EP0287142A2 - A boiler element - Google Patents

A boiler element Download PDF

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Publication number
EP0287142A2
EP0287142A2 EP88200501A EP88200501A EP0287142A2 EP 0287142 A2 EP0287142 A2 EP 0287142A2 EP 88200501 A EP88200501 A EP 88200501A EP 88200501 A EP88200501 A EP 88200501A EP 0287142 A2 EP0287142 A2 EP 0287142A2
Authority
EP
European Patent Office
Prior art keywords
boiler
heat exchange
exchange element
water
temperature area
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP88200501A
Other languages
German (de)
French (fr)
Other versions
EP0287142B1 (en
EP0287142A3 (en
Inventor
Jan Hubertus Anna Deckers
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Robert Bosch GmbH
Original Assignee
Radson BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Radson BV filed Critical Radson BV
Priority to AT88200501T priority Critical patent/ATE64990T1/en
Publication of EP0287142A2 publication Critical patent/EP0287142A2/en
Publication of EP0287142A3 publication Critical patent/EP0287142A3/en
Application granted granted Critical
Publication of EP0287142B1 publication Critical patent/EP0287142B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H1/00Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters
    • F24H1/22Water heaters other than continuous-flow or water-storage heaters, e.g. water heaters for central heating
    • F24H1/38Water heaters other than continuous-flow or water-storage heaters, e.g. water heaters for central heating with water contained in separate elements, e.g. radiator-type element

