EP0411136A1 - Polyester copolymer - Google Patents
Polyester copolymer Download PDFInfo
- Publication number
- EP0411136A1 EP0411136A1 EP90901021A EP90901021A EP0411136A1 EP 0411136 A1 EP0411136 A1 EP 0411136A1 EP 90901021 A EP90901021 A EP 90901021A EP 90901021 A EP90901021 A EP 90901021A EP 0411136 A1 EP0411136 A1 EP 0411136A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mole
- polyester copolymer
- glycol
- terephthalic acid
- aliphatic diol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
Definitions
- the present invention relates to a polyester copolymer which gives a shaped article having a high heat resistance and which has a low rate of crystallization.
- Polycyclohexylenedimethylene terephthalate obtained from terephthalic acid and 1,4-cyclohexanedimethanol has a high melting point, and therefore, this polyester has a high heat resistance and a high resistance against the hydrolysis.
- An object of the present invention is to provide a polyester copolymer having a low rate of crystallization and providing a shaped article having a high heat resistance.
- a polyester copolymer obtained by reacting (A) a dicarboxylic acid component composed mainly of terephthalic acid or a derivative thereof with (B) a glycol component comprising (B-1) 15 to 85 mole% of an aliphatic diol having 2 to 16 carbon atoms and (B-2) 85 to 15 mole% of 1,4-cyclohexanedimethanol in which the trans-form content is at least 80 mole%.
- the dicarboxylic acid component (A) used in the present invention preferably comprises at least 90 mole% of terephthalic acid or a derivative thereof.
- terephthalic acid derivative there can be mentioned dialkyl esters of terephthalic acid having 1 to 10 carbon atoms in the alkyl group and diaryl esters of terephthalic acid having 6 to 14 carbon atoms in the aryl group.
- specific examples of the terephthalic acid derivative there can be mentioned dimethyl terephthalate, diethyl terephthalate, dipropyl terephthalate, dibutyl terephthalate and diphenyl terephthalate.
- phthalic acid As the other dicarboxylic acid that can be used together with terephthalic acid or its derivative in an amount of not more than 10 mole% of the dicarboxylic acid component, there can be mentioned phthalic acid, isophthalic acid, adipic acid, sebacic acid, naphthalene-1,4-dicarboxylic acid and naphthalene-2,6-dicarboxylic acid.
- the glycol component (B) used in the present invention comprises (B-1) 15 to 85 mole% of an aliphatic diol having 2 to 16 carbon atoms and (B-2) 85 to 15 mole% of 1,4-cyclohexanedimethanol in which the content of the trans-form is at least 80 mole%.
- aliphatic diol (B-1) having 2 to 16 carbon atoms there can be mentioned ethylene glycol, propylene glycol, tetramethylene glycol, hexamethylene glycol, neopentyl glycol, octamethylene glycol, butylethyl propanediol, diethyl propanediol and 3,9-bis(1,1-dimethyl-2-hydroxyethyl)-2,4,8,10-tetraoxaspiro-[5,5]-undecane, and ethylene glycol, propylene glycol, tetramethylene glycol and hexamethylene glycol are especially preferably used.
- aliphatic diols can be used alone or in the form of a mixture of two or more thereof.
- a polyester copolymer obtained by using an aliphatic diol having more than 16 carbon atoms as the aliphatic diol is not preferred because a shaped article obtained from this copolymer has not a satisfactory heat resistance.
- the amount of the aliphatic diol (B-1) having 2 to 16 carbon atoms is 15 to 85 mole%, preferably 30 to 70 mole%, based on the glycol component (B).
- the polyester copolymer in which the content of the component (B-1) is less than 15 mole% based on the component (B) cannot be used for attaining the object of the present invention, because the rate of crystallization of the polyester copolymer is high.
- the polyester copolymer in which the content of the component (B-1) is higher than 85 mole% based on the component (B) is not preferably used, because the rate of crystallization becomes high or the glass transition temperature is too low.
- the content of the trans-form in 1,4-cyclohexanedimethanol (B-2) used in the present invention must be at least 80 mole%.
- a shaped article formed from a polyester copolymer obtained by using 1,4-cyclohexanedimethanol having a trans-form content less than 80 mole% is not satisfactory in the heat resistance.
- the polyester copolymer of the present invention can be obtained by using terephthalic acid, dimethyl terephthalate or other terephthalic acid derivative, and ethylene glycol or other aliphatic diol and 1,4-cyclohexanedimethanol composed mainly of the trans-form as the main starting materials, carrying out an esterification reaction or an ester exchange reaction and subsequently, conducting a polycondensation reaction.
