EP0361541A2 - Druckwechsel-Adsorptionsverfahren - Google Patents
Druckwechsel-Adsorptionsverfahren Download PDFInfo
- Publication number
- EP0361541A2 EP0361541A2 EP89121323A EP89121323A EP0361541A2 EP 0361541 A2 EP0361541 A2 EP 0361541A2 EP 89121323 A EP89121323 A EP 89121323A EP 89121323 A EP89121323 A EP 89121323A EP 0361541 A2 EP0361541 A2 EP 0361541A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- bed
- pressure
- gas
- adsorption
- void space
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
- B01D53/0473—Rapid pressure swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/12—Oxygen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/102—Nitrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40013—Pressurization
- B01D2259/40015—Pressurization with two sub-steps
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40028—Depressurization
- B01D2259/4003—Depressurization with two sub-steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40028—Depressurization
- B01D2259/40032—Depressurization with three sub-steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40035—Equalization
- B01D2259/40037—Equalization with two sub-steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40043—Purging
- B01D2259/4005—Nature of purge gas
- B01D2259/40052—Recycled product or process gas
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40058—Number of sequence steps, including sub-steps, per cycle
- B01D2259/40067—Seven
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/404—Further details for adsorption processes and devices using four beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/406—Further details for adsorption processes and devices using more than four beds
- B01D2259/4061—Further details for adsorption processes and devices using more than four beds using five beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/406—Further details for adsorption processes and devices using more than four beds
- B01D2259/4063—Further details for adsorption processes and devices using more than four beds using seven beds
Definitions
- the invention relates to the purification of gases in a pressure swing adsorption system. More particularly, it relates to improvements in the processing cycle enabling improved performance to be achieved.
- the pressure swing adsorption (PSA) process provides a commercially desirable technique for separating and purifying at least one component of a feed gas mixture containing said component and at least one selectively adsorbable component. Adsorption occurs in an adsorbent bed at a higher adsorption pressure, with the selectively adsorbable component thereafter being desorbed by reducing the adsorbent bed pressure to a lower desorption pressure.
- the carrying out of the PSA process in multi-bed systems is illustrated by the Wagner patent, U.S. 3,430,418, relating to a system having at least four beds.
- the PSA process is commonly carried out, on a cyclic, in a processing sequence that includes, in each bed, (1) higher pressure adsorption with release of product effluent from the product end of the bed, (2) cocurrent depressurization to intermediate pressure with release of void space gas from the product end thereof, (3) countercurrent depressurization to a lower desorption pressure, (4) purge and (5) repressurization.
- the void space gas released during the cocurrent depressurization step is commonly employed for pressure equalization purposes and to provide purge gas to a bed at its lower desorption pressure.
- a conventional three bed system was devised for use in the separation and recovery of air and other such separations.
- This system was based on the increasing pressure adsorption step described in the McCombs patent, U.S. 3,738,087.
- air is added to an adsorbent bed for the repressurization thereof, with nitrogen being selectively adsorbed and with oxygen being discharged from the product end of the bed at rates such that the bed pressure increases to upper adsorption pressure.
- a PSA cycle incorporating said increasing pressure adsorption step includes (1) said increasing pressure adsorption step, (2) cocurrent depressurization to intermediate pressure with release of void space gas from the product end thereof, (3) countercurrent depressurization to a lower desorption pressure, (4) purge and (5) repressuriza tion.
- the void space gas released during the cocurrent depressurization step is employed, in this embodiment, for passage to other beds in the system in a pressure equalization-provide purge-pressure equalization sequence.
- This latter cycle makes unnecessary a constant pressure adsorption step as employed in the Wagner cycle. This enables more time for bed regeneration, i.e. countercurrent depressurization and purge, within a given cycle time so as to enable greater productivity and recovery and/or purity to be obtained from a given system, particularly in systems designed for relatively short overall cycle time operation.
- a PSA process including the steps of adsorption, cocurrent and countercurrent depressurization, purge and repressurization likewise is known from FR-A-2 535 981.
- cocurrent depressurization gas is passed from a depressurizing bed to an auxiliary column that separates undesirable and desirable components by longitudinal separation. Gas passes from the non-feed end of the auxiliary column for use in countercurrent repressurization of another bed.
