature of 90±10°C for 1 hour, using a Ross Double Planetary mixture. Carbon black (Mogul L (Cabot), 250 g.) and ISOPAR L (500 g.) are added, and mixing is continued for 1 hour. ISOPAR L (2000 g.), preheated to 110°C is added, and mixing is continued for a further 1 hour. The source of heat is withdrawn, while continuing mixing until the temperature has fallen to less than 40°C. Of the resultant mixture, 3050 g. are milled at a temperature of 40±2-3°C for about 22 hours with ISOPAR L (4000 g.) in a Sweco M18 Vibratory Mill containing 0.5˝ alumina cylinders. The product is a 12.5% solids concentrate; a working dispersion is obtained by diluting with ISOPAR L to a 1.5% solids content. In the Examples which follow, the Savin 870 photocopier requires 1.5 kg. of this working solution, to which is added 7 - 8 ml. of 10% lecithin in ISOPAR L as charge director, while the Savin V45 photocopier requires 0.8 kg. of this working solution, to which is added 3.5 - 4 ml. of 10% lecithin in ISOPAR L as charge director.
- Elvax II type 5720 solvates substantial amounts of ISOPAR L (and is thereby plasticized) at temperatures in the range of about 65°C to 100°C. In the method of toner manufacture described above, a temperature of between 70°C and 90°C is used.
- The non-volatile portion of the toner solution has a viscosity of not less than 2x10⁶ centipoise at a temperature of 121 ±1°C.
- The invention will now be illustrated by the following non-limitative Examples:
- A Savin V45 photocopier which was modified to incorporate at the fixing and fusing stage a hot roller system as described above at an optimum temperature of 120 ±10°C for minimum offset, was operated with a substrate speed of about 314 mm./sec., with a pressure of 6 kg. applied at each side of the pair of rollers, and using the liquid toner prepared as above. The length of the nip was about 4 - 6 mm. Under these conditions the major part of the ISOPAR L in the toner image was retained therein, while fusing and fixing was achieved.
- A Savin 870 photocopier, having its internal fuser rendered inoperative, was used to generate copies on paper using the liquid toner prepared as described hereinabove. The copies were then subjected to flash illumination of about 0.75 Joule/cm² and 400 microsecond pulse duration. Under these conditions the major part of the ISOPAR L in the toner image was retained therein, while fusing and fixing was achieved.
- It will be appreciated by persons skilled in the art that the present invention is not limited to what has been particularly shown and described hereinabove. The scope of the present invention is limited, rather, solely by the claims which follow:
Claims (12)
- An imaging process which comprises the steps of developing an image with liquid toner including a liquid carrier and toner particles, transferring the liquid toner image to an image bearing surface of a substrate and fusing and fixing the image thereto by the application of energy and pressure, characterized by selecting at least the energy applied upon fusing and fixing and the properties of the liquid carrier, such that at least 50% of the liquid carrier in the transferred image remains therein after fixing and fusing thereof.
- An electrostatic imaging process comprising the steps of:
developing an electrostatic image with liquid toner including at least pigmented thermoplastic polymer particles and a liquid carrier;
transferring the developed liquid toner image to a substrate;
transporting the substrate through a nip defined by a portion of the surface of a first roller and a portion of the surface of a second elastomer coated roller; and
fusing and fixing the substrate-supported developed image by the application of heat thereto from the surface of said first roller,
characterized by selecting at least the temperature at which the fusing and fixing is effected, the rate of transport of the substrate, and the properties of the liquid carrier, such that at least 50% of the liquid carrier in the substrate supported image is not evaporated therefrom. - A process according to claim 2 wherein said step of transferring comprises the sub-steps of transferring the image first to an intermediate surface and from the intermediate surface to the substrate.
- A process according to claim 1 wherein said application of energy and pressure is effected by applying a heated surface to the image.
- A process according to claim 4, wherein said heated surface is the surface of a first elastomer-coated roller.
- A process according to claim 4, wherein said heated surface is the surface of a continuous belt.
- A process according to claim 5, wherein the substrate is transported through a nip defined by a portion of the surface of said first elastomer-coated roller facing said image bearing surface and portion of the surface of a second elastomer-coated roller, the coating of said second roller being softer than the coating of said first roller.
- A process according to claim 5, wherein the substrate is transported through a nip defined by a portion of the surface of said first elastomer-coated roller facing said image bearing surface and a portion of the surface of a second elastomer-coated roller, wherein the coating of said second roller has a thickness greater than that of the coating of said first roller.
- A process according to claim 8, wherein the ratio of the thickness of the coating of said first roller to the ratio of the thickness of the coating of said second roller is smaller than 1:10.
- A process according to any of the preceding claims wherein said particles are plasticized by said carrier liquid during fusing and fixing of the image to the substrate.
