DK177132B1 - Automatic Dishwasher - Google Patents

Automatic Dishwasher Download PDF

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Publication number
DK177132B1
DK177132B1 DKPA201001004A DKPA201001004A DK177132B1 DK 177132 B1 DK177132 B1 DK 177132B1 DK PA201001004 A DKPA201001004 A DK PA201001004A DK PA201001004 A DKPA201001004 A DK PA201001004A DK 177132 B1 DK177132 B1 DK 177132B1
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DK
Denmark
Prior art keywords
water
formate
enzyme
washing
dishwashing detergent
Prior art date
Application number
DKPA201001004A
Other languages
Danish (da)
Inventor
Boe Paaskesen
Original Assignee
Respekt Danmark As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Respekt Danmark As filed Critical Respekt Danmark As
Priority to DKPA201001004A priority Critical patent/DK177132B1/en
Priority to DK11188100.9T priority patent/DK2450427T3/en
Priority to EP11188100.9A priority patent/EP2450427B1/en
Application granted granted Critical
Publication of DK177132B1 publication Critical patent/DK177132B1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38618Protease or amylase in liquid compositions only
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02Inorganic compounds
    • C11D7/04Water-soluble compounds
    • C11D7/10Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

Enzymbaseret, saitholdigt, vandfortyndbart maskinopvaskemiddel omfattende: 0-2% enzymer af typen amylase og protease, 5-10% uorganiske salte valgt blandt natriumchlorid og kaliumtripolyfosfat, 20-25% formiat og 60-70 % vand.Enzyme-based, saline-containing, water-dilutable dishwashing detergent comprising: 0-2% enzymes of the amylase and protease type, 5-10% inorganic salts selected from sodium chloride and potassium tripolyphosphate, 20-25% formate and 60-70% water.

Description

DK 177132 B1DK 177132 B1

Titel: MASKINOPVASK Baggrund: 5 Respekt Danmark A/S har udviklet et nyt maskinopvaskemiddel som ønskes patentanmeldt.Title: MACHINE WASHING Background: 5 Respect Denmark A / S has developed a new machine dishwashing liquid that is wanted to be patent-pending.

Nyhedsværdien og opfindelsen ligger i: 10 · At anvende enzymer og salte i kombination til maskinopvask • At via salte at kunne styre konduktiviteten således der sker løbende dosering og således vaskeeffekten ikke reduceres • At vasken kan foretages ved lavere temperaturer, 40 gr C, hvilket giver en økonomisk, energi- og miljømæssig gevinst for kunderne.The novelty value and invention lies in: 10 · Using enzymes and salts in combination with machine washing • Being able to control the conductivity through salts so that continuous dosing is done and thus the washing effect is not reduced • That the washing can be done at lower temperatures, 40 gr C, which gives a financial, energy and environmental benefit for customers.

15 »At tilbyde branchen et produkt, der ikke er farligt for hverken sikkerhed, sundhed eller miljø og som dermed ikke lovmæssigt kræver restriktioner i anvendelsen.15 »To offer the industry a product that is not hazardous to either safety, health or the environment and which thus does not legally require restrictions on its use.

Kendt teknik 20 US 7211552 B1 beskriver en ikke-toksisk, miljøvenlig, enzymatisk rengøringssammensætning til rengøring af kirurgiske instrumenter. Sammensætningen indeholder 64-68% vand, 1-2% natriumformiat, 4-6% natriumtripolyfosfat, 0,1-0,3% calciumklorid, 3-5% protease og 1-3% amylase. Sammensætningen ifølge 25 den foreliggende opfindelse adskiller sig herfra ved at indeholde væsentligt mere formiat og mindre enzym.Prior art US 7211552 B1 discloses a non-toxic, environmentally friendly, enzymatic cleaning composition for cleaning surgical instruments. The composition contains 64-68% water, 1-2% sodium formate, 4-6% sodium tripolyphosphate, 0.1-0.3% calcium chloride, 3-5% protease and 1-3% amylase. The composition of the present invention differs from this by containing substantially more formate and less enzyme.

