EP0082456A2 - Prémélanges concentrés d'agents adoucissant le linge - Google Patents

Prémélanges concentrés d'agents adoucissant le linge Download PDF

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Publication number
EP0082456A2
EP0082456A2 EP82111555A EP82111555A EP0082456A2 EP 0082456 A2 EP0082456 A2 EP 0082456A2 EP 82111555 A EP82111555 A EP 82111555A EP 82111555 A EP82111555 A EP 82111555A EP 0082456 A2 EP0082456 A2 EP 0082456A2
Authority
EP
European Patent Office
Prior art keywords
carbon atoms
alkyl
methyl
weight
molecular weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP82111555A
Other languages
German (de)
English (en)
Other versions
EP0082456B1 (fr
EP0082456A3 (en
Inventor
Adolf Dr. May
Hans-Walter Dr. Bücking
Manfred Schreiber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Priority to AT82111555T priority Critical patent/ATE22919T1/de
Publication of EP0082456A2 publication Critical patent/EP0082456A2/fr
Publication of EP0082456A3 publication Critical patent/EP0082456A3/de
Application granted granted Critical
Publication of EP0082456B1 publication Critical patent/EP0082456B1/fr
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/645Mixtures of compounds all of which are cationic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/001Softening compositions
    • C11D3/0015Softening compositions liquid
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144Alcohols; Metal alcoholates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165Ethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/372Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing etherified or esterified hydroxy groups ; Polyethers of low molecular weight
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46Compounds containing quaternary nitrogen atoms
    • D06M13/463Compounds containing quaternary nitrogen atoms derived from monoamines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46Compounds containing quaternary nitrogen atoms
    • D06M13/47Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
    • D06M13/473Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions

Definitions

  • washed textiles especially those made from cellulose fibers, have an unpleasant hardening after drying. This occurs particularly when the laundry is done in the washing machine.
  • Such undesirable hardening of the handle can be eliminated by treating the textiles after washing in a rinsing bath with cationic substances which contain at least two long-chain aliphatic residues in the molecule.
  • the water-dispersible dialkyldimethylammonium salts or imidazoline derivatives of the formulas I - III are used in particular for this purpose:
  • R 1 is alkyl or alkenyl with 8-22, preferably 10-18, carbon atoms
  • R 3 is methyl or hydrogen
  • x is 1-5
  • A is an anion such as C1 (-) , Br (-) , CH 3 OSO 3 (-) or CH 3 OPO 3 (-) .
  • the products of these formulas I - III have a liquid or solid consistency. If R 1 is a saturated residue, the product is solid at room temperature. The transport then takes place in heated tankers or rail tank cars. It is delivered in barrels for transport to overseas.
  • the manufacturers of fabric softeners then have the products transferred to heated tank systems. If the raw material is processed, the warmed-up product is dispersed in hot water. If barrel goods are processed, the products must first be liquefied in a barrel heating system and can then be further processed.
  • the alkyl radicals of the compounds I - III consist of unsaturated units
  • these derivatives are liquid at room temperature. They can be processed into dispersions with cold water. Liquid fabric softener raw materials, however, have a reduced softening effect compared to the saturated derivatives. In order to achieve comparable grip properties, much more cationic substance has to be offered to the tissue in the case of unsaturated compounds.
  • 1 kg of the types of compounds of the formula I to III with a saturated radical R 1 corresponds to approximately 1.33 kg of the types of compound of the formula I to III with an unsaturated radical R 1 .
  • auxiliary plasticizers listed under b) can each be used individually or in mixtures with one another.
  • the premixes according to the invention can also contain further substances and auxiliaries.
  • auxiliaries such as cationic or nonionic surface-active substances, solubilizers such as e.g. p-cumene sulfonate, electrolytes, acidifying agents such as e.g. Phosphoric acid, acetic acid, organic complexing agents, optical brighteners as well as colors and fragrances. They serve to additionally influence the handle of the goods or other properties of the textiles to be treated or to adjust the viscosity, to regulate the pH or to increase the stability at low temperatures.
  • laundry softener premixes according to the invention are described. Percentages are percentages by weight in all cases. In all cases, these premixes are prepared by simply stirring the liquid individual components in the cold.
  • liquid cloudy viscosity 650 mPas
  • liquid cloudy viscosity 700 mPas
  • Example 2 25 g of the premix from Example 2 are mixed with 0.9 g of perfume. and 1 g of a non-ionic emulsifier of the isctridecyl alcohol type mixed with 10 EO. 5 ml of a 10% CaCl 2 solution in 61.4 ml of cold water are added. This solution is stirred into the premix. A stable emulsion is obtained. The viscosity is approx. 150 mPas.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
EP82111555A 1981-12-18 1982-12-13 Prémélanges concentrés d'agents adoucissant le linge Expired EP0082456B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT82111555T ATE22919T1 (de) 1981-12-18 1982-12-13 Konzentrierte vormischungen von waescheweichspuelmitteln.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19813150179 DE3150179A1 (de) 1981-12-18 1981-12-18 Konzentrierte vormischungen von waescheweichspuelmitteln
DE3150179 1981-12-18