- Such cocurrent depressurization and countercurrent repressurization between each succeeding pair of beds is accomplished by passage of gas through the auxiliary column in opposite flow directions.
- a pressure swing adsorption process for the separation and recovery of a less readily adsorbable component of a feed gas mixture in an adsorption system capable of selectively adsorbing a more readily adsorbable component from said gas mixture, the adsorption system containing at least three adsorbent beds, each of which undergoes, on a cyclic basis, a processing sequence that includes (1) adsorption with discharge of the less readily adsorbable component as product effluent from the product end of the bed, (2) cocurrent depressurization with release of void space gas from the product end of the bed and the passage of said gas to other beds in the system for pressure eqali zation and for provide purge purposes, (3) countercurrent depressurization to lower desorption pressure with release of said more readily adsorbable component from the feed end of the bed, (4) purge at said lower desorption pressure, (5) partial repressurization by pressure equalization with
- the PSA process of the present invention particularly is suited for the enhanced separation and recovery of oxygen from air.
- the PSA process of the invention advantageously employs novel simultaneous cycle steps that enable the total cycle time to be reduced, product recovery to be enhanced, and BSF reductions to be achieved.
- the time required for the separate provide purge step is desirably shorter than the purge step, with the overall countercurrent depressurization and purge time enabling adequate bed regeneration to be accomplished with the overall shorter total cycle times permissible in the practice of the invention.
- the objects of the invention are accomplished by the incorporation into the PSA process as described above with reference to the Wagner patent of a simultaneous cycle step relating to the cocurrent depressurization and the countercurrent depressurization portions of the overall cycle.
- a simultaneous step enables the total cycle time to be reduced and BSF reductions, i.e. increased adsorbent productivity, to be obtained.
- Enhanced bed capacity can be achieved in the practice of the invention at minimized overall cycle times without degradation of product effluent purity or recovery.
- the invention has been found to actually result in significant improvements in product recovery as compared with the standard commercial 3-bed PSA process and system referred to above.
- the invention can advantageously be employed in multi-bed PSA systems having at least three adsorbent beds therein, with systems containing four beds being highly desirable for some applications. Five, slx or seven adsorbent bed systems are also desirable in some instances. While the invention can be practiced in systems having 8 or more beds, it is commonly expedient to employ two 4-bed systems, or the like, as an alternative to such higher number of beds in a single system. It will be understood that, in such multi-bed systems, the feed gas may be passed to more than one bed at any particular stage of the processing cycle. Thus, the feed gas is often passed to at least two beds at any given time in the operation of such multi-bed systems.
- the PSA process desirably employs two, three or more pressure equalization steps in which cocurrent depressurization gas released from one bed at an elevated pressure is used to partially repressurize another bed initially at lower pressure and to provide purge to a bed at lower desorption pressure.
- the invention can be used in a variety of processing cycles such as, for example, those involving five or more beds with two beds on adsorption at any given time, in overlapping sequence, during the overall PSA processing cycle.
- processing cycles such as, for example, those involving five or more beds with two beds on adsorption at any given time, in overlapping sequence, during the overall PSA processing cycle.
- PSA processes and systems can be adapted so as to take advantage of the desirable benefits of the invention in desirable PSA cycles.
- A represents an adsorption step at an upper adsorption pressure with discharge of the less readily adsorbable component as product effluent from the product end of the bed
- PP represents a cocurrent depressurization step in which void space gas is released from the product end of the bed for use in providing purge gas to another bed typically at its lower desorption pressure, said bed being depressurized from an upper intermediate pressure to an intermediate pressure level
- P represents a purge step typically at lower desorption pressure in which void space gas released from another bed is passed directly to said bed undergoing its purge step, with said purge step being seen to be of longer duration than the provide purge step PP
- R represents repressurization to upper adsorption pressure
- E1/PP represents a cocurrent depressurization step in which void space gas released during cocurrent depressurization from said upper adsorption pressure to an upper intermediate pressure is passed simultaneously to one other bed in the system being partially repress
- E1/PP and E2/BD As two pressure equalization steps are employed, i.e said E1/PP and E2/BD and their counterparts E2 and E1, the overall cycle is referred to in the heading of the Table as a (412) E1/PP - E2/BD cycle, the 4 representing the number of beds, the 1 representing the number of beds on adsorption at any given time, and the 2 representing the number of direct pressure equalization steps, and E1/PP - E2/BD denoting the steps wherein the two simultaneous processing features described above are employed in the PSA processing cycle to obtain the benefits referred to herein.