- Catalysts customarily used for the preparation of polyesters can be used for the esterification reaction or ester exchange reaction and the polycondensation reaction.
- a flame retardant, a fibrous reinforcer, a filler, an oxidation stabilizer, a heat stabilizer, a colorant, an ultraviolet absorbent and the like can be added to the polyester copolymer of the present invention according to need.
- Terephthalic acid as the dicarboxylic acid component and a glycol component comprising 1,4-cyclohexanedimethanol, ethylene glycol, 1,4-butanediol and 1,6-hexanediol at a ratio shown in Table 1 were subjected to esterification at 260' C in the presence of tetrabutyl titanate as the esterification catalyst in an amount of 0.1 % based on the obtained polymer Then antimony trioxide and phosphorous acid were added as the polycondensation catalyst in amounts of 0.03% and 0.04%, respectively, and polycondensation was carried out under a reduced pressure at 285 to 320° C, whereby various polyester copolymers were prepared. Each of the obtained polyester copolymers was recovered in the form of a strand polymer, cooled with water and pelletized by a cutter.
- the obtained pellet was molded into a molded article having a thickness of 6.4 mm, a length of 127 mm, and a width of 12.6 mm by using a 1-ounce small injection molding machine at a cylinder temperature of 310 to 320° C and a mold temperature of 310 to 320° C.
- Each of the molded articles was a transparent test piece. Each test piece was heated at 140' C corresponding to the molding temperature for the preparation of a sheet or a bottle for 15 minutes, and the degree of whitening by the crystallization was examined. The results are shown in Table 1.
- the degree of whitening was evaluated according to the following scale:
- the polyester copolymer of the present invention has a low rate of crystallization, and a shaped article obtained from this copolymer has a high heat resistance. Accordingly, the range of application of the shaped article of the polyester resin is wider.
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
The title copolymer is obtained by reacting a dicarboxylic acid component mainly composed of terephthalic acid or its derivative with a glycol component composed of 15 to 85 mol % of an aliphatic diol having 2 to 16 carbon atoms and 85 to 15mol % of 1,4-cyclohexanedimethanol at least 80 mol % of which is in the trans form.This polyester copolymer has a low crystallization rate and an excellent heat resistance.
Description
- The present invention relates to a polyester copolymer which gives a shaped article having a high heat resistance and which has a low rate of crystallization.
- Polycyclohexylenedimethylene terephthalate obtained from terephthalic acid and 1,4-cyclohexanedimethanol has a high melting point, and therefore, this polyester has a high heat resistance and a high resistance against the hydrolysis.
- Attempts have been made to use this polyester as films or bottles by utilizing this characteristic property. This polyester, however, involves a problem in that since the polyester is readily crystallized, the range of the shaping conditions is narrow.
- An object of the present invention is to provide a polyester copolymer having a low rate of crystallization and providing a shaped article having a high heat resistance.
- More specifically, in accordance with the present invention, there is provided a polyester copolymer obtained by reacting (A) a dicarboxylic acid component composed mainly of terephthalic acid or a derivative thereof with (B) a glycol component comprising (B-1) 15 to 85 mole% of an aliphatic diol having 2 to 16 carbon atoms and (B-2) 85 to 15 mole% of 1,4-cyclohexanedimethanol in which the trans-form content is at least 80 mole%.
- The dicarboxylic acid component (A) used in the present invention preferably comprises at least 90 mole% of terephthalic acid or a derivative thereof. As the terephthalic acid derivative, there can be mentioned dialkyl esters of terephthalic acid having 1 to 10 carbon atoms in the alkyl group and diaryl esters of terephthalic acid having 6 to 14 carbon atoms in the aryl group. As specific examples of the terephthalic acid derivative, there can be mentioned dimethyl terephthalate, diethyl terephthalate, dipropyl terephthalate, dibutyl terephthalate and diphenyl terephthalate.
- As the other dicarboxylic acid that can be used together with terephthalic acid or its derivative in an amount of not more than 10 mole% of the dicarboxylic acid component, there can be mentioned phthalic acid, isophthalic acid, adipic acid, sebacic acid, naphthalene-1,4-dicarboxylic acid and naphthalene-2,6-dicarboxylic acid.