Publications (3)

Publication Number Publication Date
EP0082456A2 true EP0082456A2 (fr) 1983-06-29
EP0082456A3 EP0082456A3 (en) 1984-11-28
EP0082456B1 EP0082456B1 (fr) 1986-10-15

Family

ID=6149087

Family Applications (1)

Application Number Title Priority Date Filing Date
EP82111555A Expired EP0082456B1 (fr) 1981-12-18 1982-12-13 Prémélanges concentrés d'agents adoucissant le linge

Country Status (8)

Country Link
US (1) US4476030A (fr)
EP (1) EP0082456B1 (fr)
JP (1) JPS58109681A (fr)
AT (1) ATE22919T1 (fr)
BR (1) BR8207359A (fr)
CA (1) CA1193403A (fr)
DE (2) DE3150179A1 (fr)
ZA (1) ZA829282B (fr)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0122141A2 (fr) * 1983-04-08 1984-10-17 Unilever Plc Compositions adoucissantes pour matières textiles
GB2139658A (en) * 1983-05-11 1984-11-14 Colgate Palmolive Co Concentrated fabric softening composition
EP0159196A2 (fr) * 1984-04-19 1985-10-23 Unilever N.V. Composition adoucissante aqueuse concentrée pour tissus
GB2157728A (en) * 1984-04-19 1985-10-30 Unilever Plc Aqueous fabric softening composition
GB2157730A (en) * 1984-04-19 1985-10-30 Unilever Plc Aqueous concentrated fabric softening composition
EP0163910A1 (fr) * 1984-05-04 1985-12-11 Hoechst Aktiengesellschaft Produits de lavage contenant un agent adoucissant
EP0164966A2 (fr) * 1984-06-12 1985-12-18 Imperial Chemical Industries Plc Agents de conditionnement pour tissus
EP0186967A1 (fr) * 1984-11-30 1986-07-09 Thomas Swan And Co., Ltd. Dérivés d'imidazolines quaternisés appropriés pour l'application d'amollissants de textile
EP0374609A2 (fr) * 1988-12-17 1990-06-27 Pfersee Chemie GmbH Adoussicant hydrophile pour matériaux fibreux et son application
EP0437988A2 (fr) * 1989-12-08 1991-07-24 Rhone-Poulenc Chimie Composé lessiviel à base d'un polyphosphate et d'un agent optiquement actif, son procÀ©dé de préparation et son utilisation en détergence
GB2260771A (en) * 1991-10-23 1993-04-28 Cussons Int Ltd Fabric softener concentrate
WO1995006097A1 (fr) * 1993-08-24 1995-03-02 Sasol Chemical Industries (Proprietary) Limited Composition de traitement de tissus
WO1996016147A1 (fr) * 1994-11-17 1996-05-30 Henkel Kommanditgesellschaft Auf Aktien Dispersions aqueuses de cire
EP0730023A2 (fr) * 1995-03-01 1996-09-04 Colgate-Palmolive Company Concentrés de détergents
WO1997034975A1 (fr) * 1996-03-22 1997-09-25 The Procter & Gamble Company Composition concentree adoucissante pour textiles stable aux temperatures extremes et compose adoucissant hautement insature
WO1997034976A1 (fr) * 1996-03-22 1997-09-25 The Procter & Gamble Company Melange concentre stable servant a preparer une composition adoucissante pour tissus