- the E1/PP step is carried out, e.g. in bed 1, by the cocurrent depressurization of said bed with the void space gas released from the product end of the bed being simultaneously passed to bed 3 for pressure equalization at upper intermediate pressure and to bed 4 for the initial portion of the purge step in said bed.
- the E2/BD step is carried out with additional void space gas being released from the product end of bed 1, which is cocurrently depressurized to a lower intermediate pressure, said gas being passed to bed 4 for pressure equalization at said lower intermediate pressure.
- Bed 1 is simultaneously depressurized countercurrently by the discharge of gas from the feed end thereof.
- the BD portion of the step is continued after completion of the E2 portion upon pressure equalization of depressurizing bed 1 and repressurizing bed 4 at said lower intermediate pressure.
- the E2 step represents partial repressurization of a bed from its lower desorption pressure to lower intermediate pressure by the passage of void space gas thereto, typically directly, from a bed being cocurrently depressurized in its E2/BD step from intermediate pressure to said lower intermediate pressure by pressure equalization with said bed being partially repressurized from its lower desorption pressure to said lower intermediate pressure.
- E1 represents further partial repressurization to upper intermediate pressure by the passage of void space gas thereto, typically directly, from a bed being cocurrently depresurized in its E1/PP step from upper adsorption pressure to upper intermediate pressure by pressure equalization with said bed being partially repressurized from its lower to its upper intermediate pressure.
- each bed being operated at an upper adsorption pressure of 377 kPa (40 psig)
- a 160 second total or overall cycle time can be effectively utilized.
- the BSF of commercial 13X, 8 x 12 beaded, molecular sieve adsorbent has 1500 kg (3,000 lb.) of said 13X/TPD of oxygen product at 90 % product purity. Revocery of oxygen product was 53 %.
- the process of the present invention uses an increasing pressure adsorption step as the repressurization step, i.e. step R of Tables I and II, following partial repressurization of a bed by pressure equalization, i.e. steps E2 and E1 of said Tables.
- the repressurization to upper adsorption pressure is carried out with product effluent being simultaneously discharged from the product end of the bed.
- the constant pressure adsorption step can thus be made shorter to allow for more time for bed regeneration purposes, thereby enabling product purity and/or recovery to be enhanced.
- said increasing pressure adsorption step can advantageously be employed, together with the E2/BD step of the invention in 3-bed PSA systems without a constant pressure adsorption step or the E1/PP step of the process of the parent application. This processing variation can also be employed in PSA systems having more than three beds.
- the PSA system will comprise conduit means for passing void space gas released from the product end of a bed during cocurrent depressurization from said upper intermediate pressure to another bed for providing purge gas to said bed.
- Conduit means are also provided for passing additional void space gas released from the product end of the bed, during further cocurrent depressurization thereof from said intermediate pressure to a lower intermediate pressure, to another bed in the system for pres sure equalization therebetween at lower intermediate pressure and for simultaneously discharging gas from the feed end of the bed.
- Control means can be provided for precluding the passage of gas from the bed to which gas had been passed during pressure equalization at lower intermediate pressure upon continuance of the discharge of gas from the feed end of the bed, i.e. the continued BD portion of the E2/BD step, down to said lower desorption pressure upon completion of the pressure equalization at lower intermediate pressure.
- the pressure swing adsorption process herein disclosed and claimed can be advantageously employed to selectively adsorb at least one component of a feed gas mixture, thereby separating and purifying a desired product effluent gas. While the invention is particularly advantageous for separating and recovering oxygen as the less readily adsorbable component of air from nitrogen as the more readily adsorbable component thereof, it will be appreciated by those skilled in the art that various other separations, including the recovery of hydrogen from feed gas mixtures or even the separation and recovery of nitrogen as the product effluent from feed air is feasible depending upon the performance characteristics of the particular adsorbent employed in the PSA system and its ability to selectively adsorb one component from a feed gas mixture in preference to another, less readily adsorbable component.
