EP0018630A1 - Washing agent for textiles - Google Patents

Washing agent for textiles Download PDF

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Publication number
EP0018630A1
EP0018630A1 EP80102333A EP80102333A EP0018630A1 EP 0018630 A1 EP0018630 A1 EP 0018630A1 EP 80102333 A EP80102333 A EP 80102333A EP 80102333 A EP80102333 A EP 80102333A EP 0018630 A1 EP0018630 A1 EP 0018630A1
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EP
European Patent Office
Prior art keywords
weight
fatty acid
quaternary ammonium
ethylene oxide
moles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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EP80102333A
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German (de)
French (fr)
Inventor
Hans Dr. Andree
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Henkel AG and Co KGaA
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Henkel AG and Co KGaA
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Publication of EP0018630A1 publication Critical patent/EP0018630A1/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • the invention relates to a powdery or granular detergent with a fabric softening effect for the simultaneous washing and care of delicates in the washing machine or by hand.
  • the washing effect of such combinations is particularly good if the ratio of the nonionic surfactant to the quaternary ammonium compound is in the ratio 4: 1 to 1: 1 .
  • Powdered detergents for machine washing based on nonionic addition products of ethylene oxide with certain alkylphenols, fatty alcohols, mercaptans, fatty acid monoethanolamides or fatty amines as nonionic surfactant components, which contain cationic ammonium compounds for foam control, are described in DE-AS 12 20 956.
  • the invention was therefore based on the object of providing a powdery or granular detergent for mild detergents which has optimum washing power, textile-softening properties and also foaming behavior and which can be used both in the washing machine and for washing by hand.
  • the polyglycol ethers of the formula I which are suitable according to the invention as constituent a) are derived from natural or synthetic primary fatty alcohols or oxo alcohols.
  • Oxo alcohols are produced by reacting linear olefins with carbon monoxide and hydrogen according to the known oxo process by hydroformylation and subsequent hydrogenation.
  • Commercially available oxo alcohol mixtures which are suitable for the preparation of the surfactant component a) suitable are, for example, the oxo alcohols available from Deutsche Shell Chemie Deutschen under the trade name "Dobanol", which have about 25% by weight of 2-alkyl branched alcohols; other suitable oxo alcohols are available under the name "Synprol” from Imperial Chemical Industries Ltd.
  • Suitable products based on oxo alcohols are, for example, various "Lutensol” types from BASF with approx. 30-35% by weight of branched alcohols and some "Lial” types from Liquichimica SpA with approx. 60% by weight. on branched alcohols.
  • Typical preferred products are, for example, "Dobanol 45-7”, which consists of at least 95% C 14 / C 15 oxo alcohol with an average of 7 moles of ethylene oxide; also “Lutensol AO-8”, which is a C 13 / C 15 oxo alcohol ethoxylate with an average of 8 moles of ethylene oxide and “Lutensol ON-70”, which is a C 9 / C 11 oxo alcohol ethoxylate with average 7 Mole represents ethylene oxide.
  • Typical surfactants derived from fatty alcohols are based, for example, on tallow fatty alcohol or the commercial products "Lorol” with 8-18 carbon atoms from Henkel.
  • Typical preferred products are, for example, “Dehydol TA 5" and “Dehydol TA 14" (Henkel), which are tallow fatty alcohol polyglycol ethers with 5 and 14 moles of ethylene oxide per mole of alcohol.
  • Another preferred product is, for example, the commercial product "Marli p al KF" (Chemische Werke Huls), a C 10 / C 12 fatty alcohol ethoxylate with an average of 6 moles of ethylene oxide.
  • polyglycol ethers are the addition products derived from oleyl alcohol or cetyl alcohol with 5-10 moles of ethylene oxide or technical mixtures of predominantly oleyl and cetyl alcohol with 5-10 moles of ethylene oxide, the iodine number of which is between approximately 40 and approximately 60. Also preferred is the commercial product "Dehydol LS 4" (Henkel), a C 12 / C 14 fatty alcohol Ethoxylate with about 4 moles of ethylene oxide. These polyglycol ethers, individually or in a mixture, form component a) of the agents according to the invention.
  • the finished agent are contained in the finished agent at 5-20% by weight, preferably at 7-15% by weight, and can be wholly or partly by the C 8 -C 15 alkylaryl polyglycol ethers known as nonionic surfactants, such as nonylphenol with approx 5 to about 15 moles of ethylene oxide are replaced.
  • nonionic surfactants such as nonylphenol with approx 5 to about 15 moles of ethylene oxide are replaced.
  • Fatty acid mono- or diethanolamides with a fatty acid residue having 12-18 carbon atoms are suitable as component b) of the agents according to the invention. Both the compounds with a uniform number of carbon atoms in the fatty acid ester and mixtures of fatty acid ethanolamides with differently long fatty acid residues can be used.
  • a preferred product is derived from coconut fatty acid with a proportion of more than 50% by weight of C 12 fatty acid, approx. 20% by weight C 14 fatty acid, approx. 10% by weight C 16 fatty acid and another Share of saturated and unsaturated C 18 fatty acid. Such a product is commercially available under the name "Comperlan 100" (Henkel).
  • Another suitable product is the coconut fatty acid diethanolamide commercially available as "Comperlan KD" (Henkel).
  • the fatty acid ethanolamides are contained in the agents according to the invention to 1-10% by weight, preferably to 2-5% by weight.
  • the quaternary ammonium compounds with preferably two long-chain, preferably saturated aliphatic radicals each having 14-26, preferably 16-20, carbon atoms and at least one quaternary nitrogen atom in the molecule are suitable as textile-softening active ingredients (component c)).
  • the long-chain aliphatic radicals can be straight-chain or branched and accordingly hzw from fatty acids. from fatty amines, Guerbetamines, or from the alkylamines obtainable by reduction of nitroparaffins.
  • quaternary ammonium compounds are, in particular, derivatives of Ammöniaks, ie the quaternary salts obtainable by alkylation of long-chain secondary amines, such as the compounds distearyldimethylammonium chloride or ditalgalkyldimethylammonium chloride, or the reaction of 1 mol of an aminoalkylethylenediamine or hydroxyalkylethylenediamine with 2 mol of a long-chain C 14 -C 26 fatty acid or their esters obtainable imidazoline compounds which are subsequently converted into the quaternary imidazolinium compounds by alkylation.
  • long-chain secondary amines such as the compounds distearyldimethylammonium chloride or ditalgalkyldimethylammonium chloride, or the reaction of 1 mol of an aminoalkylethylenediamine or hydroxyalkylethylenediamine with 2 mol of a long-chain C 14 -C 26 fatty acid or their esters obtainable imid
  • the anion generally consists of the acid residue which has arisen from the alkylating agent used in the quaternization.
  • the alkylating agent used in the quaternization for example, chloride, bromide, methyl sulfate, ethyl sulfate, methane, ethane or toluenesulfonate, preferably chloride and / or methyl sulfate, are therefore suitable as anions.
  • Typical preferred fabric softeners are, for example, ditallow alkyldimethylammonium chloride (for example the commercial products “Präpagen WK” and “Präpagen WKT", Hoechst, "Adogen 442", Ashland) or distearyldimethylammonium chloride (for example "Arosurf TA 100", Ashland) and 2-heptadecyl-1-methyl 1-oleoylamid-ethyl-imidazolinium methosulfate.
  • ditallow alkyldimethylammonium chloride for example the commercial products "Präpagen WK” and “Präpagen WKT", Hoechst, "Adogen 442", Ashland
  • distearyldimethylammonium chloride for example "Arosurf TA 100", Ashland
  • 2-heptadecyl-1-methyl 1-oleoylamid-ethyl-imidazolinium methosulfate for example, dit
  • the textile-softening active ingredients are present in the agents according to the invention to 2-10% by weight, preferably 3-7% by weight, with the textile-softening active ingredient c) preferably comprising more than 25, in particular more than 30% by weight in the the polyglycol ether a), the fatty acid ethanolamide b) and the fabric softening active ingredient c) is present surfactant component.
  • the agents according to the invention contain 60-92% by weight of additives usually present in detergents as further constituents.
  • additives usually present in detergents as further constituents.
  • builders include calcium-precipitating or complexing inorganic or organic compounds.
  • Inorganic precipitating or complexing substances are, for example, pyrophosphate, triphosphate, higher polyphosphates and metaphosphates and the cation-exchanging alkali alumosilicates, as described, for example, in DE-AS 24 12 837, in particular zeolites A and X.
  • Suitable organic compounds are, for example, polycarboxylic acids, hydroxycarboxylic acids , Amino carboxylic acids, carboxyalkyl ethers, polyanionic polymeric carboxylic acids, phosphonic acids.
  • Other structural substances are weakly acidic, neutral or alkaline inorganic salts, such as bicarbonates, carbonates, borates or silicates of alkalis, alkali sulfates, and the alkali salts of organic, non-capillary-active, 1-8 C-atoms containing sulfonic acids, carboxylic acids and sulfocarboxylic acids.
  • the agents according to the invention preferably contain about 10-50% by weight sodium tripolyphosphate, 2-10% by weight water glass with a Na 2 0: SiO 2 ratio of, for example, 1: 3.4, and sodium sulfate as builders.
  • the agents according to the invention are in powder form. These are fine-grained to granular or spherical products that are easy to pour. They can be produced by all methods known in the art. For example, you can mix the powdered components together and spray oily or pasty components, such as nonionic surfactants, onto the product. Another production possibility consists in pasting the constituents of the agents with water to a paste which is converted into a powder by evaporating the water, for example on rollers or in atomizing towers. After / 8 Hot drying can then also incorporate heat-sensitive or volatile substances, such as fragrances.
  • the detergents according to the invention can be used for washing and simultaneously softening fine laundry articles made of wool, synthetic fibers such as polyester, polyacrylonitrile, polyamide and mixtures of wool and synthetic fibers.
  • the washing and softening process can take place either in the washing machine or by hand at washing temperatures up to about 60 ° C., preferably up to about 30 ° C.
  • the application concentration of the agents is generally from 1 to 10 g / l of wash liquor, preferably from 2 to 5 g / l.
  • the detergents are characterized by the fact that they clean the textiles perfectly and at the same time give them a pleasant feel and anti-electrostatic properties. When washing by hand in the washbasin, they form a dense, pleasant foam, and no foaming is observed when washing in the washing machine. The foam can also be easily rinsed out.
  • An agent of the above composition is a detergent according to the invention containing conventional additives in conventional amounts.
  • the detergents according to the invention listed in Examples 1-5 were found to wash fine textiles made of wool, polyacrylonitrile or wool / polyacrylonitrile mixtures, as well as polyamide / cotton mixtures in the washing machine up to 60 ° C, preferably up to about 30 ° C, and by hand as products with a balanced combination of properties with regard to their washing power, their softening effect and their foaming behavior.

