EP0000879A1 - Process for the preparation of aromatic carbonic acid esters - Google Patents
Process for the preparation of aromatic carbonic acid esters Download PDFInfo
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- EP0000879A1 EP0000879A1 EP78100570A EP78100570A EP0000879A1 EP 0000879 A1 EP0000879 A1 EP 0000879A1 EP 78100570 A EP78100570 A EP 78100570A EP 78100570 A EP78100570 A EP 78100570A EP 0000879 A1 EP0000879 A1 EP 0000879A1
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C68/00—Preparation of esters of carbonic or haloformic acids
- C07C68/06—Preparation of esters of carbonic or haloformic acids from organic carbonates
Definitions
- the invention relates to a process for the preparation of aromatic carbonic acid esters from aliphatic carbonic acid esters and phenols by transesterification in the presence of organotin compounds.
- transesterification of aliphatic carbonic acid esters with phenols in the presence of strong bases or of alkali compounds is known according to DBP 971 790, 1 020 184, 1 026 958 and 1 031 512.
- Transesterification processes catalyzed in this way have the disadvantage that they are not very selective, so that considerable amounts of carbon dioxide are released in a side reaction.
- DOS 2 528 412 and 2 552 907 describe transesterification processes for the production of aromatic carbonic acid esters, in which Lewis acids, ie transition metal halides or the corresponding acyloxy, alkoxy or aryloxy compounds, are used as catalysts.
- Lewis acids ie transition metal halides or the corresponding acyloxy, alkoxy or aryloxy compounds
- catalysts on Titan asis have the disadvantage that they color the end products strongly red-brown. This coloring is particularly unpleasant if the end products do not have to be purified by recrystallization or distillation, as is the case with polycarbonates, for example.
- the object of the invention was achieved by using organotin compounds as transesterification catalysts.
- the invention therefore relates to processes for the preparation of aromatic carbonic acid esters by transesterification of dialkyl carbonates with phenols with the elimination of alcohols in the presence of catalysts, which are characterized in that organotin compounds are used as catalysts.
- the favorable catalytic action of the catalysts according to the invention is surprising since they cannot be called Lewis acids.
- the organotin halogen compounds such as dibutyltin dichloride or dioctyltin dichloride, in which a formal relationship to typical Lewis acids such as aluminum trichloride or titanium tetrachloride could most likely be assigned, are completely ineffective.
- the organotin compounds used according to the invention may therefore not contain any direct tin-halogen compound.
- organotin compounds for example include trimethyltin, Triäthylzinnbenzoat, tributyltin acetate, triphenyltin acetate, dibutyltin diacetate, dibutyltin dilaurate, dioctyltin dilaurate, Dibutylzinnadipinat, Methoxytributylzinn, Methoxytriphenylzinn, Phenoxytriäthylzinn, dimethoxydibutyltin, Dimethylzinnglykolat, Diäthoxydibutylzinn, Diphenoxydibutylzinn, Dimethoxydiphenylzinn, Triäthylzinnhydroxid, triphenyltin hydroxide, Hexaäthylstannoxan , Hexabutylstannoxane, tetrabutyldiphenoxystannoxane, dibutyltin oxide and diocty
- those compounds are used whose vapor pressure is low even at the required reaction temperatures, i.e. those with organometallically bonded alkyl radicals of at least four carbon atoms.
- Preferred dialkyl carbonates are those of the general formula (III) used, in which R 7 is an alkyl radical having C 1 -C 10 .
- Dimethyl carbonate, diethyl carbonate, dipropyl carbonate, diisopropyl carbonate, dibutyl carbonate, dioctyl carbonate, diisooctyl carbonate and dicyclohexyl carbonate can preferably be used.
- Suitable phenols are preferably those of the general formula (IV) in which X is hydrogen, an alkyl radical with C1-C3, a halogen atom, preferably chlorine, or a nitro group and n is 1 or 2.
- Particularly preferred phenols for the process according to the invention are phenol, o, m, p-cresol, o, m, p-chlorophenol, o, m, p-ethylphenol, o, m, p-propylphenol, o, m, p -Nitrophenol, 2,6-dimethylphenol, 2,4-dimethylphenol and 3,4-dimethylphenol are used.
- bisphenols such as dihydroxydiarylalkanes with C 1 -C 4 in the alkyl radical, for example bisphenol A, can also be used. They are not split under the process conditions and can thus be converted directly into polycarbonates. Based on pure raw materials, these are almost colorless and do not require any additional cleaning steps.
- the catalysts are used in concentrations of about 0.001-20% by weight, based on the total amount of the reaction mixture.
- the weight ratio of dialkyl carbonate: phenol can vary within wide limits and is between about 1:99 and 99: 1, preferably 1: 9 and 9: 1. It depends on this ratio whether alkylphenyl carbonate or diaryl carbonate predominates in the end product.