Definitions

  • This invention relates to a light-metal, one-piece heat exchange element, in particular for a central heating boiler, comprising a substantially flat, box-shaped body through which a water passage extends along a curved path between an inlet and an outlet, said water passage having a varying sectional area, the flat side walls of the body being provided with protrusions extending into flue gas passages on either side of said body, said flue gas passages having a decreasing sectional area in the direction of flow of the gas.
  • the water passage has a serpentine or zigzag form, with a sectional area decreasing uniformly over the total length of the water passage from the inlet in the low gas temperature area to the outlet in the high gas temperature area so strongly (e.g. in the ratio of 2:1) that the flow velocity at the outlet is higher than at the inlet.
  • the present invention is based on the insight that in the high gas temperature area, the temperature differ­ential with the heated water is amply sufficient to ensure effective and fast heat transfer.
  • the hot gas will give up the major part of its heat to the heat exchange element in the first half of the gas trajectory.
  • the gas in the second half of the gas trajectory is brought in a heat-exchanging relationship with relatively slowly flowing and moreover relatively cold water, it is possible to strongly cool the gas, and even to bring it to condensation level.
  • the protrusions can be designed as studs arranged according to a pattern of laterally offset rows, with the interspace of the studs decreasing gradually from the high towards the low gas temperature area, e.g. in total in the ratio of 2.5:1.
  • EP-A-0021512 discloses, per se, a heat exchanger wherein pins are provided in the flue gas passages in a pattern of laterally offset rows, with the interspace of the studs decreasing gradually from the high to the low temperature area, but not in combination with counter-currently supplied water with the velocity of the discharged hot water being higher than that of the entering cold water.
  • the present invention also concerns a water heating boiler comprising a heat exchange element according to the present invention and a burner, the boiler element according to the present invention being fittingly enclosed on either side by a substantially U-shaped duct for supplying a combustible gas and air mixture to the top of a perforate burner plate disposed in a burner chamber provided above the boiler element, the bottom of said chamber being in open communication with the flue gas passages enclosed by the body of the boiler element and the inner wall of the gas/air duct.
  • Such a central heating boiler if fitted with a boiler element of outside dimensions in the order of 25 ⁇ 15 ⁇ 20 (H ⁇ W ⁇ T), a water passage decreasing stepwise in cross section from about 10 cm2 at the inlet to about 5 cm2 at the outlet, and on either side studs having on an average a cross-sectional area of 1 cm2 and, in the high gas temperature area, a length of 23 mm and an interspace of 7 mm and in the low temper­ ature area a length of 15 mm and an interspace of 5 mm, can provide per kg of aluminium a power output of about 3 KW, which is very high for such a small and light-weight boiler.
  • a heat-resistant burner i.e. one having a perforate plate made e.g. from ceramic material, to the rear of which the gas and air mixture is supplied under pressure, and which, at the front, functions as a burner bed. This allows to obtain a flue gas temperature exceeding 1,200°C.
  • the boiler element cast in one piece from light metal, such a aluminium alloy, has a flat, box-shaped body 1 with a water inlet nipple 2 and a water discharge nipple 3 in one of the end walls.
  • closable studs 4 which serve for removing the casting core.
  • a water passage 5 extends in serpentine fashion, whose sectional area decreases stepwise down to a ratio of 2:1, see Figs. 1 and 3.
  • finger-shaped protrusions 6 Extending from the side walls 1a, 1b on either side of body 1, are finger-shaped protrusions 6, which in the embodiment shown, have the form of four-sided studs, which taper slightly for ease of release from the mould. Studs 6 are arranged in a pattern of laterally offset horizontal rows (see Fig. 2), which are placed more closely together at the bottom than at the top. As shown in Fig. 1, studs 6 are also shorter at the bottom of the body 1 than at the top.
  • a chamber 10 containing a perforate burner plate B.
  • Fig. 4 shows a gas supply device 11 and a blower 12 for the forced supply of a combustible gas and air mixture through the U-shaped duct 8 to the top of burner chamber 10.
  • flue gases are generated in burner chamber 10 which have a very high temperature of about 1,200°C, and which are forcibly moved downwardly through the flue gas passages 9 and are discharged through the bottom of the boiler element, cooled at 70-80°C or lower.
  • burner chamber 10 which have a very high temperature of about 1,200°C, and which are forcibly moved downwardly through the flue gas passages 9 and are discharged through the bottom of the boiler element, cooled at 70-80°C or lower.
  • body 1 Through their passage in the labyrinthine trajectory between studs 6, they give up heat, directly to body 1 and indirectly through studs 6 with which they are brought into close contact due to vortexes produced thereby.
  • body 1 Through body 1 the heat absorbed is transferred to the water flowing in passage 5.
  • the heat transfer or thermal conduction per unit of surface area is determined by the temperature differential and the time.
  • the cold water in the lower, low-temperature area of the boiler element flows much more slowly than in the upper, high gas temperature area. It is true that in the lower, low gas temperature area, the heated surface area has been reduced on the gas side by narrowing the flue gas passages 9, but because the studs are more closely spaced, the flue gas, whose volume has been reduced due to drop in temperature, intensely swirled in the narrow passages between studs 6 and hence forced into close contact with the stud sides and with the portions of the body walls 1a, 1b intermediate studs 6, so that the flue gases have an opportunity of optimally giving off their heat.
  • baffles 13-17 form a serpentine or zigzag trajectory 5 in the hollow inner space of body 1, which trajectory becomes narrower at each bend and, in the embodiment shown, is halved in five steps so that, with a constant flow rate, the output velocity at 3 is about double the input velocity at 2.
  • the water is heated during its passage through body 1 and thereby expands, the velocity at outlet 3 will be more than double the velocity at inlet 2.
  • An essential feature of the present invention is that in the portion of the heat exchanger where relatively cool flue gases have to give off their (residual) heat to cold inflowing water, the water passes at a relatively low velocity and the flue gases are forced to make frequent and intensively contacts, with the heated surface, while in the high gas temperature area, a large contact surface area is offered to the inflowing gases of very high temperature.
  • the large temperature differential in the order of 1,100°C) enables a fast heat transfer to the water, so that this can be discharged relatively quickly.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Air Supply (AREA)
  • Steam Or Hot-Water Central Heating Systems (AREA)

