EP0417794A2 - Flüssigkristall Anzeigevorrichtung - Google Patents

Flüssigkristall Anzeigevorrichtung Download PDF

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Publication number
EP0417794A2
EP0417794A2 EP90117675A EP90117675A EP0417794A2 EP 0417794 A2 EP0417794 A2 EP 0417794A2 EP 90117675 A EP90117675 A EP 90117675A EP 90117675 A EP90117675 A EP 90117675A EP 0417794 A2 EP0417794 A2 EP 0417794A2
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EP
European Patent Office
Prior art keywords
liquid crystal
conjugated
crystal display
display device
substrates
Prior art date
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Granted
Application number
EP90117675A
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English (en)
French (fr)
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EP0417794A3 (en
EP0417794B1 (de
Inventor
Nobuyuki Itoh
Tugiko Taniguchi
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Sharp Corp
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Sharp Corp
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Publication of EP0417794A3 publication Critical patent/EP0417794A3/en
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    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1337—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/52—Liquid crystal materials characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
    • C09K19/58—Dopants or charge transfer agents
    • C09K19/582—Electrically active dopants, e.g. charge transfer agents

Definitions

  • the present invention relates to liquid crystal display devices wherein a ferroelectric liquid crystal is used.
  • Liquid crystals include those of chiral smectic C phase (hereinafter referred to simply as "SmC* liquid crystals") having a helical structure and exhibiting ferroelectric properties.
  • SmC* liquid crystals chiral smectic C phase
  • the orientation of the liquid crystal molecules can be changed from a definite state to another state for switching drive.
  • Switching drive causes the SmC* liquid crystals within the cell to produce altered birefringent light, so that the transmitted light is controllable by interposing the cell between two polarizers.
  • the orientation of the liquid crystal molecules is maintained in the state before the discontinuation by the ability of the interface to regulate the orientation.
  • a memory effect is also available.
  • Such a liquid crystal display device comprises two glass substrates opposed to each other in parallel, and a plurality of transparent electrodes arranged in the form of parallel stripes and formed on each of the opposed surfaces of the substrates.
  • the transparent electrodes on one of the glass substrates are arranged perpendicular to those of the other glass substrate.
  • the electrode bearing surface of each substrate is further formed with an orientation film with an insulation film interposed therebetween.
  • a layer of SmC* liquid crystals is provided between the two glass substrates.
  • the liquid crystal device has the following problem.
  • the uneven presence of charges resulting from the spontaneous polarization of liquid crystal molecules produces an electric field (polarization electric field) within the device, impairing the memory effect in memory states, i.e., in a state wherein the orientation angle of the molecules is + ⁇ , and in a state wherein the angle is - ⁇ (i.e., the memory effect in a bistable state).
  • a polarization electric field due to uneven presence of polarized charges of liquid crystal molecules is present within the cell even in the memory state as shown in FIG. 2 (a). Accordingly, in response to the polarization electric field, the liquid crystal molecules are altered in orientation so as to minimize the energy within the cell as seen in FIG. 2 (b). Presumably for this reason, it becomes impossible to assume a bistable memory state.
  • Indicated at 6 in FIG. 2 is the C-director of liquid crystal molecules, and at 7 the spontaneous polarization of liquid crystal molecules. The tip of this arrow represents + pole, and the other end of the arrow represents - pole. Represented by 8 and 9 are positive and negative polarized charges, respectively, as unevenly present.
  • Indicated at 10 is the presence of the polarization electric field in the direction of the arrow.
  • an object of the present invention is to provide a liquid crystal display device having a bistable memory effect prevented from impairment due to a polarization electric field.
