EA025435B1 - Способ риформинга углеводородов - Google Patents

Способ риформинга углеводородов Download PDF

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EA025435B1
EA025435B1 EA201490176A EA201490176A EA025435B1 EA 025435 B1 EA025435 B1 EA 025435B1 EA 201490176 A EA201490176 A EA 201490176A EA 201490176 A EA201490176 A EA 201490176A EA 025435 B1 EA025435 B1 EA 025435B1
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cho
cco
reactor
gas
partial oxidation
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EA201490176A
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EA201490176A1 (ru
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Ким Аасберг-Петерсен
Сейер Петер Кристензен
Сандаль Томас Кристензен
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Хальдор Топсёэ А/С
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Priority claimed from EP11009101.4A external-priority patent/EP2594527A1/en
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Publication of EA201490176A1 publication Critical patent/EA201490176A1/ru
Publication of EA025435B1 publication Critical patent/EA025435B1/ru

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Abstract

Изобретение касается способа получения синтез-газа посредством автотермического риформинга, в котором остаточный газ, полученный в ходе последующего синтеза Фишера-Тропша, гидрогенизируют, а затем вводят в стадию автотермического риформинга.

Description

Настоящее изобретение касается способа получения синтез-газа, используемого для получения углеводородов путем синтеза Фишера-Тропша. В частности, изобретение касается способа получения синтез-газа посредством автотермического риформинга, в котором остаточный газ, полученный в ходе последующего процесса, в частности, в ходе синтеза Фишера-Тропша, гидрогенизируют, а затем вводят в процесс автотермического риформинга. В соответствии с более общим аспектом настоящее изобретение охватывает удаление олефинов в газе для уменьшения металлического запыливания металлических частей, находящихся в контакте с газом, в частности, для уменьшения металлического запыливания в АТР (установке автотермического риформинга), КЧО (реакторе каталитического частичного окисления) или ЧО (реакторе частичного окисления), а также в другом оборудовании, расположенном на последующих стадиях технологического процесса, через которое проходит газ.

Claims (1)

1. Способ получения синтез-газа из углеводородного сырья с пониженной склонностью к металлическому запыливанию по меньшей мере частей камеры сгорания установки автотермического риформинга (АТР), реактора каталитического частичного окисления (КЧО) или реактора частичного окисления (ЧО), включающий стадии, на которых подают указанное углеводородное сырье в реактор АТР, КЧО или ЧО и отводят поток полученного горячего синтез-газа из АТР, КЧО или ЧО, при этом подают непосредственно в указанный реактор АТР, КЧО или ЧО гидрогенизированный остаточный газ, полученный пропусканием остаточного газа из стадии синтеза Фишера-Тропша, через стадию гидрогенизации с использованием катализатора гидрогени-
EA201490176A 2011-06-29 2012-06-20 Способ риформинга углеводородов EA025435B1 (ru)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DKPA201100485 2011-06-29
EP11009101.4A EP2594527A1 (en) 2011-11-16 2011-11-16 Process for reforming hydrocarbons
DKPA201100947 2011-12-06
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Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2838849C (en) * 2011-06-29 2020-09-01 Haldor Topsoe A/S Process for reforming hydrocarbons comprising feeding a hydrogenated tail gas to the reforming stage
MX2015003867A (es) * 2012-10-23 2015-07-17 Haldor Topsøe As Proceso para la preparacion de hidrocarburos.
GB201303723D0 (en) * 2013-03-01 2013-04-17 Johnson Matthey Plc Process for treating gas mixtures
DE102016002728A1 (de) * 2016-03-08 2017-09-14 Linde Aktiengesellschaft Verfahren zur Erzeugung von Synthesegas
UA127479C2 (uk) * 2017-07-25 2023-09-06 Хальдор Топсьое А/С Спосіб отримання синтез-газу
EP3658491B1 (en) 2017-07-25 2023-08-30 Topsoe A/S Method for the preparation of ammonia synthesis gas
CN110944938A (zh) * 2017-07-25 2020-03-31 托普索公司 用于制备合成气的方法
AU2018305877B2 (en) * 2017-07-25 2024-04-18 Haldor Topsøe A/S Method for the preparation of synthesis gas
CA3070981A1 (en) 2017-09-29 2019-04-04 Research Triangle Institute Methods and apparatus for production of hydrogen
US10738247B2 (en) 2017-11-15 2020-08-11 Gas Technology Institute Processes and systems for reforming of methane and light hydrocarbons to liquid hydrocarbon fuels
CN109453544A (zh) * 2019-01-04 2019-03-12 朗慕 高效自动液液萃取机
EP4110727A1 (en) * 2020-02-28 2023-01-04 Topsoe A/S Method for the preparation of synthesis gas
WO2022100899A1 (en) 2020-11-13 2022-05-19 Technip France A process for producing a hydrogen-comprising product gas from a hydrocarbon
WO2024094818A1 (en) 2022-11-04 2024-05-10 Topsoe A/S Conversion of unsaturated hydrocarbon containing off-gases for more efficient hydrocarbon production plant

