EP0098052A2 - Improvements in or relating to freezers - Google Patents

Improvements in or relating to freezers Download PDF

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Publication number
EP0098052A2
EP0098052A2 EP83303118A EP83303118A EP0098052A2 EP 0098052 A2 EP0098052 A2 EP 0098052A2 EP 83303118 A EP83303118 A EP 83303118A EP 83303118 A EP83303118 A EP 83303118A EP 0098052 A2 EP0098052 A2 EP 0098052A2
Authority
EP
European Patent Office
Prior art keywords
freezer
brine solution
casing
compressor
cold store
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP83303118A
Other languages
German (de)
French (fr)
Other versions
EP0098052A3 (en
Inventor
Peter William Crossley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Thorn EMI Domestic Appliances Ltd
Original Assignee
Thorn EMI Domestic Appliances Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Thorn EMI Domestic Appliances Ltd filed Critical Thorn EMI Domestic Appliances Ltd
Publication of EP0098052A2 publication Critical patent/EP0098052A2/en
Publication of EP0098052A3 publication Critical patent/EP0098052A3/en
Withdrawn legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D11/00Self-contained movable devices, e.g. domestic refrigerators
    • F25D11/006Self-contained movable devices, e.g. domestic refrigerators with cold storage accumulators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D11/00Self-contained movable devices, e.g. domestic refrigerators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D25/00Charging, supporting, and discharging the articles to be cooled
    • F25D25/02Charging, supporting, and discharging the articles to be cooled by shelves
    • F25D25/028Cooled supporting means

Definitions

  • This invention relates to freezers.
  • a freezer characterised in that it incorporates a cold store having an eutectic temperature less than a desired operating temperature of the freezer.
  • a freezer as set forth in the immediately preceding paragraph wherein the cold store has an evaporator coil of a refrigeration system of the freezer contained therein, thereby substantially limiting the lowest operating temperature of the evaporator to the temperature of the oold store.
  • the cold store comprises a brine solution, having an appropriate eutectic temperature, which gives up heat energy and thus undergoes a phase change, during the operation of the compressor, and which slowly absorbs heat energy from within the freezer and thus undergoes a reverse phase change, when the compressor is not in operation.
  • an upright freezer having an outer housing 1 and a door 2 contains a number of shelves, labelled 3 to 6 respectively, upon which items of frozen food, such as that shown at 7, are stored.
  • Each shelf comprises a casing 8, which is filled with a brine solution 10 having an eutectic temperature a few degrees lower than the desired operating temperature of the freezer, the brine solution 10 also having an evaporator coil 9 immersed therein.
  • each shelf is connected in series and form part of a refrigeration system of known construction including a compressor (not shown in the diagram), which is situated to the rear of the food storage compartment of the freezer.
  • the compressor is run (to the extent necessary) on a cheap rate of electricity, such as "Economy 7," so that, due to the evaporator coils being immersed within the brine solution, heat energy is transferred from the brine solution, which thus undergoes a phase change, into the evaporator coils, thus providing a cold store within each shelf.
  • a cheap rate of electricity such as "Economy 7”
  • the brine solution then slowly absorbs heat energy from within the freezer, so that the solution undergoes a reverse phase change over a substantial length of time, thus maintaining a substantially constant desired operating temperature within the freezer.
  • the brine solution may be substantially greater in volume in one phase than the other, so that, to accommodate for the volume increase, it may be necessary to provide an air gap between the surface of the solution within the casing 8 and the upper surface of the casing.
  • Such a gap may also prove necessary to provide means for ensuring good thermal contact between the upper surface of the casing, upon which the food items are placed, and the solution.
  • These means may comprise, for example, protuberances extending down from the upper surface of the casing into the solution.
  • this arrangement in accordance with the present invention should provide a substantial energy saving, as the compressor is only run during a period of cheap rate of electricity, and thus this substantially lowers the running cost of a freezer of this kind, as well as providing improved refrigeration efficiency due to lower night-time ambient temperatures, which reduce the temperature difference between the evaporator and condensor of the refrigeration system.
  • the present invention could be incorporated within a chest freezer, as well as an upright freezer as in the preferred embodiment.
  • a chest freezer due to the distribution of food in a chest freezer, it may be necessary to use a combination of both cold store sachets and shelves to ensure that a substantially constant desired temperature is maintained within the whole volume of the freezer.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Devices That Are Associated With Refrigeration Equipment (AREA)

Abstract

A freezer, having an outer housing (1) and a door (2), contains a number of shelves (3 to 6) upon which frozen food (7) is stored.
Each shelf comprises a casing (8) filled with brine solution (10) having an eutectic temperature a few degrees lower than the desired operating temperature of the freezer. An evaporator coil (9), forming part of a refrigeration system, including a compressor, of the freezer, is immersed in the brine solution (10) in each casing.
During the night storage period, the compressor is run on cheap rate electricity and the brine solution (10) gives up heat energy, thereby undergoing a phase change.
During the daytime, the compressor is stopped and the brine solution (10) slowly absorbs heat energy from within the freezer, thereby slowly undergoing a reverse phase change and maintaining a substantially constant desired operating temperature of the freezer.