  • the present invention provides a liquid crystal display device comprising a pair of substrates each having transparent electrodes over the surface thereof and an orientation film over the electrode, and a liquid crystal interposed between the pair of substrates, the liquid crystal being a ferroelectric liquid crystal composition having incorporated therein a conjugated cyano compound or conjugated halogen compound serving as an electron acceptor.
  • a ferroelectric liquid crystal composition which has incorporated therein a conjugated cyano compound or conjugated halogen compound serving as an electron acceptor.
  • ferroelectric liquid crystals for use in the composition are responsive to the application of voltage at a high speed to exhibit a specified orientation for transmitting or blocking light for the display device.
  • Useful ferroelectric liquid crystals are those which have a chiral center, are not racemates and possess permanent dipole moment perpendicular to the long axes of molecules and hence exhibit Sc* phase.
  • liquid crystals examples include (S)-4′-n-octyloxy-­ biphenyl-4-carboxylic acid-1-trifluoromethyl-heptyl ester, (s)-4′-n-octyloxy-biphenyl-4-carboxylic acid-1-trifluoromethyl-3-phenyl-(tranc)-2-propenyl ester, DOBAMBC (p-decyloxybenzylidene-p′-amino-2-methlbutyl­cinnamic acid ester), MORA-8 (S-4-(6-methyl)octyl­resorcylidene-4,-octylaniline, DOBA-1-MBC (p-decyloxy-­benzylidene-p′-amino-1-methylbutylicinnamic acid ester), appropriate mixture thereof.
  • DOBAMBC p-decyloxy-­benzylidene-p′-amino-1
  • the liquid crystals are used as admixed with other substances to adjust the temperature range wherein the liquid crystals exhibit Sc* phase.
  • Commercially available ferroelectric liquid crystals which are adapted to exhibit Sc* phase at room temperature are CS-1014, CS-1013, CS-1017 (which are products of Chisso Corporation), and ZLI4237/000 (product of Merck & Co., Inc.)
  • the conjugated cyano compound or conjugated halogen compound serving as an electron acceptor acts to give a bistable memory effect to the ferroelectric liquid crystal or composition thereof.
  • Usable as such compounds are those capable of attenuating or neutralizing the polarization electric field produced within the device by uneven presence of polarized charges due to the spontaneous polarization of the ferroelectric liquid crystal molecules.
  • the conjugated cyano compound is one having cyano groups and a carbon -carbon double bond which can be conjugated with the triple bond of the cyano groups.
  • DDQ dichlorodicyanoparabenzoquinone
  • TCNQ tetracyanoquinodimethane
  • TE tetracyanoethylene
  • TFTCNQ tetrafluorotetracyanoquinodimethane
  • TCNB tetracyanobenzene since these compounds act on liquid crystals up to 20 (nc/cm2) in spontaneous polarization so as to cause the liquid crystal to exhibit a remarkable bistable memory effect.
  • Examples of useful conjugated halogen compounds are dichlorodifluoroquinone, dichloroanthraquinone, tetrachlorodiphenoquinone (TCDQ), tetrabromodiphenoquinone (TBDQ) and the like.
  • the conjugated cyano compound or conjugated halogen compound serving as an electron acceptor can be used usually in an amount of 100 to 5000 ppm based on the ferroelectric liquid crystal composition.
  • the amount is 100 to 500 ppm since a satisfactory bistable memory effect and uniform display characteristics can then be obtained even if the substrates are not smaller than 7.5 cm square.
  • the amount is in excess of 500 ppm, a satisfactory memory effect and uniform display characteristics are still available if the substrates are small, whereas in the case where the substrates are not smaller than 7.5 cm square, a chromatographic effect produces variations in the color of display in the direction away from the injecting opening or irregularities in characteristics such as switching behavior to impair the uniformity of the display. The excessive amount is therefore undesirable.
  • the liquid crystal display device of the present invention can be prepared by selectively forming transparent electrodes on the surface of each of a pair of substrates, further forming an orientation film over the electrodes on each substrate, arranging the pair of substrates usually at a spacing of 1 to 4 ⁇ m with their orientation films opposed to each other, and subsequently injecting into the space between the substrates a ferroelectric liquid crystal composition incorporating therein a specified quantity of the conjugated cyano compound or conjugated halogen compound serving as an electron acceptor.
