EP0363471A1 - Dyed mineral pigments and applications - Google Patents
Dyed mineral pigments and applicationsInfo
- Publication number
- EP0363471A1 EP0363471A1 EP89904933A EP89904933A EP0363471A1 EP 0363471 A1 EP0363471 A1 EP 0363471A1 EP 89904933 A EP89904933 A EP 89904933A EP 89904933 A EP89904933 A EP 89904933A EP 0363471 A1 EP0363471 A1 EP 0363471A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- hectorite
- pigment
- mineral
- dye
- organic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/28—Colorants ; Pigments or opacifying agents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0041—Optical brightening agents, organic pigments
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B63/00—Lakes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
- C09B69/02—Dyestuff salts, e.g. salts of acid dyes with basic dyes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/40—Compounds of aluminium
- C09C1/405—Compounds of aluminium containing combined silica, e.g. mica
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/40—Compounds of aluminium
- C09C1/42—Clays
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/68—Particle size between 100-1000 nm
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/20—Particle morphology extending in two dimensions, e.g. plate-like
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/90—Other properties not specified above
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
Definitions
- This invention relates to pigments useful for coloring or tinting inks, paints, plastics and rubber, and more particularly, relates to such pigments which are produced as reaction products of minerals and cationic organic dyes.
- Minerals have been used historically in a number of applications such as viscosifiers, anti-settling agents, thixotropes or rheological additives in both aqueous and organic systems. Numerous patents have been issued covering the uses of minerals, including smectite-type minerals, in paints, greases, cosmetics, inks, polyesters and other areas. Also it has been known for many years that layered silicate minerals such as kaolinite, mica, vermiculite, and smectites have a natural exchange capacity for cationic compounds both of the inorganic and organic types. It is this natural exchange capacity characteristic which allows smectitic clays to be converted to useful thixotropes for organic systems.
- organic cationic dye such as methylene blue
- organic cationic dyes can be fixed to any layered silicate mineral that possessed an ionic charge.
- the pigment to be dyed must accept and hold the dye, not only during the dyeing step but also in subsequent processing steps. Failure to hold the dye results in reduced efficiency of the treatment, and disposal or recirculation of colored filtrates is economically undesirable.
- U.S. Patent No. 4,410,364 discloses a printing ink formed by dispersing therein an ink coloring material and an organophilic clay gellant.
- the organophilic clay gellant is the reaction product of an organic cation, an organic anion, and a smectite-type clay which has a cationic exchange capacity of at least 75 milliequivalents per 100 grams of the clay so that an organic cation-organic anion complex is intercalated with the smectite-type clay and the cationic exchange sites of the smectite-type clay are substituted with the organic cation.
- U. S. Patent No. 4,116,866 discloses the reaction product of a clay with a quaternary ammonium cationic compound.
- bentonite and hectorite the latter being described as a swelling magnesium-lithium silicate clay.
- Other types of smectite-type clays disclosed in this patent for reaction include montmorillonite, beidellite, saponite and stevensite.
- a similar product is disclosed in U.S. Patent No. 4,287,086.
- U.S. Patent No. 4,105,578 to Finlayson et al discloses organophilic clay gellants prepared as the reaction product of a smectite-type clay and a quaternary ammonium compound. These products are also said to have good dispersability in organic liquids and to form gels and to be useful in lubricating greases, oil paste muds, oil-based packer fluids, paint-varnish-lacquer removers, paints, and foundry molding sand binders and the like.
- a series of older U.S. patents including U.S. Patent No. 2,531,440, 2,531,427, and 2,966,506 disclose modified clay complexes which are compatible with organic liquids.
- organic clay complexes comprise the reaction product of a clay such as montmorillonite or bentonite and including hectorite with an organic compound of the quaternary ammonium type.
- the clays used in this series of patents are said to have base exchange capacities which range from about 15 to 100 based on milliequivalents of exchangeable base per 100 grams of clay. These products are disclosed for use as gelling agents.
- U.S. Patent No. 4,382,868 discloses organophilic clays which have enhanced dispersability in organic liquids, the organophilic clays being prepared by extruding a mixture of a smectite clay, a quaternary cationic organic compound, water and an alcohol.
- U.S. Patent No. 3,974,125 discloses thixotropic agents comprising clays which have been reacted with dialkyl dimethyl ammonium quaternary salts and incorporation of these products into polyesters.
- 3,864,294 discloses coating compositions in the form of a gel which comprise an amine modified montmorillonite clay, a swelling agent therefor, and a non-volatile oleaginous agent for wetting the clay.
