EP0117923B1 - Hartlotzusatzmetalle auf Nickelbasis - Google Patents

Hartlotzusatzmetalle auf Nickelbasis Download PDF

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Publication number
EP0117923B1
EP0117923B1 EP83113237A EP83113237A EP0117923B1 EP 0117923 B1 EP0117923 B1 EP 0117923B1 EP 83113237 A EP83113237 A EP 83113237A EP 83113237 A EP83113237 A EP 83113237A EP 0117923 B1 EP0117923 B1 EP 0117923B1
Authority
EP
European Patent Office
Prior art keywords
metal
brazing
filler metal
foil
brazing filler
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP83113237A
Other languages
English (en)
French (fr)
Other versions
EP0117923A1 (de
Inventor
Debasis Bose
Amitava Datta
Nicholas John De Cristofaro
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Allied Corp
Original Assignee
Allied Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Allied Corp filed Critical Allied Corp
Publication of EP0117923A1 publication Critical patent/EP0117923A1/de
Application granted granted Critical
Publication of EP0117923B1 publication Critical patent/EP0117923B1/de
Expired legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24—Selection of soldering or welding materials proper
    • B23K35/32—Selection of soldering or welding materials proper with the principal constituent melting at more than 1550 degrees C
    • B23K35/322—Selection of soldering or welding materials proper with the principal constituent melting at more than 1550 degrees C a Pt-group metal as principal constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C45/00—Amorphous alloys
    • C22C45/04—Amorphous alloys with nickel or cobalt as the major constituent

Definitions

  • Brazing is a process for joining metal parts, often of dissimilar composition, to each other.
  • a filler metal that has a melting point lower than that of the base metal parts to be joined together is interposed between the metal parts to form an assembly.
  • the assembly is then heated to a temperature sufficient to melt the filler metal. Upon cooling, a strong, corrosion resistant, leak-tight joint is formed.
  • the homogeneous brazing foil of the invention is fabricated by a process which comprises forming a melt of the composition and quenching the melt on a rotating quench wheel at a rate of at least about 10 5 °C/sec. Rapid quenching of the alloys is facilitated by the presence therein of substantial amounts of silicon (contained in the solid state as hard, brittle silicides).
  • an improved process for joining two or more metal parts by brazing comprises:
  • the homogeneous, ductile brazing foil of the invention can be placed inside the joint prior to the brazing operation.
  • Use of the homogeneous, ductile nickel based foil provided by this invention also permits brazing to be accomplished by processes such as dip brazing in molten salts, which are not readily accomplished with powder or rod-type fillers.
  • the brazing material In any brazing process, the brazing material must have a melting point that will be sufficiently high to provide strength to meet service requirements of the metal parts brazed together. However, the melting point must not be so high as to make difficult the brazing operation. Further, the filler material must be compatible, both chemically and metallurgically, with the materials being brazed. The brazing material must be more noble than the metal being brazed to avoid corrosion. Ideally, the brazing material must be in ductile foil form so that complex shapes may be stamped therefrom. Finally, the brazing foil should be homogeneous, that is, contain no binders or other materials that would otherwise form voids or contaminating residues during brazing.
  • homogeneous is meant that the foil, as produced, is of substantially uniform composition in all dimensions.
  • ductile is meant that foil can be bent to a round radius as small as ten times the foil thickness without fracture.
  • Silicon is added to depress the melting temperature of nickel; palladium is added to depress the melting temperature and to provide corrosion resistance of the joint.
  • the metal alloys of the present invention can be produced in various forms, including powder, foil or sheet by application of various rapid solidification and comminution techniques.
  • One method commonly used to fabricate these alloys into powder form involves gas or water atomization of molten alloys.
  • Other techniques, widely used in the industry, are described in the following documents.
  • the brazing material of the invention is advantageously produced in foil (or ribbon) form, and may be used in brazing applications as cast, whether the material is glassy or a solid solution.
  • foils of glassy metal alloys may be heat treated to obtain a crystalline phase, preferably fine-grained, in order to promote longer die life when stamping of complex shapes is contemplated.
  • the brazing foils of the invention are also superior to various powder brazes of the same composition in providing good braze joints. This is probably due to the ability to apply the brazing foil where the braze is required, rather than depending on capillarity to transport braze filler metal from the edge of surfaces to be brazed.
  • Ribbons about 2.54 to 25.4 mm wide and about 13 to 76 pm thick were formed by squirting a melt of the particular composition by overpressure of argon onto a rapidly rotating copper chill wheel (surface speed about 1500 to 3000 cm/s.). Metastable homogeneous ribbons of substantially glassy alloys having the compositions set forth in Table I were produced.
  • the liquidus and solidus temperatures of the ribbons mentioned in Example 1 were determined by Differential Thermal Analysis (DTA) Technique.
  • DTA Differential Thermal Analysis
  • the individual samples were heated side by side with an inert reference material at uniform rate and the temperature difference between them was measured as a function of temperature.
  • the resulting curve known as a thermogram, was a plot of heat-energy change vs. temperature, from which the beginning of melting and end of melting, known respectively as solidus and liquidus temperatures, were determined. Values thus determined are set forth in Table II below.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)

Claims (8)

