EA200700773A1 - COMPLEX METHOD FOR HYDROCARBON SYNTHESIS - Google Patents

COMPLEX METHOD FOR HYDROCARBON SYNTHESIS

Info

Publication number
EA200700773A1
EA200700773A1 EA200700773A EA200700773A EA200700773A1 EA 200700773 A1 EA200700773 A1 EA 200700773A1 EA 200700773 A EA200700773 A EA 200700773A EA 200700773 A EA200700773 A EA 200700773A EA 200700773 A1 EA200700773 A1 EA 200700773A1
Authority
EA
Eurasian Patent Office
Prior art keywords
reforming
zone
partial oxidation
feed stream
hydrocarbon
Prior art date
Application number
EA200700773A
Other languages
Russian (ru)
Inventor
Вильхельмус Йоханнес Фринцискус Схолтен
Тиан Хой Тио
Original Assignee
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Шелл Интернэшнл Рисерч Маатсхаппий Б.В. filed Critical Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Publication of EA200700773A1 publication Critical patent/EA200700773A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0255—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a non-catalytic partial oxidation step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Abstract

Описан способ получения синтез-газа из углеводородного сырья. Способ включает в себя стадии: (i) разделение углеводородного сырья с получением первого потока сырья и второго потока сырья; (ii) каталитический риформинг первого потока сырья по меньшей мере в одной зоне риформинга для того, чтобы получить продукт риформинга; (iii) окисление второго потока сырья по меньшей мере в одной зоне парциального окисления, чтобы получить продукт парциального окисления; (iv) смешивание части или всего продукта риформинга и части или всего продукта парциального окисления, чтобы получить топливный газ (синтез-газ) в зоне смешивания, которая отделена от зоны риформинга и зоны парциального окисления; (v) нагревание зоны (зон) риформинга с помощью топливного газа; и (vi) необязательно, выделение диоксида углерода из охлажденного топливного газа, чтобы получить поток синтез-газа с малым содержанием диоксида углерода. Этот синтез-газ может быть использован для получения углеводородных продуктов, например, в синтезе Фишера-Тропша. В настоящем изобретении разработан комплексный способ получения углеводородных продуктов из углеводородного сырья в углеводородные продукты. Эксплуатация стадии риформинга и стадии парциального окисления по параллельной схеме в отличие от последовательной схемы обеспечивает эффективное средство для улучшения характеристик энергетического баланса на этих двух стадиях. Кроме того, способ согласно изобретению обеспечивает гибкий режим работы, поскольку соотношение Н/СО можно легко регулировать различными способами.A method for producing synthesis gas from hydrocarbon feeds is described. The method includes the steps of: (i) separating a hydrocarbon feedstock to produce a first feed stream and a second feed stream; (ii) catalytic reforming of a first feed stream in at least one reforming zone in order to obtain a reforming product; (iii) oxidizing a second feed stream in at least one partial oxidation zone to obtain a partial oxidation product; (iv) mixing part or all of the reforming product and part or all of the partial oxidation product to obtain fuel gas (synthesis gas) in the mixing zone, which is separated from the reforming zone and the partial oxidation zone; (v) heating the reforming zone (s) with fuel gas; and (vi) optionally, separating carbon dioxide from the chilled fuel gas to obtain a low carbon dioxide synthesis gas stream. This synthesis gas can be used to produce hydrocarbon products, for example, in the Fischer-Tropsch synthesis. The present invention has developed an integrated method for producing hydrocarbon products from hydrocarbon feedstocks to hydrocarbon products. The operation of the reforming stage and the partial oxidation stage in a parallel circuit as opposed to a sequential circuit provides an effective means for improving the energy balance characteristics in these two stages. In addition, the method according to the invention provides a flexible operating mode, since the H / CO ratio can be easily controlled in various ways.

EA200700773A 2004-10-04 2005-10-04 COMPLEX METHOD FOR HYDROCARBON SYNTHESIS EA200700773A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP04256132 2004-10-04
PCT/EP2005/054992 WO2006037782A1 (en) 2004-10-04 2005-10-04 Integrated process for hydrocarbon synthesis

Publications (1)

Publication Number Publication Date
EA200700773A1 true EA200700773A1 (en) 2007-08-31

Family

ID=34930716

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200700773A EA200700773A1 (en) 2004-10-04 2005-10-04 COMPLEX METHOD FOR HYDROCARBON SYNTHESIS

Country Status (5)

Country Link
EP (1) EP1794083A1 (en)
AU (1) AU2005291226B2 (en)
EA (1) EA200700773A1 (en)
MY (1) MY158899A (en)
WO (1) WO2006037782A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EA021509B1 (en) * 2009-03-16 2015-07-30 Сауди Бейсик Индастриз Корпорейшн Process for producing a mixture of aliphatic and aromatic hydrocarbons
GB201115929D0 (en) 2011-09-15 2011-10-26 Johnson Matthey Plc Improved hydrocarbon production process
WO2016016256A1 (en) * 2014-07-29 2016-02-04 Eni S.P.A. Integrated sct-cpo/atr process for the production of synthesis gas
WO2016016257A1 (en) * 2014-07-29 2016-02-04 Eni S.P.A. Integrated sct-cpo/pox process for producing synthesis gas
WO2016016251A1 (en) * 2014-07-29 2016-02-04 Eni S.P.A. Integrated sct-cpo/sr process for producing synthesis gas
US10260005B2 (en) 2016-08-05 2019-04-16 Greyrock Technology LLC Catalysts, related methods and reaction products

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8530272D0 (en) * 1985-12-09 1986-01-22 Shell Int Research Producing liquid hydrocarbons
US5122299A (en) * 1989-12-11 1992-06-16 The M. W. Kellogg Company Autothermal steam reforming process
MY139324A (en) * 2001-06-25 2009-09-30 Shell Int Research Integrated process for hydrocarbon synthesis
US7138001B2 (en) * 2003-03-16 2006-11-21 Kellogg Brown & Root Llc Partial oxidation reformer-reforming exchanger arrangement for hydrogen production
JP4745219B2 (en) * 2003-03-18 2011-08-10 ケロッグ ブラウン アンド ルート，インコーポレイテッド Self-thermal reformer for hydrogen production-reformer exchanger arrangement

Also Published As

Publication number Publication date
AU2005291226A1 (en) 2006-04-13
WO2006037782A1 (en) 2006-04-13
AU2005291226B2 (en) 2009-04-02
EP1794083A1 (en) 2007-06-13
MY158899A (en) 2016-11-30

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