- This product is indicated as adapted for pigment-containing coating systems such as in nail enamel compositions.
- European Patent Application No. 206,800 published March 30, 1986, discloses water insoluble pigments which comprise a complex of the water insoluble inorganic anionic exchange material which has a layered structure and a water soluble dye.
- the anionic exchange material with the layered structure may comprise any of a number of known mineral materials including magnesium aluminum chloride and the dyes are organic dyes.
- the present invention provides a coloring pigment useful for coloring materials which is an improvement over these prior known products.
- a further object of the present invention is to provide a pigment for coloring materials which comprises the reaction product of an organic dye with a mineral.
- a still further object of the present invention is to provide methods for preparation of pigments useful for coloring or tinting various products which comprises reaction of a mineral having a small particle size and high cation exchange capacity with a cationic organic dye.
- An even further object of the present invention is to provide colored or tinted inks, paints, plastics and rubber, wherein the coloring agent is a pigment which is the reaction product of a cationic organic dye with a hectorite mineral, the hectorite mineral being characterized by having a small average particle size, a novel morphology and high cation exchange capacity.
- the pigment has color strength equal to commercial pigments and does not bleed in water or oil, and is easily dispersable in aqueous and organic media.
- a coloring pigment useful for coloring or tinting inks, paints, plastics and rubber comprising the reaction product of a cationic organic dye and a mineral, preferably a hectorite mineral, the mineral having a small average particle size and a high cation exchange capacity.
- the present invention also provides a method for preparation of pigments useful for coloring or tinting inks, paints, plastics and rubber which comprises reacting a cationic organic dye with a mineral, the mineral having a small average particle size, a novel morphology and high cation exchange capacity, the reaction being carried out in dried form or in an aqueous medium, and recovering the reaction product.
- compositions containing a coloring pigment which comprises the reaction product of a cationic organic dye and a mineral, the mineral having a small average particle size and high cation exchange capacity.
- Figure 1 is an enlarged photograph (40,000X) of the Nevada hectorite mineral used in the present invention.
- Figure 2 is an enlarged photograph (40,000X) of a California hectorite.
- the present invention relates to a pigment which is useful for coloring or tinting various materials including inks, paints, plastics and rubber.
- This pigment is the reaction product of a cationic organic dye and a mineral which is characterized by unique physical and chemical characteristics .
- the pigment produced in accordance with the present invention provides a lower-priced pigment which has the same color strength as commercially used organic and inorganic pigments.
- the pigment has a color strength equal to commercially-used organic and inorganic pigments when used in color loading amounts of only about 40 to 100% of the amounts required of commercial organic or inorganic pigments. It has unexpectantly been found that these unique pigments do not bleed in water or oil when treated with the proper level of cationic dye and when ground properly, yield pigments which disperse easily into both water and organic media.
- the pigments of the present invention can be used in any application where coloring or tinting of a finished material is desired.
- Inks, paints, plastics and rubber are major systems in which the new dye/mineral pigments can be used.
- the dye pigments can be prepared by any number of reaction routes and in fact all methods of preparing organically reacted materials - - rheological , thixotropes , viscosifiers or anti-settling agents, can be used successfully. Depending on the end use of the new dye/mineral pigment, certain of the steps may or may not be used. Thus the new pigments can be prepared by an essentially dry process or a wet slurry process. Any process by which the organic dye can be exchanged for the naturally occurring counter ion on the mineral can be used in the manufacture of the pigments.
- additional steps such as sodium exchange of the clay, heating, shearing of the mineral slurry, shearing of the dye mineral product, or special drying and grinding conditions can be used. Many of these steps are conventionally used in the manufacture of organo clays for rheological, thixotropic, viscosifiers and anti-settling agents.
- organo clay materials of the art cannot be used for adding color to a material which requires pigmenting.
- the base material selected for organo clays is often selected so as to have a high enough brightness that it does not interfere with the development of color in the system in which the organo clays are used.
- the dye/mineral pigments of the present invention are selected so that they provide color to the system in which they are used.
- organo clays conventionally add viscosity to the system whereas the dye/mineral pigments of this invention can be selected so that the dye/mineral pigments yield as small a viscosity increase as possible in the system in which they are used.
- the starting material used in organo clays is normally selected so that it has the best swelling when converted to the organo clay.
- the mineral can be selected so as to provide any desired increase in viscosity or swelling or even none at all.
- the minerals used to prepare pigments according to the present invention comprise any mineral which have a small particle size, a very high cation exchange capacity, and unique charge density distribution as defined herein.