Abstract

The agent suitable for simultaneous washing and softening of delicate articles is based on non-ionic surfactants containing quaternary ammonium compounds which soften textiles. The agent consists of (a) 5-20 (7-15) per cent by weight of one or more polyglycol ethers, (b) 1-10 (2-5) per cent by weight of a C12-C18-fatty acid ethanolamide, (c) 2-10 (3-7) per cent by weight of a quaternary ammonium salt which is derived from ammonia or imidazoline and has 2 long-chain aliphatic radicals and 60-92 per cent by weight of conventional components of a washing agent for delicate materials. (a) is a polyglycol ether of the formula I <IMAGE> in which R<1> is a linear alkyl or alkenyl group with 8-20 carbon atoms, R<2> is H or C1-C4-alkyl, n = 2-20; (a) can also be a C8-C15- alkylarylpolyglycol ether with 3-15 ethoxy units alone or mixed with polyglycol ethers of the formula I.

Description

Die Erfindung betrifft ein pulverförmiges oder körniges Waschmittel mit textilweichmachender Wirkung zum gleichzeitigen Waschen und Pflegen von Feinwaschartikeln in der Waschmaschine oder von Hand.The invention relates to a powdery or granular detergent with a fabric softening effect for the simultaneous washing and care of delicates in the washing machine or by hand.

Es bestand seit langem ein Bedarf an einem pulverförmigen oder körnigen, textilweichmacherhaltigen Feinwaschmittel, das den Textilien während des Waschprozesses die erwünsch- ten weichmachenden und antistatischen Eigenschaften verleiht. Wegen der bekannten Unverträglichkeit der üblichen Textilweichmacher vom Typ der quartäcen Ammonium- bzw. Imidazoliniumverbindungen mit anionischen Tensiden war die Verwendung von anionischen Tensiden in derartigen Präparten ausgeschlossen. Es lag deshalb nahe, Kombinationen aus nichtionischen Tensiden und quartären Ammoniumverbindungen einzusetzen. So sind aus der GB-PS 830 864 Flüssigwaschmittel bekannt, die nichtionische Tenside und quartäre Ammoniumverbindungen, die einen langkettigen Alkylrest und drei kurzkettige Alkylreste aufwaisen, bekannt. Nach den Angaben in der Zeitschrift Seifen-Öle-Fette-Wachse (1963), 4, S. 78, ist der Wascheffekt derartiger Kombinationen besonders gut, wenn das Verhältnis des nichtionischen Tensids zur quartären Ammoniumverbindung im Mengenverhältnis 4 : 1 bis 1 : 1 liegt.There has long been a need for a powdery or granular detergent containing fabric softener that gives the textiles the desired softening and antistatic properties during the washing process. Because of the known incompatibility of the usual textile plasticizers of the quaternary ammonium or imidazolinium type with anionic surfactants, the use of anionic surfactants in such preparations was excluded. It therefore made sense to use combinations of nonionic surfactants and quaternary ammonium compounds. From GB-PS 830 864 liquid detergents are known, the nonionic surfactants and quaternary ammonium compounds, which have a long-chain alkyl radical and three short-chain alkyl radicals. According to the information in the magazine Seifen-Öle-Fette-Wwachs (1963), 4, p. 78, the washing effect of such combinations is particularly good if the ratio of the nonionic surfactant to the quaternary ammonium compound is in the ratio 4: 1 to 1: 1 .