- the alkylaryl carbonate formed in addition to diaryl carbonate can be separated off by distillation without difficulty and either reacted with fresh phenol or, after the diaryl carbonate has been separated off, can react further with the phencl still present.
- the reaction temperatures are preferably in the range from 50 to 250 ° C., particularly preferably in the range from 100 to 200 ° C. It is advantageous to work at a pressure of 1 torr to 20 atm abs, preferably 1-5 atm.
- Solvents such as aliphatic or aromatic hydrocarbons can also be used.
- a preferred procedure is to bring the transesterification mixture to the desired reaction temperature in a longer column, while the alcohol is removed overhead, to the extent that it is released in the reaction mixture, if appropriate with the aid of an inert gas stream.
- excess dialkyl carbonate is passed through a melt of the phenol to be reacted, while a mixture consisting of the alcohol and dialkyl carbonate is continuously distilled off.
- the components can be separated in a separate step using customary methods.
- the process products can be used as starting materials for the production of polycarbonates by known processes or of crop protection agents.
- the yield based on the converted phenol, is thus 96% of theory. Th. During the reaction, 0.014 mol of CO 2 are split off. This corresponds to a loss of carbonate of 1.05%.
- the reaction product is colored deep red-brown before distillation. Even after the distillation, the diphenyl carbonate still shows a red-brown tinge.
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Abstract
Description
Die Erfindung betrifft ein Verfahren zur Herstellung aromatischer Kohlensäureester aus aliphatischen Kohlensäureestern und Phenolen durch Umesterung in Gegenwart von zinnorganischen Verbindungen.The invention relates to a process for the preparation of aromatic carbonic acid esters from aliphatic carbonic acid esters and phenols by transesterification in the presence of organotin compounds.
Die Umesterung aliphatischer Kohlensäureester mit Phenolen in Anwesenheit starker Basen bzw. von Alkaliverbindungen ist nach DBP 971 790, 1 020 184, 1 026 958 und 1 031 512 bekannt. Derart katalysierte Umesterungsverfahren haben den Nachteil, wenig selektiv zu sein, so daß in einer Nebenreaktion erhebliche Mengen an Kohlendioxid freigesetzt werden.The transesterification of aliphatic carbonic acid esters with phenols in the presence of strong bases or of alkali compounds is known according to DBP 971 790, 1 020 184, 1 026 958 and 1 031 512. Transesterification processes catalyzed in this way have the disadvantage that they are not very selective, so that considerable amounts of carbon dioxide are released in a side reaction.
In den DOS 2 528 412 und 2 552 907 sind Umesterungsverfahren zur Herstellung aromatischer Kohlensäureester beschrieben, bei denen als Katalysatoren Lewissäuren, d.h. Ubergangsmetallhalogenide oder die entsprechenden Acyloxy-, Alkoxy- oder Aryloxy-Verbindungen verwendet werden. Von den Verbindungen der Elemente Al, Ti, U, V, Zn, Fe und Sn sind nur die des Titans von wirtschaftlichem Interesse, da nur diese hinreichend wirksam und selektiv sind. Diese Katalysatoren auf Titan asis haben aber den Nachteil, daß sie die Endprodukte stark rot-braun färben. Diese Färbung tritt besonders dann unangenehm in Erscheinung, wenn sich die Endprodukte nicht ourch Umkristalliseren oder Destillieren reinigen assen, wie das z.B. bei Polycarbonaten der Fall ist.DOS 2 528 412 and 2 552 907 describe transesterification processes for the production of aromatic carbonic acid esters, in which Lewis acids, ie transition metal halides or the corresponding acyloxy, alkoxy or aryloxy compounds, are used as catalysts. Of the compounds of the elements Al, Ti, U, V, Zn, Fe and Sn, only those of titanium are of economic interest, since only these are sufficiently effective and selective. This However, catalysts on Titan asis have the disadvantage that they color the end products strongly red-brown. This coloring is particularly unpleasant if the end products do not have to be purified by recrystallization or distillation, as is the case with polycarbonates, for example.
Es war deshalb die Aufgabe gestellt, Katalysatoren zu finden, die neben einer zumindest den Titankatalysatoren gleichwertigen Umesterungswirksamkeit und Selektivität auch den Vorteil aufweisen, die Endprodukte nicht wesentlich zu verfärben.It was therefore the task of finding catalysts which, in addition to a transesterification activity and selectivity at least equivalent to the titanium catalysts, also have the advantage of not significantly discoloring the end products.
