EP0255978A2 - Composition de nettoyage acide liquide - Google Patents
Composition de nettoyage acide liquide Download PDFInfo
- Publication number
- EP0255978A2 EP0255978A2 EP87201455A EP87201455A EP0255978A2 EP 0255978 A2 EP0255978 A2 EP 0255978A2 EP 87201455 A EP87201455 A EP 87201455A EP 87201455 A EP87201455 A EP 87201455A EP 0255978 A2 EP0255978 A2 EP 0255978A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- detergent
- active compound
- acid
- composition
- cationic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/40—Monoamines or polyamines; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
Definitions
- Acidic liquid toilet bowl cleaning compositions are well known in the art. They usually consist of an aqueous solution of a strong acid, to which various desirable additives have been added, such as detergent-active compounds, germicides, perfumes, corrosion inhibitors, colouring agents and so on. As detergent-active compounds anionic, nonionic and cationic detergents have been suggested for inclusion in such acidic liquid toilet bowl cleaning compositions. When desired, a pleasing colour is imparted to such compositions by adding a suitable dye, such as a blue dye. Such compositions are particularly effective in removing toilet scale deposits, derived from the water supply to the toilet.
- compositions contain the cationic detergent-active compound in an amount of 0.1-10% by weight. Mixtures of several cationic detergents, as well as of a cationic and a nonionic detergent may also be used.
- the dyestuffs suitable for use according to the present invention are those which undergo a pH-dependent colour change in the acid pH range, i.e. for the present invention in the range of 2-6 in aqueous solution.
- Typical examples of such dyestuffs are the triarylmethane types such as Acid Blue 1 (CI 42045), Acid Blue 9 (CI 42090), Acid Violet 17 (CI 42650) and Mordant Blue 1 (CI 43830).
- the compositions contain from 0.0001-1% by weight of the dyestuff.
- other dyestuffs which do not undergo a pH-dependent colour change may additionally be included so as to achieve a change to a desired colour.
- inorganic acids such as hydrochloric acid, sulphuric acid, nitric acid and sulphamic acid are suitable; the compositions contain the acid in an amount of 0.5-25% by weight.
- the pH of the compositions of the present invention is below 2, and in most useful cases below 1.
- compositions of the invention can be thickened by surfactants, by polymeric materials such as xanthan gums, polyacrylates and by inorganic thickeners such as silicas and clays.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB868619391A GB8619391D0 (en) | 1986-08-08 | 1986-08-08 | Acidic liquid cleaning composition |
GB8619391 | 1986-08-08 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0255978A2 true EP0255978A2 (fr) | 1988-02-17 |
EP0255978A3 EP0255978A3 (fr) | 1989-03-08 |
Family
ID=10602444
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP87201455A Ceased EP0255978A3 (fr) | 1986-08-08 | 1987-07-30 | Composition de nettoyage acide liquide |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0255978A3 (fr) |
JP (1) | JPS6343999A (fr) |
AU (1) | AU607708B2 (fr) |
BR (1) | BR8703992A (fr) |
CA (1) | CA1329751C (fr) |
GB (1) | GB8619391D0 (fr) |
ZA (1) | ZA875848B (fr) |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2717108A1 (fr) * | 1994-03-14 | 1995-09-15 | Sgb | Procédé de nettoyage, gamme de produits d'entretien et produits utilisés dans le procédé. |
EP0754749A1 (fr) * | 1995-07-20 | 1997-01-22 | The Procter & Gamble Company | Adoucissants textiles contenant des colorants solubles dans l'eau à décoloration réduite |
US5691291A (en) * | 1994-10-28 | 1997-11-25 | The Procter & Gamble Company | Hard surface cleaning compositions comprising protonated amines and amine oxide surfactants |