Description

  • This invention relates to freezers.
  • In conventional freezers, the interior temperature tends to vary, thus necessitating frequent control by switching the compressor on and off to maintain the desired operating temperature within the freezer.
  • The running of a freezer can therefore prove to be rather expensive, as the starting and stopping of the compressor at frequent intervals requires a substantial amount of energy.
  • It is therefore an object of the present invention to provide a cold store which operates substantially at a specific temperature and thereby to reduce the frequency of operation of the compressor, thus achieving an energy saving.
  • It is a further object of the invention to so proportion the cold store that it becomes possible to operate the compressor substantially only during a night storage period on a cheap rate of electricity, in particular "Economy 7", and to maintain substantially the desired temperature within the freezer during the remaining time period.
  • According to one aspect of the present invention there is provided a freezer characterised in that it incorporates a cold store having an eutectic temperature less than a desired operating temperature of the freezer.
  • According to another aspect of the invention there is provided a freezer as set forth in the immediately preceding paragraph wherein the cold store has an evaporator coil of a refrigeration system of the freezer contained therein, thereby substantially limiting the lowest operating temperature of the evaporator to the temperature of the oold store.
  • Incorporating the evaporator coil within the cold store can therefore substantially improve refrigeration efficiency.
  • Moreover, as a consequence of night-time operation of the compressor, ambient temperatures are likely to be lower than during the day-time, which consequently lowers the condensing temperature of the refrigeration system, thereby further improving refrigeration efficiency.
  • In a preferred embodiment, the cold store comprises a brine solution, having an appropriate eutectic temperature, which gives up heat energy and thus undergoes a phase change, during the operation of the compressor, and which slowly absorbs heat energy from within the freezer and thus undergoes a reverse phase change, when the compressor is not in operation.
  • The invention will now be further described by way of example only with reference to the accompanying drawing, the single figure of which shows a schematic sectional view of the food storage compartment of a freezer incorporating the present invention.
  • Referring to the figure, an upright freezer, having an outer housing 1 and a door 2, contains a number of shelves, labelled 3 to 6 respectively, upon which items of frozen food, such as that shown at 7, are stored.
  • Each shelf comprises a casing 8, which is filled with a brine solution 10 having an eutectic temperature a few degrees lower than the desired operating temperature of the freezer, the brine solution 10 also having an evaporator coil 9 immersed therein.
  • The respective evaporator coils in each shelf are connected in series and form part of a refrigeration system of known construction including a compressor (not shown in the diagram), which is situated to the rear of the food storage compartment of the freezer.
  • During the night storage period of approximately seven hours duration, the compressor is run (to the extent necessary) on a cheap rate of electricity, such as "Economy 7," so that, due to the evaporator coils being immersed within the brine solution, heat energy is transferred from the brine solution, which thus undergoes a phase change, into the evaporator coils, thus providing a cold store within each shelf.
  • At the end of the night storage period, operation of the compressor is stopped, and it should not be required to run again until the following night storage period.
  • During the daytime, the brine solution then slowly absorbs heat energy from within the freezer, so that the solution undergoes a reverse phase change over a substantial length of time, thus maintaining a substantially constant desired operating temperature within the freezer.
  • However, the brine solution may be substantially greater in volume in one phase than the other, so that, to accommodate for the volume increase, it may be necessary to provide an air gap between the surface of the solution within the casing 8 and the upper surface of the casing.
  • If such a gap is to be provided, it may also prove necessary to provide means for ensuring good thermal contact between the upper surface of the casing, upon which the food items are placed, and the solution. These means may comprise, for example, protuberances extending down from the upper surface of the casing into the solution.
  • It can clearly be seen that this arrangement in accordance with the present invention should provide a substantial energy saving, as the compressor is only run during a period of cheap rate of electricity, and thus this substantially lowers the running cost of a freezer of this kind, as well as providing improved refrigeration efficiency due to lower night-time ambient temperatures, which reduce the temperature difference between the evaporator and condensor of the refrigeration system.
  • Alternative embodiments incorporating the present invention may, of course be envisaged, such as the use of sachets containing a brine solution, which may be deposited in various positions within the freezer.
  • Alternative solutions may also be utilised, as long as they have eutectic temperatures less than the desired operating temperature of the freezer.
  • It will be appreciated that the present invention could be incorporated within a chest freezer, as well as an upright freezer as in the preferred embodiment. However, due to the distribution of food in a chest freezer, it may be necessary to use a combination of both cold store sachets and shelves to ensure that a substantially constant desired temperature is maintained within the whole volume of the freezer.