- Imaging apparatus comprising:
means (2, 16, 18, 20, 22) for developing an image with liquid toner including a liquid carrier and toner particles; and
transferring and fixing apparatus (46, 68, 70) operative to transfer the liquid toner image to an image bearing surface of a substrate and to fuse and fix the image thereto by the application of energy and pressure,
characterized in that the energy applied, by the transferring and fixing apparatus is arranged such that the energy applied upon fusing and fixing in combination with the properties of the liquid carrier, are such, that at least 50% of the liquid carrier in the transferred image remains therein after fixing and fusing thereof. - Imaging apparatus comprising:
means (2, 16, 18, 20, 22) for developing an electrostatic image with liquid toner including at least pigmented thermoplastic polymer particles and a liquid carrier;
means (46) for transferring the developed liquid toner image to a substrate (100);
means (68, 70) for transporting the substrate through a nip defined by a portion of the surface of a first roller (68) and a portion of the surface of a second elastomer coated roller (70) and for fusing and fixing the substrate-supported developed image by the application of heat thereto from the surface of said first roller,
characterized in that the means for transporting and for fusing and fixing are so arranged such that at the temperature at which the fusing and fixing is effected and at the rate of transport of the substrate, in combination with the properties of the liquid carrier at least 50% of the liquid carrier in the substrate supported image is not evaporated therefrom.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/202,687 US5270776A (en) | 1988-06-06 | 1988-06-06 | Method for fusing developed image |
US202687 | 1988-06-06 | ||
US26886188A | 1988-11-08 | 1988-11-08 | |
US268861 | 1988-11-08 | ||
PCT/NL1989/000040 WO1989012258A2 (en) | 1988-06-06 | 1989-06-05 | Method for fusing developed image |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19930201225 Division EP0559299A3 (en) | 1988-06-06 | 1989-06-05 | Imaging apparatus having liquid toner development station |
EP93201225.5 Division-Into | 1993-04-28 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0418300A1 EP0418300A1 (en) | 1991-03-27 |
EP0418300B1 true EP0418300B1 (en) | 1995-02-01 |
Family
ID=26897933
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89906818A Expired - Lifetime EP0418300B1 (en) | 1988-06-06 | 1989-06-05 | Method for fusing developed image |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0418300B1 (en) |
JP (2) | JP3229308B2 (en) |
DE (1) | DE68921001T2 (en) |
WO (1) | WO1989012258A2 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6623902B1 (en) | 1991-03-28 | 2003-09-23 | Hewlett-Packard Indigo B.V. | Liquid toner and method of printing using same |
US6146803A (en) * | 1991-03-28 | 2000-11-14 | Indigo N.V. | Polymer blend liquid toner compositions |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3795033A (en) * | 1969-10-17 | 1974-03-05 | Minnesota Mining & Mfg | Fixing process |
DE2354374A1 (en) * | 1972-11-08 | 1974-07-25 | Oce Van Der Grinten Nv | FIXING DEVICE |
US4137340A (en) * | 1975-09-16 | 1979-01-30 | Agfa-Gevaert N.V. | Method for fixing electrophoretically formed toner images |
JPS56104364A (en) * | 1980-01-24 | 1981-08-20 | Ricoh Co Ltd | Fixing and drying device in wet type electrophotographic copier |
JPS58209768A (en) * | 1982-05-31 | 1983-12-06 | Showa Electric Wire & Cable Co Ltd | Silicone rubber roll |
JPS60176073A (en) * | 1984-02-22 | 1985-09-10 | Hokushin Ind Inc | Manufacture of heat-fixing roll of electrophotographic copying machine |
JPS61186975A (en) * | 1985-02-14 | 1986-08-20 | Ricoh Co Ltd | Oilless fixing roll |
US4766462A (en) * | 1986-07-21 | 1988-08-23 | Xerox Corporation | Liquid carrier recovery system |
-
1989
- 1989-06-05 JP JP50619389A patent/JP3229308B2/en not_active Expired - Lifetime
- 1989-06-05 DE DE68921001T patent/DE68921001T2/en not_active Expired - Fee Related
- 1989-06-05 WO PCT/NL1989/000040 patent/WO1989012258A2/en active IP Right Grant
- 1989-06-05 EP EP89906818A patent/EP0418300B1/en not_active Expired - Lifetime
-
2001
- 2001-06-19 JP JP2001184606A patent/JP2002072740A/en active Pending
Also Published As
Publication number | Publication date |
---|---|
WO1989012258A3 (en) | 1990-07-12 |
JP2002072740A (en) | 2002-03-12 |
DE68921001D1 (en) | 1995-03-16 |
JP3229308B2 (en) | 2001-11-19 |
WO1989012258A2 (en) | 1989-12-14 |
EP0418300A1 (en) | 1991-03-27 |
JPH04500414A (en) | 1992-01-23 |
DE68921001T2 (en) | 1995-08-31 |
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