US5965514A (en) * | 1996-12-04 | 1999-10-12 | The Procter & Gamble Company | Compositions for and methods of cleaning and disinfecting hard surfaces |
US5990064A (en) * | 1994-10-28 | 1999-11-23 | The Procter & Gamble Company | Compositions and methods for cleaning hard surfaces using protonated amines and amine oxide surfactants |
WO2003014282A1 (fr) * | 2001-08-06 | 2003-02-20 | Colgate-Palmolive Company | Composition de nettoyage liquide a changement de couleur |
WO2004078896A1 (fr) * | 2003-03-05 | 2004-09-16 | Unilever Plc | Procede de traitement d'un produit textile au moyen d'une mousse a changement de couleur |
WO2005003276A1 (fr) * | 2003-06-18 | 2005-01-13 | Unilever Plc | Compositions de traitement de blanchissage |
WO2006041739A1 (fr) * | 2004-10-04 | 2006-04-20 | The Procter & Gamble Company | Composition comprenant un colorant complexant les metaux et un tensioactif |
WO2008117235A1 (fr) * | 2007-03-26 | 2008-10-02 | The Procter & Gamble Company | Système de composition liquide possédant un changement d'indication visuelle |
WO2008117233A1 (fr) * | 2007-03-26 | 2008-10-02 | The Procter & Gamble Company | Système de composition détergente liquide avec changement d'indication visuelle |
US7651989B2 (en) | 2003-08-29 | 2010-01-26 | Kimberly-Clark Worldwide, Inc. | Single phase color change agents |
US8067350B2 (en) | 2005-12-15 | 2011-11-29 | Kimberly-Clark Worldwide, Inc. | Color changing cleansing composition |
US20140158166A1 (en) * | 2012-12-10 | 2014-06-12 | Milliken & Company | Cleaning composition and method for using the same |
WO2017200496A1 (fr) | 2016-05-18 | 2017-11-23 | Hayat Kimya Sanayi Anonim Sirketi | Composition de nettoyage à double usage pour l'élimination du tartre |
US9926519B2 (en) | 2012-06-08 | 2018-03-27 | S. C. Johnson & Son, Inc. | Self-adhesive detergent compositions with color-changing systems |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4743395A (en) * | 1986-09-12 | 1988-05-10 | The Drackett Company | Thickened acid cleaner compositions containing quaternary ammonium germicides and having improved thermal stability |
JPH01240600A (ja) * | 1988-03-18 | 1989-09-26 | Seiwa Kogyo Kk | トイレ用洗浄剤 |
GB9000028D0 (en) * | 1990-01-02 | 1990-03-07 | Shell Int Research | Cleaning of equipment used in a liquid phase oxidation process |
JP4884768B2 (ja) * | 2005-12-28 | 2012-02-29 | 花王株式会社 | 硬質表面用洗浄剤 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1313180A (en) * | 1970-09-23 | 1973-04-11 | Unilever Ltd | Surface active liquids |
US4016089A (en) * | 1974-11-11 | 1977-04-05 | Regan Glen B | Denture cleaning concentrate |
US4302253A (en) * | 1980-02-19 | 1981-11-24 | R. T. Vanderbilt Company, Inc. | Thickeners for acid cleaning compositions |
-
1986
- 1986-08-08 GB GB868619391A patent/GB8619391D0/en active Pending
-
1987
- 1987-07-30 EP EP87201455A patent/EP0255978A3/fr not_active Ceased
- 1987-07-30 CA CA000543417A patent/CA1329751C/fr not_active Expired - Fee Related
- 1987-08-04 JP JP62195144A patent/JPS6343999A/ja active Pending
- 1987-08-04 AU AU76549/87A patent/AU607708B2/en not_active Ceased
- 1987-08-06 BR BR8703992A patent/BR8703992A/pt not_active Application Discontinuation
- 1987-08-07 ZA ZA875848A patent/ZA875848B/xx unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1313180A (en) * | 1970-09-23 | 1973-04-11 | Unilever Ltd | Surface active liquids |
US4016089A (en) * | 1974-11-11 | 1977-04-05 | Regan Glen B | Denture cleaning concentrate |
US4302253A (en) * | 1980-02-19 | 1981-11-24 | R. T. Vanderbilt Company, Inc. | Thickeners for acid cleaning compositions |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2717108A1 (fr) * | 1994-03-14 | 1995-09-15 | Sgb | Procédé de nettoyage, gamme de produits d'entretien et produits utilisés dans le procédé. |
