EP0251192A3 - Lubricant for metal formation - Google Patents

Lubricant for metal formation Download PDF

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Publication number
EP0251192A3
EP0251192A3 EP87109098A EP87109098A EP0251192A3 EP 0251192 A3 EP0251192 A3 EP 0251192A3 EP 87109098 A EP87109098 A EP 87109098A EP 87109098 A EP87109098 A EP 87109098A EP 0251192 A3 EP0251192 A3 EP 0251192A3
Authority
EP
European Patent Office
Prior art keywords
weight
lubricant
wax
cold
forming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP87109098A
Other languages
German (de)
Other versions
EP0251192A2 (en
EP0251192B1 (en
Inventor
Yoshio Nagae
Takashi Kawakami
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nihon Parkerizing Co Ltd
Original Assignee
Nihon Parkerizing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nihon Parkerizing Co Ltd filed Critical Nihon Parkerizing Co Ltd
Priority to AT87109098T priority Critical patent/ATE75770T1/en
Publication of EP0251192A2 publication Critical patent/EP0251192A2/en
Publication of EP0251192A3 publication Critical patent/EP0251192A3/en
Application granted granted Critical
Publication of EP0251192B1 publication Critical patent/EP0251192B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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    • C10M143/00Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/02Polyethene
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    • C10M143/00Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/10Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aromatic monomer, e.g. styrene
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    • C10M145/00Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/10Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
    • C10M145/12Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
    • C10M145/14Acrylate; Methacrylate
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    • C10M145/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/10Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
    • C10M145/16Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate polycarboxylic
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    • C10M149/00Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
    • C10M149/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M149/06Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
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    • C10M149/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M149/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrile group
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    • C10M153/04Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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    • C10M159/02Natural products
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    • C10M2201/041Carbon; Graphite; Carbon black
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    • C10M2201/042Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
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    • C10M2201/061Carbides; Hydrides; Nitrides
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    • C10M2201/062Oxides; Hydroxides; Carbonates or bicarbonates
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    • C10M2201/065Sulfides; Selenides; Tellurides
    • C10M2201/066Molybdenum sulfide
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    • C10M2201/10Compounds containing silicon
    • C10M2201/105Silica
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    • C10M2201/16Carbon dioxide
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    • C10M2201/18Ammonia
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
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    • C10M2205/022Ethene
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    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08Amides
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08Amides
    • C10M2215/082Amides containing hydroxyl groups; Alkoxylated derivatives
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    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/024Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
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    • C10M2217/02Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/026Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrile group
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    • C10M2217/06Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10M2225/02Macromolecular compounds from phosphorus-containg monomers, obtained by reactions involving only carbon-to-carbon unsaturated bonds
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
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    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01Emulsions, colloids, or micelles
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    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015Dispersions of solid lubricants
    • C10N2050/02Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Lubricants (AREA)
  • Paints Or Removers (AREA)
  • Forging (AREA)

Abstract

The aqueous lubricant for metal cold-forming contains 10 to 35% by weight of a thermosetting acrylate-based resin having a glass transition point of -10 to +25 DEG C, 3 to 15% by weight of wax and 0.5 to 5% by weight of a surfactant, the thermosetting resin/wax weight ratio being adjusted to 2-12. Particularly suitable resins are of the general formula -(Ra-Rb-Rc-Rd)n-, Ra, Rb, Rc and Rd being different monomers and "n" being a degree of polymerisation from 1,000 to 50,000. The wax should have a melting point above 45 DEG C. In the process for faciliting the cold-forming of metallic workpieces, the lubricant is applied to the metal surface, dried on in air to form a coating weight from 0.5 to 30 g/m<2>, heated to a temperature of 80 to 120 DEG C (object temperature) and finally cured.
EP87109098A 1986-06-27 1987-06-24 Lubricant for metal formation Expired - Lifetime EP0251192B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT87109098T ATE75770T1 (en) 1986-06-27 1987-06-24 METAL FORMING LUBRICANT.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP151178/86 1986-06-27
JP61151178A JPS638489A (en) 1986-06-27 1986-06-27 Lubricant for metal cold working

Publications (3)

Publication Number Publication Date
EP0251192A2 EP0251192A2 (en) 1988-01-07
EP0251192A3 true EP0251192A3 (en) 1988-05-04
EP0251192B1 EP0251192B1 (en) 1992-05-06

Family

ID=15513003

Family Applications (1)

Application Number Title Priority Date Filing Date
EP87109098A Expired - Lifetime EP0251192B1 (en) 1986-06-27 1987-06-24 Lubricant for metal formation

Country Status (4)