Pulverförmige Waschmittel für die Maschinenwäsche auf Basis nichtionischer Anlagerungsprodukte von Ethylenoxid an bestimmte Alkylphenole, Fettalkohole, Mercaptane, Fettsäuremonoethanolamide oder Fettamine als'nichtionische Tensidkomponente, die zur Schaumdämpfung kationische Ammoniumverbindungen enthalten, sind in der DE-AS 12 20 956 beschrieben.Powdered detergents for machine washing based on nonionic addition products of ethylene oxide with certain alkylphenols, fatty alcohols, mercaptans, fatty acid monoethanolamides or fatty amines as nonionic surfactant components, which contain cationic ammonium compounds for foam control, are described in DE-AS 12 20 956.

Diese Lösungsvorschläge können jedoch nicht befriedigen, weil mit diesen Waschmitteln keine Ausgewogenheit hinsichtlich Waschkraft, Weichmachungsleistung und Schäumverhalten in der Waschmaschine und bei der Wäsche von Hand erreicht werden kann. Der Fachmann konnte diesem Stand der Technik keine Anregung entnehmen, wie ein pulverförmiges Waschmittel mit einer optimalen Kombination der erwünschten Eigenschaften zusammengesetzt sein müßte. Der Fachmann mußte vielmehr annehmen, daß ein waschwirksames Tensid den in'der Waschlauge vorhandenen Textilweichmacher zusammen mit dem Schmutz von den Textilfasern ablösen bzw. fernhalten würde und deshalb der angestrebte textilweichmachende Effekt nicht eintreten könnte. Umgekehrt wäre eine gute weichmachende Wirkung aber mit einem nur ungenügend reinigenden Tensid zu erzielen.However, these proposed solutions cannot be satisfactory because these detergents cannot achieve a balance in terms of washing power, softening performance and foaming behavior in the washing machine and during washing by hand. The person skilled in the art could not take any suggestion from this prior art as to how a powder detergent should be composed with an optimal combination of the desired properties. Rather, the person skilled in the art had to assume that a detersive surfactant would detach the textile softener present in the wash liquor together with the dirt or keep it away from the textile fibers and therefore the desired textile softening effect could not occur. Conversely, a good softening effect would be achieved with an insufficiently cleaning surfactant.

Der Erfindung lag daher die Aufgabe zugrunde, ein pulverförmiges oder körniges Waschmittel für Feinwaschmittel bereitzustellen, das ein Optimum an Waschvermögen, an textilweichmachenden Eigenschaften und auch an Schäumverhalten aufweist, und das sowohl in der Waschmaschine als auch für die Wäsche von Hand verwendet werden kann.The invention was therefore based on the object of providing a powdery or granular detergent for mild detergents which has optimum washing power, textile-softening properties and also foaming behavior and which can be used both in the washing machine and for washing by hand.

Die Aufgabe wurde erfindungsgemäß gelöst durch ein pulverförmiges Waschmittel, das

  • a) 5 - 20 Gew.-% eines aliphatischen Polyglykolethers oder eines Gemisches von mehreren Polyglykolethern der Formel
    Figure imgb0001
    in der R eine geradkettige Alkyl- oder Alkenylgruppe mit 8 - 20 Kohlenstoffatomen, R2 Wasserstoff oder eine C1-C4-Alkylgruppe und n einen Wert von 2 - 20 bedeuten, und/ oder eines C8-C15-Alkylarylpolyglykolethers mit 3 - 15 Ethoxyeinheiten,
  • b) 1 - 10 Gew.-% eines C12-C18-Fettsäureethanolamids,
  • c) 2 - 10 Gew.-% eines textilweichmachenden quartären Ammoniumsalzes, ausgewählt aus den Derivaten des Ammoniaks und/oder des Imidazolins mit vorzugsweise 2 langkettigen aliphatischen Resten im Molekül,
  • d) 60 - 92 Gew.-% übliche Bestandteile eines Feinwaschmittels enthält.
The object was achieved according to the invention by a powdered detergent which
  • a) 5 - 20 wt .-% of an aliphatic polyglycol ether or a mixture of several polyglycol ethers of the formula
    Figure imgb0001
     in which R is a straight-chain alkyl or alkenyl group with 8-20 carbon atoms, R 2 is hydrogen or a C 1 -C 4 alkyl group and n is a value of 2 - 20, and / or a C 8 -C 15 alkylaryl polyglycol ether with 3 15 ethoxy units,
  • b) 1-10% by weight of a C 12 -C 18 fatty acid ethanol amide,
  • c) 2-10% by weight of a textile-softening quaternary ammonium salt, selected from the derivatives of ammonia and / or imidazoline with preferably 2 long-chain aliphatic radicals in the molecule,
  • d) contains 60-92% by weight of conventional components of a mild detergent.

Die erfindungsgemäß als Bestandteil a) geeigneten Polyglykolether der Formel I leiten sich von natürlichen oder synthetischen primären Fettalkoholen oder Oxoalkoholen ab. Oxoalkohole werden durch Umsetzung linearer Olefine mit Kohlenstoffmonoxid und Wasserstoff nach dem bekannten Oxo-Verfahren durch Hydroformylierung und anschließende Hydrierung hergestellt. Handelsübliche Oxoalkohol-Gemische, die sich für die Herstellung der Tensid-Komponente a) eignen, sind beispielsweise die unter der Handelsbezeichnung "Dobanol" erhältlichen Oxo-Alkohole der Deutschen Shell Chemie Gesellschaft, die ca. 25 Gew.-% an 2-alkylverzweigten Alkoholen aufweisen; andere geeignete Oxo- Alkohole sind unter der Bezeichnung "Synprol" der Imperial Chemical Industries Ltd. erhältliche mit ca. 50 - 70 Gew.- an 2-alkylverzweigten Alkoholen; weitere geeignete Produkte auf Basis von Oxo-Alkoholen sind z.B. verschiedene "Lutensol"-Typen der BASF mit ca. 30 - 35 Gew.-% an verzweigten Alkoholen und einige "Lial"-Typen der Liquichimica S.p.A. mit ca. 60 Gew.-% an verzweigten Alkoholen. Typische bevorzugte Produkte,sind beispielsweise "Dobanol 45-7", das zu mindestens 95 % aus C14/C15-OxoAlkohol mit durchschnittlich 7 Mol Ethylenoxid besteht; ferner "Lutensol AO-8", das ein C13/C15-Oxo-Alkohol- Ethoxylat mit durchschnittlich 8 Mol Ethylenoxid und "Lutensol ON-70", das ein C9/C11-Oxo-Alkohol-Ethoxylat mit durchschhittlich 7 Mol Ethylenoxid darstellt.The polyglycol ethers of the formula I which are suitable according to the invention as constituent a) are derived from natural or synthetic primary fatty alcohols or oxo alcohols. Oxo alcohols are produced by reacting linear olefins with carbon monoxide and hydrogen according to the known oxo process by hydroformylation and subsequent hydrogenation. Commercially available oxo alcohol mixtures which are suitable for the preparation of the surfactant component a) suitable are, for example, the oxo alcohols available from Deutsche Shell Chemie Gesellschaft under the trade name "Dobanol", which have about 25% by weight of 2-alkyl branched alcohols; other suitable oxo alcohols are available under the name "Synprol" from Imperial Chemical Industries Ltd. available with about 50 - 70 wt .-% of 2-alkyl branched alcohols; Other suitable products based on oxo alcohols are, for example, various "Lutensol" types from BASF with approx. 30-35% by weight of branched alcohols and some "Lial" types from Liquichimica SpA with approx. 60% by weight. on branched alcohols. Typical preferred products are, for example, "Dobanol 45-7", which consists of at least 95% C 14 / C 15 oxo alcohol with an average of 7 moles of ethylene oxide; also "Lutensol AO-8", which is a C 13 / C 15 oxo alcohol ethoxylate with an average of 8 moles of ethylene oxide and "Lutensol ON-70", which is a C 9 / C 11 oxo alcohol ethoxylate with average 7 Mole represents ethylene oxide.