WO 2008/116915 beskriver en enzymsammensætning indeholdende et enzym, en inhibitor bestående af phenylborsyre eller et derivat deraf og 0,1-20% af et 30 opløst salt. Det opløste salt anvendes til at forbedre effekten af phenylborsy-reinhibitoren. Sammensætningen kan anvendes som maskinopvaskemiddel. Sammensætningen ifølge den foreliggende opfindelse adskiller sig herfra ved at DK 177132 B1 2 indeholde en begrænset mængde enzym samt mindst 25% af et opløst salt, hvoraf mindst 20% af sammensætningen udgøres af et formiatsalt.WO 2008/116915 discloses an enzyme composition containing an enzyme, an inhibitor consisting of phenylboronic acid or a derivative thereof and 0.1-20% of a dissolved salt. The dissolved salt is used to enhance the effect of the phenylboronic reinhibitor. The composition can be used as a machine dishwasher detergent. The composition of the present invention differs from this in that DK 177132 B1 2 contains a limited amount of enzyme as well as at least 25% of a dissolved salt, of which at least 20% of the composition is a formate salt.

2. Gyldighed: 52. Validity: 5

Patentet ønskes til Danmark.The patent is wanted in Denmark.

3. Om opfindelsen 10 3.1 Teknisk område3. About the invention 10 3.1 Technical field

Opfindelsen angår en væske - et såkaldt opvaskemiddel til anvendelse i opvaskemaskiner. Der er tale om alle typer af maskiner, hvor der sker en løbende dosering under selve vaskeprocessen.The invention relates to a liquid - a so-called detergent for use in dishwashers. These are all types of machines where continuous dosing is done during the washing process itself.

1515

Opvaskemidlet finder anvendelse i maskiner og i private hjem, men som oftest vil der være tale om større, industrielle opvaskemaskiner og opvasketunneler.The detergent is used in machines and in private homes, but most often it will be large industrial dishwashers and dishwashers.

De findes typisk i restauranter, kantiner, hotelkøkkener og lignende steder.They are typically found in restaurants, canteens, hotel kitchens and similar places.

20 Opvaskemidlet i processen har flere funktioner. Det skal reducere overfladespændingen i vandet, for derved at øge vandets vaskeeffekt. Det skal desuden aktivt medvirke til at løsne de forskellige former for snavs, der består af de forskellige stoffer, der indgår i drikke- og fødevarer, bl.a. fedt, proteiner m.v.20 The detergent in the process has several functions. It should reduce the surface tension in the water, thereby increasing the washing power of the water. In addition, it must actively contribute to loosening the various forms of dirt, which consist of the various substances contained in beverages and foods, including fat, proteins, etc.

25 Væsken skal også kunne fjerne belægninger, der for eksempel opstår i kaffe og tekopper, efter længere tids brug - uden opvask - og det skal sikre, at vandet og dermed kalken ikke binder i overfladen, hvorved der dannes synlige grå aflejringer f.eks. drikkeglas.25 The liquid must also be able to remove coatings, which occur, for example, in coffee and teacups, after prolonged use - without washing up - and it must ensure that the water and thus the lime does not bond to the surface, thereby forming visible gray deposits, e.g. drinking glasses.

30 Væsken skal desuden sikre, at løsnet snavs ikke senere sætter sig i vaskeemnerne under vaskeprocessen og endelig skal eventuelle reststoffer være uskadelige i forbindelse med brug af servicen.30 The liquid must also ensure that loosened dirt does not settle later in the wash items during the washing process and finally any residual substances must be harmless in connection with the use of the service.

DK 177132 B1 3DK 177132 B1 3

Disse egenskaber skal alle være til stede uanset hvilket materiale servicen består af, f.eks. metallegeringer som rustfrit stål, aluminiumsgryder, porcelæn, glas, plastik osv. Væskens påvirkning af disse materialer skal være neutral, således der ikke dannes misfarvninger på servicen.These properties must all be present regardless of the material of the service, e.g. metal alloys such as stainless steel, aluminum pots, porcelain, glass, plastic, etc. The influence of the liquid on these materials must be neutral, so that no discoloration of the service is formed.