Abstract

A counter-current heat exchange element, in particular for a central heating boiler, comprising a substantially flat box-shaped body (1) containing a water passage (5), the flat side walls (1a, 1b) of said body (1) being provided with protrusions (6) extending into flue passages (9) on both sides of said body (1) and being arranged according to a pattern of laterally offset rows with the lateral spacing of said protrusions (6) gradually decreasing from the high temperature area towards the low temperature area in each flue passage (9), the water passage (5) extending along a serpentine trajectory between a cool water inlet (2) in the low flue gas temperature area and a heated water outlet (3) in the high flue gas temperature area, the water passage (5) narrowing from the inlet (2) towards the outlet (3) in such a manner that the water flow velocity at the outlet (3) is higher than at the inlet (2).

Description

  • This invention relates to a light-metal, one-piece heat exchange element, in particular for a central heating boiler, comprising a substantially flat, box-shaped body through which a water passage extends along a curved path between an inlet and an outlet, said water passage having a varying sectional area, the flat side walls of the body being provided with protrusions extending into flue gas passages on either side of said body, said flue gas passages having a decreasing sectional area in the direction of flow of the gas.
  • In a water heater of this kind, which is disclosed in NL-A-7604830, corresponding with FR-A-2 310 537, flue gases flow from a burner arranged underneath the boiler element along the body upwards between the protru­sions, which are designed as vertical longitudinal ribs. The water to be heated is introduced at the bottom of the boiler element and flows concurrently with the flue gases upwards into a curved water passage whose sectional area is larger at the water outlet than at the inlet. For the purpose of keeping the flow velocities of gas and water constant, in the known boiler element, the contraction of the flue gases due to cooling and the expansion of the water due to heating are compensated for by varying the respective sectional areas of passage. In view of the slight expansion of water over the temper­ ature range which in the practice of a central heating boiler is between about 20° and about 85°C, this means a hardly perceptible increase in sectional area necessary for keeping the velocity of the flow of water constant. The temperature of the flue gases, which in conventional atmospheric burners decreases from e.g. 800° to 150°C, requires a larger reduction of the sectional area for a constant gas velocity.
  • It is an object of the present invention to provide a heat exchange element of the above kind, designed for a central heating boiler, in which an optimum capacity is obtained using a minimum of light metal.
  • To that effect, according to the present invention, while the heat exchange element is designed as a counter current exchange element the water passage has a serpentine or zigzag form, with a sectional area decreasing uniformly over the total length of the water passage from the inlet in the low gas temperature area to the outlet in the high gas temperature area so strongly (e.g. in the ratio of 2:1) that the flow velocity at the outlet is higher than at the inlet.
  • The present invention is based on the insight that in the high gas temperature area, the temperature differ­ential with the heated water is amply sufficient to ensure effective and fast heat transfer. The hot gas will give up the major part of its heat to the heat exchange element in the first half of the gas trajectory. As the gas in the second half of the gas trajectory is brought in a heat-exchanging relationship with relatively slowly flowing and moreover relatively cold water, it is possible to strongly cool the gas, and even to bring it to condensation level.
  • For obtaining optimum heat transfer over the entire length of the flue gas passages, into which protrusions of decreasing height project to increase the heated surface area, according to the present invention, the protrusions can be designed as studs arranged according to a pattern of laterally offset rows, with the interspace of the studs decreasing gradually from the high towards the low gas temperature area, e.g. in total in the ratio of 2.5:1.
  • In the high gas temperature area, heat transfer per unit of time is high, because the temperature differ­ential relative to the water flowing in the adjoining part of the water passage is large and in the low gas temperature area, true, the heated surface area is smaller than in the high gas temperature area but, due to the closer spacing of the studs, an inventive contact with the low temperature flue gas is ensured and the adverse effect of the lower temperature differential on the heat transfer between the flue gas and water is compensated for at least in parts.
  • It is observed that EP-A-0021512 discloses, per se, a heat exchanger wherein pins are provided in the flue gas passages in a pattern of laterally offset rows, with the interspace of the studs decreasing gradually from the high to the low temperature area, but not in combination with counter-currently supplied water with the velocity of the discharged hot water being higher than that of the entering cold water.
  • The present invention also concerns a water heating boiler comprising a heat exchange element according to the present invention and a burner, the boiler element according to the present invention being fittingly enclosed on either side by a substantially U-shaped duct for supplying a combustible gas and air mixture to the top of a perforate burner plate disposed in a burner chamber provided above the boiler element, the bottom of said chamber being in open communication with the flue gas passages enclosed by the body of the boiler element and the inner wall of the gas/air duct.