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5763716A (en) * 1986-05-08 1998-06-09 Rentech, Inc. Process for the production of hydrocarbons
WO2001042175A1 (en) * 1999-12-09 2001-06-14 Den Norske Stats Oljeselskap As Optimum integration of fischer-tropsch synthesis and syngas production
WO2001098239A1 (en) * 2000-06-20 2001-12-27 Chevron U.S.A. Inc. Process for the purification of olefins
US20020120018A1 (en) * 2001-02-20 2002-08-29 Moore Richard O. Hydrocarbon recovery in a fischer-tropsch process
WO2003035590A1 (en) * 2001-10-23 2003-05-01 Texaco Development Corporation Fischer-tropsch tail-gas utilization
US20040063797A1 (en) * 2002-09-26 2004-04-01 Kim Aasberg-Petersen Process for the production of synthesis gas
WO2006056594A1 (en) * 2004-11-26 2006-06-01 Shell Internationale Research Maatschappij B.V. Method for treatment of a gas
EP1860063A1 (en) * 2006-05-22 2007-11-28 Shell Internationale Researchmaatschappij B.V. Process for preparing a paraffin product
US20090186952A1 (en) * 2005-06-14 2009-07-23 Andre Peter Steynberg Process for the Preparation and Conversion of Synthesis Gas.

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB632386A (en) 1946-10-18 1949-11-28 Standard Oil Dev Co Improvements in or relating to the production of fuel gas
DK147705C (da) 1982-09-07 1985-05-13 Haldor Topsoe As Fremgangsmaade til fremstilling af carbonhydrider ud fra syntesegas
DK149529C (da) 1983-05-11 1986-12-22 Haldor Topsoe As Fremgangsmaade til fremstilling af syntetiske carbonhydrider ud fra syntesegas
US6114400A (en) 1998-09-21 2000-09-05 Air Products And Chemicals, Inc. Synthesis gas production by mixed conducting membranes with integrated conversion into liquid products
CN1365340A (zh) * 1999-07-29 2002-08-21 萨索尔技术(控股)有限公司 天然气转化成烃和氨
US6818198B2 (en) * 2002-09-23 2004-11-16 Kellogg Brown & Root, Inc. Hydrogen enrichment scheme for autothermal reforming
JP2009519371A (ja) 2005-12-15 2009-05-14 サソル・テクノロジー・(プロプライアタリー)・リミテッド 天然ガスからの炭化水素の生成
US20090184293A1 (en) 2008-01-18 2009-07-23 Han Pat A Process for reforming hydrocarbons
CA2838849C (en) * 2011-06-29 2020-09-01 Haldor Topsoe A/S Process for reforming hydrocarbons comprising feeding a hydrogenated tail gas to the reforming stage
BR112014031972A2 (pt) * 2012-06-19 2017-06-27 Haldor Topsoe As processo para reforma de hidrocarbonetos e processo para iniciar um processo de gás-para-líquido
KR101957939B1 (ko) * 2012-09-05 2019-03-13 할도르 토프쉐 에이/에스 가스 액화 공정의 시동 방법

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5763716A (en) * 1986-05-08 1998-06-09 Rentech, Inc. Process for the production of hydrocarbons
WO2001042175A1 (en) * 1999-12-09 2001-06-14 Den Norske Stats Oljeselskap As Optimum integration of fischer-tropsch synthesis and syngas production
WO2001098239A1 (en) * 2000-06-20 2001-12-27 Chevron U.S.A. Inc. Process for the purification of olefins
US20020120018A1 (en) * 2001-02-20 2002-08-29 Moore Richard O. Hydrocarbon recovery in a fischer-tropsch process
WO2003035590A1 (en) * 2001-10-23 2003-05-01 Texaco Development Corporation Fischer-tropsch tail-gas utilization
US20040063797A1 (en) * 2002-09-26 2004-04-01 Kim Aasberg-Petersen Process for the production of synthesis gas
WO2006056594A1 (en) * 2004-11-26 2006-06-01 Shell Internationale Research Maatschappij B.V. Method for treatment of a gas
US20090186952A1 (en) * 2005-06-14 2009-07-23 Andre Peter Steynberg Process for the Preparation and Conversion of Synthesis Gas.
EP1860063A1 (en) * 2006-05-22 2007-11-28 Shell Internationale Researchmaatschappij B.V. Process for preparing a paraffin product

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
A AL-MESHARI, LIITLE J: "METAL DUSTING BEHAVIOUR OF FURNACE TUBE ALLOYS", JOURNAL OF ENGINEERING AND APPLIED SCIENCE, ASIAN RESEARCH PUBLISHING NETWORK (ARPN), vol. 4, no. 8, 8 October 2009 (2009-10-08), pages 66 - 81, XP055049751 *
D. J. YOUNG, J. ZHANG, C. GEERS, M. SCHÜTZE: "Recent advances in understanding metal dusting: A review", MATERIALS AND CORROSION, WILEY, vol. 62, no. 1, 1 February 2011 (2011-02-01), pages 7 - 28, XP001559940, ISSN: 0947-5117, DOI: 10.1002/maco.201005675 *

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CN103748033A (zh) 2014-04-23
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AU2012278043B2 (en) 2016-01-07
MX2013015028A (es) 2014-01-24
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US9162886B2 (en) 2015-10-20
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EA201490176A1 (ru) 2014-04-30
US20160046488A1 (en) 2016-02-18
CN103748033B (zh) 2016-12-07
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CN106957674A (zh) 2017-07-18
EA030771B1 (ru) 2018-09-28
EA201691199A1 (ru) 2016-10-31
BR112013033570A2 (pt) 2017-12-19
US20140135409A1 (en) 2014-05-15
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