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3204165A1 (de) * 1982-02-06 1983-08-11 Hoechst Ag, 6230 Frankfurt Konzentrierte waescheweichspuelmittel
US4772403A (en) * 1985-01-30 1988-09-20 Colgate Palmolive Company Fabric softener composition
US4654152A (en) * 1985-10-07 1987-03-31 Domtar Inc. Base mix fabric softener
US4741842A (en) * 1986-01-27 1988-05-03 Colgate-Palmolive Company Particulate detergent softener compositions comprising a mixture of cationic softener and ethoxylated amine
DE3706664A1 (de) * 1987-02-28 1988-09-08 Henkel Kgaa Fluessige textilbehandlungsmittel
US4885102A (en) * 1987-07-17 1989-12-05 Kao Corporation Cloth-softening liquid composition containing quaternary ammonium compound and a polyether derivative or cationic surfactant polymer
ES2065367T3 (es) * 1988-01-28 1995-02-16 Unilever Nv Composicion para el tratamiento de tejidos y su preparacion.
JPH0756112B2 (ja) * 1988-02-17 1995-06-14 花王株式会社 濃縮型衣料用柔軟仕上剤
JP2631389B2 (ja) * 1988-05-19 1997-07-16 ライオン株式会社 柔軟剤組成物
MX9801520A (es) * 1995-08-31 1998-05-31 Colgate Palmolive Co Composiciones suavizadoras de telas estables.
GB0121806D0 (en) 2001-09-10 2001-10-31 Unilever Plc A method of reducing the viscosity of fabric conditioning compositions
GB0121802D0 (en) 2001-09-10 2001-10-31 Unilever Plc Fabric conditioning compositions
WO2023105205A1 (fr) 2021-12-06 2023-06-15 Reckitt Benckiser Health Limited Composition de désinfection et d'adoucissement du linge
GB2613660B (en) * 2021-12-06 2024-07-17 Reckitt Benckiser Health Ltd Laundry sanitizing and softening composition

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3154489A (en) * 1960-07-18 1964-10-27 Armour & Co Surface active compositions
DE3019076A1 (de) * 1979-05-21 1980-12-04 Unilever Nv Fluessiges textilweichmachermittel
EP0022555A1 (fr) * 1979-07-12 1981-01-21 Hoechst Aktiengesellschaft Adoucissant pour matières textiles
EP0023334A1 (fr) * 1979-07-25 1981-02-04 Hoechst Aktiengesellschaft Agent d'assouplissement pour le linge

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2966013D1 (en) * 1979-01-11 1983-09-01 Procter & Gamble Concentrated fabric softening composition
DE3066798D1 (en) * 1979-04-21 1984-04-12 Procter & Gamble Fabric softening composition
EP0056695B2 (fr) * 1981-01-16 1987-09-09 THE PROCTER & GAMBLE COMPANY Compositions pour le traitement de matières textiles

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3154489A (en) * 1960-07-18 1964-10-27 Armour & Co Surface active compositions
DE3019076A1 (de) * 1979-05-21 1980-12-04 Unilever Nv Fluessiges textilweichmachermittel
EP0022555A1 (fr) * 1979-07-12 1981-01-21 Hoechst Aktiengesellschaft Adoucissant pour matières textiles
EP0023334A1 (fr) * 1979-07-25 1981-02-04 Hoechst Aktiengesellschaft Agent d'assouplissement pour le linge

Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0122141B1 (fr) * 1983-04-08 1989-11-15 Unilever Plc Compositions adoucissantes pour matières textiles
EP0122141A2 (fr) * 1983-04-08 1984-10-17 Unilever Plc Compositions adoucissantes pour matières textiles
GB2139658A (en) * 1983-05-11 1984-11-14 Colgate Palmolive Co Concentrated fabric softening composition
EP0159196A3 (fr) * 1984-04-19 1987-03-18 Unilever N.V. Composition adoucissante aqueuse concentrée pour tissus
EP0159196A2 (fr) * 1984-04-19 1985-10-23 Unilever N.V. Composition adoucissante aqueuse concentrée pour tissus
GB2157729A (en) * 1984-04-19 1985-10-30 Unilever Plc Aqueous concentrated fabric softening composition
GB2157728A (en) * 1984-04-19 1985-10-30 Unilever Plc Aqueous fabric softening composition
GB2157730A (en) * 1984-04-19 1985-10-30 Unilever Plc Aqueous concentrated fabric softening composition
US4622154A (en) * 1984-04-19 1986-11-11 Lever Brothers Company Aqueous fabric softening composition
US4627925A (en) * 1984-04-19 1986-12-09 Lever Brothers Company Aqueous concentrated fabric softening composition
EP0163910A1 (fr) * 1984-05-04 1985-12-11 Hoechst Aktiengesellschaft Produits de lavage contenant un agent adoucissant
EP0164966A3 (en) * 1984-06-12 1988-04-20 Imperial Chemical Industries Plc Fabric conditioners
EP0164966A2 (fr) * 1984-06-12 1985-12-18 Imperial Chemical Industries Plc Agents de conditionnement pour tissus
EP0186967A1 (fr) * 1984-11-30 1986-07-09 Thomas Swan And Co., Ltd. Dérivés d'imidazolines quaternisés appropriés pour l'application d'amollissants de textile
EP0374609A3 (fr) * 1988-12-17 1992-03-04 Pfersee Chemie GmbH Adoussicant hydrophile pour matériaux fibreux et son application
EP0374609A2 (fr) * 1988-12-17 1990-06-27 Pfersee Chemie GmbH Adoussicant hydrophile pour matériaux fibreux et son application
EP0437988B1 (fr) * 1989-12-08 1996-06-19 Rhone-Poulenc Chimie Composé lessiviel à base d'un polyphosphate et d'un agent optiquement actif, son procédé de préparation et son utilisation en détergence
EP0437988A2 (fr) * 1989-12-08 1991-07-24 Rhone-Poulenc Chimie Composé lessiviel à base d'un polyphosphate et d'un agent optiquement actif, son procÀ©dé de préparation et son utilisation en détergence
GB2260771A (en) * 1991-10-23 1993-04-28 Cussons Int Ltd Fabric softener concentrate
WO1995006097A1 (fr) * 1993-08-24 1995-03-02 Sasol Chemical Industries (Proprietary) Limited Composition de traitement de tissus
GB2295626A (en) * 1993-08-24 1996-06-05 Sasol Chemical Ind Fabric treatment composition
GB2295626B (en) * 1993-08-24 1998-02-11 Sasol Chemical Ind Fabric treatment composition
WO1996016147A1 (fr) * 1994-11-17 1996-05-30 Henkel Kommanditgesellschaft Auf Aktien Dispersions aqueuses de cire
EP0730023A2 (fr) * 1995-03-01 1996-09-04 Colgate-Palmolive Company Concentrés de détergents
EP0730023A3 (fr) * 1995-03-01 1999-08-11 Colgate-Palmolive Company Concentrés de détergents
WO1997034975A1 (fr) * 1996-03-22 1997-09-25 The Procter & Gamble Company Composition concentree adoucissante pour textiles stable aux temperatures extremes et compose adoucissant hautement insature
WO1997034976A1 (fr) * 1996-03-22 1997-09-25 The Procter & Gamble Company Melange concentre stable servant a preparer une composition adoucissante pour tissus

Also Published As

Publication number Publication date
JPH0325549B2 (fr) 1991-04-08
JPS58109681A (ja) 1983-06-30
DE3150179A1 (de) 1983-06-23
CA1193403A (fr) 1985-09-17
DE3273801D1 (en) 1986-11-20
US4476030A (en) 1984-10-09
EP0082456B1 (fr) 1986-10-15
EP0082456A3 (en) 1984-11-28
BR8207359A (pt) 1983-10-18
ZA829282B (en) 1983-09-28
ATE22919T1 (de) 1986-11-15

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