1. Metallegierung mit einer Zusammensetzung bestehend aus 25 bis 35 Atom-% Palladium und 15 bis 20 Atom-% Silicium, wobei der Rest aus Nickel und beiläufigen Verunreinigungen besteht, worin die Metallegierung eine wenigstens 50%-ig glasartige Struktur hat.
2. Metallegierungszusammensetzung nach Anspruch 1, die eine wenigstens 90 %-ig glasartige Struktur hat.
3. Hartlotzusatzmetall mit einer Zusammensetzung bestehend aus 25 bis 35 Atom-% Palladium und 15 bis 25 Atom-% Silicium, wobei der Rest aus Nickel und beiläufigen Verunreinigungen besteht, dadurch gekennzeichnet, daß das Metall eine wenigstens 50 %-ig glasartige Struktur und eine Liquidustemperatur geringer als 1000°C hat.
4. Harlotzusatzmetall nach Anspruch 3, wobei dieses Zusatzmetall in Pulverform vorliegt.
5. Hartlotzusatzmetall nach Anspruch 3, wobei dieses Zusatzmetall in der Form einer homogenen Folie vorliegt.
6. Hartlotzusatzmetall nach Anspruch 5, wobei die Folie eine Dicke im Bereich von 0,0005 bis 0,0040 inch (12 bis 100 pm) hat.
7. Hartlotzusatzmetall nach Anspruch 5, wobei die Folie duktil ist und eine wenigstens 90 %-ig glasartige Struktur hat.
8. Verfahren zum Verbinden zweier oder mehrerer Metallteile miteinander, bei dem man
a) ein Zusatzmetall mit einer Zusammensetzung bestehend aus 25 bis 35 Atom-% Palladium und 15 bis 20 Atom-% Silicium, wobei der Rest aus Nickel und beiläufigen Verunreinigungen besteht, zwischen den Metallteilen unter Bildung einer Anordnung einfügt, wobei das Zusatzmetall einen geringeren Schmelzpunkt als jener jedes der Teile hat,
b) die Anordnung auf wenigstens die Schmelztemperatur des Zusatzmetalles erhitzt und
c) die Anordnung kühlt,

dadurch gekennzeichnet, daß als das Zusatzmetall eine homogene Folie auf Nickelbasis mit wenigstens 50 %-ig glasartiger Struktur verwendet wird.
EP83113237A 1983-02-28 1983-12-30 Hartlotzusatzmetalle auf Nickelbasis Expired EP0117923B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/470,403 US4448618A (en) 1983-02-28 1983-02-28 Nickel based brazing filler metals
US470403 1983-02-28

Publications (2)

Publication Number Publication Date
EP0117923A1 EP0117923A1 (de) 1984-09-12
EP0117923B1 true EP0117923B1 (de) 1988-02-24

Family

ID=23867498

Family Applications (1)

Application Number Title Priority Date Filing Date
EP83113237A Expired EP0117923B1 (de) 1983-02-28 1983-12-30 Hartlotzusatzmetalle auf Nickelbasis

Country Status (5)

Country Link
US (1) US4448618A (de)
EP (1) EP0117923B1 (de)
JP (1) JPS59166392A (de)
CA (1) CA1229507A (de)
DE (1) DE3375721D1 (de)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8713807D0 (en) * 1987-06-12 1987-07-15 Nl Petroleum Prod Cutting structures for rotary drill bits
US4746379A (en) * 1987-08-25 1988-05-24 Allied-Signal Inc. Low temperature, high strength nickel-palladium based brazing alloys
US5424140A (en) * 1989-10-10 1995-06-13 Alliedsignal Inc. Low melting nickel-palladium-silicon brazing alloys
US5405573A (en) * 1991-09-20 1995-04-11 General Electric Company Diamond pellets and saw blade segments made therewith
JP2002527214A (ja) 1998-10-19 2002-08-27 スリーエム イノベイティブ プロパティズ カンパニー 耐腐蝕性のニッケルベースの合金を混入する歯科矯正装置
KR100755477B1 (ko) 2003-07-07 2007-09-04 가부시키가이샤 아이에이치아이 땜납재 시트 및 그 제조방법
CN101272880B (zh) * 2005-07-22 2012-03-21 西门子公司 用于修补部件的方法
CH705321A1 (de) * 2011-07-19 2013-01-31 Alstom Technology Ltd Lötfolie zum Hochtemperaturlöten und Verfahren zum Reparieren bzw. Herstellen von Bauteilen unter Verwendung dieser Lötfolie.

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3070875A (en) * 1959-11-24 1963-01-01 Westinghouse Electric Corp Novel brazing alloy and structures produced therewith
US3856513A (en) * 1972-12-26 1974-12-24 Allied Chem Novel amorphous metals and amorphous metal articles
US4149881A (en) * 1978-06-28 1979-04-17 Western Gold And Platinum Company Nickel palladium base brazing alloy
US4169744A (en) * 1978-06-28 1979-10-02 Western Gold And Platinum Company Nickel-chromium-silicon alloy brazing foil

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SCRIPTA METALLURGICA, vol. 9, no. 7, 1975, pages 787-789, Pergamon Press, Inc., Elmsford, N.Y., US, H.S. CHEN et al.: "Young's modulus and hardness of metallic (Pdl-xNix).835Si165 glasses" *

Also Published As

Publication number Publication date
DE3375721D1 (en) 1988-03-31
US4448618A (en) 1984-05-15
JPS6258837B2 (de) 1987-12-08
CA1229507A (en) 1987-11-24
JPS59166392A (ja) 1984-09-19
EP0117923A1 (de) 1984-09-12

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