EA200000262A1 - Полимеризация олефинов - Google Patents

Полимеризация олефинов

Info

Publication number
EA200000262A1
EA200000262A1 EA200000262A EA200000262A EA200000262A1 EA 200000262 A1 EA200000262 A1 EA 200000262A1 EA 200000262 A EA200000262 A EA 200000262A EA 200000262 A EA200000262 A EA 200000262A EA 200000262 A1 EA200000262 A1 EA 200000262A1
Authority
EA
Eurasian Patent Office
Prior art keywords
molecular weight
transition metals
olefins
polyolefins
polymerization
Prior art date
Application number
EA200000262A
Other languages
English (en)
Inventor
Эдвард Брайан Кафлин
Самуэл Дэвид Артур
Стивен Дейл Иттел
Original Assignee
Е.И.Дюпон Де Немур Энд Компани
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Е.И.Дюпон Де Немур Энд Компани filed Critical Е.И.Дюпон Де Немур Энд Компани
Publication of EA200000262A1 publication Critical patent/EA200000262A1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Organic Insulating Materials (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Смеси разных полиолефинов или разветвленных полиолефинов можно получить непосредственной, предпочтительно одновременной полимеризацией одного или нескольких полимеризуемых олефинов с использованием систем из двух или более содержащих переходные металлы активных катализаторов полимеризации, один из которых содержит предпочтительно переходные металлы в виде комплексов с выбранными лигандами. Полиолефиновые продукты могут иметь полимеры, которые различаются по молекулярной массе, молекулярно-массовому распределению, кристалличности или другим факторам, и пригодны в качестве формуемых смол и для получения пленок.Международная заявка была опубликована вместе с отчетом о международном поиске.
EA200000262A 1997-08-27 1998-08-26 Полимеризация олефинов EA200000262A1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US5707797P 1997-08-27 1997-08-27
PCT/US1998/017656 WO1999010391A1 (en) 1997-08-27 1998-08-26 Polymerization of olefins

Publications (1)

Publication Number Publication Date
EA200000262A1 true EA200000262A1 (ru) 2000-08-28

Family

ID=22008357

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200000262A EA200000262A1 (ru) 1997-08-27 1998-08-26 Полимеризация олефинов

Country Status (19)