  • Such a central heating boiler, if fitted with a boiler element of outside dimensions in the order of 25 × 15 × 20 (H × W × T), a water passage decreasing stepwise in cross section from about 10 cm² at the inlet to about 5 cm² at the outlet, and on either side studs having on an average a cross-sectional area of 1 cm² and, in the high gas temperature area, a length of 23 mm and an interspace of 7 mm and in the low temper­ ature area a length of 15 mm and an interspace of 5 mm, can provide per kg of aluminium a power output of about 3 KW, which is very high for such a small and light-weight boiler. Preferably, use is made of a heat-resistant burner, i.e. one having a perforate plate made e.g. from ceramic material, to the rear of which the gas and air mixture is supplied under pressure, and which, at the front, functions as a burner bed. This allows to obtain a flue gas temperature exceeding 1,200°C.
  • One embodiment of the boiler element according to the present invention will now be described, by way of example, with reference to the accompanying drawings, in which:
    • Fig. 1 is a vertical part-sectional elevation of a boiler fitted with the boiler element according to the present invention;
    • Fig. 2 is a side-elevational view of the boiler according to the arrow II-II of Fig. 1;
    • Fig. 3 is a longitudinal sectional view taken on the line III-III of Fig. 1; and
    • Fig. 4 is an end elevational view of the boiler according to the arrows IV-IV of Fig. 3.
  • As shown in the drawings, the boiler element, cast in one piece from light metal, such a aluminium alloy, has a flat, box-shaped body 1 with a water inlet nipple 2 and a water discharge nipple 3 in one of the end walls. Formed in the opposite end wall are closable studs 4, which serve for removing the casting core.
  • Between water inlet 2 and outlet 3, a water passage 5 extends in serpentine fashion, whose sectional area decreases stepwise down to a ratio of 2:1, see Figs. 1 and 3.
  • Extending from the side walls 1a, 1b on either side of body 1, are finger-shaped protrusions 6, which in the embodiment shown, have the form of four-sided studs, which taper slightly for ease of release from the mould. Studs 6 are arranged in a pattern of laterally offset horizontal rows (see Fig. 2), which are placed more closely together at the bottom than at the top. As shown in Fig. 1, studs 6 are also shorter at the bottom of the body 1 than at the top.
  • Against the tops of the lugs 6 lies the inner wall 7 of a substantially U-shaped gas/air duct 8. With the side walls 1a, 1b of body 1 wall 7 encloses flue gas passages 9.
  • Above body 1, there is provided a chamber 10, containing a perforate burner plate B. Fig. 4 shows a gas supply device 11 and a blower 12 for the forced supply of a combustible gas and air mixture through the U-shaped duct 8 to the top of burner chamber 10.
  • In operation, flue gases are generated in burner chamber 10 which have a very high temperature of about 1,200°C, and which are forcibly moved downwardly through the flue gas passages 9 and are discharged through the bottom of the boiler element, cooled at 70-80°C or lower. During their passage in the labyrinthine trajectory between studs 6, they give up heat, directly to body 1 and indirectly through studs 6 with which they are brought into close contact due to vortexes produced thereby. Through body 1 the heat absorbed is transferred to the water flowing in passage 5. The heat transfer or thermal conduction per unit of surface area is determined by the temperature differential and the time.
  • As a result of the construction of the boiler element, the cold water in the lower, low-temperature area of the boiler element, flows much more slowly than in the upper, high gas temperature area. It is true that in the lower, low gas temperature area, the heated surface area has been reduced on the gas side by narrowing the flue gas passages 9, but because the studs are more closely spaced, the flue gas, whose volume has been reduced due to drop in temperature, intensely swirled in the narrow passages between studs 6 and hence forced into close contact with the stud sides and with the portions of the body walls 1a, 1b intermediate studs 6, so that the flue gases have an opportunity of optimally giving off their heat.
  • The design of the water passage 5 is highly important for the efficiency of the boiler element. Baffles 13-17 form a serpentine or zigzag trajectory 5 in the hollow inner space of body 1, which trajectory becomes narrower at each bend and, in the embodiment shown, is halved in five steps so that, with a constant flow rate, the output velocity at 3 is about double the input velocity at 2. As, in addition, the water is heated during its passage through body 1 and thereby expands, the velocity at outlet 3 will be more than double the velocity at inlet 2.
  • An essential feature of the present invention is that in the portion of the heat exchanger where relatively cool flue gases have to give off their (residual) heat to cold inflowing water, the water passes at a relatively low velocity and the flue gases are forced to make frequent and intensively contacts, with the heated surface, while in the high gas temperature area, a large contact surface area is offered to the inflowing gases of very high temperature. The large temperature differential (in the order of 1,100°C) enables a fast heat transfer to the water, so that this can be discharged relatively quickly.