Typische von Fettalkoholen abgeleitete Tenside basieren z.B. auf Talgfettalkohol oder den Handelsprodukten "Lorol" mit 8 - 18 Kohlenstoffatomen der Firma Henkel. Typische bevorzugte Produkte sind z.B. "Dehydol TA 5" und "Dehydol TA 14" (Henkel), die Talgfettalkoholpolyglykolether mit 5 bzw. 14 Mol Ethylenoxid pro Mol Alkohol darstellen. Ebenfalls ein bevorzugtes Produkt ist z.B. das Handelsprodukt "Marlipal KF" (Chemische Werke Hüls), ein C10/C12-Fettalkohol-Ethoxylat mit durchschnittlich 6 Mol Ethylenoxid.Typical surfactants derived from fatty alcohols are based, for example, on tallow fatty alcohol or the commercial products "Lorol" with 8-18 carbon atoms from Henkel. Typical preferred products are, for example, "Dehydol TA 5" and "Dehydol TA 14" (Henkel), which are tallow fatty alcohol polyglycol ethers with 5 and 14 moles of ethylene oxide per mole of alcohol. Another preferred product is, for example, the commercial product "Marli p al KF" (Chemische Werke Huls), a C 10 / C 12 fatty alcohol ethoxylate with an average of 6 moles of ethylene oxide.

Weiterhin geeignete und bevorzugte Polyglykolether sind die von Oleylalkohol oder Cetylalkohol abgeleiteten Anlagerungsprodukte mit 5 - 10 Mol Ethylenoxid bzw. technische Gemische aus überwiegend Oleyl- und Cetylalkohol mit 5 - 10 Mol Ethylenoxid, deren Jodzahl zwischen ca. 40 und ca. 60 liegt. Ebenfalls bevorzugt ist das Handelsprodukt "Dehydol LS 4" (Henkel), ein C12/C14-Fettalkohol- Ethoxylat mit ca. 4 Mol Ethylenoxid. Diese Polyglykolether bilden einzeln oder im Gemisch den Bestandteil a) der erfindungsgemäßen Mittel. Sie sind im fertigen Mittel zu 5 - 20 Gew.-%, vorzugsweise zu 7 - 15 Gew.-% enthalten und können ganz oder teilweise durch die als nichtionische Tenside bekannten C8-C15-Alkylaryl-Polyglykolether, wie z.B. Nonylphenol mit ca. 5 bis ca. 15 Mol Ethylenoxid ersetzt werden.Further suitable and preferred polyglycol ethers are the addition products derived from oleyl alcohol or cetyl alcohol with 5-10 moles of ethylene oxide or technical mixtures of predominantly oleyl and cetyl alcohol with 5-10 moles of ethylene oxide, the iodine number of which is between approximately 40 and approximately 60. Also preferred is the commercial product "Dehydol LS 4" (Henkel), a C 12 / C 14 fatty alcohol Ethoxylate with about 4 moles of ethylene oxide. These polyglycol ethers, individually or in a mixture, form component a) of the agents according to the invention. They are contained in the finished agent at 5-20% by weight, preferably at 7-15% by weight, and can be wholly or partly by the C 8 -C 15 alkylaryl polyglycol ethers known as nonionic surfactants, such as nonylphenol with approx 5 to about 15 moles of ethylene oxide are replaced.

Als Bestandteil b) der erfindungsgemäßen Mittel sind Fettsäuremono- oder -diethanolamide mit einem Fettsäurerest mit 12 - 18 Kohlenstoffatomen geeignet. Hierbei können sowohl die Verbindungen mit einer einheitlichen Kohlenstoffanzahl im Fettsäurersst als auch Gemische von Fettsäureethanolamiden mit unterschiedlich langen Fettsäureresten verwendet werden. Ein bevorzugtes Produkt leitet sich von Kokosfettsäure mit einem Anteil von mehr als 50 Gew.-% an C12-Fettsäure, ca. 20 Gew.-% C14-Fettsäure, ca. 10 Gew.-% C16-Fettsäure und einem weiteren Anteil gesättigter und ungesättigter C18-Fettsäure ab. Ein derartiges Produkt ist unter der Bezeichnung "Comperlan 100" (Henkel) im Handel. Ein ebenfalls geeignetes Produkt ist das als "Comperlan KD" (Henkel) im Handel erhältliche Kokosfettsäurediethanolamid. Die Fettsäureethanolamide sind zu 1 - 10 Gew.-%, vorzugsweise zu 2 - 5 Gew.-% in den erfindungsgemäßen Mitteln enthalten.Fatty acid mono- or diethanolamides with a fatty acid residue having 12-18 carbon atoms are suitable as component b) of the agents according to the invention. Both the compounds with a uniform number of carbon atoms in the fatty acid ester and mixtures of fatty acid ethanolamides with differently long fatty acid residues can be used. A preferred product is derived from coconut fatty acid with a proportion of more than 50% by weight of C 12 fatty acid, approx. 20% by weight C 14 fatty acid, approx. 10% by weight C 16 fatty acid and another Share of saturated and unsaturated C 18 fatty acid. Such a product is commercially available under the name "Comperlan 100" (Henkel). Another suitable product is the coconut fatty acid diethanolamide commercially available as "Comperlan KD" (Henkel). The fatty acid ethanolamides are contained in the agents according to the invention to 1-10% by weight, preferably to 2-5% by weight.

