EP0194018A1 - Forming components made of hard metal - Google Patents

Forming components made of hard metal Download PDF

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Publication number
EP0194018A1
EP0194018A1 EP86300605A EP86300605A EP0194018A1 EP 0194018 A1 EP0194018 A1 EP 0194018A1 EP 86300605 A EP86300605 A EP 86300605A EP 86300605 A EP86300605 A EP 86300605A EP 0194018 A1 EP0194018 A1 EP 0194018A1
Authority
EP
European Patent Office
Prior art keywords
layer
grains
layers
component
hard metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP86300605A
Other languages
German (de)
French (fr)
Inventor
Roy Cooper
Trevor Hugh Owen
Christopher Thomas Peters
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Boart International Ltd
Original Assignee
Boart International Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Boart International Ltd filed Critical Boart International Ltd
Publication of EP0194018A1 publication Critical patent/EP0194018A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F7/00Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
    • B22F7/06Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00Aspects linked to processes or compositions used in powder metallurgy

Definitions

  • a hardmetal is usually composed of grains of a hard abrasion resistant material such as a metal carbide, nitride or the like and a binder metal.
  • a hard abrasion resistant material such as a metal carbide, nitride or the like
  • a binder metal The most common form of hardmetal is tungsten carbide with cobalt as the binder, but frequently tungsten carbide is mixed with other metal carbides such as titanium carbide and vanadium carbide.
  • the component in question could be a hard wearing surface such as the surface of a metal rolling roll or it could be used in a tool for cutting or eroding other material such as an insert or button for a rock drill, or the component could provide surface fracture resistance.
  • a method of forming a hard metal component comprises forming two layers of abrasion resistant grains each mixed with a metal binder in substantially the same volumetric proportions, the grains in the first layer being substantially coarser than the grains in the second layer, pressing the layers together and sintering the thus pressed layers to produce the component, whereby the first layer after sintering has a lesser metal binder content than the second layer.
  • the one layer is preferably substantially thinner than the other layer, and the grains in the first layer are about twice the size of the grains in the second layer.
  • a wire drawing die was made using a two stage pressing operation. Two centre mandrels of different diameters were used. The diameters are calculated to give the required layer thicknesses in the sintered product taking into account shrinkage during sintering.
  • Tungsten carbide mixed with cobalt to an amount of 6% by mass was used.
  • the nominal grain size for the inner layer was 3 to 5 micrometres while that of the outerlayer was 1 to 2 micrometres.
  • Powder of the finer grain size was first poured into the pressing die with a large diameter mandrel at the centre. After pre-pressing at 50% of the final pressing pressure, the first mandrel was removed and replaced with the smaller diameter mandrel. Powder of the coarser grain size was poured into the annular cavity around the mandrel. The mandrel was removed after final pressing at 150 MPa and the pressing was sintered in a vaccuum at 1400°C for 30 min.
  • anvil of ultra high pressure apparatus could have its tip formed with a layer having a higher binder metal concentration than the body of the anvil.
  • the layer will provide thoughness and protection against surface fracture or cracks.
  • the essence of the invention is that layered hardmetal products, with differing binder metal contents in the layers, can be made without spalling and cracking by having differential grain sizes but substantially the same initial binder metal content.

Abstract

A hard metal component such as a wire drawing die is made from a first or inner layer with coarse grained tungsten carbide particles and an outer or second layer with finer grained tungsten carbide particles. Initially the layers have the same content of cobalt. The layers are pressed and then sintered. After sintering the first layer is reduced in cobalt content, but has a much higher wear resistance than a conventional component for the same purpose.