Die erfindungsgemäße Lösung der Aufgabe gelang durch die Verwendung zinnorganischer Verbindungen als Umesterungskatalysatoren. Gegenstand der Erfindung sind daher Verfahren zur Herstellung von aromatischen Kohlesäureester durch Umesterung von Dialkylcarbonaten mit Phenolen unter Abspaltung von Alkoholen in Gegenwart von Katalysatoren, die dadurch gekennzeichnet sind, daß als Katalysatoren zinnorganische Verbindungen verwendet werden.The object of the invention was achieved by using organotin compounds as transesterification catalysts. The invention therefore relates to processes for the preparation of aromatic carbonic acid esters by transesterification of dialkyl carbonates with phenols with the elimination of alcohols in the presence of catalysts, which are characterized in that organotin compounds are used as catalysts.
Die günstige katalytische Wirkung der erfindungsgemäßen Katalysatoren ist überraschend, da man sie nicht als Lewissäuren bezeichnen kann. Ganz im Gegenteil ist festzustellen, daß gerade die zinnorganischen Halogenverbindungen wie Dibutylzinndichlorid oder Dioctylzinndichlorid, bei denen noch am ehesten eine formale Verwandtschaft zu typischen Lewissäuren wie Aluminiumtrichlorid oder Titantetrachlorid zugerechnet werden könnte, völlig unwirksam sind. Die erfindungsgemäß verwendeten zinnorganischen Verbindungen dürfen daher keine direkte Zinn-Halogen-Verbindung enthalten.The favorable catalytic action of the catalysts according to the invention is surprising since they cannot be called Lewis acids. On the contrary, it can be stated that the organotin halogen compounds such as dibutyltin dichloride or dioctyltin dichloride, in which a formal relationship to typical Lewis acids such as aluminum trichloride or titanium tetrachloride could most likely be assigned, are completely ineffective. The organotin compounds used according to the invention may therefore not contain any direct tin-halogen compound.
Die Wirksamkeit der erfindungsgemäßen Katalysatoren,gemessen an der Geschwindigkeit der Alkoholabspaltung, unterscheidet sich praktisch nicht von der von Verbindungen des Titans wie z.B. des Tetrabutyltitanats.Doch sind Vorteile darin zu sehen, daß in den beiden Verfahrensprodukten Alkylarylcarbonat und Diarylcarbonat das Verhältnis zugunsten des letzteren verschoben ist und unter vergleichbaren Bedingungen eine etwa um die Hälfte geringere Kohlendioxidabspaltung beobachtet wird.The effectiveness of the catalysts according to the invention, measured in terms of the rate of alcohol splitting, practically does not differ from that of compounds of titanium such as e.g. However, advantages can be seen in the fact that the ratio in the two process products alkylaryl carbonate and diaryl carbonate is shifted in favor of the latter and that, under comparable conditions, an approximately half reduction in carbon dioxide elimination is observed.
Für das erfindungsgemäße Verfahren eignen sich besonders zinnorganische Verbindungen der allgemeinen Formel (I)
- Y für einen Rest
- R 1 die Bedeutung von R2 hat, und
- x eine ganze Zahl von 1 - 3 bedeutet, oder Dialkylzinnoxide mit jeweils 1-12 C-Atome im Alkylrest oder zinnorganische Verbindungen der allgemeinen Formel (II)
- R3 und R4 gleich oder verschieden, die oben angegebene Bedeutunq von R 2 haben,
- und R die Bedeutung von R2 hat oder für einen Rest OR 6 steht, in dem R 6 die Bedeutung von R2 hat.
- Y for a rest
- R 1 has the meaning of R 2 , and
- x is an integer from 1 to 3, or dialkyltin oxides each having 1-12 C atoms in the alkyl radical or organotin compounds of the general formula (II)
- R 3 and R 4 are the same or different and have the meaning of R 2 given above,
- and R has the meaning of R 2 or represents a radical O R 6 in which R 6 has the meaning of R 2 .
Für das erfindungsgemäße Verfahren sind ganz besonders geeignete zinnorganische Verbindungen wie z.B.: Trimethylzinnacetat, Triäthylzinnbenzoat, Tributylzinnacetat, Triphenylzinnacetat, Dibutylzinndiacetat, Dibutylzinndilaurat, Dioctylzinndilaurat, Dibutylzinnadipinat, Methoxytributylzinn, Methoxytriphenylzinn, Phenoxytriäthylzinn, Dimethoxydibutylzinn, Dimethylzinnglykolat, Diäthoxydibutylzinn, Diphenoxydibutylzinn, Dimethoxydiphenylzinn, Triäthylzinnhydroxid, Triphenylzinnhydroxid, Hexaäthylstannoxan, Hexabutylstannoxan, Tetrabutyldiphenoxystannoxan, Dibutylzinnoxid und Dioctylzinnoxid.For the inventive process particularly suitable organotin compounds, for example include trimethyltin, Triäthylzinnbenzoat, tributyltin acetate, triphenyltin acetate, dibutyltin diacetate, dibutyltin dilaurate, dioctyltin dilaurate, Dibutylzinnadipinat, Methoxytributylzinn, Methoxytriphenylzinn, Phenoxytriäthylzinn, dimethoxydibutyltin, Dimethylzinnglykolat, Diäthoxydibutylzinn, Diphenoxydibutylzinn, Dimethoxydiphenylzinn, Triäthylzinnhydroxid, triphenyltin hydroxide, Hexaäthylstannoxan , Hexabutylstannoxane, tetrabutyldiphenoxystannoxane, dibutyltin oxide and dioctyltin oxide.