  • the ferroelectric liquid crystal layer is driven by applying a voltage selectively across the transparent electrodes for use in displaying desired characters, images or the like.
  • the conjugated cyano compound or conjugated halogen compound serving as an electron acceptor and added to the ferroecletric liquid crystal attenuates or neutralizes the polarization electric field produced within the device by uneven presence of polarized charges due to the spontaneous polarization of the liquid crystal molecules.
  • transparent electrodes 2a, 2b were formed on glass substrates 1a, 1b, and the electrodes were coated with OCD TYPE-II, product of Tokyo Oyokagaku Co., Ltd., using a spinner, followed by baking to form insulation film 3 of SiO2.
  • 1% m-cresol solution of nylon 6 product of Toray Industries, Ltd. was coated on the insulating film using a spinner, and the coating was baked and rubbed to form orientation film 4a, 4b.
  • the two substrates thus prepared were spaced apart by 2.0 ⁇ m as opposed to each other to form a cell.
  • DDQ dichlorodicyanoparabenzoquinone
  • the assembly was interposed between two polarizers to prepare a liquid crystal display device, which was small in threshold pulse width (150 ⁇ sec), exhibited a high value (95%) in memory retention area as seen in FIG. 3, and was found to exhibit satisfactory bistable memory at the pixel portions of the electrode matrix.
  • Example 6 liquid crystal display devices were prepared in the same manner as in Example 1 except that the amount of DDQ, which was 350 ppm in Example 1, was changed to 100, 200, 500, 1000, 2000 or 5000 ppm.
  • the devices exhibited satisfactory bistable memory at the pixel portions of the electrode matrix.
  • those prepared with use of 200 ppm or 500 ppm of DDQ were found more satisfactory in bistable memory.
  • the devices exhibited satisfactory bistable memory.
  • a liquid crystal display device was prepared in the same manner as in Example 1 with the exception of using a ferroelectric liquid crystal free from DDQ in place of the liquid crystal incorporating DDQ and used in Example 1.
  • the device was great in threshold pulse width (190 ⁇ sec) and small in memory retention area (65%) as seen in FIG. 3.
  • a device equivalent to the one shown in FIG. 1 was prepared.
  • Each of two substrates was coated with SiO2 (OCD TYPE-II, product of Tokyo Oyokagaku Co., Ltd.) by a spinner, followed by baking to prepare an insulation film, which was then coated with PSI-XS012 by a spinner, followed by baking to form an orientation film.
  • the two substrates thus prepared were rubbed and then spaced apart by 2.0 ⁇ m to obtain a cell.
  • TFTCNQ tetrafluorotetracyanoquino­dimethane
  • the cell was observed as interposed between two polarizers to find that even if the substrates were larger than 7.5 cm square, the pixel portions of the electrode matrix exhibited satisfactory bistable memory and uniform display characteristics.
  • Example 5 Eight liquid crystal display devices were prepared in the same manner as in Example 5 with the exception of using dichlorodicyanoparabenzoquinone (DDQ), tetracyanoquinodimethane (TCNQ), tetracyanoethylene (TCE), tetracyanobenzene (TCNB), dichlorodifluoroquinone, dichloroanthraquinone, tetrachlorodiphenoquinone (TCDQ) or tetrabromodiphenoquinone (TBDQ) in place of tetrafluorotetracyanoquinodimethane (TFTCNQ) used in Example 5. Like the device of Example 5, these devices exhibited satisfactory bistable memory and uniform display characteristics.
  • DDQ dichlorodicyanoparabenzoquinone
  • TCNQ tetracyanoquinodimethane
  • TCE tetracyanoethylene
  • TCNB tetracyanobenzene
  • a liquid crystal display device was prepared in the same manner as in Example 1 except that the ferroelectric liquid crystal substance, CS-1014, used in Example 1 was replaced by the composition listed in Table 1 and having incorporated therein 2% of the compound represented by:
  • the device obtained was satisfactory in display characteristics.
  • a liquid crystal display device was prepared in the same manner as in Example 1 except that the ferroelectric liquid crystal substance, CS-1014, used in Example 1 was replaced by the mixture listed in Table 2.
  • the device obtained exhibited satisfactory display characteristics.
  • the present invention provides liquid crystal display devices having a bistable memory effect prevented from impairment due to polarization electric field.