Description

    BACKGROUND OF THE INVENTION
  • This invention relates to components made of hard metal. A hardmetal is usually composed of grains of a hard abrasion resistant material such as a metal carbide, nitride or the like and a binder metal. The most common form of hardmetal is tungsten carbide with cobalt as the binder, but frequently tungsten carbide is mixed with other metal carbides such as titanium carbide and vanadium carbide.
  • The component in question could be a hard wearing surface such as the surface of a metal rolling roll or it could be used in a tool for cutting or eroding other material such as an insert or button for a rock drill, or the component could provide surface fracture resistance.
  • SUMMARY OF THE INVENTION
  • According to the invention a method of forming a hard metal component comprises forming two layers of abrasion resistant grains each mixed with a metal binder in substantially the same volumetric proportions, the grains in the first layer being substantially coarser than the grains in the second layer, pressing the layers together and sintering the thus pressed layers to produce the component, whereby the first layer after sintering has a lesser metal binder content than the second layer.
  • The one layer is preferably substantially thinner than the other layer, and the grains in the first layer are about twice the size of the grains in the second layer.
  • DESCRIPTION OF AN EMBODIMENT
  • A wire drawing die was made using a two stage pressing operation. Two centre mandrels of different diameters were used. The diameters are calculated to give the required layer thicknesses in the sintered product taking into account shrinkage during sintering.
  • Tungsten carbide mixed with cobalt to an amount of 6% by mass was used. The nominal grain size for the inner layer was 3 to 5 micrometres while that of the outerlayer was 1 to 2 micrometres.
  • Powder of the finer grain size was first poured into the pressing die with a large diameter mandrel at the centre. After pre-pressing at 50% of the final pressing pressure, the first mandrel was removed and replaced with the smaller diameter mandrel. Powder of the coarser grain size was poured into the annular cavity around the mandrel. The mandrel was removed after final pressing at 150 MPa and the pressing was sintered in a vaccuum at 1400°C for 30 min.
  • Tests showed that the binder content in the inner, thin layer of the sintered component was reduced by about 50%. The component was ground and polished and then used for wire drawing. The normal production dies at the wire drawing operation in question normally draw between 5 to 5,5 tons of wire before the dies have to be replaced. With the die made as described above 6,5 tons of wire was drawn before the wire no longer fell within the diameter specification.
  • In a converse situation the layer with the finer grain size could be the thinner one. Thus an anvil of ultra high pressure apparatus could have its tip formed with a layer having a higher binder metal concentration than the body of the anvil. The layer will provide thoughness and protection against surface fracture or cracks.
  • The essence of the invention is that layered hardmetal products, with differing binder metal contents in the layers, can be made without spalling and cracking by having differential grain sizes but substantially the same initial binder metal content.

Claims (5)

1. A method of forming a hardmetal component comprising forming two layers of abrasion resistant grains each mixed with a metal binder in substantially the same volumetric proportions, the grains in the first layer being substantially coarser than the grains in the second layer, pressing the layers together and sintering the thus pressed layers to produce the component, whereby the first layer after sintering has a lesser metal binder content than the second layer.
2. The method claimed in claim 1 in which the one layer is substantially thinner than the other layer.
3. The method claimed in either one of the above claims in which the grains in the first layer are about twice the size of the grains in the second layer.
4. The method claimed in any one of the above claims in which the grain size in the first layer is between 3 to 5 micrometers and the grain size in the second layer is between 1 to 2 micrometers.
5. The method claimed in any one of the above claims in which the component is a wire drawing die and the first layer is the thinner layer and is around the die opening.
EP86300605A 1985-01-31 1986-01-29 Forming components made of hard metal Withdrawn EP0194018A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ZA85761 1985-01-31
ZA850761 1985-01-31

Publications (1)

Publication Number Publication Date
EP0194018A1 true EP0194018A1 (en) 1986-09-10

Family

ID=25577738

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86300605A Withdrawn EP0194018A1 (en) 1985-01-31 1986-01-29 Forming components made of hard metal

Country Status (4)

Country Link
EP (1) EP0194018A1 (en)
JP (1) JPS61231104A (en)
IE (1) IE860272L (en)
NO (1) NO860333L (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996020057A1 (en) * 1994-12-23 1996-07-04 Kennametal Inc. Composite cermet articles and method of making
WO1997007256A1 (en) * 1995-08-11 1997-02-27 Kennametal Inc. Hard composite and method of making the same
US5623723A (en) * 1995-08-11 1997-04-22 Greenfield; Mark S. Hard composite and method of making the same
US6908688B1 (en) 2000-08-04 2005-06-21 Kennametal Inc. Graded composite hardmetals
WO2005056854A1 (en) * 2003-12-15 2005-06-23 Sandvik Intellectual Property Ab Cemented carbide tools for mining and construction applications and method of making the same
US7449043B2 (en) 2003-12-15 2008-11-11 Sandvik Intellectual Property Aktiebolag Cemented carbide tool and method of making the same
WO2013082002A1 (en) * 2011-11-29 2013-06-06 Smith International Inc. High pressure carbide component incorporating gradient structures
US9463507B2 (en) 2006-11-20 2016-10-11 Kabushiki Kaisha Miyanaga Method for producing hard tip