- The glycol component (B) used in the present invention comprises (B-1) 15 to 85 mole% of an aliphatic diol having 2 to 16 carbon atoms and (B-2) 85 to 15 mole% of 1,4-cyclohexanedimethanol in which the content of the trans-form is at least 80 mole%.
- As the aliphatic diol (B-1) having 2 to 16 carbon atoms, there can be mentioned ethylene glycol, propylene glycol, tetramethylene glycol, hexamethylene glycol, neopentyl glycol, octamethylene glycol, butylethyl propanediol, diethyl propanediol and 3,9-bis(1,1-dimethyl-2-hydroxyethyl)-2,4,8,10-tetraoxaspiro-[5,5]-undecane, and ethylene glycol, propylene glycol, tetramethylene glycol and hexamethylene glycol are especially preferably used. These aliphatic diols can be used alone or in the form of a mixture of two or more thereof. A polyester copolymer obtained by using an aliphatic diol having more than 16 carbon atoms as the aliphatic diol is not preferred because a shaped article obtained from this copolymer has not a satisfactory heat resistance.
- The amount of the aliphatic diol (B-1) having 2 to 16 carbon atoms is 15 to 85 mole%, preferably 30 to 70 mole%, based on the glycol component (B). The polyester copolymer in which the content of the component (B-1) is less than 15 mole% based on the component (B) cannot be used for attaining the object of the present invention, because the rate of crystallization of the polyester copolymer is high. The polyester copolymer in which the content of the component (B-1) is higher than 85 mole% based on the component (B) is not preferably used, because the rate of crystallization becomes high or the glass transition temperature is too low.
- The content of the trans-form in 1,4-cyclohexanedimethanol (B-2) used in the present invention must be at least 80 mole%. A shaped article formed from a polyester copolymer obtained by using 1,4-cyclohexanedimethanol having a trans-form content less than 80 mole% is not satisfactory in the heat resistance.
- The polyester copolymer of the present invention can be obtained by using terephthalic acid, dimethyl terephthalate or other terephthalic acid derivative, and ethylene glycol or other aliphatic diol and 1,4-cyclohexanedimethanol composed mainly of the trans-form as the main starting materials, carrying out an esterification reaction or an ester exchange reaction and subsequently, conducting a polycondensation reaction.
- Catalysts customarily used for the preparation of polyesters can be used for the esterification reaction or ester exchange reaction and the polycondensation reaction.
- A flame retardant, a fibrous reinforcer, a filler, an oxidation stabilizer, a heat stabilizer, a colorant, an ultraviolet absorbent and the like can be added to the polyester copolymer of the present invention according to need.
- The present invention will now be described with reference to the following examples.
- Terephthalic acid as the dicarboxylic acid component and a glycol component comprising 1,4-cyclohexanedimethanol, ethylene glycol, 1,4-butanediol and 1,6-hexanediol at a ratio shown in Table 1 were subjected to esterification at 260' C in the presence of tetrabutyl titanate as the esterification catalyst in an amount of 0.1 % based on the obtained polymer Then antimony trioxide and phosphorous acid were added as the polycondensation catalyst in amounts of 0.03% and 0.04%, respectively, and polycondensation was carried out under a reduced pressure at 285 to 320° C, whereby various polyester copolymers were prepared. Each of the obtained polyester copolymers was recovered in the form of a strand polymer, cooled with water and pelletized by a cutter.
- Each of the obtained polyester copolymers was decomposed with an aqueous solution of hydrazine, and the glycol component was analyzed by the gas chromatography. The results are shown in Table 1.
- Each of the obtained polyester copolymers was dissolved in a phenol/tetrachloroethane mixed solvent (1/1 weight ratio) and the intrinsic viscosity ηsp/C was measured at a polymer concentration of 0.5 g/dl. The results are shown in Table 1.
- The obtained pellet was molded into a molded article having a thickness of 6.4 mm, a length of 127 mm, and a width of 12.6 mm by using a 1-ounce small injection molding machine at a cylinder temperature of 310 to 320° C and a mold temperature of 310 to 320° C.
- Each of the molded articles was a transparent test piece. Each test piece was heated at 140' C corresponding to the molding temperature for the preparation of a sheet or a bottle for 15 minutes, and the degree of whitening by the crystallization was examined. The results are shown in Table 1.
- The degree of whitening was evaluated according to the following scale:
- A: transparent (not changed)
- B: slightly whitened and hazy
- C: frosted glass-like and transparent
- D: turbid and opaque
- The polyester copolymer of the present invention has a low rate of crystallization, and a shaped article obtained from this copolymer has a high heat resistance. Accordingly, the range of application of the shaped article of the polyester resin is wider.