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Nonlinear Science (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Mathematical Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Liquid Crystal Substances (AREA)
  • Liquid Crystal (AREA)
EP90117675A 1989-09-14 1990-09-13 Flüssigkristall Anzeigevorrichtung Expired - Lifetime EP0417794B1 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP239590/89 1989-09-14
JP23959089 1989-09-14
JP80083/90 1990-03-27
JP2080083A JP2746456B2 (ja) 1989-09-14 1990-03-27 液晶表示装置

Publications (3)

Publication Number Publication Date
EP0417794A2 true EP0417794A2 (de) 1991-03-20
EP0417794A3 EP0417794A3 (en) 1992-02-26
EP0417794B1 EP0417794B1 (de) 1994-07-27

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EP90117675A Expired - Lifetime EP0417794B1 (de) 1989-09-14 1990-09-13 Flüssigkristall Anzeigevorrichtung

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US (1) US5350537A (de)
EP (1) EP0417794B1 (de)
JP (1) JP2746456B2 (de)
KR (1) KR910006762A (de)
DE (1) DE69011021T2 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1413620A1 (de) * 2002-10-23 2004-04-28 Sony International (Europe) GmbH Negativtypflüssigkristalle enthaltend Dotierstoffe

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5611941A (en) * 1995-07-17 1997-03-18 Rainbow Display Serivices Method for forming a ferroelectric liquid crystal spatial light modulator utilizing a planarization process
DE102004004047B3 (de) * 2004-01-27 2005-09-08 Infineon Technologies Ag Resistiv arbeitender Speicher für Low-Voltage-Anwendungen

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3932298A (en) * 1973-07-19 1976-01-13 Temple University Nematic liquid crystals with charge-transfer acceptors as dopants
JPS61133285A (ja) * 1984-11-30 1986-06-20 Sharp Corp スメクチツクｃ▲＊▼液晶組成物
EP0365255A2 (de) * 1988-10-19 1990-04-25 Matsushita Electric Industrial Co., Ltd. Ferroelektrische Flüssigkristallmischung und Flüssigkristallanzeigevorrichtung

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DE2731263A1 (de) * 1976-07-13 1978-01-26 Japan Synthetic Rubber Co Ltd Verfahren zur herstellung eines polymeren oder mischpolymeren aus einem norbornenderivat und katalysator dafuer
JPS5511545A (en) * 1978-07-12 1980-01-26 Ajinomoto Co Inc Novel cyano-substituted diphenoxyquinone and its preparation
JPS56139578A (en) * 1980-04-03 1981-10-31 Toshiba Corp Liquid crystal display device
JPS56139579A (en) * 1980-04-03 1981-10-31 Toshiba Corp Liquid crystal display device
EP0106175B1 (de) * 1982-09-30 1988-12-07 Showa Denko Kabushiki Kaisha Elektroleitende flüssigkristalline Substanz und Polymer
US4535042A (en) * 1983-02-24 1985-08-13 Hiroyuki Kitayama Electrophotographic photosensitive member with electron donor and acceptor layers
US4907859A (en) * 1983-11-15 1990-03-13 Canon Kabushiki Kaisha Liquid crystal device and image forming apparatus utilizing liquid crystal device
FR2564231B1 (fr) * 1984-05-10 1986-09-05 Commissariat Energie Atomique Films conducteurs de l'electricite comprenant au moins une couche monomoleculaire d'un complexe organique a transfert de charge et leur procede de fabrication
DE3490738T1 (de) * 1984-07-24 1986-11-20 General Scanning Inc., Watertown, Mass. Steller mit Ausgleich-Induktionsfluß-Weg
JPS6348388A (ja) * 1986-08-19 1988-03-01 Matsushita Electric Ind Co Ltd アクテイブマトリクス型液晶表示素子
US4879059A (en) * 1986-09-02 1989-11-07 Canon Kabushiki Kaisha Liquid crystal device
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JP2521105B2 (ja) * 1987-09-03 1996-07-31 日本カーリット株式会社 液晶材料の電界応答速度を上げる方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3932298A (en) * 1973-07-19 1976-01-13 Temple University Nematic liquid crystals with charge-transfer acceptors as dopants
JPS61133285A (ja) * 1984-11-30 1986-06-20 Sharp Corp スメクチツクｃ▲＊▼液晶組成物
EP0365255A2 (de) * 1988-10-19 1990-04-25 Matsushita Electric Industrial Co., Ltd. Ferroelektrische Flüssigkristallmischung und Flüssigkristallanzeigevorrichtung

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1413620A1 (de) * 2002-10-23 2004-04-28 Sony International (Europe) GmbH Negativtypflüssigkristalle enthaltend Dotierstoffe
US7014891B2 (en) 2002-10-23 2006-03-21 Sony International (Europe) Gmbh Response to the negative-type liquid crystals

Also Published As

Publication number Publication date
KR910006762A (ko) 1991-04-30
JP2746456B2 (ja) 1998-05-06
US5350537A (en) 1994-09-27
EP0417794A3 (en) 1992-02-26
DE69011021D1 (de) 1994-09-01
JPH03219209A (ja) 1991-09-26
DE69011021T2 (de) 1995-03-16
EP0417794B1 (de) 1994-07-27

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