Country Link
US (1) US6114483A (ru)
EP (2) EP1012194B1 (ru)
JP (1) JP2001514272A (ru)
KR (1) KR20010023353A (ru)
CN (1) CN1268144A (ru)
AT (1) ATE279450T1 (ru)
AU (1) AU9205398A (ru)
BR (1) BR9814445A (ru)
CA (1) CA2300085A1 (ru)
DE (1) DE69827020T2 (ru)
EA (1) EA200000262A1 (ru)
HK (1) HK1027365A1 (ru)
HU (1) HUP0002912A3 (ru)
ID (1) ID24427A (ru)
IL (1) IL133986A0 (ru)
NO (1) NO20000867L (ru)
PL (1) PL338979A1 (ru)
TR (1) TR200000533T2 (ru)
WO (1) WO1999010391A1 (ru)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6822062B2 (en) 1997-03-10 2004-11-23 Eastman Chemical Company Supported group 8-10 transition metal olefin polymerization catalysts
US6660677B1 (en) 1997-03-10 2003-12-09 Eastman Chemical Company Supported group 8-10 transition metal olefin polymerization catalysts
KR100541311B1 (ko) * 1998-03-30 2006-01-10 이 아이 듀폰 디 네모아 앤드 캄파니 올레핀의 중합
US6150295A (en) * 1998-03-30 2000-11-21 Phillips Petroleum Company Polymerization catalysts and processes therefor
US6372869B1 (en) * 1998-05-26 2002-04-16 E. I. Du Pont De Nemours And Company Molecular weight control in olefin polymerization
ATE277955T1 (de) * 1998-10-14 2004-10-15 Du Pont Olefinpolymerisation
US6291608B1 (en) * 1998-12-23 2001-09-18 Phillips Petroleum Company Polymerization catalyst system and polymerization process
WO2000050470A2 (en) 1999-02-22 2000-08-31 Eastman Chemical Company Catalysts containing n-pyrrolyl substituted nitrogen donors
US6545108B1 (en) 1999-02-22 2003-04-08 Eastman Chemical Company Catalysts containing N-pyrrolyl substituted nitrogen donors
JP2003510427A (ja) * 1999-09-29 2003-03-18 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー ポリエチレンの製造
US6806332B2 (en) * 1999-11-12 2004-10-19 North Carolina State University Continuous method and apparatus for separating polymer from a high pressure carbon dioxide fluid stream
US6914105B1 (en) 1999-11-12 2005-07-05 North Carolina State University Continuous process for making polymers in carbon dioxide
GB0003363D0 (en) * 2000-02-14 2000-04-05 Bp Chem Int Ltd Polymer blends
US6605677B2 (en) 2000-02-18 2003-08-12 Eastman Chemical Company Olefin polymerization processes using supported catalysts
US7056996B2 (en) 2000-02-18 2006-06-06 E. I. Du Pont De Nemours And Company Productivity catalysts and microstructure control
US6579823B2 (en) 2000-02-18 2003-06-17 Eastman Chemical Company Catalysts containing per-ortho aryl substituted aryl or heteroaryl substituted nitrogen donors
MXPA02011836A (es) * 2000-05-31 2003-05-14 Du Pont Catalizadores para la polimerizacion de olefinas.
US6706891B2 (en) 2000-11-06 2004-03-16 Eastman Chemical Company Process for the preparation of ligands for olefin polymerization catalysts
SE0102764D0 (sv) 2001-08-17 2001-08-17 Astrazeneca Ab Compounds
PL203864B1 (pl) 2001-08-17 2009-11-30 Dow Global Technologies Inc Kompozycje polietylenowe i zastosowanie kompozycji polietylenowej
US6699813B2 (en) 2001-11-07 2004-03-02 Bridgestone Corporation Lanthanide-based catalyst composition for the manufacture of polydienes
GB0226930D0 (en) 2002-11-19 2002-12-24 Astrazeneca Ab Chemical compounds
US7008899B2 (en) * 2003-08-11 2006-03-07 Bridgestone Corporation Lanthanide-based catalyst composition for producing cis-1,4-polydienes
US7094849B2 (en) * 2003-12-15 2006-08-22 Bridgestone Corporation Bulk polymerization process for producing polydienes
TW200600086A (en) 2004-06-05 2006-01-01 Astrazeneca Ab Chemical compound
WO2006040527A1 (en) 2004-10-16 2006-04-20 Astrazeneca Ab Process for making phenoxy benzamide compounds
TW200714597A (en) 2005-05-27 2007-04-16 Astrazeneca Ab Chemical compounds
WO2007005400A2 (en) 2005-07-01 2007-01-11 Albemarle Corporation Aluminoxanate salt compositions having improved stability in aromatic and aliphatic solvents
KR20110084339A (ko) 2005-07-09 2011-07-21 아스트라제네카 아베 당뇨병 치료에 있어 ｇｌｋ 활성화제로서 사용하기 위한 헤테로아릴 벤즈아미드 유도체
TW200738621A (en) 2005-11-28 2007-10-16 Astrazeneca Ab Chemical process
TW200825063A (en) 2006-10-23 2008-06-16 Astrazeneca Ab Chemical compounds
CL2007003061A1 (es) 2006-10-26 2008-08-01 Astrazeneca Ab Compuestos derivados de 3,5-dioxi-benzamida; proceso de preparacion; composicion farmaceutica que comprende a dichos compuestos; y su uso para tratar una enfermedad mediada a traves de glk, tal como la diabetes tipo 2.
AU2007336016A1 (en) 2006-12-21 2008-06-26 Astrazeneca Ab Novel crystalline compound useful as GLK activator
CN102171213A (zh) 2008-08-04 2011-08-31 阿斯利康(瑞典)有限公司 吡唑并[3，4]嘧啶-4-基衍生物及其治疗糖尿病和肥胖症的用途
GB0902434D0 (en) 2009-02-13 2009-04-01 Astrazeneca Ab Chemical process
GB0902406D0 (en) 2009-02-13 2009-04-01 Astrazeneca Ab Crystalline polymorphic form
AR076221A1 (es) * 2009-04-09 2011-05-26 Astrazeneca Ab Derivado de pirazol [4,5-e] pirimidina y su uso para tratar diabetes y obesidad
AR076220A1 (es) 2009-04-09 2011-05-26 Astrazeneca Ab Derivados de pirazol [4,5 - e] pirimidina
EP2643366B1 (en) 2010-11-22 2015-03-25 Albemarle Corporation Activator compositions, their preparation, and their use in catalysis
US10221264B2 (en) 2012-04-27 2019-03-05 W. R. Grace & Co.-Conn. Activator compositions, their preparation, and their use in catalysts
US10961331B2 (en) * 2018-12-19 2021-03-30 Chevron Phillips Chemical Company Lp Ethylene homopolymers with a reverse short chain branch distribution
CN115572341B (zh) * 2022-11-04 2024-04-23 大连万慷工业科技有限公司 一类功能化聚烯烃弹性体及其制备方法