Claims (1)
1. A polyester copolymer obtained by reacting (A) a dicarboxylic acid component composed mainly of terephthalic acid or a derivative thereof with (B) a glycol component comprising (B-1) 15 to 85 mole% of an aliphatic diol having 2 to 16 carbon atoms and (B-2) 85 to 15 mole% of 1,4-cyclohexanedimethanol in which the transform content is at least 80 mole%.
A polyester copolymer as set forth in claim 1, wherein the derivative of terephthalic acid is a dialkyl ester of terephthalic acid having 1 to 10 carbon atoms in the alkyl group or a diaryl ester of terephthalic acid having 6 to 14 carbon atoms in the aryl group.
A polyester copolymer as set forth in claim 1, wherein the glycol component (B) comprises 30 to 70 mole% of the aliphatic diol (B-1) and 70 to 30 mole% of 1,4-cyclohexanedimethanol (B-2).
A polyester copolymer as set forth in claim 1, wherein the aliphatic diol is ethylene glycol.
A polyester copolymer as set forth in claim 1, wherein the aliphatic diol is at least one member selected from the group consisting of propylene glycol, tetramethylene glycol and hexamethylene glycol.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP334862/88 | 1988-12-28 | ||
| JP334861/88 | 1988-12-28 | ||
| JP33486188 | 1988-12-28 | ||
| JP33486288 | 1988-12-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0411136A1 true EP0411136A1 (en) | 1991-02-06 |
| EP0411136A4 EP0411136A4 (en) | 1992-03-18 |
Family
ID=26574973
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19900901021 Withdrawn EP0411136A4 (en) | 1988-12-28 | 1989-12-28 | Polyester copolymer |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US5095089A (en) |
| EP (1) | EP0411136A4 (en) |
| KR (1) | KR930006047B1 (en) |
| WO (1) | WO1990007535A1 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0595413A1 (en) * | 1992-10-26 | 1994-05-04 | Axxis N.V. | Plastic sheet, a process for the manufacture thereof and formed articles containing the sheet |
| WO2003008477A1 (en) * | 2001-07-18 | 2003-01-30 | Eastman Chemical Company | Amorphous copolyesters |
| WO2005105920A1 (en) * | 2004-04-28 | 2005-11-10 | E.I. Dupont De Nemours And Company | Apparatus comprising poly(cyclohexanedimethanol terephthalate) and process therefor |
| US7025925B2 (en) | 2003-02-03 | 2006-04-11 | Eastman Chemical Company | Extrusion blow molded articles |
| US7834127B2 (en) | 2001-07-18 | 2010-11-16 | Eastman Chemical Company | Amorphous copolyesters |
| US9777111B2 (en) | 2005-10-20 | 2017-10-03 | Grupo Petrotemex, S.A. De C.V. | PET polymer with improved properties |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5378796A (en) * | 1994-02-09 | 1995-01-03 | Eastman Chemical Company | Process for preparing copolyesters |
| US20060100330A1 (en) * | 2004-11-10 | 2006-05-11 | Natarajan Kavilipalayam M | Composition for use in forming an article |
| EP1852269A4 (en) * | 2005-02-21 | 2009-04-01 | Techno Polymer Co Ltd | Laminate for laser marking |
| EP1852270B1 (en) * | 2005-02-21 | 2013-09-25 | Techno Polymer Co., Ltd. | Process for producing a laser-marked laminate and use of a laminate for laser marking |
| US7375167B2 (en) * | 2005-05-09 | 2008-05-20 | Basf Se | Hydrolysis-resistance composition |
| US20070003746A1 (en) * | 2005-06-30 | 2007-01-04 | Solutia, Inc. | Polymer interlayers comprising poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB988316A (en) * | 1962-05-05 | 1965-04-07 | Dehydag Gmbh | Process for the preparation of trans-1,4-dimethylolcyclohexane |
| DE1222205B (en) * | 1955-12-22 | 1966-08-04 | Eastman Kodak Co | Certain polyesters for making foils or threads |
| DE1258086B (en) * | 1961-03-09 | 1968-01-04 | Eastman Kodak Co | High-melting polyester for the production of threads and foils |
| DE1935252A1 (en) * | 1969-07-11 | 1971-01-14 | Hoechst Ag | Amorphous linear copolyesters |