55

Der eksisterer i dag allerede midler, der tilgodeser mange af ovenstående krav - men fælles for alle disse midler er at de er baseret på højt alkali (dvs. pH14) og dermed et meget aggressivt miljø. Ligeledes har mange af produkterne tilsætning af chlor for at opnå en yderligere rensende effekt. Udover den høje pH 10 er midlerne således også skadelig for mennesker og miljø.Today, agents already exist that meet many of the above requirements - but common to all these agents is that they are based on high alkali (ie pH14) and thus a very aggressive environment. Also, many of the products have the addition of chlorine to obtain a further purifying effect. In addition to the high pH 10, the agents are also harmful to humans and the environment.

3.2 Kort beskrivelse af opfindelsen3.2 Brief Description of the Invention

Det har nu vist sig, at der er muligt at fremstille et koncentrat, som er miljøven-15 ligt og hvor koncentratet i modsætning til hidtil kendte midler kan anvendes til alle typer for maskinopvask uden brug af høj alkali eller chlor.It has now been found that it is possible to prepare a concentrate which is environmentally friendly and in which the concentrate, contrary to known means, can be used for all types of machine washing without the use of high alkali or chlorine.

Koncentratet omfatter enzymer, salte og vand, justeret til pH på ca. 8,5.The concentrate comprises enzymes, salts and water, adjusted to a pH of approx. 8.5.

20 Opfindelsen angår således et enzymbaseret saltholdigt maskinopvaskemiddel omfattende op til 2% enzymer at typen amylase og protease, 5-10 % uorganiske salte valgt blandt natriumchlorid og kaliumtripolyfosfat, 20-25% formiat og resten vand.The invention thus relates to an enzyme-based saline dishwashing detergent comprising up to 2% enzymes of type amylase and protease, 5-10% inorganic salts selected from sodium chloride and potassium tripolyphosphate, 20-25% formate and the remainder water.

25 Væsken tilsættes maskinopvaskemaskinen som koncentrat og påføres vaskeprocessen via konduktiviteten i vaskevandet.The liquid is added to the machine dishwasher as a concentrate and applied to the washing process via the conductivity of the washing water.

Væsken har den fordel, at det blødgør vandet og reducerer overfladespændingen. Endvidere eliminerer midlet kalkaflejringer fra vandet. Opvaskemidlet er 30 desuden temperaturstabilt og kan være effektivt ved lavere temperaturer. Det er stabilt under transport og opbevaring, og endelig er det ikke korroderende eller giver misfarvninger på forskellige materialer som plastik, glas, porcelæn, diverse metallegeringer m.v.The liquid has the advantage of softening the water and reducing the surface tension. Furthermore, the agent eliminates lime deposits from the water. In addition, the detergent is temperature stable and can be effective at lower temperatures. It is stable during transport and storage, and finally it is not corrosive or discolorable on various materials such as plastic, glass, porcelain, various metal alloys etc.

DK 177132 B1 4DK 177132 B1 4

Eksempel: 5 KONCENTRAT VÆGT %Example: 5 CONCENTRATE WEIGHT%

Vand 66,0Water 66.0

Natriumchlorid,(salt) 2,0Sodium chloride, (salt) 2.0

Kaliumformiat (formiat) 22,8Potassium formate (formate) 22.8

Kaliumtripolyfosfat (salt) 6,4Potassium tripolyphosphate (salt) 6.4

Fosforsyre (pH justering) 1,3Phosphoric acid (pH adjustment) 1.3

Stainzyme (amylase) (enzym) 0,75Stain enzyme (amylase) (enzyme) 0.75

Everlase (protease) (enzym) 0,75Everlase (protease) (enzyme) 0.75

Claims (3)