- the preferred minerals are selected from the group consisting of hectorite bentonite, montmorillonite, zeolites and the like as well as mixtures thereof. Hectorites are preferred minerals. Minerals whose characteristics have been altered synthetically are also within the scope of the invention. Hectorites in general are known as magnesium/lithium/ silicate clays.
- the hectorites used in the formation of the products of the present invention are small particle size hectorites which have a very high cation exchange capacity and which has a unique charge density distribution.
- the charge density distribution can be seen or detected by differences in the x-ray diffraction spacing. Spacings obtained with this measurement are related to the size of the molecule used and charge density distribution. The hectorites used in this invention provide much higher spacings than other clays of this class when treated in the same manner.
- the hectorite preferably used in this invention is a McDermitt, Nevada hectorite and is of the type which is preferably mined in the state of Nevada and which is characterized by a morphology which is distinct from that of other known hectorites.
- the hectorite has a very fine particle size and will average about 0.1 to 0.6 in average particle size and preferably is about 0.4 microns in average particle size.
- This hectorite is a calciummagnesium hectorite which means that it contains larger amounts of calcium than conventional hectorites. The hectorite therefore does not swell as much in aqueous systems as sodium hectorites.
- the hectorite Because of the large amount of calcium and magnesium contained in the hectorite, it is preferred according to this invention to conduct a conventional exchange reaction with sodium carbonate and/or a sodium exchange resin to convert the calcium form to the sodium form.
- the resulting product has a very high cation exchange capacity in the range of 110 to 150 milliequivalents per 100 grams of the dry clay.
- the cation exchange capacity in milliequivalents per 100 grams of dry clay is calculated on the Ammonium Acetate-Kjeldahl Cation Exchange Capacity test.
- the hectorite preferably used in the invention to prepare the coloring agents is found only in Nevada and according to this invention is described as being McDermitt, Nevada hectorite.
- the hectorite is mined as a crude product at the site in Nevada and is processed to obtain the products suitable for use in this invention by conventional clay processing procedures.
- the crude hectorite mineral is dried and crushed or ground to reduce the particle size.
- the crude mineral is then mixed with water and soda ash or other form of sodium carbonate and extruded through extruders which apply shear to the material. It is preferred to extrude about 1-3 times to obtain good mixing and also at this stage to obtain an exchange reaction with the sodium carbonate to convert at least a portion of the calcium form to the sodium form.
- an optional step is then to try and again grind the resulting product.
- the hectorite is then made down with water usually under steam and then screened to remove the coarse particles.
- the resulting product is then centrifuged to separate out fines so as to recover a clean clay fraction which contains no more than about 1-2% of contaminants.
- This hectorite has a morphology different from other hectorites of the art in that the particles are generally square or plate-like in shape and are of fine particle size averaging between about .1 and .6 microns. This is to be contrasted with other hectorites which are generally narrow lath-type hectorites.
- the hectorite of the invention has a charge density which causes a greater than 28.5 angstroms D(001) spacing.
- the charge density is measured by X-ray diffraction based on the D(001) spacing on the mineral using a dimethyl dihydrogenated tallow ammonium chloride treatment equal to the cation exchange capacity of the material. This determination is made by running an X-ray diffraction pattern. In general as the cation exchange capacity increases, the charge density will also increase. In the present case, the charge density of the hectorite of the invention is so high that the molecule will actually become vertical or stand erect during the determination.
- the hectorite used in the present invention has a number of characteristics which distinguish it from other hectorites and other minerals of the smectite class . It is these unusual advantages including the high cation exchange capacity which contribute to the substantial advantages achieved when forming the coloring agent of the present invention.
- This hectorite is reacted with a dye and preferably a cationic organic dye to form the products of the present invention.
- the dyes can be any conventional dye which will react with the hectorite base mineral but preferably is a cationic dye.
- These cationic dyes are well known and include such materials as methyl violet, methylene blue, victoria blue, rhodamine red, Auramine yellow and the specific dyes listed below. Victoria Blue B Methylene Blue Methyl violet X
- a hectorite aqueous slurry which may contain from about 1 to 10% solids of hectorite by weight.
- the hectorite slurry is then heated to about 50 to 100oC with good mixing and the dye is then dissolved in water and the dye solution is then added and then allowed to react with the hectorite for about 10 minutes to 1 hour with good mixing.
- the dye/ hectorite pigment is preferably sheared under high agitation conditions for a short time to achieve the final mixing.
- the sheared material may then be filtered and washed to remove excess salt.
- the filter cake is then dried and preferably ground to a very fine particle size.