Vorzugsweise werden solche Verbindungen verwendet, deren Dampfdruck auch bei den erforderlichen Reaktionstemperaturen niedrig ist, d.h. solche mit metallorganisch gebundenen Alkylresten von mindestens vier Kohlenstoffatomen.Preferably those compounds are used whose vapor pressure is low even at the required reaction temperatures, i.e. those with organometallically bonded alkyl radicals of at least four carbon atoms.
Als Dialkylcarbonate werden vorzugsweise solche der allgemeinen Formel (III)
Als Phenole eignen sich vorzugsweise solche der allgemeinen Formel (IV)
Anstelle der einwertigen Phenole können auch Bisphenole wie Dihydroxydiarylalkane mit C1-C4 im Alkylrest, so z.B. Bisphenol A, eingesetzt werden. Sie werden unter den Verfahrenbedingungen nicht gespalten und können so unmittelbar in Polycarbonate übergeführt werden. Diese sind, geht man von reinen Ausgangsstoffen aus, nahezu farblos und bedürfen keiner zusätzlichen Reinigungsschritte.Instead of the monohydric phenols, bisphenols such as dihydroxydiarylalkanes with C 1 -C 4 in the alkyl radical, for example bisphenol A, can also be used. They are not split under the process conditions and can thus be converted directly into polycarbonates. Based on pure raw materials, these are almost colorless and do not require any additional cleaning steps.
Die Katalysatoren werden in Konzentrationen von etwa 0,001 - 20 Gew.-%, bezogen auf die gesamte Menge des Reaktionsgutes, angewendet. Das Gewichtsverhältnis von Dialkylcarbonat : Phenol kann in weiten Grenzen schwanken und zwischen etwa 1:99 und 99:1, vorzugsweise 1:9 und 9:1 liegen. Von diesem Verhältnis hängt es ab, ob im Endprodukt Alkylphenylcarbonat oder Diarylcarbonat überwiegt.The catalysts are used in concentrations of about 0.001-20% by weight, based on the total amount of the reaction mixture. The weight ratio of dialkyl carbonate: phenol can vary within wide limits and is between about 1:99 and 99: 1, preferably 1: 9 and 9: 1. It depends on this ratio whether alkylphenyl carbonate or diaryl carbonate predominates in the end product.
Ohne Schwierigkeit kann das neben Diarylcarbonat gebildete Alkylarylcarbonat durch Destillation abgetrennt und entweder mit frischem Phenol umgesetzt oder nach Abtrennung des Diarylcarbonats mit dem noch vorhandenen Phencl weiterreagieren.The alkylaryl carbonate formed in addition to diaryl carbonate can be separated off by distillation without difficulty and either reacted with fresh phenol or, after the diaryl carbonate has been separated off, can react further with the phencl still present.
Die Reaktionstemperaturen liegen vorzugsweise im Bereich von 50 - 250°C, besonders bevorzugt im Bereich von 100 - 200°C. Vorteilhafterweise wird bei einem Druck von 1 Torr bis 20 Atm abs, vorzugsweise 1 - 5 Atm gearbeitet.The reaction temperatures are preferably in the range from 50 to 250 ° C., particularly preferably in the range from 100 to 200 ° C. It is advantageous to work at a pressure of 1 torr to 20 atm abs, preferably 1-5 atm.
Lösungsmittel wie aliphatische oder aromatische Kohlenwasserstoffe können mitverwendet werden.Solvents such as aliphatic or aromatic hydrocarbons can also be used.
Eine bevorzugte Verfahrensweise besteht darin, das Umesterungsgemisch an einer längeren Kolonne auf die gewünschte Reaktionstemperatur zu bringen, während der Alkohol über Kopf in dem Maße, wie er im Reaktionsgut freigesetzt wird, gegebenenfalls mit Hilfe eines inerten Gasstroms abgetrennt wird.A preferred procedure is to bring the transesterification mixture to the desired reaction temperature in a longer column, while the alcohol is removed overhead, to the extent that it is released in the reaction mixture, if appropriate with the aid of an inert gas stream.