1. Enzymbaseret, saltholdigt, vandfortyndbart maskinopvaskemiddel omfattende: 5 0-2% enzymer af typen amylase og protease 5-10% uorganiske salte valgt blandt natriumchlorid og kaliumtripolyfosfat 20-25% formiat 10 60-70 % vand.An enzyme-based, saline, water-dilutable dishwashing detergent comprising: 0-2% of enzymes of the amylase type and protease 5-10% of inorganic salts selected from sodium chloride and potassium tripolyphosphate 20-25% formate 10 60-70% water. 2. Maskinopvaskemiddel ifølge krav 1 kendetegnet ved, at formiat er defineret som kaliumformiat. 15Machine dishwashing detergent according to claim 1, characterized in that formate is defined as potassium formate. 15 3. Anvendelse af et maskinopvaskemiddel ifølge krav 1 eller 2 til enhver form for maskinopvask.Use of a machine dishwashing detergent according to claim 1 or 2 for any machine dishwashing.
DKPA201001004A 2010-11-05 2010-11-05 Automatic Dishwasher DK177132B1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DKPA201001004A DK177132B1 (en) 2010-11-05 2010-11-05 Automatic Dishwasher
DK11188100.9T DK2450427T3 (en) 2010-11-05 2011-11-07 Dishwasher detergent
EP11188100.9A EP2450427B1 (en) 2010-11-05 2011-11-07 Dishwasher detergent

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA201001004A DK177132B1 (en) 2010-11-05 2010-11-05 Automatic Dishwasher
DK201001004 2010-11-05

Publications (1)

Publication Number Publication Date
DK177132B1 true DK177132B1 (en) 2012-01-30

Family

ID=45442813

Family Applications (2)

Application Number Title Priority Date Filing Date
DKPA201001004A DK177132B1 (en) 2010-11-05 2010-11-05 Automatic Dishwasher
DK11188100.9T DK2450427T3 (en) 2010-11-05 2011-11-07 Dishwasher detergent

Family Applications After (1)

Application Number Title Priority Date Filing Date
DK11188100.9T DK2450427T3 (en) 2010-11-05 2011-11-07 Dishwasher detergent

Country Status (2)

Country Link
EP (1) EP2450427B1 (en)
DK (2) DK177132B1 (en)

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4537707A (en) * 1984-05-14 1985-08-27 The Procter & Gamble Company Liquid detergents containing boric acid and formate to stabilize enzymes
KR100294361B1 (en) 1992-07-23 2001-09-17 피아 스타르 Mutant Alpha-amylase, Detergent, Dish Cleaner, and Liquid
PL310326A1 (en) 1993-02-11 1995-12-11 Genencor Int Novel oxidation-stable mutants of alpha-amylase as well as detergent and starch liquefaction compositions containing them
AR000862A1 (en) 1995-02-03 1997-08-06 Novozymes As VARIANTS OF A MOTHER-AMYLASE, A METHOD TO PRODUCE THE SAME, A DNA STRUCTURE AND A VECTOR OF EXPRESSION, A CELL TRANSFORMED BY SUCH A DNA STRUCTURE AND VECTOR, A DETERGENT ADDITIVE, DETERGENT COMPOSITION, A COMPOSITION FOR AND A COMPOSITION FOR THE ELIMINATION OF
US5763385A (en) 1996-05-14 1998-06-09 Genencor International, Inc. Modified α-amylases having altered calcium binding properties
US5698507A (en) * 1996-09-10 1997-12-16 Colgate-Palmolive Co. Nonaqueous gelled automatic dishwashing composition
US7211552B1 (en) 2002-11-13 2007-05-01 Melton Sherwood Thoele Enzymatic detergent
JP5718636B2 (en) 2007-03-27 2015-05-13 ノボザイムス アクティーゼルスカブ Stable enzyme solution and production method

Also Published As

Publication number Publication date
EP2450427A2 (en) 2012-05-09
EP2450427A3 (en) 2012-08-01
DK2450427T3 (en) 2014-07-14
EP2450427B1 (en) 2014-05-07

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Effective date: 20171130