Als textilweichmachende Wirkstoffe (Bestandteil c)) eignen sich die quartären Ammoniumverbindungen mit vorzugsweise zwei langkettigen, vorzugsweise gesättigten aliphatischen Resten mit je 14 - 26, vorzugsweise 16 - 20 Kohlenstoffatomen und wenigstens einem quartären Stickstoffatom im Molekül. Die langkettigen aliphatischen Reste können geradkettig oder verzweigt sein und dementsprechend von Fettsäuren hzw. von Fettaminen, Guerbetaminen, oder aus den durch Reduktion von Nitroparaffinen erhältlichen Alkylaminen abstammen. Bei diesen quartären Ammoniumverbindungen handelt es sich insbesondere um Derivate des Ammöniaks, d.h. um die durch Alkylierung von langkettigen .sekundären Aminen erhältlichen quartären Saize, wie z.B. die Verbindungen Distearyldimethylammoniumchlorid bzw. Ditalgalkyldimethylammoniumchlorid, oder um die durch Umsetzung von 1 Mol eines Aminoalkylethylendiamins oder Hydroxyalkylethylendiamins mit 2 Mol einer langkettigen, C14-C26-Fettsäure oder deren Ester erhältlichen Imidazolinverbindungen, die anschließend durch Alkylierung in die quartären Imidazoliniumverbindungen, übergeführt werden. In diesen quartären Ammoniumverbindungen besteht das Anion im allgemeinen aus dem Säurerest, der aus dem bei der Quaternierung verwendeten Alkylierungsmittel entstanden ist. Beispielsweise kommt als Anion daher Chlorid, Bromid, Methylsulfat, Ethylsulfat, Methan-, Ethan- oder Toluolsulfonat, vorzugsweise Chlorid und/oder Methylsulfat in Betracht. Typische bevorzugte Textilweichmacher sind beispielsweise Ditalgalkyldimethylammoniumchlorid (beispielsweise die Handelsprodukte "Präpagen WK" und "Präpagen WKT", Hoechst, "Adogen 442", Ashland) oder Distearyldimethylammoniumchlorid (beispielsweise "Arosurf TA 100", Ashland) und 2-Heptadecyl-1-methyl-1-oleoylamid- ethyl-imidazoliniummethosulfat.The quaternary ammonium compounds with preferably two long-chain, preferably saturated aliphatic radicals each having 14-26, preferably 16-20, carbon atoms and at least one quaternary nitrogen atom in the molecule are suitable as textile-softening active ingredients (component c)). The long-chain aliphatic radicals can be straight-chain or branched and accordingly hzw from fatty acids. from fatty amines, Guerbetamines, or from the alkylamines obtainable by reduction of nitroparaffins. These quaternary ammonium compounds are, in particular, derivatives of Ammöniaks, ie the quaternary salts obtainable by alkylation of long-chain secondary amines, such as the compounds distearyldimethylammonium chloride or ditalgalkyldimethylammonium chloride, or the reaction of 1 mol of an aminoalkylethylenediamine or hydroxyalkylethylenediamine with 2 mol of a long-chain C 14 -C 26 fatty acid or their esters obtainable imidazoline compounds which are subsequently converted into the quaternary imidazolinium compounds by alkylation. In these quaternary ammonium compounds, the anion generally consists of the acid residue which has arisen from the alkylating agent used in the quaternization. For example, chloride, bromide, methyl sulfate, ethyl sulfate, methane, ethane or toluenesulfonate, preferably chloride and / or methyl sulfate, are therefore suitable as anions. Typical preferred fabric softeners are, for example, ditallow alkyldimethylammonium chloride (for example the commercial products "Präpagen WK" and "Präpagen WKT", Hoechst, "Adogen 442", Ashland) or distearyldimethylammonium chloride (for example "Arosurf TA 100", Ashland) and 2-heptadecyl-1-methyl 1-oleoylamid-ethyl-imidazolinium methosulfate.

Die textilweichmachenden Wirkstoffe sind zu 2 - 10 Gew.-%, vorzugsweise 3 - 7 Gew.-% in den erfindungsgemäßen Mitteln enthalten, wobei der textilweichmachende Wirkstoff c) vorzugsweise zu mehr als 25, insbesondere mehr als 30 Gew.-% in der aus dem Polyglykolether a), dem Fettsäureethanolamid b) und dem textilweichmachenden Wirkstoff c) bestehenden Tensidkomponente enthalten ist.The textile-softening active ingredients are present in the agents according to the invention to 2-10% by weight, preferably 3-7% by weight, with the textile-softening active ingredient c) preferably comprising more than 25, in particular more than 30% by weight in the the polyglycol ether a), the fatty acid ethanolamide b) and the fabric softening active ingredient c) is present surfactant component.

Außer den Polyglykolethern, dem Fettsäureethanolamid und quartären Ammoniumverbindungen enthalten die erfindungsgemäßen Mittel 60 - 92 Gew.-% üblicherweise in Waschmitteln vorhandene Zusatzstoffe als weitere Bestandteile. Dies sind beispielsweise Gerüststoffe, Duftstoffe, Farbstoffe sowie Schmutzträger, Enzyme, optische Aufheller oder geringe Mengen Wasser. Zu den Gerüststoffen zählen Calcium fällende oder komplexierende anorganische oder organische Verbindungen. Anorganische fällende bzw. komplexierende Stoffe sind z.B. Pyrophosphat, Triphosphat, höhere Polyphosphate und Metaphosphate und die kationenaustauschenden Alkalialumosilikate, wie sie beispielsweise in der DE-AS 24 12 837 beschrieben sind, insbesondere die Zeolithe A und X. Geeignete organische Verbindungen sind z.B. Polycarbonsäuren, Hydroxycarbonsäuren, Aminocarbonsäuren, Carboxyalkylether, polyanionische polymere Carbonsäuren, Phosphonsäuren. Weitere Gerüstsübstanzen sind schwach sauer, neutral oder alkalisch reagierende anorganische Salze, wie z.B. Bicarbonate, Carbonate, Borate oder Silikate der Alkalien, Alkalisulfate, sowie die Alkalisalze von organischen, nicht kapillaraktiven, 1 - 8 C-Atome enthaltenden Sulfonsäuren, Carbonsäuren und Sulfocarbonsäuren. Vorzugsweise enthalten die erfindungsgemäßen Mittel ca. 10 - 50 Gew.-% Natriumtripolyphosphat, 2 - 10 Gew.-% Wasserglas mit einem Na20 : SiO2 Verhältnis von beispielsweise 1 : 3,4 sowie Natriumsulfat als Gerüststoffe.In addition to the polyglycol ethers, the fatty acid ethanolamide and quaternary ammonium compounds, the agents according to the invention contain 60-92% by weight of additives usually present in detergents as further constituents. These are, for example, builders, fragrances, dyes and dirt carriers, enzymes, optical brighteners or small amounts of water. The builders include calcium-precipitating or complexing inorganic or organic compounds. Inorganic precipitating or complexing substances are, for example, pyrophosphate, triphosphate, higher polyphosphates and metaphosphates and the cation-exchanging alkali alumosilicates, as described, for example, in DE-AS 24 12 837, in particular zeolites A and X. Suitable organic compounds are, for example, polycarboxylic acids, hydroxycarboxylic acids , Amino carboxylic acids, carboxyalkyl ethers, polyanionic polymeric carboxylic acids, phosphonic acids. Other structural substances are weakly acidic, neutral or alkaline inorganic salts, such as bicarbonates, carbonates, borates or silicates of alkalis, alkali sulfates, and the alkali salts of organic, non-capillary-active, 1-8 C-atoms containing sulfonic acids, carboxylic acids and sulfocarboxylic acids. The agents according to the invention preferably contain about 10-50% by weight sodium tripolyphosphate, 2-10% by weight water glass with a Na 2 0: SiO 2 ratio of, for example, 1: 3.4, and sodium sulfate as builders.