- Suitable adsorbent materials may include zeolitic molecular sieves, activated carbon, silica gel, activated alumina and the like. Zeolitic molecular sieve adsorbents are generally desirable for said oxygen separation and recovery from air, with said 13 X adsorbent or 5A molecular sieve being standard materials that can readily be employed in the commercial practice of the prior art approaches improved as herein disclosed and claimed.
- the invention enables the overall cycle time to be desirably minimized, with cycle times of from about 140 to about 180 seconds being feasible in various embodiments, particularly in 4-bed systems, while somewhat longer times may be required in embodiments wherein a 5-bed system is employed with two beds in adsorption at any given time and in which an increase in recovery is obtainable as compared with a 4-bed system.
- oxygen product recovery in air separation applications of the invention are readily obtainable within the range of from about 50 % to about 60 %, typically from about 53 % to about 55 %.
- the invention will thus be seen to satisfy the desire in the art for improvements in the PSA technology as applied to various gas separation operations, such as the separation and recovery of oxygen from air.
- the simultaneous cycle step of the invention thus enables increased adsorbent productivity to be achieved, providing increased bed capacity, while product recovery improvements averaging about 5 to 6 % can be obtained as compared with the commercial 3-bed PSA process.
- the processing cycles of the invention advantageously employ provide purge steps shorter in time than the time provided for the actual purge of the bed, with the overall cycle times being minimized without degradation of product effluent purity.
- the invention thus enhances the feasibility of applying PSA technology in practical, commercial gas separation operations in a more efficient, effective manner than was heretofore possible utilizing the PSA technology as developed heretofore in the art.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Of Gases By Adsorption (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Gas Separation By Absorption (AREA)
- Treating Waste Gases (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Disintegrating Or Milling (AREA)
- Processing Of Solid Wastes (AREA)
- Compressors, Vaccum Pumps And Other Relevant Systems (AREA)
- Fats And Perfumes (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT89121323T ATE105729T1 (de) | 1984-10-05 | 1986-03-19 | Druckwechsel-adsorptionsverfahren. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/658,306 US4589888A (en) | 1984-10-05 | 1984-10-05 | Pressure swing adsorption process |
EP86902180A EP0261111B1 (de) | 1984-10-05 | 1986-03-19 | Druckwechseladsorptionsverfahren und vorrichtung |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP86902180.8 Division | 1987-09-29 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0361541A2 true EP0361541A2 (de) | 1990-04-04 |
EP0361541A3 EP0361541A3 (en) | 1990-08-22 |
EP0361541B1 EP0361541B1 (de) | 1994-05-18 |
Family
ID=24640705
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89121323A Expired - Lifetime EP0361541B1 (de) | 1984-10-05 | 1986-03-19 | Druckwechsel-Adsorptionsverfahren |
EP86902180A Expired - Lifetime EP0261111B1 (de) | 1984-10-05 | 1986-03-19 | Druckwechseladsorptionsverfahren und vorrichtung |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP86902180A Expired - Lifetime EP0261111B1 (de) | 1984-10-05 | 1986-03-19 | Druckwechseladsorptionsverfahren und vorrichtung |
Country Status (12)
Country | Link |
---|---|
US (1) | US4589888A (de) |
EP (2) | EP0361541B1 (de) |
JP (1) | JPS63502809A (de) |
KR (1) | KR920002080B1 (de) |
AT (1) | ATE57623T1 (de) |
AU (1) | AU592558B2 (de) |