US5990064A (en) * | 1994-10-28 | 1999-11-23 | The Procter & Gamble Company | Compositions and methods for cleaning hard surfaces using protonated amines and amine oxide surfactants |
US5691291A (en) * | 1994-10-28 | 1997-11-25 | The Procter & Gamble Company | Hard surface cleaning compositions comprising protonated amines and amine oxide surfactants |
EP0754749A1 (fr) * | 1995-07-20 | 1997-01-22 | The Procter & Gamble Company | Adoucissants textiles contenant des colorants solubles dans l'eau à décoloration réduite |
US5965514A (en) * | 1996-12-04 | 1999-10-12 | The Procter & Gamble Company | Compositions for and methods of cleaning and disinfecting hard surfaces |
WO2003014282A1 (fr) * | 2001-08-06 | 2003-02-20 | Colgate-Palmolive Company | Composition de nettoyage liquide a changement de couleur |
WO2004078896A1 (fr) * | 2003-03-05 | 2004-09-16 | Unilever Plc | Procede de traitement d'un produit textile au moyen d'une mousse a changement de couleur |
WO2005003276A1 (fr) * | 2003-06-18 | 2005-01-13 | Unilever Plc | Compositions de traitement de blanchissage |
US7858568B2 (en) | 2003-08-29 | 2010-12-28 | Kimberly-Clark Worldwide, Inc. | Single phase color change agents |
US7651989B2 (en) | 2003-08-29 | 2010-01-26 | Kimberly-Clark Worldwide, Inc. | Single phase color change agents |
WO2006041739A1 (fr) * | 2004-10-04 | 2006-04-20 | The Procter & Gamble Company | Composition comprenant un colorant complexant les metaux et un tensioactif |
CN101035887B (zh) * | 2004-10-04 | 2011-03-09 | 宝洁公司 | 具有金属配位染料和表面活性剂的组合物 |
US7550422B2 (en) | 2004-10-04 | 2009-06-23 | The Procter & Gamble Company | Composition with a metal-complexing dye and surfactant |
US8067350B2 (en) | 2005-12-15 | 2011-11-29 | Kimberly-Clark Worldwide, Inc. | Color changing cleansing composition |
WO2008117233A1 (fr) * | 2007-03-26 | 2008-10-02 | The Procter & Gamble Company | Système de composition détergente liquide avec changement d'indication visuelle |
WO2008117235A1 (fr) * | 2007-03-26 | 2008-10-02 | The Procter & Gamble Company | Système de composition liquide possédant un changement d'indication visuelle |
US9926519B2 (en) | 2012-06-08 | 2018-03-27 | S. C. Johnson & Son, Inc. | Self-adhesive detergent compositions with color-changing systems |
US20140158166A1 (en) * | 2012-12-10 | 2014-06-12 | Milliken & Company | Cleaning composition and method for using the same |
WO2014092865A3 (fr) * | 2012-12-10 | 2014-09-12 | Milliken & Company | Composition de nettoyage et procédé pour l'utilisation de celle-ci |
US9688946B2 (en) | 2012-12-10 | 2017-06-27 | Milliken & Company | Cleaning composition and method for using the same |
WO2017200496A1 (fr) | 2016-05-18 | 2017-11-23 | Hayat Kimya Sanayi Anonim Sirketi | Composition de nettoyage à double usage pour l'élimination du tartre |
Also Published As
Publication number | Publication date |
---|---|
AU7654987A (en) | 1988-02-11 |
ZA875848B (en) | 1989-04-26 |
GB8619391D0 (en) | 1986-09-17 |
JPS6343999A (ja) | 1988-02-25 |
BR8703992A (pt) | 1988-04-05 |
EP0255978A3 (fr) | 1989-03-08 |
CA1329751C (fr) | 1994-05-24 |
AU607708B2 (en) | 1991-03-14 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
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AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): CH DE ES FR GB IT LI NL SE |
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PUAL | Search report despatched |
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17P | Request for examination filed |
Effective date: 19890220 |
|
17Q | First examination report despatched |
Effective date: 19900430 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN REFUSED |
|
18R | Application refused |
Effective date: 19920606 |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: STIRLING, THOMAS |