Die erfindungsgemäßen Mittel liegen als Pulver vor. Darunter versteht man feinteilige bis körnige oder kugelige Produkte, die gut schüttfähig sind. Sie lassen sich nach allen in der Technik bekannten Verfahren herstellen. So kann man z.B. die pulverförmigen Bestandteile miteinander vermischen und ölige oder pastenförmige Bestandteile, wie z.B. nichtionische Tenside auf das Produkt aufsprühen. Eine andere Herstellungsmöglichkeit besteht darin, daß man die Bestandteile der Mittel mit Wasser zu einem Brei anteigt, den man durch Verdämpfen des Wassers, z.B. auf Walzen oder in Zerstäubungstürmen in ein Pulver überführt. Nach dem /8 Heißtrocknen lassen sich dann noch wärmeempfindliche oder flüchtige Substanzen, wie beispielsweise Duftstoffe einarbeiten.The agents according to the invention are in powder form. These are fine-grained to granular or spherical products that are easy to pour. They can be produced by all methods known in the art. For example, you can mix the powdered components together and spray oily or pasty components, such as nonionic surfactants, onto the product. Another production possibility consists in pasting the constituents of the agents with water to a paste which is converted into a powder by evaporating the water, for example on rollers or in atomizing towers. After / 8 Hot drying can then also incorporate heat-sensitive or volatile substances, such as fragrances.

Die erfindungsgemäßen Waschmittel können zum Waschen und gleichzeitigen Weichmachen von Feinwaschartikeln aus Wolle, synthetischen Fasern wie Polyester, Polyacrylnitril, Polyamid und Mischungen aus Wolle und synthetischen Fasern benutzt werden. Der Wasch- und Weichmachungsvorgang kann entweder in der Waschmaschine oder auch von Hand bei Waschtemperaturen bis zu etwa 60 C, vorzugsweise bis etwa 30 °C erfolgen. Die Anwendungskonzentration der Mittel liegt im allgemeinen bei 1 bis 10 g/l Waschlauge, vorzugsweise bei 2 bis 5 g/l. Die Waschmittel zeichnen sich dadurch aus, daß sie die Textilien einwandfrei reinigen und ihnen gleichzeitig einen angenehmen Griff und antielektrostatische Eigenschaften verleihen. Bei der Wäsche von Hand im Waschbecken bilden sie einen dichten angenehmen Schaum aus, beim Waschen in der Waschmaschine wird kein Überschäumen beobachtet. Außerdem läßt sich der Schaum problemlos ausspülen.The detergents according to the invention can be used for washing and simultaneously softening fine laundry articles made of wool, synthetic fibers such as polyester, polyacrylonitrile, polyamide and mixtures of wool and synthetic fibers. The washing and softening process can take place either in the washing machine or by hand at washing temperatures up to about 60 ° C., preferably up to about 30 ° C. The application concentration of the agents is generally from 1 to 10 g / l of wash liquor, preferably from 2 to 5 g / l. The detergents are characterized by the fact that they clean the textiles perfectly and at the same time give them a pleasant feel and anti-electrostatic properties. When washing by hand in the washbasin, they form a dense, pleasant foam, and no foaming is observed when washing in the washing machine. The foam can also be easily rinsed out.

Die folgenden Beispiele beschreiben erfindungsgemäße Waschmittel.The following examples describe detergents according to the invention.

Beispiel 1example 1

7 Gew.-% Talgfettalkohol mit ca. 14 Mol Ethylenoxid ("Dehydol TA 14", Henkel) 3 Gew.-% Kokosfettsäuremonoethanolamid ("Comperlan 100", Henkel) 5 Gew.-% Distearyldimethylammoniumchlorid, ca. 95%ig ("Arosurf TA 100", Ashland) Rest Gerüststoffe, geringe Mengen Feuchtigkeit.7% by weight tallow fatty alcohol with approx. 14 mol ethylene oxide ("Dehydol TA 14", Henkel) 3% by weight coconut fatty acid monoethanolamide ("Comperlan 100", Henkel) 5% by weight distearyldimethylammonium chloride, approx. 95% ("Arosurf TA 100 ", Ashland) rest builders, small amounts of moisture.

Beispiel 2Example 2

5 Gew.-% C14/C15-Oxoalkohol-Ethoxylat mit ca. 7 Mol Ethylenoxid ("Dobanol 45-7", Shell) 4 Gew.-% C10/C12-Fettalkohol-Ethoxylat mit ca. 6 Mol Ethylenoxid ("Marlipal KF", Chemische Werke Hüls) 4 Gew.-% Kokosfettsäurediethanolamid ("Comperlan KD", Henkel) 5,5 Gew.-% Ditalgalkyldimethylammoniumchlorid, eingesetzt als 75%ige Flüssigkeit, Rest Isopropylalkohol und Wasser ("Präpagen WKT", Hoechst) Rest Gerüststoffe, geringe Mengen Wasser.5% by weight of C 14 / C 15 oxo alcohol ethoxylate with about 7 moles of ethylene oxide ("Dobanol 45-7", Shell) 4% by weight of C 10 / C 12 fatty alcohol ethoxylate with about 6 moles of ethylene oxide ("Marlipal KF", Chemische Werke Hüls) 4% by weight of coconut fatty acid diethanolamide ("Comperlan KD", Henkel) 5.5% by weight of ditallow alkyldimethylammonium chloride, used as a 75% liquid, the rest isopropyl alcohol and water ("Präpagen WKT", Hoechst) rest builders, small amounts of water.

Beispiel 3Example 3

6 Gew.-% Talgfettalkohol mit ca. 5 Mol Ethylenoxid ("Dehydol TA 5", Henkel) 4 Gew.-% C13/C15-Oxoalkohol-Ethoxylat mit ca. 8 Mol Ethylenoxid ("Lutensol A0 8", BASF) 4,5 Gew.-% Kokosfettsäuremonoethanolamid ("Comperlan 100", Henkel) 5 Gew.-% Ditalgalkyldimethylammoniumchlorid, ca. 100%ig ("Präpagen WK", Hoechst) 30 Gew.-% Natriumtripolyphosphat 4,5 Gew.-% Natriumsilikat (Na2O : SiO2 = 1 : 3,35) als wäßrige Lösung 0,5 Gew.-% Parfümöl Rest Natriumsulfat, Wasser.6% by weight tallow fatty alcohol with approx. 5 mol ethylene oxide ("Dehydol TA 5", Henkel) 4% by weight C 13 / C 15 oxo alcohol ethoxylate with approx. 8 mol ethylene oxide ("Lutensol A0 8", BASF) 4.5% by weight of coconut fatty acid monoethanolamide ("Comperlan 100", Henkel) 5% by weight of ditallow alkyldimethylammonium chloride, approx. 100% ("Präpagen WK", Hoechst) 30% by weight of sodium tripolyphosphate, 4.5% by weight of sodium silicate (Na 2 O: SiO 2 = 1: 3.35) as an aqueous solution 0.5% by weight of perfume oil, remainder sodium sulfate, water.