- An important aspect of the present invention is to determine the amount of dye which is to be reacted with the hectorite to form the coloring pigment of the invention.
- a preferred procedure to follow in determining the amount of dye is to use a procedure of the American
- A weight of the hectorite to be treated (dry weight);
- the water used can be tap water or deionized water. It is not necessary to heat the reaction slurry but the better results are provided with heat. Shearing improves the clay dispersion and treatment effectiveness but is not critical to produce the product. Drying can be carried out under controlled low- temperature conditions to prevent the material from drying to excessive hardness. Milling is preferably carried out to obtain the desired fineness for each application.
- the preferred loading amounts When incorporated into ink, the preferred loading amounts will range up to about 12 weight percent which corresponds to about 7 weight percent hectorite in the final pigment. Loading amounts in plastics range from about 0.50 to 0.75 weight percent.
- a hectorite clay slurry was prepared by adding 15 grams of dry hectorite to water. The slurry was then heated with agitation at 80oC for 30 minutes. Then 5.05 grams of cationic methylene blue dye was formed as an aqueous solution and added to the hectorite clay slurry. The mixture was then heated for an additional period at 80oC then cooled and filtered. The dye-treated hectorite was then recovered.
- the hectorite slurry was heated to 60 to 80°C while being mixed on a Lightnin Mixer.
- the dye was dissolved in water at 5% solids.
- the dye solution was then added to the hectorite slurry and allowed to react for 30 minutes with mixing and heating at 60°-80°C.
- the dyed hectorite pigment was then sheared for one minute in a large Waring blender.
- the sheared material was poured on filters and vacuum filtered and wash water was applied to remove excess salt.
- the filter cake was dried at 80oC in an oven and ground through a 0.062 inch round hole screen and four passes through a 0.020 inch round hole screen on a Mikro Sampl Mill.
- Another sample was prepared as above and milled only one pass each through a 0.062 and 0.020 round hole screens on a Mikro Sampl Mill.
- This second sample was jet milled at Alpine American Corporation in a 100 AFG Mill. Both of these materials were compounded in polypropylene plastic and injection molded. Test results showed properties of the non-jet milled sample were fairly comparable to the unfilled polypropylene except in Gardner drop weight impact while results from the jet milled sample increased the Gardner drop weight impact back towards the unfilled polypropylene values.
- Jet milling the methyl violet sample improved coloring capacity as the non-jet milled sample was translucent while the jet milled sample was opaque.
- TENSILE TENSILE ELONGA TENSILE BLONCA.
- a dye-hectorite pigment was prepared which contained various dyes including victoria blue, methylene blue, methyl violet, rhodamine red, and Auramine yellow. Samples of these dye-hectorite pigments were incorporated into Himont PP6601 at 0.5 and 0.75 wt% levels. All samples were stabilized with 0.075% of a thioester and 0.1% phenolic Goodrite 3114. These products are shown in Table IV.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Dispersion Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Nanotechnology (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Abstract
Un pigment de coloration qui sert à colorer ou à teinter des encres, des peintures, des plastiques et du caoutchouc fait intervenir le produit de réaction d'une teinture organique cationique et d'un minéral, de préférence de l'hectorite, le minérau présentant une granulométrie moyenne faible et une capacité d'échange de cations élevée. Le pigment présente une excellente stabilité de couleur et ne déteint pas dans l'eau ou l'huile, et peut facilement se disperser dans un milieu aqueux ou organique.A coloring pigment which is used to color or tint inks, paints, plastics and rubber involves the reaction product of a cationic organic dye and a mineral, preferably hectorite, the mineral having a low average particle size and a high cation exchange capacity. The pigment has excellent color stability and does not fade in water or oil, and can easily disperse in an aqueous or organic medium.
