DK1188779T3 - Process for the preparation of a storage stable, rheologically active solution of urea urethane with broad compatibility - Google Patents

Process for the preparation of a storage stable, rheologically active solution of urea urethane with broad compatibility

Info

Publication number
DK1188779T3
DK1188779T3 DK01116384T DK01116384T DK1188779T3 DK 1188779 T3 DK1188779 T3 DK 1188779T3 DK 01116384 T DK01116384 T DK 01116384T DK 01116384 T DK01116384 T DK 01116384T DK 1188779 T3 DK1188779 T3 DK 1188779T3
Authority
DK
Denmark
Prior art keywords
preparation
storage stable
active solution
urea urethane
broad compatibility
Prior art date
Application number
DK01116384T
Other languages
Danish (da)
Inventor
Karlheinz Haubennestel
Ulrich Dr Orth
Axel Woocker
Heribert Holtkamp
Christoph Buchmann
Original Assignee
Byk Chemie Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Byk Chemie Gmbh filed Critical Byk Chemie Gmbh
Application granted granted Critical
Publication of DK1188779T3 publication Critical patent/DK1188779T3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G71/00—Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule
    • C08G71/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/282—Alkanols, cycloalkanols or arylalkanols including terpenealcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/282—Alkanols, cycloalkanols or arylalkanols including terpenealcohols
    • C08G18/2825—Alkanols, cycloalkanols or arylalkanols including terpenealcohols having at least 6 carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/284—Compounds containing ester groups, e.g. oxyalkylated monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/3237—Polyamines aromatic
    • C08G18/324—Polyamines aromatic containing only one aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/04—Thixotropic paints

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Paints Or Removers (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Medicinal Preparation (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

The invention relates to a process for preparing a solution which comprises urea urethanes and is effective as a thixotropic agent, which involves reacting at least two structurally different monohydroxy compounds with an excess of toluylene diisocyanate to form monoisocyanate adducts, removing the unreacted portion of the toluylene diisocyanate, and reacting the resultant monoisocyanate adducts with diamines in an aprotic solvent in the presence of a lithium salt to form urea urethanes. The invention also relates to the use of the solution to receive thixotropic coating compositions.
DK01116384T 2000-08-16 2001-07-06 Process for the preparation of a storage stable, rheologically active solution of urea urethane with broad compatibility DK1188779T3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10039837A DE10039837C2 (en) 2000-08-16 2000-08-16 Process for the preparation of a storage-stable, rheologically effective urea urethane solution with broad compatibility

Publications (1)

Publication Number Publication Date
DK1188779T3 true DK1188779T3 (en) 2004-08-30

Family

ID=7652494

Family Applications (1)

Application Number Title Priority Date Filing Date
DK01116384T DK1188779T3 (en) 2000-08-16 2001-07-06 Process for the preparation of a storage stable, rheologically active solution of urea urethane with broad compatibility

Country Status (10)

Country Link
EP (1) EP1188779B1 (en)
JP (1) JP4942262B2 (en)
KR (1) KR100796040B1 (en)
CN (1) CN1204117C (en)
AT (1) ATE268790T1 (en)
CA (1) CA2352660C (en)
DE (2) DE10039837C2 (en)
DK (1) DK1188779T3 (en)
ES (1) ES2220631T3 (en)
TW (1) TWI226892B (en)