| US4093603A (en) * | 1977-01-19 | 1978-06-06 | Eastman Kodak Company | Copolyesters of terephthalic acid, 1,2-propanediol and 1,4-cyclohexanedimethanol |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE592181A (en) * | 1955-12-22 | |||
| US4246381A (en) * | 1979-06-18 | 1981-01-20 | Union Carbide Corporation | Polyarylate blends with copolyesters |
| US4259478A (en) * | 1979-12-14 | 1981-03-31 | Eastman Kodak Company | Process for preparing high molecular weight copolyesters |
| JPS5821430A (en) * | 1981-07-31 | 1983-02-08 | Toyobo Co Ltd | Polyester film having improved printability |
| EP0109647B2 (en) * | 1982-11-18 | 1993-09-15 | Asahi Kasei Kogyo Kabushiki Kaisha | Easily dyeable copolyester fiber and process for preparing the same |
| US4786692A (en) * | 1982-12-20 | 1988-11-22 | General Electric Company | High strength, reduced heat distortion temperature thermoplastic composition |
| US4557982A (en) * | 1983-04-07 | 1985-12-10 | Teijin Limited | Magnetic recording flexible disc |
| US4900610A (en) * | 1988-02-19 | 1990-02-13 | Hoechst Celanese Corporation | Polyester molding composition |
| JPH0562345A (en) * | 1991-09-06 | 1993-03-12 | Matsushita Electric Ind Co Ltd | Audio magnetic recording/reproducing device |
-
1989
- 1989-12-28 EP EP19900901021 patent/EP0411136A4/en not_active Withdrawn
- 1989-12-28 KR KR1019900701915A patent/KR930006047B1/en not_active IP Right Cessation
- 1989-12-28 WO PCT/JP1989/001326 patent/WO1990007535A1/en not_active Application Discontinuation
- 1989-12-28 US US07/571,537 patent/US5095089A/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1222205B (en) * | 1955-12-22 | 1966-08-04 | Eastman Kodak Co | Certain polyesters for making foils or threads |
| DE1258086B (en) * | 1961-03-09 | 1968-01-04 | Eastman Kodak Co | High-melting polyester for the production of threads and foils |
| GB988316A (en) * | 1962-05-05 | 1965-04-07 | Dehydag Gmbh | Process for the preparation of trans-1,4-dimethylolcyclohexane |
| DE1935252A1 (en) * | 1969-07-11 | 1971-01-14 | Hoechst Ag | Amorphous linear copolyesters |
| US4093603A (en) * | 1977-01-19 | 1978-06-06 | Eastman Kodak Company | Copolyesters of terephthalic acid, 1,2-propanediol and 1,4-cyclohexanedimethanol |
Non-Patent Citations (1)
| Title |
|---|
| See also references of WO9007535A1 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0595413A1 (en) * | 1992-10-26 | 1994-05-04 | Axxis N.V. | Plastic sheet, a process for the manufacture thereof and formed articles containing the sheet |
| BE1006297A3 (en) * | 1992-10-26 | 1994-07-12 | Axxis Nv | Plastic sheet, process for the production thereof and shape parts containing the plate. |
| US5709929A (en) * | 1992-10-26 | 1998-01-20 | Axxis N.V. | Plastic sheet, a process for the manufacture thereof and formed articles containing the sheet |
| WO2003008477A1 (en) * | 2001-07-18 | 2003-01-30 | Eastman Chemical Company | Amorphous copolyesters |
| US7026027B2 (en) | 2001-07-18 | 2006-04-11 | Eastman Chemical Company | Amorphous copolyesters |
| US7834127B2 (en) | 2001-07-18 | 2010-11-16 | Eastman Chemical Company | Amorphous copolyesters |
| US7025925B2 (en) | 2003-02-03 | 2006-04-11 | Eastman Chemical Company | Extrusion blow molded articles |
| WO2005105920A1 (en) * | 2004-04-28 | 2005-11-10 | E.I. Dupont De Nemours And Company | Apparatus comprising poly(cyclohexanedimethanol terephthalate) and process therefor |
| US9777111B2 (en) | 2005-10-20 | 2017-10-03 | Grupo Petrotemex, S.A. De C.V. | PET polymer with improved properties |
Also Published As
| Publication number | Publication date |
|---|---|
| KR930006047B1 (en) | 1993-07-03 |
| KR910700288A (en) | 1991-03-14 |
| WO1990007535A1 (en) | 1990-07-12 |
| EP0411136A4 (en) | 1992-03-18 |
| US5095089A (en) | 1992-03-10 |
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