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4921236B1 (ru) * 1970-12-11 1974-05-30
US4937299A (en) * 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
US4530914A (en) * 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
DE3621763A1 (de) * 1986-06-28 1988-01-21 Bayer Ag Verfahren zur herstellung von verzweigtem niederdruckpolyethen, neue niederdruckpolyethene und praeformierte bifunktionelle katalysatoren
DE3703038A1 (de) * 1987-02-03 1988-08-11 Bayer Ag Verzweigte niederdruckpolyolefine und verfahren zu ihrer herstellung
US4966951A (en) * 1988-09-26 1990-10-30 Phillips Petroleum Company High strength linear, low density polyethylene polymerization process
FI85588C (fi) * 1989-06-05 1992-05-11 Neste Oy Foerfarande foer reglering av molekylviktsfoerdelningen och molekylvikten av oligomerisations- eller polymerisationsprodukter av eten.
US5071927A (en) * 1990-10-09 1991-12-10 Phillips Petroleum Company High-temperature slurry polymerization of ethylene
US5137994A (en) * 1991-05-23 1992-08-11 Union Carbide Chemicals & Plastics Technology Corporation Process for the simultaneous trimerization and copolymerization of ethylene
DE59209897D1 (de) * 1991-05-27 2001-04-26 Targor Gmbh Verfahren zur Herstellung von Polyolefinen mit breiter Molmassenverteilung
CA2077744C (en) * 1991-09-30 2003-04-15 Edwar Shoukri Shamshoum Homogeneous-heterogeneous catalyst system for polyolefins
US5562958A (en) * 1991-10-15 1996-10-08 The Dow Chemical Company Packaging and wrapping film
JPH05194636A (ja) * 1992-01-20 1993-08-03 Mitsui Toatsu Chem Inc α−オレフィンの重合方法
US5643846A (en) * 1993-04-28 1997-07-01 Fina Technology, Inc. Process for a isotactic/syndiotactic polymer blend in a single reactor
JP3325719B2 (ja) * 1994-09-13 2002-09-17 三菱化学株式会社 エチレン重合体の製造法
US5622906A (en) * 1994-09-16 1997-04-22 Phillips Petroleum Company Compositions useful for olefin polymerization and processes therefor and therewith
AU729324B2 (en) * 1995-01-24 2001-02-01 E.I. Du Pont De Nemours And Company Alpha-olefins and olefin polymers and processes therefor
US5714556A (en) * 1995-06-30 1998-02-03 E. I. Dupont De Nemours And Company Olefin polymerization process
JPH09143228A (ja) * 1995-11-22 1997-06-03 Sumitomo Chem Co Ltd エチレン−α−オレフィン共重合体の製造方法
JP3749756B2 (ja) * 1996-04-09 2006-03-01 三井化学株式会社 オレフィン重合用触媒およびオレフィンの重合方法
WO1997038024A1 (fr) * 1996-04-09 1997-10-16 Mitsui Chemicals, Inc. Catalyseur de polymerisation d'olefines, procede de polymerisation d'olefines, compositions de polymeres d'olefines et articles thermoformes
JPH09278824A (ja) * 1996-04-09 1997-10-28 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびオレフィンの重合方法
US6194341B1 (en) * 1996-06-17 2001-02-27 Exxon Chemical Patents Inc. Mixed transition metal catalyst systems for olefin polymerization
US5753785A (en) * 1996-12-16 1998-05-19 Fina Technology, Inc. Production of E-B copolymers with a single metallocene catalyst and a single monomer
DE19707236A1 (de) * 1997-02-24 1998-08-27 Targor Gmbh Katalysatorzusammensetzung

Also Published As

Publication number Publication date
US6114483A (en) 2000-09-05
PL338979A1 (en) 2000-12-04
DE69827020D1 (de) 2004-11-18
KR20010023353A (ko) 2001-03-26
BR9814445A (pt) 2000-10-03
TR200000533T2 (tr) 2000-11-21
ATE279450T1 (de) 2004-10-15
JP2001514272A (ja) 2001-09-11
DE69827020T2 (de) 2006-02-02
HK1027365A1 (en) 2001-01-12
EP1012194A1 (en) 2000-06-28
AU9205398A (en) 1999-03-16
ID24427A (id) 2000-07-20
CN1268144A (zh) 2000-09-27
IL133986A0 (en) 2001-04-30
NO20000867D0 (no) 2000-02-22
EP1012194B1 (en) 2004-10-13
HUP0002912A3 (en) 2001-03-28
EP1400540A3 (en) 2007-02-21
EP1400540A2 (en) 2004-03-24
CA2300085A1 (en) 1999-03-04
NO20000867L (no) 2000-04-18
EP1400540A8 (en) 2004-07-07
HUP0002912A2 (hu) 2000-12-28
WO1999010391A1 (en) 1999-03-04

Similar Documents

Publication Publication Date Title
EA200000262A1 (ru) Полимеризация олефинов
EA200001002A1 (ru) Способ полимеризации олефинов
DE69825559D1 (de) Polymerisation von olefinen
DE60016206D1 (de) Polymerisation von ethylen
ID21656A (id) Polimerisasi etilena
BR9911200A (pt) Processo de polimerização e copolìmero de etileno e uma ou mais olefinas da fórmula h2c=chr21
MY108973A (en) Polyethylene copolymer and polymerization process
WO2001092348A3 (en) Polymerization of olefins
DE69924965D1 (de) Verfahren zur polymerisierung von olefine; polyethylene, und filme, und gegenstände damit hergestellt
DE60020108D1 (de) Polymerisation von ethylen
AU7836300A (en) Polymerization of olefins with bimetallic polymerisation catalyst system
GB1249023A (en) Olefin copolymers
EP1127897A3 (en) Catalyst composition comprising specific iron or cobalt complexes and process for the oligomerization or polymerization of ethylene therewith