Claims (7)

1. A light-metal, one-piece heat exchange element, in particular for a central heating boiler, comprising a substantially flat, box-shaped body (1) through which a water passage (5) extends in a curved path between an inlet (2) and an outlet (3), said water passage having a varying sectional area, with the flat side walls (1a, 1b) of body (1) being provided with protrusions (6) extending into flue gas passages (9), disposed on either side of body (1), said flue gas passages having a decreasing sectional area in the direction of flow of the gas, characterized in that, while the heat exchange element is constructed as a counter-current exchange element, the water passage (5) has a serpentine or zigzag form with a sectional area decreasing from the inlet (2) in the low gas temperature area to the outlet (3) in the high gas temperature area so strongly that the flow velocity at outlet (3) is higher than at inlet (2).
2. A heat exchange element as claimed in claim 1, characterized in that the sectional area at the inlet (2) is about twice as large as at the outlet (3).
3. A heat exchange element as claimed in claim 1 or 2, characterized in that, for forming the serpentine or zigzag water trajectory, the boiler element (1) comprises baffles (13-17) whose interspace and length are such that the sectional area is reduced upon each reversal of the flow direction.
4. A heat exchange element having protrusions (6) of a height decreasing in gas flow direction throughout the entire length of the flue gas passages (9), said protrusions projecting into said passages to increase the heated surface area thereof, characterized in that the protrusions are formed as studs (6), arranged in a pattern of laterally offset rows, with the interspace of the studs (6) decreasing gradually from the high to the low gas temperature area.
5. A heat exchange element as claimed in claim 4, characterized in that the interspace of studs (6) in the high gas temperature area is 2.5 times as large as in the low gas temperature area.
6. A water heating boiler having a heat exchange element as claimed in any of the preceding claims, characterized in that the boiler element is fittingly enclosed on either side by a substantially U-shaped duct (8) for supplying a combustible gas and air mixture to the top of a perforate burner plate (B) disposed in a burner chamber (10) provided above the boiler element, the bottom of said chamber (10) being in open communication with the flue gas passages (9) enclosed by the body of the boiler element and the inner wall (7) of the gas and air duct (8).
7. A boiler as claimed in claim 6, characterized in that the burner plate (B) is made of ceramic material.
EP88200501A 1987-03-18 1988-03-18 A boiler element Expired - Lifetime EP0287142B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT88200501T ATE64990T1 (en) 1987-03-18 1988-03-18 BOILER ELEMENT.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL8700641A NL8700641A (en) 1987-03-18 1987-03-18 BOILER ELEMENT.
NL8700641 1987-03-18