Ein Mittel der vorstehenden Zusammensetzung stellt ein übliche Zusatzstoffe in üblichen Mengen enthaltendes erfindungsgemäßes Waschmittel dar.An agent of the above composition is a detergent according to the invention containing conventional additives in conventional amounts.

Beispiel 4Example 4

4 Gew.-% eines Oleyl-/Cetyl-Fettalkohol-Ethoxylats mit ca. 10 Mol Ethylenoxid und einer Jodzahl des Alkoholgemisches von ca. 50 4 Gew.-% eines C12/C14-Fettalkohol-Ethoxylats mit ca. 4 Mol Ethylenoxid ("Dehydol LS 4", Henkel) 2 Gew.-% Kokosfettsäuremonoethanolamid mit einem Anteil von mehr als 50 Gew.-% C12-Fettsäure im FettSäurerest ("Comperlan 100", Henkel) 4 Gew.-% Ditalgalkyldimethylammoniumchlorid, eingesetzt als 75%ige Paste, Rest Isopropylalkohol und Wasser ("Präpagen WK", Hoechst) .Rest Gerüststoffe, Wasser.4% by weight of an oleyl / cetyl fatty alcohol ethoxylate with approx. 10 mol ethylene oxide and an iodine number of the alcohol mixture of approx. 50 4% by weight of a C 12 / C 14 fatty alcohol ethoxylate with approx. 4 mol ethylene oxide ("Dehydol LS 4", Henkel) 2% by weight of coconut fatty acid monoethanolamide with a proportion of more than 50% by weight of C 12 fatty acid in the fatty acid residue ("Comperlan 100", Henkel) 4% by weight of ditallow alkyldimethylammonium chloride, used as 75 % paste, remainder isopropyl alcohol and water ("Präpagen WK", Hoechst). Remainder builders, water.

Beispiel 5Example 5

4 Gew.-% eines Nonylphenolpolyglykolethers mit ca. 6,5 Mol Ethylenoxid ("Dehydrophen 65", Henkel) Gew.-% eines C12/C14-Fettalkohol-Ethoxylats mit ca. 4 Mol Ethylenoxid ("Dehydol LS 4", Henkel) 3 Gew.-% Kokosfettsäuremonoethanolamid ("Comperlan 100", Henkel) 4,5 Gew.-% 2-Heptadecyl-1-methyl-1-oleoylamid-ethyl- imidazoliniummethosulfat Rest Gerüststoffe, Wasser.4% by weight of a nonylphenol polyglycol ether with about 6.5 mol of ethylene oxide ("Dehydrophen 65", Henkel)% by weight of a C 12 / C 14 fatty alcohol ethoxylate with about 4 mol of ethylene oxide ("Dehydol LS 4", Henkel) 3% by weight of coconut fatty acid monoethanolamide ("Comperlan 100", Henkel) 4.5% by weight of 2-heptadecyl-1-methyl-1-oleoylamid-ethyl-imidazolinium methosulfate, rest of builders, water.

Die in den Beispielen 1 - 5 aufgeführten erfindungsgemäßen-Waschmittel erwiesen sich bei der Wäsche von Feintextilien aus Wolle, Polyacrylnitril oder Wolle/Polyacrylnitril-Gemischen, sowie Polyamid/Baumwolle-Gemischen in der Waschmaschine bis 60 °C, vorzugsweise bis etwa 30 °C, und von Hand als Produkte mit einer ausgewogenen Eigenschaftskombination hinsichtlich ihrer Waschkraft, ihrer weichmachenden Wirkung und ihres Schäumverhaltens.The detergents according to the invention listed in Examples 1-5 were found to wash fine textiles made of wool, polyacrylonitrile or wool / polyacrylonitrile mixtures, as well as polyamide / cotton mixtures in the washing machine up to 60 ° C, preferably up to about 30 ° C, and by hand as products with a balanced combination of properties with regard to their washing power, their softening effect and their foaming behavior.

Claims (5)