In einer anderen Verfahrensvariante wird überschüssiges Dialkylcarbonat durch eine Schmelze des umzusetzenden Phenols geleitet, während ein aus dem Alkohol und Dialkylcarbonat bestehendes Gemisch laufend abdestilliert. Die Trennung der Komponenten kann in einem separaten Schritt nach üblichen Methoden erfolgen.In another process variant, excess dialkyl carbonate is passed through a melt of the phenol to be reacted, while a mixture consisting of the alcohol and dialkyl carbonate is continuously distilled off. The components can be separated in a separate step using customary methods.
Die Ergebnisse beider Verfahrensweisen unterscheiden sich nicht wesentlich.The results of both procedures do not differ significantly.
Die Verfahrensprodukte können als Ausgangsstoffe zur Herstellung von Polycarbonaten nach bekannten Verfahren oder von Pflanzenschutzmitteln verwendet werden.The process products can be used as starting materials for the production of polycarbonates by known processes or of crop protection agents.
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a) In einer 2,9 m hohen, mit Glasringen beschickten verspiegelten Füllkörperkolonne werden 470 g (5 Mol) Phenol, 90 g (1 Mol) Dimethylcarbonat, 50 g n-Heptan und 5,7 g Diphenoxydibutylzinn zum Sieden erhitzt. Durch Eintropfen von Heptan wird die Innentemperatur bei 1550C gehalten. Ein Gemisch von Methanol und Heptan wird bei 59,5 - 60°C über Kopf destilliert. In dem Maße, wie die Reaktion voranschreitet, wird weiteres Dimethylcarbonat im unteren Kolonnendrittel eingetropft. Insgesamt werden so innerhalb von 30 h 315 g = 3,5 Mol Dimethylcarbonat eingesetzt. Etwa während der Reaktion abgespaltenes Kohlendioxid wird durch einen schwachen Stickstoffstrom in einer mit n-Natronlauge gefüllten Waschflasche absorbiert. Das Reaktionsgut wird über eine 1,1 m hohe Kolonne fraktioniert. Nach einem aus Methanol, Dimethylcarbonat und Heptan bestehenden Vorlauf gehen bei 80 - 87°C/15 Torr 313 g (3,33 Mol) unumgesetztes Phenol, bei 95 - 97°C/13 Torr 118 g (0,78 Mol) Methylphenylcarbonat (
- b) Ein Gemisch von 45,6 g (0,2 Mol) 2,2-Bis-(4-hydroxyphenyl)-propan, 47,1 g (0,22 Mol) des nach a) hergestellten Diphenylcarbonats und 0,008 g Natriummethylat wird langsam bis auf 210° unter 20 Torr erhitzt, wobei. die Hauptmenge des abgespaltenen Phenols abdestilliert. Dann wird der Druck auf 0,2 Torr ermäßigt und die Temperatur während einer Stunde auf 250 C und während zweier weiterer Stunden auf 280°C erhöht, bis die Schmelze so zäh geworden ist, daß sie sich kaum mehr rühren läßt. Beim Abkühlen erhält man einen klaren, farblosen, elastischen Kunststoff, aus dessen Schmelze Formkörper mit hervorragenden Festigkeitseigenschaften hergestellt werden können.b) A mixture of 45.6 g (0.2 mol) of 2,2-bis (4-hydroxyphenyl) propane, 47.1 g (0.22 mol) of the product according to a) Issued diphenyl carbonate and 0.008 g of sodium methylate is slowly heated to 210 ° below 20 torr, whereby. the majority of the phenol cleaved off. The pressure is then reduced to 0.2 torr and the temperature is raised to 250.degree. C. for one hour and to 280.degree. C. for another two hours until the melt has become so tough that it can hardly be stirred. When cooling, a clear, colorless, elastic plastic is obtained, from the melt of which molded articles with excellent strength properties can be produced.
An einer 2,3 m hohen verspiegelten Füllkörperkolonne werden 470 g (5 Mol) Phenol, 118 g (1 Mol) Diäthylcarbonat, 200 g Xylol und 4 g Dimethoxydibutylzinn zum Sieden erhitzt. Über Kopf geht bei 78 - 80°C Äthanol über. In den unteren Kolonnenteil wird so viel Diäthylcarbonat eingetropft, daß die Innentemperatur bei 157 - 158°C gehalten wird. Insgesamt werden im Laufe von 28 h 2,5 Mol Diäthylcarbonat eingebracht, während 1,8 Mol Äthanol abdestilliert werden. Ein schwacher Stickstoffstrom führt das Abgas durch eine mit n-Natronlauge beschickte Waschflasche. Das Reaktionsgut wird über eine 1 m Kolonne fraktioniert. Nach Abdestillieren von Xylol und nichtumgesetztem Diäthylcarbonat gehen bei 76 - 80°C/13 Torr 302 g Phenol über. Der Rückstand weist eine schwach graue Färbung auf. Bei 102 - 107°C/12 Torr destillieren Äthylphenylcarbonat (113 g = 0,68 Mol;
In der gleichen Weise, wie in Beispiel 2 beschrieben, werden 5 Mol Phenol mit 2,5 Mol Diäthylcarbonat unter Verwendung von 4 g Titantetrabutylat als Katalysator innerhalb 28 h bei einer Innentemperatur von 157 - 158°C umgesetzt.In the same way as described in Example 2, 5 mol of phenol are reacted with 2.5 mol of diethyl carbonate using 4 g of titanium tetrabutylate as catalyst within 28 hours at an internal temperature of 157-158 ° C.