Publications (3)

Publication Number Publication Date
EP0287142A2 true EP0287142A2 (en) 1988-10-19
EP0287142A3 EP0287142A3 (en) 1988-12-07
EP0287142B1 EP0287142B1 (en) 1991-07-03

Family

ID=19849727

Family Applications (1)

Application Number Title Priority Date Filing Date
EP88200501A Expired - Lifetime EP0287142B1 (en) 1987-03-18 1988-03-18 A boiler element

Country Status (4)

Country Link
EP (1) EP0287142B1 (en)
AT (1) ATE64990T1 (en)
DE (1) DE3863461D1 (en)
NL (1) NL8700641A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU618840B2 (en) * 1988-09-14 1992-01-09 Showa Denko Kabushiki Kaisha A condenser
EP0608030A1 (en) * 1993-01-19 1994-07-27 N.V. Radson-Alutherm Three-way combi-boiler
EP1669689A2 (en) * 2004-12-08 2006-06-14 Robert Bosch Gmbh Heat exchanger
DE102007060508A1 (en) 2007-12-15 2009-06-18 Robert Bosch Gmbh Heat exchanger for a heater
WO2019008005A1 (en) * 2017-07-07 2019-01-10 Bekaert Combustion Technology B.V. Cast element for a heat exchanger

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10306699A1 (en) 2003-02-18 2004-09-02 Robert Bosch Gmbh Heat exchanger with a flow-optimized heat-absorbing flow channel, in particular for a heater
DE102007057062A1 (en) 2007-11-27 2009-05-28 Robert Bosch Gmbh Heat exchanger, in particular for a heater

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1425473A (en) * 1972-01-27 1976-02-18 Applegate G Sectional heat exchangers
NL7604830A (en) * 1975-05-09 1976-11-11 Finterm S P A HEAT EXCHANGER.
US4201263A (en) * 1978-09-19 1980-05-06 Anderson James H Refrigerant evaporator
EP0021512A1 (en) * 1979-06-20 1981-01-07 Rheem Nederland B.V. Heat exchanger for use in a central heating boiler or the like and heating apparatus comprising such a heat exchanger
FR2507293A1 (en) * 1981-06-03 1982-12-10 Dru Bv HIGH YIELD BOILER WITHOUT BLOWER

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1425473A (en) * 1972-01-27 1976-02-18 Applegate G Sectional heat exchangers
NL7604830A (en) * 1975-05-09 1976-11-11 Finterm S P A HEAT EXCHANGER.
US4201263A (en) * 1978-09-19 1980-05-06 Anderson James H Refrigerant evaporator
EP0021512A1 (en) * 1979-06-20 1981-01-07 Rheem Nederland B.V. Heat exchanger for use in a central heating boiler or the like and heating apparatus comprising such a heat exchanger
FR2507293A1 (en) * 1981-06-03 1982-12-10 Dru Bv HIGH YIELD BOILER WITHOUT BLOWER

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU618840B2 (en) * 1988-09-14 1992-01-09 Showa Denko Kabushiki Kaisha A condenser
EP0608030A1 (en) * 1993-01-19 1994-07-27 N.V. Radson-Alutherm Three-way combi-boiler
EP1669689A2 (en) * 2004-12-08 2006-06-14 Robert Bosch Gmbh Heat exchanger
EP1669689A3 (en) * 2004-12-08 2010-11-17 Robert Bosch Gmbh Heat exchanger
DE102007060508A1 (en) 2007-12-15 2009-06-18 Robert Bosch Gmbh Heat exchanger for a heater
WO2019008005A1 (en) * 2017-07-07 2019-01-10 Bekaert Combustion Technology B.V. Cast element for a heat exchanger

Also Published As

Publication number Publication date
DE3863461D1 (en) 1991-08-08
ATE64990T1 (en) 1991-07-15
EP0287142B1 (en) 1991-07-03
NL8700641A (en) 1988-10-17
EP0287142A3 (en) 1988-12-07

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