EA201791087A1 - Синтез фишера-тропша - Google Patents

Синтез фишера-тропша

Info

Publication number
EA201791087A1
EA201791087A1 EA201791087A EA201791087A EA201791087A1 EA 201791087 A1 EA201791087 A1 EA 201791087A1 EA 201791087 A EA201791087 A EA 201791087A EA 201791087 A EA201791087 A EA 201791087A EA 201791087 A1 EA201791087 A1 EA 201791087A1
Authority
EA
Eurasian Patent Office
Prior art keywords
fischer
synthesis
tropsch
catalyst
moving
Prior art date
Application number
EA201791087A
Other languages
English (en)
Other versions
EA034262B1 (ru
Inventor
Ричард Нил Волш
Жан Луи Гауш
Эндри Вилэльмус Жубер
Вик Альбертус Мариц Ван
Йоханнес Хеннинг Вильджоэн
Марсель Жюрген Краузе
Original Assignee
Сасол Тэкнолоджи Проприэтэри Лимитэд
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Сасол Тэкнолоджи Проприэтэри Лимитэд filed Critical Сасол Тэкнолоджи Проприэтэри Лимитэд
Publication of EA201791087A1 publication Critical patent/EA201791087A1/ru
Publication of EA034262B1 publication Critical patent/EA034262B1/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/10—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B01J38/18—Treating with free oxygen-containing gas with subsequent reactive gas treating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/72—Regeneration or reactivation of catalysts, in general including segregation of diverse particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/045—Regeneration
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/342—Apparatus, reactors with moving solid catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/342—Apparatus, reactors with moving solid catalysts
    • C10G2/343—Apparatus, reactors with moving solid catalysts according to the "moving-bed" method
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/62—Catalyst regeneration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Способ (10) синтеза продуктов (20) Фишера-Тропша предусматривает подачу синтез-газа (30) в реактор (16) синтеза Фишера-Тропша с подвижным слоем, содержащий катализатор синтеза Фишера-Тропша в подвижном слое катализатора, и каталитическое превращение по меньшей мере части синтез-газа (30) в подвижном слое катализатора в продукты (20) Фишера-Тропша. Продукты (20) Фишера-Тропша отводят из реактора (16) синтеза Фишера-Тропша с подвижным слоем. Способ (10) также предусматривает, когда реактор синтеза Фишера-Тропша с подвижным слоем (16) находится в рабочем режиме, извлечение части (50) катализатора синтеза Фишера-Тропша из реактора (16) синтеза Фишера-Тропша с подвижным слоем, добавление реактивированного катализатора (57, 58) синтеза Фишера-Тропша в реактор (16) синтеза Фишера-Тропша с подвижным слоем и добавление свежего катализатора (60, 58) синтеза Фишера-Тропша, в дополнение к реактивированному катализатору (57,58), в реактор (16) синтеза Фишера-Тропша с подвижным слоем.
EA201791087A 2014-11-20 2015-10-26 Синтез фишера-тропша EA034262B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ZA201408551 2014-11-20
PCT/ZA2015/050016 WO2016081956A1 (en) 2014-11-20 2015-10-26 Fischer-tropsch synthesis

Publications (2)

Publication Number Publication Date
EA201791087A1 true EA201791087A1 (ru) 2018-01-31
EA034262B1 EA034262B1 (ru) 2020-01-22

Family

ID=55443346

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201791087A EA034262B1 (ru) 2014-11-20 2015-10-26 Синтез фишера-тропша

Country Status (9)