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10241853B3 (en) * 2002-09-09 2004-01-22 Byk-Chemie Gmbh Polymeric urea urethane as a rheology control agent and manufacturing process
BRPI0412310B1 (en) * 2003-07-08 2015-08-18 Nuplex Resins Bv Use of a rheology controlling agent, rheology modifying agent, concentrates, and improved rheology compositions
KR100482427B1 (en) * 2003-12-19 2005-04-14 박장원 Crosslinked foam which has inner-cavity structure, and process of forming thereof
US7144450B2 (en) * 2004-12-04 2006-12-05 Xerox Corporation Phase change inks containing trans-1,2-cyclohexane bis(urea-urethane) compounds
US7560587B2 (en) * 2004-12-04 2009-07-14 Xerox Corporation Bis[urea-urethane] compounds
US7220300B2 (en) * 2004-12-04 2007-05-22 Xerox Corporation Phase change inks containing bis(urea-urethane) compounds
WO2007105258A1 (en) * 2006-03-07 2007-09-20 The Yokohama Rubber Co., Ltd. Thixotropy-imparting agent, hardenable resin composition making use of the same and method of using the hardenable resin composition
DE102006010721B4 (en) * 2006-03-08 2010-04-15 Byk-Chemie Gmbh Biuret compounds for rheology control
KR100803024B1 (en) * 2006-07-25 2008-02-14 케이에스케미칼 주식회사 The preparing method of urethane-urea solution which is used as thixotropic agent in the paint
DE202008008419U1 (en) 2008-04-23 2009-06-04 Byk-Chemie Gmbh Stable dispersions of inorganic nanoparticles
DE102008029858A1 (en) * 2008-04-23 2009-10-29 Byk-Chemie Gmbh Stable dispersions of inorganic nanoparticles
DE102008038488A1 (en) 2008-08-20 2010-02-25 Henkel Ag & Co. Kgaa Moisture-curing waterproof coating
DE102008059702A1 (en) * 2008-12-01 2010-06-02 Byk-Chemie Gmbh Process for the preparation of rheologically active urea urethanes in organic salts
WO2010121898A1 (en) * 2009-04-21 2010-10-28 Huntsman International Llc Polyisocyanate composition
DE102009021912A1 (en) 2009-05-19 2010-12-02 Byk-Chemie Gmbh From oxetane-based macromonomers available polymers, processes for their preparation and their use as additives in coating materials and plastics
DE102009021913A1 (en) 2009-05-19 2010-12-02 Byk-Chemie Gmbh Terminal unsaturated, oxetane-based macromonomers and process for their preparation
EP2292675A1 (en) 2009-09-08 2011-03-09 BYK-Chemie GmbH Polyureas as a rheology controlling agents.
KR101685740B1 (en) 2010-01-28 2016-12-12 비와이케이-케미 게엠베하 Coating preparation containing urea components and amide components
JP2014510808A (en) * 2011-02-22 2014-05-01 ビーエーエスエフ ソシエタス・ヨーロピア Rheological agents for radiation curable coating materials
EP2644632A1 (en) * 2012-03-29 2013-10-02 Huntsman International Llc Isocyanate-based prepolymer
EP2644633A1 (en) * 2012-03-29 2013-10-02 Huntsman International Llc Isocyanate-based prepolymer
EP2931771B1 (en) 2012-12-15 2016-09-07 BYK-Chemie GmbH Composition for rheology control
TR201808677T4 (en) * 2014-04-15 2018-07-23 Byk Chemie Gmbh Storage-stable urea preparations suitable for use as rheology control agents.
ES2668352T3 (en) 2014-04-15 2018-05-17 Byk-Chemie Gmbh Rheology control agent comprising a combination of active substance
WO2015158407A1 (en) 2014-04-15 2015-10-22 Byk-Chemie Gmbh Composition for rheology control
CN107849209B (en) * 2015-07-27 2020-12-15 毕克化学有限公司 Urea urethanes for rheology control
KR101835720B1 (en) 2015-11-30 2018-03-08 케이에스케미칼 주식회사 Manufacturing method of thixotropic agent with shear thinning
CN110494462B (en) 2017-01-30 2021-11-16 毕克化学有限公司 Preparation and use of urea group-containing and/or carbamate group-containing amides as rheology control agents and in rheology control agents
EP3459985B1 (en) * 2017-09-22 2020-06-17 Cliq Swisstech Gmbh Urea urethanes (ii)
US11377553B2 (en) 2017-04-13 2022-07-05 Byk-Chemie Gmbh Polymer suitable as a thickener
EP3428233A1 (en) 2017-07-13 2019-01-16 Sika Technology Ag Coating system with high surface roughness
US11795343B2 (en) 2017-11-14 2023-10-24 Basf Se Process for preparing urea urethane polymer
WO2019122222A1 (en) 2017-12-21 2019-06-27 Byk-Chemie Gmbh Urea group containing anti-sagging rheology control agents
US20200308106A1 (en) 2017-12-21 2020-10-01 Byk-Chemie Gmbh Urea and urethane group containing anti-settling rheology control additive
KR102071950B1 (en) 2017-12-28 2020-01-31 낙우산업(주) Nanoclay to improve thickening and thixotropic behavior in natural paints and the preparing process the same
CN108070066B (en) * 2017-12-29 2020-11-27 陈鹏 Paint and ink anti-settling agent and preparation method thereof
US11299580B2 (en) * 2018-03-27 2022-04-12 Advansix Resins & Chemicals Llc Thixotropic rheology modifying agent compositions
JP7332251B2 (en) * 2018-06-28 2023-08-23 ホヤ レンズ タイランド リミテッド Polymerizable composition for optical members
EP3906268B1 (en) 2019-01-04 2022-11-23 Byk-Chemie GmbH Rheology control additive containing urea component
JP7314298B2 (en) 2019-03-14 2023-07-25 ベーイプシロンカー ヘミー ゲゼルシャフト ミット ベシュレンクター ハフトゥング Rheology Control Additives Containing Cyclic Amides
EP4200347A1 (en) * 2020-08-24 2023-06-28 Basf Se Urea urethane compounds
CN116670220A (en) 2020-12-04 2023-08-29 毕克化学有限公司 Rheology control agent
DE102021128685A1 (en) 2021-11-04 2023-05-04 Voco Gmbh Highly effective, silica-free, storage-stable dental etching gel
WO2024008765A1 (en) 2022-07-06 2024-01-11 Byk-Chemie Gmbh Composition comprising a cyclic amide