298 g Phenol werden zurückgewonnen. 149 g (0,9 Mol) Äthylphenylcarbonat und 92 g (0,43 Mol) Diphenylcarbonat werden erhalten.298 g of phenol are recovered. 149 g (0.9 mol) of ethylphenyl carbonate and 92 g (0.43 mol) of diphenyl carbonate are obtained.
Die Ausbeute, bezogen auf umgesetztes Phenol, beträgt somit 96 % d. Th. Während der Reaktion werden 0,014 Mol C02 abgespalten. Das entspricht einem Verlust an Carbonat von 1,05 %.The yield, based on the converted phenol, is thus 96% of theory. Th. During the reaction, 0.014 mol of CO 2 are split off. This corresponds to a loss of carbonate of 1.05%.
Das Reaktionsprodukt ist vor der Destillation tief rot-braun gefärbt. Auch nach der Destillation weist das Diphenylcarbonat noch einen rot-braunen Stich auf.The reaction product is colored deep red-brown before distillation. Even after the distillation, the diphenyl carbonate still shows a red-brown tinge.
In einer Apparatur wie im Beispiel 2 beschrieben werden 1880 g (20 Mol) Phenol, 300 g (2,54 Mol) Diäthylcarbonat und 20 g Tetrabutyldiphenoxystannoxan unter Überleiten von Stickstoff zum Sieden erhitzt, bis über Kopf bei 78-79,5°C Äthanol abdestilliert. Im unteren Kolonnenteil wird Diäthylcarbonat derart zugesetzt, daß die Sumpftemperatur bei 176°C - 178°C gehalten wird. Im Laufe von 25 h kommen insgesamt 644 g (8 Mol) Diäthylcarbonat zur Anwendung. 253 g (5,5 Mol) Äthanol werden abdestilliert. Nach Abdestillieren des nicht umgesetzten Diäthylcarbonats gehen bei 82 - 88°C/20 Torr 1339 g Phenol, bei 114 - 118oC/ 20 Torr 291 g (1,75 Mol) Äthylphenylcarbonat und 391 g (1,825 Mol) Diphenylcarbonat über. Die Ausbeute, bezogen auf umgesetztes Phenol, beträgt somit 98,5 % d. Th. Im Abgas werden 1,35 g (0,035 Mol) Kohlendioxid nachgewiesen, das entspricht einem Verlust von 1 % Carbonat..In an apparatus as described in Example 2, 1880 g (20 mol) of phenol, 300 g (2.54 mol) of diethyl carbonate and 20 g of tetrabutyldiphenoxystannoxane are passed over heated to boiling by nitrogen until ethanol was distilled off overhead at 78-79.5 ° C. In the lower part of the column, diethyl carbonate is added in such a way that the bottom temperature is kept at 176 ° C.-178 ° C. A total of 644 g (8 mol) of diethyl carbonate are used in the course of 25 hours. 253 g (5.5 mol) of ethanol are distilled off. C / 20 Torr 88 ° 1,339 g of phenol, at 114 - - After distilling off the unreacted Diäthylcarbonats go at 82,118 o C / 20 torr 291 g (1.75 mol) Äthylphenylcarbonat and 391 g (1.825 mol) of diphenyl carbonate over. The yield, based on the converted phenol, is thus 98.5% of theory. Th. 1.35 g (0.035 mol) of carbon dioxide are detected in the exhaust gas, which corresponds to a loss of 1% carbonate.