Claims (10)

1. A freezer characterised in that it incorporates a cold store having an eutectic temperature less than a desired operating temperature of the freezer.
2. A freezer as claimed in Claim 2 wherein the cold store has an evaporator coil of a refrigeration-system of the freezer contained therein, thereby substantially limiting. the lowest operating temperature of the evaporator to'the temperature of the cold store.
3. A freezer as claimed in Claim 1 or 2 wherein the cold store comprises a brine solution, having an appropriate eutectic temperature, which gives up heat energy, thereby under-going a phase change, during operation of a compressor of a refrigeration system of the freezer, and which absorbs heat energy from within the freezer over a substantial period of time, thereby undergoing a reverse phase change, when the compressor is not in operation.
4. A freezer as claimed in Claim 3 including at least one shelf comprising a casing, said casing being filled with said brine solution.
5. A freezer as claimed in Claim 4 wherein said brine solution in said casing of said at least one shelf has an evaporator coil of a refrigeration system of the freezer immersed therein.
6. A freezer as claimed in Claim 5 wherein each evaporator coil immersed in the brine solution of the casing of each shelf is connected in series in said refrigeration system.
7. A freezer as claimed in Claim 4, 5 or 6 wherein an air gap is provided between the surface of said brine solution in said casing and an upper surface of said casing.
8. A freezer as claimed in Claim 7 wherein means are provided in said casing to ensure substantially good thermal contact between said upper surface and said brine solution.
9. A freezer as claimed in Claim 8 wherein said means comprises protuberances extending in a generally downward direction from said upper surface and into said brine solution.
10. A freezer as claimed in Claim 1, 2 or 3 wherein said cold store comprises at least one sachet containing brine solution, said at least one sachet being deposited within the freezer.
EP83303118A 1982-06-26 1983-05-31 Improvements in or relating to freezers Withdrawn EP0098052A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8218572 1982-06-26
GB8218572 1982-06-26

Publications (2)

Publication Number Publication Date
EP0098052A2 true EP0098052A2 (en) 1984-01-11
EP0098052A3 EP0098052A3 (en) 1984-03-28

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP83303118A Withdrawn EP0098052A3 (en) 1982-06-26 1983-05-31 Improvements in or relating to freezers

Country Status (1)

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EP (1) EP0098052A3 (en)

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0141840A1 (en) * 1983-04-22 1985-05-22 GREENER, Richard C. Cold storage cell for refrigeration system
FR2678718A1 (en) * 1991-07-02 1993-01-08 Selnor Refrigeration appliance fitted with a heat accumulator
WO1994005959A1 (en) * 1992-09-01 1994-03-17 Allan John Cassell Refrigerator and freezer units
DE4331934C1 (en) * 1993-09-16 1995-05-04 Elbau Elektronik Bauelemente G Implantable biosensor and drug administration arrangement and sterilisation method
EP0794396A1 (en) * 1996-03-08 1997-09-10 Société d'Electromenager du Nord Selnor Cold generating apparatus having a heat exchanger with heat storage
FR2745894A1 (en) * 1996-03-08 1997-09-12 Selnor Refrigerator or freezer heat exchanger with thermal accumulator
WO1999009359A1 (en) 1997-08-14 1999-02-25 Etc Energietechnik Und Chemie Gmbh & Co. Kg Solar heat powered cooling plant
EP1124101A2 (en) * 2000-02-11 2001-08-16 CANDY S.p.A. Refrigerator appliance with refrigeration grid provided with eutectic plates
EP1327837A2 (en) * 2002-01-09 2003-07-16 Electrolux Home Products Corporation N.V. Automatic cooling agent valve
WO2004063648A1 (en) * 2003-01-10 2004-07-29 Liebherr-Hausgeräte Ochsenhausen GmbH Freezer and defrosting method
KR20130071576A (en) * 2011-12-21 2013-07-01 엘지전자 주식회사 Refrigerator
CN103597300A (en) * 2011-03-14 2014-02-19 Bsh博世和西门子家用电器有限公司 Refrigeration device having a heat store
WO2015100119A1 (en) * 2013-12-23 2015-07-02 The Coca-Cola Company Intermittent power grid ready cooler
WO2016179215A1 (en) * 2015-05-05 2016-11-10 Tokitae Llc Refrigeration devices including temperature-controlled container systems
US9523522B2 (en) 2013-11-27 2016-12-20 Tokitae Llc Refrigeration devices including temperature-controlled container systems
WO2017099913A1 (en) * 2015-12-11 2017-06-15 The Coca-Cola Company Systems and methods for providing a phase change material panel and charging unit for cooling a cabinet of a merchandiser
US9726418B2 (en) 2013-11-27 2017-08-08 Tokitae Llc Refrigeration devices including temperature-controlled container systems
WO2018057147A1 (en) * 2016-09-26 2018-03-29 Hussmann Corporation Refrigerated merchandiser including eutectic plate refrigeration
CN109442849A (en) * 2018-11-01 2019-03-08 中科美菱低温科技股份有限公司 A kind of storage box and its control system based on phase-change material
CN110487001A (en) * 2019-09-11 2019-11-22 海信(山东)冰箱有限公司 A kind of refrigerator