1. Pulverförmiges, weichmachendes Waschmittel für Feinwasch-Textilien auf der Basis von nichtionischen Tensiden mit einem Gehalt an quartären Ammoniumverbindungen, dadurch gekennzeichnet, daß es a) 5 - 20 Gew.-% eines aliphatischen Polyglykolethers oder eines Gemisches von mehreren Polyglykolethern der Formel
Figure imgb0002
in der R1 eine geradkettige Alkyl- oder Alkenylgruppe mit 8 - 20 Kohlenstoffatomen, R2 Wasserstoff oder eine C1-C4-Alkylgruppe und n einen Wert von 2 - 20 bedeuten, und/ oder eines C8-C15-Alkylarylpolyglykolethers mit 3 - 15 Ethoxyeinheiten, b) 1 - 10 Gew.-% eines C12-C18-Fettsäureethanolamids, c) 2 - 10 Gew.-% eines textilweichmachenden quartären Ammoniumsalzes, ausgewählt aus den Derivaten des Ammoniaks und/oder des Imidazelins mit vorzugsweise 2 langkettigen aliphatischen Resten im Molekül, d) 60 - 92 Gew.-% übliche Bestandteile eines Feinwaschmittels enthält. 1. Powdery, softening detergent for delicates based on nonionic surfactants containing quaternary ammonium compounds, characterized in that it a) 5 - 20 wt .-% of an aliphatic polyglycol ether or a mixture of several polyglycol ethers of the formula
Figure imgb0002
 in which R 1 is a straight-chain alkyl or alkenyl group with 8-20 carbon atoms, R 2 is hydrogen or a C 1 -C 4 -alkyl group and n is a value of 2 - 20, and / or a C 8 -C 15 -alkylarylpolyglycol ether with 3 - 15 ethoxy units, b) 1-10% by weight of a C 12 -C 18 fatty acid ethanol amide, c) 2-10% by weight of a textile-softening quaternary ammonium salt, selected from the derivatives of ammonia and / or imidazeline with preferably 2 long-chain aliphatic radicals in the molecule, d) contains 60-92% by weight of conventional components of a mild detergent. 2. Mittel nach Anspruch 1, dadurch gekennzeichnet, daß es a) 7 - 15 Gew.-% Polyglykolether der Formel I, b) 2 - 5 Gew.-% Fettsäureethanolamid, c) 3 - 7 Gew.-% textilweichmachendes quartäres Ammoniumsalz enthält. 2. Composition according to claim 1, characterized in that it a) 7-15% by weight of polyglycol ether of the formula I, b) 2-5% by weight of fatty acid ethanolamide, c) 3 - 7 wt .-% textile softening quaternary ammonium salt. 3. Mittel nach Anspruch 1 und 2, dadurch gekennzeichnet, daß es Bestandteil c) zu mehr als 25 Gew.-%, vorzugsweise mehr als 30 Gew.-%, bezogen auf die aus den Bestandteilen a), b) und c) bestehende Tensidkomponente enthält.3. Composition according to claim 1 and 2, characterized in that it contains component c) to more than 25 wt .-%, preferably more than 30 wt .-%, based on those consisting of components a), b) and c) Contains surfactant component. 4. Mittel nach Anspruch 1 bis 3, dadurch gekennzeichnet, daß es a) 3 - 6 Gew.-% eines Anlagerungsproduktes eines aus Oleyl- und Cetylalkohol bestehenden Fettalkoholgemisches mit ca. 10 Mol Ethylenoxid und 3 - 6 Gew.-% eines Anlagerungsproduktes eines C12/ C14-Fettalkoholgemisches mit ca. 4 Mol Ethylenoxid b) 2 - 4 Gew.-% eines Kokosfettsäuremono- oder -diethanolamids c) 3 - 6 Gew.-% eines quartären Ammoniumsalzes mit 2 langkettigen aliphatischen Resten im Molekül, das sich von Ammoniak ableitet und dessen Anion aus der Chlorid, Bromid, Methylsulfat, Ethylsulfat, Methan-, Ethan- oder Toluolsulfonat umfassenden Gruppe ausgewählt ist, d) 78 - 89 Gew.-% übliche Bestandteile eines Fein- waschmittels enthält. 4. Composition according to claim 1 to 3, characterized in that it a) 3-6% by weight of an adduct of a fatty alcohol mixture consisting of oleyl and cetyl alcohol with about 10 moles of ethylene oxide and 3-6% by weight of an adduct of a C 12 / C 14 fatty alcohol mixture with about 4 moles of ethylene oxide b) 2-4% by weight of a coconut fatty acid mono- or diethanolamide c) 3-6% by weight of a quaternary ammonium salt with 2 long-chain aliphatic radicals in the molecule which is derived from ammonia and whose anion is selected from the group comprising chloride, bromide, methyl sulfate, ethyl sulfate, methane, ethane or toluenesulfonate, d) contains 78-89% by weight of customary components of a mild detergent. 5. Mittel nach Anspruch 1 bis 4, dadurch gekennzeichnet, daß es aus a) 4,0 Gew.-% eines Anlagerungsproduktes eines aus Oleyl- und Cetylalkohol bestehenden Fettalkoholgemisches der Jodzahl 50 mit ca. 10 Mol Ethylenoxid und. 4,0 Gew.-% eines Anlagerungsproduktes eines C12/ C14-Fettalkoholgemisches mit ca. 4 Mol Ethylenoxid b) 2,0 Gew.-% Kokosfettsäuremonoethanolamid c) 4,0 Gew.-% Ditalgalkyldimethylammoniumchlorid d) 4,5 Gew.-% Natriumsilikat (Na2O : SiO2 = 1 : 3,4) 30,0 Gew.-% Natriumtripolyphosphat 41,5 Gew.-% Natriumsulfat 10,0 Gew.-% Wasser besteht. 5. Composition according to claim 1 to 4, characterized in that it consists of a) 4.0 wt .-% of an adduct of a le from O yl and cetyl alcohol existing fatty alcohol mixture of iodine value 50 with about 10 moles of ethylene oxide and. 4.0% by weight of an adduct of a C 12 / C 14 fatty alcohol mixture with about 4 moles of ethylene oxide b) 2.0% by weight of coconut fatty acid monoethanolamide c) 4.0% by weight of ditallow alkyldimethylammonium chloride d ) 4.5% by weight sodium silicate (Na 2 O: SiO 2 = 1: 3.4) 30.0% by weight sodium tripolyphosphate 41.5% by weight sodium sulfate 10.0% by weight water.
EP80102333A 1979-05-07 1980-04-30 Washing agent for textiles Withdrawn EP0018630A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0044003A1 (en) * 1980-07-10 1982-01-20 Henkel Kommanditgesellschaft auf Aktien Liquid washing agent with a content of discolouration inhibiting additives
EP0084411B1 (en) * 1982-01-07 1985-09-04 Albright &amp; Wilson Limited Composition and method for cleaning hydrocarbon oil from hard surfaces
FR2569717A1 (en) * 1984-09-04 1986-03-07 Colgate Palmolive Co Laundry softener-detergent compsns.
US4623471A (en) * 1984-03-31 1986-11-18 Henkel Kommanditgesellschaft Auf Aktien Aqueous textile washing compositions
EP0547723A1 (en) * 1991-12-18 1993-06-23 Colgate-Palmolive Company Free-flowing powder fabric softening composition and process for its manufacture
EP0547722A1 (en) * 1991-12-18 1993-06-23 Colgate-Palmolive Company Free-flowing powder fabric softening composition and process for its manufacture

Citations (3)

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Publication number Priority date Publication date Assignee Title
DE2529444A1 (en) * 1975-07-02 1977-01-27 Exquisit Kosmetik Gmbh LIQUID DETERGENT
DE2609807A1 (en) * 1976-03-10 1977-09-15 Exquisit Kosmetik Gmbh Washing and rinsing composition for softening textiles - nonionic surfactant, softening agent and polyglycol difatty acid ester
EP0000595A1 (en) * 1977-06-29 1979-02-07 THE PROCTER &amp; GAMBLE COMPANY Low-phosphate detergent composition for fabric washing

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2529444A1 (en) * 1975-07-02 1977-01-27 Exquisit Kosmetik Gmbh LIQUID DETERGENT
DE2609807A1 (en) * 1976-03-10 1977-09-15 Exquisit Kosmetik Gmbh Washing and rinsing composition for softening textiles - nonionic surfactant, softening agent and polyglycol difatty acid ester
EP0000595A1 (en) * 1977-06-29 1979-02-07 THE PROCTER &amp; GAMBLE COMPANY Low-phosphate detergent composition for fabric washing

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0044003A1 (en) * 1980-07-10 1982-01-20 Henkel Kommanditgesellschaft auf Aktien Liquid washing agent with a content of discolouration inhibiting additives
EP0084411B1 (en) * 1982-01-07 1985-09-04 Albright &amp; Wilson Limited Composition and method for cleaning hydrocarbon oil from hard surfaces
US4623471A (en) * 1984-03-31 1986-11-18 Henkel Kommanditgesellschaft Auf Aktien Aqueous textile washing compositions
FR2569717A1 (en) * 1984-09-04 1986-03-07 Colgate Palmolive Co Laundry softener-detergent compsns.
EP0547723A1 (en) * 1991-12-18 1993-06-23 Colgate-Palmolive Company Free-flowing powder fabric softening composition and process for its manufacture
EP0547722A1 (en) * 1991-12-18 1993-06-23 Colgate-Palmolive Company Free-flowing powder fabric softening composition and process for its manufacture
GR1001506B (en) * 1991-12-18 1994-02-28 Colgate Palmolive Co Free-flowing powder fabric softening composition and process for its manufacture.
TR26894A (en) * 1991-12-18 1994-08-22 Colgate Palmolive Co Free-flow dust fabric softener composition and process for manufacturing.
AU662780B2 (en) * 1991-12-18 1995-09-14 Colgate-Palmolive Company, The Free-flowing powder fabric softening composition and process for its manufacture

Also Published As

Publication number Publication date
BR8002782A (en) 1980-12-16
DE2918364A1 (en) 1980-11-20

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