Claims (5)
verwendet werden.2. The method according to claim 1, characterized in that as organotin compounds of the general formula (I)
be used.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE2736062 | 1977-08-10 | ||
DE19772736062 DE2736062A1 (en) | 1977-08-10 | 1977-08-10 | Process for the preparation of aromatic carbonic acid esters |
Publications (2)
Publication Number | Publication Date |
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EP0000879A1 true EP0000879A1 (en) | 1979-03-07 |
EP0000879B1 EP0000879B1 (en) | 1980-08-20 |
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ID=6016076
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EP78100570A Expired EP0000879B1 (en) | 1977-08-10 | 1978-08-02 | Process for the preparation of aromatic carbonic acid esters |
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EP (1) | EP0000879B1 (en) |
JP (1) | JPS5448733A (en) |
DE (2) | DE2736062A1 (en) |
IT (1) | IT1106869B (en) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0338760A2 (en) * | 1988-04-16 | 1989-10-25 | Mitsui Petrochemical Industries, Ltd. | Process for production of aromatic carbonate compound |
GB2255972A (en) * | 1991-04-12 | 1992-11-25 | Davy Res & Dev Ltd | Production of diaryl carbonates. |
US5344954A (en) * | 1992-08-13 | 1994-09-06 | Bayer Aktiengesellschaft | Process for the preparation of diaryl carbonates |
US5627301A (en) * | 1994-03-29 | 1997-05-06 | Council Of Scientific & Industrial Research | Process for the preparation of mono-alkylcarbonate of bisphenols |
DE102007044033A1 (en) | 2007-09-14 | 2009-03-19 | Bayer Materialscience Ag | Process for the preparation of diaryl or alkylaryl carbonates from dialkyl carbonates |
EP2062868A2 (en) | 2007-11-20 | 2009-05-27 | Bayer MaterialScience AG | Process for purifying diaryl carbonates |
US7629485B2 (en) | 2004-12-21 | 2009-12-08 | Asahi Kasei Chemicals Corporation | Process for producing aromatic carbonate |
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Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4403056A (en) * | 1980-02-11 | 1983-09-06 | Stauffer Chemical Company | Carbonate esters, carbonate ester compositions, and plasticized compositions |
US4410464A (en) * | 1982-03-15 | 1983-10-18 | General Electric Company | Diaryl carbonate process |
US4609501A (en) * | 1983-12-27 | 1986-09-02 | General Electric Company | Process for the preparation of aromatic carbonates |
JPH0662512B2 (en) * | 1986-05-27 | 1994-08-17 | ダイセル化学工業株式会社 | Method for producing diphenyl carbonate |
DE4006520A1 (en) * | 1990-03-02 | 1991-09-05 | Bayer Ag | Di:aryl or alkyl carbonate prodn. from alkyl carbonate - using polymeric hydroxy-stannoxane as ester exchange catalyst for high activity and selectivity |
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US5807964A (en) * | 1997-03-17 | 1998-09-15 | General Electric Company | Process for the preparation of polycarbonates |
US6093842A (en) * | 1998-09-25 | 2000-07-25 | General Electric Company | Process for continuous production of carbonate esters |
WO2005123657A1 (en) | 2004-06-17 | 2005-12-29 | Asahi Kasei Chemicals Corporation | Process for producing aromatic carbonate |
CN100532347C (en) | 2004-07-13 | 2009-08-26 | 旭化成化学株式会社 | Industrial process for producing aromatic carbonate |
EA010033B1 (en) | 2004-07-14 | 2008-06-30 | Асахи Касеи Кемикалз Корпорейшн | Process for producing aromatic carbonate on industrial scale |
US20070255069A1 (en) | 2004-07-14 | 2007-11-01 | Shinsuke Fukuoka | Process for Industrially Producing an Aromatic Carboante |
US7812189B2 (en) | 2004-08-25 | 2010-10-12 | Asahi Kasei Chemicals Corporation | Industrial process for production of high-purity diphenyl carbonate |
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RU2372322C2 (en) | 2004-12-24 | 2009-11-10 | Асахи Касеи Кемикалз Корпорейшн | Method of producing aromatic carbonate |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3714234A (en) * | 1968-07-02 | 1973-01-30 | Rohm & Haas | Catalysts and esterification process |
DE2528412A1 (en) * | 1974-06-25 | 1976-01-08 | Snam Progetti | PROCESS FOR THE PRODUCTION OF AROMATIC CARBONATES |
DE2552907A1 (en) * | 1974-11-25 | 1976-05-26 | Anic Spa | PROCESS FOR THE PRODUCTION OF AROMATIC CARBONATES |
DE2725255A1 (en) * | 1976-06-18 | 1977-12-22 | Nitto Chemical Industry Co Ltd | PROCESS FOR THE PRODUCTION OF DIMETHYLAMINOAETHYLMETHACRYLATE |