Country Link
US (1) US10190057B2 (ru)
CN (1) CN107207969B (ru)
AU (1) AU2015349653B2 (ru)
BR (1) BR112017010259B1 (ru)
CA (1) CA2968237C (ru)
EA (1) EA034262B1 (ru)
PE (1) PE20171029A1 (ru)
WO (1) WO2016081956A1 (ru)
ZA (1) ZA201703886B (ru)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107987907B (zh) * 2016-10-26 2020-07-10 中国石油天然气股份有限公司 一种由合成气制备富含甲烷气体的方法
CN107987906A (zh) * 2016-10-26 2018-05-04 中国石油天然气股份有限公司 一种生产甲烷的方法
US20210238484A1 (en) * 2018-06-05 2021-08-05 Sabic Global Technologies B.V. Bulk-metal crystalline transition metal based heterogeneous catalysts, methods of making and uses thereof
US11045793B1 (en) 2020-07-24 2021-06-29 Qatar University Controlled on-pot design of mixed copper/zinc oxides supported aluminum oxide as an efficient catalyst for conversion of syngas to heavy liquid hydrocarbons and alcohols under ambient conditions feasible for the Fischer-Tropsch synthesis

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5260239A (en) 1992-12-18 1993-11-09 Exxon Research & Engineering Company External catalyst rejuvenation system for the hydrocarbon synthesis process
US6201030B1 (en) 1999-09-22 2001-03-13 Syntroleum Corporation Process and apparatus for regenerating a particulate catalyst
US6486220B1 (en) 1999-11-17 2002-11-26 Conoco Inc. Regeneration procedure for Fischer-Tropsch catalyst
US6869978B2 (en) 1999-11-17 2005-03-22 Conocophillips Company Pressure swing catalyst regeneration procedure for Fischer-Tropsch catalyst
US6812179B2 (en) * 2001-04-25 2004-11-02 Syntroleum Corporation Process for regenerating a slurry fischer-tropsch catalyst
US6900151B2 (en) 2001-11-13 2005-05-31 Exxonmobil Research And Engineering Company In situ catalyst regeneration/activation process
US6458857B1 (en) * 2001-11-20 2002-10-01 Exxonmobil Research And Engineering Company Process for maximizing 371° C.+ production in fischer-tropsch process
US6753354B2 (en) 2002-01-29 2004-06-22 Exxonmobil Research And Engineering Company Fischer-tropsch catalyst enhancement
US6800579B2 (en) 2002-01-29 2004-10-05 Exxonmobil Research And Engineering Company Catalyst regeneration
US6838487B1 (en) 2003-12-04 2005-01-04 Rentech, Inc. Method and apparatus for regenerating an iron-based Fischer-Tropsch catalyst
US9295976B2 (en) 2006-08-25 2016-03-29 Nippon Steel Engineering Co., Ltd Catalyst for producing hydrocarbon from syngas, method for producing catalyst, method for regenerating catalyst, and method for producing hydrocarbon from sysngas
US9168501B2 (en) * 2007-09-10 2015-10-27 Res Usa, Llc Commercial Fischer-Tropsch reactor
GB2482905B (en) 2010-08-19 2016-01-13 Gtl F1 Ag Fischer-tropsch catalyst regeneration
PE20140422A1 (es) 2010-10-27 2014-04-01 Sasol Tech Pty Ltd La operacion de procesos que emplean un catalizador que se desactiva a traves del tiempo
GB201107070D0 (en) * 2011-04-27 2011-06-08 Davy Process Techn Ltd FT process using can reactor
FR2998812B1 (fr) 2012-12-05 2014-11-21 IFP Energies Nouvelles Injection d'additif dans une unite de synthese d'hydrocarbures a partir de gaz de synthese permettant de controler et maintenir une concentration homogene en catalyseur

Also Published As

Publication number Publication date
PE20171029A1 (es) 2017-07-17
US10190057B2 (en) 2019-01-29
US20170321126A1 (en) 2017-11-09
BR112017010259A2 (pt) 2018-07-03
BR112017010259B1 (pt) 2020-12-01
CN107207969A (zh) 2017-09-26
WO2016081956A1 (en) 2016-05-26
CN107207969B (zh) 2019-05-07
AU2015349653B2 (en) 2020-06-04
CA2968237C (en) 2021-10-26
CA2968237A1 (en) 2016-05-26
ZA201703886B (en) 2019-02-27
AU2015349653A1 (en) 2017-06-08
EA034262B1 (ru) 2020-01-22

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