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0054846A1 (en) * 1980-12-22 1982-06-30 General Electric Company Diamond and cubic boron nitride abrasive compacts using size selective abrasive particle layers and process for making same
US4359335A (en) * 1980-06-05 1982-11-16 Smith International, Inc. Method of fabrication of rock bit inserts of tungsten carbide (WC) and cobalt (Co) with cutting surface wear pad of relative hardness and body portion of relative toughness sintered as an integral composite

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4359335A (en) * 1980-06-05 1982-11-16 Smith International, Inc. Method of fabrication of rock bit inserts of tungsten carbide (WC) and cobalt (Co) with cutting surface wear pad of relative hardness and body portion of relative toughness sintered as an integral composite
EP0054846A1 (en) * 1980-12-22 1982-06-30 General Electric Company Diamond and cubic boron nitride abrasive compacts using size selective abrasive particle layers and process for making same

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5806934A (en) * 1994-12-23 1998-09-15 Kennametal Inc. Method of using composite cermet articles
CN1107565C (en) * 1994-12-23 2003-05-07 钴碳化钨硬质合金公司 Composite cermet articles and method of making
WO1996020057A1 (en) * 1994-12-23 1996-07-04 Kennametal Inc. Composite cermet articles and method of making
US5677042A (en) * 1994-12-23 1997-10-14 Kennametal Inc. Composite cermet articles and method of making
US5679445A (en) * 1994-12-23 1997-10-21 Kennametal Inc. Composite cermet articles and method of making
US5697042A (en) * 1994-12-23 1997-12-09 Kennametal Inc. Composite cermet articles and method of making
US5776593A (en) * 1994-12-23 1998-07-07 Kennametal Inc. Composite cermet articles and method of making
US6183687B1 (en) 1995-08-11 2001-02-06 Kennametal Inc. Hard composite and method of making the same
US5623723A (en) * 1995-08-11 1997-04-22 Greenfield; Mark S. Hard composite and method of making the same
WO1997007256A1 (en) * 1995-08-11 1997-02-27 Kennametal Inc. Hard composite and method of making the same
US6908688B1 (en) 2000-08-04 2005-06-21 Kennametal Inc. Graded composite hardmetals
WO2005056854A1 (en) * 2003-12-15 2005-06-23 Sandvik Intellectual Property Ab Cemented carbide tools for mining and construction applications and method of making the same
US7427310B2 (en) 2003-12-15 2008-09-23 Sandvik Intellectual Property Ab Cemented carbide tools for mining and construction applications and method of making same
US7449043B2 (en) 2003-12-15 2008-11-11 Sandvik Intellectual Property Aktiebolag Cemented carbide tool and method of making the same
US7678327B2 (en) 2003-12-15 2010-03-16 Sandvik Intellectual Property Aktiebolag Cemented carbide tools for mining and construction applications and method of making same
US7708936B2 (en) 2003-12-15 2010-05-04 Sandvik Intellectual Property Aktiebolag Cemented carbide tool and method of making the same
US9463507B2 (en) 2006-11-20 2016-10-11 Kabushiki Kaisha Miyanaga Method for producing hard tip
WO2013082002A1 (en) * 2011-11-29 2013-06-06 Smith International Inc. High pressure carbide component incorporating gradient structures
US9764523B2 (en) 2011-11-29 2017-09-19 Smith International, Inc. High pressure carbide component with surfaces incorporating gradient structures

Also Published As

Publication number Publication date
NO860333L (en) 1986-08-01
IE860272L (en) 1986-07-31
JPS61231104A (en) 1986-10-15

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Inventor name: PETERS, CHRISTOPHER THOMAS

Inventor name: OWEN, TREVOR HUGH

Inventor name: COOPER, ROY