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US18331188A | 1988-04-05 | 1988-04-05 | |
US183311 | 1988-04-05 |
Publications (2)
Publication Number | Publication Date |
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EP0363471A1 true EP0363471A1 (en) | 1990-04-18 |
EP0363471A4 EP0363471A4 (en) | 1991-06-19 |
Family
ID=22672286
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP19890904933 Ceased EP0363471A4 (en) | 1988-04-05 | 1989-04-05 | Dyed mineral pigments and applications |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0363471A4 (en) |
JP (1) | JPH03500059A (en) |
CN (1) | CN1047681A (en) |
AU (1) | AU3449789A (en) |
WO (1) | WO1989009804A1 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1236972B (en) * | 1989-11-03 | 1993-05-07 | Eniricerche Spa | ORGANOFILA CLAY AND PROCEDURE FOR ITS PREPARATION. |
NL1012587C2 (en) * | 1999-07-13 | 2001-01-16 | Tno | Nanocomposite coating composition, contains layered inorganic filler which has been modified using a compound with at least two ionic groups |
WO2001004050A1 (en) * | 1999-07-13 | 2001-01-18 | Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno | Nanocomposite coatings |
AU2002351580A1 (en) * | 2001-12-14 | 2003-06-30 | Georgi Kirov | Organomineral pigment fillers, methods for their manufacture and applications |
GB0308487D0 (en) | 2003-04-14 | 2003-05-21 | Ciba Spec Chem Water Treat Ltd | Paper coating compositions |
JP4777023B2 (en) * | 2005-09-06 | 2011-09-21 | キヤノン株式会社 | Color image acquisition method and color imaging apparatus |
CN112004891A (en) * | 2018-04-04 | 2020-11-27 | 阿尔塔纳股份公司 | Effect pigments based on pigmented hectorite and coated pigmented hectorite and their manufacture |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS508462B1 (en) * | 1969-09-02 | 1975-04-04 | ||
JPS5244377B2 (en) * | 1974-03-29 | 1977-11-08 | ||
JPS5464644A (en) * | 1977-10-31 | 1979-05-24 | Shiseido Co Ltd | Cosmetics |
JPS58134154A (en) * | 1982-02-03 | 1983-08-10 | Toyo Soda Mfg Co Ltd | Pigment composition |
JPS61111367A (en) * | 1985-05-15 | 1986-05-29 | Pola Chem Ind Inc | Production of colored extender pigment |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1423137A (en) * | 1972-02-23 | 1976-01-28 | Johnson Matthey Co Ltd | Printing ink |
JPS5347139A (en) * | 1976-10-12 | 1978-04-27 | Kato Matsuo | Sash roller |
US4193806A (en) * | 1977-06-27 | 1980-03-18 | N L Industries, Inc. | Viscosity increasing additive for printing inks |
US4081496A (en) * | 1977-06-27 | 1978-03-28 | N L Industries, Inc. | Thixotropic polyester compositions containing an organophilic clay gellant |
-
1989
- 1989-04-05 JP JP1504754A patent/JPH03500059A/en active Pending
- 1989-04-05 EP EP19890904933 patent/EP0363471A4/en not_active Ceased
- 1989-04-05 WO PCT/US1989/001391 patent/WO1989009804A1/en not_active Application Discontinuation
- 1989-04-05 AU AU34497/89A patent/AU3449789A/en not_active Abandoned
- 1989-05-29 CN CN89103635A patent/CN1047681A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS508462B1 (en) * | 1969-09-02 | 1975-04-04 | ||
JPS5244377B2 (en) * | 1974-03-29 | 1977-11-08 | ||
JPS5464644A (en) * | 1977-10-31 | 1979-05-24 | Shiseido Co Ltd | Cosmetics |
JPS58134154A (en) * | 1982-02-03 | 1983-08-10 | Toyo Soda Mfg Co Ltd | Pigment composition |
JPS61111367A (en) * | 1985-05-15 | 1986-05-29 | Pola Chem Ind Inc | Production of colored extender pigment |
Non-Patent Citations (6)
Title |
---|
See also references of WO8909804A1 * |
World Patents Index (Latest), Accession No. 86-178909,Week 28, Derwent Publications Ltd., London, GB & JP-A-61111367 (Pola Kasei Kogyo KK) 29-05-1986 * |
World Patents Index Accession No 75-29800W, Week 18 Derwent Publications Ltd, London GB & JP-B-50008462 (Kato C.) 04.04.1975 * |
World Patents Index Accession No 77-85943Y, Week 48 Derwent Publications Ltd, London GB & JP-B-52044377 (Pola Kasai Kogyo KK) 08.11.1977 * |
World Patents Index Accession No 79-49819B, Week 27 Derwent Publications Ltd, London GB & JP-A-54064644 (Shiseido KK) 24.05.1979 * |
World Patents Index Accession No 83-767250, Week 38 Derwent Publications Ltd, London GB & JP-A-58134154 (Toyo Soda MFG KK) 10.08.1983 * |
Also Published As
Publication number | Publication date |
---|---|
JPH03500059A (en) | 1991-01-10 |
CN1047681A (en) | 1990-12-12 |
EP0363471A4 (en) | 1991-06-19 |
WO1989009804A1 (en) | 1989-10-19 |
AU3449789A (en) | 1989-11-03 |
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