DE69633869D1 - Molybdan-modifierte vanadin-phosphor-oxidkatalysatoren zur herstellung von maleinsäureanhydrid - Google Patents

Molybdan-modifierte vanadin-phosphor-oxidkatalysatoren zur herstellung von maleinsäureanhydrid

Info

Publication number
DE69633869D1
DE69633869D1 DE69633869T DE69633869T DE69633869D1 DE 69633869 D1 DE69633869 D1 DE 69633869D1 DE 69633869 T DE69633869 T DE 69633869T DE 69633869 T DE69633869 T DE 69633869T DE 69633869 D1 DE69633869 D1 DE 69633869D1
Authority
DE
Germany
Prior art keywords
molybdan
phosphoroxide
vanadin
catalysts
manufacture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69633869T
Other languages
English (en)
Other versions
DE69633869T2 (de
Inventor
R Felthouse
A Keppel
J Schaefer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huntsman Specialty Chemicals Corp
Huntsman Petrochemical LLC
Original Assignee
Huntsman Specialty Chemicals Corp
Huntsman Petrochemical LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huntsman Specialty Chemicals Corp, Huntsman Petrochemical LLC filed Critical Huntsman Specialty Chemicals Corp
Publication of DE69633869D1 publication Critical patent/DE69633869D1/de
Application granted granted Critical
Publication of DE69633869T2 publication Critical patent/DE69633869T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00819—Materials of construction
    • B01J2219/00835—Comprising catalytically active material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)
DE69633869T 1995-10-02 1996-09-24 Molybdan-modifierte vanadin-phosphor-oxidkatalysatoren zur herstellung von maleinsäureanhydrid Expired - Lifetime DE69633869T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US538005 1983-09-30
US08/538,005 US5945368A (en) 1995-10-02 1995-10-02 Molybdenum-modified vanadium-phosphorus oxide catalysts for the production of maleic anhydride
PCT/US1996/015724 WO1997012674A1 (en) 1995-10-02 1996-09-24 Molybdenum-modified vanadium-phosphorus oxide catalysts for the production of maleic anhydride

Publications (2)

Publication Number Publication Date
DE69633869D1 true DE69633869D1 (de) 2004-12-23
DE69633869T2 DE69633869T2 (de) 2005-03-17

Family

ID=24145033

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69633869T Expired - Lifetime DE69633869T2 (de) 1995-10-02 1996-09-24 Molybdan-modifierte vanadin-phosphor-oxidkatalysatoren zur herstellung von maleinsäureanhydrid

Country Status (4)

Country Link
US (2) US5945368A (de)
EP (1) EP0876212B1 (de)
DE (1) DE69633869T2 (de)
WO (1) WO1997012674A1 (de)