Country Link
EP (1) EP0251192B1 (en)
JP (1) JPS638489A (en)
AT (1) ATE75770T1 (en)
DE (2) DE3720841A1 (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3916128A1 (en) * 1989-05-18 1990-11-22 Roehm Gmbh AQUEOUS FUNCTIONAL LIQUIDS CONTAINING THICKENING AGENTS ON A POLY (METH) ACRYLATE BASE
WO1992016603A1 (en) * 1991-03-22 1992-10-01 Henkel Corporation Lubrication for cold forming of metals
DE4445993A1 (en) * 1994-12-22 1996-06-27 Metallgesellschaft Ag Lubricant for metal forming
US5547595A (en) * 1995-02-07 1996-08-20 Henkel Corporation Aqueous lubricant and process for cold forming metal, particularly pointing thick-walled metal tubes
US6899770B1 (en) 1999-03-04 2005-05-31 Henkel Corporation Composition and process for treating metal surfaces
US6291407B1 (en) 1999-09-08 2001-09-18 Lafrance Manufacturing Co. Agglomerated die casting lubricant
US6432886B1 (en) 1999-09-08 2002-08-13 Mary R. Reidmeyer Agglomerated lubricant
DE10258291A1 (en) * 2002-12-13 2004-07-08 Henkel Kgaa Process for coating metal substrates with a free-radically polymerizable coating agent and coated substrates
US7696136B2 (en) 2004-03-11 2010-04-13 Crompton Corporation Lubricant compositions containing hydroxy carboxylic acid and hydroxy polycarboxylic acid esters
JP4668826B2 (en) * 2006-03-31 2011-04-13 住友金属工業株式会社 Cold drawing method for metal and method for producing drawn material
JP4597896B2 (en) * 2006-03-31 2010-12-15 住友金属工業株式会社 Cold drawing method and method for producing drawn tube
JP4597897B2 (en) * 2006-03-31 2010-12-15 住友金属工業株式会社 Cold drawing method and drawn material manufacturing method
CN101993770B (en) * 2010-11-18 2013-08-21 江南大学 Lubricating agent for high-speed wire drawing and preparation method thereof
JP2015183150A (en) * 2014-03-26 2015-10-22 貴和化学薬品株式会社 Lubricant for plastic processing
CN110144255A (en) * 2019-04-30 2019-08-20 厦门加美石油集团有限公司 A kind of easy cleaning cold-heading molding oil and preparation method thereof
CN112588846A (en) * 2020-11-23 2021-04-02 江阴法尔胜泓昇不锈钢制品有限公司 Production process of alloy steel wire for cold heading

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2529892A1 (en) * 1974-07-08 1976-01-29 Nippon Paint Co Ltd SURFACE TREATMENT FOR METALWORKING
EP0043182A1 (en) * 1980-06-02 1982-01-06 Uss Engineers And Consultants, Inc. Lubricant composition and metal forming process
DE3223442A1 (en) * 1981-06-24 1983-01-20 Em Lubricants Inc LUBRICANT FOR METAL FORMING AND METHOD FOR ITS APPLICATION
EP0175547A2 (en) * 1984-09-19 1986-03-26 Nihon Kousakuyu Co. Ltd. Cold working lubricants for metallic conduits
FR2571381A1 (en) * 1984-08-31 1986-04-11 Nippon Kokan Kk COLD ROLLING OIL FOR STEEL SHEETS

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5234704B2 (en) * 1972-09-01 1977-09-05

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2529892A1 (en) * 1974-07-08 1976-01-29 Nippon Paint Co Ltd SURFACE TREATMENT FOR METALWORKING
EP0043182A1 (en) * 1980-06-02 1982-01-06 Uss Engineers And Consultants, Inc. Lubricant composition and metal forming process
DE3223442A1 (en) * 1981-06-24 1983-01-20 Em Lubricants Inc LUBRICANT FOR METAL FORMING AND METHOD FOR ITS APPLICATION
FR2571381A1 (en) * 1984-08-31 1986-04-11 Nippon Kokan Kk COLD ROLLING OIL FOR STEEL SHEETS
EP0175547A2 (en) * 1984-09-19 1986-03-26 Nihon Kousakuyu Co. Ltd. Cold working lubricants for metallic conduits

Also Published As

Publication number Publication date
DE3720841A1 (en) 1988-01-14
EP0251192A2 (en) 1988-01-07
DE3778764D1 (en) 1992-06-11
ATE75770T1 (en) 1992-05-15
EP0251192B1 (en) 1992-05-06
JPH0437878B2 (en) 1992-06-22
JPS638489A (en) 1988-01-14

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