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5415040A (en) * 1977-07-04 1979-02-03 Kanebo Ltd Bobbin exchange apparatus fof spun yarn winder
DE2822908C2 (en) * 1978-05-26 1980-03-20 Byk-Mallinckrodt Chemische Produkte Gmbh, 4230 Wesel Thixotropic agents for coating agents
ATE29138T1 (en) * 1984-01-27 1987-09-15 Byk Chemie Gmbh ADDITIONAL COMPOUNDS SUITABLE AS DISPERSING AGENT, PROCESS FOR THEIR PRODUCTION, THEIR USE AND SOLIDS COATED WITH THEM.
JPH0786133B2 (en) * 1986-03-13 1995-09-20 大日本インキ化学工業株式会社 Thixotropic coating composition
US4683279A (en) * 1986-07-08 1987-07-28 Air Products And Chemicals, Inc. Low melting urethane linked toluenediisocyanates
DE3706151A1 (en) * 1987-02-26 1988-09-08 Bayer Ag POLYHANE-MODIFIED POLYETHERURETHANES AND THEIR USE AS EMULSION SPLITTERS FOR WATER-IN-OIL EMULSIONS
US4942213A (en) * 1987-12-04 1990-07-17 Byk-Chemie Gmbh Addition compounds useful as dispersing agents and dispersion stabilizers, process for producing them, their use and solids coated therewith
JP2974491B2 (en) * 1992-03-05 1999-11-10 共栄社化学株式会社 Anti-sagging agent for non-aqueous paints
DE19636382A1 (en) * 1996-09-09 1998-03-12 Bayer Ag Pigment preparations for ink jet printing
DE19919482C2 (en) * 1999-04-29 2001-04-26 Byk Chemie Gmbh Process for the preparation of a thixotropic agent and its use
JP3904349B2 (en) * 1999-08-05 2007-04-11 三井化学株式会社 Thixotropic agent and method for producing the same

Also Published As

Publication number Publication date
CN1204117C (en) 2005-06-01
CA2352660A1 (en) 2002-02-16
DE10039837A1 (en) 2002-03-07
EP1188779A1 (en) 2002-03-20
ATE268790T1 (en) 2004-06-15
EP1188779B1 (en) 2004-06-09
KR20020014680A (en) 2002-02-25
ES2220631T3 (en) 2004-12-16
TWI226892B (en) 2005-01-21
JP4942262B2 (en) 2012-05-30
CA2352660C (en) 2008-10-21
JP2002105042A (en) 2002-04-10
CN1338453A (en) 2002-03-06
DE10039837C2 (en) 2003-03-20
KR100796040B1 (en) 2008-01-21
DE50102521D1 (en) 2004-07-15

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