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US6107234A (en) * 1999-01-29 2000-08-22 Scientific Design Company, Inc. Phosphorus/vanadium maleic anhydride catalyst preparation
WO2001052983A1 (en) * 2000-01-20 2001-07-26 E.I. Dupont De Nemours And Company Vanadium-phosphorus oxide catalysts with promoter reagents
DE10011309A1 (de) 2000-03-10 2001-09-13 Basf Ag Verfahren zur Herstellung von Maleinsäreanhydrid
DE10011307A1 (de) 2000-03-10 2001-09-13 Basf Ag Katalysator und Verfahren zur Herstellung von Maleinsäureanhydrid
DE10046072A1 (de) * 2000-09-15 2002-03-28 Basf Ag Katalysator-Precursor für die Herstellung von Maleinsäureanhydrid
WO2003006414A2 (en) * 2001-07-12 2003-01-23 Exxonmobil Chemical Patents Inc. Producing maleic anhydride from a c4 stream in an oxygenate to olefin process
AU2003222279C1 (en) * 2002-03-11 2009-04-09 Battelle Memorial Institute Microchannel reactors with temperature control
DE10211445A1 (de) 2002-03-15 2003-10-02 Basf Ag Katalysator-Precursor für die Herstellung von Maleinsäureanhydrid und Verfahren zu dessen Herstellung
DE10211446A1 (de) 2002-03-15 2003-10-02 Basf Ag Verfahren zur Herstellung eines Vanadium, Phosphor und Sauerstoff enthaltenden Katalysators
DE10235355A1 (de) 2002-08-02 2004-02-19 Basf Ag Verfahren zur Herstellung von Maleinsäureanhydrid
US7404936B2 (en) * 2002-10-22 2008-07-29 Velocys Catalysts, in microchannel apparatus, and reactions using same
DE10334582A1 (de) 2003-07-28 2005-02-24 Basf Ag Verfahren zur Herstellung von Maleinsäureanhydrid
TW200719968A (en) * 2005-10-31 2007-06-01 Sued Chemie Ag Catalyst molding for partial oxidation reactions
US7619099B2 (en) * 2006-04-17 2009-11-17 Scientific Design Company, Inc. Reduction of acrylic acid in the production of maleic anhydride
US20070270597A1 (en) * 2006-05-18 2007-11-22 Basf Aktiengesellschaft Process for preparing maleic anhydride in a microchannel reactor
DE102007025869A1 (de) 2007-06-01 2008-07-03 Basf Se Verfahren der Wiederbeschickung der Reaktionsrohre eines Rohrbündelreaktors mit einem neuen Katalysatorfestbett
JP5360834B2 (ja) * 2008-03-25 2013-12-04 バブコック日立株式会社 鉄化合物の影響を抑制した排ガス浄化触媒
US20110257414A1 (en) 2008-12-22 2011-10-20 Basf Se Catalyst molded bodies and method for producing maleic acid anhydride
CN102325592B (zh) 2008-12-22 2014-12-10 巴斯夫欧洲公司 用于生产马来酸酐的催化剂及方法
US20120149919A1 (en) 2009-08-26 2012-06-14 Basf Se Maleic anhydride synthesis catalyst precursor and process for its preparation
DE102010040923A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Ethanol und Formaldehyd
DE102010040921A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Methanol und Essigsäure
DE102010052126A1 (de) 2010-11-22 2012-05-24 Süd-Chemie AG Katalysatorformkörper für durchströmte Festbettreaktoren
US8658557B2 (en) * 2011-10-25 2014-02-25 Ineos Usa Llc Catalyst for n-butane oxidation to maleic anhydride
US8785344B2 (en) 2012-02-20 2014-07-22 Basf Se Gas phase oxidation catalyst with low charge transport activation energy
CN103691467B (zh) * 2012-09-27 2016-01-13 中国石油化工股份有限公司 一种催化剂及其制备方法和应用
DE102013008207A1 (de) 2013-05-14 2014-11-20 Basf Se Verfahren zur Herstellung von Acrylsäure mit hoher Raum-Zeit-Ausbeute
DE102013008206A1 (de) 2013-05-14 2014-11-20 Basf Se Verfahren zur Herstellung von Vinylidencarbonsäure(ester)n durch Umsetzung von Formaldehyd mit Alkylcarbonsäure(estern)n
US9073846B2 (en) 2013-06-05 2015-07-07 Celanese International Corporation Integrated process for the production of acrylic acids and acrylates
US9120743B2 (en) 2013-06-27 2015-09-01 Celanese International Corporation Integrated process for the production of acrylic acids and acrylates
DE102014004786B4 (de) * 2014-04-02 2021-09-30 Clariant International Ltd. Alkalimetall-modifizierter Vanadium-Phosphor-Oxid (VPO)-Katalysator
DE102017000865A1 (de) 2017-01-31 2018-08-02 Clariant Produkte (Deutschland) Gmbh Synthese eines MoVNbTe-Katalysators mit erhöhter spezifischer Oberfläche und höherer Aktivität für die oxidative Dehyxdrierung von Ethan zu Ethylen
DE102019100983A1 (de) 2019-01-16 2020-07-16 Clariant International Ltd Verfahren zur herstellung eines vpo-katalysators
IT201900013167A1 (it) 2019-07-29 2021-01-29 Polynt S P A Letto catalitico multistrato per l'ossidazione parziale di n-butano ad anidride maleica.
DE102019127789A1 (de) * 2019-10-15 2021-04-15 Clariant International Ltd. Neues Katalysatorsystem für die Herstellung von Maleinsäureanhydrid durch katalytische Oxidation von n-Butan
CN113842934B (zh) * 2020-06-28 2023-07-21 中国石油化工股份有限公司 一种氧化催化剂及其制备方法与应用
CN114433151B (zh) * 2020-10-31 2024-02-13 中国石油化工股份有限公司 一种钒磷氧催化剂及其制备方法和应用
CA3230756A1 (en) 2021-09-14 2023-03-23 Carlotta Cortelli Catalyst for the partial oxidation of n-butane to maleic anhydride
EP4357019A1 (de) 2022-10-21 2024-04-24 Clariant International Ltd Vpo-katalysator mit verbesserter selektivität und stabilität sowie verfahren zu dessen herstellung
WO2024084002A1 (en) 2022-10-21 2024-04-25 Clariant International Ltd Mechanically stable vpo catalyst and process for the production thereof
DE102022004204A1 (de) 2022-11-12 2024-05-23 Hans-Jürgen Eberle Vefahren zur Herstellung von Maleinsäureanhydrid

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US3919257A (en) * 1973-02-09 1975-11-11 Standard Oil Co Ohio Catalytic vapor phase oxidation of n-butene to maleic anhydride using two different catalysts maintained in two distinct and separate portions of the reaction zone
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Also Published As

Publication number Publication date
US5945368A (en) 1999-08-31
US5929256A (en) 1999-07-27
EP0876212B1 (de) 2004-11-17
DE69633869T2 (de) 2005-03-17
WO1997012674A1 (en) 1997-04-10
EP0876212A1 (de) 1998-11-11

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