BR (1) | BR8607117A (de) |
DE (1) | DE3675218D1 (de) |
IN (1) | IN170501B (de) |
NO (1) | NO874811L (de) |
WO (1) | WO1987005529A1 (de) |
ZA (1) | ZA862098B (de) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0545559A2 (de) * | 1991-11-06 | 1993-06-09 | The Boc Group, Inc. | Trennung von Gasmischungen |
EP0590562A1 (de) * | 1992-10-01 | 1994-04-06 | Air Products And Chemicals, Inc. | Rückverdichtung von Entspannungsabgasen |
EP0750934A2 (de) * | 1995-06-30 | 1997-01-02 | Air Products And Chemicals, Inc. | Vakuum-Wechsel-Adsorptionsverfahren |
Families Citing this family (57)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4589888A (en) * | 1984-10-05 | 1986-05-20 | Union Carbide Corporation | Pressure swing adsorption process |
FR2599274B1 (fr) * | 1986-06-02 | 1988-08-26 | Air Liquide | Procede et installation de separation d'un melange gazeux par adsorption. |
AT385051B (de) * | 1986-08-07 | 1988-02-10 | Voest Alpine Ag | Huettenwerk und verfahren zur erzeugung von stahl |
US4723966A (en) * | 1986-12-11 | 1988-02-09 | Union Carbide Corporation | Gas separation by pressure swing adsorption |
CA1325182C (en) | 1987-12-29 | 1993-12-14 | Union Carbide Corporation | Pressure swing adsorption process |
US4810265A (en) * | 1987-12-29 | 1989-03-07 | Union Carbide Corporation | Pressure swing adsorption process for gas separation |
US5013337A (en) * | 1988-12-06 | 1991-05-07 | Uop | Process for separating a mixture of molecular species using crystalline microporous metal sulfide compositions |
US5004482A (en) * | 1989-05-12 | 1991-04-02 | Union Carbide Corporation | Production of dry, high purity nitrogen |
US4934148A (en) * | 1989-05-12 | 1990-06-19 | Union Carbide Corporation | Dry, high purity nitrogen production process and system |
US4931070A (en) * | 1989-05-12 | 1990-06-05 | Union Carbide Corporation | Process and system for the production of dry, high purity nitrogen |
DD288533A5 (de) * | 1989-10-25 | 1991-04-04 | Veb Komplette Chemieanlagen Dresden,De | Verfahren zum trennen von gasgemischen durch druckwechseladsorption |
US5126120A (en) * | 1990-10-02 | 1992-06-30 | Uop | Crystalline microporous zinc phosphate compositions |
US5085674A (en) * | 1990-10-25 | 1992-02-04 | Union Carbide Industrial Gases Technology Corporation | Duplex adsorption process |
US5203888A (en) * | 1990-11-23 | 1993-04-20 | Uop | Pressure swing adsorption process with multiple desorption steps |
US5122357A (en) * | 1991-03-18 | 1992-06-16 | Uop | Crystalline microporous metal oxysulfide compositions |
US5128025A (en) * | 1991-03-18 | 1992-07-07 | Uop | Hydrocarbon conversion processes using a novel crystalline microporous metal oxysulfide composition |
US5132020A (en) * | 1991-10-15 | 1992-07-21 | Mobil Oil Corp. | Sorption of alcohols using zeolite beta |
US5449450A (en) * | 1992-04-10 | 1995-09-12 | Uop | Hydrocarbon conversion process using a crystalline microporous metallo-zinc phosphate composition |
US5302362A (en) * | 1992-04-10 | 1994-04-12 | Uop | Crystalline microporous metallo-zinc phosphate compositions |
AU5135593A (en) * | 1992-09-22 | 1994-04-12 | Arbor Research Corporation | System for separation of oxygen from argon/oxygen mixture |
US5328503A (en) * | 1992-11-16 | 1994-07-12 | Air Products And Chemicals, Inc. | Adsorption process with mixed repressurization and purge/equalization |
US5429664A (en) * | 1993-02-22 | 1995-07-04 | Air Products And Chemicals, Inc. | Pressure swing absorption with recycle of void space gas |
US5294247A (en) * | 1993-02-26 | 1994-03-15 | Air Products And Chemicals, Inc. | Adsorption process to recover hydrogen from low pressure feeds |
US5411578A (en) * | 1994-05-10 | 1995-05-02 | Air Products And Chemicals, Inc. | Vacuum swing adsorption process with mixed repressurization and provide product depressurization |