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH146947A (en) * 1930-07-25 1931-05-15 Farkas Pal Refrigeration system.
US1839651A (en) * 1928-09-12 1932-01-05 Copeman Lab Co Sharp freezing unit
US2428312A (en) * 1943-05-01 1947-09-30 Henry M Herbener Refrigerator
US2428311A (en) * 1940-05-07 1947-09-30 Henry M Herbener Refrigerator with holdover arrangement
US2521063A (en) * 1946-03-29 1950-09-05 Dole Refrigerating Co Two-temperature refrigerator
US2814186A (en) * 1955-12-28 1957-11-26 Dole Refrigerating Co Truck plates
US2889694A (en) * 1957-01-09 1959-06-09 Dole Refrigerating Co Refrigerant plates
DE1501216A1 (en) * 1965-09-07 1969-10-23 Bbc Brown Boveri & Cie Freezer with a removable partition plate that can be moved to subdivide the refrigeration compartment
US3747364A (en) * 1970-07-14 1973-07-24 Laing Nikolaus New freezing chamber with refrigeration storage
DE2726954A1 (en) * 1977-06-15 1979-01-04 Walter Holzer Deep freeze system with latent heat storage - utilises low tariff electricity operating storage utilising latent heat of freezing
EP0053589A2 (en) * 1980-12-01 1982-06-09 INDESIT INDUSTRIA ELETTRODOMESTICI ITALIANA S.p.A. Perfected refrigerator
GB2094459A (en) * 1981-01-19 1982-09-15 Tokyo Shibaura Electric Co Refrigerator

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1839651A (en) * 1928-09-12 1932-01-05 Copeman Lab Co Sharp freezing unit
CH146947A (en) * 1930-07-25 1931-05-15 Farkas Pal Refrigeration system.
US2428311A (en) * 1940-05-07 1947-09-30 Henry M Herbener Refrigerator with holdover arrangement
US2428312A (en) * 1943-05-01 1947-09-30 Henry M Herbener Refrigerator
US2521063A (en) * 1946-03-29 1950-09-05 Dole Refrigerating Co Two-temperature refrigerator
US2814186A (en) * 1955-12-28 1957-11-26 Dole Refrigerating Co Truck plates
US2889694A (en) * 1957-01-09 1959-06-09 Dole Refrigerating Co Refrigerant plates
DE1501216A1 (en) * 1965-09-07 1969-10-23 Bbc Brown Boveri & Cie Freezer with a removable partition plate that can be moved to subdivide the refrigeration compartment
US3747364A (en) * 1970-07-14 1973-07-24 Laing Nikolaus New freezing chamber with refrigeration storage
DE2726954A1 (en) * 1977-06-15 1979-01-04 Walter Holzer Deep freeze system with latent heat storage - utilises low tariff electricity operating storage utilising latent heat of freezing
EP0053589A2 (en) * 1980-12-01 1982-06-09 INDESIT INDUSTRIA ELETTRODOMESTICI ITALIANA S.p.A. Perfected refrigerator
GB2094459A (en) * 1981-01-19 1982-09-15 Tokyo Shibaura Electric Co Refrigerator