-
1977
- 1977-08-10 DE DE19772736062 patent/DE2736062A1/en not_active Withdrawn
-
1978
- 1978-08-02 EP EP78100570A patent/EP0000879B1/en not_active Expired
- 1978-08-02 DE DE7878100570T patent/DE2860235D1/en not_active Expired
- 1978-08-08 IT IT50656/78A patent/IT1106869B/en active
- 1978-08-09 JP JP9628078A patent/JPS5448733A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3714234A (en) * | 1968-07-02 | 1973-01-30 | Rohm & Haas | Catalysts and esterification process |
DE2528412A1 (en) * | 1974-06-25 | 1976-01-08 | Snam Progetti | PROCESS FOR THE PRODUCTION OF AROMATIC CARBONATES |
DE2552907A1 (en) * | 1974-11-25 | 1976-05-26 | Anic Spa | PROCESS FOR THE PRODUCTION OF AROMATIC CARBONATES |
DE2725255A1 (en) * | 1976-06-18 | 1977-12-22 | Nitto Chemical Industry Co Ltd | PROCESS FOR THE PRODUCTION OF DIMETHYLAMINOAETHYLMETHACRYLATE |
Cited By (25)
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EP0338760A2 (en) * | 1988-04-16 | 1989-10-25 | Mitsui Petrochemical Industries, Ltd. | Process for production of aromatic carbonate compound |
EP0338760A3 (en) * | 1988-04-16 | 1990-01-10 | Mitsui Petrochemical Industries, Ltd. | Process for production of aromatic carbonate compound |
AU619823B2 (en) * | 1988-04-16 | 1992-02-06 | Mitsui Chemicals, Inc. | Process for production of aromatic carbonate compound |
GB2255972A (en) * | 1991-04-12 | 1992-11-25 | Davy Res & Dev Ltd | Production of diaryl carbonates. |
US5344954A (en) * | 1992-08-13 | 1994-09-06 | Bayer Aktiengesellschaft | Process for the preparation of diaryl carbonates |
US5627301A (en) * | 1994-03-29 | 1997-05-06 | Council Of Scientific & Industrial Research | Process for the preparation of mono-alkylcarbonate of bisphenols |
US7629485B2 (en) | 2004-12-21 | 2009-12-08 | Asahi Kasei Chemicals Corporation | Process for producing aromatic carbonate |
US8003817B2 (en) | 2007-05-25 | 2011-08-23 | Bayer Materialscience Ag | Process for the preparation of diaryl carbonates or arylalkyl carbonates from dialkyl carbonates |
DE102007044033A1 (en) | 2007-09-14 | 2009-03-19 | Bayer Materialscience Ag | Process for the preparation of diaryl or alkylaryl carbonates from dialkyl carbonates |
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DE102009016853A1 (en) | 2009-04-08 | 2010-10-14 | Bayer Materialscience Ag | Process for the preparation of diaryl or alkylaryl carbonates from dialkyl carbonates |
US8952189B2 (en) | 2009-04-08 | 2015-02-10 | Bayer Materialscience Ag | Process for preparing diaryl carbonates or alkyl aryl carbonates from dialkyl carbonates |
EP2239249A1 (en) | 2009-04-08 | 2010-10-13 | Bayer MaterialScience AG | Method for producing diarylcarbonates or arylalkylcarbonates from dialkylcarbonates |
DE102009053370A1 (en) | 2009-11-14 | 2011-05-19 | Bayer Materialscience Ag | Process for the purification of dialkyl carbonates |
EP2322261A2 (en) | 2009-11-14 | 2011-05-18 | Bayer MaterialScience AG | Method for cleaning dialkyl carbonates |
DE102010042937A1 (en) | 2010-10-08 | 2012-04-12 | Bayer Materialscience Aktiengesellschaft | Process for the preparation of diaryl carbonates from dialkyl carbonates |
EP2457891A1 (en) | 2010-10-08 | 2012-05-30 | Bayer MaterialScience AG | Method for manufacturing diaryl carbonates from dialkyl carbonates |
US8304509B2 (en) | 2010-10-08 | 2012-11-06 | Bayer Intellectual Property Gmbh | Process for preparing diaryl carbonates from dialkyl carbonates |
EP2650278A1 (en) | 2012-04-11 | 2013-10-16 | Bayer MaterialScience AG | Method for manufacturing diaryl carbonates from dialkyl carbonates |
US9284254B2 (en) | 2012-09-20 | 2016-03-15 | Sabic Global Technologies B.V. | Process for the continuous manufacture of aryl alkyl carbonate and/or diaryl carbonate using vapor recompression |
WO2014095776A1 (en) | 2012-12-18 | 2014-06-26 | Bayer Materialscience Ag | Method for producing diaryl carbonate |
US9765012B2 (en) | 2012-12-18 | 2017-09-19 | Covestro Deutschland Ag | Method for producing diaryl carbonate |
Also Published As
Publication number | Publication date |
---|---|
IT1106869B (en) | 1985-11-18 |
DE2736062A1 (en) | 1979-02-22 |
DE2860235D1 (en) | 1980-12-04 |
IT7850656A0 (en) | 1978-08-08 |
EP0000879B1 (en) | 1980-08-20 |
JPS5448733A (en) | 1979-04-17 |
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