JP3309197B2 (ja) * | 1995-03-02 | 2002-07-29 | 住友精化株式会社 | 濃縮酸素の回収方法 |
US5656067A (en) * | 1996-02-23 | 1997-08-12 | Air Products And Chemicals, Inc. | VSA adsorption process with energy recovery |
FR2746668B1 (fr) * | 1996-03-27 | 1998-04-30 | Air Liquide | Procede de traitement d'un melange de gaz par adsorption a variation de pression |
FR2756752B1 (fr) * | 1996-12-05 | 2001-09-14 | Air Liquide | Procede et installation de traitement d'un melange gazeux par adsorption a variation de pression |
US5735938A (en) * | 1997-01-15 | 1998-04-07 | Praxair Technology, Inc. | Method for production of nitrogen using oxygen selective adsorbents |
US5938819A (en) * | 1997-06-25 | 1999-08-17 | Gas Separation Technology Llc | Bulk separation of carbon dioxide from methane using natural clinoptilolite |
GB9723033D0 (en) * | 1997-11-01 | 1998-01-07 | Domnick Hunter Ltd | Selective absorption of components of a gas mixture |
US6197092B1 (en) | 1999-03-22 | 2001-03-06 | Engelhard Corporation | Selective removal of nitrogen from natural gas by pressure swing adsorption |
US6210466B1 (en) * | 1999-08-10 | 2001-04-03 | Uop Llc | Very large-scale pressure swing adsorption processes |
US6558451B2 (en) * | 2000-05-10 | 2003-05-06 | Airsep Corporation | Multiple bed pressure swing adsorption method and apparatus |
US6454838B1 (en) * | 2000-06-21 | 2002-09-24 | Air Products And Chemicals, Inc. | Six bed pressure swing adsorption process with four steps of pressure equalization |
ES2254458T3 (es) * | 2000-08-02 | 2006-06-16 | Wearair Oxygen Inc. | Concentrador de oxigeno portatil miniaturizado. |
US6444012B1 (en) | 2000-10-30 | 2002-09-03 | Engelhard Corporation | Selective removal of nitrogen from natural gas by pressure swing adsorption |
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- 1986-03-19 EP EP89121323A patent/EP0361541B1/de not_active Expired - Lifetime
- 1986-03-19 KR KR1019870701076A patent/KR920002080B1/ko not_active IP Right Cessation
- 1986-03-19 BR BR8607117A patent/BR8607117A/pt active Search and Examination
- 1986-03-19 EP EP86902180A patent/EP0261111B1/de not_active Expired - Lifetime
- 1986-03-19 AU AU56217/86A patent/AU592558B2/en not_active Ceased
- 1986-03-19 DE DE8686902180T patent/DE3675218D1/de not_active Expired - Lifetime
- 1986-03-19 JP JP61501738A patent/JPS63502809A/ja active Granted
- 1986-03-19 WO PCT/US1986/000535 patent/WO1987005529A1/en active IP Right Grant
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1987
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EP0545559A2 (de) * | 1991-11-06 | 1993-06-09 | The Boc Group, Inc. | Trennung von Gasmischungen |
EP0545559A3 (en) * | 1991-11-06 | 1993-09-01 | The Boc Group, Inc. | Separation of gas mixtures |
EP0590562A1 (de) * | 1992-10-01 | 1994-04-06 | Air Products And Chemicals, Inc. | Rückverdichtung von Entspannungsabgasen |
EP0750934A2 (de) * | 1995-06-30 | 1997-01-02 | Air Products And Chemicals, Inc. | Vakuum-Wechsel-Adsorptionsverfahren |
EP0750934A3 (de) * | 1995-06-30 | 1997-03-05 | Air Prod & Chem | Vakuum-Wechsel-Adsorptionsverfahren |
Also Published As
Publication number | Publication date |
---|---|
AU5621786A (en) | 1987-10-09 |
ZA862098B (en) | 1986-11-26 |
EP0361541A3 (en) | 1990-08-22 |
IN170501B (de) | 1992-04-04 |
AU592558B2 (en) | 1990-01-18 |
NO874811L (no) | 1988-01-18 |
EP0261111A1 (de) | 1988-03-30 |
WO1987005529A1 (en) | 1987-09-24 |
US4589888A (en) | 1986-05-20 |
JPS63502809A (ja) | 1988-10-20 |
JPH0350570B2 (de) | 1991-08-02 |
NO874811D0 (no) | 1987-11-18 |
DE3675218D1 (de) | 1990-11-29 |
EP0361541B1 (de) | 1994-05-18 |
EP0261111B1 (de) | 1990-10-24 |
ATE57623T1 (de) | 1990-11-15 |
BR8607117A (pt) | 1988-02-09 |
KR920002080B1 (ko) | 1992-03-10 |
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