Cited By (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0141840A1 (en) * 1983-04-22 1985-05-22 GREENER, Richard C. Cold storage cell for refrigeration system
EP0141840A4 (en) * 1983-04-22 1985-09-16 Richard C Greener Cold storage cell for refrigeration system.
FR2678718A1 (en) * 1991-07-02 1993-01-08 Selnor Refrigeration appliance fitted with a heat accumulator
WO1994005959A1 (en) * 1992-09-01 1994-03-17 Allan John Cassell Refrigerator and freezer units
DE4331934C1 (en) * 1993-09-16 1995-05-04 Elbau Elektronik Bauelemente G Implantable biosensor and drug administration arrangement and sterilisation method
FR2745894A1 (en) * 1996-03-08 1997-09-12 Selnor Refrigerator or freezer heat exchanger with thermal accumulator
EP0794396A1 (en) * 1996-03-08 1997-09-10 Société d'Electromenager du Nord Selnor Cold generating apparatus having a heat exchanger with heat storage
WO1999009359A1 (en) 1997-08-14 1999-02-25 Etc Energietechnik Und Chemie Gmbh & Co. Kg Solar heat powered cooling plant
EP1124101A2 (en) * 2000-02-11 2001-08-16 CANDY S.p.A. Refrigerator appliance with refrigeration grid provided with eutectic plates
EP1124101A3 (en) * 2000-02-11 2001-09-05 CANDY S.p.A. Refrigerator appliance with refrigeration grid provided with eutectic plates
EP1327837A2 (en) * 2002-01-09 2003-07-16 Electrolux Home Products Corporation N.V. Automatic cooling agent valve
EP1327837A3 (en) * 2002-01-09 2005-09-07 Electrolux Home Products Corporation N.V. Automatic cooling agent valve
WO2004063648A1 (en) * 2003-01-10 2004-07-29 Liebherr-Hausgeräte Ochsenhausen GmbH Freezer and defrosting method
CN103597300B (en) * 2011-03-14 2016-11-09 Bsh家用电器有限公司 There is the refrigerating appliance of hot memory
CN103597300A (en) * 2011-03-14 2014-02-19 Bsh博世和西门子家用电器有限公司 Refrigeration device having a heat store
KR20130071576A (en) * 2011-12-21 2013-07-01 엘지전자 주식회사 Refrigerator
US9523522B2 (en) 2013-11-27 2016-12-20 Tokitae Llc Refrigeration devices including temperature-controlled container systems
US9726418B2 (en) 2013-11-27 2017-08-08 Tokitae Llc Refrigeration devices including temperature-controlled container systems
WO2015100119A1 (en) * 2013-12-23 2015-07-02 The Coca-Cola Company Intermittent power grid ready cooler
EP3087332B1 (en) * 2013-12-23 2021-03-24 The Coca-Cola Company Intermittent power grid ready cooler
US10156395B2 (en) 2013-12-23 2018-12-18 The Coca-Cola Company Intermittent power grid ready cooler
WO2016179215A1 (en) * 2015-05-05 2016-11-10 Tokitae Llc Refrigeration devices including temperature-controlled container systems
CN107709907A (en) * 2015-05-05 2018-02-16 脱其泰有限责任公司 Include the refrigerating plant of controlled temperature containment system
CN107709907B (en) * 2015-05-05 2020-10-02 脱其泰有限责任公司 Refrigeration device comprising a temperature-controlled container system
CN108603718A (en) * 2015-12-11 2018-09-28 可口可乐公司 The system and method for phase-change material panel and filling unit for providing the cabinet for cooling down vending machine
WO2017099913A1 (en) * 2015-12-11 2017-06-15 The Coca-Cola Company Systems and methods for providing a phase change material panel and charging unit for cooling a cabinet of a merchandiser
CN108603718B (en) * 2015-12-11 2021-05-07 可口可乐公司 System and method for providing a phase change material panel and a fill unit for cooling a cabinet of a vending machine
WO2018057147A1 (en) * 2016-09-26 2018-03-29 Hussmann Corporation Refrigerated merchandiser including eutectic plate refrigeration
GB2569064A (en) * 2016-09-26 2019-06-05 Hussmann Corp Refrigerated merchandiser including eutectic plate refrigeration
US10188223B2 (en) 2016-09-26 2019-01-29 Hussmann Corporation Refrigerated merchandiser including eutectic plate refrigeration
CN109442849B (en) * 2018-11-01 2020-11-13 中科美菱低温科技股份有限公司 Preservation box based on phase-change material and control system thereof
CN109442849A (en) * 2018-11-01 2019-03-08 中科美菱低温科技股份有限公司 A kind of storage box and its control system based on phase-change material
CN110487001A (en) * 2019-09-11 2019-11-22 海信(山东)冰箱有限公司 A kind of refrigerator

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